Hidrometalurgia

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24\cf0\f0\charscalex100 {Hidrometalurgia I }\par\column\pard\li0\ri0\sl-306\slmu
lt0 \fs24\cf0\f0\charscalex100 {Universidad Catolica del Norte }\par\pard\sect\s
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lex100\b \i {Orgenes y Evolucin Histrica de la Hidrometalurgia}\b0 \i0 \tab \fs24\c
f0\f0\charscalex100\b \i {__________________________ 3}\b0 \i0 \par\pard\li826\r
i0\sl-373\slmult0 \fs20\cf0\f0\charscalex100\b {Introduccin _____________________
__________________________________________________ 3}\b0 \par\pard\li1066\ri0\sl
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l-240\slmult0 \fs16\cf0\f0\charscalex100 {Reactivos de Lixiviacin. ______________
______________________________________________________4}\par\pard\li826\ri0\sl-3
86\slmult0 \fs20\cf0\f0\charscalex100\b {Historia de la Hidrometalurgia_________
_______________________________________________ 5}\b0 \par\pard\li1066\ri0\sl-21
3\slmult0 \fs16\cf0\f0\charscalex100 {La Hidrometalurgia en la historia ________
______________________________________________________5}\par\pard\li1066\ri0\sl226\slmult0 \fs16\cf0\f0\charscalex100 {Estado Actual de la Hidrometalurgia del
cobre en Chile ____________________________________________6}\par\pard\li600\ri0
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s en Hidrometalurgia}\b0 \i0 { }\fs22\cf0\f0\charscalex100\b \i {_______________
________ 9}\b0 \i0 \par\pard\li826\ri0\sl-373\slmult0 \fs20\cf0\f0\charscalex100
\b {Estructura de los Minerales ________________________________________________
__________ 9}\b0 \par\pard\li1066\ri0\sl-213\slmult0 \fs16\cf0\f0\charscalex100
{Estructura de enlaces metlicos _________________________________________________
______________9}\par\pard\li1066\ri0\sl-226\slmult0 \fs16\cf0\f0\charscalex100 {
Estructura de enlaces inicos ____________________________________________________
_____________9}\par\pard\li1066\ri0\sl-226\slmult0 \fs16\cf0\f0\charscalex100 {E
structura de enlaces covalentes_________________________________________________
______________9}\par\pard\li1066\ri0\sl-240\slmult0 \fs16\cf0\f0\charscalex100 {
Estructura de enlaces mixtos ___________________________________________________

______________9}\par\pard\li826\ri0\sl-386\slmult0 \fs20\cf0\f0\charscalex100\b
{Caractersticas Estructurales del Agua __________________________________________
______ 10}\b0 \par\pard\li1066\ri0\sl-213\slmult0 \fs16\cf0\f0\charscalex100 {Es
tructura del Agua ______________________________________________________________
_________10}\par\pard\li1066\ri0\sl-226\slmult0 \fs16\cf0\f0\charscalex100 {Cons
tante Dielctrica ________________________________________________________________
______11}\par\pard\li826\ri0\sl-386\slmult0 \fs20\cf0\f0\charscalex100\b {Ioniza
cin del agua ________________________________________________________________ 11}
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___________________________________________________________________________12}\
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Amortiguadores de pH ___________________________________________________12}\par
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d ____________________________________________________________________14}\par\pa
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idos y Formacin de Complejos __________________________________________15}\par\pa
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__________________________________________________________________17}\par\pard\l
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________________________________________________________20}\par\pard\li1066\ri0\
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____________________________________________ 37}\b0 \par\pard\li1066\ri0\sl-213\
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______________________________________________37}\par\pard\li826\ri0\sl-386\slmu
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_____________________________________ 41}\b0 \par\pard\li826\ri0\sl-386\slmult0
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_________________________________ 46}\b0 \par\pard\li1066\ri0\sl-213\slmult0 \fs

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_________________________ 52}\b0 \par\pard\li826\ri0\sl-373\slmult0 \fs20\cf0\f0
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Seleccin de un Mtodo de Lixiviacin ________________________________________________
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Minerales Oxidados de cobre en Medio Alcalino___________________________________
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erias y su Accin Sobre los Sulfuros _____________________________________________

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acin de Metales. _____________________________________________________________ 83
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del Oro y Plata con Tiourea_____________________________________________________
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de Metales Nobles del Grupo del Platino________________________________________
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86\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {Hidrometalurgia I }\par\pard\l
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0\par\pard\li586\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {La minera a pa
rtir de soluciones o Hidrometalurgia se define como las formas de rec
uperacin de un }\par\pard\li586\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {
metal o compuesto desde su mena por medio de una solucin que fluye d
isolviendo las especies de }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\c
harscalex100 {inters desde la roca, esto es aplicable tanto para mineral
es lixiviables como para minerales que }\par\pard\li586\ri0\sl-240\slmult0
\fs20\cf0\f1\charscalex100 {requieren de reacciones qumicas, aguas de descartes y
soluciones de formacin natural. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\pa
r\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Algunos minerales se
lixivian en forma natural, formando soluciones ricas las que son llamadas Aguas
de }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {Mina, la rec
uperacin de estas soluciones representa las primeras aplicaciones de la Hidrometa
lurgia. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-253\
slmult0 \fs20\cf0\f1\charscalex100 {La Hidrometalurgia es un campo interdis
ciplinario que comprende la geologa, qumica, hidrologa, }\par\pard\li600\ri0\

sl-226\slmult0 \fs18\cf0\f1\charscalex100 {metalurgia extractiva, minera, ingenie
ra de procesos y economa. Algunos de los factores que se han de }\par\pard\li600\r
i0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {considerar en un proyecto hidromet
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arscalex100 {6. }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {
7. }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {8. }\par\pard
\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {9. }\par\column\pard\li0\r
i0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charsca
lex100 {La qumica de lixiviacin }\par\pard\li0\ri0\sl-226\slmult0 \fs20\cf0\f1\cha
rscalex100 {La qumica de la roca (ganga) }\par\pard\li0\ri0\sl-226\slmult0 \fs20\
cf0\f1\charscalex100 {Los flujos de solucin en el mineral (precolacin) }\par\pard\
li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Espacio libre en el mineral p
ara permitir el paso de la solucin }\par\pard\li0\ri0\sl-226\slmult0 \fs20\cf0\f1
\charscalex100 {Porosidad de la roca }\par\pard\li0\ri0\sl-226\slmult0 \fs20\cf0
\f1\charscalex100 {Transporte desde el interior de la roca a el flujo (difusin qum
ica) }\par\pard\li0\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {Tecnologa de r
ecuperacin del metal/mineral }\par\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\chars
calex100 {Impacto ambiental }\par\pard\li0\ri0\sl-226\slmult0 \fs20\cf0\f1\chars
calex100 {Perdida de soluciones }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn
16840\marglsxn666\margrsxn133\pard\li600\ri0\sl-226\slmult0 \*\tx1306\fs20\cf0\f
1\charscalex100 {10. }\tab \fs20\cf0\f1\charscalex100 {Qumica de la solucin rica }
\par\pard\li600\ri0\sl-240\slmult0 \*\tx1306\fs20\cf0\f1\charscalex100 {11. }\ta
b \fs20\cf0\f1\charscalex100 {Balance de agua }\par\pard\li600\ri0\sl-226\slmult
0 \*\tx1306\fs20\cf0\f1\charscalex100 {12. }\tab \fs20\cf0\f1\charscalex100 {Man
ejo de soluciones (piscinas, bombeo, riego, coleccin, etc.). }\par\pard\li600\ri0
\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charsca
lex100 {Actualmente los solventes de inters comercial son en base de ag
ua, por lo que se hablara de las }\par\pard\li600\ri0\sl-226\slmult0 \fs2
0\cf0\f1\charscalex100 {soluciones de lixiviacin como del sistemas acuosos. }\pa
6\cf0\f1\charscalex100 {La lixiviacin de minerales se puede separar en do
s grandes grupos, la lixiviacin In situ, que trata un }\par\pard\li600\r
i0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {yacimiento sin moverlo del lug
ar y de superficie, la cual se basa en la extraccin del mineral util
izando }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {mtodos de
minera tradicional seguido de reduccin de tamao, preparacin del mineral o no, antes
de }\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {ser contactad
o con la solucin lixiviante. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pa
rd\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {La operacin de lixiviacin
y recoleccin de las soluciones, esta asociada a una operacin de separacin }\par\par
d\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {del metal/mineral desde l
as soluciones, realizada usualmente en el entorno del cuerpo mineralizado, las }
\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {soluciones genera
das en la lixiviacin son conocidas como \uc1\u8220XPregnant Leach Solution\uc1\u8
221X o PLS, en tanto el }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charsca
lex100 {flujo que retorna a la lixiviacin se conoce como solucin Refino, es decir,
es un circuito cerrado. }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\m
arglsxn666\margrsxn133\cols2\colno1\colw10013\colsr-0\colno2\colw1080\pard\li586
\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pa
rd\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf
0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0
\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\l

lt0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586
\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-266\slmult0 \fs24\cf0\f0\cha
rscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\p
ar\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\c
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\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-240\slmult0 \fs24\cf0
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r\pard\li586\ri0\sl-293\slmult0 \fs24\cf0\f1\charscalex100 {Que es la lixiviacin
}\par\column\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {Universidad
Catolica del Norte }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\margls
xn666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl240\slmult0 \fs18\cf0\f1\charscalex100 {Consideremos un sistema de lixiviacin
simple y un par de experimentos cuyos resultados son de fcil }\par\pa
rd\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {entendimiento, el sistem
a es un evento al que todos estamos familiarizados, disolucin de azcar en una }\pa
r\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {tasa de caf, el siste
ma es simple porque: }\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li77
3\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {a) La solubilidad del azcar
en agua es alta e ilimitada, con lo que respecta a una cucharada en
una }\par\pard\li946\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {tasa. }\pa
r\pard\li773\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {b) No hay reacciones
qumicas con otros solutos }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f1\char
scalex100 {c) No hay interferencia de slidos }\par\pard\li586\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Que pa

sa si ponemos azcar a la forma de azcar flor, azcar granulada o un cu
bo de azcar en una }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscale
x100 {tasa de agua?, que pasa si calentamos el agua?, y si agitamos con una cuch
ara? }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {Las respu
estas son obvias, basado en nuestra experiencia personal podemos induci
r que este }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {com
portamiento es similar en la lixiviacin de un mineral. }\par\pard\li586\ri0\sl-21
3\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\r
i0\sl-346\slmult0 \fs26\cf0\f0\charscalex100\b {Clasificacin de las Reacciones de
Lixiviacin. }\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0
\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {Las reacciones de lixiviacin se puede
n clasificar de acuerdo al medio que solubiliza el metal de inters. }\par\pard\li
586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\
charscalex100 {1. Disolucin de sales o neutra: Hay sales que se separan en sus io
nes por contacto con la fase lquida. }\par\pard\li586\ri0\sl-240\slmult0 \fs14\c
f0\f1\charscalex100 {2.}\fs20\cf0\f1\charscalex100 { Disolucin cida. Se requiere d
e un proveer protones (H}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1
\charscalex100 {) para realizar la lixiviacin.}\par\pard\li586\ri0\sl-240\slmult0
\fs14\cf0\f1\charscalex100 {3.}\fs20\cf0\f1\charscalex100 { Disolucin alcalina.
El in (OH}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {
) es el agente activo para metales que forman complejos solubles. }\par\pard\li5
86\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {4. Intercambio bsico. Este tipo
de reaccin produce un slido cuyo Kps es menor que el Kps del reactante. }\par\pa
rd\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {5. Lixiviacin con formacin
de complejos. El lixiviante forma complejos solubles con el metal de inters. }\
par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {6. Lixiviacin con o
xidacin directa. El agente lixiviante es un oxidante, un compuesto vido de electro
nes. }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {7. Lixivia
cin cida con oxidacin. La lixiviacin cida es posible, despus de una oxidacin. }\par\p
rd\li586\ri0\sl-240\slmult0 \fs12\cf0\f1\charscalex100 {8.}\fs16\cf0\f1\charscal
ex100 { Lixiviacin con oxidacin y formacin de complejos. En este caso los
productos de oxidacin no son }\par\pard\li773\ri0\sl-213\slmult0 \fs20\cf0\
f1\charscalex100 {solubles o no son estables a menos que exista un agente comple
jante. }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {9. Lixivi
acin con reduccin. Existen algunos compuestos que son solubles en sus e
stados de oxidacin }\par\pard\li773\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex1
00 {inferiores y por lo tanto sern solubles bajo condiciones reductoras.}{\super
\fs14\up4\cf0\f1\charscalex100 {.}}\fs20\cf0\f1\charscalex100 {. }\par\pard\li58
6\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\p
ard\li586\ri0\sl-320\slmult0 \fs26\cf0\f0\charscalex100\b {Reactivos de Lixiviac
in. }\b0 \par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-306\s
lmult0 \fs20\cf0\f1\charscalex100 {Para que ocurra la lixiviacin, debe emplearse
un reactivo, llamado lixiviante, cuyo objetivo es solubilizar }\par\pard\li586\r
i0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {en el medio acuoso el metal que se
quiere recuperar. }\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773
\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Factores que debe cumplir un bue
n lixiviante: }\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\s
l-253\slmult0 \*\tx1306\fs20\cf0\f1\charscalex100 {1. }\tab \fs20\cf0\f1\charsca
lex100 {Habilidad para disolver el metal de inters (qu tan rpido disuelve al metal?,
hasta qu grado?). }\par\pard\li773\ri0\sl-226\slmult0 \*\tx1306\fs20\cf0\f1\chars
calex100 {2. }\tab \fs20\cf0\f1\charscalex100 {Selectividad (qu pasa con los eleme
ntos indeseables?). }\par\pard\li773\ri0\sl-226\slmult0 \*\tx1306\fs20\cf0\f1\ch
arscalex100 {3. }\tab \fs20\cf0\f1\charscalex100 {Compatibilidad de las solucion
es obtenidas con las operaciones siguientes. }\par\pard\li773\ri0\sl-240\slmult0
\*\tx1306\fs20\cf0\f1\charscalex100 {4. }\tab \fs20\cf0\f1\charscalex100 {Propi
edades no corrosivas (materiales de construccin). }\par\pard\li773\ri0\sl-226\slm
ult0 \*\tx1306\fs20\cf0\f1\charscalex100 {5. }\tab \fs20\cf0\f1\charscalex100 {F
acilidad de regenerar o reciclar el reactivo lixiviante. }\par\pard\li773\ri0\sl
-226\slmult0 \*\tx1306\fs20\cf0\f1\charscalex100 {6. }\tab \fs20\cf0\f1\charscal
ex100 {Disponibilidad y costo. }\par\pard\li773\ri0\sl-226\slmult0 \*\tx1306\fs2

0\cf0\f1\charscalex100 {7. }\tab \fs20\cf0\f1\charscalex100 {Grado de toxicidad.
}\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-253\slmult0
\fs20\cf0\f1\charscalex100 {Los reactivos lixiviantes ms comunes son los siguien
tes: }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn1
33\cols5\colno1\colw2106\colsr-0\colno2\colw2093\colsr-0\colno3\colw2240\colsr-0
\colno4\colw1840\colsr-0\colno5\colw2813\pard\li893\ri0\sl-213\slmult0 \fs18\cf0
\par\pard\li893\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex100\b {cidos }\b0 \par\
pard\li840\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Sulfrico}\par\column\pa
0\f0\charscalex100\b {Bsicos }\b0 \par\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\c
harscalex100 {Hidrxido de sodio}\par\column\pard\li146\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li146\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex100\b {Complejantes
}\b0 \par\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Sulfato de amo
nio}\par\column\pard\li146\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li146\ri0\sl-25
3\slmult0 \fs20\cf0\f0\charscalex100\b {Oxidantes }\b0 \par\pard\li0\ri0\sl-240\
slmult0 \fs20\cf0\f1\charscalex100 {Cloruro frrico}\par\column\pard\li320\ri0\sl213\slmult0 \fs18\cf0\par\pard\li320\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex1
00\b {Reductores }\b0 \par\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex10
0 {Anhdrido sulfuroso}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\margls
xn666\margrsxn133\cols4\colno1\colw4253\colsr-0\colno2\colw2200\colsr-0\colno3\c
olw2226\colsr-0\colno4\colw2413\pard\li733\ri0\sl-240\slmult0 \*\tx2066\fs20\cf0
\f1\charscalex100 {Clorhdrico}\tab \fs20\cf0\f1\charscalex100 {Carbonato de sodio
}\par\column\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Cianuro de
sodio}\par\column\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Sulfat
o frrico}\par\column\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Hidrg
eno}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133
\cols5\colno1\colw2480\colsr-0\colno2\colw1786\colsr-0\colno3\colw1920\colsr-0\c
olno4\colw2226\colsr-0\colno5\colw2680\pard\li933\ri0\sl-240\slmult0 \fs20\cf0\f
1\charscalex100 {Ntrico}\par\column\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\char
scalex100 {Amonaco}\par\column\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscale
x100 {Cloruro de sodio}\par\column\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\char
scalex100 {Hipoclorto de sodio}\par\column\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\
f1\charscalex100 {cido sulfhdrico}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn1
6840\marglsxn666\margrsxn133\cols4\colno1\colw4666\colsr-0\colno2\colw1400\colsr
-0\colno3\colw3946\colsr-0\colno4\colw1080\pard\li800\ri0\sl-240\slmult0 \*\tx19
73\fs20\cf0\f1\charscalex100 {Sulfuroso}\tab \fs20\cf0\f1\charscalex100 {Carbona
to de amonio}\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586
rd\li586\ri0\sl-386\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\co
lumn\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Tiourea}\par\column
\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Perxido de hidrgeno}\par\
pard\li373\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Aire (oxgeno)}\par\colu
mn\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\c
\fs18\cf0\par\pard\li0\ri0\sl-386\slmult0 \fs24\cf0\f0\charscalex100 {4 }\par\p
ard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\sect
\sectd\sbkpage

7;32768}}
0\cf0\f0\charscalex100\b \i {Historia de la Hidrometalurgia }\b0 \i0 \par\pard\l
r\pard\li586\ri0\sl-400\slmult0 \fs26\cf0\f0\charscalex100\b {La Hidrometalurgia
en la historia }\b0 \par\column\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charsc
alex100 {Universidad Catolica del Norte }\par\pard\sect\sectd\sbknone\pgwsxn1189
3\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\pa
r\pard\li586\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {A diferencia de la p
irometalrgia, la cual, fue desarrollada durante la edad de los Metales (4000
y 3000 }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {A.C). L
a Hidrometalurgia no fue conocida, ni registrada, sino hasta bastante ms tarde. }
fs18\cf0\f1\charscalex100 {Las primeras aplicaciones de la Hidrometaturgia fuero
n realizadas en China, durante la dinasta Han (5 }\par\pard\li586\ri0\sl-226\slmul
t0 \fs18\cf0\f1\charscalex100 {dinasta, aos 117 al 122 A.C.) Liu-An, rey d
e Huainan, en su libro Huainancius, reportaba la }\par\pard\li586\ri0\sl240\slmult0 \fs20\cf0\f1\charscalex100 {transformacin del fierro en cobre metlico
al poner en contacto fierro metlico con chalcantita Cu}{\super \fs14\up4\cf0\f1\c
harscalex100 {2+}}\fs20\cf0\f1\charscalex100 {+ Fe }\par\pard\li586\ri0\sl-253\sl
mult0 \fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { Cu +
Fe}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs18\cf0\f1\charscalex100 {,
, sin embargo, la cementacin, como proceso industrial, solo fue aplicad
a durante los }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\f1\charscalex100 {
siglos VIl y VIll D.C., mediante el tratamiento de vertientes de agua
s cidas que eran producidas por la }\par\pard\li586\ri0\sl-226\slmult0 \fs2
0\cf0\f1\charscalex100 {oxidacin natural o inducida de minerales sulfurados de co
bre. El metal era obtenido por la oxidacin in-}\par\pard\li586\ri0\sl-240\slmult0
\fs20\cf0\f1\charscalex100 {situ de minerales de cobre, las cuales surgan en for
ma de vertientes conteniendo sulfato de cobre, el que }\par\pard\li586\ri0\sl-22
6\slmult0 \fs18\cf0\f1\charscalex100 {al saturarse precipitaba como chalcant
ita, este proceso recibi el nombre de cobre-hiel, dado el sabor }\par\p
ard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {amargo del sulfato. }\
par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-253\slmult0 \f
s20\cf0\f1\charscalex100 {En Occidente, no fue hasta el Siglo VIl que los alquim
istas se apasionaron con la transmutacin del fierro }\par\pard\li586\ri0\sl-226\s
lmult0 \fs20\cf0\f1\charscalex100 {en cobre al poner en contacto el vitriolo azu
l (una solucin de sulfato de cobre) con algn trozo de fierro, . }\par\pard\li586\r
i0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\chars
calex100 {El descubrimiento en el Siglo VIII, por parte de Jabir lbn el-Hayyan (
720-813), del agua regia, (mezcla de }\par\pard\li586\ri0\sl-240\slmult0 \fs20\c
f0\f1\charscalex100 {HCl y HNO}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs20\cf0\f1
\charscalex100 {) nico solvente capaz de disolver el oro, marca el inicio de la H
idrometalurgia actual. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li
600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {En el Siglo XVI, la extraccin
de cobre por mtodos lquidos recibi alguna atencin. As, la lixiviacin en }\par\pard\li6
00\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {pilas fue usada en las montaas
de Hartz, en Alemania, y en las minas de Ro Tinto, en Espaa. En estas }\par\pard\l
i600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {operaciones los minerales

de pirita conteniendo sulfuros de cobre se apilaban al aire libre, d
onde se }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {dejaban
oxidar expuestos a la accin de la lluvia, del aire y la intervencin
natural de bacterias. Las }\par\pard\li600\ri0\sl-226\slmult0 \fs16\cf0\f1\c
harscalex100 {soluciones de sulfato se recogan en la base de las pilas
y se precipitaba el cobre usando chatarra de }\par\pard\li600\ri0\sl-240
\slmult0 \fs16\cf0\f1\charscalex100 {fierro. Este proceso de precipitacin re
cibi desde ese entonces el nombre castellano de cementacin, }\par\pard\li6
00\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {que le es asignado hasta hoy.
}\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-240\slmult0
\fs16\cf0\f1\charscalex100 {En el Siglo XVIII, la produccin de potasa en
Qubec para la industria de jabn y vidrio, se realizaba }\par\pard\li600
\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {lixiviando con agua las cenizas
de los hornos de lea y de la quema de bosques, las cenizas se agitaban }\par\pard
\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {con agua, se filtraban,
y luego se evaporaban hasta sequedad para producir la potasa. Se es
tima que }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {para l
ograr 1 ton de potasa era necesario quemar alrededor de 1 hectrea de bosques. }\p
ar\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs
20\cf0\f1\charscalex100 {El ao 1887 se puede sealar como el nacimiento de
la Hidrometalurgia industrial moderna, cuando }\par\pard\li586\ri0\sl-240\
slmult0 \fs20\cf0\f1\charscalex100 {simultneamente se inventaron dos procesos de
gran relevancia. }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100
{1. El proceso de cianuracin de oro, desarrollado por John Stewart Mac Arthur y l
os hermanos Robert y }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex
100 {William Forrest. Consista en la disolucin del oro desde minerales de baja ley
con una solucin alcalina }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charsc
alex100 {diluida de cianuro de sodio, seguidamente el oro es precipitado por cem
entacin con zinc. }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100
{2. El proceso inventado por Karl Joseph Bayer para la produccin de un precipita
do cristalino y puro de }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charsca
lex100 {AI(OH)}{\sub \fs12\cf0\f1\charscalex100 {3}}\fs16\cf0\f1\charscalex100 {
, mediante la lixiviacin alcalina en caliente de bauxita. De las soluc
iones alcalinas precipita el }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1
\charscalex100 {hidrxido en forma filtrable, el cual, despus de ser lavad
o y secado, se calcina para producir un Al}{\sub \fs14\cf0\f1\charscalex
100 {2}}\fs20\cf0\f1\charscalex100 {0}{\sub \fs14\cf0\f1\charscalex100 {3 }}\par
\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {puro. Este ltimo es el
ectrolizado en sales fundidas para producir aluminio metlico. }\par\pard\li586\ri
0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charsc
alex100 {A inicios del Siglo XX, los desarrollos en la produccin de en
erga elctrica permitieron reemplazar la }\par\pard\li586\ri0\sl-226\slmult0 \f
s20\cf0\f1\charscalex100 {cementacin con chatarra de Fe por la electrlisis de solu
ciones de lixiviacin, efectuado por primera vez }\par\pard\li586\ri0\sl-226\slmul
t0 \fs20\cf0\f1\charscalex100 {en el mundo a escala industrial en Chuquicamata,
Chile (1915). }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {La
sntesis del amonaco, NH}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs20\cf0\f1\charsca
lex100 {, en Alemania, durante la I Guerra Mundial, permiti su uso en la forma de
}\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {hidrxido de am
onio, NH}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs18\cf0\f1\charscalex100 {(OH),
en la lixiviacin de cobre nativo, en el Distrito del Lago Superior,
y de }\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {minerales
de malaquita/azurita, en Alaska (1916), de igual manera, la lixiviacin
cida de zinc, desde }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charsca
lex100 {minerales oxidados. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pa
rd\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {Dcada de los 40, el
esfuerzo blico para obtener el uranio que se requera en el Proyecto Ma
nhattan }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {para la
produccin de la bomba atmica, permiti desarrollar a nivel industrial los procesos d
e extraccin }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {por s

olventes y de intercambio inico con resinas slidas. }\par\pard\sect\sectd\sbknone\
pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw10013\colsr-0\c
olno2\colw1080\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri
0\sl-266\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\column\pard\l
rd\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-240\slmult0 \fs24\cf0\f0
\charscalex100 {5 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn
666\margrsxn133\pard\sect\sectd\sbkpage
7;32768}}
slmult0 \fs20\cf0\f1\charscalex100 {Dcada de los 50, se desarrollo la lixiviacin a
moniacal a presin de concentrados sulfurados de nquel y }\par\pard\li586\ri0\sl-24
0\slmult0 \fs18\cf0\f1\charscalex100 {su recuperacin por precipitacin con gas hidrg
eno, por Sherrit-Gordon, en Fort Saskatchewan, Canad, }\par\pard\li586\ri0\sl-226
\slmult0 \fs18\cf0\f1\charscalex100 {la aplicacin de este proceso rpidamente
se ampli, tanto en medio cido como alcalino, a los }\par\pard\li586\ri0\
sl-226\slmult0 \fs18\cf0\f1\charscalex100 {concentrados sulfurados de otros meta
les como cobalto, zinc, cobre, lateritas, concentrados mixtos muy }\par\pard\li5
86\ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {difciles de separar (Co/Ni, Co
/Ni/Cu, etc.), y a minerales de uranio y de tungsteno en los aos 70 y
de }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {oro en los ao
s 80. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-240\sl
mult0 \fs18\cf0\f1\charscalex100 { Dcada de los 60, se comenz a entender el rol de
las bacterias en la disolucin de algunos minerales }\par\pard\li586\ri0\sl-253\s
lmult0 \fs20\cf0\f1\charscalex100 {sulfurados particularmente de piritas FeS}{\s
ub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 { lo que potenci su
aplicacin en la lixiviacin de minerales de }\par\pard\li600\ri0\sl-213\slmult0 \fs
18\cf0\f1\charscalex100 {cobre considerados econmicamente marginales, tanto in-si
tu como en botaderos en Arizona, USA. Esta }\par\pard\li600\ri0\sl-226\slmult0 \
fs18\cf0\f1\charscalex100 {tcnica fue posteriormente aplicada con provecho para l
a produccin de uranio en los aos 70 y de oro }\par\pard\li600\ri0\sl-226\slmult0 \
fs18\cf0\f1\charscalex100 {desde minerales encapsulados con piritas en los aos 80
. En 1967, se pone en marcha exitosamente la }\par\pard\li600\ri0\sl-226\slmult0
\fs18\cf0\f1\charscalex100 {primera planta comercial de SX-EO para cobre, Blueb
ird, de la Ranchers Exploration, en Arizona, usando }\par\pard\li600\ri0\sl-240\

slmult0 \fs20\cf0\f1\charscalex100 {LIX 64, el primer reactivo comercial para co
bre. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-240\slm
ult0 \fs18\cf0\f1\charscalex100 {Dcada de los 70, el desarrollaron de nuevos reac
tivos de extraccin por solventes para cobre, unida a la }\par\pard\li600\ri0\sl-2
26\slmult0 \fs16\cf0\f1\charscalex100 {electro-obtencin, permiti la aplicacin m
asiva de esta tcnica. Inicialmente, se destacan proyectos en }\par\pard\l
i600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {USA, Zambia y Per. En este pe
rodo se establecieron los mecanismos electroqumicos que gobiernan la }\par\pard\li
600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {disolucin de los sulfuros, est
o permiti el desarrollo de tecnologas para el tratamiento hidrometalrgico }\par\par
d\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {de concentrados de cob
re. Entre ellos se destacan: el proceso ARBITER usando amonaco y los }
\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {procesos CYMETY C
LEAR, ambos en ambiente clorhdrico probados a escala piloto por Cyprus y Duval. }
fs18\cf0\f1\charscalex100 {Dcada de los 80, la aplicacin de carbn activado,
unida a la lixiviacin en pilas con aglomeracin, }\par\pard\li600\ri0\sl-2
26\slmult0 \fs18\cf0\f1\charscalex100 {potencian la produccin de oro desde minera
les de baja ley, asimismo la aplicacin de oxidacin previa }\par\pard\li600\ri0\sl226\slmult0 \fs18\cf0\f1\charscalex100 {permiti el tratamiento de minerales de or
o considerados refractarios. Durante esta dcada en la industria }\par\pard\li600\
ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {del cobre de USA se produce el fe
nmeno de conversin tecnolgica de la minera tradicional. Impulsada }\par\pard\li600\r
i0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {por altos costos debido que l
a industria minera estaba en una fase de madurez, con sindicatos }\par
\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {poderosos, enfrento l
as primeras regulaciones ambientales, adems, se produjo una baja de precios del }
\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {cobre, lo cual
hizo cerrar a la mayor parte de las operaciones mineras. Varios prod
uctores }\par\pard\li600\ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {desapare
cieron, pero otros iniciaron una conversin hacia operaciones de lixiviac
in LX, principalmente }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscal
ex100 {en botaderos, seguida de SX y EO lo que les cambi de escenario ambiental y
el perfil de costos y as les }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\ch
arscalex100 {permiti reabrir muchas de sus operaciones cerradas. }\par\pard\li586
rd\li586\ri0\sl-333\slmult0 \fs26\cf0\f0\charscalex100\b {Estado Actual de la Hi
drometalurgia del cobre en Chile }\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li586\ri0\sl-320\slmult0 \fs20\cf0\f1\charscalex100 {En Chile dada
la enorme gravitacin tanto en trminos econmicos como de volmenes produci
dos, }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {hablar de
desarrollo ligado a la Industria minera, significa inevitablemente refe
rirse al desarrollo de la }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\c
harscalex100 {minera del cobre. En relacin con la Hidrometalurgia ocurre lo mismo
y si bien puede resultar interesante }\par\pard\li586\ri0\sl-240\slmult0 \fs20\c
f0\f1\charscalex100 {el desarrollo de las tcnicas hidrometalrgicas en las
industrias del salitre, del yodo y del litio, como }\par\pard\li586\ri0\
sl-226\slmult0 \fs20\cf0\f1\charscalex100 {asimismo las usadas en la minera del o
ro, todas estas tcnicas estn incluidas y representadas, en las }\par\pard\li586\ri
0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {tecnologas usadas por la Hidrometalu
rgia del cobre. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0
\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {La Hidrometalurgia del cobre en
Chile est basada en las tecnologas de lixiviacin, extraccin por }\par\pard
\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {solventes y electro-obte
ncin (LX-SX-EO). Dichas tcnicas, aunque se desarrollaron en pocas }\par\par
d\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {diferentes y se han adopt
ado por separado y en diversas pocas de la historia de la metalurgia del cobre, }
\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {han alcanzado una
avanzada etapa de desarrollo y madurez. }\par\pard\li586\ri0\sl-213\slmult0 \fs
18\cf0\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Desde la in

troduccin de la lixiviacin por percolacin en bateas seguida de electro-obtencin dire
cta en }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {Chuquicam
ata, 1915 y Potrerillos, 1928, se ha recorrido un largo camino. Otras
faenas, como Mantos }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charsca
lex100 {Blancos y Sagasca, utilizaron esta experiencia en sus plantas c
onstruidas en 1961 y 1972, }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\
charscalex100 {respectivamente. De todas ellas, en la actualidad slo se
mantienen operativas las bateas de Mantos }\par\pard\li586\ri0\sl-226\slmul
t0 \fs18\cf0\f1\charscalex100 {Blancos. En la industria del salitre (fines
del Siglo XIX) tambin se ha operado con bateas, conocidas }\par\pard\l
i586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {como cachuchos, procesos Sha
nks y Guggenheim, solamente las plantas de Mara Elena y de Pedro de }\par\pard\li
586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {Valdivia siguen operando. }\p
18\cf0\f1\charscalex100 {Para el cobre, se uso inicialmente la lixiviacin
en bateas, el cobre era recuperado como cemento de }\par\pard\li586\ri0
\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {cobre. Esta tecnologa se ha usad
o en diversas instalaciones de la pequea minera del cobre y, }\par\pard\
li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {principalmente, en las plan
tas regionales de la Empresa Nacional de Minera (ENAMI). Este producto si }\par
\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\c
olno1\colw10013\colsr-0\colno2\colw1080\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\
s24\cf0\f0\charscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-320\s
lmult0 \fs24\cf0\f0\charscalex100 {6 }\par\pard\sect\sectd\sbknone\pgwsxn11893\p
ghsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sbkpage
7;32768}}
\fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {bien se
trata de un precipitado de muy alta ley, con 75 a 85% de cobre r
equiere, de un tratamiento de }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\
f1\charscalex100 {fundicin y refinacin que aumenta los costos y, generalmente, los
torna prohibitivos. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li58
6\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {Otra aplicacin, usada con mi
nerales de altas leyes, es la lixiviacin por agitacin con lavado en }\p
ar\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {contracorriente, se

guida de cementacin con chatarra, a fines de los 60 e inicios de los 70, este pro
ceso }\par\pard\li586\ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {en la min
era del cobre ha sido utilizado hasta fines de los 80, las plantas d
e agitacin de Carolina de }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\ch
arscalex100 {Michilla, Ojancos, ENAMI-Taltal y ENAMI-Vallenar. No obstante
, todava hoy en Mantos Blancos se }\par\pard\li586\ri0\sl-226\slmult0 \fs18
\cf0\f1\charscalex100 {contina lixiviado por agitacin las especies oxidadas
de cobre contenidas en los concentrados del }\par\pard\li586\ri0\sl-226\s
lmult0 \fs16\cf0\f1\charscalex100 {circuito de flotacin de xidos, como un c
omplemento al circuito principal de lixiviacin de minerales en }\par\pard
\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {bateas. En la metalurgia d
el oro son numerosas las plantas que usan la lixiviacin por agitacin, seguida }\pa
r\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {de lavado o filtrado
en contracorriente, para tratar minerales de mayor ley y para concentrados, com
o es }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {el caso de
El Pen, La Coipa, CanCan y El Indio. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0
\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Con la invencin de
l proceso de aglomeracin-curado seguido de lixiviacin en pilas, proceso TL, permit
e }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {la puesta en m
archa de la mina Lo Aguirre, de la Sociedad Minera Pudahuel, en 1980, este proce
so ha }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {permitido
la explotacin de minerales de leyes bajas: desde 1,8% de Lo Aguirre,
en 1980, a leyes }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex
100 {menores que 0,5% como ocurre actualmente en El Abra, Radomiro Tomic y Lomas
Bayas. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-253\
slmult0 \fs20\cf0\f1\charscalex100 {La tcnica de aglomeracin y lixiviacin en pilas,
con cal, cemento y soluciones de cianuro se ha usado, }\par\pard\li586\ri0\sl-2
26\slmult0 \fs20\cf0\f1\charscalex100 {para la recuperacin de oro y plata.
Mediante este proceso se han tratado minerales de baja ley, }\par\pard
\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {alcanzando incluso leyes
de oro inferiores a 1 gramo por tonelada, San Cristbal, Antofagasta,
y de }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Refugio,
en Maricunga, y el proyecto de Cerro Casale, tambin ubicado en el di
strito de Maricunga, }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscal
ex100 {antiguos relaves, como fue el caso del retratamiento de los relaves de fl
otacin de Mantos de Punitaqui, }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\c
harscalex100 {por Minera Tamaya, a partir de 1988. De manera similar, en la mine
ra del salitre y del yodo, la lixiviacin }\par\pard\li586\ri0\sl-226\slmult0 \fs20
\cf0\f1\charscalex100 {en pilas se desarrolla desde inicios de los aos 90. }\par\
pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-253\slmult0 \fs18\
cf0\f1\charscalex100 {La incorporacin de extraccin por solventes para cobre
en la planta piloto de Chuquicamata, 1970 es }\par\pard\li586\ri0\sl-22
6\slmult0 \fs20\cf0\f1\charscalex100 {seguida por la puesta en marcha de
Lo Aguirre, 1980, la cual es la primera aplicacin comercial de }\par\pa
rd\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {extraccin por solventes e
n Chile. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-253
\slmult0 \fs20\cf0\f1\charscalex100 {Otras aplicaciones de la extraccin por solve
nte en Chile son: }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\r
i0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {1- La planta de SX-EO en 1984.de E
l Teniente, trata las aguas que percolan por la lixiviacin in-situ en el }\par\pa
rd\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {crter de la explotacin, pr
oducto del paso de aguas de deshielo, produce soluciones con 1 a 1,5 g/l Cu, }\p
ar\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {pero altamente vari
ables en concentracin y caudal segn la estacin. }\par\pard\li586\ri0\sl-213\slmult
0 \fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {2- La
planta SX-EO del Proyecto Ripios de Chuquicamata en 1987, lixiviacin en bota
dero de los ripios }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex10
0 {de lixiviacin en bateas de Chuquicamata, los que, unidos a las soluciones de l
as bateas cargadas con }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscal
ex100 {mineral fresco, dan una alimentacin media a SX de 10 a 12 g/l

Cu, se constituye en una de las }\par\pard\li586\ri0\sl-226\slmult0 \fs20
\cf0\f1\charscalex100 {operaciones de SX con las soluciones de mayor concentracin
en el mundo. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\s
l-240\slmult0 \fs18\cf0\f1\charscalex100 {3- La Lixiviacin Bacterial TL-SX-EO
de sulfuros de cobre en Lo Aguirre, es la primera LX bacterial de
}\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {minerales fresco
s, 1985, se trata del tratamiento secundario (mediante lixiviacin bacteriana) de
los ripios }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {con
contenidos de cobre sulfurado remanentes de la lixiviacin TL primaria,
efectuada qumicamente }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscale
x100 {sobre los minerales principalmente oxidados y mixtos de cobre que caracter
izaron la operacin inicial del }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\c
harscalex100 {yacimiento Lo Aguirre, gradualmente la alimentacin fresca de minera
les desde la mina se fue tornando }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\
f1\charscalex100 {cada vez ms alta en sulfuros, hasta hacerse insignificantes los
contenidos de xidos ya desde 1987, con }\par\pard\li600\ri0\sl-226\slmult0 \fs20
\cf0\f1\charscalex100 {lo cual, a partir de ese momento, la lixiviacin pas a ser ni
camente bacterial. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\
ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Hacia fines de los aos 80 e
inicios de los 90, debido a un aumento en los precios del cobre, a
l }\par\pard\li600\ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {agotamiento d
e las ms altas leyes en los minerales, a los mayores costos asociados
a los procesos }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex10
0 {tradicionales, a la creciente preocupacin por el ambiente y a la llegada de in
versionistas extranjeros, es }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\ch
arscalex100 {posible apreciar un significativo cambio en la tendencia, s
urgiendo un gran nmero de proyectos para }\par\pard\li586\ri0\sl-226\slmult
0 \fs20\cf0\f1\charscalex100 {cobre susceptibles de aprovechar las tcnicas de LXSX-EO. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-253\s
lmult0 \fs20\cf0\f1\charscalex100 {Desde entonces se han estudiado, a nive
l piloto y en el propio lugar de cada proyecto, numerosas }\par\pard\l
i586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {variaciones del sistema,
como son la recuperacin de cobre desde minerales exticos y refractarios,
}\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {alimentacin slo d
e sulfuros, tratamiento de minerales de leyes extremadamente bajas, uso exclusiv
o de }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {agua de m
ar, trabajo a gran altura sobre el nivel del mar, trabajo bajo condi
ciones climticas muy }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscale
x100 {adversas, etc., mantenindose en todos los casos las caractersticas
propias del proceso: bajos costos }\par\pard\sect\sectd\sbknone\pgwsxn11893\
pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw10013\colsr-0\colno2\colw10
80\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs
18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-266\slm
ult0 \fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-21
l-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-240\slmult0 \fs24\cf0\f0\charscalex1
00 {7 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn
133\pard\sect\sectd\sbkpage
7;32768}}
\fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {operacio
nales, simplicidad del proceso, buena compatibilidad con el ambiente y alta cali
dad del producto, }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100
{en la generalidad de los casos, en la forma de ctodos de alta calidad, segn norm
as BSI y ASTM. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\
sl-253\slmult0 \fs16\cf0\f1\charscalex100 {La primera inversin de esta serie
corresponde al Proyecto Lince, perteneciente a la asociacin entre }\par
\pard\li586\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {Outokumpu, y Minera
Michilla. Esta aplicacin tiene la particularidad de ser la primera op
eracin en el }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {mu
ndo que utiliz agua de mar para la lixiviacin, para la obtencin de ctodos de alta ca
lidad va LX-SX-}\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {EO
. Su produccin se encuentra inscrita y aceptada en el London Metal Exchange (LME)
y es reconocida }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100
{por la calidad de sus ctodos. Su inicio de operaciones fue en 1991 y se expandi a
l doble en 1995. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri
0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {Posteriormente, surgen otros proyec
tos como Cerro Colorado en 1993 (con dos expansiones en 96 y 98) }\par\pard\li58
6\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {y Quebrada Blanca, en 1994,
este ltimo ubicado a gran altitud (4.300 m s.n.m.) y con el desafo
de }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {implementar
la lixiviacin bacterial en condiciones climticas adversas, El Abra, en 1
996, la mayor }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {
operacin en el mundo de este tipo construida como una sola unidad: 225.000 ton/ao
de ctodos, entre }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {
muchos otros. }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\
margrsxn133\cols2\colno1\colw10013\colsr-0\colno2\colw1080\pard\li586\ri0\sl-213
0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\p
ult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl
-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li58
ard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213

-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-400\slmult0 \fs24\cf0\f0\charscalex
100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard
mult0 \fs24\cf0\f0\charscalex100 {8 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pg
hsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sbkpage
7;32768}}
\pard\li3506\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {Universidad Catolica
del Norte }\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\s
lmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-2
53\slmult0 \fs20\cf0\f0\charscalex100\b {Elementos de qumica de soluciones en Hid
rometalurgia }\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn
666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-25
3\slmult0 \fs20\cf0\f1\charscalex100 {En Hidrometalurgia se trata con reacciones
heterogneas del tipo slido/lquido, slido/liquido/gas. Para }\par\pard\li586\ri0\sl226\slmult0 \fs20\cf0\f1\charscalex100 {lo cual, se deben revisar algunos aspect
os de la estructura de los minerales. }\par\pard\li586\ri0\sl-213\slmult0 \fs18
t0 \fs20\cf0\f0\charscalex100\b \i {Estructura de los Minerales }\b0 \i0 \par\pa
0\f1\charscalex100 {Los minerales se clasifican, desde el punto de vista
estructural como: metlicos, inicos o covalentes. }\par\pard\li586\ri0\sl-26
6\slmult0 \fs20\cf0\f1\charscalex100 {Esta clasificacin es ideal, pues es comn enc
ontrar situaciones de traslape entre estos tipos de enlaces}\fs24\cf0\f0\charsca
lex100 {. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-21
3\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-280\slmult0 \fs20\cf0\f0\charscalex100
\b {Estructura de enlaces metlicos }\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\
cf0\par\pard\li586\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {En los metal
es, los tomos estn empaquetados muy prximos entre s, esto da como result
ado el }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {arreglo
muy denso. Existen traslapes de los orbtales entre tomos en la totalid
ad del cristal, as es }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charsc
alex100 {posible, que un electrn se mueva desde un orbital de un tomo hacia un orb
ital de otro tomo, de esta }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\chars
calex100 {manera, los electrones de valencia pueden considerarse deslocalizados,
es decir, ellos no pertenecen a }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f
1\charscalex100 {un tomo individual sino al cristal considerado como un todo. Est
o explica la alta conductividad elctrica }\par\pard\li586\ri0\sl-240\slmult0 \fs2
0\cf0\f1\charscalex100 {de los metales. }\par\pard\li586\ri0\sl-213\slmult0 \fs1
lt0 \fs20\cf0\f0\charscalex100\b {Estructura de enlaces inicos }\b0 \par\pard\li5
86\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-306\slmult0 \fs18\cf0\f1\c
harscalex100 {La estabilidad de los minerales que contienen iones, se debe a la
tendencia de ciertos tomos a perder }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0
\f1\charscalex100 {electrones, y a otros de ganarlos. Estos tomos estn fuertemente
unidos por fuerzas electrostticas. Por }\par\pard\li586\ri0\sl-240\slmult0 \fs18
\cf0\f1\charscalex100 {ejemplo, el cristal de NaCI, cada n Na}{\super \fs12\up4\cf
0\f1\charscalex100 {+}}\fs18\cf0\f1\charscalex100 { est rodeado de seis iones Cl}
{\super \fs12\up4\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charscalex100 { y. simil
armente, cada in Cl}{\super \fs12\up4\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\chars
calex100 { est }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {ro
deado de seis iones Na}{\super \fs12\up4\cf0\f1\charscalex100 {+}}\fs18\cf0\f1\c
harscalex100 {. Los enlaces inicos mantienen unido cada in a todos sus vecinos a
travs }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\f1\charscalex100 {del cristal
. As, el cristal es una unidad gigante, ionicamente sujeta. Como resultado, estos
cristales son }\par\pard\li586\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {d
uros, rgidos y alto punto de fusin, son malos conductores elctricos pero
cuando se disuelven o se }\par\pard\li586\ri0\sl-240\slmult0 \fs16\cf0\f1\
charscalex100 {funden, los iones pasan a ser independientes y altamente
mviles, y la solucin o sustancia fundida se }\par\pard\li586\ri0\sl-226\sl
mult0 \fs16\cf0\f1\charscalex100 {transforma en un conductor elctrico. Los
cristales inicos se fracturan con dificultad, pero, cuando las }\par\pard
\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {fracturas ocurren, se prod
ucen a lo largo de los planos de iones del cristal. }\par\pard\li586\ri0\sl-213\
\sl-266\slmult0 \fs20\cf0\f0\charscalex100\b {Estructura de enlaces covalentes }

\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-320\slmul
t0 \fs18\cf0\f1\charscalex100 {En las especies covalentes, los tomos estn s
ujetos por enlaces de electrones compartidos o }\par\pard\li586\ri0\sl-226
\slmult0 \fs20\cf0\f1\charscalex100 {covalentes. Pueden ser minerales formados p
or unidades discretas o bien de estructura reticulada: }\par\pard\li586\ri0\sl-2
0 {a) }{ }\fs20\cf0\f0\charscalex100\b \ul {Unidades discretas:}\b0 \ul0 \fs20\
cf0\f1\charscalex100 { no existen fuerzas de enlace que se extiendan ms
all de esas unidades }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charsca
lex100 {discretas, por esto, las fuerzas intermoleculares son dbiles, ellos son b
landos, de bajo punto de fusin y }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1
\charscalex100 {calor de vaporizacin. En el azufre elemental (S}{\super \f
s12\up4\cf0\f1\charscalex100 {0}}\fs18\cf0\f1\charscalex100 {), cada tomo est
sujeto a dos tomos vecinos, }\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\
charscalex100 {formando anillos de ocho miembros. }\par\pard\li586\ri0\sl-213\sl
mult0 \fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {b)
}{ }\fs18\cf0\f0\charscalex100\b \ul {Estructura reticulada: }\b0 \ul0 { }\fs1
6\cf0\f1\charscalex100 {los enlaces se extienden a lo largo de todo el
slido. Por esto, son duros, }\par\pard\li586\ri0\sl-253\slmult0 \fs18\cf0\f1
\charscalex100 {estables, generalmente insolubles, y no pueden ser dividi
dos en pequeas unidades. En SiO}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\c
f0\f1\charscalex100 {, el silicio }\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf
0\f1\charscalex100 {ocupa el centro de un tetrahedro, compartiendo electrones co
n cuatro oxgenos situados en los vrtices }\par\pard\li586\ri0\sl-226\slmult0 \fs18
\cf0\f1\charscalex100 {del tetraedro, y los cuatro tomos del tetraedro es
tn compartidos con otros tetraedros, resultando una }\par\pard\li600\ri0\sl
-240\slmult0 \fs20\cf0\f1\charscalex100 {estructura tri-dimensional. La fractura
requiere que muchos de estos enlaces qumicos se rompan. }\par\pard\li600\ri0\sl213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600
\ri0\sl-266\slmult0 \fs20\cf0\f0\charscalex100\b {Estructura de enlaces mixtos }
\b0 \par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-306\slmul
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}}}}\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\margtsxn666\margbsxn173\col
s2\colno1\colw6106\colsr-0\colno2\colw4986\pard\li586\ri0\sl-306\slmult0 \fs24\c
f0\f0\charscalex100 {Hidrometalurgia I }\par\column\pard\li0\ri0\sl-306\slmult0
\fs24\cf0\f0\charscalex100 {Universidad Catolica del Norte }\par\pard\sect\sectd
\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-213\s
sl-253\slmult0 \fs20\cf0\f0\charscalex100\b {Metlico-inico}\b0 \fs20\cf0\f1\charsc
alex100 {: minerales como la galena (PbS), esfalerita (ZnS) y calcopiri
ta (CuFeS}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {),
presentan }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\f1\charscalex100 {propie
dades caractersticas de los metales: lustre, opacidad y conductividad elc
trica. Esta ltima }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex10
0 {propiedad es, sin embargo, mucho menor que la de los metales, moti
vo por el cual se les llama }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\
f1\charscalex100 {semiconductores. Es el resultado de un movimiento restringido
de los electrones en el reticulado debido a }\par\pard\li586\ri0\sl-226\slmult0
\fs20\cf0\f1\charscalex100 {defectos estructurales. }\par\pard\li586\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f0\charscalex100\b
{Covalente-inico:}\b0 \fs16\cf0\f1\charscalex100 { un enlace inico puede ser
parcialmente covalente y viceversa, el cloruro de plata, }\par\pard\li5
86\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {AgCl, es un cristal predominan
temente inico, pero los electrones del cloruro no estn todos localizados }\par\par
d\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {en torno al ncleo de
cloro y pueden pasar al ncleo de plata, dado que estos electrones estn
}\par\pard\li600\ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {compartidos, e
l enlace entre ellos es parcialmente covalente y es ms fuerte que el
enlace inico, esto }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex1
00 {explica su insolubilidad en agua. Existen tambin minerales enlazados
en forma tanto inica como }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\c
harscalex100 {covalente. En los carbonatos, el enlace entre carbono y o
xgeno es covalente, mientras que entre el }\par\pard\li586\ri0\sl-240\slmul
t0 \fs18\cf0\f1\charscalex100 {carbono y el ion metlico es inico. La ensta
tita (Mg}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {(Si}{
\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O}{\sub \fs14\cf
0\f1\charscalex100 {6}}\fs18\cf0\f1\charscalex100 {)) consiste de una cadena
de silicato, en la }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\f1\charsca
lex100 {que el silicio est enlazado covalentemente con el oxgeno, mientra
s el magnesio est presente como }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf
0\f1\charscalex100 {ion. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard
\li586\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex100\b {Metlico-covalente}\b0 \fs
20\cf0\f1\charscalex100 {: la pirita (FeS}{\sub \fs14\cf0\f1\charscalex100 {2}}\
fs20\cf0\f1\charscalex100 {) puede ser considerada un mineral de enlace mixto de
l tipo metlico-}\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {co
valente. Tiene un lustre metlico, estructura cbica y el ion disulfuro S}{\sub \fs1
4\cf0\f1\charscalex100 {2}}\fs14\cf0\f1\charscalex100 {2-}\fs20\cf0\f1\charscale
x100 { es covalente por naturaleza. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf
\fs20\cf0\f0\charscalex100\b \i {Caractersticas Estructurales del Agua }\b0 \i0 \
s18\cf0\par\pard\li586\ri0\sl-333\slmult0 \fs20\cf0\f0\charscalex100\b {Estructu
ra del Agua }\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0
\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {En la molcula de agua, el ncleo
del hidrgeno no se posiciona en una lnea recta, sino que en las }\par
\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {esquinas de un tringul
o. Adems de los enlaces covalentes, entre el oxgeno y el ncleo de hidrgeno }\par\pa
rd\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {hay dos pares de electro
nes solitarios en la capa exterior del tomo de oxgeno. }\par\pard\li586\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100
{Una consecuencia de este arreglo de electrones es que la molcula de agua es pola
r, es decir, el centro }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscal
ex100 {de las cargas positivas no coincide con el de las cargas negativas. Una c
arga positiva se ubica en cada }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\

charscalex100 {ncleo de hidrgeno y ocho cargas positivas en el ncleo del
oxgeno, la carga negativa del par de }\par\pard\li600\ri0\sl-240\slmult0 \
fs16\cf0\f1\charscalex100 {electrones solitarios est localizada mucho ms arri
ba del ncleo de oxgeno, y hay un desplazamiento }\par\pard\li600\ri0\sl-22
6\slmult0 \fs20\cf0\f1\charscalex100 {de electrones en los enlaces hacia el tomo
de oxgeno, ms electronegativo. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\p
ard\li600\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {Como resultado de la al
ta polaridad de las molculas de agua, el enlace de hidrgeno se posiciona entre }\p
ar\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {los mismos dipolos
de las molculas de agua, como se aprecia en la Figura 1. Cada molcula de agua
}\par\pard\li600\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {forma cuatro
enlaces de hidrgeno con las dems molculas que la rodean. Los enlaces de
hidrgeno }\par\pard\li600\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {son db
iles, por efecto de la temperatura, las vibraciones moleculares aumenta
n y son suficientes para }\par\pard\li600\ri0\sl-226\slmult0 \fs16\cf0\f1\ch
arscalex100 {romperse en el punto de ebullicin. Al enfriarse, el agua s
e congela para formar cristales de hielo de }\par\pard\li600\ri0\sl-240\s
lmult0 \fs20\cf0\f1\charscalex100 {estructura hexagonal. }\par\pard\li1560\ri0\s
l-213\slmult0 \fs18\cf0\par\pard\li1560\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li
1560\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1560\ri0\sl-213\slmult0 \fs18\cf0\p
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fs18\cf0\par\pard\li1560\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1560\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li1560\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1560\
ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1560\ri0\sl-213\slmult0 \fs18\cf0\par\pa
rd\li1560\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1560\ri0\sl-213\slmult0 \fs18\
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1560\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1560\ri0\sl-320\slmult0 \fs20\cf0\f
0\charscalex100\b {Figura 1 molecula de agua con mostrando la polaridad del ella
ce de hidrogeno }\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\margl
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par\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {10 }\par\pard\sect\s
ectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sbk
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8\cf0\par\pard\li586\ri0\sl-280\slmult0 \fs20\cf0\f0\charscalex100\b {Constante
Dielctrica }\b0 \par\column\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex10
0 {Universidad Catolica del Norte }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghs
xn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard
\li586\ri0\sl-320\slmult0 \fs20\cf0\f1\charscalex100 {La constante dielctrica cor
responde a la habilidad para neutralizar un campo elctrico, por medio de la }\par
\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {orientacin de sus molcu
las, de forma que sus extremos positivos enfrenten el polo negativo del campo }\
par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {elctrico, y a su
vez sus extremos cargados negativamente enfrentan el polo positivo. E
l grado de }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {neu
tralizacin del campo elctrico est directamente relacionado con la polaridad de la s
ustancia. }\par\pard\li5280\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li5280\ri0\sl
-293\slmult0 \fs20\cf0\f1\charscalex100 {Cnte dielctrica (}\fs20\cf0\f2\charscale
x100 {\uc1\u949X}\fs20\cf0\f1\charscalex100 {) }\par\pard\sect\sectd\sbknone\pgw
sxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw5746\colsr-0\colno
2\colw5346\pard\li3746\ri0\sl-200\slmult0 \fs20\cf0\f1\charscalex100 {Compuesto
}\par\pard\li3746\ri0\sl-266\slmult0 \fs20\cf1\f1\charscalex100 {H}{\sub \fs14\c
f1\f1\charscalex100 {2}}\fs20\cf1\f1\charscalex100 {O }\par\pard\li3746\ri0\sl213\slmult0 \fs20\cf0\f1\charscalex100 {Metanol }\par\pard\li3746\ri0\sl-226\slm
ult0 \fs20\cf0\f1\charscalex100 {Etanol }\par\pard\li3746\ri0\sl-253\slmult0 \fs
20\cf0\f1\charscalex100 {H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\cha
rscalex100 {S }\par\pard\li3746\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {C
}{\sub \fs14\cf0\f1\charscalex100 {6}}\fs20\cf0\f1\charscalex100 {H}{\sub \fs14\
cf0\f1\charscalex100 {6}}\par\pard\li3746\ri0\sl-226\slmult0 \fs20\cf0\f1\charsc
alex100 {CCl}{\sub \fs14\cf0\f1\charscalex100 {4}}\par\pard\li3746\ri0\sl-226\sl
mult0 \fs20\cf0\f1\charscalex100 {CH}{\sub \fs14\cf0\f1\charscalex100 {4}}\par\p
ard\li3746\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {Aire }\par\pard\li3746
\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {Mica }\par\pard\li3746\ri0\sl-22
6\slmult0 \fs20\cf0\f1\charscalex100 {Poliestireno }\par\column\pard\li13\ri0\sl
-213\slmult0 \fs20\cf0\f1\charscalex100 {a 298 K }\par\pard\li173\ri0\sl-240\slm
ult0 \fs20\cf1\f1\charscalex100 {78.5 }\par\pard\li173\ri0\sl-226\slmult0 \fs20\
cf0\f1\charscalex100 {32.6 }\par\pard\li253\ri0\sl-226\slmult0 \fs20\cf0\f1\char
scalex100 {24 }\par\pard\li226\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {9.
3 }\par\pard\li226\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {2.2 }\par\pard
\li226\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {2.2 }\par\pard\li226\ri0\s
l-226\slmult0 \fs20\cf0\f1\charscalex100 {1.7 }\par\pard\li0\ri0\sl-240\slmult0
\fs20\cf0\f1\charscalex100 {1.00006 }\par\pard\li226\ri0\sl-226\slmult0 \fs20\cf
0\f1\charscalex100 {5.4 }\par\pard\li226\ri0\sl-226\slmult0 \fs20\cf0\f1\charsca
lex100 {2.5 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\ma
rgrsxn133\pard\li2720\ri0\sl-360\slmult0 \fs20\cf0\f0\charscalex100\b {Tabla 1 C
onstante dielctrica para algunos compuestos }\b0 \par\pard\li600\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li600\ri0\sl-373\slmult0 \fs20\cf0\f1\charscalex100 {El ag
ua tiene una alta constante dielctrica, por tanto, es uno de los solventes ms pola
res que existen, }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100
{esto se debe a la presencia de un tomo muy electronegativo, O, y dos muy poco el
ectronegativos, los H. }\par\pard\li600\ri0\sl-226\slmult0 \fs16\cf0\f1\charscal
ex100 {Como consecuencia las molculas o partculas cargadas elctricamente so
n fcilmente disociadas en }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\cha
rscalex100 {presencia de agua. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par
\cf0\f0\charscalex100\b \i {Ionizacin del agua }\b0 \i0 \par\pard\li600\ri0\sl-21
{El agua pura es un mal conductor elctrico. Esta dbil conductancia se debe a la p
olaridad del agua y a la }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charsc
alex100 {asociacin de las molculas de H}{\sub \fs12\cf0\f1\charscalex100 {2}}

\fs18\cf0\f1\charscalex100 {O a travs de puentes de hidrgeno. Si una molcu
la de agua es }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100
{dividida en H}{\super \fs12\up3\cf0\f1\charscalex100 {+}}\fs18\cf0\f1\charscale
x100 { y OH}{\super \fs12\up3\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charscalex10
0 {, el ion H}{\super \fs12\up3\cf0\f1\charscalex100 {+ }}\fs18\cf0\f1\charscale
x100 {es muy pequeo y presenta una elevada densidad de carga, por lo tanto, }\par
\pard\li586\ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {no puede existir a
islado por s mismo, se asociar a otra molcula de H}{\sub \fs12\cf0\f1\cha
rscalex100 {2}}\fs16\cf0\f1\charscalex100 {O en la ubicacin del par de }\pa
r\pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {electrones solitario
s para formar H}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs20\cf0\f1\charscalex100
{O}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 {, ion
hidronio, como se muestra a continuacin: }\par\pard\li4000\ri0\sl-400\slmult0 \fs
14\cf0\f2\charscalex100 {+}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\
marglsxn666\margrsxn133\cols6\colno1\colw1346\colsr-0\colno2\colw1013\colsr-0\co
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00\pard\li720\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li720\ri0\sl-293\slmult0 \fs
24\cf0\f0\charscalex100\i {H}\i0 { }\fs24\cf0\f0\charscalex100 {O}\par\pard\li72
0\ri0\sl-333\slmult0 \fs24\cf0\f0\charscalex100\i {H}\i0 { }\fs24\cf0\f0\charsca
lex100 {N}\par\column\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0
\sl-333\slmult0 \fs14\cf0\f2\charscalex100 {+}\par\pard\li0\ri0\sl-306\slmult0 \
*\tx733\fs22\cf0\f0\charscalex100 {O}{ }\fs22\cf0\f2\charscalex100 {+}{ }\fs22\c
f0\f0\charscalex100 {H}\tab \fs22\cf0\f2\charscalex100 {\uc1\u8658X}\par\column\
pard\li0\ri0\sl-240\slmult0 \fs24\cf0\f2\charscalex100 {\uc1\u63726X}\par\pard\l
i0\ri0\sl-226\slmult0 \fs22\cf0\f2\charscalex100 {\uc1\u63727X}\par\pard\li0\ri0
\sl-226\slmult0 \fs22\cf0\f2\charscalex100 {\uc1\u63727X}\par\pard\li0\ri0\sl-22
6\slmult0 \fs24\cf0\f2\charscalex100 {\uc1\u63727X}\par\pard\li0\ri0\sl-240\slmu
lt0 \fs24\cf0\f2\charscalex100 {\uc1\u63727X}\par\pard\li0\ri0\sl-240\slmult0 \f
s24\cf0\f2\charscalex100 {\uc1\u63728X}\par\column\pard\li0\ri0\sl-213\slmult0 \
fs18\cf0\par\pard\li0\ri0\sl-293\slmult0 \fs24\cf0\f0\charscalex100\i {H}\i0 { }
\fs24\cf0\f0\charscalex100 {O}\par\pard\li0\ri0\sl-333\slmult0 \fs24\cf0\f0\char
scalex100\i {H}\i0 { }\fs24\cf0\f0\charscalex100 {N}\par\column\pard\li213\ri0\s
l-213\slmult0 \fs18\cf0\par\pard\li213\ri0\sl-466\slmult0 \fs24\cf0\f2\charscale
x100 {\uc1\u8722X}\par\pard\li0\ri0\sl-213\slmult0 \*\tx386\fs24\cf0\f0\charscal
ex100\i {O}\i0 \tab \fs24\cf0\f0\charscalex100\i {H}\i0 \par\column\pard\li0\ri0
\sl-240\slmult0 \fs24\cf0\f2\charscalex100 {\uc1\u63737X}\par\pard\li0\ri0\sl-22
6\slmult0 \fs24\cf0\f2\charscalex100 {\uc1\u63738X}\par\pard\li0\ri0\sl-226\slmu
lt0 \fs24\cf0\f2\charscalex100 {\uc1\u63738X}\par\pard\li0\ri0\sl-226\slmult0 \f
s24\cf0\f2\charscalex100 {\uc1\u63738X}\par\pard\li0\ri0\sl-240\slmult0 \fs24\cf
0\f2\charscalex100 {\uc1\u63738X}\par\pard\li0\ri0\sl-240\slmult0 \fs24\cf0\f2\c
harscalex100 {\uc1\u63739X}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\
marglsxn666\margrsxn133\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\r
i0\sl-293\slmult0 \fs18\cf0\f1\charscalex100 {El enlace entre el O y el H
, representado por una flecha llena, se llama }{ }\fs20\cf0\f0\charscalex
100\b {enlace dativo, }\b0 { }\fs20\cf0\f1\charscalex100 {o }{ }\fs20\cf0\f0\ch
arscalex100\b {enlace de}\b0 \par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f0\ch
arscalex100\b {coordinacin, }\b0 { }\fs18\cf0\f1\charscalex100 {dado que es su
ministrado por el par de electrones solitarios del tomo de oxgeno. El }
\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {nmero de iones H}{
\super \fs12\up4\cf0\f1\charscalex100 {+}}\fs18\cf0\f1\charscalex100 { y OH}{\su
per \fs12\up4\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charscalex100 { es muy pequeo
, por lo que la constante de equilibrio a temperatura ambiente }\par\pard\li586\
ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {para la reaccin que sigue: }\par\p
f0\f1\charscalex100 {H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charsca
lex100 {O }\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 {
H}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { + OH}{
\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {,}{ }\fs20
\cf0\f1\charscalex100 {K = [H}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\c
f0\f1\charscalex100 {] [OH}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\

f1\charscalex100 {] = 10}{\super \fs14\up4\cf0\f1\charscalex100 {-14}}\par\pard\
li586\ri0\sl-440\slmult0 \fs20\cf0\f1\charscalex100 {[H}{\super \fs14\up4\cf0\f1
\charscalex100 {+}}\fs20\cf0\f1\charscalex100 {] concentracin del ion hidrgeno (pr
otn). }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {[OH}{\super
\fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {] concentracin de
iones OH}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100
{ (hidroxilo). }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\
sl-240\slmult0 \fs20\cf0\f1\charscalex100 {La constante de equilibrio depende de
la temperatura, Tabla II. }\par\pard\li1906\ri0\sl-213\slmult0 \fs18\cf0\par\p
ard\li1906\ri0\sl-360\slmult0 \fs20\cf0\f0\charscalex100\b {Tabla II Efecto de l
a temperatura en la constante de ionizacion del agua }\b0 \par\pard\sect\sectd\s
bknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw9893\col
sr-0\colno2\colw1200\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\
586\ri0\sl-320\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\column\
cf0\f0\charscalex100 {11 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\m
arglsxn666\margrsxn133\pard\sect\sectd\sbkpage
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7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}
7;32768}}

3\margtsxn666\margbsxn173\cols3\colno1\colw3466\colsr-0\colno2\colw1973\colsr-0\
colno3\colw5653\pard\li586\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {Hidrom
etalurgia I }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586
lt0 \fs20\cf0\f0\charscalex100\b {cidos y Bases }\b0 \par\column\pard\li0\ri0\sl
0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-346\slmult0 \fs20\cf0\f1\charscal
ex100 {Temperatura }\par\pard\li506\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex10
0 {0 }\par\pard\li453\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {10 }\par\pa
rd\li453\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {20 }\par\pard\li453\ri0\
sl-240\slmult0 \fs20\cf0\f1\charscalex100 {25 }\par\pard\li453\ri0\sl-240\slmult
0 \fs20\cf0\f1\charscalex100 {30 }\par\pard\li453\ri0\sl-240\slmult0 \fs20\cf0\f
1\charscalex100 {40 }\par\pard\li453\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex1
00 {50 }\par\pard\li453\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {60 }\par\
pard\li453\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {70 }\par\pard\li453\ri
0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {80 }\par\pard\li453\ri0\sl-240\slmu
lt0 \fs20\cf0\f1\charscalex100 {90 }\par\pard\li400\ri0\sl-240\slmult0 \fs20\cf0
\f1\charscalex100 {100 }\par\column\pard\li666\ri0\sl-306\slmult0 \fs24\cf0\f0\c
harscalex100 {Universidad Catolica del Norte }\par\pard\li0\ri0\sl-213\slmult0 \
fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-266\slmul
t0 \fs20\cf0\f1\charscalex100 {K}{\sub \fs14\cf0\f1\charscalex100 {H2O}}\fs20\cf
0\f1\charscalex100 {x10}{\super \fs14\up4\cf0\f1\charscalex100 {14}}\par\pard\li
133\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {0.1139 }\par\pard\li133\ri0\s
l-240\slmult0 \fs20\cf0\f1\charscalex100 {0.2920 }\par\pard\li133\ri0\sl-240\slm
ult0 \fs20\cf0\f1\charscalex100 {0.6809 }\par\pard\li186\ri0\sl-240\slmult0 \fs2
0\cf0\f1\charscalex100 {1.008 }\par\pard\li186\ri0\sl-240\slmult0 \fs20\cf0\f1\c
harscalex100 {1.469 }\par\pard\li186\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex1
00 {2.919 }\par\pard\li186\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {5.474
}\par\pard\li186\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {9.614 }\par\pard
\li186\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {15.10 }\par\pard\li240\ri0
\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {23.4 }\par\pard\li240\ri0\sl-240\slm
ult0 \fs20\cf0\f1\charscalex100 {35.5 }\par\pard\li240\ri0\sl-240\slmult0 \fs20\
cf0\f1\charscalex100 {51.3 }\par\pard\li346\ri0\sl-213\slmult0 \fs18\cf0\par\par
fs40\cf0\f2\charscalex100 {[ ][ ]}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsx
n16840\marglsxn666\margrsxn133\cols4\colno1\colw6000\colsr-0\colno2\colw653\cols
r-0\colno3\colw213\colsr-0\colno4\colw4226\pard\li586\ri0\sl-306\slmult0 \fs20\c
f0\f1\charscalex100 {En agua presenta el equilibrio H}{\sub \fs14\cf0\f1\ch
arscalex100 {2}}\fs20\cf0\f1\charscalex100 {O }{ }\fs20\cf0\f2\charscalex100 {\u
c1\u8660X}\fs20\cf0\f1\charscalex100 {H}{\super \fs14\up4\cf0\f1\charscalex100 {
+}}\fs20\cf0\f1\charscalex100 { + OH}{\super \fs14\up4\cf0\f1\charscalex100 {}}\fs24\cf0\f0\charscalex100\i {K}\i0 { }\fs24\cf0\f2\charscalex100 {=}\par\col
umn\pard\li266\ri0\sl-173\slmult0 \fs24\cf0\f0\charscalex100\i {OH}\i0 \par\pard
\li0\ri0\sl-426\slmult0 \fs34\cf0\f2\charscalex100 {[}{\sub \fs24\cf0\f0\charsca
lex100\i {H}\i0 }\fs24\cf0\f0\charscalex100\i {O}\i0 \fs34\cf0\f2\charscalex100
{]}\par\column\pard\li0\ri0\sl-186\slmult0 \fs14\cf0\f2\charscalex100 {\uc1\u872
2X}\par\column\pard\li0\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {, pero
la concentracin [H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex
100 {O] es }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\ma

mult0 \fs20\cf0\f1\charscalex100 {constante, con lo que queda }\par\pard\li1
666\ri0\sl-520\slmult0 \fs26\cf0\f2\charscalex100 {=}{ }\fs40\cf0\f2\charscalex1
00 {[ ][ ]}\par\pard\li1133\ri0\sl-333\slmult0 \*\tx2346\fs26\cf0\f0\charscalex1
00\i {K}\i0 {\sub \fs16\cf0\f0\charscalex100\i {H}\i0 }\fs16\cf0\f0\charscalex10
0\i {O}\i0 \tab \fs26\cf0\f0\charscalex100\i {OH}\i0 { }\fs16\cf0\f2\charscalex1
00 {\uc1\u8722X}{\sub \fs26\cf0\f2\charscalex100 {=}}\par\column{\trowd\trleft0\
trkeep\trftsWidth1\trpaddl0\trpaddr0\trpaddfl3\trpaddfr3 \clvertalt\clbrdrt\brdr
none\clbrdrl\brdrnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb\clNoWrap\clftsW
idth3\clwWidth6853\clpadt0\clpadr0\clpadft3\clpadfr3\cellx10720 \pard\li0\ri0\sl
-213\widctlpar\intbl \fs16\cf0\f2\charscalex100 {\uc1\u8722X}\par\pard\li0\ri0\s
l-186\widctlpar\intbl \fs16\cf0\f0\charscalex100\i {H}\i0 \fs12\cf0\f0\charscale
x100 {2}\fs16\cf0\f0\charscalex100\i {O}\i0 \fs26\cf0\f2\charscalex100 {=}\fs26\
cf0\f0\charscalex100\i {OH}\i0 \fs26\cf0\f0\charscalex100\i {K}\i0 \fs18\cf0\f1\
charscalex100 {, cuyo valor a 18C se denomina producto inico del }\fs14\
cf0\f0\charscalex100 {2}\cell\row}\pard\li240\ri0\sl-186\slmult0 \fs16\cf0\f2\ch
arscalex100 {\uc1\u8722X}\fs16\cf0\f0\charscalex100 {14}\par\pard\sect\sectd\sbk
none\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols4\colno1\colw1440\colsr
-0\colno2\colw1666\colsr-0\colno3\colw733\colsr-0\colno4\colw7253\pard\li586\ri0
\sl-186\slmult0 \fs20\cf0\f1\charscalex100 {agua }\par\column\pard\li0\ri0\sl-93
\slmult0 \fs12\cf0\f0\charscalex100 {2}\par\column\pard\li120\ri0\sl-213\slmult0
\fs26\cf0\f0\charscalex100\i {x}\i0 \par\pard\li0\ri0\sl-213\slmult0 \fs26\cf0\
f0\charscalex100 {1}{ }\fs26\cf0\f0\charscalex100 {10}\par\column\pard\li0\ri0\s
l-186\slmult0 \fs20\cf0\f1\charscalex100 {. }\par\pard\sect\sectd\sbknone\pgwsxn
0\par\pard\li586\ri0\sl-253\slmult0 \*\tx5480\fs20\cf0\f1\charscalex100 {Un cido
es una sustancia que produce protones.}\tab \fs20\cf0\f1\charscalex100 {U
na base es una sustancia que produce iones }\par\pard\li600\ri0\sl-240\sl
mult0 \fs20\cf0\f1\charscalex100 {hidroxilo.}{ }\fs20\cf0\f1\charscalex100 {Si u
na solucin acuosa es neutra, se cumplir que [H}{\super \fs14\up4\cf0\f1\charscalex
100 {+}}\fs20\cf0\f1\charscalex100 {] = [OH}{\super \fs14\up4\cf0\f1\charscalex1
00 {-}}\fs20\cf0\f1\charscalex100 {] = 10}{\super \fs14\up4\cf0\f1\charscalex100
{-7}}\fs20\cf0\f1\charscalex100 { si es cida [H}{\super \fs14\up4\cf0\f1\charsca
lex100 {+}}\fs20\cf0\f1\charscalex100 {] > 10}{\super \fs14\up4\cf0\f1\charscale
x100 {-7 }}\fs20\cf0\f1\charscalex100 {y es }\par\pard\li586\ri0\sl-240\slmult0
\fs20\cf0\f1\charscalex100 {bsica [OH}{\super \fs14\up4\cf0\f1\charscalex100 {-}}
\fs20\cf0\f1\charscalex100 {] > 10}{\super \fs14\up4\cf0\f1\charscalex100 {-7}}\
fs20\cf0\f1\charscalex100 {. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\p
ard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {La acidez o alcalini
dad de una solucin est definida por la escala de pH y pOH, definida
como pH = -}\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Lo
g[H}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs18\cf0\f1\charscalex100 {] y
pOH = -Log[OH}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charsca
lex100 {]. Las escalas de pH y pOH se relacionan entre s, y los valo
res de pH y de }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex10
0 {pOH suman 14. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri
0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {El pH de una solucin 0,1 Molar de HC
I (3,65 g/l ) equivale a pH=1, y el pH de una solucin de 0,1 Molar }\par\pard\li5
86\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {de NaOH (4 g/l ) es pH 13. }\p
18\cf0\par\pard\li773\ri0\sl-266\slmult0 \fs20\cf0\f0\charscalex100\b {Solucione
s Tampn o Amortiguadores de pH }\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\
par\pard\li586\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {En los procesos
hidrometatrgicos es importante que el pH no se desve mucho desde un determinado
}\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {valor.}{ }\fs20
\cf0\f1\charscalex100 {Esto se logra, normalmente, aadiendo al sistema una solucin
tampn, buffer o amortiguadora de }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f
1\charscalex100 {tal forma que cuando un cido o una base se producen a causa del
proceso, el pH del sistema no cambie }\par\pard\li600\ri0\sl-226\slmult0 \fs20\c
f0\f1\charscalex100 {sustancialmente. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\

cf0\par\pard\li600\ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {La solucin ta
mpn es una mezcla de un cido dbil y una de sus sales, por ejemplo, ci
do actico y }\par\pard\li600\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {ace
tato de sodio. La ionizacin del cido actico est dada por: CH}{\sub \fs14\
cf0\f1\charscalex100 {3}}\fs20\cf0\f1\charscalex100 {COOH }{ }\fs20\cf0\f2\chars
calex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { CH}{\sub \fs14\cf0\f1\charsc
alex100 {3}}\fs20\cf0\f1\charscalex100 {COO}{\super \fs14\up4\cf0\f1\charscalex1
00 {-}}\fs20\cf0\f1\charscalex100 { + H}{\super \fs14\up4\cf0\f1\charscalex100
{+}}\fs20\cf0\f1\charscalex100 {,}{ }\fs20\cf0\f1\charscalex100 {y su }\par\pa
rd\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\coln
o1\colw7946\colsr-0\colno2\colw3146\pard\li6493\ri0\sl-413\slmult0 \fs40\cf0\f2\
charscalex100 {[ ][}\par\column\pard\li0\ri0\sl-520\slmult0 \fs16\cf0\f2\charsca
lex100 {\uc1\u8722X}{ }\fs40\cf0\f2\charscalex100 {]}\par\pard\sect\sectd\sbknon
e\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols8\colno1\colw6066\colsr-0\
colno2\colw240\colsr-0\colno3\colw360\colsr-0\colno4\colw320\colsr-0\colno5\colw
1186\colsr-0\colno6\colw280\colsr-0\colno7\colw720\colsr-0\colno8\colw1920\pard\
li586\ri0\sl-186\slmult0 \fs20\cf0\f1\charscalex100 {constante de equilibrio
de disociacin, est dada: }\par\column\pard\li0\ri0\sl-213\slmult0 \fs24\cf0\f0\
charscalex100\i {K}\i0 \par\column\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f2\char
scalex100 {=}\par\column\pard\li0\ri0\sl-426\slmult0 \fs34\cf0\f2\charscalex100
{[}\par\column\pard\li0\ri0\sl-240\slmult0 \fs24\cf0\f0\charscalex100\i {CH}\i0
{\sub \fs16\cf0\f0\charscalex100 {3}}\fs24\cf0\f0\charscalex100\i {COO}\i0 \par\
pard\li893\ri0\sl-426\slmult0 \fs34\cf0\f2\charscalex100 {]}\par\column\pard\li0
\ri0\sl-306\slmult0 \fs24\cf0\f2\charscalex100 {=}\par\column\pard\li613\ri0\sl120\slmult0 \fs16\cf0\f0\charscalex100 {5}\par\pard\li0\ri0\sl-293\slmult0 \fs24
\cf0\f0\charscalex100 {1}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\charscalex10
0 {8}\fs24\cf0\f0\charscalex100\i {x}\i0 \fs24\cf0\f0\charscalex100 {10}\fs16\cf
0\f2\charscalex100 {\uc1\u8722X}\par\column\pard\li0\ri0\sl-186\slmult0 \fs20\cf
0\f1\charscalex100 { donde: }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn168
40\marglsxn666\margrsxn133\pard\li6733\ri0\sl-213\slmult0 \fs24\cf0\f0\charscale
x100\i {CH}\i0 { }\fs24\cf0\f0\charscalex100\i {COOH}\i0 \par\pard\sect\sectd\sb
knone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols11\colno1\colw1120\col
sr-0\colno2\colw213\colsr-0\colno3\colw1400\colsr-0\colno4\colw2346\colsr-0\coln
o5\colw386\colsr-0\colno6\colw333\colsr-0\colno7\colw573\colsr-0\colno8\colw160\
colsr-0\colno9\colw346\colsr-0\colno10\colw1320\colsr-0\colno11\colw2893\pard\li
626\ri0\sl-600\slmult0 \fs40\cf0\f2\charscalex100 {[ ] [}\par\column\pard\li0\ri
0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-333\slmult0 \fs24\cf0\f2\charscal
ex100 {=}\par\column\pard\li0\ri0\sl-520\slmult0 \fs24\cf0\f0\charscalex100\i {K
}\i0 { }\fs24\cf0\f0\charscalex100\i {CH}\i0 {\sub \fs16\cf0\f0\charscalex100 {3
}}\fs24\cf0\f0\charscalex100\i {COO}\i0 \fs16\cf0\f2\charscalex100 {\uc1\u8722X}
{ }\fs40\cf0\f2\charscalex100\ul {]}\ul0 \par\column\pard\li0\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li0\ri0\sl-320\slmult0 \fs20\cf0\f1\charscalex100 { y toma
ndo logaritmo}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri
0\sl-320\slmult0 \fs24\cf0\f0\charscalex100\i {pH}\i0 \par\column\pard\li0\ri0\s
00 {=}{ }\fs24\cf0\f2\charscalex100 {\uc1\u8722X}\par\column\pard\li0\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-320\slmult0 \fs24\cf0\f0\charscalex100 {l
og}{ }\fs24\cf0\f0\charscalex100\i {K}\i0 \par\column\pard\li0\ri0\sl-213\slmult
0 \fs18\cf0\par\pard\li0\ri0\sl-333\slmult0 \fs24\cf0\f2\charscalex100 {\uc1\u87
22X}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-320\sl
mult0 \fs24\cf0\f0\charscalex100 {log}\par\column\pard\li213\ri0\sl-120\slmult0
\fs16\cf0\f0\charscalex100 {3}\par\pard\li0\ri0\sl-426\slmult0 \fs34\cf0\f2\char
scalex100 {[}{\sub \fs24\cf0\f0\charscalex100\i {CH}\i0 }\fs14\cf0\f0\charscalex
100 {3}\fs24\cf0\f0\charscalex100\i {COOH}\i0 {\super \fs34\up-2\cf0\f2\charscal
ex100\ul {]}\ul0 }\par\pard\li53\ri0\sl-520\slmult0 \*\tx1053\fs40\cf0\f2\charsc
alex100 {[}\tab \fs14\cf0\f2\charscalex100 {\uc1\u8722X}{ }\fs40\cf0\f2\charscal
ex100 {]}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-3
20\slmult0 \fs20\cf0\f1\charscalex100 {, en una solucin }\par\pard\sect\sectd\
sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw6973\co
lsr-0\colno2\colw4120\pard\li1373\ri0\sl-426\slmult0 \fs34\cf0\f2\charscalex100
{[}{\sub \fs24\cf0\f0\charscalex100\i {CH}\i0 }\fs16\cf0\f0\charscalex100 {3}\fs
24\cf0\f0\charscalex100\i {COOH}\i0 { }\fs34\cf0\f2\charscalex100 {]}\par\column
\pard\li0\ri0\sl-213\slmult0 \*\tx440\fs24\cf0\f0\charscalex100\i {CH}\i0 \tab \
fs24\cf0\f0\charscalex100\i {COO}\i0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pg
hsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw7333\colsr-0\colno2\colw3760\
pard\li2440\ri0\sl-426\slmult0 \fs34\cf0\f2\charscalex100 {[}{\sub \fs24\cf0\f0\
charscalex100\i {CH}\i0 }\fs24\cf0\f0\charscalex100\i {COOH}\i0 {\super \fs34\up
-2\cf0\f2\charscalex100\ul {]}\ul0 }\par\pard\li3493\ri0\sl-373\slmult0 \fs14\cf
0\f2\charscalex100 {\uc1\u8722X}{\super \fs24\up2\cf0\f2\charscalex100 {=}}\par\
column\pard\li0\ri0\sl-120\slmult0 \fs14\cf0\f0\charscalex100 {3}\par\pard\sect\
sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols5\colno1\colw2
480\colsr-0\colno2\colw373\colsr-0\colno3\colw746\colsr-0\colno4\colw466\colsr-0
\colno5\colw7026\pard\li586\ri0\sl-186\slmult0 \fs20\cf0\f1\charscalex100 {tampn
la relacin }\par\column\pard\li0\ri0\sl-520\slmult0 \fs40\cf0\f2\charscalex100
{[}\par\column\pard\li0\ri0\sl-120\slmult0 \fs14\cf0\f0\charscalex100 {3}\par\co
lumn\pard\li0\ri0\sl-520\slmult0 \fs40\cf0\f2\charscalex100 {]}{\super \fs24\up9
\cf0\f0\charscalex100 {1}}\par\column\pard\li0\ri0\sl-186\slmult0 \fs18\cf0\f1\c
harscalex100 {, entonces el pH es igual a 4,74, si un cido se agrega
a esta }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margr
sxn133\pard\li2533\ri0\sl-213\slmult0 \fs24\cf0\f0\charscalex100\i {CH}\i0 { }\f
s24\cf0\f0\charscalex100\i {COO}\i0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pgh
sxn16840\marglsxn666\margrsxn133\pard\li2893\ri0\sl-120\slmult0 \fs14\cf0\f0\cha
rscalex100 {3}\par\pard\li586\ri0\sl-186\slmult0 \fs20\cf0\f1\charscalex100 {sol
ucin, una proporcin del ion acetato se convierte en cido actico y si se agrega una b
ase, de cido }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\ma
mult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\s
l-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li5
86\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\
pard\li586\ri0\sl-293\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\
column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs
ult0 \fs18\cf0\par\pard\li0\ri0\sl-266\slmult0 \fs24\cf0\f0\charscalex100 {12 }\
par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard
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l Norte }\par\pard\li386\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li386\ri0\sl-546\
slmult0 \fs34\cf0\f2\charscalex100 {[}{\sub \fs24\cf0\f0\charscalex100\i {CH}\i0
}\fs24\cf0\f0\charscalex100\i {COOH}\i0 {\super \fs34\up-2\cf0\f2\charscalex100
\ul {]}\ul0 }\par\pard\li480\ri0\sl-520\slmult0 \fs24\cf0\f0\charscalex100\i {CH
}\i0 {\super \fs14\up11\cf0\f0\charscalex100 {3}}\fs24\cf0\f0\charscalex100\i {C
OO}\i0 \fs14\cf0\f2\charscalex100 {\uc1\u8722X}{ }\fs40\cf0\f2\charscalex100 {]}
\par\pard\li440\ri0\sl-520\slmult0 \fs40\cf0\f2\charscalex100 {[}\par\pard\sect\
sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols3\colno1\colw6
946\colsr-0\colno2\colw866\colsr-0\colno3\colw3280\pard\li586\ri0\sl-186\slmult0
\fs20\cf0\f1\charscalex100 {actico se convierte en ion acetato.}{ }\fs20\cf0\f1\
charscalex100 {En cualquier caso, la relacin }\par\pard\li586\ri0\sl-186\slmult0
\fs20\cf0\f1\charscalex100 {relacin a la unidad y el pH se mantiene casi inaltera
do. }\par\column\pard\li0\ri0\sl-120\slmult0 \fs14\cf0\f0\charscalex100 {3}\par\
column\pard\li0\ri0\sl-186\slmult0 \fs20\cf0\f1\charscalex100 { cambia ligeramen
te con }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsx
n133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-266\slmult0 \
fs20\cf0\f1\charscalex100 {El pH de una solucin de 100 ml de 0,5 M cido
actico (CH}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs20\cf0\f1\charscalex100 {CO
OH) y 0,5 M acetato de sodio }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0
\f1\charscalex100 {(CH}{\sub \fs12\cf0\f1\charscalex100 {3}}\fs18\cf0\f1\charsca
lex100 {COONa) es 4.74, si se le agrega 0,001 moles de hidrxido de sodio (NaOH).}

{ }\fs18\cf0\f1\charscalex100 {Los 100 ml de solucin }\par\pard\li600\ri0\sl-226\
slmult0 \fs20\cf0\f1\charscalex100 {contienen 0,05 moles de CH}{\sub \fs14\c
f0\f1\charscalex100 {3}}\fs18\cf0\f1\charscalex100 {COOH y 0,05 moles de CH
}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs20\cf0\f1\charscalex100 {COONa.}{ }\fs1
8\cf0\f1\charscalex100 {Cuando se agregan 0,001 moles de }\par\pard\li586\r
i0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {NaOH a esta solucin, una cantidad e
quivalente de cido actico reaccionar para convertirse en acetato }\par\pard\li600\r
i0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {de sodio.}{ }\fs20\cf0\f1\charsca
lex100 {Esto entrega 0,049 moles de cido y 0,051 moles de ion acetato
en la solucin final.}{ }\fs20\cf0\f1\charscalex100 {Las }\par\pard\li586\ri0\
sl-240\slmult0 \fs20\cf0\f1\charscalex100 {concentraciones respectivas sern 0,49
M y 0,51 M, y el pH = - Log 1,8 x 10}{\super \fs14\up4\cf0\f1\charscalex100 {-5}
}\fs20\cf0\f1\charscalex100 { -Log (0,49/0.51) = 4,76 }\par\pard\li586\ri0\sl-21
3\slmult0 \fs20\cf0\f1\charscalex100 {El cambio de pH fue insignificante, solame
nte desde 4,74 a 4,76.}{ }\fs20\cf0\f1\charscalex100 {En contraste, cuando se ag
regan 0,001 }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {mole
s de NaOH a 100 ml de agua, sin solucin tampn, el pH resultante llega a 10. }\par\
cf0\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-293\slmult
0 \fs20\cf0\f0\charscalex100\b \i {Solubilidad en agua }\b0 \i0 \par\pard\li600\
ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-320\slmult0 \fs20\cf0\f1\char
scalex100 {La solubilidad en el agua se relaciona con su polaridad y la asociacin
de las molculas de H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscale
x100 {O entre s, }\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {
a travs de los enlaces de hidrgeno.}{ }\fs20\cf0\f1\charscalex100 {A contin
uacin se vern las reglas generales de solubilidad, el }\par\pard\li586\ri0
\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {producto de solubilidad y el efecto
de iones compartidos y formacin de complejos. }\par\pard\li586\ri0\sl-213\slmult0
\slmult0 \fs20\cf0\f0\charscalex100\b {Reglas generales de solubilidad }\b0 \par
\cf0\f1\charscalex100 {Las soluciones acuosas se producen al disolver una
sustancia en agua resultando una mezcla }\par\pard\li586\ri0\sl-226\slmul
t0 \fs18\cf0\f1\charscalex100 {homognea sin reaccin qumica, es decir, sin romperse
los enlaces o transferirse electrones.}{ }\fs18\cf0\f1\charscalex100 {Las reglas
}\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {generales de so
lubilidad son las siguientes: }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\
pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex100\b \ul {Gases:}\b0 \ul0
\fs20\cf0\f1\charscalex100 { Pequeas molculas gaseosas como el oxgeno, O}{\s
ub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {, o hidrgeno, H}
{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {, se disuelve
n en agua }\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {enca
jando en los espacios de la estructura del agua.}{ }\fs20\cf0\f1\charscalex100 {
La solubilidad gaseosa es pequea y disminuye al }\par\pard\li586\ri0\sl-240\slmul
t0 \fs20\cf0\f1\charscalex100 {aumentar la temperatura debido a que las fuerzas
que las mantienen unidas son muy dbiles. }\par\pard\li586\ri0\sl-213\slmult0 \fs1
8\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100\b \ul {Molcula
s polares:}\b0 \ul0 \fs18\cf0\f1\charscalex100 { como la acetona o el alc
ohol, y bases se disuelven fcilmente en agua formando }\par\pard\li600\ri
0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {enlaces de hidrgeno. La solubili
dad disminuye al aumentar la temperatura a causa de la debilidad de }
\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {esos enlaces con
respecto a las vibraciones trmicas. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0
\par\pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex100\b {Molculas no-pola
res:}\b0 \fs20\cf0\f1\charscalex100 { estas molculas, como el tetracloruro de car
bono, CCl}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs20\cf0\f1\charscalex100 {, o e
l benceno, C}{\sub \fs14\cf0\f1\charscalex100 {6}}\fs20\cf0\f1\charscalex100 {H}
{\sub \fs14\cf0\f1\charscalex100 {6}}\fs20\cf0\f1\charscalex100 {, son }\par\par
d\li600\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {insolubles en agua debido
a la inhabilidad de sta para formar enlaces de hidrgeno. }\par\pard\li600\ri0\sl213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-253\slmult0 \fs18\cf0\f0\charscalex1

00\b {Cristales inicos:}\b0 \fs16\cf0\f1\charscalex100 { Se disuelven en agu
a a causa de dos razones: i) la tendencia a hidratarse de los }\par\
pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {iones en el cristal
, ii) el debilitamiento de las fuerzas electrostticas de atraccin intern
a en un cristal }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex10
0 {inico (energa del reticulado) como resultado de la presencia de las
molculas de agua, altamente }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\c
harscalex100 {polares.}{ }\fs18\cf0\f1\charscalex100 {La alta constante dielctric
a del agua hace que las fuerzas de atraccin entre cationes y aniones }\par\pard\l
i600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {en una sal se reduzcan, por
un factor de 80 veces, cuando el agua se encuentra entre ellos. }\par\pard\li600
rscalex100\b \ul {Cristales no-inicos:}\b0 \ul0 \fs18\cf0\f1\charscalex100 { co
mo los metales o cristales covalentes son insolubles debido a la impo
sibilidad }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {de la
s molculas de agua de debilitar los fuertes enlaces, metlicos o covalen
tes, que mantienen }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex
100 {fuertemente sujetos los tomos dentro del cristal. }\par\pard\li600\ri0\sl-21
{Efecto de solventes orgnicos: la adicin de un solvente orgnico a una solucin acuos
a de un electrolito }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex1
00 {normalmente disminuye la solubilidad de los solutos, debido a que
la constante dielctrica del medio }\par\pard\li600\ri0\sl-226\slmult0 \fs20\c
f0\f1\charscalex100 {disminuye, lo que fortalece las fuerzas entre los i
ones.}{ }\fs20\cf0\f1\charscalex100 {Por ejemplo, la adicin de acetona (con
stante }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {dielctrica
= 20) a una solucin de sulfato ferroso produce la precipitacin del F
eSO}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs20\cf0\f1\charscalex100 {*H}{\sub \f
s14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O, ya que la }\par\p
ard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {acetona tiene una const
ante dielctrica menor que la del agua. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\
cf0\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Efecto de fuer
zas nter-inicas: electrolitos levemente solubles son ms solubles en soluciones de s
ales }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {extraas que
en agua pura.}{ }\fs20\cf0\f1\charscalex100 {En soluciones diluidas los iones es
tn libres y separados, de forma que no se }\par\pard\li600\ri0\sl-226\slmult0 \fs
20\cf0\f1\charscalex100 {influencian entre s.}{ }\fs20\cf0\f1\charscalex100 {Sin
embargo, en soluciones ms concentradas: }\par\pard\li586\ri0\sl-240\slmult0 \fs20
\cf0\f1\charscalex100 {i) Cualquier in est rodeado con iones de carga opuesta. }\p
ar\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2
\colno1\colw9893\colsr-0\colno2\colw1200\pard\li586\ri0\sl-213\slmult0 \fs18\cf0
fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmu
slmult0 \fs24\cf0\f0\charscalex100 {13 }\par\pard\sect\sectd\sbknone\pgwsxn11893
\pghsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sbkpage
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{\shp{\*\shpinst\shpleft3240\shptop9880\shpright3240\shpbottom10173\shpfhdr0\shp
wr3\shpwrk0\shpfblwtxt1\shplid2341\shpz29\shpbxpage\shpbypage
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\fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {ii) Las
interacciones electrostticas son ms fuertes, ya que los iones estn ms prximos. }\par\
cf0\par\pard\li586\ri0\sl-280\slmult0 \fs20\cf0\f0\charscalex100\b {Producto de
solubilidad }\b0 \par\pard\li3666\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3666\r
i0\sl-280\slmult0 \fs14\cf0\f2\charscalex100 {\uc1\u8594X}\par\pard\li3613\ri0\s

l-213\slmult0 \fs24\cf0\f0\charscalex100 {V}\par\pard\sect\sectd\sbknone\pgwsxn1
0\f0\charscalex100 {1}\par\pard\li586\ri0\sl-266\slmult0 \*\tx3666\*\tx3906\fs20
\cf0\f1\charscalex100 {En un proceso homogneo AB }\tab \fs14\cf0\f2\charscale
x100 {\uc1\u8592X}\tab \fs20\cf0\f1\charscalex100 { A + B, la velocidad de
la reaccin directa (haca adelante) V}{\sub \fs14\cf0\f1\charscalex100 {1}}\
fs20\cf0\f1\charscalex100 {, es }\par\pard\li3600\ri0\sl-253\slmult0 \fs24\cf0\
f0\charscalex100 {V}{\sub \fs14\cf0\f0\charscalex100 {2}}\par\pard\li586\ri0\sl186\slmult0 \fs18\cf0\f1\charscalex100 {proporcional a la concentracin de AB
, mientras que la velocidad de la reaccin reversible (hacia atrs }\par\p
ard\li586\ri0\sl-200\slmult0 \fs18\cf0\f1\charscalex100 {hacia la izquierda) V}{
\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\charscalex100 {, es proporciona
l tanto a las concentraciones de A como de B. Esto puede expresarse }\par\pard\l
i586\ri0\sl-186\slmult0 \fs20\cf0\f1\charscalex100 {como: }\par\pard\li613\ri0\
sl-546\slmult0 \fs26\cf0\f0\charscalex100\i {V}\i0 {\sub \fs16\cf0\f0\charscalex
100 {1}}\fs26\cf0\f2\charscalex100 {=}{ }\fs26\cf0\f0\charscalex100\i {k}\i0 {\s
ub \fs16\cf0\f0\charscalex100 {1}}\fs34\cf0\f2\charscalex100 {[ ]}{\sub \fs20\cf
0\f1\charscalex100 {y}}\fs26\cf0\f0\charscalex100\i {V}\i0 {\sub \fs16\cf0\f0\ch
arscalex100\i {2}\i0 }\fs26\cf0\f2\charscalex100 {=}{ }\fs26\cf0\f0\charscalex10
0\i {k}\i0 {\sub \fs16\cf0\f0\charscalex100\i {2}\i0 }\fs34\cf0\f2\charscalex100
{[ ][ ]}\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-266\
slmult0 \fs18\cf0\f1\charscalex100 {Donde k}{\sub \fs12\cf0\f1\charscalex100 {1
}}\fs18\cf0\f1\charscalex100 { y k}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\
cf0\f1\charscalex100 { son las constantes de velocidad de las reacciones
hacia delante y hacia atrs, }\par\pard\li586\ri0\sl-226\slmult0 \*\tx2186\f
s18\cf0\f1\charscalex100 {respectivamente.}\tab \fs18\cf0\f1\charscalex100 {Ahor
a bien, en el equilibrio ambas velocidades se igualan, es decir, V}{\
sub \fs12\cf0\f1\charscalex100 {1}}\fs18\cf0\f1\charscalex100 { = V}{\sub \fs1
2\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\charscalex100 {, lo que }\par\pard\sec
t\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\col
w2253\colsr-0\colno2\colw8840\pard\li1600\ri0\sl-333\slmult0 \fs34\cf0\f2\charsc
alex100 {[ ][ ]}\par\pard\li600\ri0\sl-426\slmult0 \fs20\cf0\f1\charscalex100 {e
quivale a }{\sub \fs34\cf0\f2\charscalex100\ul {[ ]}\ul0 }\par\column\pard\li0\r
i0\sl-426\slmult0 \*\tx506\fs24\cf0\f2\charscalex100 {=}{\super \fs24\up5\cf0\f0
\charscalex100\i {k}\i0 }\fs16\cf0\f0\charscalex100 {1}\tab \fs24\cf0\f2\charsca
lex100 {=}{ }\fs24\cf0\f0\charscalex100\i {K}\i0 { }\fs20\cf0\f1\charscalex100 {
donde K es la constante de equilibrio. }\par\pard\li213\ri0\sl-253\slmult0 \fs2
4\cf0\f0\charscalex100\i {k}\i0 {\sub \fs16\cf0\f0\charscalex100 {2}}\par\pard\s
ect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0
lex100 {Consideremos ahora la disolucin de una sal AB, escasamente soluble en ag
ua, la que se disocia en los }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\c
harscalex100 {iones A}{\super \fs14\up3\cf0\f1\charscalex100 {+ }}\fs20\cf0\f1\c
harscalex100 {y B}{\super \fs14\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charsc
alex100 {.}{ }\fs20\cf0\f1\charscalex100 {La velocidad de disolucin depender del re
a superficial de la sal.}{ }\fs20\cf0\f1\charscalex100 {Una vez que la solucin }\
par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {se satura, la diso
lucin se detiene, ya que la velocidad de recristalizacin se iguala con la de disol
ucin.}\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-240\slmu
lt0 \fs18\cf0\f1\charscalex100 {Dado que la cantidad de AB no influye en
el grado de saturacin, puede ser considerada como una }\par\pard\li600\
ri0\sl-520\slmult0 \fs20\cf0\f1\charscalex100 {constante.}{ }\fs20\cf0\f1\charsc
alex100 {As, queda }{ }\fs40\cf0\f2\charscalex100 {[ ][ ]}\fs14\cf0\f2\charscalex
100 {\uc1\u8722X}{\sub \fs24\cf0\f2\charscalex100 {=}}\fs24\cf0\f0\charscalex100
\i {K}\i0 {\sub \fs14\cf0\f0\charscalex100\i {PS}\i0 }\fs24\cf0\f2\charscalex100
{=}{ }\fs24\cf0\f0\charscalex100\i {K}\i0 {\super \fs34\up-1\cf0\f2\charscalex1
00 {[ ]}}\fs20\cf0\f1\charscalex100 { donde: Kps es el}{ }\fs20\cf0\f1\charscale
x100 {producto de solubilidad. }\par\pard\li586\ri0\sl-320\slmult0 \fs20\cf0\f1\
charscalex100 {Las concentraciones deben expresarse en molaridad. }\par\pard\li

charscalex100 {La Tabla III muestra el producto de solubilidad determinados a pa
rtir de datos experimentales.}\par\pard\li3880\ri0\sl-213\slmult0 \fs18\cf0\par\
pard\li3880\ri0\sl-360\slmult0 \fs20\cf0\f0\charscalex100\b {Tabla III }\b0 \fs2
0\cf0\f1\charscalex100 {Productos de solubilidad }\par\pard\sect\sectd\sbknone\p
gwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw5706\colsr-0\col
no2\colw5386\pard\li2640\ri0\sl-360\slmult0 \*\tx4080\fs20\cf0\f0\charscalex100\
b {Compuesto }\b0 \tab \fs20\cf0\f0\charscalex100\b {Kps }\b0 \par\column\pard\l
i0\ri0\sl-360\slmult0 \*\tx1440\fs20\cf0\f0\charscalex100\b {Compuesto }\b0 \tab
\fs20\cf0\f0\charscalex100\b {Kps }\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893
\pghsxn16840\marglsxn666\margrsxn133\cols4\colno1\colw4080\colsr-0\colno2\colw16
26\colsr-0\colno3\colw1440\colsr-0\colno4\colw3946\pard\li2640\ri0\sl-333\slmult
0 \fs20\cf0\f1\charscalex100 {AI(OH)}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\p
ard\li2640\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {BaCO}{\sub \fs14\cf0\f
1\charscalex100 {3}}\par\pard\li2640\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex1
00 {BaCrO}{\sub \fs14\cf0\f1\charscalex100 {4}}\par\pard\li2640\ri0\sl-293\slmul
t0 \fs20\cf0\f1\charscalex100 {BaF}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\par
d\li2640\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {BaSO}{\sub \fs14\cf0\f1\
charscalex100 {4}}\par\pard\li2640\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100
{CaCO}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\pard\li2640\ri0\sl-293\slmult0
\fs20\cf0\f1\charscalex100 {CaF}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\l
i2640\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {CaSO}{\sub \fs14\cf0\f1\cha
rscalex100 {4}}\par\pard\li2640\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {C
u(OH)}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\li2640\ri0\sl-293\slmult0 \
fs20\cf0\f1\charscalex100 {U(IO}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs20\cf0\f
1\charscalex100 {)}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\column\pard\li0\ri0
\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {3 x 10}{\super \fs14\up3\cf0\f1\char
scalex100 {-34}}\par\pard\li0\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {5 x
10}{\super \fs14\up4\cf0\f1\charscalex100 {-9}}\par\pard\li0\ri0\sl-293\slmult0
\fs20\cf0\f1\charscalex100 {2,1 x 10}{\super \fs14\up4\cf0\f1\charscalex100 {-1
0}}\par\pard\li0\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {1,7 x 10}{\super
\fs14\up4\cf0\f1\charscalex100 {-6}}\par\pard\li0\ri0\sl-293\slmult0 \fs20\cf0\
f1\charscalex100 {1,1 x 10}{\super \fs14\up4\cf0\f1\charscalex100 {-10}}\par\par
d\li0\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {4,5 x 10}{\super \fs14\up4\
cf0\f1\charscalex100 {-9}}\par\pard\li0\ri0\sl-293\slmult0 \fs20\cf0\f1\charscal
ex100 {3,9 x 10}{\super \fs14\up4\cf0\f1\charscalex100 {-11}}\par\pard\li0\ri0\s
l-293\slmult0 \fs20\cf0\f1\charscalex100 {2,4 X 10}{\super \fs14\up3\cf0\f1\char
scalex100 {-5}}\par\pard\li0\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {4,8
X 10}{\super \fs14\up4\cf0\f1\charscalex100 {-20}}\par\pard\li0\ri0\sl-280\slmul
t0 \fs20\cf0\f1\charscalex100 {7,4 x 10}{\super \fs14\up3\cf0\f1\charscalex100 {
-8}}\par\column\pard\li0\ri0\sl-333\slmult0 \fs20\cf0\f1\charscalex100 {Mg(OH)}{
\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\li0\ri0\sl-293\slmult0 \fs20\cf0\f
1\charscalex100 {Mn(OH)}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\li0\ri0\s
l-293\slmult0 \fs20\cf0\f1\charscalex100 {Hg}{\sub \fs14\cf0\f1\charscalex100 {2
}}\fs20\cf0\f1\charscalex100 {CI}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\
li0\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {AgBrO}{\sub \fs14\cf0\f1\char
scalex100 {3}}\par\pard\li0\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {AgBr
}\par\pard\li0\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {AgCl }\par\pard\li
0\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {Ag}{\sub \fs14\cf0\f1\charscale
x100 {2}}\fs20\cf0\f1\charscalex100 {CrO}{\sub \fs14\cf0\f1\charscalex100 {4}}\p
ar\pard\li0\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {Agl }\par\pard\li0\ri
0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {AgSCN }\par\pard\li0\ri0\sl-306\slm
ult0 \fs20\cf0\f1\charscalex100 {ZnCO}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\
column\pard\li0\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {8.9 X 10}{\super
f1\charscalex100 {2 X 10}{\super \fs14\up4\cf0\f1\charscalex100 {-13}}\par\pard\
li0\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {1,2 X 10}{\super \fs14\up4\cf
0\f1\charscalex100 {-18}}\par\pard\li0\ri0\sl-293\slmult0 \fs20\cf0\f1\charscale
x100 {5,5 x 10}{\super \fs14\up4\cf0\f1\charscalex100 {-5}}\par\pard\li0\ri0\sl293\slmult0 \fs20\cf0\f1\charscalex100 {5 X 10}{\super \fs14\up4\cf0\f1\charscal
ex100 {-13}}\par\pard\li0\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {1,8 x 1

0}{\super \fs14\up4\cf0\f1\charscalex100 {-10}}\par\pard\li0\ri0\sl-293\slmult0
\fs20\cf0\f1\charscalex100 {1,2 X 10}{\super \fs14\up4\cf0\f1\charscalex100 {-12
}}\par\pard\li0\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {8,3 X 10}{\super
f1\charscalex100 {1,1 X 10}{\super \fs14\up4\cf0\f1\charscalex100 {-12}}\par\par
d\li0\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {1 x 10}{\super \fs14\up3\cf
0\f1\charscalex100 {-10}}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\ma
rglsxn666\margrsxn133\cols3\colno1\colw4080\colsr-0\colno2\colw1626\colsr-0\coln
o3\colw5386\pard\li2640\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {La(OH)}{\
sub \fs14\cf0\f1\charscalex100 {3}}\par\pard\li2640\ri0\sl-386\slmult0 \fs20\cf0
\f1\charscalex100 {PbSO}{\sub \fs14\cf0\f1\charscalex100 {4}}\par\column\pard\li
0\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {2 X 10}{\super \fs14\up4\cf0\f1
\charscalex100 {-21}}\par\pard\li0\ri0\sl-386\slmult0 \fs20\cf0\f1\charscalex100
{1,6 X 10}{\super \fs14\up4\cf0\f1\charscalex100 {-8}}\par\column\pard\li0\ri0\
sl-293\slmult0 \*\tx1440\fs20\cf0\f1\charscalex100 {Zn(OH)}\fs14\cf0\f1\charscal
ex100 {2amorfo}\tab \fs20\cf0\f1\charscalex100 {3 X 10}{\super \fs14\up4\cf0\f1\
charscalex100 {-16}}\par\pard\li0\ri0\sl-386\slmult0 \fs20\cf0\f1\charscalex100
{Zn(OH)}\fs12\cf0\f1\charscalex100 {2cristalino}\fs20\cf0\f1\charscalex100 { 6
x 10}{\super \fs14\up4\cf0\f1\charscalex100 {-17}}\par\pard\sect\sectd\sbknone\p
gwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \fs
18\cf0\par\pard\li586\ri0\sl-386\slmult0 \fs20\cf0\f1\charscalex100 {Se suele ut
ilizar esta constante de equilibrio de electrolitos fuertes slo en los casos de b
aja concentracin }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {
por 2 razones principalmente: }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16
840\marglsxn666\margrsxn133\cols2\colno1\colw1306\colsr-0\colno2\colw9786\pard\l
i586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {1. }\par\column\pard\li0\ri0
\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {Las soluciones concentradas no s
on soluciones ideales, y las expresiones de la constante de }\par\pard\
sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\
colw9893\colsr-0\colno2\colw1200\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\char
scalex100 {equilibrio no son aplicables. }\par\pard\li586\ri0\sl-213\slmult0 \fs
100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard
cf0\f0\charscalex100 {14 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\m
arglsxn666\margrsxn133\pard\sect\sectd\sbkpage
7;32768}}

xn133\cols2\colno1\colw1306\colsr-0\colno2\colw9786\pard\li586\ri0\sl-213\slmult
0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-24
0\slmult0 \fs20\cf0\f1\charscalex100 {2. }\par\column\pard\li0\ri0\sl-213\slmult
mult0 \fs20\cf0\f1\charscalex100 {Debido a la baja concentracin, no se puede calc
ular directamente la solubilidad de estas sales, sin }\par\pard\sect\sectd\sbkno
ne\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-226\slmult0
\fs18\cf0\f1\charscalex100 {embargo, se puede detectar los iones disuelto
s mediante la medicin de voltaje. Estas mediciones dan }\par\pard\li586\r
i0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {directamente el Kps. }\par\pard\li
charscalex100\ul {CLCULO DE LA SOLUBILIDAD}\ul0 \fs20\cf0\f1\charscalex100\ul { }
\ul0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-253\slmu
lt0 \fs20\cf0\f1\charscalex100 {Cmo calcular la solubilidad de una sal a partir d
el valor de Kps, o viceversa. }\par\pard\li586\ri0\sl-466\slmult0 \fs20\cf0\f1\
charscalex100 {El producto de solubilidad de la reaccin: BaCO}{\sub \fs14\cf0\f1\
charscalex100 {3}}\fs20\cf0\f1\charscalex100 { Ba}{\super \fs14\up4\cf0\f1\chars
calex100 {+2}}\fs20\cf0\f1\charscalex100 { + CO}{\sub \fs14\cf0\f1\charscalex100
{3}}\fs14\cf0\f1\charscalex100 { -2 }\fs20\cf0\f1\charscalex100 {es Kps = 5,0 x
10}{\super \fs14\up4\cf0\f1\charscalex100 {-9}}\fs20\cf0\f1\charscalex100 {; lu
ego, [Ba}{\super \fs14\up4\cf0\f1\charscalex100 {+2}}\fs20\cf0\f1\charscalex100
{][CO}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs14\cf0\f1\charscalex100 { -2}{\sub
\fs20\cf0\f1\charscalex100 {]= }}\par\pard\li586\ri0\sl-253\slmult0 \fs18\cf0\f
1\charscalex100 {K}{\sub \fs12\cf0\f1\charscalex100 {ps}}\fs18\cf0\f1\charscalex
100 { =5,0x10}{\super \fs12\up4\cf0\f1\charscalex100 {-9}}\fs18\cf0\f1\charscale
x100 {, las unidades de concentracin es mol/L, la ecuacin indica que por cada mol
de Ba}{\super \fs12\up4\cf0\f1\charscalex100 {+2}}\fs18\cf0\f1\charscalex100 { q
ue se }\par\pard\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {disuelve,
hay un mol del CO}{\sub \fs12\cf0\f1\charscalex100 {3}}\fs12\cf0\f1\charscalex10
0 {-2}\fs18\cf0\f1\charscalex100 {, [Ba}{\super \fs12\up4\cf0\f1\charscalex100 {
+2}}\fs18\cf0\f1\charscalex100 {] = [CO}{\sub \fs12\cf0\f1\charscalex100 {3}}\fs
12\cf0\f1\charscalex100 {-2}\fs18\cf0\f1\charscalex100 {], por lo tanto obtenemo
s que: [Ba}{\super \fs12\up4\cf0\f1\charscalex100 {2+}}\fs18\cf0\f1\charscalex10
0 {][CO}{\sub \fs12\cf0\f1\charscalex100 {3}}\fs12\cf0\f1\charscalex100 {-2}\fs1
8\cf0\f1\charscalex100 {] = [Ba}{\super \fs12\up4\cf0\f1\charscalex100 {2+}}\fs1

8\cf0\f1\charscalex100 {]}{\super \fs12\up4\cf0\f1\charscalex100 {2}}\fs18\cf0\f
1\charscalex100 { = 5,0x }\par\pard\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charsc
alex100 {10}{\super \fs12\up4\cf0\f1\charscalex100 {-9 }}\fs18\cf0\f1\charscalex
100 {=> [Ba}{\super \fs12\up4\cf0\f1\charscalex100 {+2}}\fs18\cf0\f1\charscalex
100 {] = 7,07 x10}{\super \fs12\up4\cf0\f1\charscalex100 {-5}}\fs16\cf0\f1\ch
arscalex100 {, que es la concentracin de Ba}{\super \fs12\up4\cf0\f1\charsc
alex100 {+2}}\fs16\cf0\f1\charscalex100 {, igual a la concentracin de CO}{\
sub \fs12\cf0\f1\charscalex100 {3}}\fs12\cf0\f1\charscalex100 {-2}\fs18\cf0\f1\c
harscalex100 {, luego la }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\char
scalex100 {solubilidad del BaCO}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs20\cf0\f
1\charscalex100 { es 7,07 x 10}{\super \fs14\up4\cf0\f1\charscalex100 {-5}}\fs20
\cf0\f1\charscalex100 { M }\par\pard\li600\ri0\sl-373\slmult0 \fs20\cf0\f1\chars
calex100 {Para una reaccin del tipo: A}{\sub \fs14\cf0\f1\charscalex100 {(s)}}\fs
20\cf0\f1\charscalex100 {bB}{\super \fs14\up4\cf0\f1\charscalex100 {+c}}\fs14\cf
0\f1\charscalex100 {(ac)}{\super \fs20\cf0\f1\charscalex100 {+cC}}\fs14\cf0\f1\c
harscalex100 {-b}\fs14\cf0\f1\charscalex100 {(ac)}\fs20\cf0\f1\charscalex100 {,
el producto de solubilidad es Kps = [B}{\super \fs14\up4\cf0\f1\charscalex100 {+
c}}\fs20\cf0\f1\charscalex100 {]}{\super \fs14\up4\cf0\f1\charscalex100 {b}}\fs2
0\cf0\f1\charscalex100 {[C}{\super \fs14\up4\cf0\f1\charscalex100 {-b}}\fs20\cf0
\f1\charscalex100 {]}{\super \fs14\up4\cf0\f1\charscalex100 {c}}\par\pard\li586\
ri0\sl-453\slmult0 \*\tx4813\fs18\cf0\f1\charscalex100 {Considerando la siguie
nte reaccin: CaF}\fs12\cf0\f1\charscalex100 {2(s)}\tab \fs18\cf0\f1\charscalex1
00 { Ca}{\super \fs12\up3\cf0\f1\charscalex100 {+2}}\fs12\cf0\f1\charscalex100
{(ac)}\fs18\cf0\f1\charscalex100 { + 2F}{\super \fs12\up3\cf0\f1\charscalex100
{-}}\fs12\cf0\f1\charscalex100 {(ac)}\fs18\cf0\f1\charscalex100 {: Kps [Ca}{\
super \fs12\up3\cf0\f1\charscalex100 {+2}}\fs18\cf0\f1\charscalex100 {][F}{\supe
r \fs12\up3\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charscalex100 {]}{\super \fs12
\up3\cf0\f1\charscalex100 {2}}\fs16\cf0\f1\charscalex100 {, de la tabla sabe
mos que }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {Kps = 3
,9 x 10}{\super \fs12\up3\cf0\f1\charscalex100 {-11}}\fs18\cf0\f1\charscalex100
{. Segn la estequiometra y considerando agua pura, la nica fuente de Ca}{\super \fs
12\up3\cf0\f1\charscalex100 {+2}}\fs18\cf0\f1\charscalex100 { y F}{\super \fs12\
up3\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charscalex100 { es la sal, }\par\pard\
li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {se disuelven 2 veces ms ione
s F}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 { que
Ca}{\super \fs14\up4\cf0\f1\charscalex100 {+2}}\fs20\cf0\f1\charscalex100 {. Con
esto, podemos escribir lo siguiente: [F}{\super \fs14\up4\cf0\f1\charscalex100
{-}}\fs20\cf0\f1\charscalex100 {] = 2[Ca}{\super \fs14\up4\cf0\f1\charscalex100
{+2}}\fs20\cf0\f1\charscalex100 {]: }\par\pard\li586\ri0\sl-440\slmult0 \fs20\cf
0\f1\charscalex100 {[Ca}{\super \fs14\up4\cf0\f1\charscalex100 {+2}}\fs20\cf0\f1
\charscalex100 {].(2[Ca}{\super \fs14\up4\cf0\f1\charscalex100 {+2}}\fs20\cf0\f1
\charscalex100 { ])}{\super \fs14\up4\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\char
scalex100 { = 3,9x 10}{\super \fs14\up4\cf0\f1\charscalex100 {-11}}\fs20\cf0\f1\
charscalex100 { => [Ca}{\super \fs14\up4\cf0\f1\charscalex100 {+2}}\fs20\cf0\f1\
charscalex100 {] = 2,1 x 10}{\super \fs14\up4\cf0\f1\charscalex100 {-4}}\fs20\cf
0\f1\charscalex100 { M }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li
586\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {Como se disuelve 1 mol de Ca}
{\super \fs14\up4\cf0\f1\charscalex100 {+2}}\fs20\cf0\f1\charscalex100 { por cad
a mol de sal, la solubilidad del CaF}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\
cf0\f1\charscalex100 { es 2,1x10}{\super \fs14\up4\cf0\f1\charscalex100 {-4}}\fs
20\cf0\f1\charscalex100 { M. }\par\pard\li586\ri0\sl-453\slmult0 \fs18\cf0\f1\ch
arscalex100 {Cuando se disuelve cromato de plata (Ag}{\sub \fs12\cf0\f1\charscal
ex100 {2}}\fs18\cf0\f1\charscalex100 {CrO}{\sub \fs12\cf0\f1\charscalex100 {4}}\
fs18\cf0\f1\charscalex100 {) en agua pura, cul es la relacin entre [Ag}{\super \fs1
2\up4\cf0\f1\charscalex100 {+}}\fs18\cf0\f1\charscalex100 {] y [CrO}{\sub \fs12
\cf0\f1\charscalex100 {4}}\fs12\cf0\f1\charscalex100 {-2}{\sub \fs18\cf0\f1\char
scalex100 {]? }}\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {C
ombinando este resultado y la ecuacin de Kps calcule la solubilidad de la sal. }\
par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-266\slmult0 \*
\tx3173\fs18\cf0\f1\charscalex100 {La reaccin es Ag}{\sub \fs12\cf0\f1\charscalex

100 {2}}\fs18\cf0\f1\charscalex100 {CrO}\fs12\cf0\f1\charscalex100 {4(s)}\tab \f
s18\cf0\f1\charscalex100 { 2Ag}{\super \fs12\up4\cf0\f1\charscalex100 {+}}\fs12\
cf0\f1\charscalex100 {(aq)}\fs18\cf0\f1\charscalex100 { + CrO}{\super \fs12\up4\
cf0\f1\charscalex100 {+2}}\fs12\cf0\f1\charscalex100 {4 (ac)}\fs18\cf0\f1\charsc
alex100 {, se disuelven 2 moles de plata por cada cromato, luego: }\par\pard\li5
86\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {[Ag}{\super \fs12\up3\cf0\f1\c
harscalex100 {+}}\fs18\cf0\f1\charscalex100 {] = 2[CrO}{\sub \fs12\cf0\f1\charsc
alex100 {4}}\fs12\cf0\f1\charscalex100 {-2}\fs18\cf0\f1\charscalex100 {] lo cual
es la relacin entre las concentraciones. El producto de solubilidad es [Ag}{\sup
er \fs12\up3\cf0\f1\charscalex100 {+}}\fs18\cf0\f1\charscalex100 {]}{\super \fs1
2\up3\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\charscalex100 {[CrO}{\sub \fs12\cf0\
f1\charscalex100 {4}}\fs12\cf0\f1\charscalex100 {-2}{\sub \fs18\cf0\f1\charscale
x100 {] }}\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {= Kps =
1,2 x10}{\super \fs14\up3\cf0\f1\charscalex100 {-12}}\fs20\cf0\f1\charscalex100
{, remplazando, obtenemos que (2[CrO}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs14
\cf0\f1\charscalex100 {-2}{\sub \fs20\cf0\f1\charscalex100 {])}}\fs14\cf0\f1\cha
rscalex100 {2}\fs20\cf0\f1\charscalex100 { [CrO}{\sub \fs14\cf0\f1\charscalex100
{4}}\fs14\cf0\f1\charscalex100 {-2}\fs20\cf0\f1\charscalex100 {] = 1,2 x 10}\fs
14\cf0\f1\charscalex100 {-12 }\fs20\cf0\f1\charscalex100 {=> [CrO}{\sub \fs14\cf
0\f1\charscalex100 {4}}\fs14\cf0\f1\charscalex100 {-2}\fs20\cf0\f1\charscalex100
{] = 6,69 x 10}{\super \fs14\up3\cf0\f1\charscalex100 {-5}}\par\pard\li586\ri0\
sl-186\slmult0 \fs20\cf0\f1\charscalex100 {M, como se disuelve 1 mol de cromato
por cada mol de sal, entonces la solubilidad del cromato de plata es }\par\pard\
li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {6,69 x 10}{\super \fs14\up4
\cf0\f1\charscalex100 {-5}}\fs20\cf0\f1\charscalex100 {. }\par\pard\li586\ri0\sl
100 {La solubilidad del CuCl (PM CuCl = 99) en agua es 0,042 g/l a
20C, es decir, la solucin saturada }\par\pard\li586\ri0\sl-240\slmult0 \fs20
\cf0\f1\charscalex100 {contiene 0,042/99 mol/l de Cu}{\super \fs14\up4\cf0\f1\ch
arscalex100 {+}}\fs20\cf0\f1\charscalex100 { y una cantidad igual de CI}{\super
\fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {.}{ }\fs20\cf0\f1
\charscalex100 {As: Kps = [Cu}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf
0\f1\charscalex100 {] [Cl}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f
1\charscalex100 {]= (0,042/99) * (0,042/99) }\par\pard\li600\ri0\sl-240\slmult0
\fs20\cf0\f1\charscalex100 {= 1,8 * 10}{\super \fs14\up4\cf0\f1\charscalex100 {7}}\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-240\slmult
0 \fs20\cf0\f1\charscalex100 {PbCl}{\sub \fs14\cf0\f1\charscalex100 {2 }}\fs20\c
f0\f1\charscalex100 {(PM = 278) la solubilidad en agua es 6,37 g/l a
0C , es decir, en el equilibrio se tiene: }\par\pard\li586\ri0\sl-253\slmu
lt0 \fs20\cf0\f1\charscalex100 {PbCl}\fs14\cf0\f1\charscalex100 {2(s)}\fs20\cf0\
f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 {Pb}{\super \fs14\up4\c
f0\f1\charscalex100 {2+}}\fs14\cf0\f1\charscalex100 {(aq)}\fs20\cf0\f1\charscale
x100 {+2CI}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs14\cf0\f1\charscalex100
{(aq)}\fs18\cf0\f1\charscalex100 { la solucin saturada contiene 6,37/278 (
mol/l) de Pb}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscal
ex100 { y 2x6,37/278 (mol/l) de }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf
0\f1\charscalex100 {CI}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\c
harscalex100 {.}{ }\fs20\cf0\f1\charscalex100 {As resulta que: Kps=[Pb}{\super \f
s14\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 {]x[CI}{\super \fs1
4\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {]}{\super \fs14\up4\c
f0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 { = (6,37/278) x (2x6,37/278)
}{\super \fs14\up4\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 { = 4,8 x
10}\fs14\cf0\f1\charscalex100 {-5 }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf
0\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {Conociendo el Kp
s de una sustancia, se puede determinar su solubilidad.}\par\pard\li586\ri0\sl-2
0 {El producto de solubilidad del Mg(OH)}{\sub \fs14\cf0\f1\charscalex100 {2}}\f
s20\cf0\f1\charscalex100 { est dado por Mg(OH)}{\sub \fs14\cf0\f1\charscalex100 {
2}}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { Mg}{\sup
er \fs14\up3\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 { + 2 OH}{\sup

er \fs14\up3\cf0\f1\charscalex100 {- }}\fs20\cf0\f1\charscalex100 {Kps = 8,9 x 1
0}{\super \fs14\up3\cf0\f1\charscalex100 {-12}}\fs20\cf0\f1\charscalex100 {, y s
u PM }\par\pard\li600\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {= 58,3 lueg
o: }\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Kps = [Mg}{\s
uper \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 {] [OH}{\sup
er \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {]}{\super \fs1
4\up4\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 { = 8,9 x 10}{\super \
fs14\up4\cf0\f1\charscalex100 {-12}}\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0
\f1\charscalex100 {Ya que la solubilidad normalmente se expresa en g/l,
definiremos las concentraciones molares del ion }\par\pard\li586\ri0\sl-24
0\slmult0 \*\tx6866\*\tx7066\fs20\cf0\f1\charscalex100 {[Mg}{\super \fs14\up4\cf
0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 {] y del anin [OH}{\super
\fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {], respectivamen
te como [Mg}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscale
x100 {] = X/PM}\tab \fs20\cf0\f1\charscalex100 {y}\tab \fs20\cf0\f1\charscalex
100 {[OH}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {
]=2X/PM reemplazando en }\par\pard\li1093\ri0\sl-426\slmult0 \fs34\cf0\f2\char
scalex100 {[ ][ ]}{\super \fs16\up5\cf0\f0\charscalex100 {2}}\par\pard\sect\sect
d\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols6\colno1\colw880\c
olsr-0\colno2\colw360\colsr-0\colno3\colw453\colsr-0\colno4\colw373\colsr-0\coln
o5\colw1106\colsr-0\colno6\colw7920\pard\li640\ri0\sl-213\slmult0 \fs24\cf0\f0\c
harscalex100\i {K}\i0 \par\column\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f2\chars
calex100 {=}\par\column\pard\li386\ri0\sl-213\slmult0 \fs24\cf0\f0\charscalex100
\i {X}\i0 \par\pard\li0\ri0\sl-520\slmult0 \fs40\cf0\f2\charscalex100 {[ ]}\par\
column\pard\li0\ri0\sl-173\slmult0 \fs16\cf0\f0\charscalex100 {3}\par\column\par
d\li920\ri0\sl-120\slmult0 \fs16\cf0\f0\charscalex100 {12}\par\pard\li0\ri0\sl-3
06\slmult0 \fs24\cf0\f2\charscalex100 {=}{ }\fs24\cf0\f0\charscalex100 {8}\fs24\
cf0\f0\charscalex100 {.}\fs24\cf0\f0\charscalex100 {9}\fs24\cf0\f0\charscalex100
\i {x}\i0 \fs24\cf0\f0\charscalex100 {10}{ }\fs14\cf0\f2\charscalex100 {\uc1\u87
22X}\par\column\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 { o sea:
4X}{\super \fs14\up4\cf0\f1\charscalex100 {3}}\fs20\cf0\f1\charscalex100 {=8,9x1
0 }{\super \fs14\up4\cf0\f1\charscalex100 {12}}\fs20\cf0\f1\charscalex100 {x(58,
3)}{\super \fs14\up4\cf0\f1\charscalex100 {3}}\fs20\cf0\f1\charscalex100 { despe
jando: X = 1,31 x 10}{\super \fs14\up4\cf0\f1\charscalex100 {-4}}\fs20\cf0\f1\ch
arscalex100 { * 58,3 g/l = 7,61 x }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghs
xn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\chars
calex100 {10}{\super \fs14\up4\cf0\f1\charscalex100 {-3}}\fs20\cf0\f1\charscalex
100 { g/l. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-2
00\slmult0 \fs20\cf0\f0\charscalex100\b {Efecto de iones Compartidos y Formacin d
e Complejos }\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0
\sl-320\slmult0 \fs18\cf0\f1\charscalex100 {La solubilidad cambia con la pr
esencia de otros iones: disminuye como resultado del efecto de iones }
\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {compartidos, y au
menta a causa de la formacin de complejos. }\par\pard\li586\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {La Figura
2 muestra la solubilidad del AgCl al adicionar HCl, se aprecia una disminucin de
la solubilidad }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {a
bajas concentraciones de HCI, debido a la presencia de [Cl}{\super \f
s14\up4\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charscalex100 {] como ion compa
rtido entre HCI y AgCl, }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn1684
0\marglsxn666\margrsxn133\cols2\colno1\colw9893\colsr-0\colno2\colw1200\pard\li5
pard\li586\ri0\sl-333\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\
column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs
18\cf0\par\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {15 }\par\pard
\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\sect\se
ctd\sbkpage

7;32768}}
{\*\shpinst
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0600C0A3AF7A318EF400668CD1B7DE971EF40094B4514005145140051451400514514000A28A2801
077FAD2D145001DE8A28A003F8A8ED4514001ED41E94514005145140076A28A2800A28A280034514
5002514514001A4A28A006E7934EED451400B4D63C8A28A0051F7851DE8A28017B5068A28010D145
1400BDE8F5A28A0041D29C68A28013BD1451401FFFD9}
}}}}

7;32768}}

\fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {cuando e
l [Cl}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {] a
umenta, la concentracin del ion [Ag}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\f
s20\cf0\f1\charscalex100 {] debe disminuir para mantener el valor del Kps. El }\
par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {aumento de la s
olubilidad a altas concentraciones de HCI se debe a la formacin de un
ion complejo, }\par\pard\li600\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100
{[AgCl}{\sub \fs12\cf0\f1\charscalex100 {4}}\fs18\cf0\f1\charscalex100 {]}{\supe
r \fs12\up4\cf0\f1\charscalex100 {3-}}\fs18\cf0\f1\charscalex100 {, la concentra
cin del ion plata no-acomplejado, [Ag}{\super \fs12\up4\cf0\f1\charscalex100 {+}}
\fs18\cf0\f1\charscalex100 {], disminuye.}{ }\fs18\cf0\f1\charscalex100 {Para ma
ntener el valor de Kps }\par\pard\li600\ri0\sl-213\slmult0 \fs20\cf0\f1\charscal
ex100 {constante, el equilibrio de desplaza favoreciendo la disolucin del AgCl. }
\par\pard\li3533\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3533\ri0\sl-213\slmult0
13\slmult0 \fs18\cf0\par\pard\li3533\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li353
pard\li3533\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3533\ri0\sl-213\slmult0 \fs1
8\cf0\par\pard\li3533\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3533\ri0\sl-213\sl
mult0 \fs18\cf0\par\pard\li3533\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3533\ri0
\sl-213\slmult0 \fs18\cf0\par\pard\li3533\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li3533\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3533\ri0\sl-213\slmult0 \fs18\cf0
\fs20\cf0\f0\charscalex100\b { Figura 2 Solubilidad del AgCl en HCl }\b0 \par\p
f0\f1\charscalex100 {Cmo se calcular la solubilidad o Kps, si hay ms de una sal
que aporta iones? Por ejemplo, si en una }\par\pard\li586\ri0\sl-253\slmult
0 \fs20\cf0\f1\charscalex100 {solucin saturada de cloruro de plata (1L), s
e agrega 1.0x10}{\super \fs14\up4\cf0\f1\charscalex100 {-2}}\fs20\cf0\f1\chars
calex100 { M de AgNO}\fs14\cf0\f1\charscalex100 {3(s)}\fs20\cf0\f1\charscalex
100 { (altamente soluble). La }\par\pard\li586\ri0\sl-253\slmult0 \fs18\cf0\f
1\charscalex100 {presencia del Ag}{\super \fs12\up4\cf0\f1\charscalex100 {+}}\fs
18\cf0\f1\charscalex100 { proveniente del AgNO}{\sub \fs12\cf0\f1\charscalex100
{3}}\fs18\cf0\f1\charscalex100 { es un "esfuerzo" aplicado al equilibrio de la s
olubilidad del cloruro }\par\pard\li586\ri0\sl-186\slmult0 \fs20\cf0\f1\charscal
ex100 {de plata, la posicin del equilibrio debe desplazarse de manera de suavizar
el esfuerzo, a medida que se }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\c
harscalex100 {agrega AgNO}{\sub \fs12\cf0\f1\charscalex100 {3}}\fs18\cf0\f1\cha
rscalex100 { precipita algo de AgCl, por lo que se puede concluir que
la solubilidad del AgCl (con }\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0
\f1\charscalex100 {respecto a [Cl}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs
20\cf0\f1\charscalex100 {] en una solucin de [Ag}{\super \fs14\up4\cf0\f1\charsca
lex100 {+}}\fs20\cf0\f1\charscalex100 {] = 1,0 X 10}{\super \fs14\up4\cf0\f1\cha
rscalex100 {-2}}\fs20\cf0\f1\charscalex100 { M es menor que en agua pura. }\par\
pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Se calcula [CI-] en
la solucin, basado en el producto de solubilidad, Kps= 1.8x10}{\super
\fs12\up4\cf0\f1\charscalex100 {-10}}\fs18\cf0\f1\charscalex100 {, tenemos que
}\par\pard\li1506\ri0\sl-253\slmult0 \fs26\cf0\f0\charscalex100\i {K}\i0 \par\p
ard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols3\col
no1\colw946\colsr-0\colno2\colw746\colsr-0\colno3\colw9400\pard\li693\ri0\sl-213
\slmult0 \fs26\cf0\f0\charscalex100\i {Cl}\i0 \par\column\pard\li0\ri0\sl-320\sl
mult0 \fs16\cf0\f2\charscalex100 {\uc1\u8722X}{\sub \fs26\cf0\f2\charscalex100 {
=}}\par\column\pard\li0\ri0\sl-120\slmult0 \fs16\cf0\f0\charscalex100\i {ps}\i0
\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\col
s2\colno1\colw1373\colsr-0\colno2\colw9720\pard\li613\ri0\sl-213\slmult0 \*\tx10
53\fs26\cf0\f0\charscalex100 {[}\tab \fs26\cf0\f0\charscalex100 {]}\par\column\p
ard\li400\ri0\sl-186\slmult0 \fs16\cf0\f2\charscalex100 {+}\par\pard\li0\ri0\sl213\slmult0 \*\tx506\fs26\cf0\f0\charscalex100 {[}{ }\fs26\cf0\f0\charscalex100\

i {Ag}\i0 \tab \fs26\cf0\f0\charscalex100 {]}\par\pard\sect\sectd\sbknone\pgwsxn
0\f1\charscalex100 {Ahora, [Ag}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\
cf0\f1\charscalex100 {] proviene de 2 sales, [Ag}{\super \fs14\up4\cf0\f1\charsc
alex100 {+}}\fs20\cf0\f1\charscalex100 {] = [Ag}{\super \fs14\up4\cf0\f1\charsca
lex100 {+}}\fs20\cf0\f1\charscalex100 {]}\fs14\cf0\f1\charscalex100 {AgNO3}\fs20
\cf0\f1\charscalex100 { + [Ag}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\c
f0\f1\charscalex100 {]}\fs14\cf0\f1\charscalex100 {AgCl}\fs20\cf0\f1\charscalex1
00 {, [Ag}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100
{]}\fs14\cf0\f1\charscalex100 {AgNO3}\fs20\cf0\f1\charscalex100 { es 1.0x 10}{\s
uper \fs14\up4\cf0\f1\charscalex100 {-2}}\fs20\cf0\f1\charscalex100 { M cantidad
agregada }\par\pard\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {en el
experimento y el [Ag}{\super \fs12\up4\cf0\f1\charscalex100 {+}}\fs18\cf0\f
1\charscalex100 {]}\fs12\cf0\f1\charscalex100 {AgCl}\fs16\cf0\f1\charscalex100 {
debe ser menor que 1,34x10}{\super \fs12\up4\cf0\f1\charscalex100 {-5}}\fs
16\cf0\f1\charscalex100 { M, lo cual es la concentracin de Ag}{\super \fs
12\up4\cf0\f1\charscalex100 {+}}\fs18\cf0\f1\charscalex100 { en }\par\pard\li58
6\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {agua pura. Entonces, podemos
aproximar relativamente bien que [Ag}{\super \fs12\up3\cf0\f1\charscalex10
0 {+}}\fs18\cf0\f1\charscalex100 {]= 1.0x10}{\super \fs12\up3\cf0\f1\charscalex
100 {-2}}\fs18\cf0\f1\charscalex100 { M, pues }\par\pard\li586\ri0\sl-253\slmu
lt0 \fs20\cf0\f1\charscalex100 {[Ag}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\
fs20\cf0\f1\charscalex100 {]}\fs14\cf0\f1\charscalex100 {AgCl}\fs20\cf0\f1\chars
calex100 {<<<[Ag}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charsca
lex100 {]}\fs14\cf0\f1\charscalex100 {AgNO3}\fs20\cf0\f1\charscalex100 {, entonc
es, [Cl-] = 1.8 x 10}{\super \fs14\up4\cf0\f1\charscalex100 {-8}}\fs20\cf0\f1\ch
arscalex100 { M }\par\pard\li586\ri0\sl-400\slmult0 \fs18\cf0\f1\charscalex100
{Hay 1.8 x10}{\super \fs12\up4\cf0\f1\charscalex100 {-8}}\fs18\cf0\f1\charscal
ex100 { moles de CI}{\super \fs12\up4\cf0\f1\charscalex100 {-}}\fs16\cf0\f1\c
harscalex100 { disuelto en 1 L proveniente del AgCl, lo cual implica
una disminucin de la }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscal
ex100 {solubilidad del AgCl en una solucin de AgNO}{\sub \fs14\cf0\f1\charscalex1
00 {3}}\fs20\cf0\f1\charscalex100 { con una concentracin de 1.0x10}{\super \fs14\
up3\cf0\f1\charscalex100 {-2}}\fs20\cf0\f1\charscalex100 { M. }\par\pard\li586\r
i0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\chars
calex100\ul {PRECIPITACIN SELECTIVA}\ul0 \fs20\cf0\f1\charscalex100\ul { }\ul0 \p
20\cf0\f1\charscalex100 {Si a una solucin con 0,10 M de NaCI y 0,010 M de Na}{\su
b \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {CrO}{\sub \fs14\cf0
\f1\charscalex100 {4 }}\fs20\cf0\f1\charscalex100 {se agrega AgNO}{\sub \fs14\cf
0\f1\charscalex100 {3.}}\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscal
ex100 {Sabiendo que las sales AgCI}{\sub \fs12\cf0\f1\charscalex100 {(s)}}\fs18\
cf0\f1\charscalex100 { y Ag}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\ch
arscalex100 {CrO}\fs12\cf0\f1\charscalex100 {4(s)}\fs18\cf0\f1\charscalex100 {,
son relativamente insolubles, una o ambas podran precipitar, }\par\pard\li600\ri0
\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {los Kps de las sales de plata son: }
\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Kps AgCl = [Ag}{\
super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 {][Cl}{\supe
r \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {]= 1,8x 10-}{\s
uper \fs14\up4\cf0\f1\charscalex100 {10}}\par\pard\li600\ri0\sl-240\slmult0 \fs2
0\cf0\f1\charscalex100 {Kps Ag}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1
\charscalex100 {CrO}{\sub \fs14\cf0\f1\charscalex100 {4 =}}\fs20\cf0\f1\charscal
ex100 {[Ag}{\super \fs14\up3\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100
{]}{\super \fs14\up3\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {[CrO}
{\sub \fs14\cf0\f1\charscalex100 {4}}\fs14\cf0\f1\charscalex100 {-2}\fs20\cf0\f1
\charscalex100 {] =1,2 X 10}{\super \fs14\up3\cf0\f1\charscalex100 {-12}}\par\pa
rd\li586\ri0\sl-453\slmult0 \fs18\cf0\f1\charscalex100 {Las altas concentracione
s de Ag}{\super \fs12\up4\cf0\f1\charscalex100 {+}}\fs18\cf0\f1\charscalex100 {
harn que los productos de reaccin de AgCI}{\sub \fs12\cf0\f1\charscalex100 {(s)}}\

fs18\cf0\f1\charscalex100 { y Ag}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\cf0\
f1\charscalex100 {CrO}\fs12\cf0\f1\charscalex100 {4(s)}\fs18\cf0\f1\charscalex10
0 { excedan sus }\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {
Kps, y como formarn ambos precipitados. }\par\pard\li586\ri0\sl-213\slmult0 \fs18
\cf0\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Estos precipi
tados continuarn creciendo hasta que cada producto de reaccin sea igual o menor qu
e su }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Kps. Si se
ha aadido un exceso de Ag}{\super \fs12\up4\cf0\f1\charscalex100 {+}}\fs18\cf0\f1
\charscalex100 {, slo permanecer un precipitado. En este caso, para decidir cul }\p
ar\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {de los dos permanec
er, se puede calcular la concentracin de Ag}{\super \fs12\up4\cf0\f1\charscalex100
{+}}\fs18\cf0\f1\charscalex100 { requerida para formar cada precipitado }\par\p
ard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {en condiciones de equil
ibrio, para la solucin inicial, [Cl}{\super \fs14\up3\cf0\f1\charscalex100 {-}}\f
s20\cf0\f1\charscalex100 {] = 0,10 M y [CrO}{\sub \fs14\cf0\f1\charscalex100 {4}
}\fs14\cf0\f1\charscalex100 {-2}\fs20\cf0\f1\charscalex100 {] = 0.010 M }\par\pa
rd\li2386\ri0\sl-293\slmult0 \fs24\cf0\f0\charscalex100 {1}\fs24\cf0\f0\charscal
ex100 {.}\fs24\cf0\f0\charscalex100 {8}\fs24\cf0\f0\charscalex100\i {x}\i0 \fs24
\cf0\f0\charscalex100 {10}\fs16\cf0\f2\charscalex100 {\uc1\u8722X}\fs16\cf0\f0\c
harscalex100 {10}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn66
6\margrsxn133\cols4\colno1\colw2706\colsr-0\colno2\colw520\colsr-0\colno3\colw66
66\colsr-0\colno4\colw1200\pard\li1306\ri0\sl-253\slmult0 \fs20\cf0\f1\charscale
x100 {[Ag}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100
{]}\fs14\cf0\f1\charscalex100 {AgCl}{\super \fs20\cf0\f1\charscalex100 { = }}\pa
lt0 \fs18\cf0\par\pard\li586\ri0\sl-413\slmult0 \fs24\cf0\f0\charscalex100 {Osca
r Benavente }\par\column\pard\li0\ri0\sl-333\slmult0 \fs24\cf0\f0\charscalex100
{0}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\charscalex100 {1}\par\column\pard\
li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 { = 1,8 x 10}{\super \fs14\up
4\cf0\f1\charscalex100 {-9}}\fs20\cf0\f1\charscalex100 { M, }\par\column\pard\li
\par\pard\li0\ri0\sl-213\slmult0 \fs24\cf0\f0\charscalex100 {16 }\par\pard\sect\
sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sb
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3\margtsxn666\margbsxn173\cols5\colno1\colw2920\colsr-0\colno2\colw426\colsr-0\c
olno3\colw346\colsr-0\colno4\colw2413\colsr-0\colno5\colw4986\pard\li586\ri0\sl306\slmult0 \fs24\cf0\f0\charscalex100 {Hidrometalurgia I }\par\column\pard\li0\
ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\p
ard\li0\ri0\sl-266\slmult0 \fs24\cf0\f2\charscalex100 {\uc1\u63723X}\par\column\
cf0\par\pard\li0\ri0\sl-320\slmult0 \fs24\cf0\f0\charscalex100\i {x}\i0 \par\col
umn\pard\li413\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li413\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li413\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li413\ri0\sl-280\sl
mult0 \fs16\cf0\f0\charscalex100 {1}\par\pard\li0\ri0\sl-253\slmult0 \*\tx280\fs
16\cf0\f2\charscalex100 {\uc1\u8722X}\fs16\cf0\f0\charscalex100 {12}\tab \fs24\c
f0\f2\charscalex100 {\uc1\u63734X}{\super \fs16\up2\cf0\f0\charscalex100 {2}}\pa
r\column\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {Universidad Cat
olica del Norte }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn66
\fs20\cf0\f1\charscalex100 {[Ag}{\super \fs14\up3\cf0\f1\charscalex100 {+}}\fs20
\cf0\f1\charscalex100 {]}\fs14\cf0\f1\charscalex100 {Ag2CrO4}\par\column\pard\li
0\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {= }{ }\fs12\cf0\f2\charscalex10

0 {\uc1\u63724X\uc1\u63724X}\par\pard\li200\ri0\sl-240\slmult0 \fs22\cf0\f2\char
scalex100 {\uc1\u63725X}\par\column\pard\li0\ri0\sl-213\slmult0 \*\tx293\fs24\cf
0\f0\charscalex100 {1}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\charscalex100 {
2}\tab \fs24\cf0\f0\charscalex100 {10}\par\pard\li200\ri0\sl-213\slmult0 \fs24\c
f0\f0\charscalex100 {0}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\charscalex100
{010}\par\column\pard\li0\ri0\sl-240\slmult0 \fs12\cf0\f2\charscalex100 {\uc1\u6
3735X\uc1\u63735X}\par\pard\li0\ri0\sl-240\slmult0 \fs24\cf0\f2\charscalex100 {\
uc1\u63736X}\par\column\pard\li0\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {
=1.1x10}{\super \fs14\up3\cf0\f1\charscalex100 {-5}}\fs20\cf0\f1\charscalex100
{M }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133
\cf0\f1\charscalex100 {El Ag}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\c
harscalex100 {CrO}\fs14\cf0\f1\charscalex100 {4(S)}\fs20\cf0\f1\charscalex100 {
no puede permanecer en equilibrio con la solucin hasta que la concentracin de Ag}{
\super \fs14\up3\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { alcance }
\par\pard\li600\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {1.1X10}{\super \f
s12\up4\cf0\f1\charscalex100 {-5}}\fs18\cf0\f1\charscalex100 { M, pero el AgCI}{
\sub \fs12\cf0\f1\charscalex100 {(s)}}\fs18\cf0\f1\charscalex100 { precipitar cua
ndo la concentracin de Ag}{\super \fs12\up4\cf0\f1\charscalex100 {+}}\fs18\cf0\f1
\charscalex100 { alcance 1,8x10}{\super \fs12\up4\cf0\f1\charscalex100 {-9}}\fs1
8\cf0\f1\charscalex100 { M. Evidentemente, }\par\pard\li586\ri0\sl-200\slmult0 \
fs18\cf0\f1\charscalex100 {el AgCl precipitar primero, mientras que el Ag}
{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\charscalex100 {CrO}{\sub \fs12
\cf0\f1\charscalex100 {4}}\fs18\cf0\f1\charscalex100 { no formar un precipita
do hasta que se haya }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charsc
alex100 {eliminado de la solucin suficiente CI}{\super \fs12\up3\cf0\f1\charscale
x100 {-}}\fs18\cf0\f1\charscalex100 { como para permitir que la concentracin de A
g}{\super \fs12\up3\cf0\f1\charscalex100 {+}}\fs18\cf0\f1\charscalex100 { llegue
a 1.1x10}{\super \fs12\up3\cf0\f1\charscalex100 {-5}}\fs18\cf0\f1\charscalex100
{ M. }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Suponiendo
que el volumen de la solucin no cambia despus de aadir AgNO}{\sub \fs1
2\cf0\f1\charscalex100 {3}}\fs18\cf0\f1\charscalex100 {, entonces la }\par\par
d\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {concentracin de Cl}{\super
\fs12\up4\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charscalex100 { en solucin que
se requiere para que el Ag}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\
charscalex100 {CrO}{\sub \fs12\cf0\f1\charscalex100 {4}}\fs18\cf0\f1\charscalex1
00 { precipite (usando la concentracin }\par\pard\li586\ri0\sl-240\slmult0 \fs20
\cf0\f1\charscalex100 {de Ag}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf
0\f1\charscalex100 { determinada antes) es 1.64x10}{\super \fs14\up4\cf0\f1\char
scalex100 {-5}}\fs20\cf0\f1\charscalex100 { M }\par\pard\li773\ri0\sl-213\slmult
3\slmult0 \fs20\cf0\f0\charscalex100\b {Hidratacin e Hidrlisis }\b0 \par\pard\li60
0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-306\slmult0 \fs20\cf0\f1\ch
arscalex100 {Los iones en solucin se encuentran rodeados de molculas de agua. Los
cationes estn ms hidratados }\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\chars
calex100 {que los aniones debido a su menor tamao presentan una carga
ms concentrada, atrayendo mayor }\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\
f1\charscalex100 {nmero de molculas de H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs2
0\cf0\f1\charscalex100 {O, como se aprecia en la Tabla IV. }\par\pard\li3280\ri0
\sl-213\slmult0 \fs18\cf0\par\pard\li3280\ri0\sl-346\slmult0 \fs20\cf0\f0\charsc
alex100\b {Tabla IV Moleculas de agua de hidratacion }\b0 \par\pard\sect\sectd\
lsr-0\colno2\colw1546\colsr-0\colno3\colw1120\colsr-0\colno4\colw4760\pard\li260
0\ri0\sl-373\slmult0 \fs20\cf0\f1\charscalex100 {Catin }\par\pard\li2733\ri0\sl-2
3\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {Rb}{\super \fs14\up4\cf0\f1\cha
rscalex100 {+}}\par\pard\li2786\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {K
}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\par\pard\li2733\ri0\sl-240\slmult0
\fs20\cf0\f1\charscalex100 {Ag}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\par\p
ard\li2786\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {H}{\super \fs14\up4\cf

0\f1\charscalex100 {+}}\par\pard\li2733\ri0\sl-240\slmult0 \fs20\cf0\f1\charscal
ex100 {Na}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\par\pard\li2693\ri0\sl-240
\slmult0 \fs20\cf0\f1\charscalex100 {Pb}{\super \fs14\up4\cf0\f1\charscalex100 {
2+}}\par\pard\li2773\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Li}{\super \
fs14\up4\cf0\f1\charscalex100 {+}}\par\pard\li2693\ri0\sl-240\slmult0 \fs20\cf0\
f1\charscalex100 {Ba}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\par\pard\li269
3\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Ca}{\super \fs14\up4\cf0\f1\cha
rscalex100 {2+}}\par\pard\li2680\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {
Mg}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\par\pard\li2693\ri0\sl-240\slmul
t0 \fs20\cf0\f1\charscalex100 {Cd}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\p
ar\pard\li2706\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Zn}{\super \fs14\u
p4\cf0\f1\charscalex100 {2+}}\par\pard\li2706\ri0\sl-240\slmult0 \fs20\cf0\f1\ch
arscalex100 {Fe}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\par\pard\li2693\ri0
\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Cu}{\super \fs14\up4\cf0\f1\charscal
ex100 {2+}}\par\pard\li2733\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Al}{\
super \fs14\up4\cf0\f1\charscalex100 {3+}}\par\column\pard\li40\ri0\sl-373\slmul
t0 \fs20\cf0\f1\charscalex100 {Molculas }\par\pard\li373\ri0\sl-226\slmult0 \fs20
\cf0\f1\charscalex100 {en }\par\pard\li0\ri0\sl-226\slmult0 \fs20\cf0\f1\charsca
lex100 {hidratacin }\par\pard\li426\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100
{2 }\par\pard\li346\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {2-3 }\par\pa
rd\li346\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {3-4 }\par\pard\li426\ri0
\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {4 }\par\pard\li426\ri0\sl-240\slmult
0 \fs20\cf0\f1\charscalex100 {4 }\par\pard\li346\ri0\sl-240\slmult0 \fs20\cf0\f1
\charscalex100 {5-7 }\par\pard\li426\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex1
00 {6 }\par\pard\li346\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {6-8 }\par\
pard\li280\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {8-10 }\par\pard\li280\
ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {9-13 }\par\pard\li226\ri0\sl-240\
slmult0 \fs20\cf0\f1\charscalex100 {10-12 }\par\pard\li226\ri0\sl-240\slmult0 \f
s20\cf0\f1\charscalex100 {11-13 }\par\pard\li226\ri0\sl-240\slmult0 \fs20\cf0\f1
\charscalex100 {11-13 }\par\pard\li226\ri0\sl-240\slmult0 \fs20\cf0\f1\charscale
x100 {11-13 }\par\pard\li373\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {20 }
\par\column\pard\li0\ri0\sl-373\slmult0 \fs20\cf0\f1\charscalex100 {Anin }\par\pa
0\par\pard\li440\ri0\sl-146\slmult0 \fs14\cf0\f1\charscalex100 {-}\par\pard\li26
\ri0\sl-200\slmult0 \fs20\cf0\f1\charscalex100 {ClO}{\sub \fs14\cf0\f1\charscale
x100 {4}}\par\pard\li213\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {I}{\supe
r \fs14\up4\cf0\f1\charscalex100 {-}}\par\pard\li133\ri0\sl-240\slmult0 \fs20\cf
0\f1\charscalex100 {Br}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\par\pard\li42
6\ri0\sl-120\slmult0 \fs14\cf0\f1\charscalex100 {-}\par\pard\li53\ri0\sl-200\slm
ult0 \fs20\cf0\f1\charscalex100 {NO}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\pa
rd\li146\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Cl}{\super \fs14\up4\cf0
\f1\charscalex100 {-}}\par\pard\li173\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex
100 {F}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\par\column\pard\li40\ri0\sl-3
73\slmult0 \fs20\cf0\f1\charscalex100 {Molculas }\par\pard\li373\ri0\sl-226\slmul
t0 \fs20\cf0\f1\charscalex100 {en }\par\pard\li0\ri0\sl-226\slmult0 \fs20\cf0\f1
\charscalex100 {hidratacin }\par\pard\li426\ri0\sl-240\slmult0 \fs20\cf0\f1\chars
calex100 {0 }\par\pard\li346\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {0-1
}\par\pard\li426\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {2 }\par\pard\li4
26\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {2 }\par\pard\li426\ri0\sl-240\
slmult0 \fs20\cf0\f1\charscalex100 {3 }\par\pard\li426\ri0\sl-240\slmult0 \fs20\
cf0\f1\charscalex100 {5 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\ma
rglsxn666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0
lex100 {Los iones hidratados presentan la tendencia de perder iones OH}{\super \
fs14\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 { o H}{\super \fs14
\up3\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 {, proceso conocido com
o hidrlisis, }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {el c
ual puede ser representado con la ecuacin general: }\par\pard\li586\ri0\sl-213\sl
mult0 \fs18\cf0\par\pard\li586\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {[M
(H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O)}{\sub \f

s14\cf0\f1\charscalex100 {n}}\fs14\cf0\f1\charscalex100 {a+ }\fs20\cf0\f2\charsc
alex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { [M(H}{\sub \fs14\cf0\f1\charsc
alex100 {2}}\fs20\cf0\f1\charscalex100 {O)}{\sub \fs14\cf0\f1\charscalex100 {n-1
}}\fs20\cf0\f1\charscalex100 { OH]}\fs14\cf0\f1\charscalex100 {(a-1)+}\fs20\cf0\
f1\charscalex100 { + H}{\super \fs14\up3\cf0\f1\charscalex100 {+ }}\fs20\cf0\f1\
charscalex100 {o M}{\super \fs14\up3\cf0\f1\charscalex100 {a+}}\fs20\cf0\f1\char
scalex100 { + H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100
{O }\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { M(OH)}\
fs14\cf0\f1\charscalex100 {(a-1)+}\fs20\cf0\f1\charscalex100 { + H}{\super \fs14
\up3\cf0\f1\charscalex100 {+}}\par\pard\li586\ri0\sl-466\slmult0 \fs20\cf0\f1\ch
arscalex100 {El on frrico se hidroliza de esta forma: Fe}{\super \fs14\up4\cf0\f1\
charscalex100 {3+}}\fs20\cf0\f1\charscalex100 { + H}{\sub \fs14\cf0\f1\charscale
x100 {2}}\fs20\cf0\f1\charscalex100 {O }\fs20\cf0\f2\charscalex100 {\uc1\u8660X}
\fs20\cf0\f1\charscalex100 { Fe(OH)}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}
\fs20\cf0\f1\charscalex100 { + H}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\par
\cf0\f1\charscalex100 {Los aniones tambin se hidrolizan en forma anloga: }\par\par
\f1\charscalex100 {[X (H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\chars
calex100 {O)}{\sub \fs14\cf0\f1\charscalex100 {m}}\fs20\cf0\f1\charscalex100 {]}
{\super \fs14\up4\cf0\f1\charscalex100 {b- }}\fs20\cf0\f2\charscalex100 {\uc1\u8
660X}\fs20\cf0\f1\charscalex100 { [X(H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs
20\cf0\f1\charscalex100 {O)}{\sub \fs14\cf0\f1\charscalex100 {m-1}}\fs20\cf0\f1\
charscalex100 { (H)]}\fs14\cf0\f1\charscalex100 {(b-I)-}\fs20\cf0\f1\charscalex1
00 { + OH}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100
{ o X}{\super \fs14\up4\cf0\f1\charscalex100 {b-}}\fs20\cf0\f1\charscalex100 {+
H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O }\fs20\cf0\
f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { XH}\fs14\cf0\f1\chars
calex100 {(b-l)-}\fs20\cf0\f1\charscalex100 { + OH}{\super \fs14\up4\cf0\f1\char
scalex100 {-}}\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl
-266\slmult0 \fs20\cf0\f1\charscalex100 {El ion cianuro se hidroliza as: CN}{\sup
er \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 { + H}{\sub \fs
14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O }\fs20\cf0\f2\charscal
ex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { HCN + OH}{\super \fs14\up4\cf0\f
1\charscalex100 {-}}\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\
ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {La tendencia de un ion a hidroliz
arse depender de: }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn6
66\margrsxn133\cols2\colno1\colw9893\colsr-0\colno2\colw1200\pard\li586\ri0\sl-2
\par\pard\li586\ri0\sl-320\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benavente }
\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult
3\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-293\slmult0 \fs24\cf0\f0\charscalex100 {
17 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133
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xn133\cols2\colno1\colw1306\colsr-0\colno2\colw9786\pard\li586\ri0\sl-213\slmult
0\slmult0 \fs20\cf0\f1\charscalex100 {a) }\par\column\pard\li0\ri0\sl-213\slmult
mult0 \fs20\cf0\f1\charscalex100 {La razn entre la carga inica y el radio de la mo
lcula ionizada, es decir, la densidad de carga.}\par\pard\sect\sectd\sbknone\pgws
xn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-226\slmult0 \fs20\
cf0\f1\charscalex100 {Cuanto ms densa sea la carga mayor ser la hidrlisis y vicever
sa. As, mientras la hidrlisis de un ion }\par\pard\li586\ri0\sl-240\slmult0 \fs20\
cf0\f1\charscalex100 {alcalino o alcalino-trreo es indetectable, la del Ti}{\supe
r \fs14\up4\cf0\f1\charscalex100 {4+}}\fs20\cf0\f1\charscalex100 { y el V}{\supe
r \fs14\up4\cf0\f1\charscalex100 {5+}}\fs20\cf0\f1\charscalex100 { es muy import
ante. }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn
\fs20\cf0\f1\charscalex100 {b) }\par\column\pard\li0\ri0\sl-226\slmult0 \fs20\cf
0\f1\charscalex100 {La estructura electrnica.}{ }\fs20\cf0\f1\charscalex100 {Los
iones con una estructura de gas inerte tienen una tendencia mnima }\par\pard\sect
\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl
-226\slmult0 \fs20\cf0\f1\charscalex100 {a hidrolizarse.}{ }\fs20\cf0\f1\charsca
lex100 {As, el Ag}{\super \fs14\up3\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charsca
lex100 { y el Pb}{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charsc
alex100 { se hidrolizan ms fcilmente que el Ba}{\super \fs14\up3\cf0\f1\charscalex
100 {2+}}\fs20\cf0\f1\charscalex100 { y el Sr}{\super \fs14\up3\cf0\f1\charscale
x100 {2+}}\fs20\cf0\f1\charscalex100 {.}{ }\fs20\cf0\f1\charscalex100 {El Fe}{\s
uper \fs14\up3\cf0\f1\charscalex100 {3+}}\fs20\cf0\f1\charscalex100 {, el Co}{\s
uper \fs14\up3\cf0\f1\charscalex100 {3+}}\fs20\cf0\f1\charscalex100 { y el }\par
\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Cr}{\super \fs14\up4\
cf0\f1\charscalex100 {3+}}\fs20\cf0\f1\charscalex100 { lo hacen mucho ms fcilmente

que el Al}{\super \fs14\up4\cf0\f1\charscalex100 {3+}}\fs20\cf0\f1\charscalex10
0 {. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-213\slm
-280\slmult0 \fs20\cf0\f0\charscalex100\b {Complejos }\b0 \par\pard\li600\ri0\sl
100 {Los complejos son compuestos solubles en agua. Cuando se agrega amonaco a un
a solucin de sulfato }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex1
00 {de cobre, que es de color azul plido, se vuelve de color azul oscuro debido a
la formacin del complejo }\par\pard\li600\ri0\sl-266\slmult0 \fs20\cf0\f1\charsc
alex100 {amina de cobre : Cu}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\c
f0\f1\charscalex100 { + nNH}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs20\cf0\f2\ch
arscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { [Cu (NH}{\sub \fs14\cf0\f1
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0 {n}}\fs20\cf0\f1\charscalex100 { ]}{\super \fs14\up4\cf0\f1\charscalex100 {2+}
}\fs20\cf0\f1\charscalex100 {. As, el ion cobre comparte el par de electrones del
tomo }\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {de nitrgeno
del amonaco. }\par\pard\li2293\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2293\ri0\s
l-360\slmult0 \fs20\cf0\f0\charscalex100\b {Tabla V Complejos solubles de import
ancia en hidrometalurgia }\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn168
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0\f0\charscalex100\b {Ag}\b0 {\super \fs12\up2\cf0\f0\charscalex100\b {+ }\b0 }\
par\column\pard\li0\ri0\sl-320\slmult0 \fs18\cf0\f1\charscalex100 {NH3 }\par\col
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93\slmult0 \fs18\cf0\f0\charscalex100\b {As}\b0 {\super \fs12\up3\cf0\f0\charsca
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\b {As}\b0 {\super \fs10\up2\cf0\f0\charscalex100\b {5+}\b0 }\par\pard\li1520\ri
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20\ri0\sl-280\slmult0 \fs16\cf0\f0\charscalex100\b {Be}\b0 {\super \fs10\up3\cf0
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1\charscalex100 {Ag(NH}\fs12\cf0\f1\charscalex100 {3}\fs18\cf0\f1\charscalex100
{)}\fs12\cf0\f1\charscalex100 {2}\par\pard\li640\ri0\sl-213\slmult0 \fs18\cf0\pa
8\cf0\par\pard\li640\ri0\sl-360\slmult0 \*\tx1013\fs12\cf0\f1\charscalex100 {+}\
tab \fs18\cf0\f1\charscalex100 {Au(CN)}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs1
2\cf0\f1\charscalex100 {-}\par\pard\li0\ri0\sl-160\slmult0 \fs18\cf0\f1\charscal
ex100 {Au(NH}{\sub \fs12\cf0\f1\charscalex100 {3}}\fs18\cf0\f1\charscalex100 {)}
{\sub \fs12\cf0\f1\charscalex100 {2}}\par\column\pard\li0\ri0\sl-146\slmult0 \fs
18\cf0\f1\charscalex100 {AgCl}\fs12\cf0\f1\charscalex100 {2}\par\pard\li413\ri0\

\cf0\f1\charscalex100 {-}\par\pard\li0\ri0\sl-160\slmult0 \fs18\cf0\f1\charscale
x100 {AuCl}{\sub \fs12\cf0\f1\charscalex100 {4}}\par\column\pard\li293\ri0\sl-20
0\slmult0 \fs12\cf0\f1\charscalex100 {3-}\par\pard\li0\ri0\sl-160\slmult0 \fs18\
cf0\f1\charscalex100 {AlF}{\sub \fs12\cf0\f1\charscalex100 {6}}\par\pard\li346\r
i0\sl-213\slmult0 \fs18\cf0\par\pard\li346\ri0\sl-213\slmult0 \fs18\cf0\par\pard
\li346\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li346\ri0\sl-213\slmult0 \fs18\cf0\
s10\cf0\f1\charscalex100 {-}\par\column\pard\li0\ri0\sl-306\slmult0 \fs18\cf0\f1
\charscalex100 {Al(OH)}{\sub \fs12\cf0\f1\charscalex100 {4}}\par\column\pard\li0
\ri0\sl-200\slmult0 \fs12\cf0\f1\charscalex100 {-}\par\pard\li26\ri0\sl-213\slmu
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26\ri0\sl-106\slmult0 \fs12\cf0\f1\charscalex100 {-}\par\column\pard\li0\ri0\sl213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0
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scalex100 {Co(NH}\fs12\cf0\f1\charscalex100 {3}\fs18\cf0\f1\charscalex100 {)}\fs
12\cf0\f1\charscalex100 {6}\fs12\cf0\f1\charscalex100\ul {2+}\ul0 \fs18\cf0\f1\c
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}\fs12\cf0\f1\charscalex100 {-}\cell\row}\pard\li1520\ri0\sl-266\slmult0 \*\tx32
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\ul {3+}\b0 \ul0 }\fs18\cf0\f1\charscalex100 {Co(NH}{\sub \fs12\cf0\f1\charscale
x100 {3}}\fs18\cf0\f1\charscalex100 {)}{\sub \fs12\cf0\f1\charscalex100 {6}}\fs1
2\cf0\f1\charscalex100 {3+}\tab \fs18\cf0\f1\charscalex100 {Co(CN)}{\sub \fs12\c
f0\f1\charscalex100 {6}}\fs12\cf0\f1\charscalex100 {3-}\par{\trowd\trleft1520\tr
keep\trftsWidth1\trpaddl0\trpaddr0\trpaddfl3\trpaddfr3 \clvertalt\clbrdrt\brdrno
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drnone\clbrdrl\brdrnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb\clNoWrap\clft
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3\widctlpar\intbl \fs18\cf0\f1\charscalex100 {Cu(NH}\fs12\cf0\f1\charscalex100 {
3}\fs18\cf0\f1\charscalex100 {)}\fs12\cf0\f1\charscalex100 {2+}\fs18\cf0\f1\char
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ell\row}{\trowd\trleft1520\trkeep\trftsWidth1\trpaddl0\trpaddr0\trpaddfl3\trpadd
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ellx2413 \pard\li0\ri0\sl-266\widctlpar\intbl \fs18\cf0\f0\charscalex100\b {Cu}\
b0 \cell\clvertalt\clbrdrt\brdrnone\clbrdrl\brdrnone\clbrdrb\brdrnone\clbrdrr\br
drnone\cltxlrtb\clNoWrap\clftsWidth3\clwWidth1426\clpadt0\clpadr0\clpadft3\clpad
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\ul {2+}\b0 \ul0 \par\pard\li0\ri0\sl-106\widctlpar\intbl \fs18\cf0\f1\charscale

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rscalex100\b \ul {2+}\b0 \ul0 }\fs18\cf0\f1\charscalex100 {Fe(CN)}{\sub \fs12\cf
0\f1\charscalex100 {6}}\fs18\cf0\f1\charscalex100 {4}{\super \fs12\up2\cf0\f1\ch
arscalex100 {-}}\par\pard\li1520\ri0\sl-266\slmult0 \fs18\cf0\f0\charscalex100\b
{Fe}\b0 {\super \fs12\up2\cf0\f0\charscalex100\b {3+}\b0 }\fs18\cf0\f1\charscal
ex100 {Fe(CN)}\fs12\cf0\f1\charscalex100 {6}{\super \fs12\up3\cf0\f1\charscalex1
00 {3-}}\par\column\pard\li413\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li413\ri0\s
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0\f1\charscalex100 {BeF}\fs12\cf0\f1\charscalex100 {3}\par\column\pard\li0\ri0\s
l-146\slmult0 \fs18\cf0\f1\charscalex100 {Be(OH)}\fs12\cf0\f1\charscalex100 {3}\
par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0
\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-346\slmult0 \fs18\cf0\f1\charscalex100 {F
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arscalex100 {2}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri
d\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-253\slmult0 \fs12\cf0\f1\
charscalex100 {-}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn66
80\slmult0 \*\tx3266\*\tx4333\fs18\cf0\f0\charscalex100\b {Hg}\b0 {\super \fs12\
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0\f1\charscalex100 {2}}\fs12\cf0\f1\charscalex100\ul {2+}\ul0 \tab \fs18\cf0\f1\
charscalex100 {Hg(CN)}{\sub \fs12\cf0\f1\charscalex100 {4}}\fs12\cf0\f1\charscal
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\fs18\cf0\f0\charscalex100\b {Mn}\b0 {\super \fs12\up3\cf0\f0\charscalex100\b \u
l {2+}\b0 \ul0 }\fs18\cf0\f1\charscalex100 {Mn(CN)}{\sub \fs12\cf0\f1\charscalex
100 {6}}\fs18\cf0\f1\charscalex100 {4}{\super \fs12\up2\cf0\f1\charscalex100 {-}
}\par\column\pard\li360\ri0\sl-173\slmult0 \fs12\cf0\f1\charscalex100 {2-}\par\p
ard\li0\ri0\sl-160\slmult0 \fs18\cf0\f1\charscalex100 {HgS}{\sub \fs12\cf0\f1\ch
arscalex100 {2}}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666
\margrsxn133\cols5\colno1\colw2280\colsr-0\colno2\colw1986\colsr-0\colno3\colw19
\fs18\cf0\f0\charscalex100\b {Ni}\b0 {\super \fs12\up2\cf0\f0\charscalex100\b {
2+}\b0 }\par\pard\li1520\ri0\sl-280\slmult0 \fs18\cf0\f0\charscalex100\b {Pb}\b0
{\super \fs12\up3\cf0\f0\charscalex100\b {2+}\b0 }\par\pard\li1520\ri0\sl-266\s
lmult0 \fs18\cf0\f0\charscalex100\b {Pt}\b0 {\super \fs12\up3\cf0\f0\charscalex1
00\b {4+}\b0 }\par\column\pard\li586\ri0\sl-173\slmult0 \fs12\cf0\f1\charscalex1
00 {2+}\par\pard\li0\ri0\sl-146\slmult0 \fs18\cf0\f1\charscalex100 {Ni(NH}\fs12\
cf0\f1\charscalex100 {3}\fs18\cf0\f1\charscalex100 {)}\fs12\cf0\f1\charscalex100
{6}\par\column\pard\li546\ri0\sl-173\slmult0 \fs12\cf0\f1\charscalex100 {2-}\pa
r\pard\li0\ri0\sl-146\slmult0 \fs18\cf0\f1\charscalex100 {Ni(CN)}\fs12\cf0\f1\ch
arscalex100 {4}\par\pard\li480\ri0\sl-120\slmult0 \fs12\cf0\f1\charscalex100 {2}\par\pard\li66\ri0\sl-160\slmult0 \fs18\cf0\f1\charscalex100 {PbCI}{\sub \fs12\
cf0\f1\charscalex100 {4}}\par\pard\li453\ri0\sl-120\slmult0 \fs12\cf0\f1\charsca
lex100 {2-}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl
-333\slmult0 \fs18\cf0\f1\charscalex100 {Pb(OH)}{\sub \fs12\cf0\f1\charscalex100
{3}}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-226\s
lmult0 \fs12\cf0\f1\charscalex100 {-}\par\pard\sect\sectd\sbknone\pgwsxn11893\pg
colsr-0\colno3\colw4866\pard\li1520\ri0\sl-280\slmult0 \fs18\cf0\f0\charscalex10
0\b {Zn}\b0 {\super \fs12\up2\cf0\f0\charscalex100\b {2+}\b0 }\fs18\cf0\f1\chars
calex100 {Zn(NH}\fs12\cf0\f1\charscalex100 {3}\fs18\cf0\f1\charscalex100 {)}\fs1
2\cf0\f1\charscalex100 {4}{\super \fs12\up3\cf0\f1\charscalex100 {2+}}\fs18\cf0\
f1\charscalex100 {Zn(CN)}\fs12\cf0\f1\charscalex100 {4}{\super \fs12\up3\cf0\f1\
charscalex100 {2-}}\par\column\pard\li0\ri0\sl-160\slmult0 \fs18\cf0\f1\charscal
ex100 {PtCl}{\sub \fs12\cf0\f1\charscalex100 {6}}\par\column\pard\li586\ri0\sl-1
86\slmult0 \fs12\cf0\f1\charscalex100 {-}\par\pard\li0\ri0\sl-146\slmult0 \fs18\
cf0\f1\charscalex100 {Zn(OH)}\fs12\cf0\f1\charscalex100 {3}\par\pard\sect\sectd\
sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-213\sl
mult0 \fs18\cf0\par\pard\li586\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {So
n comunes las especies donantes que llevan cargas negativas, (aniones) como el:
CN}{\super \fs14\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {, F}{\
super \fs14\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {, Cl}{\supe
r \fs14\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {, SO}{\sub \fs1
4\cf0\f1\charscalex100 {4}}\fs14\cf0\f1\charscalex100 {2-}{\sub \fs20\cf0\f1\cha
rscalex100 {, }}\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {N
O}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs14\cf0\f1\charscalex100 {-}\fs20\cf0\f
1\charscalex100 {, CO}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs14\cf0\f1\charscal
ex100 {2-}\fs20\cf0\f1\charscalex100 {, OH}{\super \fs14\up4\cf0\f1\charscalex10
0 {-}}\fs20\cf0\f1\charscalex100 {, PO}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs
14\cf0\f1\charscalex100 {3-}\fs18\cf0\f1\charscalex100 { y S}{\super \fs14\up4
\cf0\f1\charscalex100 {2-}}\fs20\cf0\f1\charscalex100 {, como se aprecia en la
Tabla V. Los iones complejos pueden identificarse }\par\pard\li586\ri0\sl-186\
slmult0 \fs20\cf0\f1\charscalex100 {por mtodos fsicos y fsico-qumicos, como so
n: cambios de coloracin, mediciones infrarrojas y }\par\pard\li586\ri0\sl-2
26\slmult0 \fs20\cf0\f1\charscalex100 {ultravioletas, conductividad, intercambio
inico, extraccin por solventes. }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\
charscalex100 {Un ion acomplejado se comporta de modo diferente de otro
no-acomplejado. Por ejemplo, el AgCl }\par\pard\li586\ri0\sl-253\slmult0 \
fs20\cf0\f1\charscalex100 {precipita cuando se agrega iones CI}{\super \fs14\up4
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b \fs14\cf0\f1\charscalex100 {3}}\fs20\cf0\f1\charscalex100 {, pero no lo hace d
esde una solucin que }\par\pard\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex1
00 {contiene [Ag(CN)}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\charscale
x100 {]}{\super \fs12\up4\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charscalex100 {
ya que la plata est acomplejada como para reaccionar con el CI}{\super \fs12\up4\
cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charscalex100 {. Del mismo modo, }\par\par
d\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {el AgCl precipita cuando
se agregan Ag}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex
100 { a una solucin de NaCI, pero no desde una solucin de [PtCI}{\sub \fs14\cf0\f1
\charscalex100 {6}}\fs20\cf0\f1\charscalex100 {]}{\super \fs14\up4\cf0\f1\charsc
alex100 {2-}}\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {ya q
ue, en este caso, el cloro est acomplejado y no est libre para reaccionar con el i
on Ag}{\super \fs14\up3\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 {. }
fs18\cf0\par\pard\li586\ri0\sl-200\slmult0 \fs20\cf0\f0\charscalex100\b {Precipi
tacin }\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-306
\slmult0 \fs20\cf0\f1\charscalex100 {La precipitacin es un proceso importante en
los procesos Hidrometalurgicos. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\p
ar\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {El anlisis cualitati
vo diseado por Carl Remigius Fresenius, en 1841, (Tabla VI) est basado en datos de
}\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {solubilidad de
cloruros, sulfuros, hidrxidos y carbonatos, y hace uso de ciertas dif
erencias en la }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn6
ri0\sl-386\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\column\pard
pard\li0\ri0\sl-360\slmult0 \fs24\cf0\f0\charscalex100 {18 }\par\pard\sect\sectd
\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sbkpage
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\fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {solubili
dad que se observan cuando se agrega cido clorhdrico (HCI) diluido, seg
uido de cido }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {su
lfhdrico (H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {S).
Luego, despus de eliminar el exceso de H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs
20\cf0\f1\charscalex100 {S por ebullicin, en una secuencia posterior }\par\pard\l
i586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {se agrega exceso de hidrxido
de amonio (NH}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs20\cf0\f1\charscalex100 {O
H). }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-226\slmu
lt0 \fs18\cf0\f1\charscalex100 {El Grupo 1 incluye los cloruros metlicos i
nsolubles en HCI diluido. El Grupo 2 comprende los sulfuros }\par\pard\
li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {metlicos insolubles en HC
I y est caracterizado por una variedad de colores. Despus de separar l
os }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {sulfuros del
Grupo 2 y al neutralizar el filtrado con NH}{\sub \fs12\cf0\f1\charsca
lex100 {4}}\fs18\cf0\f1\charscalex100 {OH, slo unos pocos hidrxidos metlicos }
\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {precipitan, forma
ndo el Grupo 3. La razn de esto es que los hidrxidos de cobalto, nquel y manganeso
}\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {son solubles e
n amonaco y, adems, una gran parte de los iones metlicos que forman hi
drxidos }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {insoluble
s ya han precipitado en los grupos anteriores. }\par\pard\li586\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {Despus
de filtrar los hidrxidos, se agrega de nuevo H}{\sub \fs12\cf0\f1\chars
calex100 {2}}\fs18\cf0\f1\charscalex100 {S al filtrado con el objeto de p
recipitar los }\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {s
ulfuros metlicos del Grupo 4. Estos ltimos se distinguen de los sulfuros del Grupo
2 por el hecho que }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex1
00 {son solubles en HCI diluido. Cuando estos sulfuros han sido filtra
dos y retirados, la solucin se hace }\par\pard\li586\ri0\sl-253\slmult0 \fs
18\cf0\f1\charscalex100 {hervir para expeler el exceso de H}{\sub \fs12\cf0\f1\c
harscalex100 {2}}\fs18\cf0\f1\charscalex100 {S, se enfra y se satura con carbonat
o de amonio (NH4)}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\charscalex10
0 {CO}{\sub \fs12\cf0\f1\charscalex100 {3}}\fs18\cf0\f1\charscalex100 {, as los }
\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {carbonatos precip

itados pasan a constituir el Grupo 5. Lo que permanece an en solucin son los iones
}\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {de metales alca
linos. }\par\pard\li2746\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2746\ri0\sl-360
\slmult0 \fs20\cf0\f0\charscalex100\b {Tabla VI Precipitacion de iones metalicos
en solucion }\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn6
66\margrsxn133\cols2\colno1\colw3333\colsr-0\colno2\colw7760\pard\li2186\ri0\sl373\slmult0 \fs20\cf0\f0\charscalex100\b {Grupo }\b0 \par\column\pard\li0\ri0\sl
-373\slmult0 \*\tx4373\fs20\cf0\f0\charscalex100\b {Ion metlico precipitado como
Reactivo }\b0 \tab \fs20\cf0\f0\charscalex100\b {precipitado }\b0 \par\pard\sec
w6440\colsr-0\colno2\colw1066\colsr-0\colno3\colw3586\pard\li2186\ri0\sl-266\slm
ult0 \*\tx3320\fs20\cf0\f0\charscalex100\b {Grupo 1 }\b0 \tab \fs20\cf0\f1\chars
calex100 {Cloruros }\par\pard\li2186\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li218
6\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2186\ri0\sl-386\slmult0 \*\tx3320\fs20
\cf0\f0\charscalex100\b {Grupo 2 }\b0 \tab \fs20\cf0\f1\charscalex100 {Sulfuros
}\par\pard\li3320\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {(a) incluye los
slfuros }\par\pard\li3320\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {soluble
s en (NH}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs20\cf0\f1\charscalex100 {)}{\su
b \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {S amoniacal. }\par\
alex100 {(b) incluye los slfuros }\par\pard\li3320\ri0\sl-280\slmult0 \fs20\cf0\f
1\charscalex100 {insolubles en (NH}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs20\cf
0\f1\charscalex100 {) }{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charsca
lex100 {S }\par\pard\li3320\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {amoni
acal }\par\pard\li2186\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2186\ri0\sl-213\s
lmult0 \fs18\cf0\par\pard\li2186\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2186\ri
0\sl-213\slmult0 \fs18\cf0\par\pard\li2186\ri0\sl-213\slmult0 \fs18\cf0\par\pard
\li2186\ri0\sl-253\slmult0 \*\tx3320\fs20\cf0\f0\charscalex100\b {Grupo 3 }\b0 \
tab \fs20\cf0\f1\charscalex100 {Hidrxidos }\par\pard\li2186\ri0\sl-213\slmult0 \
lt0 \fs18\cf0\par\pard\li2186\ri0\sl-240\slmult0 \*\tx3320\fs20\cf0\f0\charscale
x100\b {Grupo 4 }\b0 \tab \fs20\cf0\f1\charscalex100 {Slfuros }\par\column\pard\l
i0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {HCl }\par\pard\li0\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl413\slmult0 \fs20\cf0\f1\charscalex100 {H}{\sub \fs14\cf0\f1\charscalex100 {2}}\
fs20\cf0\f1\charscalex100 {S (a) }\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par
\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18
\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \
t0 \fs18\cf0\par\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {H}{\sub
\fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {S (b) }\par\pard\li0
cf0\f1\charscalex100 {NH}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs20\cf0\f1\chars
calex100 {OH + }\par\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {NH}
{\sub \fs14\cf0\f1\charscalex100 {4}}\fs20\cf0\f1\charscalex100 {Cl }\par\pard\l

\fs20\cf0\f1\charscalex100 {H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\
charscalex100 {S }\par\column\pard\li200\ri0\sl-266\slmult0 \fs20\cf0\f1\charsca
lex100 {AgCl }\par\pard\li0\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 { PbC
l}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf
0\f1\charscalex100 { Hg}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\chars
calex100 {Cl}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\li200\ri0\sl-280\slm
ult0 \fs20\cf0\f1\charscalex100 {As}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\c
f0\f1\charscalex100 {S}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\pard\li0\ri0\sl
-266\slmult0 \fs20\cf0\f1\charscalex100 { Sb}{\sub \fs14\cf0\f1\charscalex100 {
2}}\fs20\cf0\f1\charscalex100 {S}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\pard\
li0\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 { SnS }\par\pard\li0\ri0\sl-2
93\slmult0 \fs20\cf0\f1\charscalex100 { SnS}{\sub \fs14\cf0\f1\charscalex100 {2
}}\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 { Bi}{\sub \fs14\
cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {S}{\sub \fs14\cf0\f1\charsc
alex100 {3}}\par\pard\li0\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 { HgS }
\par\pard\li0\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 { MoS}{\sub \fs14\c
f0\f1\charscalex100 {3}}\par\pard\li0\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex
100 { GeS}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\li200\ri0\sl-253\slmul
t0 \fs20\cf0\f1\charscalex100 {CdS }\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f
1\charscalex100 { PbS }\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\
ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 { CuS }\par\pard\li0\ri0\sl-280\s
lmult0 \fs20\cf0\f1\charscalex100 { Re}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs
20\cf0\f1\charscalex100 {S7 }\par\pard\li0\ri0\sl-280\slmult0 \fs20\cf0\f1\chars
calex100 { PtS}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\li0\ri0\sl-266\sl
mult0 \fs20\cf0\f1\charscalex100 { WS}{\sub \fs14\cf0\f1\charscalex100 {3}}\par
\pard\li200\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {Al(OH)}{\sub \fs14\cf
0\f1\charscalex100 {3}}\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\r
i0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 { Fe(OH)}{\sub \fs14\cf0\f1\charsc
alex100 {2}}\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 { Fe(OH
)}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\pard\li0\ri0\sl-280\slmult0 \fs20\cf
0\f1\charscalex100 { Cr(OH)}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\pard\li0\
ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 { Be(OH)}{\sub \fs14\cf0\f1\chars
calex100 {2}}\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 { UO}{
\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {(OH)}{\sub \fs14
\cf0\f1\charscalex100 {2}}\par\pard\li0\ri0\sl-280\slmult0 \fs20\cf0\f1\charscal
ex100 { Th(OH)}{\sub \fs14\cf0\f1\charscalex100 {4}}\par\pard\li0\ri0\sl-266\sl
mult0 \fs20\cf0\f1\charscalex100 { Ln(OH)}{\sub \fs14\cf0\f1\charscalex100 {3}}
\par\pard\li200\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {NiS }\par\pard\li
0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 { CoS }\par\pard\li0\ri0\sl-280
\slmult0 \fs20\cf0\f1\charscalex100 { MnS }\par\pard\li0\ri0\sl-266\slmult0 \fs
20\cf0\f1\charscalex100 { ZnS }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn1
-0\colno3\colw1200\pard\li2186\ri0\sl-266\slmult0 \*\tx3320\fs20\cf0\f0\charscal
ex100\b {Grupo 5 }\b0 \tab \fs20\cf0\f1\charscalex100 {Carbonatos }\par\pard\li5
0 \fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-293\s
lmult0 \fs20\cf0\f1\charscalex100 {(NH}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs2
0\cf0\f1\charscalex100 {)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\char
scalex100 {CO}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs20\cf0\f1\charscalex100 {M
gCO}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\pard\li1066\ri0\sl-266\slmult0 \fs
20\cf0\f1\charscalex100 { CaCO}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\pard\l
i1066\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 { SrCO}{\sub \fs14\cf0\f1\c
harscalex100 {3}}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\
ard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-280\slmult0 \fs24\cf0\f
0\charscalex100 {19 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\margls

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l Norte }\par\pard\li1400\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1400\ri0\sl-21
0 { BaCO}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\pard\sect\sectd\sbknone\pgws
xn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\
cf0\par\pard\li586\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {El esquema de
anlisis cualitativo comprende tambin la separacin de los metales individuales, dent
ro }\par\pard\li586\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {de cada gru
po, para fines de identificacin. Por ejemplo, los sulfuros de arsnico,
antimonio, estao y }\par\pard\li586\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex1
00 {mercurio pueden ser separados de los dems sulfuros del Grupo 2 med
iante ebullicin con sulfuro de }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\
f1\charscalex100 {amonio, particularidad que ha sido usada algunas veces en Hidr
ometalurgia. Estos sulfuros son solubles }\par\pard\li586\ri0\sl-226\slmult0 \fs
18\cf0\f1\charscalex100 {debido a la formacin de tiosales, mientras que los dems s
ulfuros no. Para mayores detalles respecto a }\par\pard\li586\ri0\sl-226\slmult0
\fs18\cf0\f1\charscalex100 {estas separaciones conviene referirse a algn t
exto dedicado de Anlisis Qumico Cualitativo, como }\par\pard\li586\ri0\sl-22
6\slmult0 \fs20\cf0\f1\charscalex100 {pueden ser, por ejemplo, los libros de Vog
el, de Reedy, o de Curtman. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pa
rd\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {Es significativo observa
r que los metales de los Grupos 2 y 4, que se precipitan en forma de sulfuros en
}\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {Tabla VI, ocu
rren normalmente en la naturaleza tambin como slfuros, excepto el mangan
eso cuya }\par\pard\li586\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {ocurre
ncia natural es como MnO2. Los metales del Grupo 3, que aqu se preci
pitan como hidrxidos, }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscal
ex100 {tambin en la naturaleza ocurren como xidos e hidrxidos, mientras q
ue los del Grupo 5, que s }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1
\charscalex100 {precipitan como carbonatos, igualmente ocurren e forma natural,
de preferencia como carbonatos. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\pa
r\pard\li586\ri0\sl-280\slmult0 \fs24\cf0\f0\charscalex100 {Oxidacin y Reduccin }\
s18\cf0\f1\charscalex100 {La adicin de oxgeno a un tomo, un ion o una molcula se den
omina como una reaccin de oxidacin. }\par\pard\li586\ri0\sl-240\slmult0 \fs16\cf0\
f1\charscalex100 {Por oposicin, la reduccin se asocia a la reaccin opuesta
, es decir, a la reaccin de remocin de }\par\pard\li586\ri0\sl-226\slmult0
\fs20\cf0\f1\charscalex100 {oxgeno desde un sistema.}\par\pard\li586\ri0\sl-226\
slmult0 \fs16\cf0\f1\charscalex100 {Al calentar un metal al aire este se
oxida y cuando el oxido formado es calentado con carbn, este se }\par
\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {reduce, ya que el oxge
no se asocia con el carbn. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard
\li586\ri0\sl-253\slmult0 \fs16\cf0\f1\charscalex100 {La oxidacin es la remoc
in de electrones desde un tomo o grupo de tomos, y la reduccin es la }
\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {adicin de electron
es a un tomo o grupo de tomos. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\p
ard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Algunas reacciones de o
xidacin y reduccin tpicas en sistemas acuosos, son: }\par\pard\sect\sectd\sbknone\p
no2\colw8226\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-280\s
lmult0 \fs20\cf0\f1\charscalex100 {S}{\super \fs14\up4\cf0\f1\charscalex100 {2-}
}\fs20\cf0\f1\charscalex100 {+ 2O}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0
\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { SO}{\sub \fs14\cf0\f
1\charscalex100 {2}}\fs14\cf0\f1\charscalex100 {2- }\par\pard\li586\ri0\sl-253\s
lmult0 \fs20\cf0\f1\charscalex100 {Fe}{\super \fs14\up3\cf0\f1\charscalex100 {0}
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1\charscalex100 {3+}}\fs20\cf0\f1\charscalex100 { + e}{\super \fs14\up4\cf0\f1\c
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calex100 {+}}\fs20\cf0\f1\charscalex100 { + 2e}{\super \fs14\up4\cf0\f1\charscal
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}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\li0\ri0\sl-253\slmult0 \fs20\cf0
\f1\charscalex100 {Cu}{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\c
harscalex100 { + 2e}{\super \fs14\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f2\char
scalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { Cu}{\super \fs14\up3\cf0\f1\
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\slmult0 \fs18\cf0\f1\charscalex100 {Las reacciones de oxidacin y reduccin s
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, el fierro es oxidado y los iones hidrgeno son al mismo tiempo reducidos, con lo
que se neutralizan }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex1
00 {las cargas de electrones, por un lado generados y, por el otro, consumidos:
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ls2\colno1\colw2013\colsr-0\colno2\colw9080\pard\li586\ri0\sl-253\slmult0 \fs20\
cf0\f1\charscalex100 {Fe}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\par\column\
pard\li0\ri0\sl-266\slmult0 \*\tx1613\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs
20\cf0\f1\charscalex100 { Fe}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\c
f0\f1\charscalex100 { + 2e- }\tab \fs20\cf0\f1\charscalex100 {Oxidacin }\par\par
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+}}\fs20\cf0\f1\charscalex100 { + 2e}{\super \fs14\up3\cf0\f1\charscalex100 {- }
}\par\pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Fe}{\super \fs14
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charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { H}{\sub \fs14\cf0\f1\cha
rscalex100 {2}}\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f2\charscalex100 {\uc1
\u8660X}{ }\fs20\cf0\f1\charscalex100 {Fe}{\super \fs14\up3\cf0\f1\charscalex100
{2+}}\fs20\cf0\f1\charscalex100 { + H}{\sub \fs14\cf0\f1\charscalex100 {2}}\par
\column\pard\li0\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {Reduccin }\par\pa
rd\li0\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Reaccin Global }\par\pard\s
ect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0
i586\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex100\b {Potencial de Electrodo }\b
0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-306\slmult0
\fs20\cf0\f1\charscalex100 {Las interfases slido/lquido generan un campo elc
trico caracterstico de la composicin de ambas }\par\pard\li586\ri0\sl-240\sl
mult0 \fs18\cf0\f1\charscalex100 {fases. Este campo elctrico surge como consecuen
cia de la discontinuidad o desequilibrio de cargas que }\par\pard\li586\ri0\sl-2
26\slmult0 \fs18\cf0\f1\charscalex100 {se produce en la superficie del slido que
se compensa por un reordenamiento de iones en el lquido. La }\par\pard\li586\ri0\
sl-226\slmult0 \fs16\cf0\f1\charscalex100 {fuerza de este campo elctrico es
la que promueve los fenmenos de transferencia de carga en las }\par\pa
rd\li586\ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {interfases slido lquido
los cuales, se traducen en equilibrios que involucran tanto a especie
s atmicas }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {del sli
do como a los iones de la solucin. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\
par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Cuando una lmina de
cobre es sumergida en una solucin cida, algunos tomos pasarn a la solucin, }\par\par
d\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {a la forma de Cu}{\super
\fs12\up3\cf0\f1\charscalex100 {2+}}\fs18\cf0\f1\charscalex100 {, dejando los el
ectrones y generando un exceso de carga negativa en la superficie del }\par\pard

\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {metal. Este proceso se
detiene cuando una cantidad de iones Cu}{\super \fs14\up4\cf0\f1\charscal
ex100 {2+}}\fs20\cf0\f1\charscalex100 {, de este sistema denominado }\par\pa
rd\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {electrodo metal-ion es c
apaz de compensar desde la solucin el exceso de carga negativa en el metal. }\par
\cf0\f1\charscalex100 {En el equilibrio, esta situacin queda caracterizada
por una diferencia de potencial entre el metal y la }\par\pard\li600\r
i0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {solucin, denominado potencial de el
ectrodo. }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margr
sxn133\cols2\colno1\colw9893\colsr-0\colno2\colw1200\pard\li586\ri0\sl-213\slmul
ri0\sl-413\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\column\pard
par\pard\li0\ri0\sl-386\slmult0 \fs24\cf0\f0\charscalex100 {20 }\par\pard\sect\s
ectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sbk
page
7;32768}}
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7;32768}}
\fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {La neces
idad del electrodo de referencia, surge a que debemos conectar elctricamente, a t
ravs de un }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {mili-v
oltmetro, la interfase de inters o electrodo de trabajo, cuya diferencia de potenc
ial se desea medir, }\par\pard\li586\ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex1
00 {con otra interfase similar, sumergida en la misma solucin para cerr
ar el circuito. Ntese que en este }\par\pard\li586\ri0\sl-226\slmult0 \fs18
\cf0\f1\charscalex100 {circuito no circula corriente. Es ms, el instrumento de me
dicin, est provisto de una alta impedancia de }\par\pard\li586\ri0\sl-226\slmult0
\fs20\cf0\f1\charscalex100 {entrada que le impide actuar como conductor. }\par\p
f0\f1\charscalex100 {La tendencia de una sustancia para ser oxidada o reducida,
es decir, para perder o ganar electrones, se }\par\pard\li600\ri0\sl-226\slmult0
\fs20\cf0\f1\charscalex100 {mide en volts y es conocida como su potencial. Cuan
do una lmina de zinc es sumergida en una solucin }\par\pard\li600\ri0\sl-240\slmul
t0 \fs20\cf0\f1\charscalex100 {de 1 M ZnSO}{\sub \fs14\cf0\f1\charscalex100 {4}}

\fs20\cf0\f1\charscalex100 { y una lmina de cobre en una solucin de 1 M CuSO}{\sub
\fs14\cf0\f1\charscalex100 {4}}\fs20\cf0\f1\charscalex100 {, las dos lminas se c
onectan con un }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {c
able y las dos soluciones con un puente salino para evitar que se m
ezclen, se puede observar que el }\par\pard\li586\ri0\sl-226\slmult0 \fs20\
cf0\f1\charscalex100 {voltmetro indicar 0,78 volts. El zinc se disolver en el compa
rtimiento del sulfato de zinc y el cobre se }\par\pard\li586\ri0\sl-226\slmult0
\fs20\cf0\f1\charscalex100 {depositar en el compartimiento del sulfato de cobre.
Los electrones liberados por el zinc al disolverse se }\par\pard\li586\ri0\sl-22
6\slmult0 \fs20\cf0\f1\charscalex100 {transfieren, a travs del cable, hacia el el
ectrodo de cobre y los iones sulfato difunden lentamente desde }\par\pard\li586\
ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {la solucin de CuSO}{\sub \fs14\cf0
\f1\charscalex100 {4}}\fs20\cf0\f1\charscalex100 { hacia la de ZnSO}{\sub \fs14\
cf0\f1\charscalex100 {4}}\fs20\cf0\f1\charscalex100 { a travs del puente salino,
para completar el circuito elctrico. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf
0\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {Por convencin,
se define como electrodo de referencia a una placa de platino sumergi
da en una }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {solu
cin 1 normal de HCl, con burbujeo de H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20
\cf0\f1\charscalex100 {, a presin atmosfrica y a 25C. Este electrodo se conoce }\pa
r\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {como el electrodo no
rmal de hidrgeno y en l ocurre el siguiente equilibrio: }\par\pard\sect\sectd\sbkn
one\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw2746\colsr0\colno2\colw8346\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl306\slmult0 \fs20\cf0\f1\charscalex100 {H}{\sub \fs14\cf0\f1\charscalex100 {2}}\
fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { 2H}{\super \
fs14\up3\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { + 2e}\fs14\cf0\f1
\charscalex100 {- }\par\column\pard\li0\ri0\sl-520\slmult0 \*\tx786\fs24\cf0\f
2\charscalex100 {\uc1\u8710X}\fs24\cf0\f0\charscalex100\i {E}\i0 { }\fs24\cf0\f2
\charscalex100 {=}{ }\fs24\cf0\f0\charscalex100 {0}\tab \fs24\cf0\f0\charscalex1
00\i {volt}\i0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\
margrsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-240\sl
mult0 \fs18\cf0\f1\charscalex100 {De esta manera, se pueden medir las dif
erencias de potencial, tambin bajo condiciones estndar, de }\par\pard\li586
\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {otras interfases con respecto al
electrodo normal de hidrgeno. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\
pard\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {Un electrodo de refere
ncia se trata de interfases donde se produce una reaccin en equilibrio estab
le y }\par\pard\li586\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {caracteriz
ado por una diferencia de potencial reproducible. El ms conocido es el
electrodo de calomel }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charsc
alex100 {saturado consiste en una fase metlica, de mercurio, en contacto con una
solucin saturada de cloruro de }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\c
harscalex100 {potasio, KCI. En este sistema, descrito esquemticamente en
la Figura 3 algunos tomos de mercurio }\par\pard\li600\ri0\sl-240\slmult0 \
fs18\cf0\f1\charscalex100 {pasan a la solucin como Hg}{\super \fs12\up4\cf0\f1\ch
arscalex100 {+}}\fs18\cf0\f1\charscalex100 { y dejando tras de s los electrones s
obre la cara del mercurio en contacto }\par\pard\li586\ri0\sl-213\slmult0 \fs20\
cf0\f1\charscalex100 {con la solucin. }\par\pard\li2786\ri0\sl-213\slmult0 \fs18\
lt0 \fs18\cf0\par\pard\li2786\ri0\sl-280\slmult0 \fs20\cf0\f0\charscalex100\b {F

igura 3 Esquema del electrodo de calomel saturado }\b0 \par\pard\li600\ri0\sl-21
{Los iones Hg}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscale
x100 { reaccionan con el Cl}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0
\f1\charscalex100 { precipitando Hg}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\c
f0\f1\charscalex100 {Cl}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charsc
alex100 { sobre la superficie del mercurio. De este modo, }\par\pard\li600\ri0\s
l-240\slmult0 \fs18\cf0\f1\charscalex100 {los iones K}{\super \fs12\up4\cf0\f1
\charscalex100 {+}}\fs18\cf0\f1\charscalex100 { libres en la solucin compens
an la carga negativa del mercurio y generan una interfase }\par\pard\li
600\ri0\sl-213\slmult0 \fs18\cf0\f1\charscalex100 {electrificada estable, debido
al recubrimiento de Hg}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\charsc
alex100 {Cl}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\charscalex100 { so
bre la superficie del mercurio cuya diferencia de }\par\pard\li586\ri0\sl-360\sl
mult0 \*\tx7373\fs20\cf0\f1\charscalex100 {potencial, medida respecto del el
ectrodo normal de hidrgeno, es de }\tab \fs24\cf0\f2\charscalex100 {\uc1\u87
10X}\fs24\cf0\f0\charscalex100\i {E}\i0 {\sub \fs16\cf0\f0\charscalex100\i {Hg}\
i0 }\fs10\cf0\f0\charscalex100 {2}{\super \fs16\up0\cf0\f0\charscalex100\i {Cl}\
i0 }\fs10\cf0\f0\charscalex100 {2}{\super \fs14\up0\cf0\f0\charscalex100 {/}}\fs
16\cf0\f0\charscalex100\i {Hg}\i0 {\super \fs24\up0\cf0\f2\charscalex100 {=}}\fs
22\cf0\f0\charscalex100 {0}\fs22\cf0\f0\charscalex100 {.}\fs22\cf0\f0\charscalex
100 {24}{ }\fs22\cf0\f0\charscalex100\i {volt}\i0 { }\fs18\cf0\f1\charscalex100
{ Las }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {reaccione
s en la interfase Hg}\fs14\cf0\f1\charscalex100 {(lquido)}\fs20\cf0\f1\charscalex
100 {/KCI}\fs12\cf0\f1\charscalex100 {(saturado)}\fs20\cf0\f1\charscalex100 {, m
ercurio versus cloruro de potasio saturado, son: }\par\pard\li586\ri0\sl-213\slm
ult0 \fs18\cf0\par\pard\li586\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {2Hg
}\fs14\cf0\f1\charscalex100 {(Iquid.)}\fs20\cf0\f1\charscalex100 { + 2CI}{\super
\fs14\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {+ 2K}{\super \fs
14\up3\cf0\f1\charscalex100 {+ }}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\c
f0\f1\charscalex100 { Hg}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\chars
calex100 {Cl}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 { +
2K}{\super \fs14\up3\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { + 2e
}{\super \fs14\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f2\charscalex100 {\uc1\u87
10X}\fs20\cf0\f1\charscalex100 {G}{\sub \fs14\cf0\f1\charscalex100 {273}}\fs20\cf
0\f1\charscalex100 {=11319 cal/mol }\par\pard\sect\sectd\sbknone\pgwsxn11893\pgh
sxn16840\marglsxn666\margrsxn133\cols2\colno1\colw9893\colsr-0\colno2\colw1200\p
\fs18\cf0\par\pard\li586\ri0\sl-413\slmult0 \fs24\cf0\f0\charscalex100 {Oscar B
enavente }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0
\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-386\slmult0 \fs24\cf0\f0\charscale
x100 {21 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margr
sxn133\pard\sect\sectd\sbkpage
7;32768}}

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A35E73F1B278A1F853AB472CA8AD3C904712B1C176F351B0BFDE3B558FFC04D00773757F6763E48B
ABB82DCCF2AC1179B205F31DBEEA2E7AB7B55DAF1BF88B7F7D71AEF86AF92D2EAE74B5D6EC0E9EF6
F3C2D0DCE559D997E71F3B6E555DEBB5562C871BCD7B250014514500145145001451450014514500
14514500145145001451450014514500145145001451450014514500145145001451450014514500
14514500145145001451450014514500145145001451450014514500145145001451450014514500
14514500145145001451450014514500145145001451450014514500145145001451450014514500
14514500145145001451450014514500145145001451450014514500145145001451450014514500
14514500145145001451450014514500145145001451450014514500145145001451450014514500
14514500145145001451450014514500145145001451450014514500145145001451450014514500
14514500145145001451450014514500145145001451450014514500145145001451450014514500
145145001451450015E71E2BF8912F8435EB9B19F464B8B4B5B38AFDE74BCC49E534CB0361366378
66FBBBB040FBCBD2BD1EB95D5FC09A36BBE214D6B538E7B9716AB6DF656976C0E165F3577A8FBFF3
7F0B657FD9A00F3DD5F51D46DBC47F132081F5E9E2B4B3864B778351658EC19A132B3E1A553B77A8
6F915BE5565C6D3B5BD1FC12F2BF813419659E79A59EC209A496794CAEEEE8ACC4B139FBCD513F81
7409AE3569E4B6BA693565F2EF88BEB81E7AF5C1F9FA638F97B657EE922B674DD2AD346D3A1D3AC5
1E3B68136C51B48EE547A6E624E2803468A28A0028A28A0028A28A0028A28A0028A28A0028A28A00
28A28A0028A28A0028A28A0028A28A0028A28A0028A28A0028A28A0028A28A0028A28A00FFD9}
sl-240\slmult0 \fs20\cf0\f1\charscalex100 {La caracterizacin de las interfases sli
do lquido, a travs de la medicin de las diferencias de potencial }\par\pard\li586\r
i0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {que reflejan los diversos esta
dos de equilibrio, es de gran inters para comprender los mecanismos e
}\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {intervenir en la
s reacciones de los procesos hidrometalrgicos. }\par\pard\li586\ri0\sl-213\slmult
0 \fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100\b {Efec
to de la Concentracin}\b0 \fs20\cf0\f1\charscalex100 {. El potencial de electrodo
vara con las concentraciones. El estado estndar }\par\pard\li586\ri0\sl-240\slmul
t0 \fs20\cf0\f1\charscalex100 {se toma con soluciones uno-molar, y el pot
encial medido se conoce como el potencial de electrodo }\par\pard\li586\
ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {estndar y se denota como E}{\super
\fs14\up4\cf0\f1\charscalex100 {0}}\fs20\cf0\f1\charscalex100 {. El potencial,
Eh, medido a cualquier otra concentracin, se relaciona con }\par\pard\li586\ri0\s
l-213\slmult0 \fs20\cf0\f1\charscalex100 {el potencial estndar mediante la ecuacin
de Nernst: }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\ma
rgrsxn133\cols4\colno1\colw1680\colsr-0\colno2\colw346\colsr-0\colno3\colw226\co
lsr-0\colno4\colw8840\pard\li973\ri0\sl-453\slmult0 \fs24\cf0\f2\charscalex100 {
=}{\super \fs14\up5\cf0\f0\charscalex100 {0}}\fs24\cf0\f2\charscalex100 {+}\par\
pard\li640\ri0\sl-213\slmult0 \*\tx1173\fs24\cf0\f0\charscalex100\i {Eh}\i0 \tab
\fs24\cf0\f0\charscalex100\i {E}\i0 \par\column\pard\li0\ri0\sl-280\slmult0 \fs
24\cf0\f0\charscalex100\i {RT}\i0 \par\pard\li0\ri0\sl-333\slmult0 \fs24\cf0\f0\
charscalex100\i {nF}\i0 \par\column\pard\li0\ri0\sl-400\slmult0 \fs24\cf0\f0\cha
rscalex100 {ln}\par\column\pard\li80\ri0\sl-426\slmult0 \fs34\cf0\f2\charscalex1
00 {[}\fs24\cf0\f0\charscalex100\i {Oxidantes}\i0 \fs34\cf0\f2\charscalex100 {]}
\par\pard\li0\ri0\sl-426\slmult0 \fs34\cf0\f2\charscalex100\ul {[}\ul0 {\sub \fs
24\cf0\f0\charscalex100 {Re}}\fs24\cf0\f0\charscalex100\i {ductores}\i0 \fs34\cf

0\f2\charscalex100\ul {]}\ul0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn168
40\marglsxn666\margrsxn133\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex
100 {R: Constante de los gases =8,31441 joule/grado =1.985 (cal/grado) (C o K) }\p
ar\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {T: Temperatura expr
esada en K }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {F: Co
nstante de Faraday = 96493 amp/seg coulombs = 23060 cal/volt }\par\pard\li586\ri
0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {n: Nmero de equivalentes }\par\pard
\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {[M}{\super \fs14\up4\cf0\f
1\charscalex100 {n+}}\fs20\cf0\f1\charscalex100 {]: Concentracin molar de M con n
cargas positivas. }\par\pard\li600\ri0\sl-466\slmult0 \fs20\cf0\f1\charscalex10
0 {Para la reduccin del H}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1
\charscalex100 { a H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscale
x100 { a temperatura ambiente,: }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn
-0\colno3\colw786\colsr-0\colno4\colw453\colsr-0\colno5\colw8146\pard\li640\ri0\
sl-213\slmult0 \fs18\cf0\par\pard\li640\ri0\sl-453\slmult0 \fs24\cf0\f0\charscal
ex100\i {Eh}\i0 { }\fs24\cf0\f2\charscalex100 {=}{ }\fs24\cf0\f2\charscalex100 {
+}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-293\slmu
lt0 \fs24\cf0\f0\charscalex100\i {RT}\i0 \par\pard\li13\ri0\sl-333\slmult0 \fs22
\cf0\f0\charscalex100\i {nF}\i0 \par\column\pard\li186\ri0\sl-720\slmult0 \fs40\
cf0\f2\charscalex100 {[ ]}{\sub \fs14\cf0\f2\charscalex100 {+}}\fs14\cf0\f0\char
scalex100 {2}\par\pard\li0\ri0\sl-213\slmult0 \fs24\cf0\f0\charscalex100 {ln}\pa
r\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-453\slmult0 \
fs24\cf0\f2\charscalex100 {=}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\p
f0\f2\charscalex100 {\uc1\u8722X}\fs24\cf0\f0\charscalex100 {0}\fs24\cf0\f0\char
scalex100 {.}\fs24\cf0\f0\charscalex100 {0591}\fs24\cf0\f0\charscalex100\i {pH}\
i0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\
pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {Cuando el agua acta com
o un agente reductor se tiene }\par\pard\li600\ri0\sl-520\slmult0 \fs20\cf0\f1\
charscalex100 {4H}{\super \fs14\up3\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charsc
alex100 { + O}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {
+ 4e}{\super \fs14\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 { -->
2H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O }\fs20\cf
0\f2\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\charscalex100 {G=-113368 cal/mol y
}{ }\fs24\cf0\f0\charscalex100\i {Eh}\i0 { }\fs24\cf0\f2\charscalex100 {=}{ }\fs
24\cf0\f2\charscalex100 {+}\fs24\cf0\f0\charscalex100 {1}\fs24\cf0\f0\charscalex
100 {.}\fs24\cf0\f0\charscalex100 {23}{ }\fs24\cf0\f2\charscalex100 {\uc1\u8722X
}{ }\fs24\cf0\f0\charscalex100 {0}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\cha
rscalex100 {0591}\fs24\cf0\f0\charscalex100\i {pH}\i0 \par\pard\li586\ri0\sl-213
{Estas dos rectas delimitan la zona de estabilidad del agua y se mue
stran en la Figura 4 como lneas }\par\pard\li586\ri0\sl-226\slmult0 \fs20\c
f0\f1\charscalex100 {punteadas }\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\pa
r\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\r
i0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\par
d\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl
493\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\pa
s18\cf0\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\r
i0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\par
f0\f1\charscalex100 {Figura 4 Diagrama de Pourbaix del agua }\par\pard\li600\ri0

lex100\b {Efecto del pH}\b0 \fs18\cf0\f1\charscalex100 { Para las reaccione
s que comprenden iones de hidrgeno el potencial del electrodo es }\par\
pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {dependiente del pH.
Esto se representa por medio de los Diagramas de Pourbaix, o Diagram
as de }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {Potencial
/pH. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-253\sl
mult0 \fs16\cf0\f1\charscalex100 {La Figura 5 muestra, los campos de esta
bilidad de los distintos compuestos del fierro en los diversos }\par\pa
rd\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {ambientes en la escala d
e pH: o bien de la escala de potencial, ambiente oxidante o reductor. }\par\pard
\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1
\colw9893\colsr-0\colno2\colw1200\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pa
\fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slm
-226\slmult0 \fs24\cf0\f0\charscalex100 {22 }\par\pard\sect\sectd\sbknone\pgwsxn
11893\pghsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sbkpage
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\fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {En medio
cido y en un ambiente reductor se formar ion ferroso, Fe}{\super \fs14\up4\cf0\f1
\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 {. Siempre en condiciones cidas, }
\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {pero con un ambie
nte altamente oxidante, se formar ion frrico, Fe}{\super \fs14\up3\cf0\f1\charscal
ex100 {3+}}\fs20\cf0\f1\charscalex100 {. En cambio, en un medio bsico y }\par\par
d\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {en condiciones reductor
as se formar hidrxido ferroso, Fe(OH)}{\sub \fs12\cf0\f1\charscalex100 {2}}\f
s18\cf0\f1\charscalex100 {. El hidrxido frrico, Fe(OH)}{\sub \fs12\cf0\f1\char
scalex100 {3}}\fs18\cf0\f1\charscalex100 {, se }\par\pard\li586\ri0\sl-213\slmu
lt0 \fs20\cf0\f1\charscalex100 {formar en condiciones altamente oxidantes hasta u
n pH cido tan bajo como 1,8. }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\cha
rscalex100 {Los Diagramas de Pourbaix estn disponibles en la bibliografa para meta

les y compuestos, para distintas }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f
1\charscalex100 {temperaturas. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par
\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100\b {Serie Electroqumica
de los Metales}\b0 \fs20\cf0\f1\charscalex100 {. Si se contacta un metal con una
solucin que contiene iones de }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\c
harscalex100 {otro metal, el primero puede disolverse, es decir, oxidars
e, y el segundo depositarse o reducirse. Por }\par\pard\li586\ri0\sl-240\
slmult0 \fs18\cf0\f1\charscalex100 {ejemplo, si Fe}{\super \fs12\up4\cf0\f1\char
scalex100 {0}}\fs18\cf0\f1\charscalex100 { se colocada en contacto con una soluc
in de Cu}{\super \fs12\up4\cf0\f1\charscalex100 {2+}}\fs18\cf0\f1\charscalex100 {
, precipita cobre metlico Cu}{\super \fs12\up4\cf0\f1\charscalex100 {0}}\fs18\cf0
\f1\charscalex100 { mientras }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\ch
arscalex100 {el fierro pasa a la solucin: }\par\pard\sect\sectd\sbknone\pgwsxn118
93\pghsxn16840\marglsxn666\margrsxn133\cols6\colno1\colw1866\colsr-0\colno2\colw
1506\colsr-0\colno3\colw666\colsr-0\colno4\colw2413\colsr-0\colno5\colw1333\cols
r-0\colno6\colw3306\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\s
l-253\slmult0 \fs20\cf0\f1\charscalex100 {Fe}{\super \fs14\up3\cf0\f1\charscalex
100 {2+}}\fs20\cf0\f1\charscalex100 {+ 2e }\par{\trowd\trleft600\trkeep\trftsWid
th1\trpaddl0\trpaddr0\trpaddfl3\trpaddfr3 \clvertalt\clbrdrt\brdrnone\clbrdrl\br
drnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb\clNoWrap\clftsWidth3\clwWidth2
66\clpadt0\clpadr0\clpadft3\clpadfr3\cellx1533 \pard\li0\ri0\sl-253\widctlpar\in
tbl \fs20\cf0\f1\charscalex100 {Cu}\cell\clvertalt\clbrdrt\brdrnone\clbrdrl\brdr
none\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb\clNoWrap\clftsWidth3\clwWidth773
\clpadt0\clpadr0\clpadft3\clpadfr3\cellx2160 \pard\li0\ri0\sl-133\widctlpar\intb
l \fs14\cf0\f1\charscalex100 {2+}\par\pard\li0\ri0\sl-120\widctlpar\intbl \fs20\
cf0\f1\charscalex100 { + 2e}\fs14\cf0\f1\charscalex100 {-}\cell\row}\pard\li586\
ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Fe}{\super \fs14\up4\cf0\f1\chars
calex100 {0}}\fs20\cf0\f1\charscalex100 { + Cu}{\super \fs14\up4\cf0\f1\charscal
ex100 {2+}}\par\column\pard\li146\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li146\ri
0\sl-266\slmult0 \fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex
100 { Fe}{\super \fs14\up3\cf0\f1\charscalex100 {0}}\par\pard\li146\ri0\sl-253\s
lmult0 \fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 {Cu}{\
super \fs14\up4\cf0\f1\charscalex100 {0}}\par\pard\li146\ri0\sl-253\slmult0 \fs2
0\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 {Fe}{\super \fs14
\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 { + Cu}{\super \fs14\u
p4\cf0\f1\charscalex100 {0}}\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li0\ri0\sl-200\slmult0 \fs12\cf0\f0\charscalex100\b {Eh (Volts)}\b0 \par\pard\li
253\ri0\sl-146\slmult0 \fs14\cf0\f0\charscalex100\b {2.0}\b0 \par\pard\li253\ri0
lex100\b {1.5}\b0 \par\pard\li560\ri0\sl-146\slmult0 \fs12\cf0\f0\charscalex100\
b {Fe(+3a)}\b0 \par\pard\li253\ri0\sl-320\slmult0 \fs14\cf0\f0\charscalex100\b {
1.0}\b0 \par\pard\li253\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li253\ri0\sl-253\s
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{14}\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrs
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0\ri0\sl-293\slmult0 \fs14\cf0\f0\charscalex100\b {
pH}\b0 \par\pard\sect
\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols3\colno1\colw
4280\colsr-0\colno2\colw1680\colsr-0\colno3\colw5133\pard\li2826\ri0\sl-213\slmu
lt0 \fs18\cf0\par\pard\li2826\ri0\sl-146\slmult0 \fs14\cf0\f0\charscalex100\b {E
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}\b0 \par\column\pard\li93\ri0\sl-213\slmult0 \fs18\cf0\
par\pard\li93\ri0\sl-146\slmult0 \fs12\cf0\f0\charscalex100\b {Mol al i ty}\b0 \
par\pard\li0\ri0\sl-173\slmult0 \fs14\cf0\f0\charscalex100\b { 1.000E+00}\b0 \p

ar\column\pard\li66\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li66\ri0\sl-146\slmult
0 \fs12\cf0\f0\charscalex100\b {Pre ssu re}\b0 \par\pard\li0\ri0\sl-173\slmult0
\fs14\cf0\f0\charscalex100\b { 1.000E+00}\b0 \par\pard\sect\sectd\sbknone\pgwsx
n11893\pghsxn16840\marglsxn666\margrsxn133\pard\li3040\ri0\sl-213\slmult0 \fs18\
cf0\par\pard\li3040\ri0\sl-213\slmult0 \fs20\cf0\f0\charscalex100\b {Figura 5 Di
agrama de Pourbaix del Fe-H}\b0 {\sub \fs14\cf0\f0\charscalex100\b {2}\b0 }\fs20
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1\charscalex100 {0}}\fs20\cf0\f1\charscalex100 { + 2Ag}{\super \fs14\up4\cf0\f1\
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0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {Aluminio }\par\pard\li0\ri0\sl-266\
slmult0 \fs20\cf0\f1\charscalex100 {Berilio }\par\pard\li0\ri0\sl-280\slmult0 \f
s20\cf0\f1\charscalex100 {Magnesio }\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f
1\charscalex100 {Sodio }\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex
100 {Calcio }\par\pard\li0\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {Potasi
o }\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {Litio }\par\colu
mn\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\c
f0\par{\trowd\trleft0\trkeep\trftsWidth1\trpaddl0\trpaddr0\trpaddfl3\trpaddfr3 \
clvertalt\clbrdrt\brdrnone\clbrdrl\brdrnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cl
txlrtb\clNoWrap\clftsWidth3\clwWidth773\clpadt0\clpadr0\clpadft3\clpadfr3\cellx7
453 \pard\li0\ri0\sl-253\widctlpar\intbl \fs20\cf0\f1\charscalex100 {Cd =Cd}\cell
\clvertalt\clbrdrt\brdrnone\clbrdrl\brdrnone\clbrdrb\brdrnone\clbrdrr\brdrnone\c
ltxlrtb\clNoWrap\clftsWidth3\clwWidth733\clpadt0\clpadr0\clpadft3\clpadfr3\cellx
8026 \pard\li0\ri0\sl-133\widctlpar\intbl \fs14\cf0\f1\charscalex100 {2+}\par\pa
rd\li0\ri0\sl-120\widctlpar\intbl \fs20\cf0\f1\charscalex100 {+ 2e}\fs14\cf0\f1\
charscalex100 {-}\cell\row}\pard\li0\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex1
00 {Fe =Fe}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100
{+ 2e}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\par\pard\li0\ri0\sl-266\slmul
t0 \fs20\cf0\f1\charscalex100 {Zn =Zn}{\super \fs14\up4\cf0\f1\charscalex100 {2+}
}\fs20\cf0\f1\charscalex100 {+ 2e}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\pa
r\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {Cr =Cr}{\super \fs14\up
3\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 {+ 2e}{\super \fs14\up3\c
f0\f1\charscalex100 {-}}\par{\trowd\trleft0\trkeep\trftsWidth1\trpaddl0\trpaddr0
\trpaddfl3\trpaddfr3 \clvertalt\clbrdrt\brdrnone\clbrdrl\brdrnone\clbrdrb\brdrno
ne\clbrdrr\brdrnone\cltxlrtb\clNoWrap\clftsWidth3\clwWidth813\clpadt0\clpadr0\cl
padft3\clpadfr3\cellx7493 \pard\li0\ri0\sl-280\widctlpar\intbl \fs20\cf0\f1\char
scalex100 {Mn =Mn}\cell\clvertalt\clbrdrt\brdrnone\clbrdrl\brdrnone\clbrdrb\brdrn
one\clbrdrr\brdrnone\cltxlrtb\clNoWrap\clftsWidth3\clwWidth720\clpadt0\clpadr0\c
lpadft3\clpadfr3\cellx8066 \pard\li0\ri0\sl-160\widctlpar\intbl \fs14\cf0\f1\cha
rscalex100 {2+}\par\pard\li0\ri0\sl-120\widctlpar\intbl \fs20\cf0\f1\charscalex1
00 {+ 2e}\fs14\cf0\f1\charscalex100 {-}\cell\row}{\trowd\trleft0\trkeep\trftsWid
th1\trpaddl0\trpaddr0\trpaddfl3\trpaddfr3 \clvertalt\clbrdrt\brdrnone\clbrdrl\br
drnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb\clNoWrap\clftsWidth3\clwWidth6
13\clpadt0\clpadr0\clpadft3\clpadfr3\cellx7293 \pard\li0\ri0\sl-266\widctlpar\in
tbl \fs20\cf0\f1\charscalex100 {Al =Al}\cell\clvertalt\clbrdrt\brdrnone\clbrdrl\b
rdrnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb\clNoWrap\clftsWidth3\clwWidth
720\clpadt0\clpadr0\clpadft3\clpadfr3\cellx7866 \pard\li0\ri0\sl-146\widctlpar\i
ntbl \fs14\cf0\f1\charscalex100 {3+}\par\pard\li0\ri0\sl-120\widctlpar\intbl \fs
20\cf0\f1\charscalex100 {+ 3e}\fs14\cf0\f1\charscalex100 {-}\cell\row}\pard\li0\
ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {Be =Be}{\super \fs14\up3\cf0\f1\ch
arscalex100 {2+}}\fs20\cf0\f1\charscalex100 {+ 2e}{\super \fs14\up3\cf0\f1\chars
calex100 {-}}\par\pard\li0\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {Mg =Mg
+ 2e}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\par\pard\li0\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {Na =Na}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\f
s20\cf0\f1\charscalex100 { + le}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\par{
\trowd\trleft0\trkeep\trftsWidth1\trpaddl0\trpaddr0\trpaddfl3\trpaddfr3 \clverta
lt\clbrdrt\brdrnone\clbrdrl\brdrnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb\
clNoWrap\clftsWidth3\clwWidth773\clpadt0\clpadr0\clpadft3\clpadfr3\cellx7453 \pa
rd\li0\ri0\sl-266\widctlpar\intbl \fs20\cf0\f1\charscalex100 {Ca =Ca}\cell\clvert
alt\clbrdrt\brdrnone\clbrdrl\brdrnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb
\clNoWrap\clftsWidth3\clwWidth733\clpadt0\clpadr0\clpadft3\clpadfr3\cellx8026 \p
ard\li0\ri0\sl-160\widctlpar\intbl \fs14\cf0\f1\charscalex100 {2+}\par\pard\li0\
ri0\sl-106\widctlpar\intbl \fs20\cf0\f1\charscalex100 {+ 2e}\fs14\cf0\f1\charsca
lex100 {-}\cell\row}{\trowd\trleft0\trkeep\trftsWidth1\trpaddl0\trpaddr0\trpaddf
l3\trpaddfr3 \clvertalt\clbrdrt\brdrnone\clbrdrl\brdrnone\clbrdrb\brdrnone\clbrd
rr\brdrnone\cltxlrtb\clNoWrap\clftsWidth3\clwWidth520\clpadt0\clpadr0\clpadft3\c
lpadfr3\cellx7200 \pard\li0\ri0\sl-280\widctlpar\intbl \fs20\cf0\f1\charscalex10
0 {K =K}\cell\clvertalt\clbrdrt\brdrnone\clbrdrl\brdrnone\clbrdrb\brdrnone\clbrdr
r\brdrnone\cltxlrtb\clNoWrap\clftsWidth3\clwWidth586\clpadt0\clpadr0\clpadft3\cl
padfr3\cellx7640 \pard\li0\ri0\sl-160\widctlpar\intbl \fs14\cf0\f1\charscalex100
{+}\par\pard\li0\ri0\sl-120\widctlpar\intbl \fs20\cf0\f1\charscalex100 {+ le}\f
s14\cf0\f1\charscalex100 {-}\cell\row}\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\
charscalex100 {Li =Li}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\cha
rscalex100 {+ le}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\par\column\pard\li0
\li0\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {+0,403 }\par\pard\li0\ri0\sl
-280\slmult0 \fs20\cf0\f1\charscalex100 {+0,440 }\par\pard\li0\ri0\sl-266\slmult
0 \fs20\cf0\f1\charscalex100 {+0,763 }\par\pard\li53\ri0\sl-266\slmult0 \fs20\cf
0\f1\charscalex100 {+0,86 }\par\pard\li53\ri0\sl-280\slmult0 \fs20\cf0\f1\charsc
alex100 {+1,19 }\par\pard\li53\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {+1
,66 }\par\pard\li53\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {+1,85 }\par\p
ard\li53\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {+2,37 }\par\pard\li0\ri0
\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {+2,714 }\par\pard\li0\ri0\sl-266\slm
ult0 \fs20\cf0\f1\charscalex100 {+2,870 }\par\pard\li0\ri0\sl-280\slmult0 \fs20\
cf0\f1\charscalex100 {+2,925 }\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\char
scalex100 {+3,045 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn
0\slmult0 \fs20\cf0\f1\charscalex100 {Los metales pueden ser ordenados de acuerd
o a su habilidad para reducir iones de otros metales, Tabla }\par\pard\li586\ri0
\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {VII. Los metales con mayor poder red
uctor se encuentran en la zona baja de la lista, lo que significa que }\par\pard
\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {pueden reducir o precipita
r los iones de todos los metales que estn ms arriba. El punto de referencia en }\p
ar\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {esta lista, es l
a reduccin del hidrgeno. Esta escala tambin se denomina serie de nobleza
de los }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {metale
s. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmul
93\slmult0 \fs20\cf0\f0\charscalex100\b {Procesos Galvnicos }\b0 \par\pard\li586\
scalex100 {El potencial elctrico generado entre dos metales, se conoce como un pr
oceso galvnico, en homenajea }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\cha
rscalex100 {Luigi Galvani, el descubridor de la corriente elctrica. }\par\pard\li
586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Una situacin parecida sucede c

uando dos trozos del mismo metal estn inmersos en dos soluciones de }\par\pard\li
586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {sus iones y son conectado
s entre s, Entonces, una corriente elctrica fluye bajo las siguientes }\
par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {condiciones: }\par
\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {i) Cuando las solucio
nes tiene diferentes concentraciones. Por ejemplo, cuando un trozo de fierro en
una }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {solucin baja
concentracin de Fe}{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\fs18\cf0\f1\c
harscalex100 { es conectado con otro trozo de fierro en una solucin de
mayor }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {concentr
acin. El trozo de la primera solucin se disolver, acta como nodo, mientras que el Fe}
{\super \fs12\up4\cf0\f1\charscalex100 {2+}}\fs18\cf0\f1\charscalex100 { de la }
\par\pard\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {segunda solucin e
mpezar a precipitarse, acta como ctodo, nodo: Fe }{ }\fs18\cf0\f2\charscalex100 {\uc
1\u8660X}\fs18\cf0\f1\charscalex100 { Fe}{\super \fs12\up3\cf0\f1\charscalex100
{2+}}\fs18\cf0\f1\charscalex100 {+ 2e}{\super \fs12\up3\cf0\f1\charscalex100 {-}
}\fs18\cf0\f1\charscalex100 {, Ctodo: Fe}{\super \fs12\up3\cf0\f1\charscalex100
{2+}}\fs18\cf0\f1\charscalex100 {+ }\par\pard\li600\ri0\sl-253\slmult0 \fs20\cf0
\f1\charscalex100 {2e}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f2\ch
arscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { Fe. El proceso continua has
ta que las concentraciones de las dos soluciones se igualan. }\par\pard\li600\ri
alex100 {ii) Cuando las dos soluciones presenta la misma concentracin de iones, p
ero diferente concentracin de }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\ch
arscalex100 {oxgeno. En el ejemplo anterior, si las dos soluciones tienen la mism
a concentracin de Fe}{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\cha
rscalex100 {, pero en una }\par\pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f1\chars
calex100 {de ellas se burbujea nitrgeno y en la otra oxgeno. A bajas concentracion
es de O}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {, el Fe
}{\super \fs14\up3\cf0\f1\charscalex100 {0}}\fs20\cf0\f1\charscalex100 { acta com
o un }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {nodo y se d
isuelve,}{ }\fs20\cf0\f1\charscalex100 {mientras que a mayores concentraciones d
e O}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {, el trozo
de fierro funcionar como }\par\pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f1\charsca
lex100 {ctodo, sobre el cual el oxgeno se reducir: 1/2O}{\sub \fs14\cf0\f1\charscal
ex100 {2}}\fs20\cf0\f1\charscalex100 { + H}{\sub \fs14\cf0\f1\charscalex100 {2}}
\fs20\cf0\f1\charscalex100 {O + 2e}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\f
s20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { 2OH}{\super \
fs14\up4\cf0\f1\charscalex100 {-}}\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\p
20\cf0\f0\charscalex100\b {Procesos Electrolticos }\b0 \par\pard\li600\ri0\sl-213
{Los procesos de oxidacin y reduccin pueden ser realizados a voluntad si se utiliz
a una fuente elctrica }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex
100 {externa (FEM: fuente electro-motriz). Un metal puede ser oxidado hacindolo a
ctuar como nodo. }\par\pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {n
odo: M}{\super \fs14\up3\cf0\f1\charscalex100 {0}}\fs20\cf0\f2\charscalex100 {\u
c1\u8660X}\fs20\cf0\f1\charscalex100 { M}{\super \fs14\up3\cf0\f1\charscalex100
{n+ }}\fs20\cf0\f1\charscalex100 {+ ne}{\super \fs14\up3\cf0\f1\charscalex100 {}}\fs20\cf0\f1\charscalex100 {, }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f
1\charscalex100 {ctodo: M}{\super \fs14\up4\cf0\f1\charscalex100 {n+}}\fs20\cf0\f
1\charscalex100 { + ne}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f2\c
harscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { M}{\super \fs14\up4\cf0\f
1\charscalex100 {0}}\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\
ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {En estos procesos se aplica
las leyes de Faraday, es decir, la cantidad de electricidad requerida
para }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {oxidar o
reducir es 6,02 x 10}{\super \fs12\up3\cf0\f1\charscalex100 {23}}\fs18\cf0\
f1\charscalex100 { tomos monovalentes, para tomos o iones de valencia sup
erior se }\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {necesi

tar un mltiplo de faradays. }\par\pard\li600\ri0\sl-453\slmult0 \*\tx2013\fs20\cf0
\f1\charscalex100 {Un Faraday }\tab \fs20\cf0\f1\charscalex100 {= 96.500 coulom
bs = 96.500 amp/s =6,02 x 10}{\super \fs14\up4\cf0\f1\charscalex100 {23}}\fs20\c
f0\f1\charscalex100 { electrones }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\
par\pard\li586\ri0\sl-253\slmult0 \*\tx2013\fs20\cf0\f1\charscalex100 {Un coulom
b }\tab \fs20\cf0\f1\charscalex100 {= 1 amp x 1 s = 6,23 x 10}{\super \fs14\up4
\cf0\f1\charscalex100 {18}}\fs20\cf0\f1\charscalex100 { electrones. }\par\pard\s
ect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\c
olw9893\colsr-0\colno2\colw1200\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard
s18\cf0\par\pard\li586\ri0\sl-253\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Bena
vente }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213
0\sl-226\slmult0 \fs24\cf0\f0\charscalex100 {24 }\par\pard\sect\sectd\sbknone\pg
wsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sbkpage
7;32768}}
\fs18\cf0\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Para cal
cular el peso de nquel depositado a partir de una solucin de NiCl}{\sub \fs14\cf0\
f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {, mediante una corriente de }\p
ar\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {0,4 amperes, que fl
uye durante 2,5 horas, se tiene: }\par\pard\li586\ri0\sl-266\slmult0 \fs20\cf0\f
1\charscalex100 {Ni}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\cha
rscalex100 { + 2e}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f2\char
scalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { Ni}{\super \fs14\up4\cf0\f1
\charscalex100 {0}}\fs20\cf0\f1\charscalex100 { se requieren 2 x 6,02 x 1
0}{\super \fs14\up4\cf0\f1\charscalex100 {23}}\fs20\cf0\f1\charscalex100 { elec
trones, para reducir 6,02x 10}{\super \fs14\up4\cf0\f1\charscalex100 {23}}\f
s20\cf0\f1\charscalex100 { tomos de Ni}{\super \fs14\up4\cf0\f1\charscalex100
{2+}}\par\pard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {(divalente,
es decir, n = 2), o sea: 2F sern requeridos para reducir 1 mol de Ni. }\par\pard\
li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f

1\charscalex100 {El peso molecular del nquel es 58,71 gramos, por lo tanto: 2F =
2 x 96.500 coulombs, para 58,71 g Ni, y }\par\pard\li586\ri0\sl-226\slmult0 \fs2
0\cf0\f1\charscalex100 {como: 1 coulomb = 1 ampere x 1 segundo, entonces: 0,4 Am
p x 2,5 h x 60 m/h x 60 s/h coulombs para X }\par\pard\li586\ri0\sl-226\slmult0
\fs20\cf0\f1\charscalex100 {g Ni }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\
par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {x = 58,71 x 0,4 x
2,5 x 60 x 60 /( 2 x 96.500)=1,094 gramos }\par\pard\li586\ri0\sl-213\slmult0 \
lmult0 \fs20\cf0\f0\charscalex100\b \i {Potencial de Electrodo y cambio de Energa
Libre }\b0 \i0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0
\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {Para las reacciones que comprenden u
na prdida o una ganancia de electrones, el potencial de electrodo }\par\pard\li58
6\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {representa el Trabajo mximo (W}{
\sub \fs12\cf0\f1\charscalex100 {max}}\fs18\cf0\f1\charscalex100 {) realizado po
r una celda electroqumica. La cantidad de electricidad }\par\pard\li586\ri0\sl-22
6\slmult0 \fs20\cf0\f1\charscalex100 {suministrada por cada equivalente de susta
ncia reaccionada es un Faraday.- }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f
1\charscalex100 {W}\fs14\cf0\f1\charscalex100 {mximo}\fs20\cf0\f1\charscalex100 {
= -}\fs20\cf0\f2\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\charscalex100 {G= -nF
Eh, donde }\fs20\cf0\f2\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\charscalex100 {G
es el cambio de energa libre de Gibbs. en condiciones estndar }\par\pard\li600\ri
alex100 {\uc1\u8710X}\fs20\cf0\f1\charscalex100 {G}{\super \fs14\up4\cf0\f1\char
scalex100 {0}}\fs20\cf0\f1\charscalex100 { = -nFE}{\super \fs14\up4\cf0\f1\chars
calex100 {0}}\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl226\slmult0 \fs20\cf0\f1\charscalex100 {Dado que el cambio de energa libre
est relacionado con la constante de equilibrio K, mediante la }\par\par
d\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {relacin. }\par\pard\li586\
ri0\sl-266\slmult0 \fs20\cf0\f2\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\charscal
ex100 {G}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\fs20\cf0\f1\charscalex100 {
= -RT ln K , se deduce que: RT ln K = nFE}{\super \fs14\up4\cf0\f1\charscalex100
{0}}\par\pard\li6160\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li6160\ri0\sl-186\sl
mult0 \fs14\cf0\f0\charscalex100 {0}\par\pard\sect\sectd\sbknone\pgwsxn11893\pgh
sxn16840\marglsxn666\margrsxn133\cols2\colno1\colw5680\colsr-0\colno2\colw5413\p
ard\li600\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {Cambiando a logaritmo d
ecimal, se tiene que: }{ }\fs24\cf0\f0\charscalex100 {log}{ }\fs24\cf0\f0\charsc
alex100\i {K}\i0 { }\fs24\cf0\f2\charscalex100 {=}\par\column\pard\li40\ri0\sl-2
13\slmult0 \fs24\cf0\f0\charscalex100\i {nFE}\i0 \par\pard\li0\ri0\sl-253\slmult
0 \fs24\cf0\f0\charscalex100 {2}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\chars
calex100 {303}\fs24\cf0\f0\charscalex100\i {RT}\i0 \par\pard\sect\sectd\sbknone\
pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {La energa
libre de Gibbs y los Potenciales de electrodo estndar est disponible e
n tablas }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {termod
inmicas. A partir de ellas es posible calcular los cambios de la ener
ga libre y de all las }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charsc
alex100 {constantes de equilibrio de las reacciones. Por convencin, se ha estable
cido que el valor de la energa }\par\pard\li586\ri0\sl-226\slmult0 \fs16\cf0\f1\c
harscalex100 {libre para los elementos en su estado estndar es cero, y,
en forma similar, tambin se ha asignado el }\par\pard\li586\ri0\sl-226\s
lmult0 \fs18\cf0\f1\charscalex100 {valor cero a la energa libre correspondi
ente a los iones de hidrgeno, usndolos as como valor de }\par\pard\li586\
ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {referencia }\par\pard\li586\ri0\
ex100 {Se tienen los siguientes clculos para obtener la constante de equilibrio d
e la reaccin: }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Cu}
{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 { + Fe}{\
super \fs14\up3\cf0\f1\charscalex100 {0}}\fs20\cf0\f2\charscalex100 {\uc1\u8660X
}\fs20\cf0\f1\charscalex100 { Cu}{\super \fs14\up3\cf0\f1\charscalex100 {0}}\fs2
0\cf0\f1\charscalex100 { + Fe}{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\par\p

f0\f1\charscalex100 {i) Usando informacin del cambio de energa libre: }\par\pard\s
olw2013\colsr-0\colno2\colw9080\pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f2\chars
calex100 {\uc1\u8710X}\fs20\cf0\f1\charscalex100 {G}{\super \fs14\up4\cf0\f1\cha
rscalex100 {0}}\fs12\cf0\f1\charscalex100 {reaccin }\par\column\pard\li0\ri0\sl253\slmult0 \fs20\cf0\f1\charscalex100 {= }\fs20\cf0\f2\charscalex100 {\uc1\u871
0X}\fs20\cf0\f1\charscalex100 {G}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\fs1
2\cf0\f1\charscalex100 {productos}{\super \fs20\cf0\f1\charscalex100 { -}}\fs20\
cf0\f2\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\charscalex100 {G}{\super \fs14\up
4\cf0\f1\charscalex100 {0}}\fs12\cf0\f1\charscalex100 {reactantes }\par\pard\sec
t\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\s
l-480\slmult0 \fs20\cf0\f2\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\charscalex100
{G}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\fs12\cf0\f1\charscalex100 {reacc
in}\fs20\cf0\f1\charscalex100 { = (0-20,3)-(15,5+0) = -35,8kcal/mol }\par\pard\se
ct\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols6\colno1\co
lw1226\colsr-0\colno2\colw853\colsr-0\colno3\colw293\colsr-0\colno4\colw426\cols
r-0\colno5\colw626\colsr-0\colno6\colw7666\pard\li626\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li626\ri0\sl-240\slmult0 \fs24\cf0\f0\charscalex100 {log}{ }\fs24\cf
0\f0\charscalex100\i {K}\i0 \par\column\pard\li0\ri0\sl-466\slmult0 \*\tx320\fs2
4\cf0\f2\charscalex100 {=}\tab \fs24\cf0\f2\charscalex100 {\uc1\u8722X}{ }\fs24\
cf0\f2\charscalex100 {\uc1\u8710X}\par\pard\li653\ri0\sl-213\slmult0 \fs22\cf0\f
0\charscalex100\i {G}\i0 \par\column\pard\li0\ri0\sl-173\slmult0 \fs14\cf0\f0\ch
arscalex100 {0}\par\column\pard\li0\ri0\sl-466\slmult0 \fs24\cf0\f2\charscalex10
0 {=}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-240\s
lmult0 \fs24\cf0\f0\charscalex100 {26}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0
\charscalex100 {25}\par\column\pard\li0\ri0\sl-466\slmult0 \fs20\cf0\f1\charscal
ex100 {K}{\sub \fs14\cf0\f1\charscalex100 {i}}\fs20\cf0\f1\charscalex100 { = 1,8
x 10}{\super \fs14\up3\cf0\f1\charscalex100 {26}}\par\pard\sect\sectd\sbknone\p
gwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li1560\ri0\sl-213\slmult0 \f
s24\cf0\f0\charscalex100 {2}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\charscale
x100 {303}\fs24\cf0\f0\charscalex100\i {RT}\i0 \par\pard\li600\ri0\sl-213\slmult
0 \fs18\cf0\par\pard\li600\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {ii) Us
ando la informacin de los potenciales de electrodo estndar. }\par\pard\li600\ri0\s
l-253\slmult0 \fs20\cf0\f1\charscalex100 {Reaccin de oxidacin: Fe}{\super \fs14\up
4\cf0\f1\charscalex100 {0}}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\
charscalex100 { Fe}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\char
scalex100 { + 2e}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charsca
lex100 { = 0,44 volt }\par\pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f1\charscale
x100 {Reaccin de reduccin: Cu}{\super \fs14\up3\cf0\f1\charscalex100 {0}}\fs20\cf0
\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 {Cu}{\super \fs14\up3\
cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 {+ 2e =-0,34 volt }\par\par
d\li586\ri0\sl-453\slmult0 \fs20\cf0\f1\charscalex100 {E}{\super \fs14\up4\cf0\f
1\charscalex100 {0}}\fs12\cf0\f1\charscalex100 {reaccin }{\super \fs20\cf0\f1\cha
rscalex100 {=E}}\fs14\cf0\f1\charscalex100 {0}\fs12\cf0\f1\charscalex100 {oxidac
in}\fs20\cf0\f1\charscalex100 { - E}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\f
s12\cf0\f1\charscalex100 {reduccin}\fs20\cf0\f1\charscalex100 { =(0,44+0,34) = 0,
78 volt }\par\pard\li1960\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1960\ri0\sl-18
6\slmult0 \fs14\cf0\f0\charscalex100 {0}\par\pard\sect\sectd\sbknone\pgwsxn11893
3\colsr-0\colno3\colw426\colsr-0\colno4\colw693\colsr-0\colno5\colw7666\pard\li6
26\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {log}{ }\fs24\cf0\f0\charscalex
100\i {k}\i0 { }\fs24\cf0\f2\charscalex100 {=}\par\column\pard\li26\ri0\sl-213\s
lmult0 \fs24\cf0\f0\charscalex100\i {nFE}\i0 \par\pard\li0\ri0\sl-266\slmult0 \f
s24\cf0\f0\charscalex100 {2}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\charscale
x100 {303}\fs24\cf0\f0\charscalex100\i {RT}\i0 \par\column\pard\li0\ri0\sl-306\s
lmult0 \fs24\cf0\f2\charscalex100 {=}\par\column\pard\li0\ri0\sl-293\slmult0 \fs
24\cf0\f0\charscalex100 {26}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\charscale
x100 {38}\par\column\pard\li0\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {K}{
\sub \fs14\cf0\f1\charscalex100 {ii}}\fs20\cf0\f1\charscalex100 { = 2,4 x 10}{\s

uper \fs14\up4\cf0\f1\charscalex100 {26}}\par\pard\sect\sectd\sbknone\pgwsxn1189
3\pghsxn16840\marglsxn666\margrsxn133\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1
\charscalex100 {Las dos modalidades de clculo para la constante de equili
brio presentan, en este caso, una diferencia }\par\pard\li600\ri0\sl-226\s
lmult0 \fs20\cf0\f1\charscalex100 {poco significativa entre ellas: }\par\pard\se
ct\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\co
lw9893\colsr-0\colno2\colw1200\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
24\cf0\f0\charscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmult
3\slmult0 \fs24\cf0\f0\charscalex100 {25 }\par\pard\sect\sectd\sbknone\pgwsxn118
93\pghsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sbkpage
7;32768}}

7;32768}}
7;32768}}
7;32768}}

\fs18\cf0\par\pard\li586\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {De igua
l manera, el equilibrio para la reaccin: CuS + 2Fe}{\super \fs14\up3\cf0
\f1\charscalex100 {3+}}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\char
scalex100 { Cu}{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charsca
lex100 { + 2Fe}{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charsc
alex100 { + S}{\super \fs14\up3\cf0\f1\charscalex100 {0}}\fs20\cf0\f1\charscal
ex100 { puede tambin }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscale
x100 {determinarse usando dos procedimientos de clculo: }\par\pard\li586\ri0\sl-2
26\slmult0 \fs20\cf0\f1\charscalex100 {) usando informacin del cambio de energa lib
re: }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f2\charscalex100 {\uc1\u8710X
}\fs20\cf0\f1\charscalex100 {G}{\super \fs14\up3\cf0\f1\charscalex100 {0}}\fs12\
cf0\f1\charscalex100 {reaccin}{\super \fs20\cf0\f1\charscalex100 { = }}\fs20\cf0\
f2\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\charscalex100 {G}{\super \fs14\up3\cf
0\f1\charscalex100 {0}}\fs12\cf0\f1\charscalex100 {productos}{\super \fs20\cf0\f
1\charscalex100 { -}}\fs20\cf0\f2\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\charsc
alex100 {G}{\super \fs14\up3\cf0\f1\charscalex100 {0}}\fs12\cf0\f1\charscalex100
{reactantes}\par\pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f2\charscalex100 {\uc1
\u8710X}\fs20\cf0\f1\charscalex100 {G}{\super \fs14\up4\cf0\f1\charscalex100 {0}

}\fs12\cf0\f1\charscalex100 {reaccin }\fs20\cf0\f1\charscalex100 {= [15,5 + 2x (20,3) +0] -[ -11,7+ 2 x(-2,52)] }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f2
\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\charscalex100 {G}{\super \fs14\up4\cf0\
f1\charscalex100 {0}}\fs12\cf0\f1\charscalex100 {reaccin }\fs20\cf0\f1\charscalex
100 {= -8,36 kcal }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn
666\margrsxn133\cols6\colno1\colw1226\colsr-0\colno2\colw853\colsr-0\colno3\colw
293\colsr-0\colno4\colw306\colsr-0\colno5\colw746\colsr-0\colno6\colw7666\pard\l
r\pard\li626\ri0\sl-253\slmult0 \fs24\cf0\f0\charscalex100 {log}{ }\fs24\cf0\f0\
charscalex100\i {K}\i0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\par
d\li0\ri0\sl-480\slmult0 \*\tx320\fs24\cf0\f2\charscalex100 {=}\tab \fs24\cf0\f2
\charscalex100 {\uc1\u8722X}{ }\fs24\cf0\f2\charscalex100 {\uc1\u8710X}\par\pard
\li653\ri0\sl-213\slmult0 \fs22\cf0\f0\charscalex100\i {G}\i0 \par\column\pard\l
rscalex100 {0}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0
\sl-480\slmult0 \fs24\cf0\f2\charscalex100 {=}\par\column\pard\li0\ri0\sl-213\sl
3\slmult0 \fs24\cf0\f0\charscalex100 {6}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\
f0\charscalex100 {130}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard
harscalex100 {Ki =1,35 x 10}{\super \fs14\up4\cf0\f1\charscalex100 {6}}\par\pard
\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li1560\
ri0\sl-213\slmult0 \fs24\cf0\f0\charscalex100 {2}\fs24\cf0\f0\charscalex100 {.}\
fs24\cf0\f0\charscalex100 {303}\fs24\cf0\f0\charscalex100\i {RT}\i0 \par\pard\li
charscalex100 {ii) usando la informacin de los potenciales de electrodo estndar, l
a reaccin anterior se puede dividir en }\par\pard\li600\ri0\sl-240\slmult0 \fs20\
cf0\f1\charscalex100 {las siguientes etapas: }\par\pard\li600\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li600\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {CuS}\fs
14\cf0\f1\charscalex100 {(S) }\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\
f1\charscalex100 { Cu}{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\c
harscalex100 { + S}{\super \fs14\up3\cf0\f1\charscalex100 {2-}}\fs20\cf0\f1\char
scalex100 {K}{\sub \fs14\cf0\f1\charscalex100 {1}}\fs20\cf0\f1\charscalex100 { =
[Cu}{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 {] [
S}{\super \fs14\up3\cf0\f1\charscalex100 {2-}}\fs20\cf0\f1\charscalex100 {] = 8
x 10}{\super \fs14\up3\cf0\f1\charscalex100 {-37}}\par\pard\sect\sectd\sbknone\p
no2\colw1480\colsr-0\colno3\colw6120\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par
\pard\li586\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {S}{\super \fs14\up4\c
f0\f1\charscalex100 {2-}}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\ch
arscalex100 { S}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\fs20\cf0\f1\charscal
ex100 {+ 2e }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Fe}{
\super \fs14\up3\cf0\f1\charscalex100 {3+}}\fs20\cf0\f1\charscalex100 { + e}{\su
per \fs14\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\
fs20\cf0\f1\charscalex100 { Fe}{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\par\
pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {2Fe}{\super \fs14\up3\
cf0\f1\charscalex100 {3+}}\fs20\cf0\f1\charscalex100 {+ S}{\super \fs14\up3\cf0\
f1\charscalex100 {2+}}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\chars
calex100 { 2Fe}{\super \fs14\up3\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscal
ex100 {+ S}{\super \fs14\up3\cf0\f1\charscalex100 {0}}\par\pard\li2026\ri0\sl-21
0 {0}\par\column\pard\li0\ri0\sl-453\slmult0 \fs20\cf0\f1\charscalex100 {E}{\sup
er \fs14\up4\cf0\f1\charscalex100 {0}}\fs20\cf0\f1\charscalex100 {= 0,48 volt }\
par\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {E}{\super \fs14\up4\
cf0\f1\charscalex100 {0}}\fs20\cf0\f1\charscalex100 { = 0,77 volt }\par\pard\li0
\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {E}{\super \fs14\up4\cf0\f1\chars
calex100 {0}}\fs20\cf0\f1\charscalex100 {= 1,25 volt }\par\column\pard\li0\ri0\s

rscalex100 {[ ]}\par\pard\li320\ri0\sl-186\slmult0 \*\tx573\fs14\cf0\f0\charscal
ex100 {2}\fs14\cf0\f2\charscalex100 {+}\tab \fs14\cf0\f0\charscalex100 {2}\par\p
ard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols7\col
no1\colw1586\colsr-0\colno2\colw786\colsr-0\colno3\colw800\colsr-0\colno4\colw24
226\ri0\sl-306\slmult0 \fs24\cf0\f2\charscalex100 {=}\par\column\pard\li0\ri0\sl
-213\slmult0 \fs24\cf0\f0\charscalex100\i {nFE}\i0 \par\column\pard\li0\ri0\sl-3
06\slmult0 \fs24\cf0\f2\charscalex100 {=}\par\column\pard\li0\ri0\sl-213\slmult0
\fs24\cf0\f0\charscalex100\i {K}\i0 \par\column\pard\li0\ri0\sl-306\slmult0 \fs
24\cf0\f2\charscalex100 {=}\par\column\pard\li0\ri0\sl-213\slmult0 \fs24\cf0\f0\
charscalex100\i {x}\i0 \par\column\pard\li0\ri0\sl-306\slmult0 \*\tx213\fs14\cf0
\f0\charscalex100 {42}\tab \fs24\cf0\f2\charscalex100 {=}\par\pard\sect\sectd\sb
r-0\colno2\colw1240\colsr-0\colno3\colw946\colsr-0\colno4\colw1000\colsr-0\colno
5\colw6346\pard\li626\ri0\sl-213\slmult0 \fs24\cf0\f0\charscalex100 {log}{ }\fs2
4\cf0\f0\charscalex100\i {K}\i0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs24\cf
0\f0\charscalex100 {2}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\charscalex100 {
303}\fs24\cf0\f0\charscalex100\i {RT}\i0 \par\column\pard\li0\ri0\sl-213\slmult0
\fs24\cf0\f0\charscalex100 {42}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\chars
calex100 {28}\par\column\pard\li0\ri0\sl-213\slmult0 \fs24\cf0\f0\charscalex100
{1}\fs24\cf0\f0\charscalex100 {.}\fs24\cf0\f0\charscalex100 {91}{ }\fs24\cf0\f0\
charscalex100 {10}\par\column\pard\li0\ri0\sl-520\slmult0 \fs42\cf0\f2\charscale
x100\ul {[ ] [ ]}\ul0 {\sub \fs24\cf0\f0\charscalex100\i {S}\i0 }\fs14\cf0\f0\ch
arscalex100 {2}\fs14\cf0\f2\charscalex100 {\uc1\u8722X}\par\pard\sect\sectd\sbkn
one\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-253\slmult
0 \fs20\cf0\f1\charscalex100 {y para la reaccin global que se busca: CuS + 2Fe}{\
super \fs14\up4\cf0\f1\charscalex100 {3+}}\fs20\cf0\f2\charscalex100 {\uc1\u8660
X}\fs20\cf0\f1\charscalex100 { Cu}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\f
s20\cf0\f1\charscalex100 { + 2Fe}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs
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scalex100 {1}\fs22\cf0\f0\charscalex100 {.}\fs22\cf0\f0\charscalex100 {52}\fs22\
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rd\li586\ri0\sl-186\slmult0 \fs18\cf0\f1\charscalex100 {Se observa una difere
ncia insignificante entre ambas dos modalidades de clculo para la const
ante de }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {equilib
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fs20\cf0\f1\charscalex100 {. Las diferencias observadas en los resultados para l
os }\par\pard\li586\ri0\sl-186\slmult0 \fs20\cf0\f1\charscalex100 {dos ejemplos
analizados, se derivan de la imprecisin propia de los datos termodinmicos de parti
da, los }\par\pard\li586\ri0\sl-186\slmult0 \fs20\cf0\f1\charscalex100 {que son
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n implcito }\par\pard\li586\ri0\sl-186\slmult0 \fs20\cf0\f1\charscalex100 {un cie
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f0\f0\charscalex100 {Hidrometalurgia I }\par\pard\li586\ri0\sl-213\slmult0 \fs18
t0 \fs24\cf0\f0\charscalex100 {Interpretacin y Uso de los Diagramas Eh/pH }\par\c
olumn\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {Universidad Catoli
ca del Norte }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\m
argrsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-253\slm
ult0 \fs20\cf0\f1\charscalex100 {En esta seccin se realizar una interpretacin prctic
a del uso de los diagramas de estabilidad Eh/pH o }\par\pard\li586\ri0\sl-226\sl
mult0 \fs20\cf0\f1\charscalex100 {diagramas de Pourbaix. Para este propsito se us
arn algunos de ellos, que servirn como ejemplo. }\par\pard\li586\ri0\sl-213\slmult
0 \fs18\cf0\par\pard\li586\ri0\sl-266\slmult0 \fs20\cf0\f0\charscalex100\b {Anlis
is de la Estabilidad del Agua }\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\
par\pard\li586\ri0\sl-306\slmult0 \fs16\cf0\f1\charscalex100 {El diagrama de
la Figura 6, se observa la escasa influencia sobre el Eh, de las pr
esiones parciales de }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscal
ex100 {oxgeno e hidrgeno (PO}{\sub \fs14\cf0\f1\charscalex100 {2, }}\fs20\cf0\f
1\charscalex100 {PH}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex
100 {) desde 1 hasta 10}{\super \fs14\up4\cf0\f1\charscalex100 {3}}\fs18\cf0

\f1\charscalex100 { atmsferas, Los campos de predominancia de los }\par\pa
rd\li586\ri0\sl-200\slmult0 \fs18\cf0\f1\charscalex100 {iones o molculas relac
ionadas con la estabilidad del agua, como son el protn, H+, y el ion
hidroxilo, }\par\pard\li586\ri0\sl-253\slmult0 \fs16\cf0\f1\charscalex100 {OH, y con especies afines al agua, como son el agua oxigenada, H}{\sub
\fs12\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\charscalex100 {O}{\sub \fs12\cf0\f1
\charscalex100 {2}}\fs16\cf0\f1\charscalex100 {, y los iones perxido, HO}{\s
ub \fs12\cf0\f1\charscalex100 {2}}\fs12\cf0\f1\charscalex100 {-}\fs18\cf0\f1\cha
rscalex100 {, e }\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100
{hidruro, H}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex10
0 {. }\par\pard\li3360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3360\ri0\sl-213\s
0\par\pard\li3360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3360\ri0\sl-213\slmult
0 \fs18\cf0\par\pard\li3360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3360\ri0\sl213\slmult0 \fs18\cf0\par\pard\li3360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li33
\pard\li3360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3360\ri0\sl-213\slmult0 \fs
18\cf0\par\pard\li3360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3360\ri0\sl-213\s
0 \fs18\cf0\par\pard\li3360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3360\ri0\sl213\slmult0 \fs18\cf0\par\pard\li3360\ri0\sl-293\slmult0 \fs20\cf0\f0\charscalex
100\b {Figura 6 Campos de estabilidad del agua }\b0 \par\pard\li600\ri0\sl-213\s
lmult0 \fs18\cf0\par\pard\li600\ri0\sl-386\slmult0 \fs18\cf0\f1\charscalex100 {E
l diagrama muestra que la existencia del H}{\sub \fs12\cf0\f1\charscalex1
00 {2}}\fs18\cf0\f1\charscalex100 {O}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\
cf0\f1\charscalex100 {, HO}{\super \fs12\up4\cf0\f1\charscalex100 {2-}}\fs18\cf
0\f1\charscalex100 { y H}{\super \fs12\up4\cf0\f1\charscalex100 {-}}\fs18\cf0\
f1\charscalex100 { es termodinmicamente inestable bajo }\par\pard\li586\ri0\s
l-213\slmult0 \fs18\cf0\f1\charscalex100 {condiciones normales, y slo se seal
an en el diagrama para mostrar su campo de actividad relativo al }\par\par
d\li586\ri0\sl-253\slmult0 \fs18\cf0\f1\charscalex100 {perodo transitorio de s
u existencia. Por ejemplo, para que el H}{\sub \fs12\cf0\f1\charscalex100
{2}}\fs18\cf0\f1\charscalex100 {O}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\cf
0\f1\charscalex100 { sea estable se requerira de una }\par\pard\li600\ri0\s
l-240\slmult0 \fs20\cf0\f1\charscalex100 {presin de oxigeno mayor que 10}{\super
\fs14\up4\cf0\f1\charscalex100 {30}}\fs20\cf0\f1\charscalex100 { atm. }\par\pard
par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100\b {Anlisis de las Re
acciones Metal/Solucin }\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard
\li586\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {En la Figura 7 se ilustra
las lneas de equilibrio de algunas reacciones metal-electrolito. Se aprecia
que }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {pueden exist
ir tres mtodos para efectuar la reduccin de los iones metlicos para precipitar un m
etal: }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn
slmult0 \fs20\cf0\f1\charscalex100 {1 }\par\column\pard\li0\ri0\sl-213\slmult0 \
t0 \fs20\cf0\f1\charscalex100 {Por aplicacin de un potencial externo: el cual deb
e ser ms negativo que el potencial de media }\par\pard\sect\sectd\sbknone\pgwsxn1
1893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-226\slmult0 \fs18\cf0
\f1\charscalex100 {celda (ver Tabla VIII), ocurrir la reduccin del ion me
tlico, lo que es la base del proceso de electro-}\par\pard\li586\ri0\sl240\slmult0 \fs20\cf0\f1\charscalex100 {obtencin. }\par\pard\sect\sectd\sbknone\
pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw1306\colsr-0\co
lno2\colw9786\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {2 }\par\
column\pard\li0\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {En la Figura 7
se puede apreciar que cada metal es susceptible de ser reducido por
cualquier }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\ma
rgrsxn133\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {otro metal
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s14\cf0\f1\charscalex100 {2}}\fs14\cf0\f1\charscalex100 {0}\fs20\cf0\f1\charscal
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{1}}\fs14\cf0\f1\charscalex100 {0}\par\pard\li586\ri0\sl-266\slmult0 \*\tx9786\
fs20\cf0\f1\charscalex100 {sobre M}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs14\cf
0\f1\charscalex100 {0}\fs20\cf0\f1\charscalex100 { y es conocido como el proceso
de cementacin y queda representado por: M}{\sub \fs14\cf0\f1\charscalex100 {1}}\
fs14\cf0\f1\charscalex100 {+z1 }\fs20\cf0\f1\charscalex100 {+ [z}{\sub \fs14\cf0
\f1\charscalex100 {1}}\fs20\cf0\f1\charscalex100 {/z}{\sub \fs14\cf0\f1\charscal
ex100 {2}}\fs20\cf0\f1\charscalex100 {] M}{\sub \fs14\cf0\f1\charscalex100 {2}}\
fs14\cf0\f1\charscalex100 {0}\tab \fs20\cf0\f2\charscalex100 {\uc1\u8660X}\par\p
ard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {M}{\sub \fs14\cf0\f1\ch
arscalex100 {1}}\fs14\cf0\f1\charscalex100 {0}\fs20\cf0\f1\charscalex100 { + [z1
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s14\cf0\f1\charscalex100 {2}}\fs14\cf0\f1\charscalex100 {z2+}\fs20\cf0\f1\charsc
alex100 { donde: E}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\fs14\cf0\f1\chars
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\cf0\par\pard\li586\ri0\sl-266\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benaven
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13\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\
sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\
ard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\p
d\li0\ri0\sl-306\slmult0 \fs20\cf0\f0\charscalex100\b {Figura 7 Potencial de ele
ctrodo }\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\mar
grsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-360\slmul
t0 \fs20\cf0\f1\charscalex100 {Los procesos comerciales ms importantes que aplica
n este principio son: }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marg
lsxn666\margrsxn133\cols2\colno1\colw3000\colsr-0\colno2\colw8093\pard\li586\ri0
lex100 {Ag(CN)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {
-/Zn}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\par\pard\li586\ri0\sl-253\slmul
t0 \fs20\cf0\f1\charscalex100 {Au(CN)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs14
\cf0\f1\charscalex100 {-}{\sub \fs20\cf0\f1\charscalex100 {/Zn}}\fs14\cf0\f1\cha
rscalex100 {0}\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Cu}
{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 {/Fe}{\su
per \fs14\up4\cf0\f1\charscalex100 {0}}\par\pard\li586\ri0\sl-240\slmult0 \fs20\
cf0\f1\charscalex100 {Cu}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f
1\charscalex100 {/Ni}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\par\pard\li586\
ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Cd}{\super \fs14\up4\cf0\f1\chars
calex100 {2+}}\fs20\cf0\f1\charscalex100 {/Zn}{\super \fs14\up4\cf0\f1\charscale

x100 {0}}\par\pard\li586\ri0\sl-306\slmult0 \fs14\cf0\f1\charscalex100 {3}\par\c
0\cf0\f1\charscalex100 {Cementacin con zinc o proceso Merrill-Crowe }\par\pard\li
0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\char
scalex100 {Cementacin de cobre con chatarra de fierro }\par\pard\li0\ri0\sl-240\s
lmult0 \fs20\cf0\f1\charscalex100 {Limpieza de electrolitos de nquel previo al EO
de Ni}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\par\pard\li0\ri0\sl-240\slmul
t0 \fs20\cf0\f1\charscalex100 {Recuperacin de cadmio previo al EO de zinc }\par\p
ard\li2066\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2066\ri0\sl-253\slmult0 \fs14
\cf0\f1\charscalex100 {+z1}\fs20\cf0\f1\charscalex100 {, utilizando hidrgeno c
omo reductor, o proceso de }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn1
6840\marglsxn666\margrsxn133\pard\li1306\ri0\sl-200\slmult0 \fs20\cf0\f1\charsca
lex100 {La reduccin de metales en solucin, M}{\sub \fs14\cf0\f1\charscalex10
0 {1}}\par\pard\li600\ri0\sl-186\slmult0 \fs20\cf0\f1\charscalex100 {precipitacin
con gases. El gas hidrgeno es capaz de reducir a todos aquellos cuyo potencial e
stndar }\par\pard\li600\ri0\sl-186\slmult0 \fs18\cf0\f1\charscalex100 {es positiv
o. En condiciones estndar la cintica es lenta y la presin parcial del hidrgeno es
muy baja. }\par\pard\li600\ri0\sl-200\slmult0 \fs18\cf0\f1\charscalex100 {Por
ello, la reduccin, slo puede llevarse a cabo en autoclaves, a elevadas
presiones de H}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs18\cf0\f1\charscalex10
0 { y }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {temperatu
ras. En este caso la reaccin general es: M}{\sub \fs14\cf0\f1\charscalex100 {1}}\
fs14\cf0\f1\charscalex100 {z1+}\fs20\cf0\f1\charscalex100 { + [z}{\sub \fs14\cf0
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calex100 {2}}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100
{ M}{\sub \fs14\cf0\f1\charscalex100 {1}}\fs14\cf0\f1\charscalex100 {0}\fs20\cf0
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alex100 {H}{\super \fs14\up3\cf0\f1\charscalex100 {+ }}\par\pard\li2666\ri0\sl-2
00\b {Tabla VIII.- Potenciales estndar de media celda, a 25C }\b0 \par\pard\sect\s
ectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols5\colno1\colw37
73\colsr-0\colno2\colw1480\colsr-0\colno3\colw2706\colsr-0\colno4\colw1933\colsr
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r\pard\li1800\ri0\sl-306\slmult0 \fs16\cf0\f1\charscalex100 {Fe}{\super \fs10\up
2\cf0\f1\charscalex100 {0}}\fs16\cf0\f1\charscalex100 { <> Fe}{\super \fs10\up2\
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ri0\sl-320\slmult0 \fs18\cf0\f1\charscalex100 {Cd}{\super \fs12\up3\cf0\f1\chars
calex100 {0}}\fs18\cf0\f1\charscalex100 { <> Cd}{\super \fs12\up3\cf0\f1\charsca
lex100 {2+}}\fs18\cf0\f1\charscalex100 { + 2 e- }\par\pard\li1853\ri0\sl-306\slm
ult0 \fs18\cf0\f1\charscalex100 {ln}{\super \fs12\up3\cf0\f1\charscalex100 {0}}\
fs18\cf0\f1\charscalex100 { <> In}{\super \fs12\up3\cf0\f1\charscalex100 {3+}}\f
s18\cf0\f1\charscalex100 { + 3 e- }\par\pard\li1773\ri0\sl-306\slmult0 \fs16\cf0
\f1\charscalex100 {Co}{\super \fs10\up2\cf0\f1\charscalex100 {0}}\fs16\cf0\f1\ch
arscalex100 { <> Co}{\super \fs10\up2\cf0\f1\charscalex100 {2+}}\fs16\cf0\f1\cha
rscalex100 { + 2 e- }\par\pard\li1826\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex
100 {Ni}{\super \fs12\up2\cf0\f1\charscalex100 {0}}\fs18\cf0\f1\charscalex100 {
<> Ni}{\super \fs12\up2\cf0\f1\charscalex100 {2+}}\fs18\cf0\f1\charscalex100 { +
2 e- }\par\pard\li1786\ri0\sl-320\slmult0 \fs16\cf0\f1\charscalex100 {Pb}{\supe
r \fs10\up3\cf0\f1\charscalex100 {0}}\fs16\cf0\f1\charscalex100 { <> Pb}{\super
\fs10\up3\cf0\f1\charscalex100 {2+}}\fs16\cf0\f1\charscalex100 { + 2 e- }\par\pa
rd\li1800\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {Fe}{\super \fs12\up3\cf
0\f1\charscalex100 {0}}\fs18\cf0\f1\charscalex100 { <> Fe}{\super \fs12\up3\cf0\
f1\charscalex100 {3+}}\fs18\cf0\f1\charscalex100 { + 3 e- }\par\pard\li586\ri0\s
cf0\par\pard\li586\ri0\sl-386\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benavent

e }\par\column\pard\li0\ri0\sl-320\slmult0 \fs18\cf0\f1\charscalex100 {E}{\super
\fs12\up3\cf0\f1\charscalex100 {0}}\fs18\cf0\f1\charscalex100 {, volts }\par\pa
rd\li93\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {0,763 }\par\pard\li93\ri0
\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {0,440 }\par\pard\li93\ri0\sl-320\slm
ult0 \fs18\cf0\f1\charscalex100 {0,403 }\par\pard\li93\ri0\sl-306\slmult0 \fs18\
cf0\f1\charscalex100 {0,342 }\par\pard\li93\ri0\sl-306\slmult0 \fs18\cf0\f1\char
scalex100 {0,277 }\par\pard\li93\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {
0,250 }\par\pard\li93\ri0\sl-320\slmult0 \fs18\cf0\f1\charscalex100 {0,126 }\par
\pard\li93\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {0,036 }\par\column\par
d\li213\ri0\sl-320\slmult0 \fs16\cf0\f1\charscalex100 {Media Celda }\par\pard\li
66\ri0\sl-320\slmult0 \fs18\cf0\f1\charscalex100 {H}{\sub \fs12\cf0\f1\charscale
x100 {2}}\fs18\cf0\f1\charscalex100 { <> 2H}{\super \fs12\up3\cf0\f1\charscalex1
00 {+}}\fs18\cf0\f1\charscalex100 { + 2 e- }\par\pard\li66\ri0\sl-293\slmult0 \f
s18\cf0\f1\charscalex100 {Bi}{\super \fs12\up2\cf0\f1\charscalex100 {0}}\fs16\cf
0\f1\charscalex100 { <> Bi}{\super \fs12\up2\cf0\f1\charscalex100 {3+}}\fs18\cf0
\f1\charscalex100 { + 3 e- }\par\pard\li13\ri0\sl-320\slmult0 \fs18\cf0\f1\chars
calex100 {Cu}{\super \fs12\up3\cf0\f1\charscalex100 {0}}\fs18\cf0\f1\charscalex1
00 { <> Cu}{\super \fs12\up3\cf0\f1\charscalex100 {2+}}\fs18\cf0\f1\charscalex10
0 { + 2e- }\par\pard\li0\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {Co}{\sup
er \fs12\up3\cf0\f1\charscalex100 {0}}\fs18\cf0\f1\charscalex100 { <> Co}{\super
\fs12\up3\cf0\f1\charscalex100 {3+}}\fs18\cf0\f1\charscalex100 { + 3 e- }\par\p
ard\li93\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {Cu}{\super \fs12\up2\cf0
\f1\charscalex100 {0}}\fs18\cf0\f1\charscalex100 { <> Cu}{\super \fs12\up2\cf0\f
1\charscalex100 {+}}\fs18\cf0\f1\charscalex100 { + e- }\par{\trowd\trleft106\trk
eep\trftsWidth1\trpaddl0\trpaddr0\trpaddfl3\trpaddfr3 \clvertalt\clbrdrt\brdrnon
e\clbrdrl\brdrnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb\clNoWrap\clftsWidt
h3\clwWidth213\clpadt0\clpadr0\clpadft3\clpadfr3\cellx6240 \pard\li0\ri0\sl-306\
widctlpar\intbl \fs18\cf0\f1\charscalex100 {Ag}\cell\clvertalt\clbrdrt\brdrnone\
clbrdrl\brdrnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb\clNoWrap\clftsWidth3
\clwWidth1106\clpadt0\clpadr0\clpadft3\clpadfr3\cellx7186 \pard\li0\ri0\sl-226\w
idctlpar\intbl \fs12\cf0\f1\charscalex100 {0}\par\pard\li0\ri0\sl-80\widctlpar\i
ntbl \fs18\cf0\f1\charscalex100 { <> Ag}\fs12\cf0\f1\charscalex100 {+}\fs18\cf0\
f1\charscalex100 { + e- }\cell\row}\pard\li13\ri0\sl-320\slmult0 \fs18\cf0\f1\ch
arscalex100 {Pd}{\super \fs12\up3\cf0\f1\charscalex100 {0}}\fs18\cf0\f1\charscal
ex100 { <> Pd}{\super \fs12\up3\cf0\f1\charscalex100 {2+}}\fs18\cf0\f1\charscale
x100 { + 2 e- }\par\pard\li53\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {Pt}
{\super \fs12\up3\cf0\f1\charscalex100 {0}}\fs16\cf0\f1\charscalex100 { <> Pt}{\
super \fs12\up3\cf0\f1\charscalex100 {2+}}\fs18\cf0\f1\charscalex100 { + 2 e- }\
par\column\pard\li0\ri0\sl-320\slmult0 \fs18\cf0\f1\charscalex100 {E}{\super \fs
12\up3\cf0\f1\charscalex100 {0}}\fs18\cf0\f1\charscalex100 {, volts }\par\pard\l
i93\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {0,000 }\par\pard\li66\ri0\sl306\slmult0 \fs18\cf0\f1\charscalex100 {-0,320 }\par\pard\li66\ri0\sl-320\slmult
0 \fs18\cf0\f1\charscalex100 {-0,337 }\par\pard\li66\ri0\sl-306\slmult0 \fs18\cf
0\f1\charscalex100 {-0,400 }\par\pard\li66\ri0\sl-306\slmult0 \fs18\cf0\f1\chars
calex100 {-0,521 }\par\pard\li66\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {
-0,799 }\par\pard\li66\ri0\sl-320\slmult0 \fs18\cf0\f1\charscalex100 {-0,987 }\p
ar\pard\li66\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {-1,200 }\par\column\
rd\li0\ri0\sl-386\slmult0 \fs24\cf0\f0\charscalex100 {28 }\par\pard\sect\sectd\s
bknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sbkpage
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\fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Dado qu
e es necesario contar con un sustrato slido de partida, debe inicialme
nte proveerse un grano }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\chars
calex100 {nucleante del metal, sobre el cual se desarrollar el crecimien
to del metal depositado. }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\cha
rscalex100 {Consecuentemente, el potencial disminuye al disminuirse gradualmente
la concentracin del ion metlico. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\pa
0\cf0\f0\charscalex100\b {Anlisis de formacin de complejo Metal/Solucin }\b0 \par\p
f0\f1\charscalex100 {Cuando se requiere un diagrama de un sistema del t
ipo Me-L-H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O
lo primero se debe considerar el }\par\pard\li600\ri0\sl-240\slmult0 \fs20\
cf0\f1\charscalex100 {sistema ligando, vale decir L-H}{\sub \fs14\cf0\f1\charsca
lex100 {2}}\fs20\cf0\f1\charscalex100 {O. En nuestro caso consideraremos el sist
ema CN-H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O: }\p
ar\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols3
\colno1\colw4026\colsr-0\colno2\colw3093\colsr-0\colno3\colw3973\pard\li2613\ri0
alex100 {Reaccin }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\
li0\ri0\sl-293\slmult0 \*\tx1293\fs20\cf0\f1\charscalex100 {H}{\super \fs14\up4\
cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { + CN}{\super \fs14\up4\cf0
\f1\charscalex100 {- }}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\tab \fs20\cf0\f1
\charscalex100 {HCN }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li0\ri0\sl-266\slmult0 \fs20\cf0\f2\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\char
scalex100 {G Kcal }\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\s
l-213\slmult0 \fs20\cf0\f1\charscalex100 {-12.58 }\par\pard\sect\sectd\sbknone\p
gwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li773\ri0\sl-213\slmult0 \fs
18\cf0\par\pard\li773\ri0\sl-306\slmult0 \fs18\cf0\f1\charscalex100 {Consideremo
s el equilibrio del cido cianhdrico log Q = log [HCN] + pH - log[CN}
{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charscalex100 {], si l
og Q < log K, }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100
{implica que el cianuro se transforma en cido. log[HCN]+pH-log[CN}{\super \fs14\
up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {] < 9.3 }\par\pard\li77
3\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f1\ch
arscalex100 {Si dibujamos un diagrama Eh-pH se obtiene el diagrama de
la Figura 8 que muestra la divisin del }\par\pard\li600\ri0\sl-240\slmult0
\fs20\cf0\f1\charscalex100 {espacio en dos regiones: la existencia de HCN a pH
< 9,3 y la existencia de cianuro a pH > 9,3. }\par\pard\sect\sectd\sbknone\pgwsx
n11893\pghsxn16840\marglsxn666\margrsxn133\cols4\colno1\colw4093\colsr-0\colno2\
colw2573\colsr-0\colno3\colw1200\colsr-0\colno4\colw3226\pard\li2146\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li2146\ri0\sl-200\slmult0 \fs12\cf0\f0\charscalex100\
b {Eh (Volts)}\b0 \par\pard\li2400\ri0\sl-146\slmult0 \fs14\cf0\f0\charscalex100
\b {2.0}\b0 \par\pard\li2400\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2400\ri0\sl
-240\slmult0 \fs14\cf0\f0\charscalex100\b {1.5}\b0 \par\pard\li2400\ri0\sl-213\s
{1.0}\b0 \par\pard\li2400\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2400\ri0\sl-2
40\slmult0 \fs14\cf0\f0\charscalex100\b {0.5}\b0 \par\pard\li2400\ri0\sl-213\slm
ult0 \fs18\cf0\par\pard\li2400\ri0\sl-240\slmult0 \fs14\cf0\f0\charscalex100\b {
0.0}\b0 \par\pard\li2346\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2346\ri0\sl-240
\slmult0 \fs14\cf0\f0\charscalex100\b {-0.5}\b0 \par\pard\li2346\ri0\sl-213\slmu
lt0 \fs18\cf0\par\pard\li2346\ri0\sl-226\slmult0 \fs14\cf0\f0\charscalex100\b {1.0}\b0 \par\pard\li2346\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2346\ri0\sl-240
\slmult0 \fs14\cf0\f0\charscalex100\b {-1.5}\b0 \par\pard\li2346\ri0\sl-213\slmu
lt0 \fs18\cf0\par\pard\li2346\ri0\sl-240\slmult0 \fs14\cf0\f0\charscalex100\b {2.0}\b0 \par\column\pard\li146\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li146\ri0\s
l-200\slmult0 \fs12\cf0\f0\charscalex100\b {C - N - H2O - System at 25.00 C}\b0
20\slmult0 \fs12\cf0\f0\charscalex100\b {HCN(a)}\b0 \par\column\pard\li0\ri0\sl213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0
cf0\f0\charscalex100\b {CN(-a)}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18
ar\pard\li0\ri0\sl-160\slmult0 \fs12\cf2\f0\charscalex100\b {H 2 O L im it s}\
b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\
cols8\colno1\colw3346\colsr-0\colno2\colw720\colsr-0\colno3\colw733\colsr-0\coln
colsr-0\colno8\colw3426\pard\li2613\ri0\sl-133\slmult0 \fs14\cf0\f0\charscalex10
0\b {0}\b0 \par\column\pard\li0\ri0\sl-133\slmult0 \fs14\cf0\f0\charscalex100\b
{2}\b0 \par\column\pard\li0\ri0\sl-133\slmult0 \fs14\cf0\f0\charscalex100\b {4}\
b0 \par\column\pard\li0\ri0\sl-133\slmult0 \fs14\cf0\f0\charscalex100\b {6}\b0 \
par\column\pard\li0\ri0\sl-133\slmult0 \fs14\cf0\f0\charscalex100\b {8}\b0 \par\

column\pard\li0\ri0\sl-133\slmult0 \fs14\cf0\f0\charscalex100\b {10}\b0 \par\col
umn\pard\li0\ri0\sl-133\slmult0 \fs14\cf0\f0\charscalex100\b {12}\b0 \par\column
\pard\li0\ri0\sl-133\slmult0 \fs14\cf0\f0\charscalex100\b {14}\b0 \par\pard\sect
\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw
7400\colsr-0\colno2\colw3693\pard\li2666\ri0\sl-280\slmult0 \fs12\cf0\f0\charsca
lex100\b {C:\\HSC5\\EpH\\CN25.iep}\b0 \par\column\pard\li0\ri0\sl-280\slmult0 \f
s14\cf0\f0\charscalex100\b {
pH}\b0 \par\pard\sect\sectd\sbknone\pgwsxn11
893\pghsxn16840\marglsxn666\margrsxn133\cols3\colno1\colw4480\colsr-0\colno2\col
w1613\colsr-0\colno3\colw5000\pard\li3080\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li3080\ri0\sl-133\slmult0 \fs14\cf0\f0\charscalex100\b {ELEMENTS}\b0 \par\pard\l
i3000\ri0\sl-160\slmult0 \fs12\cf0\f0\charscalex100\b {C
}\b0 \par\pard\li3013\ri0\sl-160\slmult0 \fs10\cf0\f0\charscalex100\b {N
}\b0 \par\column\pard\li80\ri0\sl-213\slmult0 \fs18\cf0\par\par
d\li80\ri0\sl-133\slmult0 \fs12\cf0\f0\charscalex100\b {Mol al i ty}\b0 \par\par
d\li0\ri0\sl-160\slmult0 \fs14\cf0\f0\charscalex100\b { 1.000E+00}\b0 \par\pard
\li0\ri0\sl-160\slmult0 \fs14\cf0\f0\charscalex100\b { 1.000E+00}\b0 \par\colum
n\pard\li66\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li66\ri0\sl-133\slmult0 \fs12\
cf0\f0\charscalex100\b {Pre ss u re}\b0 \par\pard\li0\ri0\sl-160\slmult0 \fs14\c
f0\f0\charscalex100\b { 1.000E+00}\b0 \par\pard\li0\ri0\sl-160\slmult0 \fs14\cf
0\f0\charscalex100\b { 1.000E+00}\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\p
ghsxn16840\marglsxn666\margrsxn133\pard\li2720\ri0\sl-426\slmult0 \fs20\cf0\f0\c
harscalex100\b {Figura 8 Diagrama de Pourbaix para el sistema HCN CN}\b0 {\super
\fs14\up4\cf0\f0\charscalex100\b {-}\b0 }\par\pard\li586\ri0\sl-213\slmult0 \fs
18\cf0\par\pard\li586\ri0\sl-360\slmult0 \fs20\cf0\f1\charscalex100 {En la Figur
a 9, se muestra el equilibrio de disociacin del HCN en funcin del pH. A un pH cerc
an a 9,21 }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {la mit
ad del cianuro total se encuentra como HCN, mientras el resto se presenta como c
ianuro libre (CN}{\super \fs12\up4\cf0\f1\charscalex100 {-}}\fs18\cf0\f1\charsca
lex100 {). }\par\pard\li586\ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {A pH
10,2, ms del 90% del cianuro total se encuentra como CN}{\super \fs12
\up4\cf0\f1\charscalex100 {-}}\fs16\cf0\f1\charscalex100 { y a pH 8,4, sobr
e el 90% esta como }\par\pard\li600\ri0\sl-213\slmult0 \fs20\cf0\f1\charscal
ex100 {HCN. Esto es extremadamente importante, ya que el cido cianhdrico tiene una
presin de vapor de 100 }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscal
ex100 {kPa, a 26C por lo que se volatiliza con facilidad, con los riesgos ambien
tales y de seguridad asociados, }\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1
\charscalex100 {adems, de generar prdidas de cianuro. }\par\pard\sect\sectd\sbkno
ne\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw9893\colsr-0
\colno2\colw1200\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-2
lmult0 \fs18\cf0\par\pard\li586\ri0\sl-413\slmult0 \fs24\cf0\f0\charscalex100 {O
scar Benavente }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\r
8\cf0\par\pard\li0\ri0\sl-386\slmult0 \fs24\cf0\f0\charscalex100 {29 }\par\pard\
sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\sect\sec
td\sbkpage

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\fs18\cf0\par\pard\li773\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Se debe
analizar el comportamiento del oro en los dos subsistemas, para lueg
o, juntarlos y generar el }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f1\c
harscalex100 {diagrama completo. }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsx
n16840\marglsxn666\margrsxn133\cols2\colno1\colw1493\colsr-0\colno2\colw9600\par
\f1\charscalex100 {i) }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f1\charscale
x100 {ii) }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl
-266\slmult0 \fs20\cf0\f1\charscalex100 {Au-HCN-H}{\sub \fs14\cf0\f1\charscalex1
00 {2}}\fs20\cf0\f1\charscalex100 {O }\par\pard\li0\ri0\sl-240\slmult0 \fs20\cf
0\f1\charscalex100 {Au-CN}{\super \fs14\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f
1\charscalex100 {-H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex
100 {O }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsx
n133\pard\li773\ri0\sl-453\slmult0 \fs20\cf0\f1\charscalex100 {Las especies a
considerar son Au(OH)}\fs14\cf0\f1\charscalex100 {3(s)}\fs20\cf0\f1\charscale
x100 {, Au, Au}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charsca
lex100 { y [Au(CN)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscale
x100 {]}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {.
Es decir m=4, las que se pueden }\par\pard\li586\ri0\sl-213\slmult0 \fs2
0\cf0\f1\charscalex100 {combinar en m(m-1)/2 = 6 ecuaciones, Tabla 9. }\par\pard
\li2973\ri0\sl-346\slmult0 \fs20\cf0\f0\charscalex100\b {Tabla 9 Combinaciones p
osibles de las 4 especies }\b0 \par\pard\li5480\ri0\sl-386\slmult0 \fs20\cf0\f1\
charscalex100 {1}\fs20\cf0\f1\charscalex100 { 2 3 4 5 6 }\par\pard\sect\sec
td\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw5480
\colsr-0\colno2\colw5613\pard\li4080\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex1
00 {Au(OH)}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\pard\li4080\ri0\sl-253\slmu
lt0 \fs20\cf0\f1\charscalex100 {Au }\par\pard\li4080\ri0\sl-266\slmult0 \fs20\cf
0\f1\charscalex100 {Au+ }\par\pard\li4080\ri0\sl-280\slmult0 \fs20\cf0\f1\charsc
alex100 {[Au(CN)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100
{]- }\par\column\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {x X
x
}\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {x
x x
}\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 { X
x }\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {
x
x x }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrs
\fs18\cf0\par\pard\li773\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {En la }\
fs24\cf0\f1\charscalex100 {Tabla 10}\fs20\cf0\f1\charscalex100 { se presentan la
s ecuaciones junto con su }\fs20\cf0\f2\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\
charscalex100 {G }\par\pard\li2680\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2680
\ri0\sl-426\slmult0 \fs24\cf0\f0\charscalex100\b {Tabla 10 Ecuaciones posibles c
on su }\b0 \fs24\cf0\f2\charscalex100 {\uc1\u8710X}\fs24\cf0\f0\charscalex100\b
{G (Kcal/mol)}\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn6
66\margrsxn133\cols4\colno1\colw4120\colsr-0\colno2\colw2360\colsr-0\colno3\colw
2026\colsr-0\colno4\colw2586\pard\li2680\ri0\sl-333\slmult0 \fs20\cf0\f1\charsca
lex100 {1}\fs20\cf0\f1\charscalex100 { }\par\pard\li2680\ri0\sl-320\slmult0 \fs1
8\cf0\f1\charscalex100 {2 }\par\column\pard\li0\ri0\sl-373\slmult0 \fs20\cf0\f1\
charscalex100 {Au(OH)}\fs14\cf0\f1\charscalex100 {3(s)}\fs20\cf0\f1\charscalex10
0 { + 3H}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 {
+ 3e}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f2\charscalex100 {\uc
1\u8660X}\par\pard\li1960\ri0\sl-253\slmult0 \fs18\cf0\f2\charscalex100 {\uc1\u8
660X}\par\column\pard\li0\ri0\sl-360\slmult0 \fs20\cf0\f1\charscalex100 {Au}{\su
per \fs14\up3\cf0\f1\charscalex100 {0}}\fs20\cf0\f1\charscalex100 { + 3H}{\sub \
fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O }\par\column\pard\li
0\ri0\sl-333\slmult0 \fs20\cf0\f1\charscalex100 {-94.31 }\par\pard\sect\sectd\sb
r-0\colno2\colw2586\pard\li4120\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {A
u(OH)}\fs14\cf0\f1\charscalex100 {3(s)}\fs20\cf0\f1\charscalex100 { + 3H}{\super
\fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { + 2e}{\super \f
s14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 { Au}{\super \fs14\
up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 {+ 3H}{\sub \fs14\cf0\f1
\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O }\par\column\pard\li0\ri0\sl-18
6\slmult0 \fs20\cf0\f1\charscalex100 {-55.13 }\par\pard\sect\sectd\sbknone\pgwsx
n11893\pghsxn16840\marglsxn666\margrsxn133\pard\li2546\ri0\sl-413\slmult0 \*\tx3
080\*\tx8506\fs20\cf0\f1\charscalex100 {3A }\tab \fs20\cf0\f1\charscalex100 {Au(
OH)3 + 2HCN(a) + H(+a) +2e-}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1
\charscalex100 { Au(CN)}\fs14\cf0\f1\charscalex100 {2}\fs20\cf0\f1\charscalex10
0 {- + 3H2O }\tab \fs20\cf0\f1\charscalex100 {-83.35 }\par\pard\li2546\ri0\sl-42
6\slmult0 \fs18\cf0\f1\charscalex100 {3B Au(OH)3 + 2CN(-a) + 3H(+a) + 2e-}\fs18
\cf0\f2\charscalex100 {\uc1\u8660X}\fs18\cf0\f1\charscalex100 { Au(CN)2(-a) + 3
H2O -108.5 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\ma
rgrsxn133\cols3\colno1\colw3733\colsr-0\colno2\colw4773\colsr-0\colno3\colw2586\
pard\li2680\ri0\sl-400\slmult0 \fs20\cf0\f1\charscalex100 {4 }\par\pard\li2546\r
i0\sl-213\slmult0 \fs18\cf0\par\pard\li2546\ri0\sl-213\slmult0 \fs18\cf0\f1\char
scalex100 {5A }\par\pard\li2546\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2546\ri0
\sl-213\slmult0 \fs18\cf0\f1\charscalex100 {5B }\par\pard\li2546\ri0\sl-213\slmu
lt0 \fs18\cf0\par\pard\li2546\ri0\sl-213\slmult0 \fs18\cf0\f1\charscalex100 {6A
}\par\column\pard\li1613\ri0\sl-426\slmult0 \*\tx2746\fs20\cf0\f1\charscalex100
{Au}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 {+ e}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\tab \fs20\cf0\f1\charscalex100 {Au}{\s
uper \fs14\up4\cf0\f1\charscalex100 {0}}\par\pard\li0\ri0\sl-426\slmult0 \fs20\c
f0\f1\charscalex100 {Au(CN)2(-a) + 2H(+a) + e-}\fs20\cf0\f2\charscalex100 {\uc1\
u8660X}\fs20\cf0\f1\charscalex100 { Au}{\super \fs14\up4\cf0\f1\charscalex100 {
0}}\fs20\cf0\f1\charscalex100 { + 2HCN(a) }\par\pard\li853\ri0\sl-426\slmult0 \f
s20\cf0\f1\charscalex100 {Au(CN)2(-a) + e-}\fs20\cf0\f2\charscalex100 {\uc1\u866
0X}\fs20\cf0\f1\charscalex100 { Au}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\
fs20\cf0\f1\charscalex100 { + 2CN(-a) }\par\pard\li1480\ri0\sl-426\slmult0 \*\tx
2746\fs20\cf0\f1\charscalex100 {Au(CN)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs2
0\cf0\f1\charscalex100 {- }\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\tab \fs20\cf
0\f1\charscalex100 {Au}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\c
harscalex100 { + 2 CN}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\par\column\par
d\li0\ri0\sl-400\slmult0 \fs20\cf0\f1\charscalex100 {-39.18 }\par\pard\li0\ri0\s
00 {-10.96 }\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\s

lmult0 \fs20\cf0\f1\charscalex100 {14.20 }\par\pard\li0\ri0\sl-213\slmult0 \fs18
\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {-53.37 }\par\pa
charscalex100 {6B }\par\column\pard\li0\ri0\sl-400\slmult0 \*\tx4160\fs20\cf0\f1
\charscalex100 {Au(CN)2(-a) + 2H(+a) Au(+a) + 2HCN(a) }\tab \fs20\cf0\f1\chars
calex100 {28.22 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn66
6\margrsxn133\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li773\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {
Notar que las reacciones 1, 2 y 4 no involucran cianuro o cido cianhdrico y por lo
tanto sern vlidas en }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex1
00 {principio para todo el rango de pH. Por otra parte, las ecuaciones 3, 5 y 6
debern ser escritas para ambas }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\c
harscalex100 {formas del ligando (cianuro y cido). }\par\pard\li773\ri0\sl-213\sl
mult0 \fs18\cf0\par\pard\li773\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {Ut
ilizando los }\fs20\cf0\f2\charscalex100 {\uc1\u8710X}\fs20\cf0\f1\charscalex100
{G se obtienen las siguientes ecuaciones: }\par\pard\sect\sectd\sbknone\pgwsxn1
1893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw6760\colsr-0\colno2\co
lw4333\pard\li813\ri0\sl-453\slmult0 \fs20\cf0\f1\charscalex100 {N}{\super \fs14
\up4\cf0\f1\charscalex100 {o}}\fs20\cf0\f1\charscalex100 {Ecuacin general }\par\p
ard\li813\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li813\ri0\sl-306\slmult0 \*\tx13
60\fs20\cf0\f1\charscalex100 {1 }\tab \fs20\cf0\f2\charscalex100 {\uc1\u949X}\fs
20\cf0\f1\charscalex100 { < 1.36 \uc1\u8211X 0.019 pH }\par\pard\li813\ri0\sl-26
6\slmult0 \*\tx1360\fs20\cf0\f1\charscalex100 {2 }\tab \fs20\cf0\f2\charscalex10
0 {\uc1\u949X}\fs20\cf0\f1\charscalex100 { < 1.19 \uc1\u8211X 0.087 pH \uc1\u821
1X 0.029 log[Au}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscal
ex100 {] }\par\pard\li813\ri0\sl-266\slmult0 \*\tx1360\fs20\cf0\f1\charscalex100
{3A }\tab \fs20\cf0\f2\charscalex100 {\uc1\u949X}\fs20\cf0\f1\charscalex100 {<2
,35-0.088pH-0.29log[Au(CN)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs14\cf0\f1\cha
rscalex100 {-}\fs20\cf0\f1\charscalex100 {+0.059log[HCN] }\par\pard\li813\ri0\sl
-253\slmult0 \*\tx1360\fs20\cf0\f1\charscalex100 {3B }\tab \fs20\cf0\f2\charscal
ex100 {\uc1\u949X}\fs20\cf0\f1\charscalex100 {<1.80-0.029pH-0.029log[Au(CN)}{\su
b \fs14\cf0\f1\charscalex100 {2}}\fs14\cf0\f1\charscalex100 {-}\fs20\cf0\f1\char
scalex100 {]+ .059log[CN}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs20\cf0\f1
\charscalex100 {] }\par\pard\li813\ri0\sl-253\slmult0 \*\tx1360\fs20\cf0\f1\char
scalex100 {4 }\tab \fs20\cf0\f2\charscalex100 {\uc1\u949X}{ }\fs20\cf0\f1\charsc
alex100 {< 1.69 + 0.059log[Au+] }\par\pard\li813\ri0\sl-266\slmult0 \*\tx1360\fs
20\cf0\f1\charscalex100 {5A }\tab \fs20\cf0\f2\charscalex100 {\uc1\u949X}\fs20\c
f0\f1\charscalex100 {>0.47-0.11pH-0.11log[HCN]+0.059log[Au(CN)}{\sub \fs14\cf0\f
1\charscalex100 {2}}\fs14\cf0\f1\charscalex100 {-}{\sub \fs20\cf0\f1\charscalex1
00 {] }}\par\pard\li813\ri0\sl-266\slmult0 \*\tx1360\fs20\cf0\f1\charscalex100 {
5B }\tab \fs20\cf0\f2\charscalex100 {\uc1\u949X}{ }\fs20\cf0\f1\charscalex100 {>
6.15-0.11log[HCN]+ 0.059log[Au(CN)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs14\c
f0\f1\charscalex100 {-}{\sub \fs20\cf0\f1\charscalex100 {] }}\par\pard\li813\ri0
\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {6A }\par\pard\li813\ri0\sl-240\slmul
t0 \fs20\cf0\f1\charscalex100 {6B }\par\column\pard\li0\ri0\sl-453\slmult0 \fs20
\cf0\f1\charscalex100 { [Au] = 1M [HCN+CN}{\super \fs14\up4\cf0\f1\charscalex100
{-}}\fs20\cf0\f1\charscalex100 {]= 1M }\par\pard\li0\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li0\ri0\sl-306\slmult0 \fs20\cf0\f2\charscalex100 {\uc1\u949X}\fs20\
cf0\f1\charscalex100 { < 1.36 - 0.019 pH }\par\pard\li0\ri0\sl-266\slmult0 \fs20
\cf0\f2\charscalex100 {\uc1\u949X}\fs20\cf0\f1\charscalex100 { < 1.19- 0.087 pH
}\par\pard\li0\ri0\sl-253\slmult0 \fs20\cf0\f2\charscalex100 {\uc1\u949X}\fs20\c
f0\f1\charscalex100 { < 2,35-.088pH }\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\
f2\charscalex100 {\uc1\u949X}\fs20\cf0\f1\charscalex100 { < 1.8-0.029 pH }\par\p
ard\li0\ri0\sl-253\slmult0 \fs20\cf0\f2\charscalex100 {\uc1\u949X}\fs20\cf0\f1\c
harscalex100 { >1.69 }\par\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f2\charscalex10
0 {\uc1\u949X}\fs20\cf0\f1\charscalex100 {> 0.47-0.11pH }\par\pard\li0\ri0\sl-25
3\slmult0 \fs20\cf0\f2\charscalex100 {\uc1\u949X}\fs20\cf0\f1\charscalex100 { >6.15 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn1
33\cols2\colno1\colw9893\colsr-0\colno2\colw1200\pard\li773\ri0\sl-213\slmult0 \
fs18\cf0\par\pard\li773\ri0\sl-320\slmult0 \fs20\cf0\f1\charscalex100 {Notar que
para la eq 6A, log Q = log [Au}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20
\cf0\f1\charscalex100 {] + 2log[CN}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\f
s20\cf0\f1\charscalex100 {]-log[Au(CN)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs1
4\cf0\f1\charscalex100 {-}{\sub \fs20\cf0\f1\charscalex100 {] }}\par\pard\li586\
\f0\charscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmult0 \fs1
lt0 \fs18\cf0\par\pard\li0\ri0\sl-320\slmult0 \fs24\cf0\f0\charscalex100 {31 }\p
ar\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\
sect\sectd\sbkpage
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slmult0 \fs20\cf0\f1\charscalex100 {En equilibrio [Au}{\super \fs14\up3\cf0\f1\c
harscalex100 {+}}\fs20\cf0\f1\charscalex100 {] = [Au(CN)}{\sub \fs14\cf0\f1\char
scalex100 {2}}\fs14\cf0\f1\charscalex100 {-}\fs20\cf0\f1\charscalex100 {], restr
iccin que implica que ninguna especie es ms estable que la otra, o }\par\pard\li60
0\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {sea, que en el equilibrio ambas

concentraciones son iguales. }\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\
pard\li773\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Au}{\super \fs14\up3\c
f0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { se convertira en Au(CN)}{\s
ub \fs14\cf0\f1\charscalex100 {2}}\fs14\cf0\f1\charscalex100 {-}\fs20\cf0\f1\cha
rscalex100 { si log Q < log K }\par\pard\li773\ri0\sl-466\slmult0 \fs20\cf0\f1\
charscalex100 {Las ecuaciones 6A y 6B revelan que el Au}{\super \fs14\up4\cf0\f1
\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { es inestable con respecto a Au(C
N)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs14\cf0\f1\charscalex100 {-}{\sub \fs2
0\cf0\f1\charscalex100 {. }}\par\pard\li773\ri0\sl-440\slmult0 \fs20\cf0\f1\char
scalex100 {Por lo tanto todas las ecuaciones que involucran Au}{\super \fs14\up4
\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { (1, 2, 4, 6A y 6B) pueden
ser descartadas. }\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\
ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Las ecuaciones 3A y 5A son vlidas
para pH < 9.3, las ecuaciones 3B y 5B son validas para pH > 9.3. }\par\pard\li77
3\ri0\sl-466\slmult0 \fs20\cf0\f1\charscalex100 {Para la presencia de Au(CN)
}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs14\cf0\f1\charscalex100 {-}\fs20\cf0\f1
\charscalex100 { y Au(OH)}{\sub \fs14\cf0\f1\charscalex100 {3,}}\fs18\cf0\f1\c
harscalex100 {la estabilidad relativa entre estas especies, esta dada po
r la }\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {ecuacin 3A
, de acuerdo a la cual Au(OH)}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs20\c
f0\f1\charscalex100 { es inestable bajo 3A. Por otra parte, Au es ines
table con }\par\pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {respe
cto a Au(CN)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs14\cf0\f1\charscalex100 {-}
\fs20\cf0\f1\charscalex100 { sobre lnea 5A. Con similar razonamiento se elimina l
a lnea en la regin de pH > 9.3. }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16
840\marglsxn666\margrsxn133\cols3\colno1\colw4280\colsr-0\colno2\colw3520\colsr0\colno3\colw3293\pard\li2240\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2240\ri0\s
l-173\slmult0 \fs12\cf0\f0\charscalex100\b {Eh (Volts)}\b0 \par\pard\li2480\ri0\
sl-160\slmult0 \fs14\cf0\f0\charscalex100\b {2.0}\b0 \par\pard\li2480\ri0\sl-213
\b {1.5}\b0 \par\pard\li2480\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2480\ri0\sl
-226\slmult0 \fs14\cf0\f0\charscalex100\b {1.0}\b0 \par\pard\li2480\ri0\sl-213\s
{0.5}\b0 \par\pard\li2480\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2480\ri0\sl-2
26\slmult0 \fs14\cf0\f0\charscalex100\b {0.0}\b0 \par\pard\li2426\ri0\sl-213\slm
-0.5}\b0 \par\pard\li2426\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2426\ri0\sl-21
3\slmult0 \fs14\cf0\f0\charscalex100\b {-1.0}\b0 \par\pard\li2426\ri0\sl-213\slm
-1.5}\b0 \par\pard\li2426\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2426\ri0\sl-22
6\slmult0 \fs14\cf0\f0\charscalex100\b {-2.0}\b0 \par\column\pard\li0\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-173\slmult0 \fs12\cf0\f0\charscalex100\b
{Au - C - N - H2O - System at 25.00 C}\b0 \par\pard\li653\ri0\sl-226\slmult0 \fs
12\cf0\f0\charscalex100\b {Au(OH)3}\b0 \par\pard\li560\ri0\sl-213\slmult0 \fs18\
0 \fs18\cf0\par\pard\li560\ri0\sl-213\slmult0 \fs12\cf0\f0\charscalex100\b {Au(C
N)2(-a)}\b0 \par\pard\li826\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li826\ri0\sl-2
fs18\cf0\par\pard\li826\ri0\sl-133\slmult0 \fs14\cf0\f0\charscalex100\b {Au}\b0
\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult

0\par\pard\li0\ri0\sl-240\slmult0 \fs12\cf2\f0\charscalex100\b {H 2 O L im it
s}\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn1
33\cols8\colno1\colw3400\colsr-0\colno2\colw706\colsr-0\colno3\colw706\colsr-0\c
olno4\colw706\colsr-0\colno5\colw666\colsr-0\colno6\colw706\colsr-0\colno7\colw7
06\colsr-0\colno8\colw3493\pard\li2693\ri0\sl-120\slmult0 \fs14\cf0\f0\charscale
x100\b {0}\b0 \par\column\pard\li0\ri0\sl-120\slmult0 \fs14\cf0\f0\charscalex100
\b {2}\b0 \par\column\pard\li0\ri0\sl-120\slmult0 \fs14\cf0\f0\charscalex100\b {
4}\b0 \par\column\pard\li0\ri0\sl-120\slmult0 \fs14\cf0\f0\charscalex100\b {6}\b
0 \par\column\pard\li0\ri0\sl-120\slmult0 \fs14\cf0\f0\charscalex100\b {8}\b0 \p
ar\column\pard\li0\ri0\sl-120\slmult0 \fs14\cf0\f0\charscalex100\b {10}\b0 \par\
column\pard\li0\ri0\sl-120\slmult0 \fs14\cf0\f0\charscalex100\b {12}\b0 \par\col
umn\pard\li0\ri0\sl-120\slmult0 \fs14\cf0\f0\charscalex100\b {14}\b0 \par\pard\s
olw7333\colsr-0\colno2\colw3760\pard\li2746\ri0\sl-266\slmult0 \fs12\cf0\f0\char
scalex100\b {C:\\HSC5\\EpH\\AuCN25.iep}\b0 \par\column\pard\li0\ri0\sl-266\slmul
t0 \fs14\cf0\f0\charscalex100\b {
pH}\b0 \par\pard\sect\sectd\sbknone\pgw
sxn11893\pghsxn16840\marglsxn666\margrsxn133\cols3\colno1\colw4506\colsr-0\colno
2\colw1560\colsr-0\colno3\colw5026\pard\li3146\ri0\sl-213\slmult0 \fs18\cf0\par\
pard\li3146\ri0\sl-133\slmult0 \fs12\cf0\f0\charscalex100\b {ELEMENTS}\b0 \par\p
ard\li3053\ri0\sl-160\slmult0 \fs12\cf0\f0\charscalex100\b {Au
}\b0 \par\pard\li3066\ri0\sl-160\slmult0 \fs12\cf0\f0\charscalex100\b {C
}\b0 \par\pard\li3080\ri0\sl-160\slmult0 \fs12\cf0\f0\cha
rscalex100\b {N
}\b0 \par\column\pard\li80\ri0\sl-213\slm
ult0 \fs18\cf0\par\pard\li80\ri0\sl-133\slmult0 \fs12\cf0\f0\charscalex100\b {Mo
l al i ty}\b0 \par\pard\li0\ri0\sl-160\slmult0 \fs12\cf0\f0\charscalex100\b { 1
.000E+00}\b0 \par\pard\li0\ri0\sl-160\slmult0 \fs12\cf0\f0\charscalex100\b { 1.
000E+00}\b0 \par\pard\li0\ri0\sl-160\slmult0 \fs12\cf0\f0\charscalex100\b { 1.0
00E+00}\b0 \par\column\pard\li80\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li80\ri0\
sl-133\slmult0 \fs12\cf0\f0\charscalex100\b {Pre s su re}\b0 \par\pard\li0\ri0\s
l-160\slmult0 \fs12\cf0\f0\charscalex100\b { 1.000E+00}\b0 \par\pard\li0\ri0\sl
-160\slmult0 \fs12\cf0\f0\charscalex100\b { 1.000E+00}\b0 \par\pard\li0\ri0\sl160\slmult0 \fs12\cf0\f0\charscalex100\b { 1.000E+00}\b0 \par\pard\sect\sectd\s
bknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li3053\ri0\sl-213\sl
mult0 \fs18\cf0\par\pard\li3053\ri0\sl-213\slmult0 \fs20\cf0\f0\charscalex100\b
{Figura 11 }\b0 \fs20\cf0\f1\charscalex100 {Diagrama Eh-pH para Au-CN-H}{\sub \f
s14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O a 25C }\par\pard\li773
rscalex100 {Como vemos la adicin de cianuro causa una gran regin de estabilidad de
l complejo Au(CN)}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs14\cf0\f1\charscalex10
0 {-}\fs20\cf0\f1\charscalex100 { a lo largo }\par\pard\li586\ri0\sl-226\slmult0
\fs20\cf0\f1\charscalex100 {de todo el rango de pH. }\par\pard\li586\ri0\sl-213
0\sl-266\slmult0 \fs20\cf0\f0\charscalex100\b {Anlisis de las Reacciones Oxido de
l Metal-Solucin }\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\
ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {En los diagramas Eh/pH, las
posibilidades de disolver un metal puede representarse grficamente de }\p
ar\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {acuerdo a la def
inicin de lmites que se hayan usado. As, para que exista el equilibrio
entre un in }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {me
tlico disuelto, o un complejo de ion metlico, debe especificarse la concentracin lmi
te de los iones }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {
en la solucin. Pourbaix define como la actividad mnima para la disolucin de especie
s el valor de 10}{\super \fs14\up4\cf0\f1\charscalex100 {-6}}\fs20\cf0\f1\charsc
alex100 {. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\f1\charscalex100 {Sin
embargo, cuando se desea lograr la disolucin, como ocurre en la extrac
cin hidrometalurgica, un }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\chars
calex100 {valor mnimo para la concentracin es de 10}{\super \fs14\up3\cf0\f1\chars
calex100 {-3}}\fs20\cf0\f1\charscalex100 { molar, la zona intermedia, comprendid
as entre 10}{\super \fs14\up3\cf0\f1\charscalex100 {-3}}\fs20\cf0\f1\charscalex1

00 { y 10}{\super \fs14\up3\cf0\f1\charscalex100 {-6}}\par\pard\li586\ri0\sl-240
\slmult0 \fs20\cf0\f1\charscalex100 {molar , representan condiciones que dan com
o resultado la corrosin. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\l
i586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {La Figura 12 presenta un
diagrama Eh/pH para el sistema Cu-O-H}{\sub \fs14\cf0\f1\charscalex100 {2
}}\fs20\cf0\f1\charscalex100 {O, muestran las regiones de }\par\pard\li586\r
i0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {pasivacin y disolucin. Los valor
es del logaritmo de las concentraciones para las especies solubles }\pa
r\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {estn indicados sobr
e los lmites. Pourbaix ha publicado gran cantidad de diagramas similare
s, de alto }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {gra
do de detalle, para muchos otros sistemas metal-Oxgeno de gran importan
cia y que muestran las }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840
\marglsxn666\margrsxn133\cols2\colno1\colw9893\colsr-0\colno2\colw1200\pard\li58
f0\f0\charscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmult0 \f
0 \fs18\cf0\par\pard\li0\ri0\sl-346\slmult0 \fs24\cf0\f0\charscalex100 {32 }\par
\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\se
ct\sectd\sbkpage
7;32768}}
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\fs18\cf0\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {condicio
nes que conducen a la corrosin o bien a la formacin de pelculas oxidadas, las cuale
s actan }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {como prot
ectoras superficiales a causa y como resultado de dicha pasivacin. }\par\pard\sec
w2760\colsr-0\colno2\colw733\colsr-0\colno3\colw2280\colsr-0\colno4\colw5320\par
f0\f0\charscalex100\b {Eh (Volts)}\b0 \par\pard\li1600\ri0\sl-186\slmult0 \fs16\
cf0\f0\charscalex100\b {1.2}\b0 \par\pard\li1600\ri0\sl-213\slmult0 \fs18\cf0\pa
r\pard\li1600\ri0\sl-186\slmult0 \fs16\cf0\f0\charscalex100\b {1.0}\b0 \par\pard
0\f0\charscalex100\b {0.8}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\
0 \fs16\cf0\f0\charscalex100\b {Cu(+2a)}\b0 \par\column\pard\li0\ri0\sl-213\slmu
lt0 \fs18\cf0\par\pard\li0\ri0\sl-240\slmult0 \fs12\cf0\f0\charscalex100\b {Cu H2O - System at 25.00 C}\b0 \par\pard\li306\ri0\sl-213\slmult0 \fs18\cf0\par\pa
\fs10\cf3\f0\charscalex100 {-03}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf
lt0 \fs16\cf0\f0\charscalex100\b {CuO}\b0 \par\pard\sect\sectd\sbknone\pgwsxn118
93\pghsxn16840\marglsxn666\margrsxn133\cols7\colno1\colw2493\colsr-0\colno2\colw
933\colsr-0\colno3\colw693\colsr-0\colno4\colw320\colsr-0\colno5\colw520\colsr-0
\colno6\colw2240\colsr-0\colno7\colw3893\pard\li1600\ri0\sl-333\slmult0 \fs16\cf
0\f0\charscalex100\b {0.6}\b0 \par\pard\li1600\ri0\sl-213\slmult0 \fs18\cf0\par\
pard\li1600\ri0\sl-173\slmult0 \fs14\cf0\f0\charscalex100\b {0.4}\b0 \par\column
\cf0\par\pard\li0\ri0\sl-120\slmult0 \fs10\cf3\f0\charscalex100 {-03}\par\column
\cf3\f0\charscalex100 {-03}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par
\par\pard\li0\ri0\sl-226\slmult0 \fs10\cf3\f0\charscalex100 {-03}\par\column\par
d\li0\ri0\sl-80\slmult0 \fs10\cf3\f0\charscalex100 {-06}\par\column\pard\li0\ri0
\sl-80\slmult0 \fs10\cf3\f0\charscalex100 {-03}\par\column\pard\li0\ri0\sl-266\s
lmult0 \fs12\cf0\f0\charscalex100\b {CuO2(-2a)}\b0 \par\pard\li293\ri0\sl-173\sl
mult0 \fs10\cf3\f0\charscalex100 {-06}\par\pard\sect\sectd\sbknone\pgwsxn11893\p
ghsxn16840\marglsxn666\margrsxn133\cols15\colno1\colw1920\colsr-0\colno2\colw853
\colsr-0\colno3\colw600\colsr-0\colno4\colw266\colsr-0\colno5\colw426\colsr-0\co
3\colsr-0\colno10\colw213\colsr-0\colno11\colw866\colsr-0\colno12\colw680\colsr0\colno13\colw186\colsr-0\colno14\colw240\colsr-0\colno15\colw2933\pard\li1600\r
i0\sl-146\slmult0 \fs14\cf0\f0\charscalex100\b {0.2}\b0 \par\pard\li1600\ri0\sl213\slmult0 \fs18\cf0\par\pard\li1600\ri0\sl-173\slmult0 \fs14\cf0\f0\charscalex
100\b {0.0}\b0 \par\pard\li1533\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1533\ri0
\sl-160\slmult0 \fs14\cf0\f0\charscalex100\b {-0.2}\b0 \par\pard\li1533\ri0\sl-2
00\b {-0.4}\b0 \par\pard\li1533\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1533\ri0
\sl-173\slmult0 \fs14\cf0\f0\charscalex100\b {-0.6}\b0 \par\pard\li1533\ri0\sl-2
00\b {-0.8}\b0 \par\pard\li1533\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1533\ri0
\sl-173\slmult0 \fs14\cf0\f0\charscalex100\b {-1.0}\b0 \par\column\pard\li0\ri0\

16\cf0\f0\charscalex100\b {1}\b0 \par\column\pard\li40\ri0\sl-173\slmult0 \fs10\
cf3\f0\charscalex100 {-06}\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li
fs18\cf0\par\pard\li0\ri0\sl-160\slmult0 \fs16\cf0\f0\charscalex100\b {3}\b0 \pa
r\column\pard\li0\ri0\sl-93\slmult0 \fs10\cf3\f0\charscalex100 {-03}\par\column\
3\slmult0 \fs16\cf0\f0\charscalex100\b {5}\b0 \par\column\pard\li0\ri0\sl-133\sl
mult0 \*\tx173\fs10\cf3\f0\charscalex100 {-06}\tab \fs16\cf0\f0\charscalex100\b
{Cu2O}\b0 \par\pard\li440\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li440\ri0\sl-213
ult0 \fs18\cf0\par\pard\li440\ri0\sl-200\slmult0 \fs16\cf0\f0\charscalex100\b {7
}\b0 \par\column\pard\li93\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li93\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li93\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li93\ri0\
sl-213\slmult0 \fs18\cf0\par\pard\li93\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li9
3\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li93\ri0\sl-133\slmult0 \fs10\cf3\f0\cha
rscalex100 {-03}\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-2
66\slmult0 \fs16\cf0\f0\charscalex100\b {Cu}\b0 \par\column\pard\li0\ri0\sl-213\
f0\charscalex100\b {9}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\
par\pard\li0\ri0\sl-106\slmult0 \fs10\cf3\f0\charscalex100 {-06}\par\column\pard
harscalex100 {-06}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0
s18\cf0\par\pard\li0\ri0\sl-333\slmult0 \fs16\cf0\f0\charscalex100\b {11}\b0 \pa
r\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \
ri0\sl-333\slmult0 \fs16\cf0\f0\charscalex100\b {13}\b0 \par\column\pard\li0\ri0

\li0\ri0\sl-133\slmult0 \fs10\cf3\f0\charscalex100 {-06}\par\column\pard\li0\ri0
s16\cf0\f0\charscalex100\b {15}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18
13\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-280\slmult0 \fs12\cf2\f0\charscalex100\
b {H 2 O lim it s}\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\mar
glsxn666\margrsxn133\cols2\colno1\colw7546\colsr-0\colno2\colw3546\pard\li1920\r
i0\sl-266\slmult0 \fs14\cf0\f0\charscalex100\b {C:\\HSC5\\EpH\\Cu25.iep}\b0 \par
\column\pard\li0\ri0\sl-266\slmult0 \fs16\cf0\f0\charscalex100\b {
pH}\b0
\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\co
ls3\colno1\colw4160\colsr-0\colno2\colw1893\colsr-0\colno3\colw5040\pard\li2466\
ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2466\ri0\sl-213\slmult0 \fs16\cf0\f0\cha
rscalex100\b {ELEMENTS}\b0 \par\pard\li2346\ri0\sl-186\slmult0 \fs16\cf0\f0\char
scalex100\b {C u
}\b0 \par\column\pard\li80\ri0\sl-213\sl
mult0 \fs18\cf0\par\pard\li80\ri0\sl-213\slmult0 \fs14\cf0\f0\charscalex100\b {M
ol al i ty}\b0 \par\pard\li0\ri0\sl-186\slmult0 \fs16\cf0\f0\charscalex100\b {
Vari abl e }\b0 \par\column\pard\li80\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li8
0\ri0\sl-213\slmult0 \fs12\cf0\f0\charscalex100\b {Pre s su re}\b0 \par\pard\li0
\ri0\sl-186\slmult0 \fs16\cf0\f0\charscalex100\b { 1.000E+00}\b0 \par\pard\sect
\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li3613\ri0\s
l-213\slmult0 \fs18\cf0\par\pard\li3613\ri0\sl-240\slmult0 \fs20\cf0\f0\charscal
ex100\b {Figura 12 Sistema Cu-O-H}\b0 {\sub \fs14\cf0\f0\charscalex100\b {2}\b0
}\fs20\cf0\f0\charscalex100\b {O a 25C }\b0 \par\pard\li586\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-373\sl
mult0 \fs20\cf0\f0\charscalex100\b {Anlisis de las Reacciones Sulfuro del Metal-S
olucin }\b0 \par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-32
0\slmult0 \fs20\cf0\f1\charscalex100 {En la Figura 13 se presenta un diagrama Eh
/pH, a 25C, para el sistema S-O-H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\
f1\charscalex100 {O, las especies estables }\par\pard\li586\ri0\sl-253\slmult0 \
fs20\cf0\f1\charscalex100 {son: SO}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs14\cf
0\f1\charscalex100 {2-}\fs20\cf0\f1\charscalex100 {, HSO}{\sub \fs14\cf0\f1\char
scalex100 {4}}\fs14\cf0\f1\charscalex100 {-}{\sub \fs20\cf0\f1\charscalex100 {,
H}}\fs14\cf0\f1\charscalex100 {2}\fs20\cf0\f1\charscalex100 {S, HS}{\super \fs14
\up3\cf0\f1\charscalex100 {-}}\fs20\cf0\f1\charscalex100 {, S}{\super \fs14\up3\
cf0\f1\charscalex100 {2-}}\fs20\cf0\f1\charscalex100 { y S}{\super \fs14\up3\cf0
\f1\charscalex100 {0}}\fs20\cf0\f1\charscalex100 {. }\par\pard\li586\ri0\sl-213
{El diagrama se ha dividido en cuadrantes, se observa que en la zona oxidante, t
anto alcalina como acida, }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\chars
calex100 {el SO}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs14\cf0\f1\charscalex100
{2-}\fs20\cf0\f1\charscalex100 { es estable, excepto en condiciones de pH < 2 do
nde es estable el ion, HSO}{\sub \fs14\cf0\f1\charscalex100 {4}}\fs14\cf0\f1\cha
rscalex100 {-}\fs20\cf0\f1\charscalex100 {. En cambio, en la }\par\pard\li600\ri
0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {zona reductora predominan especies
derivadas del azufre de carcter reductor: H}{\sub \fs14\cf0\f1\charscalex100 {2}}
\fs20\cf0\f1\charscalex100 {S, HS}{\super \fs14\up4\cf0\f1\charscalex100 {-}}\fs
20\cf0\f1\charscalex100 {, S}{\super \fs14\up4\cf0\f1\charscalex100 {2-}}\fs20\c
f0\f1\charscalex100 {. A su vez el }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0
\f1\charscalex100 {S}{\super \fs12\up4\cf0\f1\charscalex100 {0}}\fs18\cf0\f1\cha
rscalex100 { es estable slo bajo condiciones moderadamente oxidantes y m

oderadamente reductoras pero }\par\pard\li600\ri0\sl-186\slmult0 \fs20\cf0\f1\
charscalex100 {siempre a pH < 8. }\par\pard\li600\ri0\sl-440\slmult0 \fs18\cf0\f
1\charscalex100 {Durante la disolucin de minerales sulfurados, en condiciones cida
s, se forman capas de S}{\super \fs12\up3\cf0\f1\charscalex100 {0}}\fs18\cf0\f1\
charscalex100 {, pero no se }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\cha
rscalex100 {observan otras especies intermedias de azufre, tales como disulfatos
o sulfitos. En cambio, en soluciones }\par\pard\li586\ri0\sl-226\slmult0 \fs20\
cf0\f1\charscalex100 {bsicas, durante la oxidacin de compuestos sulfurados
se forman diversos compuestos intermedios }\par\pard\li586\ri0\sl-226\slmult
0 \fs20\cf0\f1\charscalex100 {meta-estables de azufre, tales como tiosulfatos, d
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fs18\cf0\par\pard\li0\ri0\sl-266\slmult0 \fs24\cf0\f0\charscalex100 {33 }\par\pa
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colno3\colw4986\pard\li586\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {Hidrom
etalurgia I }\par\pard\li1546\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1546\ri0\s
ex100\b {Eh (Volts)}\b0 \par\pard\li1826\ri0\sl-173\slmult0 \fs16\cf0\f0\charsca
lex100\b {1.0}\b0 \par\pard\li1826\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1826\
ri0\sl-200\slmult0 \fs16\cf0\f0\charscalex100\b {0.8}\b0 \par\pard\li2200\ri0\sl
-146\slmult0 \fs12\cf0\f0\charscalex100\b {HSO4(-a)}\b0 \par\pard\li1826\ri0\sl253\slmult0 \fs16\cf0\f0\charscalex100\b {0.6}\b0 \par\pard\li1826\ri0\sl-213\sl
mult0 \fs18\cf0\par\pard\li1826\ri0\sl-200\slmult0 \fs16\cf0\f0\charscalex100\b
{0.4}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-2
sl-320\slmult0 \fs12\cf0\f0\charscalex100\b {S - H2O - System at 25.00 C}\b0 \pa
s18\cf0\par\pard\li1173\ri0\sl-333\slmult0 \fs12\cf0\f0\charscalex100\b {SO4(-2a
)}\b0 \par\column\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {Univer
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14\cf0\f0\charscalex100\b {-1.0}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs1
8\cf0\par\pard\li0\ri0\sl-226\slmult0 \fs16\cf0\f0\charscalex100\b {S}\b0 \par\c
slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl146\slmult0 \fs16\cf0\f0\charscalex100\b {H2S(a)}\b0 \par\column\pard\li0\ri0\sl
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sl-146\slmult0 \fs16\cf0\f0\charscalex100\b {4}\b0 \par\column\pard\li0\ri0\sl-1
46\slmult0 \fs16\cf0\f0\charscalex100\b {6}\b0 \par\column\pard\li0\ri0\sl-146\s
lmult0 \fs16\cf0\f0\charscalex100\b {8}\b0 \par\column\pard\li0\ri0\sl-146\slmul
t0 \fs16\cf0\f0\charscalex100\b {10}\b0 \par\column\pard\li0\ri0\sl-146\slmult0
\fs16\cf0\f0\charscalex100\b {12}\b0 \par\column\pard\li0\ri0\sl-146\slmult0 \fs
16\cf0\f0\charscalex100\b {14}\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsx
n16840\marglsxn666\margrsxn133\cols3\colno1\colw3680\colsr-0\colno2\colw3813\col
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{C:\\HSC5\\EpH\\S25.iep}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\p
f0\par\pard\li0\ri0\sl-200\slmult0 \fs20\cf0\f0\charscalex100\b {Figura 13 Siste
ma S-O-H}\b0 {\sub \fs14\cf0\f0\charscalex100\b {2}\b0 }\fs20\cf0\f0\charscalex1
00\b {O a 25C }\b0 \par\column\pard\li0\ri0\sl-320\slmult0 \fs16\cf0\f0\charscale
x100\b {
pH}\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marg
lsxn666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\s
x100\b {Uso del Diagrama Eh/pH del Sistema Cu-O-S-H}\b0 {\sub \fs14\cf0\f0\chars
calex100\b {2}\b0 }\fs20\cf0\f0\charscalex100\b {O para la Disolucin de Cu}\b0 {\
sub \fs14\cf0\f0\charscalex100\b {2}\b0 }\fs20\cf0\f0\charscalex100\b {S }\b0 \p
18\cf0\f1\charscalex100 {Los diagramas Eh/pH pueden predecir las relacione
s de estabilidad y las secuencias de formacin de }\par\pard\li600\ri0\sl240\slmult0 \fs18\cf0\f1\charscalex100 {capas superficiales, a medida que progre
san las reacciones de disolucin, en la Figura 14 se presenta el }\par\pard\li600\
ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {sistema Cu-O-S-H}{\sub \fs14\cf0
\f1\charscalex100 {2}}\fs18\cf0\f1\charscalex100 {O, a 25C, asumiendo que la
concentracin molar para todas las especies disueltas }\par\pard\li600\ri0
\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {con contenido de azufre, es de 10}{\
super \fs12\up3\cf0\f1\charscalex100 {-1}}\fs18\cf0\f1\charscalex100 { molar. La
s reas de estabilidad para la calcosina, Cu}{\sub \fs12\cf0\f1\charscalex100 {2}}
\fs18\cf0\f1\charscalex100 {S, y la covelina, }\par\pard\li586\ri0\sl-240\slmult
0 \fs20\cf0\f1\charscalex100 {CuS, indican que la formacin de pelculas de producto
s slidos superficiales de S}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\fs20\cf0\
f1\charscalex100 { no se producir en la }\par\pard\li586\ri0\sl-253\slmult0 \fs18
\cf0\f1\charscalex100 {superficie del Cu}{\sub \fs12\cf0\f1\charscalex100 {2}}
\fs18\cf0\f1\charscalex100 {S, ya que la reaccin: Cu}{\sub \fs12\cf0\f1\char
scalex100 {2}}\fs18\cf0\f1\charscalex100 {S + S}{\super \fs12\up4\cf0\f1\chars
calex100 {0}}\fs18\cf0\f2\charscalex100 {\uc1\u8660X}\fs18\cf0\f1\charscalex100
{ 2 CuS es termodinmicamente favorable. En }\par\pard\li586\ri0\sl-186\slmu
lt0 \fs18\cf0\f1\charscalex100 {cambio, se puede predecir que la secuencia
de formacin de capas superficiales en la superficie del }\par\pard\li58
6\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Cu}{\sub \fs14\cf0\f1\charscale
x100 {2}}\fs20\cf0\f1\charscalex100 {S ser la siguiente Cu}{\sub \fs14\cf0\f1\cha
rscalex100 {2}}\fs20\cf0\f1\charscalex100 {S/CuS/S}{\super \fs14\up3\cf0\f1\char
scalex100 {0}}\fs20\cf0\f1\charscalex100 {. }\par\pard\li600\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li600\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {Cuando
el Cu}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {S se encu
entre en una solucin acuosa de alto potencial de oxidacin, ste reaccionar, }\par\p
ard\li586\ri0\sl-213\slmult0 \fs20\cf0\f1\charscalex100 {bajando el potencial y
en la formacin de capas de covelina porosa, CuS, sobre el sustrato de calcosina,
}\par\pard\li586\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {Cu}{\sub \fs14\c
f0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {S, como subproducto inicial.
La reaccin andica es: Cu}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charsc
alex100 {S }\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 {
CuS + Cu}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100
{ + 2e- }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-226
\slmult0 \fs20\cf0\f1\charscalex100 {Si el oxdante es oxgeno, la reaccin catdica con
sumir iones de hidrgeno en la superficie de acuerdo }\par\pard\li586\ri0\sl-266\sl
mult0 \fs20\cf0\f1\charscalex100 {con las siguientes reacciones: 1/2O}{\sub \fs1
4\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 { + 2H}{\super \fs14\up3\c
f0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { + 2e}{\super \fs14\up3\cf0\
f1\charscalex100 {-}}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charsc
alex100 { H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O }
\par\pard\li600\ri0\sl-466\slmult0 \fs20\cf0\f1\charscalex100 {En cambio, si el
par catdico involucro el frrico, se tendr la formacin de ferroso: 2Fe}{\super \fs14\
up4\cf0\f1\charscalex100 {3+}}\fs20\cf0\f1\charscalex100 {+ 2e}{\super \fs14\up4
\cf0\f1\charscalex100 {-}}\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\c
harscalex100 { 2Fe}{\super \fs14\up4\cf0\f1\charscalex100 {2+}}\par\pard\li586\r
i0\sl-440\slmult0 \fs18\cf0\f1\charscalex100 {La formacin de S}{\super \fs12\up3\
cf0\f1\charscalex100 {0}}\fs18\cf0\f1\charscalex100 { sobre la superficie de la
covelina porosa se produce en forma de capas superficiales, }\par\pard\li600\ri0
\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {no conductoras, y ocurre segn la reac
cin: CuS }\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 { Cu
}{\super \fs14\up4\cf0\f1\charscalex100 {+2}}\fs20\cf0\f1\charscalex100 { + S}{\
super \fs14\up4\cf0\f1\charscalex100 {0}}\fs20\cf0\f1\charscalex100 { + 2e}{\sup

er \fs14\up4\cf0\f1\charscalex100 {- }}\par\pard\li586\ri0\sl-213\slmult0 \fs18\
cf0\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {La reaccin in
icial (1) ocurre en el lmite superficial i, con la formacin de covelin
a, CuS, en forma de }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charsca
lex100 {capas porosas, permitiendo la salida por difusin de iones cpricos, Cu}{\
super \fs14\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 { y la co
nduccin de electrones }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex
100 {hacia el lmite superficial ii, donde el oxidante (sea oxgeno, O}{\sub \fs14\c
f0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {, o Fe}{\super \fs14\up4\cf0
\f1\charscalex100 {3+}}\fs20\cf0\f1\charscalex100 { es reducido producindose agua
, }\par\pard\li586\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {H}{\sub \fs14\
cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O, e iones, Fe}{\super \fs1
4\up4\cf0\f1\charscalex100 {2+}}\fs20\cf0\f1\charscalex100 { respectivamente. El
potencial es estabilizado por la reaccin de estado estacionario en }\par\pard\li
586\ri0\sl-186\slmult0 \fs20\cf0\f1\charscalex100 {la superficie lmite }\par\pard
f1\charscalex100 {Tan pronto como el Cu}{\sub \fs12\cf0\f1\charscalex100 {2}}\fs
18\cf0\f1\charscalex100 {S ha reaccionado completamente, decaer el potencial, lo
que da como resultado }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscale
x100 {la formacin de una capa de S}{\super \fs14\up4\cf0\f1\charscalex100 {0}}\fs
20\cf0\f1\charscalex100 { no es conductora. El oxidante ahora debe pasar por dif
usin a travs de }\par\pard\li600\ri0\sl-200\slmult0 \fs20\cf0\f1\charscalex100 {la
capa de azufre, lo que ocasiona un retardo de la cintica. }\par\pard\sect\sectd\
lsr-0\colno2\colw1200\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0
i586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-320\slmult0 \fs24\cf0\f0
\charscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\c
\fs24\cf0\f0\charscalex100 {34 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn
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-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex10
0\b {Figura 14 Sistema Cu-S-H2O a 25C }\b0 \par\pard\sect\sectd\sbknone\pgwsxn118
93\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\p
18\cf0\par\pard\li586\ri0\sl-186\slmult0 \fs20\cf0\f0\charscalex100\b \i {Reacti
vos Modificadores del Potencial (Eh) }\b0 \i0 \par\pard\li586\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li586\ri0\sl-306\slmult0 \fs20\cf0\f1\charscalex100 {Para re
alizar la medicin del potencial de xdo-reduccn (Eh) o potencial redox se utilizan los
electrodos }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {de
referencia, similares al electrodo de calomel saturado Figura 3. El po
tencial redox determina las }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\
charscalex100 {condiciones de calidad con que se est desarrollando un pr

oceso y proporciona la posibilidad de }\par\pard\li586\ri0\sl-226\slmult0 \
fs18\cf0\f1\charscalex100 {controlarlo. Muchos procesos hidrometalrgicos requiere
n de la modificacin de su potencial redox, para }\par\pard\li600\ri0\sl-240\slmul
t0 \fs20\cf0\f1\charscalex100 {lo cual se adicionan reactivos externos (oxidante
s o reductores). }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\r
i0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Como reactivos modificadores de
l potencial redox, existe una gran variedad de compuestos, siendo }\par
\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {determinante en su se
leccin el impacto econmico del potencial redox versus el costo del reactivo y las
}\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {interferencias d
e la adicin de algn elemento extrao en el balance global del circuito metalrgico. }\
s20\cf0\f1\charscalex100 {Se prefiere usar como oxidantes el oxgeno del a
ire o el agua oxigenada, H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f
1\charscalex100 {O}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex1
00 {, antes que otros }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\f1\charsc
alex100 {productos que, siendo tal vez ms efectivos, pueden producir una
contaminacin del circuito completo, }\par\pard\li586\ri0\sl-253\slmult0 \fs2
0\cf0\f1\charscalex100 {como es el caso del gas cloro, Cl}{\sub \fs14\cf0\f1\cha
rscalex100 {2}}\fs20\cf0\f1\charscalex100 {, o el permanganato de potasio, KMnO}
{\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf
0\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {De manera simila
r, entre los reductores se prefieren aquellos que sean ms afines para el balance
global }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {del circu
ito, un circuito cido se agrega anhdrido sulfuroso, SO}{\sub \fs12\cf0\f1\charscal
ex100 {2}}\fs18\cf0\f1\charscalex100 {, o chatarra de fierro o cobre, en vez de
}\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {manganeso, Mn}{\
super \fs14\up4\cf0\f1\charscalex100 {0}}\fs20\cf0\f1\charscalex100 {, o de otro
metal extrao al circuito original. }\par\pard\li586\ri0\sl-213\slmult0 \fs18\cf0
\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {En la Tabla XI se
muestran reactivos oxidantes y reductores usados en procesos hidrometalrgicos.
}\par\pard\li1960\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1960\ri0\sl-360\slmult
0 \fs20\cf0\f0\charscalex100\b {Tabla XI Potencial redox de algunos reactivos ox
idantes y reductores. }\b0 \par\pard\li4493\ri0\sl-360\slmult0 \fs20\cf0\f1\char
scalex100 {Reactivos Oxidantes }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn1
-0\colno3\colw2626\pard\li1800\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {oz
ono, O}{\sub \fs14\cf0\f1\charscalex100 {3}}\par\column\pard\li0\ri0\sl-280\slmu
lt0 \fs20\cf0\f1\charscalex100 {O}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0
\f1\charscalex100 { + H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charsc
alex100 {O }\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\cf0\f1\charscalex100 {
O}{\sub \fs14\cf0\f1\charscalex100 {3}}\fs20\cf0\f1\charscalex100 { + 2H}{\supe
r \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { + 2e}{\super \
fs14\up4\cf0\f1\charscalex100 {-}}\par\column\pard\li0\ri0\sl-240\slmult0 \fs20\
cf0\f1\charscalex100 {- 2,07 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn168
40\marglsxn666\margrsxn133\cols2\colno1\colw8466\colsr-0\colno2\colw2626\pard\li
1800\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {agua oxigenada, H}{\sub \fs1
4\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 {O}{\sub \fs14\cf0\f1\char
scalex100 {2}}\fs20\cf0\f1\charscalex100 {2H}{\sub \fs14\cf0\f1\charscalex100 {2
}}\fs20\cf0\f1\charscalex100 {O }\fs20\cf0\f2\charscalex100 {\uc1\u8660X}\fs20\c
f0\f1\charscalex100 { H}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charsc
alex100 {O}{\sub \fs14\cf0\f1\charscalex100 {2}}\fs20\cf0\f1\charscalex100 { + 2
H}{\super \fs14\up4\cf0\f1\charscalex100 {+}}\fs20\cf0\f1\charscalex100 { + 2e}{
\super \fs14\up4\cf0\f1\charscalex100 {-}}\par\pard\li3706\ri0\sl-120\slmult0 \f
s14\cf0\f1\charscalex100 {-}\par\column\pard\li0\ri0\sl-226\slmult0 \fs20\cf0\f1
\charscalex100 {- 1,77 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\ma
charscalex100 {permanganato, MnO}{\sub \fs14\cf0\f1\charscalex100 {4}}\par\pard\
li1800\ri0\sl-200\slmult0 \fs20\cf0\f1\charscalex100 {Gas cloro, Cl}{\sub \fs14\

cf0\f1\charscalex100 {2}}\par\pard\li1800\ri0\sl-240\slmult0 \fs20\cf0\f1\charsc
alex100 {pirolusita, MnO}{\sub \fs14\cf0\f1\charscalex100 {2}}\par\pard\li1800\r
i0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {nitrato, NO}{\sub \fs14\cf0\f1\cha
rscalex100 {3}}\par\pard\li1800\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {i
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i1800\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1800\ri0\sl-213\slmult0 \fs18\cf0\
par\pard\li1800\ri0\sl-280\slmult0 \fs20\cf0\f1\charscalex100 {chatarra de fierr
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{-}}\par\column\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {Universi
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lmult0 \fs18\cf0\par\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100\b {Mt
odos de Lixiviacin }\b0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marg
lsxn666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\s
l-253\slmult0 \fs20\cf0\f1\charscalex100 {Los mtodos disponibles para ejecutar la
lixiviacin de minerales, tratan de responder a las interrogantes }\par\pard\li60
0\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {fundamentales de toda actividad
industrial, en trminos de obtener el mximo beneficio econmico con el }\par\pard\li
600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {mnimo de costos. }\par\pard\li
charscalex100 {Se trata entonces de lograr un balance econmico entre los recursos
aportados: Inversin inicial, gastos }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf
0\f1\charscalex100 {operacionales (energa, reactivos, cido, agua, mano de o
bra, etc.) y los beneficios a obtener del }\par\pard\li600\ri0\sl-226\slm
ult0 \fs20\cf0\f1\charscalex100 {procesamiento de las materias primas. }\par\par
\f1\charscalex100 {Diversos procesos unitarios son aplicados previos a la operac
in de lixiviacin como: }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\margl
sxn666\margrsxn133\cols2\colno1\colw1306\colsr-0\colno2\colw9786\pard\li600\ri0\
ex100 {1 }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {2 }\par
\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {3 }\par\pard\li600\ri
0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {4 }\par\pard\li600\ri0\sl-226\slmul
t0 \fs18\cf0\f1\charscalex100 {5 }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\
cf0\par\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Explotacin minera
y transporte de mineral. }\par\pard\li0\ri0\sl-226\slmult0 \fs20\cf0\f1\charsca

lex100 {Chancado primario, secundario y terciario. }\par\pard\li0\ri0\sl-240\slm
ult0 \fs20\cf0\f1\charscalex100 {Molienda hmeda y clasificacin. }\par\pard\li0\ri0
\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {Concentracin, como la concentracin gra
vitacional, la flotacin, o una combinacin de ambas. }\par\pard\li0\ri0\sl-226\slmu
lt0 \fs20\cf0\f1\charscalex100 {Tratamiento qumico previo, como en los concentrad
os refractarios, los cuales requieren de una }\par\pard\sect\sectd\sbknone\pgwsx
n11893\pghsxn16840\marglsxn666\margrsxn133\pard\li600\ri0\sl-226\slmult0 \fs20\c
f0\f1\charscalex100 {tostacin oxidante, reductora o clorurante. }\par\pard\li600\
scalex100 {Siendo la lixiviacin un proceso qumico para acelerar su cintica
se le aplican los procedimientos }\par\pard\li600\ri0\sl-226\slmult0 \fs20
\cf0\f1\charscalex100 {desarrollados para mejorar el rendimiento cintico, ellos s
e puede lograr aplicando: }\par\pard\li960\ri0\sl-213\slmult0 \fs18\cf0\par\pard
\li960\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {1. Usando diferentes reac
tivos y lo variando su concentracin. }\par\pard\li960\ri0\sl-226\slmult0 \fs20\cf
0\f1\charscalex100 {2. Incorporando agitacin. }\par\pard\li960\ri0\sl-226\slmult
0 \fs20\cf0\f1\charscalex100 {3. Reduccin de tamao }\par\pard\li960\ri0\sl-226\sl
mult0 \fs20\cf0\f1\charscalex100 {4. Introduciendo el efecto de temperatura y p
resin. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-253\sl
mult0 \fs16\cf0\f1\charscalex100 {El factor tiempo, es decir, la duracin d
e los procesos seleccionados, es un elemento decisivo en la }\par\pard\
li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {seleccin de un mtodo de lixiv
iacin u otro, por su influencia sobre los costos, el tamao de los equipos }\par\pa
rd\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {y/o espacios involucrado
s. }\par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl-253\slmu
lt0 \fs18\cf0\f1\charscalex100 {El mtodo escogido para realizar la lixiviac
in depender principalmente de un balance econmico }\par\pard\li600\ri0\sl-226
\slmult0 \fs20\cf0\f1\charscalex100 {incluyendo valores de inversin y de operacin,
que debe tomar en cuenta: }\par\pard\li960\ri0\sl-213\slmult0 \fs18\cf0\par\par
d\li960\ri0\sl-253\slmult0 \fs16\cf0\f1\charscalex100 {1. El valor econmico d
el metal, la ley de cabeza, el tonelaje disponible, el precio de ven
ta y las }\par\pard\li1320\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {cond
iciones de calidad impuestas por el mercado }\par\pard\li960\ri0\sl-226\slmult0
\fs20\cf0\f1\charscalex100 {2. La recuperacin que se puede esperar con cada mtodo
. }\par\pard\li960\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {3. El costo d
e mina, el mtodo de extraccin y de transporte del mineral a la planta }\par\pard\l
i960\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {4. El costo de los proc
esos de reduccin de tamao: chancado, molienda, clasificacin y los }\par\pa
rd\li1320\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {eventuales pretratamien
tos de aglomeracin y/o curado. }\par\pard\li960\ri0\sl-226\slmult0 \fs18\cf0\f1\c
harscalex100 {5. El costo de los procesos de concentracin y eventual pre-tratami
ento trmico, flotacin, tuesta u }\par\pard\li1320\ri0\sl-226\slmult0 \fs20\cf0\f1\
charscalex100 {otro proceso piro-metalrgico. }\par\pard\li600\ri0\sl-213\slmult0
slmult0 \fs20\cf0\f1\charscalex100 {Los principales mtodos de lixiviacin usados en
la actualidad se pueden clasificar de la forma que sigue. }\par\pard\li773\ri0\
773\ri0\sl-266\slmult0 \fs20\cf0\f0\charscalex100\b {Lixiviacin in situ }\b0 \par
\cf0\f1\charscalex100 {La lixiviacin in-situ (en el lugar) consiste en la
aplicacin de soluciones directamente sobre el mineral }\par\pard\li586\ri
0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {que est ubicado en el yacimiento, si
n someterlo a labores de extraccin minera. Existen dos modalidades }\par\pard\li5
86\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {de lixiviacin in-situ, segn la u
bicacin del mineral respecto del nivel fretico. Debido a sus bajos costos }\par\pa
rd\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {de inversin es una tcnica
factible para la recuperacin de metales desde materiales de muy baja ley, no }\pa
r\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {explotables econmicam
ente por otros mtodos. }\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li7

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ard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs24\cf0\f
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D68AABB26C7FFFD9}
sl-240\slmult0 \fs20\cf0\f1\charscalex100 {Lixiviacin de cuerpos mineralizados
situados cerca de la superficie y sobre el nivel de las aguas }\par

\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {subterrneas. Se aplica
en las zonas ya explotadas de minas viejas o en zonas que han sido fracturadas
}\par\pard\li600\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {hidrulicamente o
con explosivos. }\par\pard\li3426\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3426\
rd\li3426\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100\b {Figura 15 Lixiviacion
in situ gravitacional }\b0 \par\pard\li773\ri0\sl-346\slmult0 \fs16\cf0\f1\char
scalex100 {Lixiviacin in-situ gravitacional las soluciones se mueven por
gravedad, lo que requiere de condiciones }\par\pard\li586\ri0\sl-240\slmult
0 \fs16\cf0\f1\charscalex100 {de alta permeabilidad o de una fragmentacin
previa, como es el caso de los yacimientos ya fracturados }\par\pard\li
586\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {por una explotacin minera
anterior, con accesos operativos en los niveles inferiores para recolec
tar las }\par\pard\li586\ri0\sl-226\slmult0 \fs16\cf0\f1\charscalex100 {solucio
nes. Por ejemplo aquellas minas sometidas a explotacin subterrnea del ti
po de hundimiento por }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charsc
alex100 {bloques ("block caving"), lixiviacin del crter de San Manuel, en Arizona,
Figura 16, o bien, son sometidos, }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0
\f1\charscalex100 {previamente, a una tronadura masiva para su fracturamiento, c
omo fue el caso experimental, probado en }\par\pard\li586\ri0\sl-226\slmult0 \fs
16\cf0\f1\charscalex100 {los aos 1970, en Old Reliable Copper, en Mammoth
, Arizona. Kennecott estudi el uso de una carga }\par\pard\li586\ri0\sl-2
26\slmult0 \fs18\cf0\f1\charscalex100 {nuclear, en los aos '70, pero varias
incgnitas en torno a la disipacin de la radiactividad y la }\par\pard\
li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {contaminacin del subsuelo qu
e se puede generar no fueron satisfactoriamente resueltas. }\par\pard\li2266\ri0
\sl-373\slmult0 \fs20\cf0\f0\charscalex100\b {Figura 16 Operacin de lixiviacion e
n crater, San Manuel, Arizona }\b0 \par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\
par\pard\li773\ri0\sl-360\slmult0 \fs20\cf0\f0\charscalex100\b {Lixiviacin in-sit
u forzada}\b0 \fs20\cf0\f1\charscalex100 {: se aplicar a yacimientos, ubicados d
ebajo del nivel fretico, en cuyo caso se }\par\pard\li600\ri0\sl-240\slmult0 \fs1
8\cf0\f1\charscalex100 {hace uso de la permeabilidad interna de la roca y de las
temperaturas y altas presiones que se generan a }\par\pard\li586\ri0\sl-226\slm
ult0 \fs20\cf0\f1\charscalex100 {varios cientos de metros de profundidad,. }\par
\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\c
olno1\colw9893\colsr-0\colno2\colw1200\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\p

f0\f0\charscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmult0 \f
lex100 {38 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\mar
grsxn133\pard\sect\sectd\sbkpage
7;32768}}
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f0\f0\charscalex100 {Hidrometalurgia I }\par\column\pard\li2040\ri0\sl-306\slmul
t0 \fs24\cf0\f0\charscalex100 {Universidad Catolica del Norte }\par\pard\li0\ri0
lex100\b {Figura 17 Lixiviacion in situ }\b0 \par\pard\sect\sectd\sbknone\pgwsxn
0\par\pard\li773\ri0\sl-360\slmult0 \fs20\cf0\f1\charscalex100 {Las soluciones
lixiviantes inyectan a travs de pozos inyectores del tipo usado en la
explotacin del }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100
{petrleo y se succiona desde otra batera de pozos cosechadores, dispuestos de form
a alternada Figura 17 }\par\pard\li586\ri0\sl-240\slmult0 \fs16\cf0\f1\charscale
x100 {como en el caso de recuperacin de uranio desde estratos permeable
s horizontales. Esta tcnica se ha }\par\pard\li586\ri0\sl-226\slmult0 \fs20\
cf0\f1\charscalex100 {usado en la recuperacin de diversas sales fcilmente solubles
, NaCl, KCl, minerales de uranio, y fosfato. }\par\pard\li773\ri0\sl-213\slmult
0 \fs18\cf0\par\pard\li773\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {Lixivi
acin forzadas tipo I Se aplica a yacimientos ubicados bajo el nivel de las aguas
subterrneas, pero }\par\pard\li586\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100
{a menos de 200 m de profundidad. Estos depsitos se fracturan en el lugar y las s
oluciones se inyectan y }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charsca
lex100 {extraen por bombeo. Es importante previo a la lixiviacin, el dr
enaje del agua desde el cuerpo }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf
0\f1\charscalex100 {mineralizado, lo cual requiere un acabado conocimiento de la
hidrologa de la zona. Figura 18 }\par\pard\li4933\ri0\sl-213\slmult0 \fs18\cf0\p
\b {Figura 18 }\b0 \par\pard\li773\ri0\sl-346\slmult0 \fs18\cf0\f1\charscalex10
0 {Lixiviacin forzadas tipo II Se aplica a depsitos de sulfuros primario
s bajo el nivel de las aguas }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0
\f1\charscalex100 {subterrneas. El material puede ser fracturado por medio
s convencionales o medios hidrostticos }\par\pard\li586\ri0\sl-240\slmult0 \f
s18\cf0\f1\charscalex100 {(hidrofracturacin). A esta profundidad, la presin
aumenta la solubilidad del oxgeno, a presin }\par\pard\li586\ri0\sl-226\slmu
lt0 \fs18\cf0\f1\charscalex100 {atmosfrica el agua en equilibrio con aire contien
e alrededor de 7 ppm de oxigeno, y para el equilibrio con }\par\pard\li586\ri0\s
l-226\slmult0 \fs18\cf0\f1\charscalex100 {oxigeno puro llega a 35 ppm este
valor de oxigeno disuelto aumenta rapidamente a aumentar la }\par\pard
\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {profundidad hasta 1000 ppm
a 300 m de profundidad, Figura 19 acelerando la oxidacin directa del mineral }\p

ar\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {sulfurado , produci
endo cido sulfrico y elevando la temperatura. }\par\pard\sect\sectd\sbknone\pgwsxn
11893\pghsxn16840\marglsxn666\margrsxn133\cols2\colno1\colw9893\colsr-0\colno2\c
olw1200\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213\slmult
{Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li
d\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-360\slmult0 \fs24\cf0\f0\
charscalex100 {39 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn
666\margrsxn133\pard\sect\sectd\sbkpage
7;32768}}
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\cf0\par\pard\li680\ri0\sl-386\slmult0 \fs20\cf0\f0\charscalex100\b {Figura 19 L
ixiviacion de depositos profundos, muestra el aumento de la solubilidad de oxgen
o con }\b0 \par\pard\li4680\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100\b {la
profundidad }\b0 \par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0
\sl-360\slmult0 \fs20\cf0\f1\charscalex100 {Aplicacin a minerales oxidados, sulfu
rados y mixtos de cobre. }\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li773\ri0\sl-253\slmult0 \fs20\cf0\f1\charscalex100 {A partir de la dcada de
l 60 empez a estudiar el problema, an cuando tcnicas similares fueron }\
par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {aplicadas artesan
almente mucho antes. Bsicamente se ha reconocido que es necesario estud
iar y }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {optimizar
parmetros de la operacin relacionados con el diseo del proceso, la qumica del proc
eso, las }\par\pard\li600\ri0\sl-240\slmult0 \fs18\cf0\f1\charscalex100 {reaccio
nes paralelas, el rol de la aireacin, la recirculacin de soluciones, la catlisis ba
cterial, etc. Por otra }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscal
ex100 {parte se reconoci la importancia de desarrollar modelos considerando no slo
la termodinmica y cintica }\par\pard\li600\ri0\sl-226\slmult0 \fs16\cf0\f1\charsc
alex100 {qumica, sino tambin considerar los efectos de la generacin de ca
lor, flujo de fluidos y fenmenos de }\par\pard\li600\ri0\sl-226\slmult0 \fs
18\cf0\f1\charscalex100 {transporte. Adicionalmente se ha reconocido que el proc
eso no es un proceso estacionario, sino que todos }\par\pard\li600\ri0\sl-226\sl
mult0 \fs16\cf0\f1\charscalex100 {los factores y parmetros cambian en el t
iempo. Cabe notar que fenomenolgicamente los procesos de }\par\pard\li600\
ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {lixiviacin in-situ, en botadero
s y en pilas son muy similares y por lo tanto los avances desarrolla
dos son }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {aplicab
les en general, la Figura 20 muestra una pila y una seccin de una lixiviacin in s
itu, en que ambas }\par\pard\li600\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100
{pueden ser representadas por una unidad de volumen, las diferencias son mnimas
desde el punto de vista }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf0\f1\charsca
lex100 {de la situacin e analizar. }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghs
xn16840\marglsxn666\margrsxn133\cols2\colno1\colw9893\colsr-0\colno2\colw1200\pa
0\par\pard\li586\ri0\sl-293\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benavente
}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmul

ult0 \fs24\cf0\f0\charscalex100 {40 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pg
hsxn16840\marglsxn666\margrsxn133\pard\sect\sectd\sbkpage
7;32768}}
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s3\colno1\colw4933\colsr-0\colno2\colw1173\colsr-0\colno3\colw4986\pard\li586\ri
0\sl-306\slmult0 \fs24\cf0\f0\charscalex100 {Hidrometalurgia I }\par\column\pard
slmult0 \fs20\cf0\f0\charscalex100\b {Figura 20 }\b0 \par\column\pard\li0\ri0\sl
-306\slmult0 \fs24\cf0\f0\charscalex100 {Universidad Catolica del Norte }\par\pa
rd\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li773
rscalex100 {Los factores importantes en la lixiviacin, pueden ser sealados como: }
*\tx1306\fs20\cf0\f1\charscalex100 {a) }\tab \fs20\cf0\f1\charscalex100 {Configu
racin del material para una buena distribucin de las soluciones. }\par\pard\li773\
ri0\sl-226\slmult0 \*\tx1306\fs20\cf0\f1\charscalex100 {b) }\tab \fs20\cf0\f1\ch
arscalex100 {Eficiente distribucin de oxgeno, para sostener las reacciones
de oxidacin en el caso de los }\par\pard\li600\ri0\sl-226\slmult0 \fs20\cf
0\f1\charscalex100 {sulfuros. }\par\pard\li773\ri0\sl-226\slmult0 \*\tx1306\fs20
\cf0\f1\charscalex100 {c) }\tab \fs20\cf0\f1\charscalex100 {Favorecer la catlisis

bacterial de dichas reacciones de oxidacin. }\par\pard\li773\ri0\sl-240\slmult0
\*\tx1306\fs20\cf0\f1\charscalex100 {d) }\tab \fs20\cf0\f1\charscalex100 {Conoci
miento de la qumica involucrada para evaluar la formacin de precipitados. }\par\pa
0\par\pard\li773\ri0\sl-266\slmult0 \fs20\cf0\f0\charscalex100\b {Lixiviacin en b
otaderos }\b0 \par\pard\li600\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li600\ri0\sl
-306\slmult0 \fs18\cf0\f1\charscalex100 {La lixiviacin en botaderos consiste
en el tratamiento de minerales de bajas leyes, bajo la ley de corte
}\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex100 {econmica para la
planta principal, conocidos como estril mineralizado o marginal. Estos marginale
s se }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 {acumulan no
rmalmente en caones o quebradas cercanas a la mina. Alcanzan alturas de 100 metro
s o }\par\pard\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {ms y el su
strato basal no siempre es el ms adecuado para recoger soluciones, sin
embargo se lea }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscalex10
0 {aplica solucin en la parte superior y colectndose en un piscinas de interseccin
en la roca impermeable }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1\charscal
ex100 {ms prxima Figura 21. Se estima que los botaderos acumulados en l
a zona sudeste de USA }\par\pard\li586\ri0\sl-240\slmult0 \fs20\cf0\f1\chars
calex100 {representan aproximadamente 5x10}{\super \fs14\up4\cf0\f1\charscalex
100 {9}}\fs18\cf0\f1\charscalex100 { toneladas, con un contenido de 7 mil
lones de toneladas de cobre }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\f1
\charscalex100 {fino. El mtodo requiere poco capital de inversin y operacin. Sin em
bargo, se obtienen recuperaciones }\par\pard\li586\ri0\sl-226\slmult0 \fs20\cf0\
f1\charscalex100 {bajas y la cintica es lenta (aos). }\par\pard\sect\sectd\sbknone
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olno2\colw1200\pard\li586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li586\ri0\sl-213
6\ri0\sl-413\slmult0 \fs24\cf0\f0\charscalex100 {Oscar Benavente }\par\column\pa
{41 }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn1
7;32768}}

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f0\f0\charscalex100 {Hidrometalurgia I }\par\column\pard\li3120\ri0\sl-306\slmul
t0 \fs24\cf0\f0\charscalex100 {Universidad Catolica del Norte }\par\pard\li0\ri0
mult0 \fs18\cf0\par\pard\li0\ri0\sl-373\slmult0 \fs20\cf0\f0\charscalex100\b {Fi
gura 21 Lixiviacion en botadero Minera el Abra }\b0 \par\pard\sect\sectd\sbknone
\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li586\ri0\sl-213\slmult0 \
lmult0 \fs20\cf0\f1\charscalex100 {En ocasiones, se trata tambin de ripios de lix
iviaciones antiguos, cuyas leyes pasan a ser interesantes al }\par\pard\li586\ri
0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {cabo de un cierto nmero de aos.
Es el caso de los antiguos botaderos de ripios de lixiviacin de }\pa
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racin de Lixiviacin de Ripios en la Figura 22 se observa un corte transversal de l
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s de Chuquicamata. }\par\pard\li2720\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li27
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d\li586\ri0\sl-226\slmult0 \fs18\cf0\f1\charscalex100 {de la que se dispone. La
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r\pard\li586\ri0\sl-240\slmult0 \fs16\cf0\f1\charscalex100 {tener ciclos muy
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cf0\f0\charscalex100 {Oscar Benavente }\par\column\pard\li0\ri0\sl-213\slmult0 \
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Hidrometalurgia

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Estructura de enlaces mixtos ___________________________________________________

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