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2184 to 2190
#2003 The Japan Institute of Metals
EXPRESS REGULAR ARTICLE
Research Institute of Engineering and Technology, Korea University, Seoul, 136-701, Korea
Division of Materials Science and Engineering, Korea University, Seoul, 136-701, Korea
Microstructures and strength of variously heat treated eutectoid steel were evaluated by magnetic property measurements. Isothermal
transformation, continuous cooling or spheroidization heat treatment was performed to produce various microstructures. Microstructural
parameters (phase, pearlite interlamellar spacing), mechanical properties (fracture strength) and magnetic parameters (coercivity, remanence,
hysteresis loss, saturation magnetization) were measured to investigate the relationships among these parameters. Coercivity and remanence
were observed to be high in order of martensite, pearlite and ferrite phase. The linear decrease of coercivity and remanence with the interlamellar
spacing and the linear increase of those with fracture strength of pearlitic eutectoid steel were found. Coercivity and remanence were suggested
as potential magnetic parameters for discriminating phases and quantitatively assessing the pearlite interlamellar spacing as well as strength of
eutectoid steel.
(Received July 14, 2003; Accepted August 26, 2003)
Keywords: eutectoid steel, pearlite interlamellar spacing, microstructure, magnetic parameter, nondestructive evaluation
1.
Introduction
Experimental Procedures
2185
Sample
Austenitizing
Holding
group
temperature
time
(K)
(min)
A-WQ
1123
240
water quenching
B-WQ
1223
15
water quenching
C-WQ
1323
15
water quenching
D-WQ
1423
15
water quenching
A-air
1123
240
air cooling
A-fur
1123
240
furnace cooling
B
C-air
1223
1323
15
15
963
air cooling
10
-
C-fur
1323
15
furnace cooling
C-1
1323
15
873
10
C-2
1323
15
923
10
C-3
1323
15
973
10
1423
15
883
10
isothermal
transformation
temperature (K)
Holding
time
(min)
Spheroidization
heat treatment
A-air-sph
1123
240
air cooling
973 K/150 h
A-fur-sph
B-sph
1123
1223
240
15
furnace cooling
963
10
973 K/150 h
973 K/150 h
C-air-sph
1323
15
air cooling
973 K/150 h
C-fur-sph
1323
15
furnace cooling
973 K/150 h
C-1-sph
1323
15
873
10
973 K/150 h
C-2-sph
1323
15
923
10
973 K/150 h
C-3-sph
1323
15
973
10
973 K/150 h
D-sph
1423
15
883
10
973 K/150h
3.
3.2
2.2
3.1
2186
(a) A-air
(b) A-fur
5m
(c) B
5m
(d) C-1
5m
(e) C-2
5m
(f) C-3
5m
5m
(g) C-air
(h) C-fur
5m
(i) D
5m
(j) C-1-sph
5m
20m
(k) C-WQ
100m
Fig. 1 Typical scanning electron micrographs of dierently heat treated specimens showing various pearlite lamellar structures ((a) to (i))
and ferrite phase of spheroidized specimen (j), and optical micrograph showing martensite phase of water quenched specimen (k).
Quantitative results of microstructural parameters, fracture strength and magnetic properties of dierently heat treated eutectoid steel.
Magnetic property
Sample
group
2187
Hc
(kAm1 )
Microstructure
Mechanical
property
Mr
(103 T)
HL
(kJm3 )
Ms
(T)
Phase/
S (mm)
FS
(MPa)
A-WQ
2.70
8.69
20.80
1.97
B-WQ
2.75
9.01
22.06
1.96
C-WQ
2.72
8.68
21.20
1.96
D-WQ
2.72
8.86
21.67
1.96
A-air
A-fur
1.88
1.71
6.12
5.47
17.82
15.94
1.95
1.94
P/0.102
P/0.160
978
827
1.83
5.91
18.68
1.95
P/0.117
938
C-air
1.79
5.87
18.29
1.95
P/0.132
890
C-fur
1.63
5.16
13.82
1.95
P/0.213
742
C-1
1.78
5.77
16.49
1.96
P/0.145
914
C-2
1.70
5.58
16.17
1.96
P/0.162
893
C-3
1.69
5.37
14.21
1.96
P/0.191
836
D
A-air-sph
1.77
1.52
5.77
4.89
14.37
14.92
1.96
1.92
P/0.140
F
878
-
A-fur-sph
1.50
4.80
14.76
1.91
B-sph
1.50
4.69
14.84
1.91
C-air-sph
1.47
4.67
14.68
1.95
C-fur-sph
1.45
4.58
15.78
1.96
C-1-sph
1.45
4.63
14.44
1.92
C-2-sph
1.49
4.64
15.70
1.93
C-3-sph
D-sph
1.49
1.46
4.55
4.58
15.07
16.09
1.92
1.95
F
F
Hc : coercivity, Mr : remanence, HL : hysteresis loss, Ms : saturation magnetization, S: pearlite interlamellar spacing, FS: fracture strength
est coercivity (1:45 1:52 kAm1 ). Water quenched, isothermally transformed or continuously cooled and spheroidized specimens had martensite, pearlite and ferrite phases,
respectively, as noted in Table 2. Therefore, the result shown
in Fig. 2(a) means that the coercivity is high in order of
martensite, pearlite and ferrite phase.
Coercivity is the additional magnetic eld required to
move the magnetic domain walls pinned, and the degree of
hindrance to wall motion determines the magnitude of
magnetic coercivity.20) It is known that residual stress eld or
microstructural defects such as precipitates, inclusions, grain
boundaries and dislocations in materials can hinder magnetic
domain wall movement and thus increase coercivity.21)
According to the results of the studies on the relation
between grain size and magnetic properties, the grain size
aects the magnetic properties in ultra low carbon steels
(Sakamoto et al.,12) Yamaura et al.,22) Gatelier-Rother et
al.23) and Tiitto24)). On the other hand, it aects the magnetic
properties little in steels containing more than 0.2 mass% of
carbon (Kwun and Burkhardt,1) Jiles4) and Nakai et al.9))
because large amount of carbide particles play a more
dominant role than grain boundaries in determining the
magnetic properties. Therefore, the dierence in grain size
between variously heat treated specimens in 0.85 mass%
carbon eutectoid steel used in this investigation can be
assumed to have little eect on the measured magnetic
properties.
Typical martensite phase of eutectoid steel consists of laths
and plates, in which the dislocation density is very high, to
the order of 1016 /m2 .25) The dislocations give rise to stress
eld around the dislocation lines, by which magnetic
domains are pinned.26) In this respect, the high coercivity in
martensite phase is thought to result mainly from the stress
eld due to dislocations in martensite laths and plates.
Supersaturated interstitial carbon atoms, which bring about
lattice stain, also might be a cause of domain pinning and
hence high coercivity. Even though it is not clear which
boundaries (lath boundary, block boundary, packet boundary) pin domain wall, considering the Moorthy et al.s
report27) that the lath boundaries pin domain wall in quenched
and tempered 0.2 mass% carbon steel, very ne subboundaries inside martensite phase could also pin domain wall to
some extent.
Coercivity of spheroidized specimens consisting of ferrite
matrix with globular cementite particles seems to arise
mainly from the pinning of domain walls to cementite
particles. In our previous research2) on the eect of
spheroidization heat treatment time on the magnetic properties of 0.45 mass% carbon steel, little change was observed in
coercivity despite of the change of the distribution or the
degree of spheroidization of fragmented cementite particles.
Therefore, the slight dierence in the distribution of
cementites can be assumed to have little eect on the
measured coercivity. On the other hand, considering that
pearlitic specimens have higher coercivity than ferritic
(spheroidized) ones, lamellar cementites seem to pin the
domain walls more strongly than globular ones.
Figure 2(b) shows the change of remanence with heat
2188
25
(a)
martensite
pearlite
ferrite
2.5
2.0
1.5
1.0
0.5
0.0
(c)
15
10
A
-W
B Q
-W
C Q
-W
D Q
-W
A Q
-a
A ir
-fu
r
C B
-a
C ir
-fu
r
C
-1
C
-2
C
-3
A
-a D
A ir-s
-fu p
r-s h
p
C B-s h
-a p
C ir-s h
-fu p
r h
C -sp
-1 h
C -sp
-2 h
C -sp
-3 h
-s
D ph
-s
ph
C B
-a
C ir
-fu
r
C
-1
C
-2
C
-3
A
-a
A ir-s D
-fu p
r-s h
p
C B-s h
-a p
i
r
C -s h
-fu p
r h
C -sp
-1 h
C -sp
-2 h
C -sp
-3 h
-s
D ph
-s
ph
A
-W
B Q
-W
C Q
-W
D Q
-W
A Q
-a
A ir
-fu
r
(b)
martensite
pearlite
ferrite
Saturation Magnetization, Ms / T
Remanence, Mr / 10-3 T
10
martensite
pearlite
ferrite
20
(d)
martensite
pearlite
ferrite
2.5
2.0
1.5
1.0
0.5
A
-W
B Q
-W
C Q
-W
D Q
-W
A Q
-a
A ir
-fu
r
C B
-a
C ir
-fu
r
C
-1
C
-2
C
-3
A
-a
A ir-s D
-fu p
r-s h
p
C B-s h
-a p
i
r
C -s h
-fu p
r h
C -sp
-1 h
C -sp
-2 h
C -sp
-3 h
-s
D ph
-s
ph
A
-W
B Q
-W
C Q
-W
D Q
-W
A Q
-a
A ir
-fu
r
0.0
C B
-a
C ir
-fu
r
C
-1
C
-2
C
-3
A
-a
A ir-s D
-fu p
r-s h
p
C B-s h
-a p
C ir-s h
-fu p
r h
C -sp
-1 h
C -sp
-2 h
C -sp
-3 h
-s
D ph
-s
ph
Coercivity, Hc / kAm-1
3.0
Fig. 2 Change of magnetic properties with heat treatment conditions: (a) coercivity, (b) remanence, (c) hysteresis loss and (d) saturation
magnetization.
Correlations of magnetic properties with interlamellar spacing and strength of pearlitic steel
Pearlitic specimens had a wide range of coercivity as
already shown in Fig. 2(a), which seemed to be related to the
dierent interlamellar spacings resulted from various heat
treatment conditions. Figure 3(a) shows the changes of
coercivity and remanence as a function of the interlamellar
spacing. Both parameters decreased linearly with increasing
the interlamellar spacing. In other words, coercivity and
remanence were higher as the interlamellar spacing was
narrower.
Lo et al.10) and Hetherington et al.28) observed the
magnetic domain walls in pearlitic steel by Lorenz microscopy and reported that they tended to be pinned against
cementite lamellae. The pinning of domain walls to cementite lamellae is thought to be due to the residual stress eld29)
arising between ferrite matrix and mismatched cementite
lamellar. Narrower interlamellar spacing means more interfaces between these two phases, and hence higher probability
to hinder the magnetic domain wall movement (higher
coercivity). From the results of linear regression analysis, the
correlations of coercivity and remanence with interlamellar
spacing can be formulated as eqs. (1) and (2), respectively.
Remanence, Mr / 10-3 T
5.2
Hc 2:09 2:20 S
Mr 6:94 8:44 S
2189
5.4
5.6
5.8
6.0
6.2
coercivity
1000
FS = 814.8 x Hc - 551.3
950
remanence
FS = 217.5 x Mr - 355.5
900
850
FS 814:8 Hc 551:3
FS 217:5 Mr 355:5
Coercivity, Hc / kAm-1
(a)
coercivity
remanence
1.9
6.0
5.8
1.8
5.6
1.7
5.4
1.6
Remanence, Mr / 10-3 T
6.2
5.2
0.08
0.12
0.16
0.20
0.24
19
2.00
hysteresis loss
saturation magnetization
(b)
1.98
18
1.96
17
16
1.94
15
1.92
14
13
0.08
0.12
0.16
0.20
Saturation Magnetization, Ms / T
20
1.90
0.24
750
700
1.6
1.7
1.8
1.9
2.0
Coercivity, Hc / kAm-1
Fig. 4 Correlations of fracture strength with magnetic coercivity and
remanence.
2.0
800
2190
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