Chemistry Form 4 End-Year Holiday Exercise

CHAPTER 3
1. In an experiment , 1.12 g of metal X is burnt in oxygen o produce 1.6 g of metal
X oxide.
What is the empirical formula of metal x oxide ?
[ Relative atomic mass : O, 16; X, 56 ]
A
2.

Na2SO3

C Na2S2O3

D Na2S2O8

B XY

C XY 2

D X2Y3

B T 2S

T 3S4

D T 4S

B RO 3

R2O3

D R 3O2

B 32

C 42

D 56

What is the maximum quantity of iron that can be extracted from 116 g of
Fe3O4 ?
[ Relative atomic mass: O,16; Fe, 56 ]
A 1.0 mole

8.

B Na2SO4

A compound with the formula of R3T4 is formed by the reaction between 42.0 g of
R and 16.0 g of T . What is the relative atomic mass of R ?
[ Relative atomic mass; T, 16 ]
A 14

7.

X2O3

0.25 moles of R combine with 12 g of oxygen to form an oxide.Which of the

following is
the empirical formula for the oxide of R ?
A R3O

6.

24 g of an element T reacts with 32 g of sulphur to form a compound.What is

the most
likely formula for this compound ?
[ Relative atomic mass , T, 6; S, 32 ]
A TS

5.

C X 2O

2.43 g of an element X combines with 1.60g of another element.what is the

empirical
formula for the resulting compound ?
[ Relative atomic mass : X= 24.3 ; Y, 16 ]
A X2Y

4.

B XO 2

One compound has the percentage composition by mass as follow : Na , 36.5 %;

S, 25.4%, and 38.10% of oxygen.What is the empirical formula of this
compound ?
[ Relative atomic mass, Na, 23; S, 32; O,16 ]
A

3.

XO

B 1.5 mole

C 2.0 mole

D 2.5 mole

A metal X forms a sulphate with the formula X2(SO4)3. What is the formula of the
nitrate of X ?
A XNO3

B X(NO 3)3

C X3NO3

D X 2NO3

9.

12.4 g of phosphorus reacts completely with 9.6 g of oxygen gas.Which of the

following is
the correct equation for the reactions ? [ P, 31 ; O, 16 ]
A P
B 3P
C 4P
D 4P

10
.

PO2
P 3 O4
2P2O3
2 P2O5

18

27

36

50

The heating reaction of potassium nitrate is represented by the equation below :

2 KNO3
2 KNO2 + O2
What is the minimum volume of gas released when 1.01 g of potassium nitrate
is
heated at room condition ?
[ Relative atomic mass: N, 14; O,16; K,39; 1 mol of gas occupies 24 dm 3 at room
condition]
A

12
.

O2
2 O2
3 O2
5 O2

The oxide for an element T has the formula T 2O3 and its relative molecular mass
is 102.
What is the relative atomic mass for T ?
[ Relative atomic mass : O, 16 ]
A

11
.

+
+
+
+

0.06

0.12

1.2

D 2.4

With the presence of a catalyst, hydrogen peroxide decomposes according to the

equation:
2 H2O2

2 H2 O

+ O2

If 4 moles of hydrogen peroxide is used, what is the volume of oxygen gas

produced at s.t.p? [1 mol of gas occupies 22.4 dm 3 at s.t.p]
A 22.4 dm3
13
.

2 Ca +

40.4

dm3

44.8 dm3

2 CaO

4.0 g

5.6 g

22.4 g

4.2 g of element X reacts with 9.6 g of element Y to form a compound with the
chemical
formula X2Y4. Given that the relative atomic mass of X is 14, find the relative
atomic mass
of Y.
A

15

O2

4 g of calcium burns completely in air to form calcium oxide. Find the mass of
calcium
oxide produced. [ Ca, 40; O, 16 ]
A 1.6 g

14
.

30.8 dm3

16

32

Hydrated magnesium sulphate is heated according to the equation below :

MgSO4 . 7 H2O (s)

MgSO4(s) +

7 H2O (g)

How many moles of water vapour is released when 54 g of magnesium sulphate

is produced ?
[ Relative atomic mass : Mg 24; O, 16; S, 32 ; H, 1 ]
A
16
.

2.7 g

5.4

8.1 g

D 10.8 g

Write a balanced equation in the chemical formula for the reaction below :
Aluminium
A
B
C
D

18
.

C 3.15 mol
D 6.3 mol
Al2O3 (s) + 3 Cu(s)

Find the mass of aluminium required to react completely with 24 g of copper(II)

oxide.
[ Relative atomic mass; O, 16; Al, 27 ; Cu, 64 ]
A

17
.

0.45 mol
B 4.5 mol
2 Al (s)
+ 3 CuO (s)

2 Al (s)
2 Al (s)
Al(s)
2 Al(s)

Iron (III) oxide

Aluminium oxide

+ Fe 2O3(s)
+ Fe 2O3(s)
+ Fe2O3 (s)
+ Fe 2O3 (s)

Al2O3
Al2O3
Al2O3
Al2O3

(s)
+ 2
(s)
+ 2
(g ) + 2
(s) + Fe

+ Iron

Fe(s)
Fe(g)
Fe(s)
(s)

Ammonia gas is formed in Haber Process according to the chemical equation

below :
N2 (g)

3 H2 ( g)

2 NH3(g)

Calculate the volume of hydrogen needed to produced 100 cm 3 of ammonia at

room conditions.
[ Relative atomic mass : N, 14 ; H, 1 ; 1 mole of gas occupies 24 dm 3 at room
conditions]
A 50 cm3
19
.

100 cm3

150 cm3

200 cm3

Sodium hydrogen carbonate decomposes on heating according to the following

equation :
2 NaHCO3 (s)

Na2CO3 (s) + CO2 (g) + H2 O (l)

If 10.0 g of sodium hydrogen carbonate is used, what is the mass of sodium

carbonate that is produced ?
[ Relative atomic mass : C, 12 ; O, 16 , Na, 23 ; H, 1 ]
A 6.4 g
20
.

5.4 g

C 5.0 g

D 2.4 g

Copper carbonate decomposes according to the equation below :

CuCO3(s)

CuO(s)

+ CO2(g)

If 24.8 g of copper carbonate is used, what is the volume of carbon dioxide

produced ?
[1 mol of gas occupies 22.4 dm3 at s.t.p]
A

5.24 dm3

2.24 dm3

3.48 dm3

D 4.48 dm3

CHAPTER 6
1. The figure 1 below shows the apparatus used in the electrolysis of molten lead(II)
bromide.

Figure 1
a) What is electrolysis ?

...[ 2 marks ]
b) State the meaning of
i)

cations :

ii)

anions :

iii)

cathode :
.

iv)

anode :

[ 4 marks]
c) Identify the anions and cations present in molten lead (II) bromide.

.[ 1 mark ]
d) Which ions are attracted to
i) anode : .
[ 2 marks]

ii) cathode :

e) Write the half equation of the discharge that occurs at the

i)

anode : ..
ii)
cathode : .
marks]

[2

f) If molten lead (II) bromide is replaced by molten sodium chloride, predict the
product
formed at
i) anode : ..
marks]

ii) cathode: ..

[2

2. The Figure 2 below shows the apparatus used to study by the electrolysis of
copper
(II) chloride solution.

Figure 2
The electrolysis is carried out using aqueous 0.001 mol dm -3 copper(II) chloride
solution
and carbon electrodes.
a) Write the formulae of all ions found in the copper (II) chloride solution.


.[ 1 mark]
b) What is observed at the electrode Y during the electrolysis ?

[ 2 marks ]
c) i) Name the product formed at the electrode X.

.[ 1 mark]
ii) State one test to verify that the product formed at electrode X is the product you
named in (i).

[ 2 marks]
d) Write the half equation for the reaction that takes place at electrode X.

.[ 1 mark]
e) i) If the experiment is repeated by using 2.0 moldm -3 aqueous copper(II) chloride
solution,
what product will be formed at electrode X ?

..[ 1 mark]

ii) Explain why the product you mentioned in (e) (i) is formed.

..
[ 2 marks]
3. Figure 3 below shows the set up of apparatus to purified a sample of impure
copper
( containing zinc and silver as impurities ) by electrolysis.

Figure 3
a) In order to refine the impure copper as in the apparatus shown, which one of the
pole
R or S is the anode ?

[ 2 marks]
b) Name a suitable electrolyte used in the process.

.[ 1 mark]
c) What happens to impure copper electrode during electrolysis? Write one equations
for the
changes.

[ 2 marks]
d) i) Would the impurities deposited on the cathode ?

..[ 1 mark]
ii) Explain your answer in (d) (i).

[ 2 marks]
e) i) What would be observed at the cathode ?


.[ 1 mark]
ii) Write an ion-electron equation to explain the observation in (e) (i).

..[ 2 marks]

4. Figure 4 below shows a voltaic cell from zinc and lead.

Figure 4
a) What is salt bridge ? What is its function ?

[ 2 marks]
b) What is the conversion of energy that takes place in the cell ?

..[ 1 mark]
c) i) In which direction do electrons flow through the circuit in Figure 4 ?

.[ 1 mark]
ii) Which is the negative terminal of the cell ?Give a reason to your answer.


..[ 2 marks]
d) i) Name the product formed at the iron electrode.

..[ 1 mark]
ii) Write an equation for the reaction that occurs.

..[ 1 mark]
e) Write an equation for the overall reaction that occurs in the voltaic cell.

..[ 1 mark]
f) What happens to the cell voltage if the iron electrode is replaced with the copper
electrode ?

.[ 1 mark]

CHAPTER 7 (OBJECTIVE QUESTIONS

1.
When 2.0 g of sodium hydroxide are present in 500 cm 3 of its solution,what is its
molarity?
[ Relative atomic mass : Na, 23 ; O, 16; H , 1 ]
A 0.001 moldm-3
mol dm-3
2.

0.1 moldm-3

D 1.0

0.01

0.02

0.10

D 0.20

What is the concentration of hydroxide ions when 8.55 g of barium hydroxide is

dissolved
in water to produce 250 cm3 of solution ?
[ Relative atomic mass : Ba, 137 ; O, 16 ; H, 1 ]
A

4.

0.01 moldm-3

Calculate the number of moles of sulphuric acid in 100 cm 3 0.2 moldm-3 of its
solution ?
[ Relative atomic mass : H,1 ; S, 32 ; O, 16 ]
A

3.

0.01

0.05

0.20

D 0.40

200 cm3 of 0.5 moldm-3 of hydrochloric acid was prepared from a standard
solution of
2 moldm-3 hydrochloric acid. Calculate the volume of the standard solution
needed to be
dilute with acid ?
A

50 cm3

75 cm3

100 cm3

D 150 cm3

5.

What is the mass of potassium hydroxide powder used to produce 100 cm 3 of

0.5 moldm-3
potassium hydroxide solution ?
[ Relative atomic mass : O, 16; K, 39, H,1 ]

A 1.4
B 2.8
C 4.2
D 5.6
Calculate the volume of water needed to be added to 40 cm 3 of 2.0 moldm-3
sulphuric acid
to obtain 80 cm3 of 1 moldm-3 sulphuric acid .
A 20 cm3

B 40 cm3

60 cm3

D 80 cm3

Questions 7 and 8 are based on the information below :

Zinc powder reacts with hydrochloric acid to produce zinc chloride and
hydrogen gas,
according to the equation :
Zn(s) + 2 HCl(aq)
7.

Calculate the mass of zinc chloride that is formed when 1.3 g of zinc powder
reacts with
excess hydrochloric acid.
[ Relative atomic mass : Zn, 65; Cl, 35.5 ]
A 1.36

B 2.72

120 cm3

6.72

240 cm3

C 360 cm3

D 480 dm3

B 0.5 moldm-3

1.0 moldm-3

2.0 moldm-3

H2SO4 + 2 LiOH
Li2SO4 + 2 H2O
50 cm3 of 0.1 moldm-3 sulphuric acid is neutralized by 100 cm 3 of lithium
hydroxide solution.
What is the concentration of lithium hydroxide solution used in the reaction ?
A 0.005 moldm-3

11
.

2 HNO3 + Ba(OH)2
Ba(NO3)2 + 2 H2O
25 cm3 of 0.5 mol dm-3 nitric acid reacts with 25 cm3 of barium hydroxide
solution. What is
the concentration of barium hydroxide solution ?
A 0.25 moldm-3

10
.

C 3.48

Calculate the volume of the hydrogen gas released at room conditions when 1.3
g of zinc
powder reacts with excess hydrochloric acid.
[ Molar volume : 24 dm3mol-1 at room conditions ]
A

9.

ZnCl2 (aq) + H2 (g)

Na2CO3 + 2 HCl

B 0.1 moldm-3

C 0.2 moldm-3

D 0.025 moldm-3

2 NaCl + CO2 + H2O

Based on the equation above, what is the volume of gas released at room

10

condition if
25 cm3 of 0.5 moldm-3 hydrochloric acid reacts with sodium carbonate ?
[ Relative atomic mass : H, 1; C, 12; O, 16; Na,23; Cl 35.5; 1 mol of gas occupies
24dm3 at
room condition ]
A 0.15
12
.

0.30

C 0.24

D 0.50

The equation below represents the reaction between hydrogen sulphide and
nitric acid.
3 H 2S

+ 2 HNO3

3 S + 2 NO

+ 4 H2O

What is the mass of nitrogen monoxide gas released if 240 cm 3 of hydrogen

sulphide gas
completely reacts with nitric acid at room condition ?
[ Relative atomic mass : N, 14; O, 16; 1 mol of gas occupies 24 dm 3 at room
condition ]
A 0.2
13
.

B 0. 23

C 0.3

D 0.34

In the reaction below, 50 cm3 of hydrochloric acid completely reacts with

magnesium ribbon
to produce 120 cm3 of hydrogen gas at room condition.
Mg +

2 HCl

Mg Cl2 + H2

What is the concentration of the hydrochloric acid used ?

[ 1 mol of gas occupies 24 dm3 at room condition ]
A

14
.

0.01

C 0.1

D 0.2

H2SO4 + Pb(NO3)2
PbSO4 + 2 HNO3
Calculate the volume of 0.2 moldm-3 sulphuric acid, H2SO4 that is needed to
react completely with 10 cm3 of 0.5 moldm-3 of lead(II) nitrate, Pb(NO3)2 solution.
A

15
.

0.005

5 cm3

10 cm3

C 15 cm3

D 25 cm3

Calcium carbonate reacts with hydrochloric acid according to the chemical

equation:
CaCO3

+ 2 HCl

CaCl2

+ CO2

+ H 2O

What is the mass of calcium carbonate that is required to produce 600 cm 3 of

carbon
dioxide gas at room conditions when it reacts with excess hydrochloric acid ?
[ Relative atomic mass : Ca, 40; C, 12 , O, 16. Molar volume : 24 dm 3mol-1 at
room
conditions ]
A 2.5 g
16

3.5 g

C 6.5 g

D 25 g

5 cm3 of lead (II) nitrate solution requires 20 cm 3 of 0.3 moldm-3 potassium

11

iodide solution
to react completely according to the ionic equation below :
Pb2+ (aq)

+ 2 I- (aq)

PbI2 (s)

What is the concentration of the lead(II) nitrate solution in moldm -3 ?

A
17
.

2.4 g

0.6

0.9

D 1.2

B 4.8 g

C 6.0 g

D 14.4 g

AgNO3 + KI
AgI + KNO3
Calculate the mass of silver iodide, AgI produced when 25 cm 3 of 1.5 moldm-3
silver nitrate, AgNO3 is mixed with 50 cm3 of 0.5 moldm-3 potassium iodide, KI
solution.
[ Relative atomic mass : Ag ,108; I, 127 ]
A 2.5 g

19
.

CuO + 2 HNO 3
Cu(NO3)2 + H2O
Copper (II) oxide powder reacts with excess nitric acid to produre copper(II)
nitrate and
water .If 11.28 g of copper(II) nitrate is formed, calculate the mass of copper (II)
oxide
used in the reaction.
[ Relative atomic mass; Cu, 64; N, 14; O, 16 ]
A

18
.

0.3

3.75 g

5.875 g

D 8.813 g

Nitric acid reacts with metal X to produce a salt according to the chemical
equation below:
X + 2 HNO3

X ( NO3)2 + H2

Calculate the volume of 1.5 moldm-3 nitric acid that is needed to completely react
with
0.54 g of metal X.
[ Relative atomic mass : X, 24 ]
A

20
.

15 cm3

20 cm3

30 cm3

45 cm3

10 cm3 of 0.25 moldm-3 T(OH)x solution is neutralized by 5 cm3 of 1.0 moldm-3

HxU solution.
The salt produced from the reaction is
A

TU

T2U

C TU 2

T3U2

CHAPTER 7 (STRUCTURE QUESTIONS)

12

1. The Figure 1 below shows the apparatus set-up of an activity to determine the end
point
in the titration of sulphuric acid and sodium hydroxide solution.

Figure 1
The results of the titration are shown in the table below.
Titration

Final burette reading ( cm3)

15.85

16.10

16.20

Initial burette reading ( cm3)

0.80

1.10

1.25

Volume of sulphuric
acid( cm3 )
a) Complete the table above.
marks]

.[2

b) What does end point mean ?

[ 2 marks]
c) Describe the colour change in the sodium hydroxide solution at the end point.

.
[ 2 marks]
d) The burette is rinsed with a small amount of dilute sulphuric acid before it is filled
with dilute
sulphuric acid. Explain why.

13


..

.
[ 2 marks]
e) Write an equation for the titration.

..
[ 2 marks]
f) Based on the results, calculate the average volume of the dilute sulphuric acid
used.

[2
marks]
g) Determine the concentration of the dilute sulphuric acid.

[3
marks]
h) Predict the volume of nitric acid needed to achieve the end point if the dilute
sulphuric acid
is replaced with acid of the same concentration. Why ?

[ 2 marks]
2. Dilute sulphuric acid is added slowly from a burette to barium hydroxide solution
in a beaker
as shown in Figure 2

14

Figure 2
a) What ions are present in the barium hydroxide solution ?

. [ 2 marks]
b) What ions are present in the dilute sulphuric acid ?

[ 2 marks]
c) What can be seen in the barium hydroxide solution when the dilute sulphuric acid
is added ?

.[ 2 marks]
d) Table 1 shows the results of the experiment.

Table 1

Volume of
dilute sulphuric acid
( cm3)
0
5
10
15
20
25
30

Brightness of the
bulb
Bright
Dimmer
Even dimmer
Goes of
Dim
Less dim
Bright

Sketch a graph show how the brightness of the bulb changes with the volume of
dilute
sulphuric acid added

15

[ 3 marks]
.
e) Explain the shape of the graph sketch in (d).

[6
marks]
3. 0.1 mol dm-3 hydrochloric acid from a burette is added little by little into a
conical flask
containing 10.0 cm3 of barium hydroxide and a few drops of methyl orange until
the end
point is reached. The burette readings of the hydrochloric acid before and after
the titration
are shown in Figure 3.

Figure 3
a) Based on Figure 3, record the initial and final readings into the table below:
Final burette reading( cm3)
Initial burette reading ( cm3)
Volume of hydrochloric acid
( cm3 )

[ 2 marks]

b) State the change in colour of the methyl orange at the end point of titration.

.[ 2 marks]

16

c) Name a suitable apparatus used to measure 10.0 cm 3 of barium hydroxide

solution.

.[ 1 mark]
d) Name the reaction that occurs in the conical flask.

.[ 1 mark]
e) What precaution must be taken when hydrochloric acid from the burette is added
to the
barium hydroxide solution in the conical flask ?

.[ 1 mark]
f) Calculate the concentration of barium hydroxide in mol dm -3.

[4
marks]
4. A student added 1 cm3 portion of an acid HA to 25 cm3 of 0.10 mol dm-3 sodium
hydroxide .
After each addition of acid , the student measured the pH of the mixture by using
a
pH meter. From the results, the student drew the titration curve shown below.

Figure 4
a) Name the chemical reaction that occurred.

17


[ 1 mark]
b) What is the pH of a neutral solution ?

.[ 1 mark]
c) What is the property of the acid, HA ?

.[ 1 mark]
d) Suggest a suitable acid for HA.

..[ 1 mark]
e) i) What is the volume of acid needed to neutralize the alkali ?

.[ 1 mark]
ii) Write a balance equation for the reaction between HA and sodium hydroxide ?

.[ 2 marks]
iii) Calculate the concentration in moldm-3 of acid HA.

[3
marks]

CHAPTER 7 (ESSAY QUESTIONS)

(a) By using one named example of a strong acid, explain the chemical
properties of an acid.
Include the chemical equations in your explanation.
Dengan menggunakan satu contoh asid kuat, terangkan sifat kimia
asid.
Sertakan persamaan-persamaan kimia dalam penerangan anda.
Aras tinggi [6 marks]
(b) Table 1 shows the observation when solution A and B is tested with a
blue litmus paper,
Jadual 1 menunjukkan pemerhatian apabila larutan A dan larutan B
18

diuji dengan kertas litmus biru.

A
B

Solution / Larutan
Ethanoic acid in water
Asid etanoik dalam air

Observation / Pemerhatian
Blue litmus paper turns red
Kertas litmus biru bertukar
merah
No change
Tiada perubahan

Ethanoic acid in propanone

Asid etanoik dalam propanon

TABLE 1 / JADUAL 1
Based on Table 1, explain the diference in the observation
Berdasarkan Jadual 1, terangkan perbezaan dalam pemerhatian itu
Aras tinggi
[4 marks]
2

The following information is about two diferent alkalis.

Maklumat di bawah adalah mengenai dua alkali yang berlainan.
Alkali
Alkali

Concentration/mold
m-3
Kepekatan /moldm-3

pH
pH

Sodium hydroxide
solution
Larutannatriumhidroksi
da

0.1

13

Ammonia solution
Larutan ammonia

0.1

10

Explain why the two alkalis have diferent pH values.

Terangkan mengapa dua alkali tersebut mempunyai nilai pH yang
berlainan.
Aras tinggi [6marks]

The following information is about two diferent acids.

Maklumat di bawah adalah mengenai dua asid yang berlainan.
Acid
asid

Concentration/mold
m-3
Kepekatan /moldm-3

pH
pH

Hydrochloric acid

0.1

1
19

solution
Larutanasidhidroklorik
Etanoic acid solution
Larutanasidetanoik

0.1

Explain why the two acids have diferent pH values.

Terangkan mengapa kedua-dua asid tersebut mempunyai nilai pH yang
berbeza.
Aras tinggi [6marks]
4

A student wanted to prepare 250 cm3 standard solution of sodium

hydroxide with a concentration of 1.0 mol dm-3 in the school
laboratory.
Seorang pelajar ingin menyediakan 250cm3 larutan piawai natrium
hidroksida dengan kepekatan 1.0 mol dm-3dalam makmal sekolah.
Describe how the student would prepare the solution.
Include the following in your description :
The material and apparatus needed,
The calculation involved,
The steps involved in the preparation.
Huraikan bagaimana pelajar itu dapat menyediakan larutan tersebut.
Sertakan yang berikut dalam huraian anda :
Bahandanradas yang perlu,
Pengiraan yang terlibat,
Langkah-langkah yang terlibatdalampenyediaan
[ Relative atomic mass : H, 1 ; O, 16 ; Na, 23 ]
[10 marks]
Aras tinggi

CHAPTER 8 (STRUCTURE)

Table below shows an experiment to investigate the effect of heat on

copper(II) carbonate.
Diagram
Gambar rajah

Procedure
Prosedur

Observation
Pemerhatian

20

CuCO3
Heat
Panaskan

Lime water
Air kapur

Copper(II)carbonate is
heated and the gas
produced is passed
through lime water.

Green solid turns

black.
The lime water turns
milky.

Kuprum(II) karbonat
dipanaskan dan gas
yang terhasil dialirkan
melalui air kapur.

Pepejal hijau
menjadi hitam.
Air kapur menjadi
keruh.

Based on the experiment :

(i) state the name of the products formed.

(ii)

[1 mark]
write a chemical equation for the reaction.

[1 mark]

Diagram shows two chemical reactions involving salt J.

Rajah menunjukkan dua tindak balas kimia melibatkan garam J.

larut dalam air

Use the information in the Diagram to answer the following questions.

Gunakan maklumat dalam Rajah itu untuk menjawab soalan-soalan berikut.

(a)

State the name of salt J.

Nyatakan nama garam J.
.
[1 mark]

(b)

Explain how you would carry out a simple test to confirm oxygen gas is
produced when salt J is heated in a test tube.
21

Terangkan bagaimana anda boleh menjalankan satu ujian ringkas untuk

mengesahkan gas oksigen terhasil apabila garam J dipanaskan.

(c)

(d)

(e)

............................................................................................................................
...........................................................................................................................
[2 marks] KBAT
State two observations when salt J is heated in a test tube?
Nyatakan dua pemerhatian apabila garam J dipanaskan dalam sebuah
tabung uji.?
.
.
[2 marks]
Write a chemical equation for the decomposition of salt J by heat
Tuliskan persamaan kimia bagi penguraian garam J oleh haba.
............................................................................................................................
[2 marks]
(i)
Name aqueous solution T / Namakan larutan akueus T.

(ii)

(f)

...................................................................................................................
[1 mark]
What is the name for the type of reaction between solution J with
solution T?
Apakah nama bagi jenis tindakbalas antara larutan J dengan larutan T?

.
[1 mark]
What is observed when an acidified solution of salt J is shaken with iron(II)
sulphate solution in a test tube and then concentrated sulphuric acid is added
slowly down the side of the test tube.
Apakah yang diperhatikan apabila larutan garam J berasid ditambahkan
larutan ferum(II) sulfat dalam sebuah tabung uji dan kemudian asid sulfurik
pekat ditambahkan dengan perlahan ke bawah melalui sisi tabung uji itu.
.
[1 mark]

CHAPTER 8 (ESSAY)

22

You are
required
to prepare dry
You are required to prepare a sample
of dry
zinc nitrate.
Describe a laboratory experiment
to prepare
the salt.
barium
sulphate
salt.
Include these in your answer :
Name of the reactants
(i)
Suggest two solutions to
List of apparatus
prepare barium sulphate
Procedure
salt.
Chemical equation.

(ii)

Describe a

Aras
tinggi [10 marks] KBAT
laboratory

experiment to
prepare the salt. In
your description,
include the chemical
equation and ionic
equation.

Aras tinggi [10marks]

KBAT
Two solutions are used to prepare carbonate salt. Diagram below shows the
reaction scheme in preparing Copper (II) Carbonate.
Blue solution of X
Larutan biru X

Method A
Kaedah A

Colourless
solution of Y
Larutan tidak
berwarna Y

Copper (II) Carbonate

Kuprum (II) Karbonat

Heated
Dipanaskan

Black residue
Baki hitam

Process 1
In process I, solution X and Y are mixed and green precipitate is
formed.
(a) (i)

Name the blue solution X and colourless solution Y in diagram

10.
Aras rendah [2 marks]
(ii)

Name the Method A.

Aras rendah [1 mark]

(iii)

Write the balanced chemical equation for the reaction in

process I.
Aras tinggi [2 marks]
(iv)
solution of
(b) (i)

State a confirmatory test to verify the cation present in the

X.
Aras sederhana [2 marks]
Name the black residue.
Aras rendah [1 mark]
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(ii)

Describe how you would prepare Copper (II) carbonate through

Method A by using a suitable salt solution.
Your answer should consist of the following:
List of material and apparatus
Procedures of the experiment
Aras tinggi [10 marks] KBAT

(c) Calculate the mass of the silver salt precipitated if 50 cm3 of 1.0
mol dm-3
silver nitrate, AgNO3 solution react completely with magnesium
chloride,
MgCl2 solution. [Relative atomic mass: Ag, 108; Cl, 35.5]
Aras tinggi [2 marks] KBAT
ANSWERS
CHAPTER 3 (OBJ Qs)
Answer :
1. D
2. A
3. B
4. D
5. B
6. D
7. B
8. B
9. C
10. B
11. B
12. D
13. C
14. C
15. C
16. B
17. A
18. C
19. A
20. D

CHAPTER 6 (STRUCTURE)

1. a) Decomposition of a compound in molten or aqueous state into its constituent

elements
when electricity is passed through it.
b) i)
ii)
iii)
iv)

positively charge ions

negatively charge ions
electrode that connect to negative terminal of a battery
electrode that connect to positive terminal of a battery

c) Pb2+ , Br

24

d) i) Br

ii) Pb2+

e) i) 2 Br - Br2 + 2e

ii) Pb2+ + 2e Pb

f) i) chlorine gas

ii) sodium metal

2. a) Cu2+ , Cl - , H+ , OH

b) Electrode Y is coated with brown solid.

c) i) Oxygen
splinter.
d) 4 OH

ii) Test with a glowing splinter.The gas ignites the glowing

O2 + 2 H2O + 4e

e) i) Chlorine gas
ii) Both OH - and Cl - are attracted to electrode X. But Cl ions are selectively
discharged because of the concentration factor.
3. a) R
b) Copper(II) sulphate solution
c) The impure electrode will dissolved. Zn Zn2+ + 2e

or Cu Cu2+ + 2e

d i) No. Ii) It would fall on the bottom.

e)i) It becomes thicker. Ii) Cu 2+ + 2e Cu4.
4.a) Contains inert ions( does not react with the electrolyte).It completes the circuit
between
2 half-cells.
b)
c)
d)
e)
f)

Chemical energy electrical energy

I) Zinc to iron
ii) Zinc. Zinc is more electropositive than iron.
I) Iron
ii) Fe 2+ + 2e Fe
Zn + Fe2+ Zn 2+ + Fe
Voltage increases.

CHAPTER 7 (OBJ Qs)

Answer :
1. C
2. B
3. D

25

4. A
5. B
6. B
7. B
8. D
9. A
10.B
11.A
12.A
13.D
14.D
15.A
16.B
17.B
18.C
19.C
20.B

CHAPTER 7 (STRUCTURE)

1. a) 15.05 cm3; 15.00 cm3; 14.95 cm3

b) The end point is a stage where an acid exactly neutralizes an alkali.
c) From pink to colourless.
d) To remove any water on the inner surface of the burette to prevent the
sulphuric acid
being diluted.
e)

2 NaOH + H2SO4

Na2SO4 + 2 H2O

f) 15.00 cm3
g) 0.2 moldm-3
h) 30 cm3. Sulphuric acid is a strong diprotic acid whereas nitric acid is a strong
monoprotic acid.
2. a) Ba2+ , OHb) H+, SO42c) A white precipitate of barium sulphate.
d) brightness of the bulb

Volume of dilute sulphuric

acid needed
5

10

15

20

25

30

26

e) Barium hydroxide solution contains free ions Ba 2+ and OH-.

- The bulb lights up brightly.
- When 5 cm3 of dilute sulphuric acid s added, the bulb becomes dimmer because
the number
Of free moving ions decreases.
- it decreases until no more free moving ions are present.( Volume of acid added is
15 cm3)
- When acid is added continuously, the number of free movng ions increases. So the
bulb
becomes increasingly brighter.
3. a) 12.10 cm3
2.25 cm3
9.85 cm3
b) From yellow to orange
c) A pipette
d) Neutralization
e) The conical flask is swirled continuously to allow the mixture to mix thoroughly.
f) 0.04925 moldm-3
4. a) Neutralization
b) 7
c) Strong acid
d) Hydrochloric acid
e) i) 7 cm3
ii) HA + NaOH NaA + H2O
iii) 0.357 moldm-3

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