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MSDS No.
AG1DF
Revision Date
9/9/2011
IMPORTANT: This MSDS is prepared in accordance with 29 CFR 1910.1200. Read this
MSDS before transporting, handling, storing or disposing of this product and forward this
information to employees, customers and users of this product.
Emergency Overview
Physical State Liquid.
Clear to light amber.
Color
Odor
Hazard Rankings
HMIS NFPA
2
Fire Hazard
Reactivity
Health Hazard
Characteristic,
kerosene-like.
WARNING!
Combustible liquid and vapor. - Can cause flash fire.
Harmful or fatal if swallowed - can enter lungs and cause
damage.
Mist or vapor can irritate the respiratory tract.
Liquid contact can cause eye or skin irritation.
Overexposure can cause central nervous system (CNS)
depression and/or other target organ effects.
Harmful to aquatic organisms.
Long-term exposure to diesel engine exhaust may cause
cancer.
Protective Equipment
Minimum Recommended
See Section 8 for Details
Technical Contact
(800) 423-8434
Product Number
Various
Medical Emergency
(832) 486-4700
CAS Number
Various
CHEMTREC Emergency
(United States Only)
(800) 424-9300
Product Family
Fuels.
Synonyms
No. 1 Ultra Low Sulfur Diesel, Diesel Fuel No. 1; K-1, Fuel Oil; Grade 1 Distilate Fuel;
Kerosene, Low Sulfur Diesel Fuel
SECTION 2. COMPOSITION
This product may be composed, in whole or in part, of any of the following refinery streams:
Hydrodesulfurized Kerosine (Petroleum) [CAS No.: 64742-81-0]
Distillates (petroleum), hydrotreated light [CAS No.: 64742-47-8]
Hydrodesulfurized middle distillate (petroleum) [CAS No.: 64742-80-9]
Distillates, petroleum, hydrodesulfurized light catalytic cracked [CAS No.: 68333-25-5]
Kerosene [CAS No.: 8008-20-6]
This product contains the following components:
Component Name(s)
MSDS No.
AG1DF
Revision Date
9/9/2011
Concentration (%)
Page Number: 1
Mixture.
25550-14-5
91-20-3
25551-13-7
92-52-4
100-41-4
1330-20-7
95-63-6
98-82-8
10 - 30
1-3
0-3
0-2
0-2
0-1
0-1
0-1
0-1
Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs.
Breathing this material may cause central nervous system depression with symptoms
including nausea, headache, dizziness, fatigue, drowsiness, or unconsciousness.
Eye Contact
This material can cause eye irritation with tearing, redness, or a stinging or burning feeling.
Further, it can cause swelling of the eyes with blurred vision. Effects may become more
serious with repeated or prolonged contact.
Skin Contact
May cause mild skin irritation with redness and/or an itching or burning feeling. Effects may
become more serious with repeated or prolonged contact. It is likely that some components
of this material are able to pass into the body through the skin and may cause similar effects
as from breathing or swallowing it.
Ingestion
Chronic Health Effects Prolonged and/or repeated contact may cause skin irritation and inflammation. Symptoms
include defatting, redness, blistering, lesions, and scaly dermatitis.
Summary
Chronic effects of ingestion and subsequent aspiration into the lungs may cause
pneumatocele (lung cavity) formation and chronic lung dysfunction.
Reports have associated repeated and prolonged occupational overexposure to light
petroleum products with irreversible brain and nervous system damage (sometimes referred
to as "Solvent or Painter's Syndrome"). Intentional misuse by deliberately concentrating and
inhaling this product may be harmful or fatal.
Prolonged or repeated overexposure to xylene, a component of this product, has been
associated with hearing damage in laboratory animals.
This material (or a component) may cause harm to the human fetus based on tests with
laboratory animals. This material, or a component of this material, has been shown to cause
cancer in laboratory animals. The relevance of this to humans is not clear.
See Toxicological Information (Section 11)
Conditions Aggravated Medical conditions aggravated by exposure to this material may include skin disorders,
chronic respiratory diseases, neurological conditions, liver or kidney dysfunction.
by Exposure
May cause damage to the following organs: kidneys, liver, upper respiratory tract, skin, eyes,
Target Organs
central nervous system (CNS).
MSDS No.
AG1DF
Revision Date
9/9/2011
Page Number: 2
Sensitizer
Combustible
Toxic
Highly Toxic
Corrosive
Carcinogenic
Irritant
Explosive
Pyrophoric
Flammable
Oxidizer
Water-reactive
Compressed Gas
Organic Peroxide
Unstable
Move victim to fresh air. If victim is not breathing, immediately begin rescue breathing. If
breathing is difficult, 100 percent humidified oxygen should be administered by a qualified
individual. Seek medical attention immediately. Keep the affected individual warm and at
rest.
Eye Contact
Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water for at
least 15 minutes while occasionally lifting and lowering eyelids. Do not use eye ointment
unless directed to by a physician. Seek medical attention if excessive tearing, irritation, or
pain persists.
Skin Contact
Remove contaminated shoes and clothing. Flush affected area with large amounts of water.
If skin surface is damaged, apply a clean dressing and seek medical attention. Do not use
ointments. If skin surface is not damaged, clean affected area thoroughly with mild soap and
water. Seek medical attention if tissue appears damaged or if pain or irritation persists.
Ingestion
Do not induce vomiting. If spontaneous vomiting is about to occur, place victims head below
knees. If victim is drowsy or unconscious, place on the left side with head down. Never give
anything by mouth to a person who is not fully conscious. Do not leave victim unattended.
Seek medical attention immediately.
Notes to Physician
INHALATION: Inhalation overexposure can produce toxic effects. Monitor for respiratory
distress. If cough or difficulty in breathing develops, evaluate for upper respiratory tract
inflammation, bronchitis, and pneumonitis. Administer supplemental oxygen with assisted
ventilation, as required.
INGESTION: If ingested, this material presents a significant aspiration and chemical
pneumonitis hazard. Induction of emesis is not recommended. Consider activated charcoal
and/or gastric lavage. If patient is obtunded, protect the airway by cuffed endotracheal
intubation or by placement of the body in a Trendelenburg and left lateral decubitus position.
MSDS No.
AG1DF
Revision Date
9/9/2011
Page Number: 3
Flash Point
>210C (>410F)
Hazardous Combustion Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and trace oxides
Products
of sulfur and/or nitrogen.
Special Properties
Combustible Liquid! This material releases vapors when heated above ambient
temperatures. Vapors can cause a flash fire. Vapors can travel to a source of ignition and
flashback. A vapor and air mixture can create an explosion hazard in confined spaces such
as sewers. Use only with adequate ventilation. If container is not properly cooled, it can
rupture in the heat of a fire.
Extinguishing Media
SMALL FIRE: Use dry chemicals, carbon dioxide, foam, or inert gas (nitrogen). Carbon
dioxide and inert gas can displace oxygen. Use caution when applying carbon dioxide or
inert gas in confined spaces.
LARGE FIRE: Use foam, water fog, or water spray. Water fog and spray are effective in
cooling containers and adjacent structures. However, water can cause frothing and/or may
not extinguish the fire. Water can be used to cool the external walls of vessels to prevent
excessive pressure, autoignition or explosion. DO NOT use a solid stream of water directly
on the fire as the water may spread the fire to a larger area.
Protection of Fire
Fighters
Firefighters must use full bunker gear including NIOSH-approved positive pressure
self-contained breathing apparatus to protect against potential hazardous combustion or
decomposition products and oxygen deficiencies. Evacuate area and fight the fire from a
maximum distance or use unmanned hose holders or monitor nozzles. Cover pooling liquid
with foam. Containers can build pressure if exposed to radiant heat; cool adjacent containers
with flooding quantities of water until well after the fire is out. Withdraw immediately from the
area if there is a rising sound from a venting safety device or discoloration of vessels, tanks,
or pipelines. Be aware that burning liquid will float on water. Notify appropriate authorities of
potential fire and explosion hazard if liquid enter sewers or waterways.
MSDS No.
AG1DF
Revision Date
9/9/2011
Page Number: 4
Handling
Storage
Consult appropriate federal, state and local authorities before reusing, reconditioning,
reclaiming, recycling or disposing of empty containers or waste residues of this product.
MSDS No.
AG1DF
Revision Date
9/9/2011
Page Number: 5
Personal Protective
Equipment
Personal protective equipment should be selected based upon the conditions under which
this material is used. A hazard assessment of the work area for PPE requirements should
be conducted by a qualified professional pursuant to OSHA regulations. The following
pictograms represent the minimum requirements for personal protective equipment. For
certain operations, additional PPE may be required.
Eye Protection
Safety glasses equipped with side shields are recommended as minimum protection in
industrial settings. Chemical goggles should be worn during transfer operations or when
there is a likelihood of misting, splashing, or spraying of this material. A suitable emergency
eye wash water and safety shower should be located near the work station.
Hand Protection
Avoid skin contact. Use heavy duty gloves constructed of chemical resistant materials such
as Viton or heavy nitrile rubber. Wash hands with plenty of mild soap and water before
eating, drinking, smoking, use of toilet facilities or leaving work. DO NOT use gasoline,
kerosene, solvents or harsh abrasives as skin cleaners.
Avoid skin contact. Wear long-sleeved fire-retardant garments (e.g., Nomex) while
working with flammable and combustible liquids. Additional chemical-resistant protective
gear may be required if splashing or spraying conditions exist. This may include an apron,
boots and additional facial protection. If product comes in contact with clothing, immediately
remove soaked clothing and shower. Promptly remove and discard contaminated leather
goods.
Body Protection
Respiratory Protection For known vapor concentrations above the occupational exposure guidelines (see below),
use a NIOSH-approved organic vapor respirator if adequate protection is provided.
Protection factors vary depending upon the type of respirator used. Respirators should be
used in accordance with OSHA requirements (29 CFR 1910.134). For airborne vapor
concentrations that exceed the recommended protection factors for organic vapor
respirators, use a full-face, positive-pressure, supplied air respirator. Due to fire and
explosion hazards, do not enter atmospheres containing concentrations greater than 10% of
the lower flammable limit of this product.
General Comments
Warning! Use of this material in spaces without adequate ventilation may result in
generation of hazardous levels of combustion products and/or inadequate oxygen levels for
breathing. Odor is an inadequate warning for hazardous conditions.
Kerosene
Nonane, all isomers
Naphthalene
AG1DF
Revision Date
9/9/2011
Page Number: 6
Biphenyl (Diphenyl)
Ethylbenzene
Cumene
Liquid.
Color
Clear to light
amber.
Odor
Characteristic, kerosene-like.
Specific Gravity
0.82 (Water = 1)
pH
Not applicable
Vapor
Density
4 (Air = 1)
Boiling Range
Melting/Freezing
Point
Not available.
Vapor Pressure
Volatility
Solubility in
Water
Viscosity
(cSt @ 40C)
AP 3
Flash Point
Additional
Properties
Chemical Stability
Stable.
Conditions to Avoid
Keep away from heat, flame and other potential ignition sources. Keep away from strong
oxidizing conditions and agents.
Materials
Incompatibility
Strong acids, alkalies, and oxidizers such as liquid chlorine, other halogens, hydrogen
peroxide and oxygen.
Hazardous
Decomposition
Products
No additional hazardous decomposition products were identified other than the combustion
products identified in Section 5 of this MSDS.
MSDS No.
AG1DF
Revision Date
9/9/2011
Page Number: 7
Naphthalene:
Studies in Humans Overexposed to Naphthalene:
Severe jaundice, neurotoxicity (kernicterus) and fatalities have been reported in young
children and infants as a result of hemolytic anemia from over-exposure to naphthalene.
Persons with Glucose 6-phosphate dehydrogenase (G6PD) deficiency are more prone to the
hemolytic effects of naphthalene. Adverse effects on the kidney have also been reported
from over-exposure to naphthalene but these effects are believed to be a consequence of
hemolytic anemia, and not a direct effect.
Studies in Laboratory Animals:
Hemolytic anemia has been observed in laboratory animals exposed to naphthalene.
Laboratory rodents exposed to naphthalene vapor for 2 years (lifetime studies) developed
non-neoplastic and neoplastic tumors and inflammatory lesions of the nasal and respiratory
tract. Cataracts and other adverse effects on the eye have been observed in laboratory
animals exposed to high levels of naphthalene. Findings from a large number of bacterial
and mammalian cell mutation assays have been negative. A few studies have shown
chromosomal effects (elevated levels of Sister Chromatid Exchange or chromosomal
aberrations) in vitro.
:
Trimethylbenzenes, all isomers
Studies of Workers:
Levels of total hydrocarbon vapors present in the breathing atmosphere of these workers
ranged from 10 to 60 ppm. The TCLo for humans is 10 ppm, with somnolence and
respiratory tract irritation noted.
Studies in Laboratory Animals:
In inhalation studies with rats, four of ten animals died after exposures of 2400 ppm for 24
hours. An oral dose of 5 mL/kg resulted in death in one of ten rats. Minimum lethal
intraperitoneal doses were 1.5 to 2.0 mL/kg in rats and 1.13 to 12 mL/kg in guinea pigs.
Mesitylene (1, 3, 5 Trimethylbenzene) inhalation at concentrations of 1.5, 3.0, and 6.0 mg/L
for six hours was associated with dose-related changes in white blood cell counts in rats. No
significant effects on the complete blood count were noted with six hours per day exposure
for five weeks, but elevations of alkaline phosphatase and SGOT were observed. Central
nervous system depression and ataxia were noted in rats exposed to 5,100 to 9,180 ppm for
two hours.
Biphenyl (Diphenyl):
Studies in Humans Overexposed to Biphenyl:
Evidence of adverse effects on the liver and the nervous system have been described in
studies of workers exposed to high levels for prolonged periods.
Studies in Laboratory Animals:
Evidence of adverse effects on the kidney and liver, and changes in whole blood (reduced
hematocrit and hemoglobin levels) have been observed in laboratory rodents following
subchronic exposure to biphenyl.
Genotoxicity & Carcinogenicity:
Biphenyl tested negative in bacteriological systems but some evidence of positive responses
have been reported in mammalian cell systems in the presence of metabolic activation. The
EPA has determined human and animal data are inadequate to classify the carcinogenic
potential of biphenyl.
Ethylbenzene:
Effects from Acute Exposure:
ORAL (LD50), Acute: 3,500 mg/kg [Rat].
DERMAL (LD50), Acute: 17,800 uL/kg [Rabbit].
MSDS No.
AG1DF
Revision Date
9/9/2011
Page Number: 8
Cumene:
Effects from Acute Exposure:
Overexposure to cumene may cause upper respiratory tract irritation and severe CNS
depression.
Effects from Prolonged or Repeated Exposure:
Studies in laboratory animals indicate evidence of adverse effects on the kidney and adrenal
glands following high level exposure. The relevance of these findings to humans is not clear
at this time. IARC has classified cumene as possibly carcinogenic to humans (Group 2B).
Freshwater Toxicity:
Concentration: 2400 ppm
cephalus) Effect: TLM
Concentration: >127 ppm
Effect: LC50
Exposure: 48 hrs.
Exposure: 96 hrs.
Saltwater Toxicity
Concentration: 10 ppm Exposure: 96 hrs. Species: Menhaden ( Brevoortia patronus)
Effect: LC50
Concentration: 10 ppm Exposure: 96 hrs. Species: Grass Shrimp Effect: LC50
Environmental Fate
MSDS No.
AG1DF
Revision Date
9/9/2011
Page Number: 9
AG1DF
NA 1993 or UN 1202
A Reportable Quantity (RQ) has not been established for this material.
Placard(s)
MSDS No.
III
Revision Date
9/9/2011
Emergency Response
Guide No.
128
Page Number: 10
This product and/or its components are listed on the Toxic Substances Control Act (TSCA)
inventory.
SARA 302/304
Emergency Planning
and Notification
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities
subject to Subparts 302 and 304 to submit emergency planning and notification information
based on Threshold Planning Quantities (TPQs) and Reportable Quantities (RQs) for "Extremely
Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355. No components were identified.
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities
subject to this subpart to submit aggregate information on chemicals by "Hazard Category" as
defined in 40 CFR 370.2. This material would be classified under the following hazard categories:
The Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
requires notification of the National Response Center concerning release of quantities of "hazardous
substances" equal to or greater than the reportable quantities (RQ's) listed in 40 CFR 302.4. As
defined by CERCLA, the term "hazardous substance" does not include petroleum, including crude oil
or any fraction thereof which is not otherwise specifically designated in 40 CFR 302.4. Chemical
substances present in this product or refinery stream that may be subject to this statute are:
Naphthalene [CAS No.: 91-20-3] RQ = 100 lbs. (45.36 kg) Concentration: <3%
Ethylbenzene [CAS No.: 100-41-4] RQ = 1000 lbs. (453.6 kg) Concentration: <1%
Xylene, all isomers [CAS No.: 1330-20-7] RQ = 100 lbs. (45.36 kg) Concentration: <1%
Cumene [CAS No.: 98-82-8] RQ = 5000 lbs. (2268 kg) Concentration: <1%
Benzene [CAS No.: 71-43-2] RQ = 10 lbs. (4.536 kg) Concentration: <0.05%
CERCLA
Clean Water Act (CWA) This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil
Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the
United States, their adjoining shorelines, or into conduits leading to surface waters must be
reported to the EPA's National Response Center at (800) 424-8802.
California
Proposition 65
This material may contain the following components which are known to the State of California to
cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of
California Proposition 65 (CA Health & Safety Code Section 25249.5):
Naphthalene: <3%
Ethylbenzene: <1%
Cumene: <1%
Diesel exhaust particulate
Toluene: <0.05%
Benzene: <0.05%
New Jersey
Right-to-Know Label
Diesel Fuel
Additional Remarks
Federal Hazardous Substances Act, related statutes, and Consumer Product Safety Commission
regulations, as defined by 16 CFR 1500.14(b)(3) and 1500.83(a)(13): This product contains
"Petroleum Distillates" which may require special labeling if distributed in a manner intended or
packaged in a form suitable for use in the household or by children. Precautionary label dialogue
should display the following: DANGER: Contains Petroleum Distillates! Harmful or fatal if
swallowed! Call Physician Immediately. KEEP OUT OF REACH OF CHILDREN!
MSDS No.
AG1DF
Revision Date
9/9/2011
Page Number: 11
EQ: Equal
ND: No Data
DISCLAIMER OF LIABILITY
THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE.
HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED
REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE
FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED
AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER
PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN
INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR
PARTICULAR PURPOSE.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE
BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO
NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE
ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE
PRODUCT.
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END OF MSDS
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