I UNIT TEST 2016 - 17

CLASS XII
CHEMISTRY
Time 90 Minutes

Marks - 40

Note - Attempt all the questions, marks of each question are indicate against it
Q -1

Express the relation between conductivity and molar conductivity of a

solution held in a cell?

Q-2

Define order of reaction.

Q -3

A chemical reaction is of second order w.r.t. a reactant. How will the

rate of reaction be affected if the concentration of this reactant is :
(a) Doubled (b) Reduced to 1/4th.

Q-4

What is meant by the molality of solution?

Q -5

What are the sign of H and S for physisorption?

Q-6

How much electricity is required in coulomb for the conversion of

(i) 1 mol of H2O to O2?
(ii) 1 mol of MnO4 to Mn2+?

Q -7

If half life of a first order reaction is x and 3/4th life period of the
same reaction is y, How X and y are related to each other.

Q -8

Differentiate between lyophilic and lyophobic colloids. Also give an

example of each

Q-9

What are Emulsions ? Explain with examples. What is the role of an

emulsifying agent.

Q -10

State henrys law. What are its limitations? Give one application of
Henrys law

Q -11

A solution containing 15 g urea ( molar mass = 60 g/mol) per litre of

solution in water has the same osmotic pressure ( Isotonic) as a
solution of glucose ( molar amss = 180 g/mol) in water. Calculate the
mass of glucose present in one litre of its solution.
Or
A 5% solution (by mass) of cane sugar( C12H22O11) in water has freezing
point of 271K. Calculate the freezing point of 5% glucose (C6H12O6) in
water if freezing point of pure water is 273.15 K.

Q-12

What are fuel cells? Explain working of H O cell. What are advantages
of using fuel cells?

Q-13

(a) State Raults law for a solution containing volatile components.

(b) Non ideal solution exhibits either positive or negative deviation
from the Raults law. What are the difference between these
deviations? Explain with one example of each.

Q -14

The rate of a reaction doubles when the temperature changes from

3
0
0
27 C to 37 C Calculate the energy of activation of the reaction
assuming that it does not change with temperature. ( R = 8.314 J/K/Mol)

Q -15

The half-life decay of radioactive C-14 is 5730 years. N archaeological

artifact containing wood had only 80% of the C-14 found in a living
tree. Estimate the age of the sample

Q-16

(a) State and explain Kohlrausch law of independent migration of

ions. Write any two applications of it

(b) Calculate the emf of the cell anf G0 for the cell reaction at 250C.
Zn(s) / Zn2+ (0.1M) Cd2+ (.01M) / Cd(s)
(Given E0Zn2+/Zn = - 0.76 V and E0Cd2+/Cd = - 0.40 V)
1F = 96500 C and R = 8.314 JK-1Mol-1
Q -17

Explain the following terms: (i) Peptisation (ii) Electrophoresis

(iii) Dialysis (iv) Coagulation (v) Shape selective Catalysis