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looking good
Tinuvin, Chimassorb, Lignostab,
Irganox, Irgafos,
Irgaguard, Irgarol, Tinopal
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Table of content
2-3
Introduction
4-5
6-7
UV absorbers
8-9
10 - 11
12 - 13
14 - 15
Product range of
Tinuvin DW, Tinuvin 5000 and HALS blends
18 - 19
Antioxidants (AO)
20 - 21
22 - 23
24 - 25
Biocides
26
Optical brighteners
27
16
Product range of
biocides and optical brighteners
28 - 29
Tinuvin DW
Tinuvin 5000 series
17
30 - 31
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Meeting tomorrows
coatings challenges today
EDC_1112_e_BR_Performance_Additives_ES.indd 4
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Introduction
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In order to protect organic substrates against harmful UVradiation and subsequent photo oxidation followed by photo
degradation the use of appropriate light stabilizers such as UV
absorbers (UVA) and free-radical scavengers such as hindered
amine light stabilizers (HALS) is necessary. UV absorbers lter
out the harmful UV light, thereby preventing color change of the
resin, of the substrate underneath and of colorants in coatings,
inks, adhesives and sealants. HALS trap free radicals once they
are formed and are effective in preventing surface defects such
as loss of gloss, cracking and chalking. While HALS are,
technically speaking, a class of antioxidants or free-radical
scavengers, the term antioxidant or AO generally refers to
additives that are primarily used as heat stabilizers. Today the
most commonly used AOs are based on sterically hindered
phenol, thioether or phosphite technologies.
CH
1
h
CH
2
4
Rr
CH*
P-H
O2
ROO r
POO r
P-H
Pr
RO r + r OH
PO r + r OH
6
ROOH
POOH
P-H
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antioxidants
mode of action
usage area
interior/exterior
exterior
interior/exterior
prevents
photo degradation
thermal oxidation
protect what?
coating surface
pigments in coatings
coating
protects against
yellowing
blistering
loss of adhesion
surface defects
loss of mechanical properties
loss of water impermeability
pigment fading
yellowing
embrittlement
loss of mechanical properties
chemical classes
2-hydroxyphenyl-benzophenones (BP)
2-(2-hydroxyphenyl)-benzotriazole (BTZ)
2-hydroxyphenyl-s-triazines (HPT)
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UV absorbers
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2
R1
HO
10 - 20 m
8-4
20 - 40 m
4-2
BTZ
R3
T
R2
R1
40 - 80 m
N
N
N
R3
H-O -
R1
N
N
N
R2
R1
2-1
HPT
Fig. 2: General structures of 2-hydroxyphenylbenzophenones (BP), 2-(2-hydroxyphenyl)-benzotriazole
(BTZ) and 2-hydroxyphenyl-s-triazine (HPT) UV absorbers
HO
R2
O
H +
R2 N
h
N
R2
N
R3
R2
N
R3
R3
R3
R1
H
O
R3
HO
N
N
N
R1
HO
R2 N
R2
R2
R
BP
BTZ
R3
HPT
Lambert-Beer Law
Transmittance T decreases exponentially,
absorbance A increases direct
proportionally to
chromophore concentration c
light path length or lm thickness d
extinction coefcient
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1
T
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10
Product range of
Tinuvin and Chimassorb
Physicochemical prameters
Product name
Chemistry
physical form
Mw
Mp
(g/mol)
(C)
automotive and
transportation
industrial
BP
solid
326
47 - 51
Chimassorb 90
BP
solid
228
61 - 65
Tinuvin 1130
BTZ
liquid
mix
Tinuvin 326
BTZ-Cl
solid
316
138 - 142
Tinuvin 384-2
BTZ
liquid
95 % in 1-methoxy-2-propyl acetate
452
Tinuvin 99-2
BTZ
liquid
95 % in 1-methoxy-2-propyl acetate
452
Tinuvin 900
BTZ
solid
448
138 - 142
Tinuvin 928
BTZ
solid
442
109 - 113
Tinuvin Carboprotect
BTZ
solid
560
132 - 136
bis- and tris-resorcinyl-triazine UVA (HPT), high photo and thermal permanence
Tinuvin 460
HPT
solid
630
97 - 101
Tinuvin 477
HPT
liquid
80 % in 2-methoxy-1-propyl acetate
mix
2-hydroxyphenyl-s-triazine UVA (HPT), best photo and thermal permanence, no interaction with amine, strong alkali or any metal catalyst, pronounced absorbance in UV-B range
Tinuvin 1577 ED
HPT
solid
425
147 - 151
Tinuvin 400
HPT
liquid
85 % in 1-methoxypropan-2-ol
647
Tinuvin 405
HPT
solid
584
73 - 77
Tinuvin 479
HPT
solid
678
39 - 43 1
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Tg (C)
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11
Market segment
furniture and
ooring
printing and
packaging
Application / remarks
architectural
adhesives
sealants
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12
Hindered amine
light stabilizers (HALS)
Hindered amine light stabilizers (HALS) are mainly derivatives of
2,2,6,6-tetramethyl piperidine (TMP). They act as radical scavengers
in the autoxidation cycle (see g.1) and inhibit the photo-oxidative
degradation of polymers in coatings, adhesives and sealants.
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Pigmentation
clear
semi-transparent
opaque
1
2
1-2
1-2
1-2
0-1
1-2
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R3
HN
N
R1 N
(CH2)8
O
13
N R1
R2
N H
pkb ~ 4 - 5
Tinuvin 770 DF
N CH3
pkb ~ 5 - 6
Tinuvin 292
Tinuvin 144
N (CH2)2 OR
pkb ~ 7 - 8
Tinuvin 622 SF
N OR
pkb ~ 8 - 10
Tinuvin 123
Tinuvin 152
Tinuvin 5100
N
N
2
N R
O
N
N
1
R1
Rr
2
N R
h, O2
N Or
ROH + R=O
N OR
ROO r
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Physicochemical prameters
Product name
Chemistry
physical form
Mw
Mp
(g/mol)
(C)
automotive and
transportation
industrial
lignin stabilizer
Lignostab 1198
lignin stabilizer
solid
172
66 - 70
Lignostab 1198 L
lignin stabilizer
solution
liquid
20 % in water
172
Tinuvin 123
N-OR HALS
liquid
737
Tinuvin 152
N-OR HALS
solid
757
72 - 76 1
Tinuvin 5100
N-OR HALS
liquid
737
Tinuvin 770 DF
N-H HALS
solid
480
81 - 85
Tinuvin 144
N-alkyl HALS
solid
685
148 - 152
Tinuvin 292
N-alkyl HALS
liquid
509 / 370
Tinuvin 292 HP
N-alkyl HALS
liquid
509 / 370
oligomeric
N-alkyl HALS
solid
3.100 - 4.000
57 - 61 1
oligomeric
N-H HALS
solid
2.600 - 3.400
92 - 96 1
Chimassorb 944 LD
oligomeric
N-H HALS
solid
2.000 - 3.100
90 - 94 1
HALS
oligomeric HALS
Tinuvin 622 SF
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Tg (C)
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15
Market segment
furniture and
ooring
printing and
packaging
Application / remarks
architectural
adhesives
sealants
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Tinuvin DW
Tinuvin DW are aqueous preparations of light stabilizers for all waterbased applications. Based on Novel Encapsulated Additive Technology
(NEAT), Tinuvin DW is supplied as low-viscous, solvent-free, storageand sedimentation-stable product form.
Tinuvin DW represents a range of selected BTZ and
HPT UVA as well as of N-OR HALS preparations. These
light stabilizer preparations are based on a proprietary
encapsulation technique where actives are essentially
dissolved in an acrylic copolymer matrix. The NEAT-based
preparations exhibit excellent long-term storage stability
without any sedimentation or phase separation in their delivery
form. The absence of Xi R43 labels and of co-solvents makes
them the ideal choice for low- to zero-VOC applications.
They are easy to incorporate and homogeneously disperse
into water and/or water-based paints and allow the post
addition at the end of the production process under normal
stirring conditions without specic equipment and/or
dispersing aids, e.g., emulsiers or dispersants. After being
incorporated into the liquid paint they do not impair paint
properties and storage stability. The Tinuvin DW range fully
maintains dry-lm properties such as inherent color, gloss
and transparency. Other properties such as water permeability
and blocking resistance, hardness and scratch resistance
are not affected.
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17
BASF Tinuvin 5000 series and other Tinuvin blends offer synergistic
combinations against surface defects, as well as color and gloss
retention in coatings, adhesives and sealants applications.
The Tinuvin 5000 series is attractive in its ease of use and its
broad and advantageous solubility and compatibility within
most solvent-based coating systems. The Tinuvin 5000 family
matches all performance requirements for architectural,
industrial and automotive applications.
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Market segment
Product name
Chemistry
Physical form
automotive and
transportation
industrial
furniture and
ooring
printing and
packaging
blends
Tinuvin 5050
liquid
Tinuvin 5060
liquid
Tinuvin 5151
liquid
Tinuvin 5248
liquid
Tinuvin 5251
liquid
Tinuvin 5272
liquid
Tinuvin 5460
liquid
Tinuvin 5866
solid
Tinuvin 5941-R
liquid
solid
solid
Tinuvin B 75
liquid
Tinuvin B 97
liquid
N-OR HALS
liquid 30 % active
Tinuvin 99-DW
BTZ
liquid 24 % active
Tinuvin 400-DW
HPT
liquid 20 % active
Tinuvin 477-DW
HPT
liquid 20 % active
Tinuvin 479-DW
HPT
liquid 20 % active
Tinuvin 5333-DW
UVA HALS
liquid 40 % active
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19
nt
Application / remarks
architectural
adhesives
sealants
HALS blend for powder coating application with triboelectric charging activity
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high-performance UVA / non-reacting HALS light stabilizer blend with broad spectral coverage
for high-durability requirements in joinery, GIP, plastic, glass and decorative applications
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20
Antioxidants (AO)
Fig. 7: AO structures
hindered
phenol AO
phosphite AO
2
OH
R2
thioether AO
R
R1
R3
R3
O
R1
P(R)3-x
S(R)2
Hindered phenol AO
Thioether AO
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21
Fig. 8: Mechanism of AO
hindered phenol AO
O
Or
OH
R2
R1
+ ROO
R2
R2
R1
R1
+ ROO
R2
R3
R1
-ROR3
r
3
R2
R1
R3
OOR
O
p-Benzoquinone
phosphite AO
R2
R3
R2
O
R1
P + ROOH
R3
O
R1
P=O
+ ROH
thioether AO
S(R)2
+ ROOH
(R)2 S=O
+ ROH
Phosphite AO
Oligomeric HALS
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Product range of
antioxidants
Physicochemical prameters
Product name
Chemistry
physical form
Mw
Mp
(g/mol)
(C)
automotive and
transportation
industrial
Irganox 1010
phenol
solid
1.178
110 - 125
Irganox 1035
phenol
solid
643
63 - 78
Irganox 1076
phenol
solid
531
50 - 55
Irganox 1098
phenol
solid
637
156 - 161
Irganox 1135
phenol
liquid
39
Irganox 1330
phenol
solid
775
240 - 245
Irganox 1425
calcium
phosphonate
solid
695
> 260
Irganox 1520 L
phenol
liquid
425
13 - 14
Irganox 1726
phenol
liquid
537
27 - 29
Irganox 245
phenol
solid
587
76 - 79
Irganox 245 DW
phenol
liquid
587
Irganox 3114
phenol
solid
784
218 - 223
Irganox 565
phenol
solid
589
91 - 96
metal deactivator
solid
553
221 - 232
Irganox PS 800
thioether
solid
515
39 - 41
Irganox PS 802
thioether
solid
531
50 - 55
Irgafos 126
phosphite
solid
604
160 - 175
Irgafos 168
phosphite
solid
647
183 - 186
Irganox MD 1024
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23
Market segment
furniture and
ooring
printing and
packaging
Application / remarks
architectural
EDC_1112_e_BR_Performance_Additives_ES.indd 24
adhesives
sealants
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24
Product range of
antioxidant blends
Physicochemical prameters
Product name
Chemistry
Mp
physical form
(C)
automotive and
transportation
industrial
AO blends
Irganox B 215
phenol / phospite
solid
116 - 179
Irganox B 225
phenol / phospite
solid
> 100
Irganox B 561
phenol / phospite
solid
> 60
Irganox B 612
phenol / phospite
solid
> 60
Irganox B 900
phenol / phospite
solid
59 - 61
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Market segment
printing and
packaging
Application / remarks
architectural
adhesives
sealants
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Biocides
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Optical brighteners
Tinopal NFW liquid is a biphenyl-stilbene derivative for waterbased white and pastel-tone paints, clear coats and overprint
varnishes to mask the yellowish inherent color and to intensify
the brilliance of white and colored base coats.
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Physicochemical prameters
Product name
CAS
Chemistry
physical form
Mw
Mp
(g/mol)
(C)
automotive and
transportation
industrial
antimicrobials
Irgaguard B 1000
3380-34-5
organic antimicrobial
solid
290
56 - 58
Irgaguard H 6000
n.n.
silver-glass / zeolite
solid
~ 600
Irgaguard D 1071
28159-98-0
organic algicide
solid
253
128 - 133
Irgarol 1051
28159-98-0
organic algicide
solid
253
129 - 133
27344-41-8
biphenyl-stilbene
liquid
563
Tinopal OB CO
7128-64-5
benzoxazole
solid
431
196 - 203
Tinopal SFP
41098-56-0
triazine-stilbene
solid
1,305
optical brightener
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Market segment
furniture and
ooring
printing and
packaging
Application / remarks
architectural
adhesives
sealants
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2-(2-hydroxyphenyl)-benzotriazole (BTZ)
1,50
1.0
1,25
absorbance / AU
absorbance / AU
0.75
1,00
0,75
0,50
0.5
0.25
0.25
0
290
310
330
350
370
390
410
0
290
430
310
330
wavelength / nm
Tinuvin 326
350
370
390
410
430
wavelength / nm
Tinuvin 384-2
Tinuvin 928
Tinuvin
Carboprotect
Tinuvin 99-2
Tinuvin 1130
Tinuvin 900
2-hydroxyphenyl-s-triazine (HPT)
2.5
2.5
2.0
absorbance / AU
absorbance / AU
2.0
1.5
1.0
1.5
1.0
0.5
0.5
0
290
310
330
350
370
390
410
430
290
310
Tinuvin 400
Tinuvin 405
EDC_1112_e_BR_Performance_Additives_ES.indd 31
330
350
370
390
410
430
wavelength / nm
wavelength / nm
Tinuvin 1577 ED
Tinuvin 460
Tinuvin 477
Tinuvin 479
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31
1.5
1.25
1.25
1.0
1.0
absorbance / AU
absorbance / AU
1.5
0.75
0.5
0.25
0.75
0.5
0.25
0
290
0
310
330
350
370
390
410
430
290
310
330
wavelength / nm
Tinuvin 5248
Tinuvin 5460
Tinuvin 5251
Tinuvin 5272
Tinuvin 5151
Tinuvin 5866
390
410
430
Tinuvin 5050
Tinuvin 5060
1.5
1.5
1.25
1.0
1.0
absorbance / AU
absorbance / AU
370
Tinuvin DW series
2-hydroxy-benzophenone (BP)
0.75
0.5
0.75
0.5
0.25
0.25
0
290
350
wavelength / nm
310
330
350
370
390
410
430
290
310
330
Chimassorb 81
EDC_1112_e_BR_Performance_Additives_ES.indd 32
Chimassorb 90
350
370
390
410
430
wavelength / nm
wavelength / nm
Tinuvin 99-DW
Tinuvin 479-DW
Tinuvin 400-DW
Tinuvin 5333-DW
Tinuvin 477-DW
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Contacts worldwide
Asia
BASF East Asia Regional Headquarters Ltd.
45/F, Jardine House
No. 1 Connaught Place
Central
Hong Kong
Tel.: +852 2731-0111
Fax: +852 2731-5633
tinuvin_asia@basf.com
North America
BASF Corporation
Resins & Additives
1609 Biddle Avenue
Wyandotte, MI 48192
USA
Tel.: +1 800 231-7868
Fax: +1 800 392-7429
polyorders@basf.com
Mexico
BASF Mexicana S.A. de C.V.
A. Insurgentes Sur 975
Col. Ciudad de los Deportes
03710 Mexico, D.F.
Mexico
Tel.: +52 55 5325-2787
+52 55 5325-2687
Fax: +52 55 5611-4897
EDC 1112 e
South America
BASF S.A.
Av. Faria Lima 3600 10 andar
Itaim Bibi So Paulo SP
04538-132
Brazil
Tel.: +55 11 3043-3637
Fax: +55 11 3043-3110
BASF SE
67056 Ludwigshafen
Germany
www.basf.com/additives
The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not
relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any
descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed
contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights
and existing laws and legislation are observed. When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene
measures adequate for handling chemicals must be observed.
= registered trademark of the BASF Group
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