Вы находитесь на странице: 1из 133

g fJiw

gulh tF khztfSfhd fw ifnaL

mKf
khF jehL Kjyikr mtf Mizgo
btsjh ghfgl khtlf gulh tF
gY khzt khza eyid fU bfhL mtf
fw

juid

ca

nkgLJtjbfd

j,

nj

My,

Gfhoid

fzF,

aa,

nta, ca, jhtua, ya, a, tuyhW,


bghUa, tfa, fzF ga Ma ghlfSfhd
fw ifnaoid g fJiw jah brJsJ.

mu
khztf

dhjh
nj

tiu

Gfhoid

mogil

mfF

neh

cUthfgLs ifnaoid khztfSF eKiw


vLJ

brW,

khztf

njfis

vbfhsjf

J jdif ftfshf cUthFkhW g


f

Jiw

nfLbfhwJ.

midJ

Ma

bgUkfis

PHYSICS QUESTION PAPER - BLUE PRINT


UNIT

1
Mark

3
5
Marks Marks

10
Marks

Total Marks

1. Electrostatics

25

2. Current
Electricity

20

3. Effects of
Electric Current

20

25

25

6. Atomic Physics

25

7. Dual Nature of
Radiation and
Matter and
Relativity

15

8. Nuclear Physics

25

9. Semiconductor
Devices and their
Applications

30

10. Communication
Systems

20

30

20

12

230

4. Electromagnetic
Induction and
Alternating
Current
5. Electromagnetic
Waves and Wave
Optics

TOTAL

1. There is a possibility of getting 65 marks if the pupil study the question and
answers for the units 1,7 and 8 completely. The distribution of marks for these
units are given in the following table.

UNIT

1 MARK

3 MARKS

5 MARKS

10 MARKS

TOTAL
MARKS

25

7
8

2
4

1
2

2
1

15
25

65

TOTAL MARKS

UNIT Areas of importance for 3 marks


questions

Areas of importance for 5 and 10 marks


questions

Coulombs law, Dipole, Electric field


lines,
Electric potential, Electric
flux, Gausss theorem, Capacitors,
Action of Points.

Electric field lines, Electric potential due to


point charge, Electric field-Axial line,
Equatorial line, Electric potential due to
dipole, Applications of Gausss theorem,
Capacitors principle, Capacitance,
Capacitors in series and in parallel, Van de
Graff generator.

Photoelectric
effect-Stopping
potential, threshold frequency, Photo
Electric cells, Electron microscope
uses and limitations, relativity.

Laws of Photo electric effects, Einsteins


photo electric equation, Photo Electric
cells, De-Broglie wave length, Length
contraction , Time dilation mass-energy
equivalency education (according to blue
print there is no 10 marks questions from
this unit )

Types of nuclei, Atomic mass unit,


Nuclear forces, Radioactivity, Curiedefinition,
Breeder
reactor,
properties of neutron Cosmic rays,
Pair production and annihilation of
matter, Elementary particles.

Bainbridge mass spectrometer, Nuclear


forces, ,, rays-properties, Radioactive
displacement laws, Half life period, Mean
life time, Neutron discovery and properties,
Geiger Muller counter, Atom bomb,
Hydrogen bomb, Nuclear reactor, Stellar
energy, p-p cycle, C-N cycle, Cosmic rays.

2. After taking practice in the above units, if they learn very well in the units
2 and 4, the pupil may get high marks.

UNIT 1 MARK

3 MARKS

5 MARKS

10 MARKS

TOTAL
MARKS

20

25

45

TOTAL MARKS

UNIT

Areas of importance for 3 mark


questions
Drift

velocity,

density,

Ohms

Mobility,
law,

Areas of importance for 5 and 10


mark questions

Current The relation between current and drift

Resistivity, velocity,

Superconductors,

Application

Temperature superconductors,

Coefficient of resistance, Kirchhoffs resistors


laws,

Comparison

potential

of

difference,

emf

and Kirchhoffs

Difference bridge,

of

Combination

series

and

laws,

of

parallel,

Wheatstones

Potentiometer

Principle,

between electric energy and power, E1/E2, Verifications of Faradays laws


Faradays

laws

of

electrolysis

Secondary cells.

, of electrolysis, Daniel cell, Leclanche


cell, Lead acid accumulator(according
to blue print there is no 10 marks
questions from this unit.)

Electromagnetic induction , Faradays Self inductance of a long solenoid,

laws of electromagnetism, Lenzs law, Energy associated with an inductor,


Flemings righthand rule, Methods of Mutual
producing

induced

emf,

inductance

of

two

long

Eddy solenoids, Inducing emf by changing

currents, Effective (rms) value of area


alternating current, Q- factor

enclosed

generator,

by the
Eddy

coil,

AC

currents,

Transformers Power losses, RLC


series circuit, Power in AC circuit.

3. After learning the above 5 units, if the students learn the units 3 and 5 the students
may get a minimum of 110/150 marks in physics.
UNIT

1 MARK

3 MARKS

5 MARKS

3
5

2
4

1
2

1
1

TOTAL
10 MARKS MARKS

1
1

20
25

45

TOTAL MARKS
UNIT

Areas of importance for 3 mark


Areas of importance for of 5 and 10
questions
mark questions
Joules law,Electric heating devices, Verification of Joules law, Thermopile,
Peltier

coefficient,

Thomson Magnetic induction due to infinitely

coefficient, Biot-Savart law, Tangent long straight conductor carrying current,


law, Definition. Ampere, Amperes Magnetic induction along the axis of a
circuital law), Current sensitivity of circular coil carrying current. Magnetic
Galvanometer Magnetic moment of a Lorentz force,
current loop .

Particle

in

Motion of charged

uniform

electric

field,

Cyclotron, Force on a current carrying


conductor placed in a magnetic field,
Conversion of galvanometer into an
ammeter and voltmeter.
Electromagnetic waves, Applications Electromagnetic

of Infrared and ultra-violet rays, characteristics

waves
,

and

their

Emission

and

Fraunhofer lines, Difference between Absorption spectrum , Raman effect,


corpuscles

and

photons,

Tyndall Total internal reflection and refraction,

effect, Rayleigh Scattering, Huygens Youngs

double

slit

experiment

Principle, Reason for darkness in the Bandwidth, Newtons rings-Radius of


centre of Newtons Rings, Difference nth dark ring, Brewsters Law, Pile of
between

Fresnel

diffraction,

and

Difference

Fraunhofer plates, Double refraction, Nicol prism,


between Uses of polarids.

interference and diffraction, Optic


axis, Optical activity Specific rotation.

4. After completing 7 lessons, the pupil are asked to learn the lesson 6, 9 and 10 if they
learn all these lessons thoroughly, students may get full mark.
UNIT 1 MARK

3 MARKS

5 MARKS

10 MARKS

TOTAL
MARKS

25

30

10

20

75

TOTAL MARKS
UNIT

Areas of importance for 3 marks


questions
of

Principle

Millikans

Bohrs

experiment,

Cathode rays, Canal rays, X-rays-properties,

Rutherford atom model, J.J. Thomson experiment, Millikans oil

Drawbacks of

Areas of importance for 5 and 10


marks questions

Postulates,

Ionization

energy,

drop experiment, Radius of the nth orbit,

Ionizing potential, Difference between Spectral series of hydrogen atom, Braggs


Hard

X-rays-soft

X-rays

Laue law, Braggs X-ray spectrometer, Ruby

experiment important facts, Moseleys laser, He-Ne laser.


Law , Characteristics of laser,
Forbidden energy gap, Intrinsic and Half wave rectifier, Bridge rectifier, and

Extrinsic

semiconductors,

Doping, relation Current amplification, Single stage

Rectification, Zener breakdown, LED, CE amplifier, Principle of feedback, feed


users Transistor Configurations, Band back amplifier Colpitts oscillator, Dewidth of amplifier, Negative feedback Morgans Theorem, Inverting amplifier,
amplifier,

Barkhausen

Advantages

of

integrated

conditions, Non-inverting amplifier, summing amplifier,


circuits, Difference amplifier, Logic gates.

Universal gates, OP-amp-Characteristics,


Uses of CRO .

10

Propagation of radio waves, Skip distance, Analysis of A.M, Radio transmission and
Skip

Modulation-necessity reception AM and FM, Radar- Principle-

zone,

Modulation,

Modulation

factor, phase diagram action and applications,

Limitations of

A.M, Scanning Digital Satellite

communication, Scanning, Fibre optical demerits.


communication

advantages

and

disadvantages.

communication-

merits

and

1 MARK QUESTIONS AND ANSWERS


UNIT 1 ELECTROSTATISTICS
1. A glass rod rubbed with silk acquires a charge of +8x10-12C. The number of electrons
it has gained or lost (5x107(lost))
2. The electrostatic force between two point charges kept at a distance apart, in a
medium r = 6, is 0.3 N, the force between them at the same separation in vacuum is
(1.8 N)
3. Electric field intensity is 400 Vm-1 at a distance of 2 m from a point charge. What
distance it will be 100 Vm-1? (4 m)
4. Two point charges +4q and +q are placed 30 cm apart. At what point on line joining
them the electric field is zero? (20 cm from the charge +4q)
5. A dipole is placed in a uniform electric field with its axis parallel to the field it
experiences (neither a net force nor a torque)
6. If a point lies at a distance x from the midpoint of the dipole, the electric potential at
this point is proportional to (1/x2)
7. Four charges +q, +q, -q and q respectively are placed at the corners A,B, C and D of
a square of side a. The electric potential at the centre O of the square is
(zero)
8. Electric potential energy (U) of two point charges is
(q1q2/40r)
9. The work done in moving 500 C charge between two points on equipotential surface
is
(zero)
10. Which of the following quantities is scalar?
(electric potential)
2 -1 -2
11. The unit of permittivity is
(C N m )
12. The number of electric lines of force originating from a charge of 1 C is
(1.129 x 1011)
13. The electric field outside the plates of two oppositely charged plane sheets of charge
density is (zero)
14. The capacitance of a parallel plate capacitor increases from 5 F to 60 F when a
dielectric is filled between the plates. The dielectric constant of the dielectric is (12)
15. A hollow metal ball carrying an electric charge produces no electric field at points
( inside the sphere)
UNIT 2 CURRENT ELECTRICITY
1. A charge of 60C passes through an electric lamp for 2 minutes. The current in the
lamp is (0.5 A)
2. The material through which electric charge can flow easily is
( copper)
3. The current flowing in a conductor is proportional to
( drift velocity)
4. A toaster operating at 240 V has a resistance of 120 . The power is (480 W)
5. If the length of a copper wire has a certain resistance R, then on doubling the length
its specific resistance ( will remain the same)
6. When two 2 resistances are in parallel, the effective resistance is (1 )
7. In the case of insulators, as the temperature decreases, resistivity (increases)
8. If the resistance of a coil is 2 at 00C and = 0.004 / 0C, then its resistance at
1000 C is ( 2.8 )
9. According to Faradays law of electrolysis, when a current is passed, the mass of ions
deposited at the cathode is independent of (resistance)
10. When n resistors of equal resistances (R) are connected in series, the effective
resistance is (nR)
6

UNIT 3 EFFECTS OF ELECTRIC CURRENT


1. Joules law of heating is
(H = VIt)
2. Nichrome wire is used as the heating element because it has (high specific
resistance)
3. Peltier coefficient at a junction of a thermocouple depends on
(the temperature of the junction)
4. In a thermocouple, the temperature of the cold junction is 200C, the neutral
temperature is 2700C. The temperature of inversion is
(5200C)

5. Which of the following equation represents Biot-Savart law?


6. In a tangent galvanometer, for a constant current, the deflection is 300. The plane of
the coil is rotated through 900. Now, for the same current, the deflection will be
( 00)
7. The period of revolution of a charged particle inside a cyclotron does not depend on
(the velocity of the particle)
8. The torque on a rectangular coil placed in a uniform magnetic field is large, when
( the number of turns is large)
9. Magnetic induction due to an infinitely long straight conductor placed in a medium of
permeability is
(l/2a)
10. Phosphor bronze wire is used for suspension in a moving coil galvanometer,
because it has ( small couple per unit twist)
11. Of the following devices, which has small resistance?(ammeter of range 0 10 A)
12. A galvanometer of resistance G is shunted with S . The effective resistance of the
combination is Ra. Then, which of the following statement is true?
(Ra is less than both G and S)
13. An ideal voltmeter has (infinite resistance)
UNIT 4 ELECTROMAGNETIC INDUCTIONS AND ALTERNATING CURRENT
1. Electromagnetic induction is not used in
( room heater)
2
2. A coil of area of cross section 0.5 m with 10 turns is in a plane which is
perpendicular to an uniform magnetic field of 0.2 Wb / m2. The flux through the coil
is
(1 Wb)
3. Lenzs law is in accordance with the law of (conservation of energy)
4. The self inductance of a straight conductor is
(zero)
5. The unit henry can also be written as a) VsA-1
b) WbA-1
c) s d)
all
Ans: (all)
6. An emf of 12 V is induced when the current in the coil changes at the rate of 40As-1.
The coefficient of self induction of the coil is
(0.3 H)
7. A DC of 5A produces the same heating effect as an AC of (5A rms current)
8. Transformer works on
(AC only)
9. The part of the AC generator that passes the current from the coil to the external
circuit is (brushes)
10. In an AC circuit the applied emf e =E0 sin (t + /2) leads the current I = I0 sin (t /2) by ()
11. Which of the following devices does not allow d.c. to pass through? (capacitor)
7

12. Which of the following cannot be stepped up in a transformer?


( input power)
13. In an ac circuit
(the average value of current is zero)
14. The power loss is less in transmission lines when ( voltage is more but current is
less)
UNIT 5 ELECTROMAGNETIC WAVES AND WAVE OPTICS
1. In an electro magnetic wave (power is transmitted in a direction perpendicular to
both the fields)
2. Electromagnetic waves are (transverse)
3. In an electromagnetic wave the phase difference between electric field E and
magnetic field B is
(zero)
4. Atomic spectrum should be
( pure line spectrum)
5. When a drop of water is introduced between the glass plate and plano convex lens in
Newtons rings system, the ring system
(contracts)
6. A beam of monochromatic light enters from vacuum into a medium of refractive
index . The ratio of the wavelengths of the incident and refracted waves is ( : 1)
7. If the wavelength of the light is reduced to one fourth, then the amount of scattering is
(increased by 256 times)
8. In Newtons ring experiment the radii of the mth and (m+4)th dark rings are
respectively5 mm and 7 mm. What is the value of m?
(10)
9. The path difference between two monochromatic light waves of wavelength 4000 A0
is 2 x 10-7 m. The phase difference between them is
()
10. Refractive index of glass is 1.5. Time taken for light to pass through a glass plate of
thickness 10 cm is (5 x 10-10 s)
11. In youngs experiment, the third bright band for wavelength of light 6000 A 0
coincides with the fourth bright band for another source in the same arrangement. The
wave length of the another source is (4500 A0)
12. A light of wavelength 6000A0 is incident normally on a grating 0.005m wide with
2500 lines. Then the maximum order is
(3)
13. A diffraction pattern is obtained using a beam of red light. What happens if the red
light is replaced by blue light?
(diffraction pattern becomes narrower and crowded together)
14. The refractive index of the medium, for the polarizing angle 600 is (1.732)
UNIT 6
ATOMIC PHYSICS
1. The cathode rays are
(a stream of electrons)
2. A narrow electron beam passes undeviated through and electric field E = 3 x 104 V/m
and an over lapping magnetic field B = 2 x 10-3 Wb/m2, The electron motion, electric
field and magnetic field are mutually perpendicular. The speed of the electron is
(1.5 x 107 ms-1)
3. According to Bohrs postulates, which of the following quantities take discrete
values? (angular momentum)
4. The ratio of the radii of the first three Bohr orbit is,
(1 : 4 : 9)
8

5. The first excitation potential energy or the minimum energy required to excite the
atom from ground state of hydrogen atom is,
(10.2eV)
6. According to Rutherford atom model, the spectral lines emitted by an atom is,
(continuous spectrum)
7. Energy levels A, B, C of a certain atom correspond to increasing values of energy
(i.e.,)EA<EB<EC. If 1, 2, 3 are the wavelengths of radiations corresponding to the
transitions C to B, B to A and C to A respectively, which of the following statements
is correct.
8. The elliptical orbits of electron in the atom were proposed by (Sommerfeld)
9. X- ray is
(phenomenon of conversion of kinetic energy into radiation)
10. In an X ray tube, the intensity of the emitted X ray beam is increased by
(increasing the filament current)
11. The energy of a photon of characteristic X ray from a Coolidge tube comes from
(an atomic transition in the target)
12. A Coolidge tube operates at 24800 V. The maximum frequency of X rays emitted
from Coolidge tube is
(6 x 1018 Hz)
13. In hydrogen atom, which of the following transitions produce a spectral line of
maximum wavelength
(6
5)
14. In hydrogen atom, which of the following transitions produce a spectral line of
maximum frequency (2
1)
15. After pumping process in laser,
(the number of atoms in the excited state is
greater than the number of atoms in the ground state)
16. The chromium ions doped in the ruby rod (absorbs green light)
UNIT 7. DUAL NATURES OF RADIATION AND MATTER AND RELATIVITY
1. A photon of frequency

is incident on a metal surface of threshold frequency v0. The

kinetic energy of the emitted photoelectron is

( h( - 0))

2. The work function of a photoelectric material is 3.3 eV. The threshold frequency will
be equal to ( 8 x 1014 Hz)
3. The stopping potential of a metal surface is independent of
(intensity of incident radiation)
4. At the threshold frequency, the velocity of the electron is (zero)
5. The photoelectric effect can be explained on the basis of (quantum theory of
light)
6. The wavelength of the matter wave is independent of
(charge)
7. If the kinetic energy of the moving particle is E, then the de Broglie wavelength is,
8. The momentum of the electron having wavelength 2A0 is (3.3 x 10-24 kg ms-1)
9. According to relativity, the length of a rod in motion (is less than its rest length)
10. If 1 kg of a substance is fully converted into energy, then the energy produced is
(9 x 1016 J)
9

UNIT 8

NUCLEAR PHYSICS

1. The nuclear radius of 4Be8 nucleus is


(1.3 x 10-13 m)
2. The nuclei 13Al 27 and 14Si28 are example of (isotones)
3. The mass defect of a certain nucleus is found to be 0.03 amu. Its binding energy is
(27.93 MeV)
4. Nuclear fission can be explained by
(liquid drop model)
5. The nucleons in a nucleus are attracted by (nuclear force)
6. The ionization power is maximum for
( particles)
7. The half life period of a certain radioactive element with disintegration constant
0.0693 per day is
(10 days)
8. The radio-isotope used in agriculture is
(15P32)
9. The average energy released per fission is (200 MeV)
10. The explosion of atom bomb is based on the principle of (uncontrolled fission
reaction)
11. Anaemia can be diagnosed by
(26Fe59)
198
12. In the nuclear reaction 80Hg198 + X
+ 1H1, X stands for (neutron)
79Au
13. In decay (neutron number decreases by one)
14. Isotopes have ( same proton number but different neutron number)
15. The time taken by the radioactive element to reduce to 1 / e time is (mean life)
16. The half life period of N13 is 10.1 minute. Its life time is
(infinity)
17. Positive rays of the same element produce two different traces in a Bainbridge mass
spectrometer. The positive ions have
(different mass with same velocity)
56
18. The binding energy of (26Fe ) nucleus is (493 MeV)
19. The ratio of nuclear density to the density of the mercury is about (1.3x1013)

UNIT 9

SEMICONDUCTOR DEVICES AND THEIR APPLICATIONS

1. The electrons in the atom of an element which determine its chemical and electrical
properties are called (valance electrons)
2. In an N type semiconductor, there are
(immobile positive ions)
3. The reverse saturation current in a PN junction diode is only due to
(minority carriers)
4. In the forward bias characteristic curve, a diode appears as
(ON switch)
5. Avalanche breakdown is primarily dependent on the phenomenon of
(collision)
6. The colour of light emitted by a LED depends on (type of semi conductor material)
7. The emitter base junction of a given transistor is forward biased and its collector
base junction is reverse biased. If the base current is increased, then its
(IC will increase)
8. Improper biasing of a transistor circuit produces
(distortion in the output signal)
9. An oscillator is
(an amplifier with feedback)
10. In a Colpitts oscillator circuit
(capacitive feedback is used)
10

11. Since the input impedance of an ideal operational amplifier is infinite,


(its input current is zero)
12. The following arrangement performs the logic function of ____ gate
(AND)
13. If the output (Y) of the following circuit is 1, the inputs A B C must be

(101)
14. According to the laws of Boolean algebra, the expression (A+AB) is equal to (A)
15. The Boolean expression ABC can be simplified as A + B + C
UNIT 10

COMMUNICATION SYSTEMS

1. High frequency waves follow


(the line of sight direction)
2. The main purpose of modulation is to (transmit low frequency information over
long distances efficiently)
3. In amplitude modulation
(the amplitude of the carrier wave varies in
accordance with the amplitude of the modulating signal)
4. In amplitude modulation, the band width is (twice the signal frequency)
5. In phase modulation
(both the phase and the frequency of the carrier wave
varies)
6. The RF channel in a radio transmitter produces
( high frequency carrier waves)
7. The purpose of dividing each frame into two fields so as to transmit 50 views of the
picture per second is ( to avoid flicker in the picture)
8. Printed document to be transmitted by fax are converted into electrical signals by the
process of
(scan)
UNIT I ELECTROSTATICS
3 Mark Questions And Answers
1. What is meant by quantization of charges ?
i ) The electric charge of any system is an integral multiple of a least amount of
charge (e).
ii) q=ne here n is an integer , e=1.602 x 10 -19 C
2. State the law of conservation of electric charges.
i) The total charge in an isolated system always remains constant.
ii) Electric charges can neither be created nor destroyed. The total charge always
remains conserved.
3. What is meant by additive nature of charge . Give an example.
The total electric charge of a system is equal to the algebraic sum of electric
charges located in the system. For example , if two charged bodies of charges +2q , 5q are brought in contact, the total charge of a system is -3q.

11

4. State Coulombs law in electrostatics.


The force of attraction or repulsion between two point charges is directly
proportional to the product of the charges and inversely proportional to the square of
the distance between them.
Vector notation: F12 =
r21
5. Define 1 Coulomb .
One Coulomb is defined as the quantity of charge which when placed at a
distance of 1 metre in air or vacuum from an equal and similar charge , experiences a
repulsive force of 9x109 N.
6. What is relative permittivity?
It is the ratio of permittivity of the medium to the permittivity in free space or
air.

r = / o
7. State the super position principle in electrostatics.
The total force on a given charge is the vector sum of the forces exerted on it
due to all other charges.

8. Define electric field intensity. Give its unit


Electric field intensity at any point is defined as the force experienced by a
unit positive charge kept at that point. Unit : NC -1
9. What is electric dipole? Define electric dipole moment.
Two equal and opposite charges separated by a very small distance constitute
an electric dipole.
The magnitude of the dipole moment is given by the product of the
magnitude of any one of the charges and the distance between them. p = q x 2d
Unit: Cm.
10. Explain the working of microwave oven.
i)
The device which is used to cook the food in a short time produces nonuniform oscillating electric field when it is operated.
ii)
The water molecules in the food act as dipoles and are excited by an
oscillating torque.
iii)
A few bonds of water molecules are broken and the heat energy produced is
used to cook food
11. Define electric potential.
The electric potential in an electric field is defined as the amount of work
done in moving a unit positive charge from infinity to that point against the electric
field. Unit : Volt (V)
12. Define electric potential difference.
The electric potential difference in an electric field is defined as the amount
of work done in moving a unit positive charge from one point to another point against
the electric field. Unit : Volt (V)
13. Define 1 Volt.
The potential difference between two points is 1 volt if 1 joule of work is done
in moving 1 Coulomb of charge from one point to another point against the electric
field.
12

14. What is electric potential energy of two point charges system?


The electric potential energy of two point charges is equal to the work done to
assemble the charges. Unit : Joule (J)
15. What is meant by equipotential surface ?
If all the points of the surface are at the same electric potential, then the
surface is called an equipotential surface.
16. Define electric flux. Give it Units.
The total number of electric lines of force, crossing through the given area is
called the electric flux. Unit : N m2 C-1
17. State Gausss law in electrostatics
The total flux of the electric field over any closed surface is equal to
the net charge enclosed by the surface ie. =

times

18. What is electrostatic shielding ?


i)
The process of isolating a certain region of space from external field is called
electrostatic shielding.
ii)
The electric field inside the conductor is zero.
19. Why is it safer to sit inside a car (bus) rather than standing under a tree during
lightning?
i)
The electric field inside the car (bus) becomes zero.
ii)
The metal body of the car (bus) provides electrostatic shielding.
iii)
During lightning the electric discharge passes through the body of the car
(bus)
20. What is electrostatic induction ?
The process of obtaining charges in a conductor without any contact with
another charge is known as electrostatic induction.
21. What is a capacitor? Define capacitance of a capacitor.
Capacitor is a device to store charges.
Capacitance of a capacitor is defined as the ratio of charge given to the conductor to
the potential developed in the conductor. Unit : farad(F)
22. Define 1 farad.
A conductor has a capacitance of 1 farad if a charge of 1 coulomb given to it
raises its potential by 1 volt.
23. What are non polar molecules ? Give examples.
A non polar molecule is one in which the centre of gravity of the positive
charges coincide with the centre of gravity of the negative charges. They do nont
permanent dipole moments. Eg : O2 , N2 , H2 etc.
24. What are polar molecules? Give examples.
A polar molecule is one in which the centre of gravity of the positive charges
are separated from the centre of gravity of the negative charges. They have permanent
dipole moments. Eg : N2O , H2O , HCl, NH3 etc.
25. What is electric polarization ?
The alignment of the dipole moments of the permanent or induced dipoles in
the direction of applied electric field is called polarisation or electric polarisation.
26. What are dielectrics? What is the effect of introducing a dielectric slab between
the plates of a parallel plate capacitor?
i)
A dielectric is an insulating material in which all the electrons are tightly
bound to the nucleus of the atom.
ii)
The capacitance of the capacitor increases if a dielectric is introduced.
13

27. Give the applications of the capacitors?


i)
They are used in the ignition system of automobile engines to eliminate
sparking.
ii)
They are used to reduce voltage fluctuations in power supplies .
iii)
They are used to increase the efficiency of power transmission.
28. What is corona discharge or action of points? Give its uses?
The leakage of electric charges from the sharp points on the charged
conductor is known as corona discharge or action of points.
It is used in electrostatic machines for collecting charges and in lightning
conductors.
29. A sample of HCl gas is placed in an electric field of 2.5 x 104 N C-1. The dipole
moment of each HCl molecule is 3.4 x 10 -30 C m. Find the maximum torque that
can act on a molecule.
Solution : :- Torque = pE
MaximumTorque max =pE[
,
-30
4
max= 3.4x10 x2.5x10

]
max=8.5x10

-26

Nm

30. Calculate the potential at a point due a charge of 4 x 10


away.

-7

C located at 0.09 m

Solution :

31. An infinite line charge produces a field of 9 x 10


Calculate the linear charge density.
Solution :

NC

-1

at a distance of 2 cm.

E=
9

=Ex
=9x104x

x10-9x2x10-2

=10-7 Cm-1
32. Three capacitors each of capacitances 9 pF are connected in series. What is the
total capacitance of the capacitor?
Solution :

= + +
= ;

Cs=3pF
14

33. Calculate the effective capacitance of the combination.


5F

10F

10F

Solution : C1 = 5F ; C2 = 10 F ;
C3 = 10 F
C2 and C3 are in series.

=
=

Cs = 5F

Now C1 and Cs are in parallel.

Cp = C1 + Cs

Cp = (5+5) F

Cp = 10F

5 Marks Questions and Answers


1. List the properties of electric lines of forces.
(i) Lines of force start from positive charge and terminate at negative charge.
(ii) Lines of force never intersect.
(iii) The tangent to a line of force at any point gives the direction of the electric field (E) at
that point.
(iv) The number of lines per unit area, through a plane at right angles to the lines, is
proportional to the magnitude of E. The lines of force are close together if, E is large and E
is small when they are far apart,
(v) The number lines of force emerging out from q charge N =

15

1. Torque acting on an electric dipole

The dipole AB is at an angle with the electric field.


The force acting on q is q E., The force on q is -qE
The net force acting on the dipole is zero
A torque acts on the dipole which tends the dipole in the direction of the field.
Torque = F 2d sin

= qE 2d sin( p = q x 2d)
= pE sin
In vector notation> p E
2.Electric potential energy of an electric dipole in uniform electric field.
It is the work done in rotating the dipole to the desired position in the electric field.

Torque on the dipole


=pE sin
The work done to rotate the dipole through an angled , dW = d
dW = pEsin d

The work done to rotate dipole through an angle , W =pE sind


W = -pE cos
Electric potential energy of an electric dipole U = - pE cos

3. The expression for electric potential at any point due to a point charge.

The potential difference between A and B , dV = -E dx


1 q
E
Electric field at A ,
4 0 x 2
1 q
dV
dx
4 0 x 2
16

The electric potential at P is the work done in moving a unit positive charge
from infinity to that point
r

q
dx
2
x
0

q
4 0 r

4. The expression for electric potential energy of two point charge system.
The electric potential energy of a two point charge system is equal to the work
done to assemble the charges.

q1
The potential at B due to q1charge , V 4 r
0

The work done to bring q2 charge to B , W =


qq
The electric potential energy U 1 2
4 0 r

V q2

The work done is stored as electric potential energy in the system


5. The energy stored in a capacitor.

The capacitor is a charge storage device. This work done to store the charges is
stored as electrostatic potential energy in the capacitor.
If dq is the additional charge given to the plate,

work done is, dw = Vdq

q
dW
C

dq

V C

q
q2
Total work done W q dq, W
0

2C

This work done is stored as electric potential energy


q2
2C
1
U CV 2
2
U

q CV

17

10 Marks Questions and Answers


1. The expression for electric field intensity at any point due to an electric dipole along the
axial line.

The charges q and +q at A and B constitute an electric dipole. P is a point at a


distance, r from the centre of the dipole along the axial line.
The electric field at the point P due to +q placed at B is

2.

The expression for electric field at any point due to electric dipole along the
equatorial line
-q and +q charges at A and B Constitute
an electric dipole.
P is a point at a distance r from the centre
of the dipole O along the equatorial line
Electric field at P due to +q
18

Electic field at P due to -q Electric field at P due to -q

E1 = E2, Resolving E1 and E2 in two perpendicular components


E1 Sin , E2 Sin cancel each otherE1 cos and E2 cos are added in the same
direction along PR
E = E1 cos + E2 cos (along PR)
E = 2 E1 cos
( E1 = E2 )
E= 2x

x cos

But, cos =

d << r,
E=
The direction of E is along the axis of the dipole and opposite to that of the dipole moment.
3.

Expression for potential at any point due to an electric dipole.


-q and +q charges at A and B form an electric dipole . Its dipole moment is p. P is a
point at a distance r from O. OP makes an angle

q
4 0 r1
q
Electric potential at P due to -q charge
4 0 r2
1 q
1 q

Potential at P due to dipole V


4 0 r1 4 0 r2
Electric potential at P due to +q charge

q
4 0 r1
q
Electric potential at P due to -q charge
4 0 r2
Electric potential at P due to +q charge

19

with the axis of the dipole

Potential at P due to dipole V

1 q
1 q

4 0 r1 4 0 r2

V =
2

Using cosine law, r1 = r + d -2 r d cos

d << r,

r 1 2 = r2 ( 1 -

),

1 1 d cos 1 1 d

1
1 cos

r1 r
r , r2 r r

V =

( 1+

V =

( p = q x 2d)
V

) ]

( 1-

p cos
4 0 r 2

Special cases

1.

=00

If

2. If=1800
3. If

=900

V=
V=

p
4 0 r 2

p
4 0 r 2

V =

4. Expression for electric field due to an infinite long straight charged wire.
Consider an uniform the charged wire of
infinite length having +q charge. Its linear
charge density is = . Let P be a point at a
distance r from the wire. Consider a cylindrical
Gaussian surface of length
and radius r ,
closed at each end by plane caps normal to the
axis.
Electric flux through the curved surface ) = E dS cos
= E dS [ = , cos =
=E(2 r )
E and d are perpendicular to each other , the flux through the plane caps is equal to zero
By Gausss law, =
E (2 r ) = ( q =

E=
The direction of E is radially outward for positive charge. The direction of E is radially
inward for negative charge.
20

5. The expression for electric field due to uniformly charged spherical shell
i) At a point outside the shell

Consider a charged shell of radius R . Let P be a point at a distance r from the centre.
The sphere with radius r is the Gaussian surface. Electric field acts perpendicular to the
surface.
Electric flux crossing normally to the surface,

= E (4 r2)

By Gausss law

E (4 r2)
E

ii) At a point on the surface


At a point on the surface E =

= ]

iii) At a point inside the shell


Let r' be the distance of the point P from the centre outside the shell . The sphere with
radius r' is the Gaussian surface.
The flux crossing normally to the surface

[ =
By Gausss law =
Here q = 0, (The total charge inside the surface is zero)
Gaussian surface

6. Principle of a capacitor , capacitance of a parallel plate capacitor.


Principle of a capacitor:-Capacitor is a device for storing electric charges.

Consider an insulated conductor (Plate A) with a positive charge

q having potential l V . The capacitance

of A is C=q/V.

When another insulated metal plate B is brought near A, negative charges are induced on
the side of B near A. An equal amount of positive charge is induced on the other side of
B. The negative charge in B decreases the potential of A, and the capacitance of A is
increased.

21

If the plate B is earthed, positive charges get neutralized. Then the potential of A
decreases further, and capacitance of A is considerably increased.

The capacitance depends on the geometry of the conductors and nature of the
medium.

Capacitance of a parallel plate capacitor

A parallel plate
capacitor consists of two
parallel metal plates X
and Y each of area A, separated by a distanced, having a surface charge
density . A charge+q is given to the plate X. It induces a charge q on the upper
surface of earthed plate Y.
Charge q = A
By the application of Gausss law, electric field at a point between the two
plates is,
=
The potential difference between X and Y

Capacitance of the parallel plate capacitor C =

C=
22

6. Capacitances of capacitors connected in series and parallel.


Capacitors in series

Capacitors in parallel

C1, C2, C3 capacitors are connected in series. C1, C2, C3 capacitors are connected in parallel .
Cs is the effective capacitance
Cp is the effective capacitance

Charge in each capacitors are equal

Potential in each capacitors are equal

V1 =

q 1 = C 1V ; q 2 = C 2V ; q 3 = C 3V
q = q1 + q2 + q3

; V2 =

; V3 =

V = V1 + V2 + V3

q = C pV

V=

CPV = V(C1+C2+C3)

q
q
q
q

Cs
C1
C2
C3

CP = C1 + C2 + C3

1
1
1
1

Cs C1 C2 C3

7. The principle , construction and working of Van de Graaff Generator.


It is used to produce electrostatic potential difference of the order of 10 7 V.
Principle : Electrostatic induction , action of points.
Construction :
A hollow metallic sphere A is
mounted on insulating pillars
A pulley B is mounted at the
centre of the sphere and another
pulley C is mounted near the
bottom. A belt made of silk
moves over the pulleys.
The pulley C is driven by an
electric motor.
Two comb shaped conductors D
and E having number of needles
are mounted near the pulleys.
104 volt is given to the comb D
by a power supply.
The comb E is connected to the
inner side of the sphere

23

Working :
Because of the high electric field near the comb D, the air gets ionised due to
action of points, the negative charges in air move towards the needles and
positive charges are repelled on towards the belt. These positive charges stick
to the belt, moves up and reaches near the comb E.

As a result of electrostatic induction, the comb E acquires negative charge


and the sphere acquires positive charge. The high electric field at the comb E
ionizes the air. Hence, negative charges are repelled to the belt, neutralizes the
positive charge on the belt b efore t he b elt p asses o ver t he p ulley. H ence
t he d escending b elt will b e l eft u ncharged.

The machine, continuously transfers the positive charge to the sphere. After
this stage no more charge can be placed on the sphere, it starts leaking to the
surrounding due to ionization of the air.

The leakage of charge from the sphere can be reduced by enclosing it in a


gas filled steel chamber at a very high pressure.

The high voltage produced in this generator can be used to accelerate positive
ions (protons, deuterons) for the purpose of nuclear disintegration.

UNIT 7 DUAL NATURE OF RADIATION AND MATTER AND RELATIVITY

3 Marks Questions and Answers


1.

What is photo electric effect?


Photo electric effect is the phenomena by which a good number of substances,
chiefly metals , emit radiations under the influence of radiation such as rays , X-rays,
ultraviolet and even visible light
2.
Define stopping potential?
The minimum negative potential given to the anode for which the photo electric
current becomes zero is called stopping potential.
3.
Define threshold ( cut-off) frequency.
Threshold frequency is defined as the minimum frequency of incident radiation
below which the photoelectric emission is not possible completely, however high the
intensity of incident radiation may be.
4.

Define work function.


The work function of a photo metal is defined as the minimum amount of
energy required to liberate an electron from the metal surface. W = h

5.

State Plancks quantum theory.


Light is emitted in the form of discrete packets of energy called quanta or photon.
The energy of each photon is E=h ,

24

6.

What are photo electric cells? Give their types.


It is a device which converts light energy into electrical energy.
Their types are
i) Photo emissive cell
ii) Photo voltaic cell
iii) Photo conductive cell
7.
What are the uses of electron microscope?
(i)It is used in the industry, to study the structure of textile fibres, surface of
metals, composition of paints etc.
(ii) In medicine and biology, it is used to study virus, and bacteria.
(iii) In physics, it has been used in the investigation of atomic structure and
structure of crystals in detail.
8.
What are the limitations of electron microscope?
An electron microscope is operated only in high vacuum. This prohibits the
use of the microscope to study living organisms which would evaporate and
disintegrates under such conditions.
9. What are De Broglie waves?
The waves associated with matter (particle) are called matter waves or De
Broglie waves.
10. Give the wave mechanical concept of an atom.
i) The electron in various orbits behaves as a wave .
ii) The stationary orbits are those in which the orbital circumference
(2r ) is an integral multiple of De Broglie wave length
iii) Stationary orbits for an electron are those which contain the complete waves of
electron (2r = n)
11. State Einsteins relativity theory.
i) There is no absolute space
ii) All motions are relative.
iii) The time, mass, length and space are interdependent and are not absolute
12. What is meant by frame of reference? Give examples.
A system of co-ordinate axes which defines the position of a particle in two or
three dimensional space is called a frame of reference.
Eg : i) Cartesian co-ordinate system ii) Our earth
13. What are inertial and non-inertial frames of references?
(i) Inertial (or) unaccelerated frames.
A frame of reference is said to be inertial, when the bodies in this frame obey
Newtons law of inertia and other laws of Newtonian mechanics. In this frame, a body
remains at rest or in continuous motion unless acted upon by a external force.
(ii) Non-inertial (or) accelerated frames
A frame of reference is said to be a non-inertial frame, when a body not acted upon by
an external force, is accelerated. In this frame, Newtons laws are not valid.
25

14. Give the concept of space in classical mechanics.


(i)Fixed frame of reference by which the position or motion of any object in the universe
could be measured.
(ii) The geometrical form of an object remains the same irrespective of changes in
position or state of motion of the object or observer.
15. Give the concept of time in classical mechanics.
(i) The time interval between two events has the same value for all observers
irrespective of their motion.
(ii) If two events are simultaneous for an observer, they are simultaneous for all
observers, irrespective of their position or motion. This means simultaneity is
absolute.
16. Give the concept of mass in classical mechanics.
In classical mechanics, the mass of the body is absolute and constant and
independent of the motion of the body.
17. State the variation of mass with respect to the velocity.
i) The mass of the body changes with velocity.
ii) Einstein established the relation between the mass of a body at rest (mo)and the
mass of the same body moving with velocity v is

18. State the postulates of special theory of relativity.


i) The laws of physics are same in all inertial frames of references .
ii) The velocity of light in free space is constant in all the frames of reference.
19. If a moves with the velocity of light, what will be its mass? Comment on your result.

0
ii. No particle can attain the velocity of light.
20. The work function of a metal is 1.8 eV. Calculate its threshold wave length.
Solution:
W = 1. 8eV = 1. 8 x 1. 6 x 10-19J
h0 = W
h =W

i. If; v = c, =

0 =
0 =
0 =

0 = 6. 902 x 10 m or 0 = 6902 A
-7

26

21.

What is the de Broglie wave length of an electron of kinetic energy120eV?


=

Solution :

=
= 1. 121 x 10-10m

(or)

= 1. 121 A
22.

Calculate the De Broglie wave length of an electron in the 4th orbit of hydrogen atom .
Solution :

r4 = 42 r1 = 16 x 0.53A
2 r4 = n,

[... r1= 0.53A]

=
=
= 3.14 x 0.53 x 10-10 x 8
= 13.313 x 10-10m

5 Marks Questions and Answers


1. The effect of intensity of incident radiation on photo electric current.
The intensity of incident radiation is varied and the corresponding photo electric current is
measured (anode potential and frequency constant).

The photo electric current increases linearly with a intensity of the incident radiation.
The photo electric current is directly proportional to number of photo electrons.
The number of photo electrons emitted per second is proportional to intensity of the
incident radiation.
2. Photo electric effect, the laws of photo electric effect
Photo electric effect is the phenomena by which a good number of substances,
chiefly metals , emit radiations under the influence of radiation such as rays , X-rays,
ultraviolet and even visible light
The laws of photo electric effect :
(i) For a given photo sensitive material, there is a minimum frequency called the
threshold frequency, below which emission of photo electrons stops completely, how
ever great the intensity may be.
27

(ii) The photo electric current is directly proportional to the intensity of the incident
radiation, provided the frequency is greater than the threshold frequency.
(iii)The photo electric emission is an instantaneous process.
(iv) The maximum kinetic energy of the photo electrons is directly proportional to
the frequency of incident radiation, but is independent of its intensity.
3.The construction and working of photo electric cells
It is a device to convert light energy into electrical energy
Construction :

It consists of a highly evacuated bulb B made of glass or


quartz. A semi cylindrical metal plate C is the cathode.
coated with a low work function material such as caesium oxide.

A thin platinum wire A serves as the anode.


Working :
When a light of suitable wave length falls on the cathode, photo
electrons are emitted, which are attracted by the anode A.
The resulting current is measured by a micro ammeter.
The current produced is proportional to the intensity of the
incident light for a given frequency.

4. Applications of photo electric cells:


i) They are used for controlling the temperature of furnaces.
(ii)They are used for automatic switching on and off the street lights.
(iii)They are used in obtaining electrical energy from sunlight during space travel.
(iv) They are used in opening and closing of door automatically.
(v)They are used in instruments measuring light illumination.
5. De Broglie wave length of matter waves
Plancks equation :
Einsteins equation:

h mc2

E = h
E = mc2

mc 2

( = )

If

c=v
h
h

or
p
mv
28

6. De Broglie wave length of an electron


1
Kinetic energy of an electron mv 2 eV
2
2eV
h
v
(
m
mv )
h

2eV
m
12.27 0

A
V
h
E=eV,
2mE
m

Since

h
2meV

7.The wave mechanical concept of atom

h
mv
The electron in various orbits behaves as a wave .
The stationary orbits are those in which the orbital circumference (2r ) is an integral
multiple of De Broglie wave length (2r = n )

De Broglie wave length

(n=1, 2, 3, . . . )
mvr

2 r = n(

nh
2

De Broglies concept confirms the Bohrs postulate.

8.Einsteins photo electric equation


Photo electric equation is explained by quantum theory
Photo electric emission is the result of interaction between a single photon and an
electron in the metal.
The energy of the photon is used i) to liberate an electron from the metal surface (work
function) ii) to impart kinetic energy to the electron
1
h W mv 2
2
29

If there is no loss of energy , v = v max


1
h W mv 2 max
2
If the frequency () , is equal to the threshold frequency,
W = h0
1
h h 0 mv 2 max
2
1
h 0 mv 2 max
2
9. Lorentz-Fitzgerald contraction ( length contraction)

Consider two frames of references S and S' . The length of the rod as measured by an
observer in S frame of reference is l0Consider the frame of reference S' moves with the
velocity v. Now the length measured by the observer is .

v2
1 2
c
v2
1 2
c

The length contracts by a factor


Eg : A circular object will appear as an ellipse for a moving observer.

10.Time dilation

The clock in the frame of reference S' gives out signals in t0seconds
The time measured by the observer is t in the frame of reference S
t

t0
1

v2
c2

t > t0
The time interval is lengthened by a factor

1
1

v2
c2

Eg: The clock in the moving ships will appear to go slower than the clocks in the earth.
30

11. Einsteins mass energy equivalence

Let mo be the rest mass and m be the mass of the body moving with velocity v
d
According to Newtons second law, F (mv)
(1)
dt
According to relativity theory
dv
dm
(2)
F m
v
dt
dt
The increase in kinetic energy
dEk = F dx
dEk =m v d v + v2dm (3)
According to Einsteins relativity theory
m

m0
1

v2
c2

(4)

Differentiating, c2dm = mv dv + v2dm

From equations (3) and (4)

dEk = c2 dm

Ek

(5)

dEk c 2 dm
m0

Kinetic energy Ek = mc2 - m0c2

Total energy = Kinetic energy + Rest mass energy


E = Ek +m0c2
2
E = mc moc2 + moc2
E = mc2
UNIT 8 NUCLEAR PHYSICS

3 Marks Questions and Answers


1. What are isotopes? Give an Example.
Isotopes are atoms of the same element having the same atomic number Z but different
mass number A. Eg.1H1, 1H2 and 1H3
2. What are meant by Isobars? Give an Example.
Isobars are atoms of different elements having the same mass number A, but different
atomic number Z. Eg. 8O16 and 7N16
3. What is meant by isotones? Give an Example.
Isotones are atoms of different elements having the same number of neutrons. E g :
14
16
6C and8O are some examples of isotones.
4. What is the value of Nuclear density? What does it show?
i) Nuclear density = 1.8161017 kgm 3
ii) The high value of the nuclear density shows that the nuclear matter is in an
extremely compressed state.
31

5. Define atomic mass unit(1 amu)


One atomic mass unit is considered as one twelfth of the mass of carbon atom 6C12.
1 am u =
1amu=1.661027 kg
6. Calculate the energy equivalent of 1amu.
1amu=1.661027 kg
According to Einsteins mass energy relation, E=mc2
E =1.661027 9 1016J
E =
eV = 931

106 eV

Energy equivalent of 1amu= 9 31MeV

7. Define mass defect.


The difference in the total mass of the nucleons and the actual mass of the nucleus
is known as the mass defect.
Zmp+Nmnm=m
8. Define Binding energy.
When the protons and neutrons combine to form a nucleus, the mass that
disappears (mass defect, m) is converted into an equivalent amount of energy
(mc2). This energy is called the binding energy of the nucleus.
Binding energy = [ZmP+Nmnm]c2 = mc2
9. What is meant by radioactivity? (natural radioactivity)
The phenomenon of spontaneous emission of highly penetrating radiations such
as , and rays by heavy elements having atomic number greater than 82 is
called radioactivity.
10. Write the Radioactive law of disintegration.
The rate of disintegration at any instant is directly proportional to the number of
atoms of the element present at that instant. i.e.
11. Define Curie.
Curie is defined as the quantity of a radio active substance which gives
3.71010disintegrations per second 3.7 1010 Becquerel = 1 curie
12. Define artificial radio activity.
The phenomenon by which even light elements are made radioactive by artificial are
induced methods is called artificial radio activity.
13. Define roentgen.
One roentgen is defined as the quantity of radiation which produces
1.61012pairs of ions in 1gram of air.

32

14. What are the methods of producing artificial radio isotopes?


(i) Artificial radio-is isotopes are produced by placing the target element in the nuclear
reactor, where plenty of neutrons are available.
E.g.:- (1)15P31 +0n1 15P32* +,
(ii) Another method of production of artificial radio-isotope is to bombard the target
element with particles from particle accelerators like cyclotron
E.g.:- 11Na23 +1H2 11Na24* +1H1
15. What is meant by radio carbon dating?
(i) The half life of C14 is 5570 years. The ratio of C14 and C12 in the atmosphere is 1:106.
(ii) Living things take C14 from food and air. However with death, the intake of C14 stops
and the C14 that is already present begins to decay.
The amount of C14 in the sample will enable the calculation of time of death i.e, the age of
the specimen could be estimated. This is called radio-carbon dating
16. What is artificial transmutation? Give example.
Artificial transmutation is the conversion of one element into another by artificial methods.
14
4
17
1
7N +2He
8O +1H
17. What are the precautions are to be taken for those, who are working in radiation
laboratories?
(i) Radio active materials are kept in thick walled lead container.
(ii) Lead aprons and lead gloves are used while working in hazardous area.
(iii)All radioactive samples are handled by a remote control process.
(iv)A small microfilm badge is always worn by the person and it is checked
periodically for the safety limit of radiation.
18. What is meant by nuclear fission?
The process of breaking up of the nucleus of a heavier atom into two fragments with the
release of large amount of energy is called nuclear fission.
19. What is meant by chain reaction?
i) A chain reaction is a self propagating process nuclear fission
ii) The number of neutrons goes on multiplying rapidly almost in a geometrical progression
20. Distinguish between electro static and cyclic particle accelerators
Sl.No.
Electro static accelerators Cyclic accelerators
1

Particles are accelerated by


applying a constant
potential difference.
They can accelerate the
particles up to a few million
electron- volt energy..
E.g. VandeGraff, Generator,
Cockcroft-Walton
generators
33

Particles are accelerated in


multiple steps imparting a small
energy in each successive step.
They can accelerate the particles
up to energy of the order of
109eV.
E.g. Cyclotron, Syncrotran, and
betatron

21. Define critical size and critical mass?


Critical size of a system containing a fissile material is defined as the
minimum size in which at least one neutron is available for further fission reaction.
The mass of the fissile material at the critical size is called critical mass.
22. What are moderators? Give examples.
Moderator is to slow down fast neutrons produced in the fission process
having an average energy of about 2MeV to thermal neutrons with an average
energy of about 0.025eV, which are in thermal equilibrium with the moderator. E.g.
Ordinary water and heavy water and graphite.
23. What are uses of Control rods? Give example.
The control rods are used to control the chain reaction by absorbing neutrons.
E.g. Cadmium and Boron.
24. What is meant by Breeder reactor?
i)There actors which produce fissile material during the operation by the
absorption of neutrons are called breeder reactors.
238
232are not fissile materials but are abundant in nature . In there
ii)92U and 90Th
actor, these can be converted in to a fissile material 94Pu239and92U233respectively
by absorption of neutrons.
25. What is Nuclear fusion or Thermo nuclear reaction?
Nuclear fusion is a process in which two or more lighter nuclei combine to form a
heavier nucleus. This reaction can be carried out only at high temperature. So it is
otherwise called thermo nuclear reaction.
26. What is meant by Cosmic Rays?
The ionising radiation many times stronger than - rays entering the earth
from all the directions from cosmic or interstellar space is known as cosmic rays.
They are of two types primary cosmic rays and secondary cosmic rays.
27. What is meant by Pair production and annihilation of matter?
The conversion of a photon into an electronpositron pair on its interaction with
the strong electric field surrounding a nucleus is called pair production.
The converse of pair production in which an electron and positron combine to
produce a photon is known as annihilation of matter.
28. Write a note on Lepton.
(i) Leptons are lighter particles having mass equal to or less than about 207 times the
mass of an electron
(ii) This group contains particles such as electron, positron, neutrino, antineutrino,
positive and negative mesons.
(iii) The neutrinos and antineutrinos are massless and chargeless particles, but
carrier of energy and spin.
29. Write a note on Mesons.
i.
Mesons are fundamental particle possessing mass intermediate between
electron and proton (me and mp).
ii.
iii.

The three types of mesons are (1) -meson (pion) (2) Kmeson
(3) - meson.
The mesons are the interaction agents between nucleons.
34

(kaon) and

30. Write a note on Baryons.


(i) Baryons form the heavier particle group.
(ii) Baryons are classified as nucleons and hyperons.
(iii)Protons and neutrons are nucleons.
(iv) There are four types of hyperons which are lambda, sigma, xi and omega
hyperons.
31. Choose the pairs of isotopes, isobars and isotones from the following isotopes.
22
24
24,
23
11Na ,
12Mg , 11Na
10Ne
Solution :(i) Isotopes : 11Na22, 11Na24
(ii) Isobars
: 12Mg24,11Na24
(iii)Isotones : 11Na24,10Ne23
32. Find the number of atoms in one gram of 3Li6 ? (Avagadro No. =6.023x1023)
Solution :No. of atoms in 6 gm of Li = 6.023x1023
No. of atoms in 1 gm of Li=(6.023x1023)
6
=1.0038x1023
33. The radioactive isotope 84Po214 undergoes a successive disintegration of two
decays and two -decays. Find the atomic number and mass number of the
resulting isotope.
Solution :214
A
4
4
0
0
84Po
ZX + 2He + 2He + -1e + -1e
A + 4 + 4 = 214
A = 214 -8 = 206
Z + 2 + 2 1 1 = 84
Z + 2 = 84 Z = 84 2 Z = 82
Hence A = 206 and Z = 82
34.The isotope 92U238 successively under goes three - decays and two-decays. What
is the resulting isotope?
238
92U

zX

He 4 + 2 He 4 + 2 He 4 + -1eo+ -1eo

A+4+4+4= 238
A= 238 12 = 226
Z + 2 + 2 + 2 1 -1= 92
Z= 92-6+2
Z=88
Hence the Isotope is 88Ra226
35.The half life of radon is 3.8 days. Calculate its mean life.
=
T (or)
= 1.443 T
= 1.443 x 3. 8
= 5. 4834 days
= 5. 5 days

35

36.What percentage of given radioactive substance will be left after 5 half life periods
Half life Period
Remaining Percentage Decayed Percentage
I

50%

50%

II

25%

(50 + 25)% = 75%

III

12.5%

(75 + 12.5)% = 87.5%

IV

6.25%

(87.5 + 6.25)% = 93.75%

3.125%

(93.75+3.125)% = 96.875%

After 5 half life periods 3.125% will be left


37.The half-life of 84Po218 is 3 minute. What percentage of the sample has
decayed in 15 minutes?
Half life Period
Remaining Percentage
I (3 minute)
50%
II (6 minute
25%
III (9 minute)
12.5%
IV (12 minute)
6.25%
V (15 minute)
3.125%
In 15 min 96.875% has decayed.

Decayed Percentage
50%
(50 + 25)% = 75%
(75 + 12.5)% = 87.5%
(87.5 + 6.25)% = 93.75%
(93.75+3.125)% = 96.875%

38.Tritium has a half life of 12.5 years. What fraction of the sample of will be left over
after 25 years?
Half life Period
Remaining Fraction
Decayed fraction
1/2

I (12. 5 Years)

3/4

II (25 Years)
No. of half lives = Total life time
Half life
=25/12.5 = 2
Sample left after 25 years =

5 Marks Questions And Answers


1. Explanation of binding energy curve.
BE/A sharply with mass number A upto20. It increases slowly after
A=20.ForA<20, there exists recurrence of peaks corresponding to those
nuclei, whose mass numbers are multiples of four and they contain not
only equal but also even number of protons and neutrons.
becomes almost flat for mass number between 40 and 120.
36

The BE/A8.8 MeV at A=56, (26Fe56). Hence, iron nucleus is the most stable.
The average B.E./A value is about 8.5 MeV for nuclei having mass number ranging
between 40 and 120. These elements are comparatively more stable and non radio
active.
For higher mass numbers the curve drops slowly and the BE/A is
about 7.6 MeV for uranium. Hence, they are unstable and radioactive.
The lesser amount of binding energy for lighter and heavier nuclei explains nuclear
fusion and fission respectively.
2. Nuclear force and properties of nuclear force.
There is some other force in the nucleus which overcomes the electrostatic
repulsion between positively charged protons and binds the protons and neutrons
inside the nucleus called nuclear force.

Nuclear force is charge independent. It is the same for all the three types of pairs of
nucleons (nn), (pp) and (np).It force is not electrostatic in nature.
Nuclear force is the strongest known force in nature.
Nuclear force is not a gravitational force. Nuclear force is about 1040 times stronger
than the gravitational force.
Nuclear force is a short range force. It is very strong between two nucleons which are
less than 1015m apart.

3. Properties of rays
They move along straight lines with high velocities.
They are deflected by electric and magnetic fields.
They produce intense ionization in the gas through which they pass. (The
ionizing power is 100 times greater than that of -rays and 10,000 times
greater than that of rays.)
They affect photographic plates.
They produce fluorescence.
Their penetrating power is less .
4. Properties of rays
(i) They move with over the range of 0.3c to 0.99c, where c is the velocity of light.
(ii) They are deflected by electric and magnetic fields.
(iii) The ionization power is comparatively low. (less than alpha particles)
(iv) They affect photographic plates.
(v) They produce fluorescence.
(vi) Their penetrating power is greater than that of rays.
5. Properties of rays
(i) They travel with the velocity of light.
(ii)They are not deflected by electric and magnetic fields.
(iii)They produce very less ionisation.
(iv)They affect photographic plates.
(v)They have a very high penetrating power.
(vi)They produce fluorescence.
37

6. Explain the SoddyFajans radio active displacement law.


-decay
When a radioactive nucleus disintegrates by emitting an -particle, the atomic
number decreases by two and mass number decreases by four.
226 Rn222 + He4
88Ra
86
2
decay
When a radioactive nucleus disintegrates by emitting a particle, the atomic
number increases by one and the mass number remains the same.
234 Pa234 + e0
90Th
91
1
decay
When a radio active nucleus emits rays, only the energy level of the nucleus
changes and the atomic number and mass number remain the same.
Eg: During the radioactive disintegration of radium (88Ra226) in to radon (86Rn222),
gamma ray of energy 0.187MeV is emitted, when radon returns from the excited state
to the ground state.
7. Properties of neutrons
Neutrons are the constituent particles of all nuclei, except hydrogen.

Neutrons are neutral particles with no charge and mass slightly greater than
that of protons.
Neutrons are stable inside the nucleus. But outside the nucleus they are unstable.
The half life of neutron is 13minutes.
1
1
0
0n 1H +1e +
As neutrons are neutral, they can easily penetrate any nucleus.
Neutrons are classified according to their kinetic energy as (a) slow neutrons(0 to
1000eV) and (b) fast neutrons(0.5MeV to 10MeV), (c) Thermal neutrons (0.025eV)
8. Medical applications of radio isotopes.
Radio cobalt (Co60) used in the treatment of cancer.
Radio-sodium (Na24) - used to detect the presence of blocks in blood vessels, to
check the effective functioning of heart Radio-iodine (I131) -used in the detection
of the nature of thyroid gland and to locate brain tumours.

Radio-iron (Fe59) -used to diagnose anaemia.

Radio-phosphorous(P32)used in the treatment of skin diseases.

9.
Biological hazards of nuclear radiations
The biological effects of nuclear radiation can be divided into three groups
(i)Short term recoverable effects
(ii)long term irrecoverable effect sand
(iii)genetic effect.
The extent to which the human organism is damaged depends upon (i) the dose and
the rate at which the radiation is given and (ii)the part of the body exposed to it.
Short term recoverable effects :
Smaller doses of radiation exposure produce skin disorder and loss of hair.
Long term irrecoverable effects :If the exposure is 100 R*, it may cause diseases like leukemia (death of red blood
corpuscle in the blood) or cancer. When it U 600 R, ultimately it causes death. Safe
38

limit is about 250 milli roentgen per week.


Genetic effect :The radiations cause injury to genes in the reproductive cells and gives rise
to mutations which pass on from generation to generation.
10. State and explain the working of Hydrogen bomb.
It is an explosive device to release a very large amount of energy by the
principle of fusion of light nuclei.
*The temperature required for the purpose of fusion is produced by the
explosion of an atom bomb produces temperature (of the order of 50 million degree
celcius.)
*A suitable assembly of deuteron and triton is arranged at the sight of
the explosion of the atom bomb.
*Favourable temperature initiates the fusion of light nuclei in an
uncontrolled manner, and releases enormous amount of heat energy.
3
2
4
1
1H +1H 2He +0n +energy
11. State
bomb.

the

principle

and

working

function

of

on

Principle :- Uncontrolled fission chain reaction.


Fissile Material :U235 or Pu239
Constructions :- An atom bomb consists of two hemispheres of U235 (or 94Pu239),
each smaller than the critical size and are kept apart by a separator aperture.
Working : When the bomb has to be exploded, a third well fitting cylinder of U235 (or
239)whose mass is also less than the
critical mass, is propelled so that
94Pu

it fuses together with the other two pieces.


The total quantity is greater than the critical mass and an uncontrolled chain
reaction takes place resulting in a terrific explosion.

Effects : The explosion releases tremendous amount of energy in the form of heat, light
and radiation.
Temperature of millions of degree celsius and pressure of millions of atmosphere
are produced.
Explosions produce shock waves.
The release of radioactive rays, neutrons and radioactive materials produce a
health hazards.

39

atom

12.

Cosmic ray showers


The cascade theory shows that the shower production involves two
processes. (i) radio active collision and (ii) pair production.
An energetic electron (e-) or positron (e+)present in cosmic rays loses energy,
when it collides with the nuclei of atoms in earths atmosphere. This energy loss
appears as high energy photon.
This photon interacts with an atomic nucleus and produce an electron (e-)
positron (e+) pair.
The electron and positron, produce more photons on interaction with nuclei,
which are further capable of bringing about pair production.
The multiplication will continue until the initial energy becomes divided and
the individual energy of the particles fall below the critical energy.

10 Marks Questions and Answers


1. Bainbridge mass spectrometer Determination of isotopic masses of nuclei

Bainbridge
mass spectro- meter is an instrument used for the accurate
determination of atomic masses.
Construction :
A beam of positive ions produced in a discharge tube is collimated in total fine
beam by two narrow slits S1 and S2.
This fine beam enters into a velocity selector.
The velocity selector allows the ions of a particular velocity of to come out of it.

40

Working :The electric field (E) and magnetic field (B) are perpendicular to each other.
They are adjusted that the deflection so that the ions do not suffer any deflection
within the velocity selector.
qE=Bqv
v=E/B

Ions having this velocity v, pass out of the velocity selector and then through
the slit S3, to enter the evacuated chamber D.

These positive ions are subjected to another strong uniform magnetic field of
induction B at right angles to the plane of the paper acting in wards.
These ions are deflected along circular path of radius R and strike the
photographic plate.
The force due to magnetic field Bqv provides the centripetal force.
B qv=mv2/R
m= B qR/v

Substituting v=E/B
m=B B qR/E
Ions with different masses trace semi-circular paths of different radii and produce
dark lines on the plate.
The distance between the opening of the chamber and the position of the dark line
gives the diameter 2 R.
Since q, B, B, E and R are known, the mass of the positive ions
and hence isotopic masses can be calculated.
2. Obtain an expression to deduce the amount of the radioactive substance present at
any moment.
Law of disintegration : The rate of disintegration at any instant is directly proportional to the number of
atoms of the element present at that instant.
Let N0 be the number of radio active atoms present initially and N, the number of
atoms at a given instant t.

here

- decay constant

At

t=0 N=N0
loge N0
loge N =
+ loge N0

loge(N/N0)=

N/N0=

N=N0

41

The number of atoms of a radio active substance decreases exponentially with


increase in time.
Half Life Period :The half life period of a radioactive element is defined as the time taken for one
half of the radio active element to under god is integration.

From the law of disintegration


N=N0
Whent=T1/2 N=N0/2
N0/2 = N0 e-T1/2
loge2 = T1/2
T1/2 =
T1/2 =

,
2.3026

T1/2 =

Half life period is inversely proportional to decay constant.


Relation between mean life and half life is given by

T1/2 = 0.6931

3. The Discovery of neutrons and properties of neutrons.


NeutronDiscovery : Bothe and Becker found that when beryllium was bombarded with -particles, a
highly penetrating radiation was emitted. Which were capable of traversing through
at hick layer of lead and was unaffected by electric and magnetic fields.
The radiation was thought to be rays.
In1932, Irene Curie and F. Joliot found that those radiations were able to knock out
protons from paraffin and similar substances that are rich in hydrogen.

Chadwick in the same year discovered that the emitted radiation consists of
particles of mass nearly equal to proton and no charge.
He called them as neutrons. (0n1)
9
4
12
1
4Be +2He 6C +0n
Whereon1 represents neutron.

42

Properties of neutrons :(i) Neutrons are the constituent particles of all nuclei, except hydrogen.
(ii) Neutrons are neutral particles with no charge and mass slightly greater
than that of protons.
(iii) Neutrons are stable inside the nucleus. But outside the nucleus they are
unstable. The half life of neutron is 13 minutes.
1
1
0
0n 1H +1e +
(iv) As neutrons are neutral, they can easily penetrate any nucleus.
(v) Neutrons are classified according to their kinetic energy as (i) slow neutrons (0
to 1000eV) and (ii) fast neutrons (0.5MeV to 10MeV). (iii) Thermal neutrons
(0.025eV)
4. GeigerMuller counter
Principle :When nuclear radiations pass through gas, ionization is produced.
Construction:tube with glass envelope (C) acts as the cathode.
A metal
A fine tungsten wire (W) along the axis of the tube acts as anode.
The tube is filled with an inert gas like argon at a low pressure.
One end is fitted with a thin mica sheet and this end acts as a window through which
radiations enter the tube.
A high potential difference of about 1000 V is applied between the electrodes
through a high resistance R of about 100 mega ohm.
Operation:
A ionizing radiation enters the counter.

Primary ionisation takes place and a few ions are produced.

Due to the high potential difference and they cause further ionisation

These ions are multiplied by further collisions.


An avalanche of electrons is produced and this avalanche of electrons on
reaching the anode generates a current pulse.
This current when passing through R develops a potential difference,
amplified by electronic circuits and is used to operate an electronic counter.
The counts in the counter is directly
proportional to the intensity of the
ionizing radiation.
The ionisation of the gas is
independent of the type of the incident
radiation.
Wilson cloud chamber detects the type
of particle.

43

5. Nuclear reactor.
A nuclear reactor is a device in which the nuclear fission reaction takes place
in a self sustained and controlled manner. The essential parts of nuclear reactor are
i) Fissile material or fuel
(i)
Fissile material or fuel
(ii)
Moderator
(iii)
Neutron source
(iv)
Control rods
(v)
The cooling system
(vi)
Neutron Reflector
(vii)
Shielding
The fissile material or nuclear fuel generally used is U235. Pu239 and U233 are used as
92
fissile material.
In the pressurised heavy water reactors (PHWR), natural uranium oxide is used as fuel.
In the pressurised light water reactors (PWR), low enriched uranium is used as fuel
In Kamini reactor U233 is used.
ii) Moderator
A Moderator converts neutrons of a moderator is to slow down fast neutrons of
energy about 2 MeV to thermal neutrons of energy about 0.025 eV,)
Moderators slow down the fast neutrons. E.g. Ordinary water and heavy water.
(iii)Neutron source
A source of neutron is required to initiate the fission chain reaction for the
first time.

E.g. A mixture of beryllium with plutonium or radium or polonium


(iv)Control rods
The control rods are used to control the chain reaction. They are very good absorbers of
neutrons
E.g. Boron, Cadmium, Boron Carbide.
(v)The cooling system
The cooling system removes the heat generated in the reactor core.
A good coolant must possess large specific heat capacity and high boiling point.

E.g. Heavy water, ordinary water, liquid sodium.


(vi) Neutron reflectors
Neutron reflectors prevent the leakage of neutrons to a large extent, by reflecting
them back.
E.g. Depleted Uranium (Uranium with less than 0.7% of 92U235), Thorium.
(vii)Shielding
There actor is surrounded by a concrete wall of thickness about 2 to 2.5m. as a
protection against harmful radiations.
Uses of reactors :1) Power production
2) To produce radio isotopes
3) Act as sources of neutrons

44

6. Stellar energy
ProtonProton cycle
1
1
2
0
1H +1H 1H +1e +(emission of positron and neutrino)
1
2
3
1H +1H 2He + (emission of gamma rays)
2 2He3 2He4 + 21H1
There action cycle is written as
41H1 2He4 +21e0 +2 +energy (26.7MeV)
CarbonNitrogen Cycle
The following cycle of reactions take place in carbon nitrogen cycle in which
carbon acts as a catalyst.
1
12
13*+ (emission of gamma rays)
1H +6C 7N
13* C13 + e0 + (emission of positron and neutrino)
7N
6
1
1
13
14
1H +6C 7N + (emission of gamma rays)
1
14
15* + (emission of gamma rays)
1H +7N 80
15* N15 + e0 + (emission of positron and neutrino)
80
7
1
1
15
12
4
1H +7N 6C +2He
The overall reaction of the above cycle is given as
41H1 2 He4 +21e0 +2 +energy(26.7MeV)
7. Cosmic Rays Latitude effect , Altitude effect .
Cosmic Rays:
The ionising radiation many times stronger than -rays entering the earth from
all the directions from cosmic or inter stellar space is known as cosmic rays.
Latitude effect :

The variation of cosmic ray intensity with geo magnetic latitude is known as
latitude effect.
Intensity is maximum at the poles (=900), minimum at the equator(=0) and
constant between latitudes of 420 and 900.
The decrease in cosmic ray intensity at the earths equator is be due to the earths
magnetic field.
The charged particles approaching poles travel almost along the direction of the
magnetic lines of force and hence maximum intensity at poles.
The charged particles approaching equator have to travel in a perpendicular
direction to the field and hence minimum intensity at the equator.

45

Altitude effect :

The study of variation of cosmic ray intensity (I) with altitude (h) is known as altitude
effect.
The intensity increases with altitude and reaches a maximum at a height of about 20 km.
Above this height there is a fall in intensity.

UNIT2 CURRENT ELECTRICITY

3 Marks Questions And Answers


1. Define Current.
The current is defined as the rate of flow of charges across any cross sectional area
a conductor.
I = q/t.
unit - ampere.(A)
2. Define drift velocity.
Drift velocity is defined as the velocity with which free electrons get drifted
towards the positive terminal, when an electric field is applied.
Unit ms-1
3. Define mobility.
Mobility is defined as the drift velocity acquired per unit electric field.
Unit: m2V1s1.
4. Define current density.
Current density at a point is defined as the quantity of charge passing per unit time
through unit area, taken perpendicular to the direction of flow of charge at that
point. J = I/A
Unit : A m-2
5. Define Ohms law
At a constant temperature, the steady current flowing through a conductor is
directly proportional to the potential difference between the two ends of the
conductor. i.e
V = IR

46

of

6. Define the resistance of a conductor


Resistance of a conductor is defined as the ratio of potential difference across the
conductor to the current flowing through it.
R=

unit ohm()

7. Define electrical resistivity of a material.


The electrical resistivity of a material is defined as the resistance offered to current
flow by a conductor of unit length having unit area of cross section.
unit: ohmm (m).
8. What is meant by superconductors?
The ability of certain metals, their compounds and alloys to conduct electricity
with zero resistance
at very low temperatures is called superconductivity. The
materials which exhibit this property are called super conductors.
9. Define Transition temperature.
The temperature at which electrical resistivity of the material suddenly drops to zero
and the material changes from normal conductor to super conductor is called the
transition temperature or critical temperature.
10. What are the changes followed at the transition temperature?
(i) The electrical resistivity drops to zero.
(ii) The conductivity becomes infinity
(iii)The magnetic flux lines are excluded from the material.
11. Define temperature coefficient of resistance.
The temperature coefficient of resistance is defined as the ratio of increase in resistance
per degree rise in temperature to its resistance at 00C. Its unit is per 0C.
12. State Kirchoffs i) current law ii) voltage law
1) Current law
The algebraic sum of the currents meeting at any junction in a circuit is zero. (law of
conservation of charge)
2) Voltage law
The algebraic sum of the products of resistance and current in each part of any closed
circuit is equal to the algebraic sum of the emfs in that closed circuit. (law of
conservation of energy)
13. What is the principle of potentiometer?
The emf of the cell ( E ) is directly proportional to its balancing
length.( )This is the principle of a potentiometer. i.e. E l
14. Why is copperwire not suitable for a potentiometer?
Copperhas
(i) Low electrical resistivity
(ii) High temperature coefficient of resistance

47

15. Distinguish between emf and potential difference


S.No. emf
Potential difference

The difference of potentials between


the two terminals of a cell in an open
circuit is called the electromotive
force (emf) of a cell.

Independent of external resistance of


the circuit.

The difference in potentials


between any two points in a closed
circuit is called potential
difference.

Proportional to the resistance between any


two points.

16. Describe the function of a watt meter.


The instrument used to measure electrical power consists of a movable coil
arranged between a pair of fixed coils in the form of a solenoid.
A pointer is attached to the movable coil. The free end of the pointer moves over a
circular scale.
When current flows through the coils, the deflection of the pointer is directly
proportional to the power.
17. Distinguish between electric power and electric energy
S.No.
Electric power
Electric energy
1

Electric power is defined as the rate of Electric energy is defined as the


doing electric work.
capacity to do work.

Power P = VI

Energy E = VIt

Unit : watt (W)

Unit: Joule(J)
Practical unit KWh

18. Define electrolysis


The passage of an electric current through a liquid causes chemical changes and this
process is called electrolysis.
19. State Faradays laws of electrolysis.
First Law: The mass of a substance liberated at an electrode is directly
proportional to the charge passing through the electrolyte.
m q or m = zIt
Second Law:The mass of a substance liberated at an electrode by a given amount
of charge is proportional to the chemical equivalent of the substance.
mE

48

20. Define electrochemical equivalent.


The electrochemical equivalent of a substance is defined as the mass of substance
liberated in electrolysis when one coulomb charge is passed through the
electrolyte. Unit - Kg C-1
21. What are the applications of secondary cells?
(i) The secondary cells are rechargeable.
(ii) They have very low internal resistance. Hence they can deliver a high current if required.
(iii)They are used in all automobiles like cars, two wheelers, trucks etc
22. Distinguish between primary cells and secondary cells
S.No.
Primary cell
Secondary Cell

23.

Electric energy is derived


irreversible chemical actions

by Electrical energy is derived


reversible chemical reactions

Cannotbe recharged

Canbe recharged

High internal resistance

Low internal resistance

Cannot supply steady current for Can supply


long time
longtime

steady

current

If 6.251018 electrons flow through a given cross section in unit time, find the
current.(Given: Charge of an electron is 1.61019 C)
Solution:

I= I=

I=
24.

= 1A

An incandescent lamp is operated at 240V and the current is 0.5A. What is the
resistance of the lamp?
Solution:

R =
R =
R=
R = 480
25. A manganin wire of length 2m has a diameter of 0.4mm with a resistance of
70. Find the resistivity of the material.
Solution: =

=
= 1.57 x 7 x 4 x 10-7
= 4.396x10-6 m

49

by

for

26. In the given network, calculate the effective resistance between points
A and B

Solution:
R1, R2 are in Parallel combination
,

= 7.5

27. Three resistors are connected in series with 10V supply as shown in the figure. Find
the voltage drop across each resistor.

Solution:
Effective resistance of series combination Rs = R1 + R2 + R3
Rs = 5 + 3 + 2 Rs = 10
Current in circuit I =

=1A

According to Ohms law V = IR


V1 = IR1 = 1 x 5 = 5V
V2 = IR2 = 1 x 3 = 3V
V3 = IR3 = 1 x 2 = 2V
V1 = 5V; V2 = 3V; V3 = 2V

50

28. In the given circuit, what is the total resistance and current supplied by the
battery.

Solution:
3, 3, 3 are parallel combination.

+ +

Rp = 1

Now Rp = 1 and 2 are in series combination.


Hence effective resistance = Rp + R4
Rs = (1+2) Rs = 3
Current supplied by the battery

I=

= = 2A

I = 2A
29. Two wires of same material and length have resistances 5 and
10 respectively. Find the ratio of radii of the two wires.
Solution: Let R1 = 5, R2 = 10, 1 = 2 =

=
=
=
r1: r2 =
:1
30. Calculate the current in the given circuit and also find the direction of the current.
A
5
10V
7
2V
B

3
D

8V
51

Solution:
Let the current flowing the circuit is I. Current flowing in the direction ABCDA(Clock wise
direction)

5 I + 7I + 3I + 5I = 10 + 2 8
20 I = 4, I = I = 0.2 A
Current is flowing in the Clock wise direction
31. Calculate the current in the given circuit and also find the direction of the current.
A
5
10V
10
B

D
20 V
According to Kirchoffs second law
5 I + 10 I + 5 I = 10 + 20,
20 I = 30 I = I = 1.5 A

Current flowing in the direction ABCDA(Clock wise direction)


32. Calculate the current in the given circuit and also find the direction of the
current.
5

10V

10

Solution:
According to Kirchoffs second law
5I+10I+5I = 10-20
20I = -10

I= I=I=-0.5A
Current I = 0.5A
Currents flows in the anti clock wise direction ( ADCBA)

52

33. The resistance of a nichrome wire at 0oC is 10. If its temperature coefficient of
resistance is 0.004/oC, find its resistance at boiling point of water. Comment on
the result.
Solution:

R100

Rt = Ro (1 + t)
R100 = Ro (1+100)
= 10 (1+ 100 x 0.004)
=10 (1 + 0.4)
= 10 x 1.4
R100 = 14

As the temperature increases the resistance also increases


34. The resistance of a platinum wire at 0 C is 4. What will be the resistance of
the wire at 100o C if the temperature coefficient of resistance of platinum is
0.0038 C.
Solution:
Rt = Ro (1 + t)
R100 = Ro (1 + 100 )
R100= 4 (1 + 100 x 0.0038)
= 4 (1 + 0.38)
= 4 x 1.38
R100 = 5.52

35. A 1.5 V carbonzinc dry cell is connected across a load of 1000.


Solution: Calculate the current and powers applied to it.
i) Current I =
=
I = 1.5x10-3 A
ii) Power P= VI
P=1.5x1.5x10-3
P=2.25x10-3 W
36.

An iron box of 400 W power is used daily for 30minutes. If the cost
per unit is 75 paise, find the weekly expense on using the iron box.
Solution: Energy Consumed
E= Pxt
E = 400 x x 7
E = 1400 Wh
E = 1.4 Unit
Cost of 1 unit = Rs. 0.75
Cost of 1.4 Units = 1.4 x 0.75
Expense = Rs 1.05
53

5 MARKS QUESTIONS AND ANSWERS


1.

Relation between current and drift velocity

Consider a conductor XY of length L and area of cross section A . An electric field


E is applied between its ends.
Let n be the number of free electrons per unit volume.

The total charge passing through the conductor q=(nAL)e

The time in which the charges pass through the conductor, t=

The current flowing through the conductor, I

I nAe vd

q
(nAL)e

t
L
v
d

2. Applications of super conductors


(i) Super conductors form the basis of energy saving power systems,
(ii)Super conducting magnets have been used to levitate trains above its rails.
(iii)Super conducting magnetic propulsion systems may be used to launch satellites
into orbits directly from the earth without the use of rockets.
(iv)T he current in a superconducting wire can flow with out any change in
magnitude, it can be used for transmission lines.
(v)Superconductors can be used as memory or storage elements in computers.
3. Effective resistance when number of resistors connected in series

Let us

consider

the resistors of resistances R1, R2, R3 and R4 connected in


series. Applied potential difference V.
In Series connection current in each resistor the same.
V1 = I R1 ; V2 = I R2, V3= I R3, V4 = I R4
Net potential
V = V1+V2+V3+V4
V = I[R1+R2+R3+R4]
(1)
Let Rs be the effective resistance
V = I Rs
(2)
From equations (1) and (2) , Effective resistance Rs = R1+R2+R3+R4
54

4. Resistors in parallel

Consider four resistors of resistances R1, R2, R3 and R4 are connected in parallel.A
source of emf V is connected to the
parallel combination in parallel connection the
potential difference (V)across each resistor is the same.

V
V
V
V
; I 2 ; I3 ; I 4
R1
R2
R3
R4
Net current I = I1 +I2 +I3 + I4.
I1

V V V V

R1 R2 R3 R4
1
1
1
1
I V

---- 1
R1 R2 R3 R4
Let the effective Resistance be Rp
V
------ 2
I
Rp
1
1
1
1
1
From equations (1) and (2)

Rp R1 R2 R3 R4

5. Temperature dependence of resistance


For conductors the resistance increases with increase in temperature.
Rt= Ro(1 + t)
is called the temperature coefficient of resistance.

The temperature coefficient of resistance is defined as the ratio of increase in resistance


per degree rise in temperature to its resistance at 00C. Its unit is per 0C.
R R0
t
R0 t

Metals have positive temperature coefficient of resistance.

55

Insulators and semiconductors(thermistors) have negative temperature coefficient of


resistance in temperature.
The temperature coefficient is low for alloys.
6. Determination of internal resistance of a cell using voltmeter

With key K open the emf of cell E is found by connecting a high resistance voltmeter
across it. A small value of resistance R is included in the external circuit and Key K is
closed. The potential difference across R is equal to the potential difference across
cell(V).
V = IR
Internal resistance of the cell (r) , V is less than E
V = E Ir
Ir = E V
equations (1) / (2 )
=

E V
r
R
V
7. Kirchhoffs second law (Voltage law)
Kirchhoffs voltage law states that the algebraic sum of the products of resistance
and current in each part of any closed circuit is equal to the algebraic sum of the emfs in
that closed circuit.
It is based on the principle of law of conservation of energy
The current in clockwise direction is taken as positive and the current in anti clock
wise direction is taken as negative.
For the circuit shown in fig;

The closed loop ABCDA


I1 R1 + I2 R2 + I2 r2 + I3 R3 + I1 r1 = E1 E2

56

8. Wheatstones bridge

Applying to Kirchhoffs first law at junction B : I1 Ig I3 = 0 (1)


At junction D: I2 + Ig I4 = 0 (2)
Applying to Kirchhoffs second law for the closed path ABDA
I1P + IgG I2R = 0
(3)
According to Kirchhoffs second law for the closed path ABCDA
I1 P + I3 Q I4 S I2 R = 0
(4)
For zero deflection Ig = 0
I1 = I3 (5)
I2 = I4 (6)
I1P = I2R (7)

Substituting the equation (5),(6),and (7) in equation 4


I1(P+Q) = I2(R+S)
(8)
Dividing equation (8) and (7)
I1 ( P Q )
RS

I1 P
R
Q
S
1 1
P
R
P R

Q S

9. Principle of potentiometer

The potentiometer wire B is connected in series with a battery (Bt), Key(K), rheostat
(Rh) This forms the primary circuit.
A primary cell is connected in series with the positive terminal A of the potentiometer, a
galvanometer, high resistance and jockey. This forms the secondary circuit.
If the potential difference between A and J is equal to the emf of the cell, no
current flows through the galvanometer. It shows zero deflection.
57

If the balancing length is l the potential difference across AJ = Irl where r is the
Resistance per unit length of the potentiometer wire
E = Irl,
El

Emf of the cell( E ) is directly proportional to its balancing length.


10. Comparison of emfs of to given primary cells using potentiometer

The potentiometer wire AB is connected in series with the battery (Bt), key(K),
Rheostat(Rh) .This forms the primary circuit

The cells with emfs E1, E2are connected with the terminals C1D1 and C2 D2 of the
DPDT switch.

Current in the primary circuit is I. The resistance per unit length of the wire is r

E1 is connected to the secondary circuit


E1 =

(1)

E2is connected to the secondary circuit


E2=

is the balancing length

is the balancing length

(2)

Dividing 1 2

E1 1

E2 2

11. Verification of Faradays first law of electrolysis

Law:
The mass of a substance liberated at an electrode is directly proportional to the charge
passing through the electrolyte. A battery, a rheostat, a key and an ammeter are connected
in series to an electrolytic cell
58

A current I1 is passed for a time t. the mass m1 of the substance deposited is obtained.

A different current I2 is passed for the same time t. The mass m2 of

the substance deposited is obtained that


m1
I
1 m I
m2 I 2

(1)

The experiment is repeated for same current I for time mass of the s u b s t a n c e

deposited is
The same current I is passed for time t2, the mass of the substance deposited is m4,

m3 t1

m4 t2

mt

(2)

From equations(1) and (2)


M It

12.Verification of Faradays second law of electrolysis

Rh

Second Law: The mass of a substance liberated at an electrode by a given amount


of charge is proportional to the chemical equivalent of the substance.

mE

The circuits are connected as shown in the diagram


The current is passed for time t.
The mass of copper deposited is found as m1

(E1-chemical equivalent of copper)


The mass of silver deposited is found as m2

(E2-chemical equivalent of silver)


m1 E1

m2 E 2

mE

59

13. Voltaic cell:


Construction :
AnodeCopper
CathodeZinc
ElectrolyteDiluted sulphuric acid
VesselGlass

Action :
Zinc rod reacts with H2SO4 and zinc rod becomes negative charge by removing Zn++ions
Copper neutralizes 2H+ ions and thus becomes positive.
The current passes from copper to zinc in the external circuit.
Emf produced by the cell 1.08V

14. Daniel cell

It cannot supply steady current for a long time.


Construction :
AnodeCopper
CathodeZinc
Electrolytecopper sulphate solution , Diluted sulphuric acid
VesselCopper
Action :

The zinc rod reacting with dilute sulphuric acid produces Zn++ ions and 2electrons
and thus becomes negative.
Zn++ ions pass through the pores of the porous potand reacts with copper
sulphate solution, producing Cu++ ions the Cu++ ions deposit on the copper vessel
and the vessel becomes positive.
When Daniel cell is connected in a circuit, the two electrons on the zinc rod
pass through the external circuit and eutralizing t h e c o p p e r ions.
Electric current passes from copper to zinc, in the external circuit
Emf produced by the cell 1.08V.

60

15. Leclanche cell


Construction:
AnodeCarbon rod
CathodeZinc rod
ElectrolyteAmmonium
solution

Chloride

VesselGlass

Action:

At the zinc rod, due to oxidation reaction Zn atom is converted in to Zn++ ions
and 2 electrons. Zn++ions reacting with ammonium chloride produces zinc
chloride and ammonia gas.
Zn++ +2NH4Cl2NH3 +ZnCl2+2H+ +2e

The positive charge of hydrogen ion is transferred to carbon rod and the two
electrons from the zinc rod move towards carbon and neutralizes the positive
charge.
Thus current flows from carbon to zinc.

Emf produced by the cell 1.5V

Current produced by the cell 0.25


16. Lead Acid accumulator
Construction :
Anode
Lead oxide
CathodeLead
ElectrolyteDiluted Sulphuric acid
VesselRubber or Glass

Action:
The spongy lead reacting with dilute sulphuric acid produces lead sulphate and two
electrons due to oxidation.
At the positive electrode due to reduction process lead oxide on reaction with
sulphuric acid produces lead sulphate and the two electrons are neutralized in this
process.
The cell has low internal resistance and hence can deliver high current.
The emf of a freshly charged cell is 2.2Volt.
The emf falls to about 2 volts during discharge .

61

UNIT 4

ELECTRO MAGNETIC INDUCTION AND ALTERNATIING CURRENT


3 Mark Questions And Answers

1. Define magnetic flux. Give its unit.


The number of magnetic lines of force crossing a closed area is called magnetic flux
unit : weber (Wb)
2. What is electromagnetic induction?
The phenomenon of producing an induced emf due to the changes in the
magnetic flux associated with a closed circuit is known as electromagnetic
induction.
3. State Faradays laws of electromagnetic induction?
First law
Whenever the amount of magnetic flux linked with a closed circuit
changes, an emf is induced in the circuit. The induced emf lasts so long as the
change in magnetic flux continues.
Second law
The magnitude of emf(e) induced in a closed circuit is directly proportional
to the rate of change of magnetic flux

linked with the circuit.

e
State Lenzs law of electromagnetic induction?
The induced current produced in a circuit always flows in such a direction
that it opposes the change or cause that produce sit.
5. State Flemings Right hand rule.(Generator Rule)
4.

The forefinger, the middle finger and the thumb of the right hand are held in the three
mutually perpendicular directions. If the forefinger points along the direction of the
magnetic field and the thumb is along the direction of motion of the conductor,
then the middle finger points in the direction of the induced current.
6.What is self induction ?
The property of a coil which enables to produce an opposing induced emf in it when
the current in the coil changes is called self induction.
7. Define coefficient of self induction
The coefficient of self induction of a coil is numerically equal to the magnetic flux
linked with a coil when unit current flows through it. Unit : Henry(H)

8. Define the unit of co-efficient of self induction


The unit of self inductance is henry(H).
One henry is defined as the self-inductance of a coil in which a change in current
of one ampere per second produces an opposing emf of one volt.
62

9.What is mutual induction ?


The phenomenon of producing an induced emf in a coil due to the change in
current in the other coil is known as mutual induction.
10.Define coefficient of mutual induction
The coefficient of mutual induction of two coils is numerically equal to the magnetic
flux linked with one coil when unit current flows through the neighbouring coil.
Unit : Henry(H)
11. Define the unit of coefficient of mutual induction.
The unit of coefficient of mutual induction is henry.
One henry is defined as the coefficient of mutual induction between a pair of coils
when a change of current of one ampere per second in one coil produces an induced emf
of on evolt in the other coil.
12.What are the factors in which coefficient of mutual induction depends.
(i)Size and shape of the coils, number of turns and permeability of material
on which the coils are wound.
(ii)proximity of the coils
13.What are the methods of producing induced emf?
The induced emf can be produced by changing
(i)the magnetic induction(B)
(ii)area enclosed by the coil(A)and
(iii)the orientation of the coil() with respect to the magnetic field.
14. State the principle of A.C. generator (A.C. dynamo)
An emf is induced in a coil when it is rotated in a uniform magnetic field.
(electromagnetic induction)
15.What are Eddy current (Foucault current) ?
When a mass of metal moves in a magnetic field or when the magnetic field through
a stationary mass of metal is altered, induced current is produced in the metal. This
induced current flows in the metal is called eddy current.
16. What is a transformer ? Give its principle.
Transformer is an electrical device used for converting low alternating voltage into
high alternating voltage and vice versa.
Principle: electromagnetic induction (Mutual induction)

63

17. Distinguish between step-up transformer and step-down transformer


Step-up transformer

Step-down transformer

1.

Increases the voltage ( Es > Ep)

Decreases the voltage (Es < Ep)

2.

Decreases the current( Is < Ip)

Increases the current ( Is > Ip)

3.

The number of turns in the


secondary coil is greater than the
number of turns in the primary coil
( Ns > Np).

The number of turns in the


secondary coil is lesser than the
number of turns in the primary
coil ( Ns < Np).

4.

Transformer ratio k >1

Transformer ratio k <1

S.No

18. Define the efficiency of a transformer


Efficiency of the transformer is defined as the ratio of output power to the input power.

19. D. C. ammeter cannot read A.C. Why?


The average value of A.C over one complete cycle is zero. So when we connect a
D.C ammeter it shows only zero deflection.
20. Define the rms value of A.C. (effective value of A.C)
The rms value of alternating current is defined as that value of the
steady current, which when passed through a resistor for a given time, will generate
the same amount of heat as generated by an alternating current when passed through
the same resistor for the same time.
21.What is meant by inductive reactance ?
The resistance offered by a coil (inductor) is known as inductive reactance.
XL= L
Unit : ohm ()
22.What is meant by capacitive reactance?
The resistance offered by a capacitor is known as capacitive reactance.
Xc=
Unit : ohm ()
23. A capacitor blocks d.c but allows a.c. w h y ?

The capacitive reactance

The frequency of d.c (


So Xc = ie. capacitive reactance becomes infinity, It is does not allow d.c
According to

it allows only a.c to pass through.

64

24. What happens in the current if the frequency of a.c voltage increases in R.L.C.
series circuit?
If the frequency of the alternating voltage increases , the impedance decreases and the
current increases . At the resonant frequency the current reaches its maximum value. If
the frequency is greater than the resonant frequency, the current decreases slowly.
25.What is resonant frequency in R.L.C. series circuit?
The particular frequency at which the impedance of the circuit becomes minimum
and therefore, the current becomes maximum is called resonant frequency of the circuit.
26.Define Q factor (Quality factor)
The Q factor of a series resonant circuit is defined as the ratio of the voltage
across a coil or capacitor to the applied voltage.
voltage across L or C
Q= applied voltage
Q=
27. What is power factor of an a.c circuit?
Power factor = cos
Here is the phase difference between alternating current and voltage. It is the ratio of
average power to its apparent power.
28.What is a choke coil?
A choke coil is an inductance coil of very small resistance used for controlling
current in an a.c.circuit.
29. Distinguish between AF choke coil and RF choke coil
S.No AF choke coil

RF choke coil

1.

Used in
circuits.

2.

They have iron core.

They have air core.

3.

Self-inductance is high.

Self-inductance is low

low

frequency Used in high frequency circuits.

30. A coil of area of cross section 0.5m2 with 10 turns is in a plane which is
perpendicular to an uniform magnetic field of 0.2Wb/m2. What is the flux
through the coil?
Solution:
Magnetic flux = NBAcos
= NBAcos0o
(...= 0o)
= 10 x 0.2 x 0.5
= 1 Wb
65

31. An emf of 10 mv is induced when the current in the coil changes at the rate of
2A s 1. W h a t i s t he coefficient of self-induction of the coil?

Solution :

e = -L

Coefficient of self-induction L =

L = 5x10-3 H (or) L = 5mH

32. An emf of 5V is induced when the current in the coil changes at the rate of
100A s 1. W h a t i s t he coefficient of self induction of the coil?
Solution :

e = -L

Coefficient of self-induction

L=

L = -0.05H

L= 0.05 H

33 . A solenoid of length1m and 0.05m diameter has 500 turns. If a current of 2A


passes through the coil, calculate the coefficient of self induction of the
coil.
Solution :

= 4 x 3.14 x 25 x 3.14 x 625 x 10-7 + 4 - 6


L = 6.16 x 10-3 H (or)
L = 6.16mH

34. Calculate the mutual inductance between two coils when a current of 4A
changing to 8A in 0.5s in one coil, induces an emf of 50mv in the other coil.
Solution:

e2 = -M(
Coefficient of mutual induction M =
M=

M = 6. 25 mH
66

x 10-3 = -6. 25 mH

35. Magnetic field through a coil having 200 turns and cross sectional area
0.04m2 changes from 0.1wbm2 to0.04 wb m2 in 0.02s.Find the induced
emf.
Solution :

200x4x10-2 x3
2x4x3
24V
The magnitude of induced emf e =24V
36. An aircraft having a wing span of 20.48m flies due north at a speed of 40
ms1. If the vertical component of earths magnetic field at the place is
2105T, Calculate the emf induced between the ends of the wings.
Solution:- Induced emf e= - B v
e = -2 x 10-5 x 20.48 x 40
= -20.48 x 80 x 10-5
= -1638.4 x10-5
e = -0.0164V
37.

An aircraft having a wing span of 10m flies due north at a speed of 720 km/ hr . If
the vertical component of earths magnetic field at the place is 3 105T, Calculate
the emf induced between the ends of the wings.

Solution:-Induced emf
e = -B v
-5
e = -3 x 10 x 10 x 720 x
e = -3 x 10 x 200 x 10-5
e = -6000 x 10-5e = - 0.06 V

38.Two rail so far railway track insulated from each other and the ground are
connected to a millivolt meter.The train runs at a speed of 180 Km/hr. Vertical
component of earths magnetic field is 0.2104 Wb/m2 and the rails are
separated by1m. Find the reading of the voltmeter.
Solution:-Induced emf
e = -B v

Reading of the voltmeter = 1m


67

39. The transformer ratio of an ideal transformer is 1:20 .Its input power and voltages
are 600mW, 6V respectively. Find the primary and the secondary current.
Solution :
= , Ep Ip = 600 mW; Ep = 6V
Ep Ip = 600 mW

But

= 100x10-3 = 0.1 A

Ip =

=
Is=

x Ip =

x 0.1 = 2A

The current in the primary coil = 0.1A


The current in the secondary coil = 2A
40. 11 kW power is transmitted at a rate of 22,000V through a wire of resistance
Find the power loss in the wire.
Solution :-

Electric power

P = VI
I =
I =

Power loss

Power loss

I = 0.5A
= I2R
= (0.5)2x 2
= 0.25 x 2
= 0.5 W

41. Write the equation of a 25 cycle currents in a wave having rms value of 30 A.
Solution :
= sin t
=

42.A capacitor of capacitance 2F is in an a.c.circuit of frequency 1000Hz. If the rms


value of the applied emf is10V,find the effective current flowing in the circuit.
Solution :
Xc = =
Xc =

Xc =
Effective current Irms=

=
Irms=

=0.126A
68

5 Marks Questions and Answers


1.Self-inductance of a long solenoid

1.

Consider a long solenoid of length and area of cross section A and number of
turns N.and the current be I
Magnetic flux per turn = BArea of each turn
NI
NI

0 A B 0

Total magnetic flux of the solenoid


NIA
0
N

0 N 2 IA

N
(1)

Magnetic flux = LI
(2)
From equations 1 and 2
0 N 2 AI
LI
`

N2A
L 0

N 2 A
L
In a medium of permeability

Energy associated with an inducted


Work has to be done by external agencies in establishing the current in an
inductor
Induced emf e L dI

dt

The small amount of work done in an interval dt


dW = e I dt
dW L

dI
I dt
dt

dW = -L I d I
The total work done to increase the current from zero to maximum
I0

W dW LIdI
0

1
W L I 02
2

The energy stored in the inductor


U

1
L I 02
2

69

3. Mutual induction of two long solenoid

S1 and S2 are two long solenoids with length and area of cross section A. N1 and
N2 are their number of turns
The magnetic flux linked with S2 due to I1 current in S1 = B1 A
N

N
B1 0 1 I1
0 1 I1 A

N
The total magnetic flux in S2 2 0 1 I1 A N 2

N1 N 2
(1)
2 0
I1 A

2 = M I1
(2)
From equations 1 and 2
MI1

0 N1 N 2 AI 1

0 N1 N 2 A

In a medium of permeability ,
N1 N 2 A
M

4. Emf induced by changing the area enclosed by the coil

The conductor PQRS is in perpendicular to the magnetic field


L1M1 The sliding conductor , its length
The initial area enclosd by the conductor L1QRM1
The conductor is displaced by a distance of dx in dt seconds. The final area is
L2QRM2
Change in the area
dA= dx
Change in magnetic flux d= B dA = B dx
d
Induced emf
e
dt
dx
e B
dt
e Bv

70

5. Power losses in a transformer and the methods to reduce the losses


S.No Power loss
Causes
Method to reduce
1.
Hysteresis loss
The repeated magnetisation Using cores made of
and demagnetization of the mumetal and silicon
iron core
steel
2.
Eddy current loss The varying magnetic flux Using
laminated
(Iron loss)
leads to eddy current and core made of stelloy
wastage of energy in the form
of heat.
3.
Flux loss
The flux produced in the Using shell type
primary is not linked with core
secondary
4.
Copper loss
Current passing through the Using thick wires
primary and secondary leads with low resistance
to Joules heating effect
6. Expression for RMS value of alternating current or prove that

Irms

I0
2

Alternating current I = Io sin t


I0, is the peak value of the alternating current
The amount of heat produced in the resistor of resistance R in a small time dt
dH = I 2R dt
The amount of heat produced in one complete cycle
H= i2Rdt
H=

( sin2

dt

I 02 RT
(1)
2
The heat produced by RMS value of the current (Irms)
2
H I rms
RT
(2)
H

From equations 1 and 2


2
I rms

I 02
2

I rms

I0
2

71

7.AC circuit with resistor only


An alternating source of emf is connected to a resistor with resistance R.

The instantaneous value of alternating emf


e = E0 sin t

(1)

The potential drop across the resistor e = iR


Potential drop must be equal to applied emf
iR = E0 sin t
i = E0 sin t
R
i = Io sin

(2)

The applied voltage and current are in phase with each other
Phase diagram

Phasor diagram

8. Power in an AC circuit (True power or average power)

The instantaneous power of an A.C circuit is the product of the instantaneous emf
and the instantaneous current flowing through it.

emf

e = E0 sin t

Current i = I0 sin( t + )

Average power consumed in one complete cycle


Pav =

=
Pav =

cos
72

Pav =

cos
= Erms Irmscos

Pav = Apparent power x Power factor

10 Mark Questions and Answers


1. Emf induced by changing the orientation of the

coil.

PQRS is a rectangular coil of N turns and area A is rotated with angular


velocity about an axis perpendicular to the direction of the magnetic field

The magnetic flux changes.


The magnetic flux = NBA cos t
The induced emf e = e= -

(NBA cos t )

e = NBA sin
e = Eosin
Here Eo = NBA

73

Plane of the coil with Induced emf


magnetic field
0o

Perpendicular

90o

parallel

Eo

180o

Perpendicular

270o

parallel

-Eo

360o

Perpendicular

2. Single phase A.C generator (A.C dynamo)


Principle: Electro magnetic induction

Construction :Essential parts


i)
Armature;:- A large number of loops or turns of insulated copper wire wound
over a laminated soft iron core.
ii)
Field magnets :Permanent magnets in the case of low power dynamos and
electro magnets in the case of high power dynamos.
iii)
Slip rings :- The metal rings R1,R2 are connected to the ends of the armature
and they rotate along with armature.
iv)
Brushes :- B1,B2 are the two flexible carbon brushes which pass on the current
from armature to external power .
Working: Armature rotates in anti clockwise direction in the magnetic field
Emf is induced in the armature coil.
The direction of induced emf is given by Flemings right hand rule.
74

First half cycle

Second half cycle


AB moves upwards

1) AB moves downwards

CD moves downwards

2) CD moves upwards
3) The current flows in
armature along DCBA.

the

The current flows in the armature


along ABCD

The current flows from B2toB1in


4) The current flows from B1 toB2
the external circuit
in the external circuit
Wave form :

Induced emf

e = Eo sin t , Here, Eo = NBA

3. Eddy currents - methods to reduce , applications


When a mass of metal moves in a magnetic field or when the magnetic field through a
stationary mass of metal is altered, induced current is produced in the metal. This induced
current flows in the metal hence this current is called eddy current.
Methods to reduce ;i) using thin laminated sheets instead of solid metal.
ii) holes drilled in the plates
Applications of Eddy current :
(i)Dead beat galvanometer
When current is passed through a galvanometer the coil
oscillates.

Eddy currents are set up in the metallic frame, which opposes


further oscillations of the coil.

The oscillations of the coil die out instantaneously, the


galvanometer is called dead beat galvanometer.

(ii)Induction furnace
The material to be melted is placed in a varying magnetic field
of high frequency.

A strong eddy current is developed inside the metal. Due to the


heating effect of the current, the metal melts.

(iii) Induction motors

Eddy currents are produced in a metallic cylinder called rotor,


when it is placed in a rotating magnetic field.
75

The eddy current initially tries to decrease the relative motion


between the cylinder and the rotating magnetic field and metallic
cylinder is set in to rotation.
These motors are used in fans.

(iv)Electrom agnetic brakes

The drum rotates along with the wheel when the train is in
motion.
When the brake is applied, a strong magnetic field is developed
and eddy currents are produced in the drum .
The eddy current oppose the motion of the drum and the train
comes to rest.

(v)Speedometer

A magnet rotates inside an aluminium cylinder (drum)


according to the speed of the vehicle.
Eddy currents produced in the drum makes it deflected through a certain angle .
A pointer attached to the drum move so vera
Calibrated scale which indicates the speed of the vehicle.

4. Transformer - principle , construction , working , efficiency , power losses


Transformer :
Transformer is an electrical device used for converting low alternating voltage into
high alternating voltage and vice versa.
principle :- Electromagnetic induction (Mutual induction)

Construction : It consists of insulated primary and secondary coils wound on a soft iron core .
A laminated soft iron core is used.

Working:
A varying alternating voltage is given to primary coils.
The magnetic flux changes in the primary coils
Magnetic flux in the secondary coil changes. An emf is induced in the secondary
coils.
Ep, Es the emfs Np, Ns the number of turns in the coils Ip, Is the currents
76

Flux linked with primary and secondary are equal.

For an ideal transformer , the input power = output power


Ep Ip = Es Is
ie.

Efficiency

= k ,the transformer ratio


Step up transformer

Step
down
transformer

Es> Ep

Ep> Es

Ns>Np

Np>Ns

Ip>Is

Is>Ip

K> 1

K< 1

= output power

Input power

Power losses i) Hysteresis loss ii) copper loss


iii) eddy current loss iv) flux loss

5. A.C circuit with inductor only

An alternating source of emf is applied to pure inductor of negligible resistance with


inductance L
Applied emf e = Eo sin t
( 1)
Induced emf

e=-L

But

e = - e'
Eo sin t = L

i=

sin t dt

Current; i =
77

i=
i=

sin t dt
sin ( t - )

Current i = Iosin ( t - )
From equations (1) and (2)
Phase diagram

(2)

the current lags behind the voltage by a phase of


phasor diagram

Reactance of the inductor

L = XL

For d.c.
= 0 XL = 0 so a pure inductor offers zero resistance to d.c. . But the
inductive reactance varies proportional to the frequency for a.c.
6. A.C circuit with capacitor only

An alternating source of emf is connected to a capacitor of capacitance C


Applied emf

e = Eo sin t

(1)

The potential drop across the capacitor = the applies emf


e=
Current i =

= (Ce)
i = (CEo sin
i = E0 C sin
i=

sin
i = Io sin

)
)
)

From equations 1 and 2 current leads the voltage by a phase of

78

(2)
.

Phase diagram

Phasor diagram

Reactance of the capacitor

Xc =

For d.c.

= 0, XC =

So a capacitor does not allow a.c to pass through

For a.c. XC

7. R, L, C series circuit
A resistor R , an inductor L , a capacitor C are connected in series and the
combination is connected across alternating source of emf

VR = I R
VR, I are in phase

VL= I XL
VL leads the current by a phase of

Vc= I Xc
Vc lags behind the current by a phase of
The circuit is considered as predominantly inductive
(i) Effective voltage
2

V = VR + (VL-VC)

V=
V=
V=I

(ii) Impedance
(iii) Phase angle between V and I
tan =
= tan-1(

Current I = Io sin (

79

Voltage phasor diagram

UNIT-3 EFFECTS OF ELECTRIC CURRENT


3 Mark Questions
1. State Joules law of heating.
2. Define Peltier coefficient.
3. Define Thomson coefficient.
4. State Biot-Savart law.
5. State Amperes circuital law.
6. Define Ampere.
7. Nichrome is used as heating element . Why?
8. What is Seebeck effect?
9. What is Peltier effect?
10. What is neutral temperature?
11. State Maxwells right hand cork screw rule.
12. State right hand palm rule.
13. State end rule.
14. Give the limitations of cyclotron
15. State Flemings left hand rule.
16. How will you increase the current sensitivity of a galvanometer?
17. Increasing the current sensitivity does not necessarily increase the voltage sensitivity.
Why?
18. Define the magnetic moment of a current loop.

5 Mark Questions
1.Explain Biot-Savart law.
2.Derive an expression for magnetic induction due to a current carrying long solenoid.
3.Give the special features of magnetic Lorentz force.
4.Obtain an expression for force between two long parallel current carrying conductors.
5. How will you convert a galvanometer into an ammeter?
6. How will you convert a galvanometer into a voltmeter?

10 mark questions
1.Explain Joule heating effect with the calorimeter experiment
2.Derive an expression for magnetic induction at any point due to an infinitely long current
carrying straight conductor .
3.Derive an expression for magnetic induction at any point along the axis of a current
carrying circular coil.
4.Explain the principle, construction and working of a tangent galvanometer.
5.Discuss the motion of a charged particle in a uniform magnetic field.
6.Explain the principle, construction and working of Cyclotron
7.Derive an expression for the force acting on a current carrying conductor kept in a
magnetic field.
80

UNIT 5 ELECTROMAGNETIC WAVES AND WAVE OPTICS


3 Mark Questions
1) What is meant by electromagnetic waves?
2) What are the uses of infra red rays?
3) What are the uses of ultra violet rays?
4) What are Fraunhofer lines?
5) Define fluorescence and phosphorescence.
6) Distinguish between corpuscle and photon.
7) State Rayleigh scattering law.
8) What is meant by Tyndall scattering?
9) Why does the sky appear blue in color?
10) What are the applications of Raman spectrum?
11) State Huygens principle.
12) What are the conditions for sustained interference?
13) What is meant by Newtons rings?
14) Why does the centre of the Newtons ring appear in dark?
15) Define Diffraction.
16) Define grating element.
17) Distinguish plane of vibration and plane of polarisation.
18) Define optic axis.
19) What are the factors on which the optic rotation depend?
20) State specific rotation.
5 Mark questions
1) Explain Corpuscular theory.
2) Explain reflection of plane wave front at a plane surface.
3) Derive the expression for the radius of the nth order dark ring in Newtons rings
experiment.
4) Explain pile of plates with diagram.
5) State and prove Brewsters law.
6) Explain Nicol prism with diagram.
7) What are polaroids? Give the uses of polaroids.

1)
2)
3)
4)
5)

10 Mark Questions
Explain emission spectra and absorption spectra.
Explain Raman effect.
Explain total internal reflection by wave theory
Derive the expression for bandwidth in Youngs double slit experiment.
Discuss the theory of interference in thin transparent film due to reflected light and
obtain condition for the intensity to be maximum and minimum.

81

UNIT 6 ATOMIC PHYSICS


3 Mark Questions
1) What are cathode rays?
2) State principle of Millikans oil drop experiment?
3) Define ionization energy.
4) Define ionization potential.
5) What are soft X-rays and hard X-rays.
6) Define excitation potential energy.
7) State Moseleys law
8) What are the applications of Moseleys law?
9) Distinguish spotaneous and simulated emission.
10) What is meant by normal population?
11) What is meant by inverted population?
12) What are the characteristics of laser?
13) Define holography.
14) What are the conditions to achieve laser action?
15) What are the important facts from law experiment?
5 Mark Questions
1) Write the properties of Cathode rays.
2) Write the properties of Canal rays.
3) Derive an expression for the distance of closest approach of Particle.
4) What are the drawbacks of Somerfields model?
5) Explain spectral series of hydrogen atom.
6) Write the properties of X- rays?
7) State and derive Braggs law.
8) Explain the Laue experiment.
9) Explain the origin of Characteristic X- ray spectrum
10) Explain the scientific and industrial applications of Laser
10 Mark Questions
1) Describe the method of determining of the specific charge(e/m) of an electron by
J.J.Thomsons method.
2) Describe the method of determining by the charge of an electron Millikans oil
drop experiment.
3) State Bohrs postulates and derive an expression for the radius of the nth orbit.
4) State Braggs law and explain Braggs X-ray spectrometer to determine the wave
length of X-rays
5) Explain the working of Ruby laser with neat sketch.
6) With the help of energy level diagram, explain the working of He-Ne laser.

82

UNIT 9 SEMICONDUCTOR DEVICES AND THEIR APPLICATIONS


3 Mark Questions
1) What is meant by forbidden energy gap?
2) What are intrinsic semiconductors?
3) What are extrinsic semiconductors?
4) What is meant by doping?
5) What are the methods of doping a semiconductor?
6) What is meant by rectification?
7) What are LEDs? what are there uses.
8) What is meant by Zenor breakdown voltage?
9) Define input characteristic of on transistor? Give its unit.
10) Define bandwidth of on amplifier.
11) What is meant by feedback? What are the types of feedback?
12) What are the advantages of negative feedback?
13) Write the Barkhausen conditions for oscillation.
14) What are the advantages of Integrated Circuit?
15) Draw the block diagram of LC oscillator.
16) Draw the circuit diagram of OR gate using diodes.
17) Draw the circuit diagram of AND gate using diodes.
18) Draw the circuit diagram of NOT gate using transistor.
19) State De- Morgans theorems.
20) What are Universal gate? why are they called so?
21) What are the important characteristics of operational amplifier?
22) What are the uses of cathode ray oscilloscope?
23) Prove (A+B)(A+C)=A+BC using Boolean identities.

5 Mark Questions
1) Explain the working of diode as a half wave rectifier.
2) Deduce the relation between and of a transistor.
3) Explain the working of a transistor as a switch .
4) Explain voltage divider bias with circuit diagram
5) State and prove De-Morgans theorem.
6) Explain OR and AND gates by using electrical circuits.
7) Explain frequency response curve of a transistor amplifier.
8) How multimeter is used as ohm meter?

10 Mark Questions
1) Explain the working of bridge rectifier.
2) Describe the working of a transistor amplifier.
3) What is meant by feedback? Derive and expression for voltage gain of an amplifier
with negative feedback?
83

4) Sketch the circuit of Colpitts oscillator. Explain its working.


5) Describe an operational amplifier. Explain its action as (i) inverting amplifier and
(ii) noninverting amplifier.
6) Describe an operational amplifier. Explain its action as (i) summing amplifier and
(ii) difference amplifier.
7) Explain the multimeter with the neat diagram.
UNIT 10COMMUNICATION SYSTEMS
3 Mark Questions
1) Write the different ways of radio wave propagation?
2) Define skip distance.
3) Define skip zone.
4) Define modulation.
5) Define modulation factor.
6) What are the limitations of amplitude modulation?
7) What are the advantages of frequency modulation?
8) Define scanning
9) What are the advantages of digital communiation?
10) What are the advantages of fibre optics communication?
5 Mark Questions
1) Draw and explain the block diagram of AM radio transmitter.
2) Draw and explain the block diagram of superheterodyne FM receiver.
3) Write the applications of radar.
4) What are the advantage and disadvantages of digital communication.
5) Write the merits of satellite communication.
6) Explain AM radio receiver with block diagram.
10 Mark Questions
1) Explain the analysis of amplitude modulated wave.
2) Draw and explain the block diagram of superheterodyne AM receiver.
3) Explain the function of video camera tube.
4) Explain Monochrome TV transmission with block diagram.
5) Explain monochrome TV receiver with block diagram.
6) Explain principle, transmission and reception of radar with block diagram.

PERSISTENCE AND PRACTICE LEAD TO SUCCESS

84

CHEMISTRY
BLUE PRINT
S.NO

LESSONS

10

marks

marks

marks

marks

TOTAL

Atomic Structure

10

Periodic classification

09

P Block Elements

12

d Block Elements

18

f - Block Elements

07

11

09

Coordination
Components
Nuclear Chemistry

Solid State

09

Thermodynamics

10

10

Chemical equilibrium

10

11

Chemical Kinetics

12

12

Surface Chemistry

11

13

Electro Chemistry I

1(1)

14

14

Electro Chemistry II

10

08

16

Isomerism in Organic
Chemistry
Hydroxy Derivatives

12

17

Ethers

07

18

Carbonyl Compounds

14

19

Carboxylic Acids

14

11

07

08

30

21

12

14

233

15

21

Organic Nitrogen
Compounds
Bio molecules

22

Chemistry in Action

20

Total

We classify the learning capacity of categories. In the first category, this package is used for
scoring pass mark. In the second stage, it is used for scoring 80 marks, the third stage is used
for scoring 120 marks and the fourth stage ,they can able to get 150/150.

Stage - I
TABLE 1
Lesson
No
5

Lesson

1 mark

3 Mark

5 Mark

10 Mark

Total

F block Elements

07

Nuclear Chemistry

09

Solid State

09

Thermodynamics

10

10

Chemical Equilibrium

10

22

Chemistry in Action

08
53

Total

In the first table, this package is used maximum scoring 53 marks.

Stage - II
TABLE 2
Lesson
Lesson
No
2
Periodic Classification

1 mark

3 Mark

5 Mark

10 Mark

Total

09

12

Surface Chemistry

11

17

Ethers

07

Total

In the stage I & II it is used for scoring 80 marks.

27

Stage III
TABLE 3
Lesson Lesson
No
1
Atomic Structure

1 mark

3 Mark

5 Mark

10 Mark

Total

10

d Block Elements

18

Coordination
Components
Electro Chemistry

11

10

14

49

Total

The stage I , II & III is used for scoring 129 marks.


Stage - IV
TABLE 4
Lesson Lesson
No
3
P Block Elements
16

Hydroxy Derivatives

1 mark

3 Mark

5 Mark

10 Mark

Total

12

12
24

Total

NOTE
To score 150/150
Practice the units mentioned in the four tables .
Practice Book back one mark questions (self evaluation) for 19 units.
Practice the questions that where asked in the PTA guide as well as previous
year public question papers.
Practice for the chapters Hydroxy derivatives and d-block elements problems.
Practice for the chapters Electro chemistry Chemical kinetics and
Isomerism in organic chemistry
1.Based on the blue print Without
one mark lessons
2. Based on the blue print Without
three mark lessons

14,15,22
5,6,14,17,21

Lesson 5 f Block Elements


5 marks questions ( Public Q.No : 54 )
1. What is Lanthanide contraction and causes?
(i) Lanthanide contraction :
The size of the M3+ ions decreases from La to Lu is called Lanthanide
contraction.
(ii) Causes :
a) Imperfect shielding of 4f electrons
b) increase in nuclear attraction
2. Discuss the consequences of Lanthanide contraction.
Consequences :
1) According to Fajans rule, in Ln(OH)3 the covalent character increases
between Ln3+ and OH- ions The order of size of Ln3+ ions are
La3+ > Ce3+ > Lu3+

2) There is regular decrease in their ionic radii.


3) Regular decrease in their tendency to act as reducing agent
4) Second and third rows of d - block elements are quite close in their properties.
5) These elements occur together in natural minerals and are difficult to
separate.
3. Write the uses of lanthanides and actinides.
Uses of lanthanides
1. pyrophoric alloy : (Ce, La, Nd, Fe, Al, C, Sc) used in cigarette lighters, flame
throwing tanks and tracer bullets.
2. Ceria and Thoria are used as gas lamp materials.
3. Cerium salts are used in dyeing cotton and as catalyst in lead storage
batteries.
4. Lanthanido thermic process. It is used to extract pure Nd, Zn, Fe, Co etc
5. Mish metal : Ce : 45 - 50% ; La : 25% ; Nd : 5% and other Lanthanide metals,
Fe, Ca mixture Used for the production of brands of steel like high resistant
stainless steels.30% mish metal and 1% Zn mixture is used in making parts of
get engines.

Uses of actinides :
(i)

U-235 is used as fuel in nuclear power plant and as a component in


nuclear weapons.

(ii)

Pu-235 used as a power source in long mission space probes

4. Write various oxidation states of Lanthanides and Actinides


Common oxidation state

Other oxidation state

Lanthanides

+3

+2,+4

Actinides

+4

+2,+3,+5,+6

5. What is the difference between Lanthanides and Actinides.


Lanthanides

Actinides

1. Binding energies of 4f electrons

Binding energies of 5f electrons are

higher.

lower.

2. 4f electrons have greater shielding

5f electrons have poor shielding

effect.

effect.

3. Most of the ions are colourless.

Most of the ions are coloured.


E.g.

U+(Red)

4. Their compounds are less basic.

Their compounds are more basic.

5. Except promethium, they are non

All of them are radioactive.

Radioactive .
6. They do not form oxocation .

They form oxocations.

7.They do not form complexes easily.

They have much greater tendency


to form complexes.

6. How are lanthanides extracted from monazite sand?


Monazite Sand
Heat 210OC

With H 2S O 4 for
several hours
Grey Mud
Cold Water

Filtrate Containing
(Ln , Th4+ , H3O , SO4 2- , HSO4-, H2PO4- )
3+

Un reacted Monazite Sand


( SiO 2, TiO 2, ZrSiO 4)
(recycle sand)

Neutralised to

(or) added HF

proper acidity

Precipitate of Th3(PO4)4
(or) Precipitate Th

Filtrate containing
lanthanide and phosphate ions
NaOH (or)
Oxalic acid
Lanthanide hydroxide (or) oxalate

Individual Lanthanides are separated by suitable physical methods.


Anhydrous fluorides and
Chlorides of lanthanides

individual metals

Tri fluorides of lanthanides

Lesson 7

- NUCLEAR CHEMISTRY

3 Marks question and answers: ( Public Q.no : 37 )


1. What is half life period?
The time required to disintegrate the half of any radioactive substance is called
half life period.
t 1/2 = 0.693/

2. What is Q value of a nuclear reaction?


The amount of energy absorbed or released during the nuclear reaction is called
Q value of nuclear reaction
Q value = (mp- mr) 931 Mev
mp= sum of masses of products
mr = sum of masses of reactants
When Q= (+) energy absorbed i.e mp>mr
Q= (-) energy released i.e mr>mp
3. Explain the Spallation reactions with example.
Spallation reaction: The reaction in which high speed projectiles may chip heavy
nucleus into several fragments
29Cu

63

1
1
37
+2He4+400MeV 17Cl +141H +160n

4. What is Binding energy of nucleus?


1. Whenever a nucleus is formed , certain mass is converted into energy.
2. The atomic mass is lower than the sum of masses of protons, neutrons and
electrons present. This difference in mass is termed as mass defect.
3. Binding Energy E = mc2
5. Write the two uses of radio carbon dating.
i. It is a great tool for correlating facts of historical importance.
ii. It is very useful in understanding the evolution of life and rise and fall of
civilizations.
Note: Public question paper problem and example problem also practice.

5 Marks - ( Public Q.No : 65 (b) )


1. Explain about the nuclear reaction taking place in sun.

2. Differentiate between chemical reaction and Nuclear reaction.


Chemical reactions
1. These reaction involve some loss,

gain or overlap of outer orbital


electrons of the reactant atoms.
2. A chemical reaction is balanced in

terms of mass only

Nuclear reactions

Nuclear reactions involve emission of alpha,


1. beta and gamma particles from the nucleus.
Nuclear reaction is balanced in terms of
2. both mass and energy.

3. The energy changes in any chemical

reaction is very much less when


compared with nuclear reaction.
4. In chemical reactions, the energy is

expressed in terms of kilojoules per


mole.
5. No new element is produced since

nucleus is unaffected.

3.

The energy changes are far exceed than


the energy changes in chemical reactions.

In nuclear reactions, the energy involved is


expressed in MeV (Million electron volts)
4. per individual nucleus.

5.

New element / isotope may be produced


during the nuclear reaction.

3. Explain Radio Carbon dating.


By knowing the amount of C14 present in plant or animal fossil the age of wood
or fossil can be determined is called radio carbon dating. C14 radio isotope of carbon
is formed in the upper atmosphere by reaction with neutrons. (cosmic rays)
14
1
14
1
7N +on 6C + 1H

The C14 atoms produced are oxidised to


of photo synthesis .

14

CO2. It is incorporated in plants as a result

Animals too consume C14 by eating plants, on death, organisms cease to take in
fresh carbonations.
0
14
14
6C 7N + -1e

Carbon - 14 begins to decay.

Half life period of C14 = 5700 years. Therefore by knowing either the amount of C14 or
the number of - particles emitted per minute per gram of carbon at the initial and
final stages, the age of carbon material can be determined by
2.303xt1/2
t=
0.693

Amount of C14 in fresh wood


log
Amount of C14 in dead wood

Uses :
1. It is a great tool for correlating facts of historical importance
2. It is very useful in understanding the evolution of life and rise and fall of
civilizations
4. Write the medicinal uses of radioactive isotopes.(March -06)
S.No
Names
Uses
1
Tritium 1H3
Measure water content of the body
2

Carbon - 11 6C11

Brain scan

Carbon - 14 6C14

Radio immunology

Iodine -131 53I131

Mercury - 197 90Hg197

diagnosis of damaged heart muscles and hyper


thyroidism
Kidney scan

Phosphorous -32 15P32

Detection of eye tumours

Iron - 59 26Fe59

Diagnosis of anemia

Cobalt - 60 27Co60

Treatment of cancer

Sodium -24 11Na24

10

Gold - 198 79Au198

Location of blood clots, and circulatory


disorders.
Curing of cancers

5. Explain the principle behind the hydrogen bomb.


The hydrogen bomb is bases on fusion reaction of hydrogen to form helium
producing large amount of energy.
Fusion takes place at the centre. Hydrogen bomb consists of an arrangement
for nuclear fission in the centre surrounded by a mixture of 1H2 and 3Li6 isotope which
provides the high temperature necessary to start the fusion.
Fission heat+ neutrons
6
1
3
4
3Li +0n 1H +2He +4.78MeV
2
3
4
1
1H +1H 2He +0n +17.6MeV

6. What is nuclear fusion reaction? Write the differences between nuclear


fission and nuclear fission
nuclear fusion
1. Two or more lighter nuclei combine to
form the heavy nucleus
2. It requires a high temperature.
3. It is not a chain reaction.

nuclear fission
A heavy nucleus splits in lighter nuclei
It does not require high temperature.
It is a chain reaction.

4. Hydrogen bomb based on the


principle of nuclear fusion.
5. Energy is released 17.6 MeV.

Atom bomb is based on the principle of


nuclear fission.
Energy is released 200 MeV.

7. What is nuclear fusion reaction?


When lighter nuclei moving at a high speed are fused together to form a
heavy nucleus, the process is called nuclear fusion.
In fusion reaction, the mass of heaver nucleus formed less than the total mass
of two lighter nuclei. Thus, just like a fission reaction, the source of energy in a fusion
reaction is also the disappearance of mass, which gets converted into energy.
Nuclear fusion reaction takes place at very high temperature of about 108K.
Therefore, this reaction is called thermonuclear reaction.
2
1H

+
Deuterium
8. What is nuclear fission reaction?

3
1H

Tritium

2He

+0n
Helium

+ Energy

Nuclear fission is the process in which a heavy nucleus breaks up into two
lighter nuclei of almost equal size with the release of an enormous amount of
Energy.

10

The process is us usually accompanied by emission of neutrons. Example


235
+ 0n1
92U

141
+ 36Kr92 +
56Ba

30n1 + 200 MeV

Further, the neutrons released (say three) from the fission of first uranium
atomos can hit three other uranium atoms. In this way a chain reaction is set up
resulting into the liberation of an enormous amount of energy. In the case of nuclear
235
fission, 92U formed breaks up in several ways.
235
+ 0n1
92U

140
+ 36Kr93 + 30n1
56Ba
144
+ 38Sr90 + 20n1
54Xe
144
+ 37Rb90 + 20n1
55Cs

236
92U

9. Explain the uses of radioactive isotope with example.


a) Study of reaction mechanism
i) Mechanism of photosynthesis in plants
*
A small quantity of Radioactive CO 2 containing radioactive oxygen O18 is
mixed with ordinary carbondioxide and the process is carried out. It has been found
that oxygen gas evolved along with sugan formation is non-radioactive. Therefore O2
produced comes from water and anot from carbondioxide. So the correct mechanism
is as follows.
*
*

6CO2 + 6H2O

C6H12O6 + 6O2

ii) Study of hydrolysis of ester


By labelling oxygen, the mechanism of ester hydrolysis can be studied by
using water labelled with O18. The hydrolysis of an ester by water enriched with
radioactive oxygen is indicated as :

Lesson 8 Solid states


3 Marks (Public Q.no : 38 )
1. State Braggs equation
A relationship between the wave length x-rays the inter planar distance in
the crystal (d) and the angle of reflection is Braggs equation.
n= 2d sin
where

n is order of reflection
is the wave length of X-rays
d is the interplanar distance in the crystal
is the angle of reflection

11

2. What are super conductors? (March, June 2006)


The ability of certain ultra cold substances to conduct electricity without
resistance is called resistivity. Substances having this property are called super
conductors.
3. Write uses of super conductor.
1. super conducting generators It consumes low energy and save more energy.
2. Super conducting magnets
- Used in High efficiency Ore separating machines.
3. Super conducting solenoids
- Nuclear Magnetic Resonance Imaging equipment
which is a whole body scan equipment.
4. What is vitreous state?
A state lying between the solid and liquid state is known as vitreous state.
5. Sketch sc , bcc and fcc Structure.
Simple Cube (sc)
Body Centred Cube (bcc)

Free Centred Cube (fcc)

6. Define - Unit cell.


Unit cell is the smallest fundamental repeating portion of a crystal lattice from
which the crystal is built by repetition in three dimension.
7. What are point Defects?
1. If the deviation occurs due to missing atoms .
2. Displaced atoms (or ) Extra atoms
3. Imperfection of atoms
Ex: Schottky Defect and frenkel defect
9. Write note about Metal excess defects.
1. A crystal of NaCl is heated in sodium vapour, it acquires a Yellow colour.
2. This yellow colour is due to the formation of non stoichiometric compound of
NaCl in which there is a slight excess of sodium.
3. This defect is called metal excess defect.

12

10. What is metal deficiency defect?


One of the positive ion is missing from its lattice site and the extra negative
charge is balanced by some nearby metal ion acquiring additional to charges instead
of one. This defect is known as metal deficiency defect.
Ex. FeO , FeS
11. Define : Super conducting transition temperature (Tc) (June 2007)
The super conduction Transition temperature (Tc) of a material is defined as a
critical temperature at which the resistivity of a material is suddenly changed to zero.
12. What are molecular crystals? Give an example.
1. The lattice points in molecular crystals consists of molecules which do not
carry any charge.
2. The forces binding the molecules together are of two types.
i) Dipole - dipole interaction Eg. Ice
ii) Vander Waals forces. Eg. All kind of molecular solids
13. Structure of CsCl-Explain.
Let us discuss the structure of CsCl for AB type. It is body centered cubic
system. The chloride ions are at the corners of a cube where as Cs + ion is at the
centre of the cube or vice versa. Each Cs+ ion is connected with eight Cl- ion and Clis connected with eight Cs+ ions.
o Cs+
Cl-

Number of chloride ions per unit =

Number of cesium ion per unit =


Thus number of CsCl units per unit cell is one.
5 Marks question and answer ( Public Q.No : 66 a )
1. Write the characteristics of Ionic Crystals.
1. They are hard and brittle.
2. They have high melting and boiling points.
3. The heat of vapourisation is high.
4. They are insulators in the solid state.
5. These crystals are soluble in water and insoluble in Non polar solvents.
6. Ionic solids are good conductors when dissolved in water.
7. Ionic crystals are hard and brittle.

13

2. Explain schottky and Frenkel defects.


1. Schottky defects. This defect is caused some of the lattice points are unoccupied. The
points which are unoccupied are called vacancies.
2. The number of missing positive and negative ions is the same in this case and thus the
crystal remains neutral.
3. Schottky defects appears generally in ionic crystals in which positive and negative ions do
not differ much in size.

Na+ Missing

Cl- Missing

Frenkel defects
1. This defect arise when an ion occupies an interstitial position between the lattice
points.
2. This defect occurs generally in ionic crystals in which the size of anion is much larger
than the cation.
3. Frenkel Defect on a crystal.

4. The crystal remains neutral since the number of positive ions is the same as the
number of negative ions. Ex: AgBr.
3. Explain Braggs spectrometer method.
1. This method is one of the important method for studying crystals using x rays. The
apparatus consists of a x-ray tube from which a narrow beam of x-rays allowed to fall on
the crystal mounted on a rotating table.
2. The rotating table is provided with scale and vernier, from which the angle of
incidence can be measured.
3. An arm which is rotating about the same axis as the crystal table, carries an
ionisation chamber.
4. The rays reflected from the crystal enter into the ionisation chamber and ionise the
gas present inside.
14

5. Due to ionisation current is produced which is measured by electrometer. The current


of ionisation is a direct measure of intensity of reflected beam from the crystal.
6. For different angles of incidence, the corresponding ionisation current is measured
from the electrometer. These values are plotted in the form of graph.
For sodium chloride, the maximum reflection or peaks for 100 plane occurred.

Sin
Ratio

5.9

11.85

18.15.

0.103
1

0.205
2

0.312
3

4. Significance of Braggs equation


1. If we use x-rays of known wavelength then the inter atomic distance (d) is an
unknown crystal can be calculated. On the other hand, if we use a crystal whose inter
atomic distance d is known then the wavelength of x-rays can be calculated.
2. The Braggs equation gives the essential condition for diffraction to occur.
3. When the experiment is done there will be a maximum reflection at a particular angle
That angle is noted. It corresponds to first order reflection (n=2). Similarly, Third,
fourth and higher order of reflection occur at certain specific angles. The values of
angles obtained are in accordance with the Braggs equation. Hence Braggs equation
is experimentally verified.
5. Explain the various types of crystals based on lattice points.
Four types :
1. Molecular Crystals

2. Covalent Crystals

3. Metallic Crystals

4. Ionic crystals

Molecular Crystals
1. The lattice points in molecular crystals consists of molecules which do not carry any charge.

2. The forces binding the molecules together are of two types.


i) Dipole - dipole interaction Eg. Ice
ii) Vander Waals forces. Eg. All kind of molecular solids

15

Covalent Crystals
The lattice in covalent crystals consists of atoms linked together by a continuous system of
covalent bonds. Eg. diamond.
Metallic crystal
Metallic crystal consists of an assemblage of positive ions immersed in a sea of mobile electrons.
Thus each electron belongs to a number of positive ions and each positive ion belong to a number of
electrons. The force that binds a metal ion to a number of electrons within its sphere of influence is
known as metallic bond.
The Vanderwaals forces are more general and occur in all kinds of molecular solids.
Ionic crystal
In ionic crystals the units occupying lattice points are positive and negative ions. Each of a
given sign is held by columbic forces of attraction to all ions of opposite sign. The forces are very
strong.

6. How are glasses formed? Explain the nature of glass.


When certain liquids are cooled rapidly there is no formation of crystals at a definite
temperature, such as occurring on slow cooling. The viscosity of the liquid increases steadily
and finally a glassy substance is formed.
Characteristics of glass :
i) The chief characteristics of glass are hardness, rigidity and ability to withstand shearing
stresses which are all properties of the solid state.
ii) Glasses are optically isotropic and on heating without any sharp transition passes into a
mobile liquid.
iii) At a high temperature glasses undergo phase transition when crystals separate first as they
do form super cooled liquid. Therefore glasses are regarded as amorphous solids or super
cooled liquids as well.
iv) Glassy or vitreous state is a condition in which certain substance can exit, lying between
the solid and liquid states.
Lesson 9
THERMODYNAMICS
3 Mark Question and Answer ( Public Q.No : 39 )
1. What is entropy? Give its unit.
Entropy is the ratio of the heat evolved (q) to the temperature (T) of the process. S = q/T .
Unit of entropy is cal / degree / mole or eu/mole
2. What is Gibbs free energy (G)
G is defined as (H-TS) when H and S are the enthalpy and entropy of the system respectively
T- temperature in Kelvin. Since H and S are state functions. G is a state function
16

3. Give Kelvin Planck statement second law of thermodynamics. (March 2007)


It is impossible to construct an engine which operated in a complete cycle will absorb heat
from a single body and convert it completely to work without leaving some change in the
working system
4. State Troutons rule.
The heat of vaporisation (Hvap) is calories per mole divided by the boiling point of
the liquid in Kelvin is a constant equal to 21 cal.deg-1 molSvap = Hvap /Tb = 21 cal deg mol
-1

-1

5. What kind of substances deviate from Troutons rule?


i) Low boiling liquids such as hydrogen and Helium which boil only a little above OK
ii) Polar substances like water, alcohol which from hydrogen bonded liquids and
exhibit very high boiling points as well as high Hvap.
iii) Liquids such as acetic acid whose molecules are partially associated in the
vapour phase and possess very low entropy vaporisation which is much less than
21 cals /mol/deg.
6. When does entropy increase in a process?
a) In a chemical reaction, when number of molecules of products are more than the
number of molecules of reactant entropy increases
b) In physical process when a solid changes to liquid, when a liquid changes to vapour and when
a solid changes to vapour, entropy increases.

7. What are spontaneous reaction?


1. Spontaneous process is the process that is natural and does not need to be induced.
It takes place on its own accord.
2. In order to find out whether a process is spontaneous or not, the entropy changes of
the system and the surroundings for the stipulated process is considered.
S= (+) ve, the entropy of the universe increases.
8. Mention the essential conditions for spontaneity in a chemical reaction.
For a spontaneous chemical process,
G<0, H<0 and S>0
Ie, H = negative, G= negative S = positive
5 Marks Question and answer ( Public Q.No : 56 )
1. State the various statement of Second Law Of Thermodynamics.
i) It is impossible to construct an engine which operated in a complete cycle will absorb heat
from a single body and convert it completely to work without leaving some changes in the
working system. This is called as the Kelvin Planck statement.
ii) It is impossible to transfer heat from a cold body to a hot body by a machine without
doing some work. This is called as the clausius statement of II law of thermodynamics.
17

iii) A process accompanied by increase in entropy tends to be spontaneous.


iv). Entropy is a measure of randomness or disorder of the molecules of a system.
v) Efficiency of a machine can never be cent percent.
vi) The heat Efficiency of any machine is given by the value of ratio of output to input
energies. Output can be in the form of any measurable energy or temperature change while
input can be in the form of heat energy or fuel amount which can be converted to heat energy.
% efficiency = input/output x 100

2. Write Characteristics of Entropy S.


1. Entropy S is a thermodynamic state function.
2. The entropy depends on the quality of the substance.
3. Entropy change S is defined as at constant temperature of the ratio of the heat changes of
a process to the temperature of the system.
The process should be reversible Srev= qrev /T(k)
4. Entropy is a measure of randomness of the molecule of a system. Entropy increases in all
spontaneous process.
5.The total entropy changes of the universe( Srev) is equal to the entropy of the system and
in its surroundings.
Suni= Ssys + Ssurr
6. For an isothermal process(T= constant), the entropy change of the universe during a
reversible process is zero.
7. There are three cases of S predicting the nature of process.

Process
S

Spontaneous
(+)ve

Equilibrium
0

Non-Spontaneous
(-)ve

8. The energy of the universe remains constant although the entropy of the universe tends to a
maximum.
9. Units of entropy: Unit of entropy is cal / degree / mole or eu/mole
10. S is related to H, for a reversible and isothermal process Srev=qrev/T .Since
H is the heat absorbed or evolved in the process at constant temperature and
pressure.S is also calculated from H as S=H/T

18

3. Write characteristics of Free energy G.


1. Free energy is defined as G= H-TS. G is a state function.
2. G is an extensive property. But G is the intensive property when mass remains
constant between initial and final states.
3. G has a single value for the thermodynamic state of the system.
4. G and G values corresponds to the system only.
5. There are three cases of G predicting the nature of process
Process
Spontaneous
Equilibrium
(-)
ve
0
G
6. G = H TS. But according to I law of thermodynamics,

Non-Spontaneous
(+)ve

H = E + PV and
E = q w.
TS = q .
G = q w + PV q
G = w + PV= Net Work
Lesson 10
CHEMICAL EQUILIBRIUM II

3 Marks Questions and Answers ( Public Q.No: 40 )


1. What is Equilibrium constant?
The ratio of product of molar concentration of products to the product of molar
concentration of reactants at equilibrium.
a A+b B

c C+d D

2. Why do equilibrium reactions referred to as dynamic equilibrium?


At equilibrium rate of forward reaction is equal to rate of backward reaction.
Reactants and products are present in the reaction mixture in definite amounts.
Therefore chemical equilibrium is called as dynamic equilibrium.
3. State the Chatliers principle.
According to Le Chatliers principle, if a system at equilibrium is subjected to a
disturbance or stress, then the equilibrium shifts in the direction that tends to nullify
the effect of disturbance of stress.
4. Define Reaction quotient (Q).
Q is defined as the ratio of product of initial concentrations of products to the product
of initial concentrations of the reactants under non equilibrium conditions.

19

5. Dissociation of PCl5 decreases in presence of Cl2. Why?


[ PCl 3] [ Cl
Kc =

[ PCl 5 ]

According to Le Chatliers principle increase in concentration of Cl2 favors backward


reaction ie dissociation of PCl5 decreases
6. What happens when ng = 0 ng = (-)ve ng = +(ve) in a gaseous reaction
Kp = Kc [RT]ng

If ng = 0
ng = (-)ve
ng = (+)ve

Kp = Kc
Kp < Kc
Kp > Kc

7. Calculate ng, for the following reactions.


1. H2 (g) + I2 (g)
2HI ( g)
n g = (n p - n r)g = 2 - 2 = 0

2. H2O
n

(g)

+ 2 Cl2 (g)

= (n

4HCl

(g)

+ O2 (g)

- n r)g = 5 - 4 = 1

8. Write the equilibrium constant for the following reactions.


i) H2O2(g) H2O(g) + O2(g)
ii) CO(g) + H2O(g) CO2(g) + H2(g)
iii) N2O4(g) 2 NO2(g)

20

5 Marks Question and Answers : (Public Q.No : 57 )


1. Describe the synthesis of NH3 by Habers process.

H2 and N2 Ratio :- 3:1


Pressure
Temperature
300-500 atm
500 C 550 C

Catalyst
Fe

% of NH3 formed
37%

The equilibrium conditions, steam is passed to remove away the ammonia as and when it is
formed so that the equilibrium remains shifted towards the product side.
2. Write synthesis of SO3 by Contact process.

SO2 and O2 Ratio :- 2:1


Pressure
Temperature
700-1200 atm
400 C 450 C

Catalyst
V 2 O5

% of SO3 formed
97%

SO3 from contact process along with steam is used in oleum and H2SO4 manufacturing
processes.

3. Derive the relation Kp = Kc (RT)ng for a general chemical equilibrium reaction.

21

ng = ( total number of stoichiometric moles of gaseous products) - ( total number of


stoichiometric moles of gaseous reactants ).
4. Derive the values of Kc and Kp for the synthesis of HI.

Initial No. of moles


No. of moles
dissociated
No. of moles at
equilibrium
Equilibrium
concentration

H2
a
x

I2
b
x

HI
0
-

(a-x)

(b-x)

2x

5. Derive the values of Kc and Kp for the Decomposition of PCl5


Initial No. of moles
No. of moles
dissociated
No. of moles at
equilibrium
Equilibrium
concentration

PCl5
a
x

PCl3
0
-

Cl2
0
-

(a-x)

22

Lesson 22
CHEMISTRY IN ACTION
3 Marks Question and Answers ( Public Q.No : 51 )
1. What are Anaesthetics? Give two examples.
The drugs which produce loss of sensation are called anaesthetics. They are two types.
(i)
General anaesthetics are the agent, which bring about loss of all modalities of
sensation, particularly pain along with reversible loss of conciousness.
(ii)
Local anaesthetics prevent the pain sensation in localised areas without affecting
the degree of consciousness
Example : Nitrous Oxide, Diethyl ether, chloroform
2. In what way Antipyretics are important?
1. Antipyretics are the compounds which are used for the purpose of reducing fever
2. lowering the body temperature to the normal
Ex. aspirin, antipyrine, phenacetin, and paracetamol.
3. What are antiseptic?
Antiseptic is a substance that rendors micro organisms innocuous by killing them or
preventing their growth.
Ex. Iodoform, 0.2 % solution of phenol .
4. Write a note on Antiprotozoals (or) Antimalarials.
1. Antiprotozoals are the chemical compounds used to cure malaria.
2. Extracts of certain plants, specially te roots and stems are extensively used as anti malarial.

Ex: Cinchona park which gives rise to quinine acts as anti malarial.
23

5. What are analgesics? Give examples.


Analgesics are the compounds which relieve all sorts of pains without the loss of
consciouness. Eg. Aspirin, Novalgin
6. What are antibiotics? Give example.
Antibotics are the chemicals present in the microorganism which inhabit the growth or
metabolism of some other microorganism. (e.g) Penicillins.
7. In what way antacids are important?
1. Antacids are drugs that provide relief from burning sensation caused by eating oily and
spicy food.
2. Antacids are the drugs used to rectify the imbalance in the acidity in the stomach.
Eg. Magnesium and Aluminium hydroxide

8. Write note on Antipasmodics.


1. Antipasmodics are used to relieve cramps, spasms of the stomach intestines and
bladder,
2. Some are used with antacid, in the treatment of peptic ulcer.
3. If prevent Nausea Vomiting and motion sickness.
Example : Anisotropine, Atropine

9. Why Iodo form and Phenolic Solutions are called antiseptics?


1. 0.2% solution of phenol and Iodo form are used as antiseptics.
2. Both are used to destroy the micro organism and so they are called antiseptics.
10. What is Food preservative? Give two examples.
A chemical substance which prevents the spoilage of food material by destroying the
food spoiling micro organism in it is called a food preservative.
e.g Sodium benzoate, Potassium meta bi sulphite
11. Write note on Anti oxidants.
1. The substances that act against oxidants are called antioxidants.
2. It protect us against cardio vascular disease, Cancer and cataract.
3. It act as radical inhibitors.
e.g. Vitamin C, Vitamin E, - carotene

24

12. How is Buna-S prepared?


Buna- s is a synthetic rubber obtained by the polymerization of butadiene and
styrene in the presence of sodium metal.

13. How is Buna N prepared?


Buna-N is obtained as a result of copolymerisation of two parts of butadiene with
one part of acrylonitrile in the presence of sodium metal.

14. How to prepare terylene or Decron or PET?


Both glycol and dicarboxylic acid being molecules with two functional groups, react
forming condensation polymers. Thus with Terphthalic acid, ethylene glycol forms the
polymer Terylene.

15. How is Nylon-66 prepared?


Nylon - 66 is obtained by condensing adipic acid with hexa methylene diamine with
the elimination of water molecule.

16. Write about Artificial Sweeteners.


Certain organic compounds which have been synthesized in laboratories are known to
be many times sweeter than cane sugar. Such compounds are called artificial sweetening
agents or artificial sweetners.
Eg. (i) Saccharin, (ii) Dulcin,

25

5 Marks Questions and Answers ( Public Q.No : 63 )


1. Explain briefly on colour and structure of dyes.
1. Chromophroes :

An organic compound appears coloured due to the presence of certain unsaturated


groups (the groups with multiple bonds) in it. Such groups with multiple bonds are called
chromophores.

2. Chromogen
The compounds containing the chromophore group is called chromogen. The colour
intensity increases with the number of chromophores or the degree of conjugation.

For example, ethene (CH2 = CH2) is colourless, but the compound


CH3 (CH = CH)6 CH3 is yellow in colour.
3. Auxochromes:
The presence of certain groups which are not chromophores themselves, but deepen
the colour of the chromogen. Such supporting groups are called auxochromes.
E.g OH, NH2, NHR, NR2.
4. The presence of an auxochrome in the chromogen molecule is essential to make it a dye.
However, if an auxochrome is present in the meta position to the chromophore, it does not
affect the colour.

2. Explain briefly on characteristics of rocket propellants.


1. The propulsion system in most space vehicles consists of rocket engines powered by
chemical propellants. These also called rocket propellants.
2. Propellants are combustible compounds which on ignition undergo rapid combustion
to release large quantities of hot gases.
3. A propellant is a combination of an oxidiser and a fuel.

26

4. Working of a propellant. When a propellant is ignited, it burns to produce a large


quantity of hot gases. These gases then come out through the nozzle of the rocket
motor. The passage of gases through the nozzle of the rocket motor, provides the
necessary thrust for the rocket to move forward according to the Newtons Third law of
Motion
5. E.g. Hydrazine, Liquid hydrogen, Polyurethane, etc.
3.What are the characteristics of dyes.

It
It
It
It

should
should
should
should

have a suitable colour


be able to fix itself or be capable of being fixed to the fabric.
be fast to light
be resistant to the action of water, dilute acids and alkalies.

Lesson wise one words questions


1.Atomic structure - II ( 2 x 1 = 2 )
1. If the value of E1 = -34.84 to which value n corresponds
Ans:-3
2. Dual character of an electron was explained by
Ans:-de-Broglie
3. De- Broglie equation is
Ans:- =h/mv
4. The value of Bohr radius for hydrogen atom is
Ans:- 0.529 x 10-8 cm
5. Which of the following particle having same kinetic energy would have
maximum de braglie wave length
Ans:- particle
6. If the energy electron in the second Bohr orbit of H - atom is -E. What is the
energy of the electron in the Bohrs first orbit?
Ans:- -4E
7. The energy of electron in an atom if given /En
Ans:-En=-22me4/n2h2
8. The bond order of oxygen molecule is
Ans:-2
9. The hybridisation in SF6 molecule is
Ans: sp3d2
10. The intramolecular hydrogen bonding is present in
Ans:- o- nitro phenol

2. Periodic classification -II ( 1 x 1 = 1 )


1) The value of C-C distance found experimentally in a saturated hydrocarbon is
Ans:-1.54
2) on moving down the group the radius of an ion
Ans:- increases
3) Effective nuclear charge (z*)can be calculated by using the formula
Ans:- z*=z-s
4) Pick the correct statement
Ans:- carbon having more nuclear charge than boron
27

5. Comparing the ionisation energy of fluorine with carbon, fluorine has


Ans:- higher ionisation energy
6. Among the following which has the maximum ionisation energy
Ans:- Nobel gases
7. The electron affinity of an atom
Ans:- inversely proportional to its size
8. Among the following which has higher electron affinity value
Ans:- fluorine
9. The scale which is based on an empirical relation between the energy of a bond
and the electro negativities of bonded atoms is
Ans:- Pauling scale
10. Electron affinity is expressed in
Ans:- KJmol-1
11. The bond length of Cl2 molecule is
Ans:- 1.98A0
12. The order of ionisation energy
Ans:- s>p>d>f
13. Across the period electron affinity
Ans:-increases
14. Noble gases, have ______ electron affinity.
Ans:- zero
15. When XA>> XB, A - B bond is
Ans:-Ionic

3 P- Block elements ( 1 x 1 = 1 )
1. Which of the following does not belong to group -13
Ans:-Ge
2. Which of the following is most abundant in earths crust?
Ans:-Si
3. An element which was burnt in limited supply of air to give oxide A which
treatment with water gives an acid B acid B on heating gives acid a which gives
yellow precipitate with AgNo3 solution A is
Ans:-P2O3
4. The compound with garlic odur is
Ans:- P2O3
5. The shape of PCl5 is
Ans:-trigonal bipyramidal
6. The compound used as smoke screen
Ans:-PH3
7. Which shows only - 1 oxidation state?
Ans:- Fluorine
8. One can draw the map of building on a glass plate by
Ans:- HF
9. Among the halogen acid, the weakest acid is
Ans:- HF
10. Halogens belongs to the group number
Ans:- 17
11. The noble gas are un reactive because they
Ans:- have stable electronic configuration
12. The shape of XeF4 is
Ans:-square planner
28

13. Which is not known?


Ans:- ArF6
14. The lightest gas which is non - inflammable is
Ans:-He
1 5.Which of the following has first ionisation energy?
Ans:- He

4. d. Block elements ( 2 x 1 = 2 )
1. The general electronic configuration of d- black elements is
Ans:- (n-1) d 1-10 ns1-2
2. Formation of coloured ions is possible when compounds contain
Ans:-lone pairs of electrons
3. Paramagnetism is common in
Ans:-d-block elements
4. The colour of [Ti(H2O)6]3+ion to
Ans:- d-d transition
5. The electronic configuration of chromium is
Ans:- 3d5 4s1
6. Paramagnetism is a property of
Ans: unpaired electrons
7. d - block elements formed coloured ions because
Ans;- They absorb some energy for d-d transition
8. The correct electronic configuration of copper atom is
Ans;- 3d10 3s1
9. Copper is extracted from
Ans:- copper pyrites
10. Silver salt used in photography is
Ans:-AgBr
11. Sodium thiosulphate is used in photography because of its
Ans:- complexing behaviour
12. Excess of sodium hydroxide reacts with zinc to form
Ans:-Na2ZnO2
13.Which of the following compounds will not give positive chromyl chloride test?
Ans:-C6H5Cl
14. Which of the ions will give colourless aqueous solution ?
Ans:-Cu+
15. Which of the following compounds is not coloured?
Ans:-NaCd Cl4
16. In the extraction of cu, the reaction which does not takes place in the Bessemer
converter is
Ans:- 2CuFes2 O2Cu2s + 2Fes + SO2
17. Select the correct statement
Ans:-mercury is a liquid metal
18. Choose the wrong statement regarding K2Cr2O7
Ans:-It reduces ferric sulphate to ferrous sulphate
19. For a transition metal ion the effective magnetic moment in BM is given by the
formula
Ans: n(n 2)
29

20. Which compound is formed when excess of KCN is added to an aqueous


solution of copper sulphate
Ans:-Cu2(CN)2 +(CN)2
21. Which of the following has maximum no of unpaired electrons?
Ans:- Mn2 +
22. Among the following statement , the incorrect one is
Ans : Argentite and cuprite are oxides.
23. The chemical composition of slag formed during the smelting process in the
extraction of copper
Ans:-FeSiO3
24. The transition element with the lowest atomic number is
Ans:- Scandium
25. Which transition element shows highest oxidation state
Ans:-Os
26. The Correct statement in respect of d- block element is
a) They are all metals.
b) They show variable valency
c) They form coloured icons and complex salts
d) All the above statement are correct

4. F- Block elements ( 2 x 1 = 2 )
1. The electronic configuration of Lanthanides is
Ans:-[Xe] 4f1-14 5d16S2
2. The electronic configuration of actinides is
Ans:-[Rn]5f 0-14 6d 7S2
3. The lanthanide is responsible for the fact that
Ans:- Zr and Hf have about the same radius
4. The most common oxidation state of lanthanides
Ans:-+3
5. Lanthanides are extracted from
Ans:-monozite
6. The elements in which the extra electron enters (n-2)f orbitals are called
Ans:-f- block elements
7. The Lanthanides contraction is due to
Ans:-imperfect shielding of 4f electron
8. Ceria used in
Ans:-gas lamp materials
9. --------- is used in gas lamp material.
Ans:- CeO2
10. Alloys of Lanthanides are called as
Ans:- mish - metals
11. Metallo thermic process involving lanthanides are called as
Ans:-Lanthanido thermic process
12. --------- form oxocations.
Ans:- actinides
13. Maximum oxidation state exhibited by lanthanides is
Ans:- +4
14. Lanthanides are separated by
Ans:-fractional crystallisation

30

6. Co - ordination compounds ( 1 x 1 = 1 )
1. Which is a double salt?
Ans:-. K2SO4 Al2(SO4)3 .
2. An example of a complex compound having co-ordination number 4
Ans:- [Cu(NH3)4]Cl2
3. The geometry of (Cu NH3)4]2+ complex ion
Ans:- square planar
4. An example of a chelating ligand is
Ans:- en
5. The geometry of complex ion [Fe(CN)6]4- is
Ans:-octahedral
6. The oxidation number of nickel in the complex ion, [NiCl4]2- is
Ans:- +2
7. Which is not an anionic complex?
Ans:- [Cu(NH3)4] Cl2
8. The geometry of (Ni (CN)4]2- is
Ans:-square planar
9. An example of ambidentate ligand is
Ans:- NO2
10. [FeF6]4- is paramagnetic because
Ans:- F- is a weaker ligand
11. In [FeII (CN)6]4- the central metal ion is
Ans:- Fe+
12. The coordination number of Ni(II) in Ni(CN4)2- is
Ans:- 4
13. The name of [ptIV (NH3)2Cl2]2
Ans:-. Diammine dichloroplatinum (IV) ion
14. For a compound K4[Fe(CN)6] 4K+ + [Fe(CN6)]4- the complex ion is
Ans:- [Fe(CN)6]415. A metal ion form the first transition series forms an octahedral complex with
magnetic moment of 4.9 BM and another octahedral complex which is diamagnetic
The metal ion is
Ans:- Fe+
16. Paramagnetic moment is expressed in
Ans:- BM
17. The type of isomerism found in the complexes [Co(NO2)(NH3)5] SO4 and
[Co(SO4)(NH3)5] NO2
Ans:- ionisation isomerism
18. Valence bond theory doesnt explain the property of complex compounds
Ans:- magnetic

7. Nuclear chemistry ( 1 x 1 = 1 )
1. The phenomenon of radio activity was discovered by
Ans:- Henry Becquarrel
2. The most penetrating radiations are
ns:-rays
3. In the nuclear reaction 92U238 82Pb 206 , the no of & particles emitted are
Ans:- 8, 6
31

4. Which one of the following particles is used to bombard 13 Al 27 to give to give 15 P30
and a neutron
Ans:- particle
5. The reaction 5B84Be8 takes place due to
Ans:- positron decay
6. Radio activity is due to
Ans:- un stable nucleus
7. In the following radio active decay 92 x 232 89y220 how many and particles are
ejected
Ans:- 3 , 3
8. 92 U 235 nucles absorbs a neutron and disintegrates into 54 xe139, 38 sr 94 and x. What
will be the product?
Ans:- 3 neutrons
9. Loss of particle is equivalent to
a) increase of proton only b) decrease of one neutron only c) both a & b
10. Which of the following is used as neutron absorber in the nuclear reactor?
Ans:- cadmium.

8. Solid State ( 1 x 1 = 1)
1. The number of chloride ions that surrounds the central Na + ion in NaCl crystal is
______.
Ans:- 6
2. The Braggs equation is ________.
Ans:- nd sin
3. A regular three dimensional arrangement of identical points in space is called
________.
Ans:- space lattice
4. The smallest repeating unit in space lattice which when repeated over and again
results in the crystal of the given substance is called ________.
Ans:- unit cell
5. The crystal structure of Cscl is ________.
Ans:-Body - centred cubic
6. An example for frenkel defect is _________.
Ans:- Agcl
7. Semi conductors which exhibit conductivity due to the flow of excess negative
electron are called ________.
Ans:- n-type semi conductors
8. In the Braggs equation for diffraction of x-ray n represents _______.
Ans:-Order of reflection
9. The number of close neighbors in a body centred cubic lattice of identical spheres
is __________.
Ans:- 8
10. The crystals which are good conductors of electricity and heat are _________.
Ans:- Molecular crystals
11. In a simple cubic cell, each point on a corner is shared by __________.
Ans:- 8 unit cell
12. The ability of certain ultra cold substances to conduct electricity without
resistance is called _____.
Ans:- super conductor
13. The total number of atoms per unit cell is bcc is
Ans:- 2
32

14. Rutile is
Ans:- Tio2
15. Semi conductors are used as
a) rectifiers b) transistors c) solar cells d) all the above
16. An example of metal deficiency defect.
Ans:- FeS

9. Thermodynamics ( 2 x 1 = 2 )
1. The amount of heat exchanged with the surrounding at constant temperature.
Ans: H
2. All the naturally occurring processes proceed spontaneously in a direction which
leads to
Ans: decrease of free energy.
3. In an adiabatic process which of the following is true?
Ans: q = 0
4. When a liquid boils, there is
Ans: an increase in entropy
5. If G for a reaction is negative, the change is
Ans: Spontaneous
6. Which of the following does not result in an increase in the entropy?
Ans: crystallisation of Sucrose from solution
7. In which of the following process, the process is always non-feasible?
Ans: H>O, S<O
8. Change in Gibbs free energy is given by
Ans: G=H-TS
9. For the reaction 2Cl(g)Cl2(g)the Signs of H and S respectively are ________.
Ans: - , -

10. Chemical equilibrium ( 2 x 1 = 2 )


1. State of chemical equilibrium is:
Ans: dynamic
2. If the equilibrium constants of the following reactions are 2A B is K1
and B 2A is K2, then
Ans: K1 = 1/K2
3. In the reversible reaction 2HI H2 + I2, Kp is
Ans c) Equal to Kc
4. In the equilibrium N2 + 3H2 2NH3, the maximum yield of ammonia will
be obtained with the process having
Ans: high pressure and low temperature
5. For the homogeneous gas reaction at 600 K
4NH3(g) + 5O2(g)
4NO(g) + 6H2O(g) the equilibrium constant Kc has the unit
Ans: (mol dm-3)
6. Two moles of ammonia gas are introduced into a previously evacuated 1.0
dm3 vessel in which it partially dissociates at high temperature. At equilibrium
1.0 mole of ammonia remains. The equilibrium constant Kc for the dissociation
is
Ans: 27/16 (mole dm-3)2
33

7. An equilibrium reaction is endothermic if K1 and K2 are the equilibrium


constants at T1 and T2 temperatures respectively and if T2 is greater than T1
then
Ans: a) K1 is less than K2

11.Chemical kinetics ( 1 x 1 = 1 )
1. Hydrolysis of an ester by dilute HCl is an example for
Ans: pseudo first order reaction
2. The unit of zero order rate constant is
Ans: (b) mol litre1 sec1
3. The excess energy which a molecule must posses to become active is
known as
Ans: activation energy
4. Arrhenius equation is
Ans: ) k = AeEa/RT
5. The term A in Arrhenius equation is called as
Ans: Frequency factor
6. The sum of the powers of the concentration terms that occur in the rate
equation is called
Ans: order
7. Reactions in which the reacting molecules react in more than one way
yielding different set of products are called
Ans: parallel reactions
8. The half life period of a first order reaction is 10 minutes. Then its rate
constant is
Ans 6.932 102 min1
9. For a reaction : aA bB, the rate of reaction is doubled when the
concentration of A is increased by four times. The rate of reaction is
equal to
Ans: k [A]
10. 2N2O5 + 4NO2 + O2

d[N205] = k1[N2O5],

dt
d [NO2 ] = k2 [N2O5] and d[O2] = k3 [N2O5], the relation between k1, k2 and k3 is
dt
dt

Ans:2k1 = k2 = 4k3
11. For a reaction, Ea = 0 and k = 4.2 105 sec1 at 300K, the value of k at
310K will be
Ans:4.2 105 sec1

12. Surface Chemistry ( 3 x 1 = 3 )


1. The migration of colloidal particles under the influence of an electric
field is known as
Ans electrophoresis
2. Which one is the correct factor that explains the increase of rate of reaction
by a catalyst
Ans: lowering of activation energy
34

3. Fog is a colloidal solution of


Ans: gas in solid
4. The phenomenon of Tyndalls effect is not observed in
Ans true solution
5. The Tyndalls effect associated with colloidal particles is due to
Ans: scattering of light
6. In case of physical adsorption, there is desorption when
Ans: temperature increases
7. Colloidal medicines are more effective because
Ans: they are easily assimilated and adsorbed
8. Oil soluble dye is mixed with emulsion and emulsion remains colourless
then, the emulsion is Ans: O/W
9. For selective hydrogenation of alkynes into alkene the catalyst used is
Ans: Pd, partially inactivated by quinoline
10. For chemisorptions, which is wrong
Ans: it forms multi molecular layers on adsorbate
11. An emulsion is a colloidal solution of
Ans: two liquids
12. Colloids are purified by
Ans: dialysis

13.Electro chemistry I ( 1 x 1 = 1)
1. The process in which chemical change occurs on passing electricity is termed as ...............
Ans electrolysis
2. The laws of electrolysis were enunciated first by ...............
Ans Faraday
3. When one coulomb of electricity is passed through an electrolytic solution, the mass
deposited on the electrode is equal to ...............
Ans electrochemical equivalent
4. Faradays laws of electrolysis are related to ...............
Ans: equivalent weight of the electrolyte
5. The specific conductance of a 0.01 M solution of KCl is 0.0014 ohm-1 cm-1 at 25oC.
Its equivalent conductance is ...............
Ans: 140 ohm1 cm2 eq1
6. The equivalent conductivity of CH3COOH at 25oC is 80 ohm-1 cm2 eq-1 and at infinite
dilution 400 ohm-1 cm2 eq-1. The degree of dissociation of CH3COOH is ...............
Ans: 0.2
7. When sodium acetate is added to acetic acid, the degree of ionisation of acetic acid
...............
Ans: decreases
8. NH4OH is a weak base because ...............
Ans: it is only partially ionised
9. Which one of the following formulae represents Ostwalds dilution law for a binary
electrolyte whose degree of dissociation is and concentration C .
Ans: K = C
(1)
10. Ostwalds dilution law is applicable in the case of the solution of ...............
Ans: CH3COOH

35

11. Which one of the following relationship is correct ?


Ans: pH = log10 1
[H]
12. When 106 mole of a monobasic strong acid is dissolved in one litre of solvent, the pH of
the solution is ..............
Ans: 6
13. When pH of a solution is 2, the hydrogen ion concentration in moles litre-1 is .............
Ans: 1 102
14. The pH of a solution containing 0.1 N NaOH solution is ..........
Ans: 13
15. A solution which is resistant to changes of pH on addition of small amounts of an acid or
a base is known as .............
Ans: buffer solution
16. The hydrogen ion concentration of a buffer solution consisting of a weak acid and its salt
is given by .............
Ans [H+] = Ka [ Acid]
[Salt]
17. Indicators used in acid-base titrations are ...........
Ans: weak organic acids or weak organic bases
18. For the titration between oxalic acid and sodium hydroxide, the indicator
used in ...........
Ans: phenolphthalein

16. Hydroxy derivatives 1( 1 x 1 = 1 )


1. Which has the highest boiling point ?
Ans: C2H5OH
2. Which is soluble in H2O ?
Ans: Alcohols
3. Order of reactivity of alcohol towards sodium metal is
Ans (b) primary > secondary > tertiary
4. The boiling point of ethyl alcohol should be less than that of
Ans: formic acid
5. Ethyl alcohol cannot be used as a solvent for CH3MgI because
Ans: CH3MgI reacts with alcohol giving methane
6. When alcohols are converted to alkyl chlorides by thionyl chloride in presence of pyridine
the intermediate formed is
Ans: alkyl chlorosulphite
7. On oxidation of an alcohol gives an aldehyde having the same number of carbon atoms as
that of alcohol. The alcohol is
Ans:1o alcohol
8. A compound that gives a positive iodo form test is
Ans: 2-pentanone
9. The compound that reacts fastest with Lucas reagent is
Ans 2-methyl propan-2-ol
10. The ionization constant of phenol is higher than that of ethanol because
Ans: phenoxide ion is stabilized through delocalisation
11. Among the following compounds strongest acid is
Ans: CH3OH

36

12. The most unlikely representation of resonance structures of p-nitrophenoxide ion is


Ans

13. p-nitrophenol is having lower pKa value than phenol because


Ans anion of p-nitrophenol is more stabilised by resonance than that of phenol
14. The reaction of Lucas reagent is fast with
Ans: (CH3)3COH
15. When phenol is distilled with Zn dust it gives
Ans: benzene
16. A compound that undergoes bromination easily is
Ans phenol
17. Isomerism exhibited by ethylene glycol is
Ans functional isomerism
18. Ethylene diamine is converted to ethylene glycol using
Ans: nitrous acid
19. Ethylene glycol forms terylene with
Ans terephthalic acid
20. 1-propanol and 2-propanol can be best distinguished by
Ans oxidation by heating with copper followed by reaction with Fehling solution
21. Glycerol is used
Ans: (a) as a sweetening agent
(b) in the manufacture of good quality soap
(c) in the manufacture of nitro glycerin
(d) in all the above
22. The alcohol obtained by the hydrolysis of oils and fats is
Ans: glycerol
23. The number of secondary alcoholic group in glycerol is
Ans: 1
24. The active component of dynamite is
Ans: Nitro glycerine
25. The reaction of ethylene glycol with PI3 gives
Ans : CH2 = CH2

17 Ethers ( 2 x 1 = 2 )
1. The isomerism exhibited by C2H5OC2H5 and CH3 O CH CH3 is
|
CH3
Ans: metamerism
37

2. Which one of the following is simple ether ?


Ans : C2H5 O C2H5
3. Diethyl ether can be decomposed with
Ans : HI
4. Oxygen atom of ether is
Ans : Comparatively inert
5. According to Lewis concept of acids and bases, ethers are
Ans : Basic
6. Intermolecular hydrogen bonds are not present in
Ans : C2H5OC2H5
7. When ethyl Iodide is treated with dry silver oxide it forms
Ans : diethylether
8. Williamson's synthesis is an example of
Ans : Nucleophilic substitution reaction
9. When ether is exposed to air for sometime an explosive substance
produced is
Ans : peroxide
10. Ether is formed when alkyl halide is treated with sodium alkoxide. This
method is known as
Ans : Williamson's synthesis

18. Carbonyl compounds ( 1 x 1 = 1 )


1. The chain isomer of 2-methyl propanal is
Ans : butanal
2. Schiffs reagent gives pink colour with
Ans : acetaldehyde
3. Isopropyl alcohol vapours with air over silver catalyst at 520 K give
Ans : acetone
4. Methyl ketones are usually characterised by
Ans : the iodoform test
5. Which of the following compounds is oxidised to give ethyl methyl
ketone ?
Ans : 2-butanol
6. Formaldehyde polymerises to give
Ans : paraformaldehyde
7. Tollens reagent is
Ans : ammoniacal silver nitrate
8. When acetaldehyde is heated with Fehling solution, it gives a precipitate of
Ans : Cu2O
9. The compound that does not undergo Cannizzaro reaction is
Ans : acetaldehyde
10. The formation of cyanohydrin from a ketone is an example of
Ans : nucleophilic addition
11. Hydrogenation of benzoyl chloride in the presence of Pd on BaSO4 gives
Ans : benzaldehyde
12. From which of the following, tertiary butyl alcohol is obtained by the action of methyl
magnesium iodide ?
Ans : CH3COCH3

38

13. During reduction of aldehydes with hydrazine and C2H5ONa the product
formed is
Ans : RCH3
14. Aldol is
Ans : 3-hydroxy butanal
15. In the reduction of acetaldehyde using LiAlH4 the hydride ion acts as
Ans : nucleophile
16. Which of the following statement is wrong ?
Ans : aldehydes and ketones undergo nucleophilic substitution
17. A cyanohydrin of a compound X on hydrolysis gives lactic acid. The X is
Ans : CH3CHO
18. The IUPAC name of CH3 C = CH C CH3 is
|
||
CH3

Ans : 4-methylpent-3-en-2-one
19. Which of the following does not give iodoform test ?
Ans : benzophenone
20. The compound which does not reduce Fehling solution is
Ans : benzaldehyde
21.CH3COCH3 Conc. H2SO4 The product is
Ans : mesitylene
22. Which compound on strong oxidation gives propionic acid ?
Ans : CH3 CH2 CH2 OH
23. The compound used in the preparation of the tranquilizer, sulphonal is
Ans : acetone
24. Calcium acetate + calcium benzoate gives
Ans : acetophenone
25. Bakelite is a product of reaction between
Ans : phenol and methanal

19.Carboxlic acids ( 1 x 1 = 1)
1. Which of the following is least acidic
Ans : C2H5OH
2. Weakest acid among the following is
Ans : Acetylene
3. Ester formation involves the reaction of
Ans : An acylhalide with an alcohol
4. Heating a mixture of sodium acetate and soda lime gives
Ans : methane
5. The acid which reduces Tollen's reagent is
Ans : formicacid
CH3
|
6. The IUPAC name of CH3 CH2 CH COOH is
Ans : 2-methyl butanoic acid
7. The Isomerism exhibited by CH3CH2COOH and CH3COOCH3 is
Ans : functional
8. The acid that cannot be prepared by Grignard reagent
Ans : formic acid
39

9. Which order of arrangement is correct interms of the strength of the acid


Ans : CH3CH2COOH < CH3COOH < HCOOH < ClCH2COOH
10. The compound which undergoes intra molecular dehydration with P2O5 is
Ans : formic acid
11. HO
C = O 1600c

The product is

H
Ans : H2 + CO2
12. When chlorine is passed through acetic acid in presence of red P, it forms.
Ans : Trichloro acetic acid
13. Which of the following compounds will react with NaHCO3 solution to give sodium salt
and CO2 ?
Ans : acetic acid
14. When propanoic acid is treated with aqueous sodium - bicarbonatate, CO2 is liberated.
The "C" of CO2 comes from
Ans : bicarbonate
15. Carboxylic acids are more acidic than phenol and alcohol because of
Ans : greater resonance stabilisation of their conjugate base
16. Among the following the strongest acid is
Ans : Cl3CCOOH
17. Which of the following compound is optically active ?
Ans : (c) CH3CH(OH)COOH (d) Cl2CHCOOH
18.CH3CH(OH)COOH
? The product is
H2O2/Fe2+

Ans : (a) CH3COCOOH


19. The compound found in some stony deposit in kidneys is
Ans : calcium oxalate
20. Ethylene cyanide on hydrolysis using acid gives
Ans : succinic acid

20.Organic nitrogen compounds ( 3 x 1 = 3 )


1. Bromo ethane reacts with silver nitrite to give
Ans : C2H5NO2
2. The isomerism exhibited by and CH3 CH2 O N = O is
Ans : functional
3. In nitro alkanes NO2 group is converted to NH2 group by the reaction
with
Ans : Sn/HCl
4. When nitromethane is reduced with Zn dust + NH4Cl in neutral medium,
we get
Ans : CH3NHOH
5. The compound that is most reactive towards electrophilic nitration is
Ans : Toluene
6. Nitromethane condenses with acetaldehyde to give
Ans : 1-nitro-2-propanol
7. Which of the following compounds has the smell of bitter almonds ?
Ans : nitrobenzene
8. Nitration of nitrobenzene results in
Ans : m-dinitro benzene
40

9. Nitrobenzene on electrolytic reduction in con. sulphuric acid, the intermediate formed is


Ans : C6H5 NHOH
10. Electrophile used in the nitration of benzene is
Ans : nitronium ion
11. The reduction of CH3 CH2 C N with sodium and alcohol results in the formation of
Ans : CH3 CH2 CH2 NH2
12. The basic character of amines is due to the
Ans : lone pair of electrons on nitrogen atom
13. The organic compound that undergoes carbylamine reaction is
Ans : C2H5NH2
14. Primary amine acts as
Ans : Lewis base
15. Oxidation of aniline with acidified potassium dichromate gives
Ans : p-benzo quinone
16. Which one of the following is a secondary amine ?
Ans : diphenyl amine
NaNO2/HCl

17.C6H5NH2
Ans:C6H5N2Cl

X. Identify X.

18. Which of the following will not undergo diazotisation ?


Ans : benzyl amine
19. Aniline differs from ethylamine by the reaction with
Ans : nitrous acid
20. When aqueous solution of benzene diazonium chloride is boiled the product formed is
Ans : (c) phenol

21.Bio molecules (2x1=2)


1. Which is a mono saccharide among the following :
Ans : Glucose
2. Identify the reducing sugar.
Ans : Glucose
3. Sucrose is not
Ans : hydrolysed to only glucose
4. Sucrose contains glucose and fructose linked by
Ans : C1 C2
5. Glucose is not oxidised to gluconic acid by
Ans : Conc. HNO3
6. Inversion of sucrose refers to
Ans : hydrolysis of sucrose to glucose and fructose
7. Glucose forms___________ with acetic anhydride and sodium acetate.
Ans : penta acetate
8. The amino acid without chiral carbon is
Ans : Glycine
9. The building block of proteins are
Ans : -amino acids
10. Which is not true of amino acid ?
Ans : amino acid is insoluble in NaOH solution
11. Two amino acids say A, B- react to give
Ans : two dipeptides
41

12. A di peptide does not have


Ans : two peptide units
13. Proteins are not sensitive to
Ans : water
14. Denaturation does not involve
Ans : breaking up of H bonding in proteins
15. Specificity of enzyme is due to
Ans : (a) the sequence of amino acids
(b) secondary structure
(c) tertiary structure
(d) all of the above
16. Ultimate products of hydrolysis of proteins is
Ans : amino acid
17. Proteins are
Ans : polypeptides
18. Which of the following contains a lipid ?
Ans : edible oil
19. Which among the following contains triglyceride ?
Ans : Cooking oil
20. Which contains a long chain ester ?
Ans : wax
21. An example of a fatty acid obtained from a cooking oil is
Ans : stearic acid
22. Which is not a saturated fatty acid ?
Ans : Oleic acid
23. Alkaline hydrolysis of cooking oil gives
Ans : (a) soap (b) glycerol
(c) fatty acid (d) both (a) and (b)
24. Hair and nail contains
Ans : keratin
25. Important constituent of cell wall is
Ans : cellulose

42

1-Mark
Practice Book back one mark questions (self evaluation) for 19 units.
Practice the questions that where asked in the PTA guide as well as previous
year public question papers.
3-Mark
Important Public exam questions are given below
ATOMIC STRUCTURE-II
1.
2.
3.
4.
5.
6.
7.
8.
9.

What do you understand by the dual character of matter?


State Heisenbergs uncertainty Principle?
Write the difference between particle and wave?
What is the significance of negative electronic energy?
What are molecular orbital ?
Why He2 is not formed?
What is bond order?
Define by hybridization?
Write the conditions for the effective hydrogen bonding?

PERIODIC CLASSIFICATION-II
1. Define Ionic radii?
2. Compare Ionisation Energy?
a.) B & Be
b.) N & O
c.) Li & Be
d.) B & C
e.) F & Ne
f.) Mg & Al
3.Why Electron affinity of fluorine less than of chlorine?
4. State Muliken scale?
5.Mention the disadvantage of pauling and muliken scale?
6. Define Electron affinity
7. Define Ionisation Energy

43

P-BLOCK ELEMENTS
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.

Write inert pair effect


Write a note on plumbo solvency
H3PO3 is diprotic why?
Prove that p2o5 a powerful dehydrating agent
H3PO4 triprotic why
Preparation of potash alum?
Preparation of phosphorous acid?
Action of heat on phosphorus acid
Electronic structure of H3PO3 & H3PO4
Write reducing property of phosphorus acid
write reducing property of H3PO4
Write reducing property of PH3
Discuss the oxidizing Power of Fluorine
Write note on Holmes Signal
How do Prepare xenon Fluoride Compounds
HF cannot be stored in glass or silica bottles Why?
Write the uses of Neon
What are the inter halogen Compounds ? How are they formed?
Write the uses of Helium?
How can you draw a Picture in glass using HF?

SURFACE CHEMISTRY
1. What is catalysis?
2. What is auto catalyst ? give example
3. what is Induced catalyst? give example
4. what is promoters? give Example?
5. what is catalytic poison? Give example
6. A colloidal solution of gas in gas is not possible Why?
7. What is Peptisation?
8. What is Helmholtz double layer?
9. What is Tyndall effect?
10. What is Brownian Movement?
11. Write note on Tanning?
12. Write Purification of drinking water by colloids?
13. How is Delta formed?
14. What are emulsion?
15. Write Medical uses of colloids?

44

5 Mark
ATOMIC STRUCTURE-II
1.
2.
3.
4.
5.
6.
7.
8.

Discuss the Davis and Germer experiment


Derive de Broglies equation what is significance?
Discuss the shapes of orbitals
Briefly explain molecular orbital Theory?
Explain the Formation of N2 molecule by molecular orbital theory
Explain the formation of O2 molecule by molecular orbital theory?
Explain salient Features regarding Hybridisation?
Explain Types of Hydrogen bonds.

1.
2.
3.
4.
5.

PERIODIC CLASSIFICATION
Explain the Factors affecting Electron affinity?
How electron negativity values help to find out the nature of bond?
Explain pauling method to determination of ionic radii ?
Explain pauling scale electron negativity ?
Explain the factors affecting ionization energy?
P-block Elements

1.
2.
3.
4.
5.
6.
7.

Explain structure of silicones ?


Explain uses of silicones?
Write the anomalous nature of fluorine.
Give on account of manufacture of lead ?
How is fluorine isolated from fluorides by?
Explain the Ramsay - Ralighs method ?
Explain the Dewars method?
D-block Elements

1.
2.
3.
4.
5.
6.

Write note on alumino thermic process:?


Extraction of copper?
Extraction of zinc
Extraction of silver.
Extraction of gold.
Write the preparation of K2Cr2O7
Co-Ordination compound

1. Explain co-ordination and Ionisation isomerism with suitable


Examples.
2. Explain Hydrate linkage and ligand isomerism with suitable Example.
3. Explain the postulates of werners theory.
4. Explain the Postulates of valance bond theory.

45

5. for the complex K4 (Fe(CN)6)


a) Name b) Central metal ion c) Ligand d) co-ordination number
e) Structure
6. For the complex[Cu(NH3)4] SO4 mention.
a) Name b) Central metal ion c) Ligand d) co-ordination number
e) Structure
7. In what why [ FeF6]4- differs from [Fe(CN)6]48. [Ni(CN)4]2- diamagnetic where as [NiCl4]2+ is paramagnetic explain.
9. Mention the function of Hemoglobin.
10. How chlorophyll is important in environmental chemistry? Mention its
functions.
Surface chemistry
1. Write briefly about the preparation of colloids by dispersion methods:
2. Write briefly about the preparation of colloids by condensation
method.
3. Preparation of colloids by chemical method.
4. Write notes on
1) Dialysis 2) Electro dialysis
5. What is electro osmosis? Explain
6. What is Electrophoresis? Explain.
7. Explain the intermediate compound formation theory .
8. Explain the Adsorption theory.
9. Write the characteristics of catalytic reaction.
10. Write the difference between the Physical and chemical adsorption?
ETHER
1.
2.
3.
4.
5.
6.

Write the preparation of diethyl ether.


Write the difference between diethyl ether and anisole.
Explain the isomerism of ethers.
Write the possible isomerism structure and names of C4H10O
Mention the methods of preparation of anisole.
How does diethyl ether react with the following reagent?
1) O2 2) Dil. H2SO4 3) PCl5
4) Con.H2SO4
5) Cl2
7. Explain the diethyl ether reacted with HI? mention its use.

46

Вам также может понравиться