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8 of 45 questions answered correctly
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1. 1. Question
The conversion of methyl chloride into dimethyl ether takes place by
Williamsons Synthesis
Hydroboration reaction
Kolbes reaction
Correct
2. 2. Question
Stephens reduction is used to prepare aldehyde from
Incorrect
3. 3. Question
The correct order of thermal stability of alkali metal follows the order
Incorrect
Thermal stability increases from lower member to higher member of alkali metal.
4. 4. Question
Which of the following is formed when acetophenone reacts with (C 6H5)3P = CH2?
Correct
5. 5. Question
Which of the following is the correct order of basic strength of the following compounds?
Incorrect
Basic strength depends on the availability of lone pair of electron over Nitrogen atom. In I &
III structure, the lone pair is easily available but in II & IV, the electrons are displaced by the
resonance.
6. 6. Question
Analgesics
Antipyretics
Antihistamine
Hypnotics
Incorrect
The structure is barbituric acid. The derivatives are luminal, seconals etc which are used as
tranquilizers.
7. 7. Question
Propionic acid when heated in presence of P 2O5 gives
Acetic anhydride
Propyne
Propanoic anhydride
Incorrect
8. 8. Question
Which of the following is not tetrahedral?
Incorrect
If a and b are the initial moles of N 2 & H2 respectively in the reversible reaction N2 + 3H2
2NH3 of volume V then which of the following relation explains the K C of the reaction?
Correct
10.
10. Question
where n is the
order of reaction.
Incorrect
11. Question
The heat of reaction for the hydrogenation of acetylene is at 25C is 42 kcal to form
ethylene. Calculate the internal energy of the reaction at the same temperature.
41kcal
42.6 kcal
40 kcal
43 kcal
Incorrect
12. Question
A metal carbonyl has the formula Cr(CO)x. What is the value of x if the effective atomic
number of Cr metal is 36?
Incorrect
13. Question
Incorrect
14.
14. Question
The ionic radii of P3+, Sb3+, As3+, & Bi3+ is in the order of
Incorrect
The atomic sizes and ionic sizes increases along the group due to successive addition of
new shells. So Bi3+ is biggest in size and P3+ is smallest in size.
15.
15. Question
When 2 moles of NH3 are present in 1.5 litre vessel at 13 and 25 atm pressure, then
Compressibility factor of
Ideal pressure of
Compressibility factor of
Ideal pressure of
is 1.879
is 20 atm
is 0.879
is 35 atm
Incorrect
Compressibility factor
16.
16. Question
Incorrect
17. Question
Which of the following molecules displaces the other three from their compounds?
Incorrect
Fluorine is the strongest oxidizing power among all. So it can displace other three from their
compound as
2NaCl + F2 NaF + Cl2
18.
18. Question
Incorrect
Rearrangement reaction takes place through hydride ion shift in carbonium ion.
19.
19. Question
Incorrect
20. Question
4 Amidoethylbenzoate
is
3 Ethoxycarbonyl benzamide
Incorrect
21.
21. Question
Chlorobenzene
Benzyl chloride
Methyl chloride
Incorrect
22.
22. Question
Propylamine
N methyl propanamine
N- methyl ethanamide
Ethanamide
Correct
23.
23. Question
Incorrect
The hybridization
H = [ V + M C + A]
= [6 + 2 0 + 0]
=4
So it is sp3 hybridised.
24.
24. Question
36 gm of Fe
36 g of Carbon
36g of Al
36g of Silver
Incorrect
(d)
25.
Butter gel
Incorrect
26. Question
For the formation of tert butyl ethyl ether by Williamsons synthesis, the reactants used are
Incorrect
27.
27. Question
A compound is optically active but gives oxime with hydroxyl amine and also gives a positive
Fehling solution test. Give the structure of the compound.
Incorrect
The compound is aldehyde as it responds Fehling solution. The compound contains chiral
carbon atom at C2 position (*).
28.
28. Question
In which of the following compounds, the electrophilic reaction will not be in meta-position?
Incorrect
All other structures show R resonance effect so the electron density is lower in ortho and
para position. Thus first, second and fourth structures show m substitution. But the lone
pair of nitrogen in third structure can resonate to the ring to create high electron density in o
& p position.
29.
29. Question
2 0 0 +1/2
3 1 1 1/2
4 2 +3 +1/2
4 3 2 1/2
Incorrect
30. Question
Inductive effect
Electromeric effect
Mesomeric effect
Hyperconjugation
Incorrect
Due to resonance, the lone pair of amide is displaced to carbonyl group which decreases the
basic characters. But in amine, alkyl group increases the density of electron due to +I effect.
31.
31. Question
List II
(I) Azithromycin
(II) Martius yellow
(III) Promethazine
(IV) Methyl orange
Incorrect
Self Explanatory.
32.
32. Question
Incorrect
33.
33. Question
What will be the work done by 3 mole of an ideal gas at 27C in reversible isothermal
expansion from 3 litres to 15 litres?
10.49 KJ
12.039 J
12.039 kJ
13.3 kJ
Incorrect
34. Question
Correct
Bis means di for bidentate ligand. As it is a neutral ligand, so no special ending. All are inside
square bracket.
35.
35. Question
Ti
Cr
Fe
Incorrect
36. Question
In acidic medium potassium dichromate changes to Cr 3+ ion. What will be the equivalent
weight of potassium dichromate in acidic medium (K = 39, Cr = 52)?
96
49
147
294
Incorrect
37.
37. Question
Incorrect
Basic nature depends on the availability of lone pair of electron over nitrogen atom (Lewis
concept). All other examples (except NH3) contain electronegative halogens which
decreases the electron density over nitrogen. In
Hence more basic.
38.
38. Question
Which of the following methods is not used for the extraction of Al metal?
Bayer process
Serpek Process
Van-Arkel Process
Hall Process
Correct
39. Question
Incorrect
The hybridization
H = [ V + M C + A]
= [7 + 7] = 7. So sp3d3.
The shape is pentagonal bipyramidal.
40.
40. Question
20 ml of ethane burnt with 70 ml of oxygen. The volume of gas left after cooling to room
temperature will be
70 ml
60 ml
50 ml
40 ml
Correct
41. Question
Which of the following elements shows highest 1st ionization potential?
Nitrogen
Oxygen
Magnesium
Helium
Correct
Ionization potential decreases along a group & increases along a period. Helium shows
highest ionization potential in the periodic table. This shows due to smallest atomic size.
42.
42. Question
3 Oxo 5, 5 dimethylcyclohexanal
Incorrect
43.
43. Question
Incorrect
44. Question
Incorrect
Methyl amine shows +I effect which increases the basic strength due to high density of lone
pair of electron over the nitrogen atom.
45.
45. Question
H is ve and S is positive
Incorrect
Gibbs equation is G = H TS
(i) The reaction is spontaneous if G = ve
(ii) The reaction is non spontaneous If G = +ve
(iii) The reaction is in a state of equilibrium if G = 0
If H is +ve and S is ve than
G = +ve T(ve)
= +ve
So option d is correct.