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Sodium hydroxide
From Wikipedia, the free encyclopedia
Sodium hydroxide
Contents
Names
Preferred IUPAC name
Sodium hydroxide[3]
Systematic IUPAC name
[4]
1 Properties
1.1 Physical properties
1.2 Chemical properties
1.2.1 Reaction with acids
1.2.2 Reaction with acidic
oxides
1.2.3 Reaction with
amphoteric metals and
oxides
1.2.4 Precipitant
1.2.5 Saponification
2 Production
3 Uses
3.1 Chemical pulping
3.2 Tissue digestion
3.3 Dissolving amphoteric metals
and compounds
3.4 Esterification and
transesterification reagent
3.5 Food preparation
3.6 Cleaning agent
https://en.wikipedia.org/wiki/Sodium_hydroxide
Sodium oxidanide
Other names
Caustic soda
Lye[1][2]
Ascarite
White caustic
Sodium hydrate[3]
Identifiers
CAS Number
1310-73-2
ChEBI
CHEBI:32145
ChemSpider
14114
EC Number
215-185-5
Gmelin Reference
68430
Jmol 3D model
Interactive image
KEGG
D01169
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MeSH
Sodium+Hydroxide
PubChem
14798
RTECS number
WB4900000
UNII
55X04QC32I
UN number
1823
InChI
SMILES
Properties[edit]
Properties
Chemical formula
NaOH
Molar mass
39.9971 g mol1
Appearance
Odor
odorless
Density
2.13 g/cm3
Melting point
Boiling point
Solubility in water
418 g/L (0 C)
1110 g/L (20 C)
Physical properties[edit]
soluble in glycerol
negligible in ammonia
insoluble in ether
Solubility in
238 g/L
methanol
Chemical properties[edit]
Reaction with acids[edit]
Sodium hydroxide reacts with protic acids to
produce water and the corresponding salts. For
example, when sodium hydroxide reacts with
hydrochloric acid, sodium chloride is formed:
NaOH(aq) + HCl(aq) NaCl(aq) + H2O
(l)
In general, such neutralization reactions are
represented by one simple net ionic equation:
OH(aq) + H+(aq) H2O(l)
This type of reaction with a strong acid releases
heat, and hence is exothermic. Such acid-base
reactions can also be used for titrations.
However, sodium hydroxide is not used as a
primary standard because it is hygroscopic and
absorbs carbon dioxide from air.
https://en.wikipedia.org/wiki/Sodium_hydroxide
Basicity (pKb)
0.2[5]
59.66 J/mol K
Std molar
64 Jmol1K1[6]
o
entropy (S
298)
Std enthalpy of
427 kJmol1[6]
o
formation (fH 298)
Gibbs free energy
(fG)
-380.7 kJ/mol
Hazards
External MSDS
GHS pictograms
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Danger
GHS hazard
statements
H314
GHS precautionary
statements
EU classification
(DSD)
C
R-phrases
R35
S-phrases
NFPA 704
0
3
1
ALK
40 mg/kg (mouse,
LDLo (lowest
published)
intraperitoneal)[8]
C 2 mg/m3[7]
Sodium hydrosulfide
Other cations
Caesium hydroxide
Lithium hydroxide
Potassium hydroxide
Rubidium hydroxide
verify (what is ?)
Unlike sodium hydroxide, the hydroxides of
most transition metals are insoluble, and
Infobox references
therefore sodium hydroxide can be used to
precipitate transition metal hydroxides. The
following colours are observed: blue-copper, green-iron(II), yellow/brown-iron(III). Zinc and lead
salts dissolve in excess sodium hydroxide to give a clear solution of Na2ZnO2 or Na2PbO2.
Aluminium hydroxide is used as a gelatinous flocculant to filter out particulate matter in water
treatment. Aluminium hydroxide is prepared at the treatment plant from aluminium sulfate by
reacting it with sodium hydroxide or carbonate.
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Production[edit]
Sodium hydroxide is industrially produced as a 50% solution by variations of the electrolytic
chloralkali process. Chlorine gas is also produced in this process. Solid sodium hydroxide is
obtained from this solution by the evaporation of water. Solid sodium hydroxide is most
commonly sold as flakes, prills, and cast blocks.[12]
In 2004, world production was estimated at 60 million dry metric tonnes of sodium hydroxide, and
demand was estimated at 51 million tonnes.[12] In 1998, total world production was around
45 million tonnes. North America and Asia each contributed around 14 million tonnes, while
Europe produced around 10 million tonnes. In the United States, the major producer of sodium
hydroxide is the Dow Chemical Company, which has annual production around 3.7 million tonnes
from sites at Freeport, Texas, and Plaquemine, Louisiana. Other major US producers include
Oxychem, PPG, Olin, Pioneer Companies, Inc. (PIONA, which was purchased by Olin), and
Formosa. All of these companies use the chloralkali process.[14]
Historically, sodium hydroxide was produced by treating sodium carbonate with calcium
hydroxide in a metathesis reaction. (Sodium hydroxide is soluble while calcium carbonate is not.)
This process was called causticizing.[15]
Ca(OH)2(aq) + Na2CO3(s) CaCO3 + 2 NaOH(aq)
This process was superseded by the Solvay process in the late 19th century, which was in turn
supplanted by the chloralkali process which we use today.
Sodium hydroxide is also produced by combining pure sodium metal with water. The byproducts
are hydrogen gas and heat, often resulting in a flame, making this a common demonstration of the
reactivity of alkali metals in academic environments; however, it is not commercially viable, as
the isolation of sodium metal is typically performed by reduction or electrolysis of sodium
compounds including sodium hydroxide.
For further information in historical production, see alkali manufacture.
Uses[edit]
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Chemical pulping[edit]
Sodium hydroxide is also widely used in pulping of wood for making paper or regenerated fibers.
Along with sodium sulfide, sodium hydroxide is a key component of the white liquor solution
used to separate lignin from cellulose fibers in the kraft process. It also plays a key role in several
later stages of the process of bleaching the brown pulp resulting from the pulping process. These
stages include oxygen delignification, oxidative extraction, and simple extraction, all of which
require a strong alkaline environment with a pH > 10.5 at the end of the stages.
Tissue digestion[edit]
In a similar fashion, sodium hydroxide is used to digest tissues, as in a process that was used with
farm animals at one time. This process involved placing a carcass into a sealed chamber, then
adding a mixture of sodium hydroxide and water (which breaks the chemical bonds that keep the
flesh intact). This eventually turns the body into a liquid with coffee-like appearance,[19][20] and the
only solid that remains are bone hulls, which could be crushed between one's fingertips.[21]
Sodium hydroxide is frequently used in the process of decomposing roadkill dumped in landfills
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by animal disposal contractors.[20] Due to its low cost and availability, it has been used to dispose
of corpses by criminals. Italian serial killer Leonarda Cianciulli used this chemical to turn dead
bodies into soap.[22] In Mexico, a man who worked for drug cartels admitted disposing of over 300
bodies with it.[23] Sodium hydroxide is a dangerous chemical due to its ability to hydrolyze
protein. If a dilute solution is spilled on the skin, burns may result if the area is not washed
thoroughly and for several minutes with running water. Splashes in the eye can be more serious
and can lead to blindness.[24] This danger is often overlooked.
Food preparation[edit]
Food uses of sodium hydroxide include washing or chemical peeling of fruits and vegetables,
chocolate and cocoa processing, caramel coloring production, poultry scalding, soft drink
processing, and thickening ice cream.[27] Olives are often soaked in sodium hydroxide for
softening; Pretzels and German lye rolls are glazed with a sodium hydroxide solution before
baking to make them crisp. Owing to the difficulty in obtaining food grade sodium hydroxide in
small quantities for home use, sodium carbonate is often used in place of sodium hydroxide.[28]
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Cleaning agent[edit]
Sodium hydroxide is frequently used as an industrial cleaning agent where it is often called
"caustic". It is added to water, heated, and then used to clean process equipment, storage tanks,
etc. It can dissolve grease, oils, fats and protein-based deposits. It is also used for cleaning waste
discharge pipes under sinks and drains in domestic properties. Surfactants can be added to the
sodium hydroxide solution in order to stabilize dissolved substances and thus prevent
redeposition. A sodium hydroxide soak solution is used as a powerful degreaser on stainless steel
and glass bakeware. It is also a common ingredient in oven cleaners.
A common use of sodium hydroxide is in the production of parts washer detergents. Parts washer
detergents based on sodium hydroxide are some of the most aggressive parts washer cleaning
chemicals. The sodium hydroxide-based detergents include surfactants, rust inhibitors and
defoamers. A parts washer heats water and the detergent in a closed cabinet and then sprays the
heated sodium hydroxide and hot water at pressure against dirty parts for degreasing applications.
Sodium hydroxide used in this manner replaced many solvent-based systems in the early 1990s
[citation needed]
when trichloroethane was outlawed by the Montreal Protocol. Water and sodium
hydroxide detergent-based parts washers are considered to be an environmental improvement over
the solvent-based cleaning methods.
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Historical uses[edit]
Sodium hydroxide has been used for detection of carbon monoxide poisoning, with blood samples
of such patients turning to a vermilion color upon the addition of a few drops of sodium
hydroxide.[30] Today, carbon monoxide poisoning can be detected by CO oximetry.
Experimental[edit]
Sodium hydroxide test for flavonoids
Safety[edit]
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Commercial brands[edit]
Red Devil Lye
Lewis Lye
See also[edit]
HAZMAT Class 8 Corrosive Substances
Common chemicals
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References[edit]
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
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Bibliography[edit]
Euro Chlor-How is chlorine made? Chlorine Online
Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.).
Butterworth-Heinemann. ISBN 0-08-037941-9.
Heaton, A. (1996) An Introduction to Industrial Chemistry, 3rd edition, New York:Blackie.
ISBN 0-7514-0272-9.
External links[edit]
International Chemical Safety Card 0360
Wikimedia Commons has
NIOSH Pocket Guide to Chemical Hazards
media related to Sodium
CDC Sodium Hydroxide NIOSH Workplace
hydroxide.
Safety and Health Topic
European Union Risk Assessment Report
Look up sodium hydroxide
Production by brine electrolysis
in Wiktionary, the free
Sodium Hydroxide Safety Data Sheet (SDS)
dictionary.
Sodium hydroxide Safety Summary (BASF)
Titration of acids with sodium hydroxide; freeware
for data analysis, simulation of curves and pH calculation
Caustic soda production in continuous causticising plant by lime soda process
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title=Sodium_hydroxide&oldid=723826229"
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