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APPLIED SCIENCE-I

JAN. 2002

N. B.:
(1)

Attempt any three questions from each section I.

(2)

Question No.6 is compulsory in section II.

(3)

Attempt any two from question Nos.7,8, & 9 in section II.

(4)

Write two section in two separate answer-books.

(5)

Assume suitable additional data if required.

Section I

1.(a) Distinguish between amorphous solid, single crystal and polycrystaline

material, write short notes on basis, lattice points, space, space lattice, lattice plane
and unit cell with diagrams.
(8)
(b)Explain wave-particle duality and De-brogile's hypothesis and prove that Debroglie's wave length of an election is inversely proportional to the square root of
accelerating voltage.
(4)
(c)Find the natural frequency of a quartz plate of thickness 1.5 mm. Given that
young's modulus for quartz 8 x 1010 N/m2 and density 2650 kg/ m3
(4)
2.(a) Explain how barrier potential formed in P-N junction, how it will change with
forward and reverse bias voltage and thus help to allow or restrict the low of current
across the junction with energy level diagram.
(7)
(b)Derive the expression for interplaner distance in terms of lattice parameter.
{4)
(c)In a C.R.T, the distance from the center of the coil to the screen is 0.3 m. The
length of the field along the axis is 5 cm. calculate the magnetic flux density B
required to produce a deflection 3 cm on the screen, if the accelerating anode
voltage is 1000 volts. Given that charge of electron 1.6 x 10 -19 coulomb and mass of
electron 9.1 x 10-31 kg
(6)
3.(a) Explain the construction of C.R.O and discuss how A.C., D.C. voltage, frequency
and phase angle between two A.C. voltage measured by C.R.O. (7)
(b)What is the important of ligancy in Ionic crystal? Calculate the critical ionic radius
ratio for ligancy-6. Give one example which is having ligancy-6. (5)
(c)A charged particle accelerated by a p.d. of 200v had a De-broglie's wavelength
equal to 0.0202A0. Find the mass of this particle and say which particle is it? Charge
of the particle = 1.6 x 10-19 C planks cosnt = 6.625x10-34 J. sec. (5)
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4.(a) Define piezo-electric effect, and show how piezo-electric oscillator produce
ultrasonic waves with proper diagram. (5)
(b)Prove that for intrinsic semiconductor fermi level will be at the middle of the
forbidden gap. What is its physical interpretation? Where will be the position of
Fermi-level for p-type and n-type semiconductor and why? (7)
(c) Molybdenum have B.C.C structure, calculate atomic radius and mass density,
given that lattice const a = 3.15A, At, wt of MO = 95.94 and avogadro's No =
6.023x1026/kg. mole
(5)
5.

Write short notes on any three: (16)

(a)
Definition of millar indices and steps to find out miller indices of a particular
lattice plane.
(b)

Working of P-N-P transistor under C.B. mode.

(c)

Uses of ultrasonic wave as flaw detector, SONAR and in cavitations effect.

(d)

Diamond structure.

(e)

Variation of Fermi level with temperature for extrinsic semiconductor.

Section II

(At.wts : H = 1, c = 12, 0 = 16, Na = 23, Mg = 24, si = 28, CI - 35.5, Ca =40, S =

32).

6.

Answer any six of the following: (18)

(a)

Write any three difference between temporary and permanent hardness.

(b)

Explain caustic Embrittlement in boilers.

(c)

Explain the drawbacks of natural rubber.

(d)

Write the effect of air pollutants present in atmosphere.

(e)

Explain any three compounds added to plastics to improve its properties.

(f)

What are the various functions of lubricants?

(g)

Explain cloud and pour point of oil.

(h) Find the acid value of a vegetable oil whose 5 ml required 2 ml of N/100 ko H
during Titration. (density of oil = 0.92).
7.(a) Explain lime-soda process of softening of water.

(8)

(b) Explain Boundary film and Extreme pressure Lubrication.

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8.(a) Explain Extrusion Moulding method of plastics.(7)

(b) Calculate lime (80% purity) and soda (90% purity) required to soften 1 lakh litre
of water containing the following impurities:
Mg(H C03) 2 = 7.1 mg/lit.

MgCO3 = 4.2 mg/lit.

Ca(HC03)2 = 8.1 mg/lit.

CaCO3= 10 mg/lit. (5)

(c) Write the importance o fBOD and COD of a sewage.

(4)

9. (a) Explain the various internal treatment methods for boiler feed water.

(5)

(b) Explain the manufacturer, properties and uses of silicon rubber. (6)
(c) A zeolite softener was completely exhausted and was regenerated by passing
1000 litre of sodium chloride solution containing 100 gm/lit of sodium chloride. How
many lit. of a sample water of hardness 500 ppm can be softened by this softener.
(5)

APPLIED SCIENCES-l

(JUNE. 2002)

N.B.:
(1)

Attempt any three questions from each section I.

(2)

Attempt two sections on different answer books.

(3)

Assume suitable data if necessary.

(4)

In section II, question No. 6 is compulsory.

(5)

Attempt any two questions from Q No. 7, 8, and 9.

(6)
At wts.: H =1, Ca = 40, C - 12, O = 16, CI = 35.5, Na = 23, Mg= 24, S = 32, is
= 28.
Section I
Data : Avogrado's No. = 6.023 x 1026/kg mole.
1.(a) Describe the crystal structure of Ba T 1 O3. identify the basis in the unit cell and
discuss some of the applications of the crystal.
(8)
(b) Define ligancy of ionic crystals, explain the significance of critical radius ratio
and obtain its value for a cubic arrangement of packing (ligency8).
(8)

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2. (a) Explain how energy bands are formed in solids. Show that for an intrinsic
semiconductor at low temperatures EF = (EC +EW)/2 where the symbols have there
usual meaning.
(8)
(b)Draw energy band structures for intrinsic, p type and n type of semiconductors
and explain how the Fermi level shifts with temperature. (4)
(c)The density of cu is 8930 km/m3 and its atomic weight is 63.546. If the average
no. of e contributed per atom is 1.23, calculate the free e concentration in cu. (4)
3.(a) Draw the potential barrier for a pn junction and explain how it affects the flow
of carriers. (4)
(b) Explain the CB characteristics of an npn transistor.

(4)

(c) Silver has FCC structure and its atomic radius is 1.441 A. find the spacing of the
(220), (200) and (111) planes. (4)
(d) Calculate the length of a quartz crystal which is used to produce ultrasonic
waves of 2 MHz and whose density and young's modulus are 2.65x 10 3 kg/m3 and 8x
1010N/M2 respectively.
(4)
4. (a) Describe the properties of a piezo electric crystal and a method to method to
produce ultrasonic waves with it.
(8)
(b) Derive an expression for the vertical deflection of an electron in a limited
magnetic field.
(8)
5.

Write short notes on any three of the following:-

(a)

Diamond crystal lattice

(b)

Packing factor of cubic crystals

(c)

Miller indices

(d)

Applications of ultrasonic waves

(e)

CRO and its use in measurements.

(f)

Dual nature of matter and be Broglie equation

(g)

Electrostatic and magnetic focusing.

(18)

Section II
6.

Answer any six of the following:-(18)

(a)What is the difference between thermoplastic and thermosetting resins?

Give suitable examples.
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(b)What are elastomers? What are the advantages of vulcanization of

rubber?
(c)

Write a short note on selection of lubricants.

(d)

Give the classification of polymerization with suitable examples.

(e)

Explain the sludge fluid film and extreme pressure lubrication.

(f)

Distinguish between fluid film and extreme pressure lubrication.

(g) What is meant by BOD and COD of water? give there significance.
(h) Calculate the carbonate and non-carbonate hardness of a sample of water
containing mgCl2 = 95 ppm, mg so4 = Ca(HC03)2 = 16.2 ppm, KCI = 12 ppm and
mg(HC03)2 = 14.6 ppm.
7.(a) Write notes on:(i) Injection moulding

(8)
(ii) Compression moulding.

(b) Describe the demineralization process for softening of water giving suitable
diagram and reactions. What are the advantages and disadvantages of this
method?
(8)
8. (a) Calculate the amount of lime (95% pure) and soda (80% pure) for softening
50,000 it. of water containing mg(HC03)2 = 14.6 ppm, CaSO4 = 6.8 ppm, Ca(HC03)2
= 8.1 ppm, mgSO4 = 12 ppm,
Na2SO4 = 15ppm and SiO2 = 2.ppm.

(6)

(b)
Define flash point and fire point of lubricant. What is the significance of these
tests? (4)
(c)

Write notes on compounding of plastics.

(6)

9.(a) Describe the sources effect and control of water pollution. Describe the
domestic and industrial waste water treatment.
(8)
(b) Describe the mechanism of thick film and boundary lubrication. (8)

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APPLIED SCIENCES-l

(JAN. 2003)

Section I
1.(a) State the basis and lattice type for the following crystal structures:
(i) Iron

(ii) Diamond

(hi) Sodium chloride. (6)

(b)An election with initial horizontal velocity u x enters vertical uniform electric field
Ey. Show that the trajectory of electron within the field region is a parabola. (4)
(c)

Draw following in a cubic unit cell:-

(4)

Planes (121), (110)

Directions (120), (111).
2.(a) Discuss motion of electrons in non-uniform electric field. Hence explain the
principle of electrostatic focusing.
(8)
(b)What is octahedral void? Obtain critical radius ratio for octahedral configuration,
(ligancy 6). (6)
(c)In a CRT employing magnetic deflection, length of the field region along the axis
is 5 cm. Intensity of magnetic field is 5 x 10-5 wb/m2. Distance of screen from center
of the field region is 20cm. Calculate deflection of electron beam if final anode
voltage is 500 volt. Given e = 1.6x10-19 C,me = 9.1x10-31 kg.
(4)
3.(a) State direct and inverse piezoelectric effect. Explain with neat- labeled
diagram the construction and working of piezoelectric oscillator. (8)
(b)Calculate kinetic energy of an electron whose de' Broglie wavelength is the same
as that of 100 keV x-ray photon. Given h = 6.63 x 10 -34 J.S, C = 3x 108 m/s, e = 1.6 x
10-19 C and me = 9.1 x 10-31 kg. (6)
(c) State de' Broglie's relation and show that Bohr's second postulate follows
logically from de' Broglie's hypothesis. (4)
4.

Write short notes on any three of the following:-

(a)

Quartz - A piezoelectric material.

(b)

Applications of ultrasonic waves.

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(c)

Pn junction diode and its characteristics.

(d)

Basic transistor action using common base configuration.

(e)

Concept of Fermi level and Fermi Dirac distribution function.

(f)

Miller indices and crystal lattice planes.

Section II

(At. wts. : H = 1 ; C = 12, 0 = 16, Na = 23, Mg = 24, CI = 35.5, Ca = 40, S = 32, Al

= 27, Fe = 56.)
6. Answer any six of the following:-

(18)

(a) Explain with equations role of coagulants in cold lime soda process.
(b)

Explain condensation polymerization with suitable examples.

(c)

Why does graphics act as a good lubricant on the surface of moon.

(d)

Why 'Hydrazine' is an ideal chemical employed for degassing water.

(e)

Explain the term acid rains.

(f)

Give preparation, properties and uses of polyurethane rubber.

(g)

Discuss the catgon conditioning of water.

(h) 6 gms of an oil was saponified with 50 ml 0.5 N alcoholic KOH. After refluxing for
2 hrs, the mixture was titrated by 25 ml of 0.5 N HCI. Find saponification value of oil.
7. (a) Explain with neat sketch and chemical reaction the zeolite-permutit process
ibr softening of water. What are the advantages and disadvantages of this process.
J6)
(b)Explain the process of vulcanization and its significance? Compare the properties
of raw rubber and vulcanized rubber? (6)
(c)Define flash point and fire of lubricants and give its significance. (4)
8.(a) Calculate the quantities of time(86% pure) required and soda (90% pure)
required for softening 25,000 litres water having following analysis:(7)
HCI = 12.5 mgs/lit, CaC03= 35.2 mgs/lit Na2SO4 = 8.8 mgs/lit, AL2 (S04)3 = 33.3
mgs/lit MgCl2 = 7.8 mgs/lit, Fe2O3 = 18.6 mgs/lit.
(b)
What ingredients are used in the compounding of plastics? What are their
functions? (5)
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(c)

Write a note on blended oils.

(4)

9.(a) Enumerate the methods of control water pollution. Discuss any one in detail.
(6)
(b)0.28 gm of CaCO3 was dissolved in HCI and the solution made up to 1 litre with
distilled water. 100 ml of the above solution required 28 ml of EDTA solution, 100 ml
of hard water sample required 33 ml of EDTA solution. After boiling 100 ml of this
water cooling and filtering and then titration required 10 ml of EDTA solution.
Calculate each type of hardness, of water.
(6)
(c)
What i s meant by fabrication of plastic? Explain Extrusion moulding with neat
sketch.
(4)

APPLIED SCIENCES-I

(JUNE. 2003)

Section I
1.(a) Write two important points regarding diamond structure. How many atoms
are there per unit cell? Derive its packing efficiency. (7)
(B) Define piezo-electric effect, and show how piezo electric oscillator produces
ultrasound (with proper circuit diagram.)
(5)
(c) A charge water drop is just floating in a uniform electric field of 250 V/M. Find the
charge on it. Given: Radius of water drop = 10 -8 m, Density of water = 103 kg/m3.
,(5)
2.

(a) What is potential barrier? How it is formed in a p-n junction? (6)

(b)

What are matter waves? Mention at least three characteristics of them. (5)

(c)An ultrasonic beam of 1 cm wavelength is sent by a ship, returns from the sea
bed after 2 sec. If velocity of ultrasonic beam in sea water is 1510 m/sec at 0C, its
salinity at 30C is 29 gm/lit, calculate the depth of sea bed at 30C and frequency of
ultrasonic beam. (6)
3.(a) Derive the formula for displacement of electron in transverse electric field.
(8)
(b) Explain the construction of C.R.O. and discuss how AC, D.C. voltage, frequency
and phase angle between two A.C. voltage measured by C.R.O. (8)
4. (a) Draw the following:- (/ = read as bar)
(i) (0 /1 1), (1 2 1), (1 /2 3)

(3)

(ii)(0 /1 1),(1 2 1),(1 2 3) (3)

(b) Show that for an instric semiconductors at low temperatures E F= (EC+EV)/2

where symbols have their usual meanings. (8)
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(c)(i) At what angle to the magnetic field the charged particle should entre to
experience maximum force?
(1)
(ii) Show that magnetic force does not act on static charge.

(1)

(iii) If the charged particle enters the magnetic field- either parallel or antiparallel
to the field direction, what is the value of result force?
(1)
5.

Write short note on:

(a)

Significance of ligancy in crystals.

(b)

Use of ultrasonic in Non-Destructive testing. (5)

(c)

Electrostatic and Magnetostatic focusing.

(5)

(6)

Section II
(At wts : H = 1; Ca = 40; mg = 24; C = 12; O = 16; S = 32; Fe = 56)
6.Answer any six of the following:-

(18)

(a) Why is hot lime soda process better than the cold process.
(b) List the difference between addition and condensation polymerization.
(c)

Define grease? Under which situation it is used as a lubricant.

(d)

What is green house effect?

(e) Explain phosphate conditioning of water.

(f) An oil blend used was analysed for its acid value 6 ml of oil required 3.5 ml.
N/100 kOH. Find its acid value state whether the blend can be still be useful for
lubrication (density oil = 0.89).
(g) What is difference between scale & sludge.
(h) Explain the significance of vulcanisation.
7. (a) Explain the demineralization of hard water, with a neat diagram and
appropriate equations.
(6)
(b)

Give preparation properties and uses of silicon rubber.

(c)

Write a note on solid lubricants. (4)

(6)

8. (a) Calculate the quantities of lime and soda (90% pure each) required for
softening 25000 litres of hard water containing following ions/chemicals.
(6)
HCO3= 12.2 PPM; C02 = 4.4PPM;
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Ca++ = 30PPM;

Mg++ = 21.6 PPM;

Fe2O3= 15.4 PPM;

H2SO4 = 4.9PPM.

(b) Give the manufacturing process, properties and uses of Bakelite. (6)
(c) Define lubrication, Explain boundary film lubrication.

(4)

9. (a) What is air pollution? Mention various types of air pollutants and discuss the
effect of following on environment:
(7)
(i) Nitrogen oxides (ii) Hydrogen sulphide (iii) Sulphur dioxide.
(b)
The hardness of 75,000 litres of a water sample was completely removed by
a permutit. The exhausted permutit then required 1500 litres of NaCl containing 117
mg of NaCl per litre regeneration calculate the hardness of water sample.
(5)
(c)Mention the various method used for fabricating plastics and discuss the transfer
moulding in detail? (4)

(APPLIED SCIENCES-l)

(JUNE. 2004)

N.B.:
(1)

Question No. l is compulsory.

(2)

Answer any four out of remaining six questions.

(3)

Assumptions made should be clearly stated.

(4)

Assume any suitable data wherever required but justify the same.

(5)

Figures to the right indicate marks.

(6) Illustrate answers with sketches wherever required.

(7) Answers to questions should be grouped and written together, i.e. all answers to
sub-questions of individual questions like Question Nos. 1,2,3 etc. should be
answered one below the other.
(8) Use legible handwriting. Use a blue/black ink pen to write answers Use of pencil
should be done only to draw diagrams and graphs.
Section I

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1.(a) Show with the help of suitable sketch the proper positions and the co-ordinates
of atoms in a unit cell of diamond structure. Give position co-ordinates of atoms
within the body. Consider one atom to be the closest to the origin.
(5)
(b) Explain procedure to determine Miller Indices of a crystal plane which intercepts
all the three axes. (5)
2. (a) Define - (i) ligancy and (ii) critical radius ratio. Find critical radius ratio for
ligancy '8' (eight). (5)
(b) Find packing density of-(i) BCC and (ii) diamond crystal structure. (5)
3. (a) Explain with proper sketches - (i) direct and (ii) inverse piezoelectric effect.
Explain its application in production of ultrasonic waves. (5)
(b) Two ships are anchored at certain distance between them. An ultrasonic signal of
50 kHz is sent from one ship to another by two routes - (i) through water and (ii)
through atmosphere. The difference between time intervals for receiving the signal
at the other ship is 2 seconds. If velocities of sound in atmosphere and in sea water
are 348 m/s and 1392 m/s respectively, find the distance between the ships. Also
find time taken by the signal to travel through water.
(5)
4. (a) An electron having charge 'e' mass 'm' and velocity V is entering normally a
limited uniform magnetic field of length '/' and strength 'B'. Find expression for
deflection of electron path on the screen
placed at a distance 'D' from the center of the magnetic field.

(5)

(b) Calculate velocities of - (i) a proton and (ii) an electron accelerated through a
potential difference of 5 kV.
(5)
(Given:

electron mass =9.1x10

proton mass = 1.67 x 10

27

-31

kg.

kg.

charge on electron

=e= 1.6x 10-19 C.

charge on proton

=e= 1.6x 10-19 C).

5. (a) Explain formation of energy bands in solids. Explain classification of solids into
conductors, insulators and semiconductors on the basic of energy band theory.
(5)
(b) Explain with neat sketches formation of P-N junction. Explain potential barrier
and its behavior in forward bias and reverse bias conditions.
(5)
6. (a) Explain construction of Cathode Ray Oscilloscope. Explain simple time base
circuit.
(5)
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(b) Show that the De Broglie wave length of a charge particle is inversely
proportional to the square root of accelerating potential. (5)
7.

Write notes on :

(i)

Electrostatic focusing

(5)

(ii)

i/p characteristics of transistor in CB configuration.

(5)

Section II
N.B.
(1)

Attempt two sections on different answer-books.

(2)

Assume suitable data if necessary.

(3) In Section II Question No.l is compulsory. Attempt any three questions from
Question Nos. 2 to 7.
Atomic Weights : H = 1, C = 12, O = 16, Ca = 40, Mg = 24, Na = 23, S = 32, CI =
35.5, is = 28.

1.

(a) What are advantages of Hot lime-soda process? (20)

(b)

What are sources of air-pollution ?

(c)

Which type of lubricants are required for cutting tools, turbines etc ?

(d)
Explain phosphate conditioning as a internal treatment method in case of
boilers.
(e)
Differentiate between Addition polymerization and Condensation
polymerization.
(f)
9 ml oil is taken from machine and it requires 1.5 ml of 0.04 N KOH. Find acid
value, (density of oil = 0.81 g/ml.).
(g)

What are sources and effects of CO as an air-pollutant?

2.

(a) Explain: Boiler corrosion;

(5)

(b) Write a note on Viscosity and Viscosity index.

3.
(a) Describe transfer moulding in polymers.
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(b) Calculate the amount of time and soda required for 50,000 lit. of water sample
containing - (4)
CaCO3 = 10 ppm,
CO2 = 4.4 ppm,
MgCl2 =9.5 ppm,
4.

Mg(HCO3)2 =14.6 ppm

CaCl2= 22.2 ppm
SiO2 = 2.8 ppm

(a) What are the moulding constituents of plastic?

(b) Explain: Ion-Exchange resins.

5.

(4)

(a) What is sewage ? How is it treated by Activated Sludge Method ?

(b) What are functions of lubricant?

6.

(6)

(7)

(3)

(a) Explain : Crepe and smoke rubber. (4)

(b) An exhausted zeolite softener was regenerated by passing 75 liters of NaCl

solution having strength 75 g/lit. If hardness of water is 300 ppm, then claculate the
total volume of water that is softened by zeolite softener. (6)
7.

(a) What is caustic embrittlement in boilers ? (5)

(b) What is cloud point and pour point ? How is it determined ?

APPLIED SCIENCE -I

(5)

(JAN. 2005)

1. (a) Explain how a charged particle fired into uniform electric field describes
parabolic motions. (5)
(b) Define lattice parameter and explain how it is related with molecular weight
and density in a single crystal. (5)
2. (a) Velocity of ultrasound waves in mild steel is 5.9 x 10 3 m/sec. The velocity
ultrasound waves in brass measured by an ultrasound gauge meter, calibrated for
mild steel is 4.8 x 103 m/sec. If thickness of brass plate measured by the ultrasound
gauge meter is 12.8 cm. What is the real thickness ?
(5)
(b) What is the De-Broglie wavelength of an electron which has been accelerated
from rest through a potential difference of 300 volts ? (5)
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3.(a) A water drop is charged by an electron and placed in electric field. What is
the intensity of electric field required to keep the charged drop stationary if radius
of drop is 10-7 m and density of water is 103kg/m3? (5)
(b) Explain wave particle duality and De-Broglie's Hypothesis.

(5)

4.(a) Write short note on formation of potential barrier at p-n junction. (5)
(b) Calculate density of Ga As using following data:

(5)

Atomic weight of Ga: 69 ; Atomic weight of As: 74

Lattice constant for Ga As = 5.6 x 10-8 cm ; Number of atoms per unit cell in GaAs
= 4.
5. (a) Compare De-Broglie wavelength associated with following particles:
i) Mass of 60 micrograms traveling with velocity of 80 m/s.
ii) Mass of 8 x 10-27 kg and traveling with velocity of 13x10 -4 km/sec.
(5)
(b) Explain with neat diagrams, electrostatic or magnetostatic focusing of an
electron beam in C.R.T.
(5)
6. (a) Explain the following:
i) Acceptor impurity.

(5)

iv) Extrinsic Semiconductor,

ii) Donor impurity. v) Fermi level,

iii) Intrinsic semiconductor.
(b) Explain procedure to determine Miller Indices of Crystal plane which intercepts
all the three axes. (5)
7. (a) An electric potential difference of 150 V is used to accelerated an electron
beam. This beam is made to pass through uniform electric field established
perpendicular to its path by a set of rectangular plates of length 10 cm. The
distance between the plates is 1 cm. and potential difference between them is 15 V.
Determine the angle of deflection of the electron beam. (5)
(b) Silver has FCC structure and it's atomic radius is 1.44 A. Find the spacing of
the (220), (200) and (111) planes.
(5)

Section II
1.
Attempt any five of the following:
(10)
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(a) Find out the temporary and permanent hardness in a sample of water with
following impurities :
Mg CO3 = 29.2 ppm, MgSO4 = 36.0 ppm, CaCL2 = 22.2 ppm, MgCl2=142.5ppm.
(b)

What is degree of hardness in water? How is it expressed ?

(c)

What is polymerization ? What are the condition for polymerization ?

(d)
What is neutralization number ? How is it helpful in accessing the quality of
lubricant ?
(e)

Define the terms: (a) Pollution (b) Pollutant.

() What are elastomers ? Mention few drawbacks of natural rubber.

2. (a) Explain the theory of Lime-Soda process with special reference to the
different functions of lime and soda.
(6)
(b) With the help of a suitable example explain condensation. Polymerization. Name
any two-thermosetting resins prepared by using condensation Polymerization. (4)

3. (a) A water sample on analysis gave the following data:

1.

MgCl2 95 ppm

2.

CSO4 272 ppm

3.

MgSO4

4.
5.

H2SO4.

SiO2

(6)

49 ppm

4 ppm

120 ppm

Calculate lime and soda requirement in kg for the softening of 10,000 liters if it is
given that lime is 85% pure and soda is 90% pure.
(b) Explain the mechanism of lubrication which is provided for delicate instruments
and machine.
(4)
4.(a) Write the synthesis, properties and uses of any one of the following:
i)

Phenol formaldehyde

ii)

Urea formaldehyde.

(6)

(b) What are the primary air pollutants ? State their source. How do they affect life
on earth ? (4)
5. (a) What are scales and sludges? What are their disadvantages? How can scale
be prevented by Phosphate conditioning ?
(6)
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(b) What is vulcanization? Explain the mechanism of vulcanization with the help of
suitable example. How is it helpful in removing the drawbacks of natural rubber ?
(4)
6. (a) Write short note on any two of the following: (6)
i)

B. O. D. ii) C.O. D.

iii)

Photochemical Smog.

(b) In determination of saponification value of vegetable oil 5 gm of oil sample was

refluxed with 50 ml of alcohol and 50 ml of 0.5 N alcoholic KOH solution. To get the
end point 20 ml of 0.5 N HCI was required. The blank reading was 52 ml. Find the
saponification value of oil.
(4)
7. (a) What are Zeolities ? Explain theory, procedure and limitations of Zeolite
process with the help of neat diagram. (6)
(b) Give brief account of Semi-Solid lubricants.

APPLIED SCIENCE - I

(4)

(JUNE 2005)

Section I
1. (a) Describe with a neat circuit diagram the production of ultrasound by Piezoelectric effect. Find out the packing density of BCC crystal and show with diagram
that coordination number of F. C. C. is 12.
(6)
(b) An electron beam passes through magnetic field of 2 x 10 -3 Wb/m2 and electric
field of 3.4 x 104 V/m both acting simultaneously at the same point. The path of
electrons remain unchanged. Calculate the electron speed. What will be radius of
circuit path if the electric field in switched off?
(4)
electronic charge = 1.6x 10-19
electronic mass = 9.1 x 10-31 kg.
2.(a)Differentiate between waves and particles and hence interpret wave particle
duality. What is Hole (6)

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Describe the forward and reverse bias characteristics curve of a P-Njunction.

(6)
(b) Silver has FCC structure and its atomic radius is 1.441 A. Find the spacing of the
(220) and (111) planes. (4)
3. (a) Obtain an expression for the final deflection of an electrical charge entering
an electric field perpendicular to the direction of motion. (6)
Write a note on the characteristic curve of a P- N - P transistor with a common base.
(6)
(b) Calculate the length of the quarter crystal which is used to produce ultrasonic
waves of 2 MHz. (4)
Density of the crystal = 2.65 x 103 kg/m3 Young's modulus of quarter = 8x 1010N/m2.
4. (a) Explain with diagram the ligancy and critical radius ratio of a crystal.

(6)

Describe the motion of an electron in crossed electric and magnetic field.

(6)

(b) Calculate the de-Broglie wavelength associated with mass 1 kg moving with a
speed of 103 m/sec. Comment on the de-Broglies wavelength. (4)
5.

Write short notes on any three:

(a)

De-Broglies wave length. (6)

(b)

Miller Indices.

(c)

C.R.O. for voltage and frequency measurement.

(d)

Energy band formation in solids. (6)

(e)

Applications of ultrasound.

(6)
(6)

(6)

Section II
(Atomic Weights : Ca = 40, Mg = 24, H = 1, O = 16, S = 32, SI = 28, CI = 35.5,
C = 12, N = 14)

6.

Attempt any five of the following:-

(10)

(a)

What are Blended oils?

(b)

Give four functions of good quality lubricant.

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(c)

What are thermoplastic and thermosetting resins ?

(d)

Write any four causes of pollution.

(e)

Why hydrazine is preferred over Na2S, Na2 SO3 ?

(f)

Why plasticizers are added during moulding ?

7.

(a)What are applications of rubber? (Give it with the specific property) (4)

(b) Calculate Lime (74% pure) and soda (90% pure) required for 5000 lit, of water
containing following impurities: (6)
Mg(HCO3)2 = 73 mg/lit.

MgSO4= 120 mg/lit.

CaCl2 = 222 mg/lit. Ca(NO3)O2 = 164 mg/lit.

SiO2= 15 mg/lit.

Ca(NO3)2.

8.(a) How demineralisation of water is carried out ?

(7)

(b) Find acid value of 3 gm of oil which required 0.2 m. of 0.025 N KOH to
neutralise free acids present.
(3)
9. (a) Draw the labelled diagram of Hot Lime Soda Process and give only
advantages of the method.
(6)
(b) Explain compression moulding. For which type of polymers it is applicable ?
(4)
10 (a) Where are the solid lubricants used ? Explain only with one example.
(b) Explain-i) Copolymerisation.
ii)

(5)

(3)

Cloud point and pour point. (2)

11 (a) What is sewage? How the activated sludge method is useful in sewage
treatment ? (6)
(b) Calculate total hardness, in ppm, in given water sample

(4)

i)
50 ml standard hard water, containing 1 mg pure CaCO 3 per ml, consumed 20
ml EDTA solution, ii)
50 ml water sample consumed 30 ml EDTA solution using
Erio-Black-T indicator.
12

(a) Explain Extreme Pressure Lubrication.

(5)

(b) Explain the effect of particulate and NOx as the pollutants. (5)

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