Академический Документы
Профессиональный Документы
Культура Документы
00
# Shell Research Ltd 2004
Trans IChemE, Part B, January 2004
Process Safety and Environmental Protection, 82(B1): 6168
www.ingentaselect.com=titles=09575820.htm
INTRODUCTION
BLOWDOWN PROGRAM
The BLOWDOWN simulation program (Haque et al.,
1992a) was developed at Imperial College principally for the
simulation of the depressurization of networks of vessels
and associated pipework on the topsides of offshore oil and
gas platforms. It has been extensively validated for such
networks (Haque et al., 1990, 1992b).
It was later extended to simulate the depressurization of
pipelines (Richardson and Saville, 1991, 1992) and BLOWDOWN predictions for large-scale LPG pipeline releases
and showed at least adequate and often good agreement with
measurements (Richardson and Saville, 1996).
Experimental evidence has shown that it is crucial to
model the thermodynamics of depressurization accurately,
since failure to do so can lead to trajectories through
phase (pressuretemperaturecomposition) space which are
grossly in error. For this reason, thermodynamic, phase and
transport properties of the multi-phase multi-component
mixture are calculated rigorously by an extended principle
of corresponding states using a proprietary computer package PREPROP. This issue is particularly important for
ethylene phase trajectories passing close to the critical
point and was one of the key decision drivers in choosing
BLOWDOWN for this study.
METHODOLOGY
Although the ethylene transported in the pipelines is high
purity, it does contain small amounts of impurities. For
61
62
SAVILLE et al.
Mole fraction
Ethylene
Methane
Ethane
0.9990
0.0005
0.0005
Table 1. The main properties for a typical pipeline type are summarized in Table 1.
Property
HPEP
LPEP
6090 bar
(Ambient 7 5) C
250 mm
Majority is 5.65 mm
(some sections are 11.9 mm)
API 5LX 52 (for 5.65 mm
wall thickness)
API 5LX 60 (for 11.9 mm
wall thickness)
500 mm of fusion bonded epoxy
Average depth 1.0 m backfilled
with natural material.
16 km
2845 bar
(Ambient 7 5) C
200 mm
8.18 mm
Pipe material
Pipe coating
Pipe depth
Distance between block valves
API 5L Grade A
For all of the simulations the operating temperature was taken as 10 C.
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B1): 6168
63
Figure 1. Schematic of the hole geometry in the pipeline and measurement locations for parameters reported in the following tables.
Hole Diameter of 50 mm
Tables 4 and 5 give the corresponding results for a 50 mm
diameter hole in the pipe wall. Calculations were performed
only for the highest and lowest pressures, since, as already
observed, the sensitivity to pressure is small.
The pressures and temperatures are very similar to those
found for the 10 mm diameter hole, except that the pressure
and temperature drops through the hole were almost undetectable. All of the changes took place during the acceleration of the fluid upstream of the hole.
Upstream
P0 (bar)
P (bar)
T (K)
VapFr
(molar)
Speed
(m s1)
P (bara)
T (K)
VapFr
(molar)
Speed
(m s1)
Mass flow
(kg s1)
90.0
79.0
69.0
59.6
42.2
43.0
44.2
46.0
273
274
276
279
0.000
0.000
0.000
0.000
163
143
121
92
39.9
41.4
43.1
45.4
273
274
276
278
0.000
0.000
0.000
0.000
164
144
122
92
4.4
3.8
3.2
2.3
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B1): 6168
64
SAVILLE et al.
Table 3. Metal temperature (K) as a function of distance from hole.
Upstream radial distance from surface of holea
P0 (bar)
S0 (0 mm)
S1 (6 mm)
S2 (12 mm)
S3 (18 mm)
S4 (24 mm)
S5 (30 mm)
90.0
79.0
69.0
59.6
273.1
274.6
276.3
278.5
278.2
279.0
279.8
280.9
280.1
280.5
281.1
281.7
281.4
281.6
281.9
282.3
282.3
282.5
282.6
282.8
283.1
283.1
283.1
283.1
Upstream
P0 (bar)
P (bar)
T (K)
VapFr
(molar)
Speed
(m s1)
P (bar)
T (K)
VapFr
(molar)
Speed
(m s1)
Mass flow
(kg s1)
90.0
59.6
40.1
45.5
273
278
0.000
0.000
167
94
39.8
45.4
272
278
0.000
0.000
166
94
114
59
Hole Diameter of 50 mm
Tables 8 and 9 give the results for flow through a 50 mm
diameter hole. The results for temperature and pressures
differ little from the 10 mm diameter hole case.
OBSERVATIONS
(1) The temperature decrease which took place before the
ethylene emerged from a hole in the pipe wall was
almost entirely concerned with acceleration of the
fluid to the point at which sufficient mass could pass
through the hole to satisfy choking conditions at its exit.
The temperature drop required for fluid that
was supercritical upstream was no more than 10 C,
but a rather larger drop was required for gas (of order
30 C).
(2) The predicted temperatures were relatively insensitive to
hole size for the range of hole sizes studied. In these
cases, the flow through the hole is not affected by
the pipeline geometry, which acts as a boundless reservoir for the flow. Temperatures can expected to be
sensitive to the hole size if it becomes comparable
with the pipeline diameter.
(3) For the HPEP, the fluid flowing through and emerging
from the hole was all liquid. The largest temperature
change took place once the fluid left the hole when
expansion to atmospheric pressure produced gasliquid
equilibrium temperatures of order 100 C.
(4) For the LPEP, the fluid flowing through and emerging
from the hole was primarily gas, although there was a
small amount of liquid. Again, the largest temperature
change occurred as the gas expanded to atmospheric
pressure outside the hole, and similar to the HPEP case
was of order 100 C.
If the pipeline is in the open where the emerging fluid can
escape freely, these low temperatures would probably not
S0 (0 mm)
S1 (15 mm)
S2 (30 mm)
S3 (45 mm)
S4 (60 mm)
S5 (75 mm)
90.0
59.6
272.5
278.3
277.1
280.3
279.3
281.3
281.1
282.1
282.2
282.6
283.1
283.1
Upstream
P0 (bar)
P (bar)
T (K)
VapFr
(molar)
Speed
(m s1)
P (bar)
T (K)
VapFr
(molar)
Speed
(m s1)
Mass flow
(kg s1)
44.0
28.0
30.1
17.9
261
255
0.952
1.000
190
237
26.4
15.5
255
247
0.925
1.000
218
269
0.95
0.55
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B1): 6168
65
S0 (0 mm)
S1 (15 mm)
S2 (30 mm)
S3 (45 mm)
S4 (60 mm)
S5 (75 mm)
44.0
28.0
261.0
255.7
272.3
269.7
276.4
274.7
279.2
278.3
281.4
281.0
283.1
283.1
Upstream
P0 (bar)
P (bar)
T (K)
VapFr
(molar)
Speed
(m s1)
P (bar)
T (K)
VapFr
(molar)
Speed
(m s1)
Mass flow
(kg s1)
44.0
28.0
29.0
17.9
259
255
0.940
1.000
200
238
28.5
17.7
259
254
0.940
1.000
203
240
24
14
S0 (0 mm)
S1 (15 mm)
S2 (30 mm)
S3 (45 mm)
S4 (60 mm)
S5 (75 mm)
44.0
28.0
259.1
255.0
268.6
266.1
273.6
272.0
277.5
276.5
280.6
280.1
283.1
283.1
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B1): 6168
66
SAVILLE et al.
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B1): 6168
67
approximately 35 C in the final stages of gas depressurization. At the end of the depressurization there is a rapid
cooling to a final wall temperature of 53 C.
The trajectory has a similar profile for the top blowdown,
however the plateau is at a lower temperature of 48 C and
reached at a lower pipeline pressure. The final wall temperature at the end of the depressurization is 58 C.
One should note that these temperatures are substantially
in excess of the 100 C of the gas which bathes the outside
of the exposed section of pipeline. The temperature gradients in the wall and close to the hole are very similar to the
ones reported earlier (see Tables 3, 5 etc.) although, of
course, the wall temperature of the hole from which the
gradient originates is following the temperature of the fluid
passing through it.
It is also interesting to observe that top depressurization
by liquid evaporation produces very much lower temperatures along the entire pipeline bottom than bottom depressurization. The lowest temperature recorded far away from
the hole is 0 C for bottom blowdown, but 25 C for the top
blowdown.
CONCLUSION
It is possible with BLOWDOWN to simulate the blowdown characteristics of an ethylene pipeline instead of
performing expensive large scale experiments. A steadystate release of supercritical ethylene through a small
corrosion or mechanical damage hole in a flowing pipeline
will remain as liquid as it passes through the hole with
minimal cooling (10 C). Flashing to a two-phase mixture
occurs outside of the hole.
The subsequent blowdown of a blocked in pipeline
section containing supercritical ethylene depends on the
(A1a)
(A1b)
(A1c)
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B1): 6168
68
SAVILLE et al.
(A2b)
(A6)
Soil
Transient conduction occurs in the surrounding soil and it
is assumed that there is good thermal contact between the
soil and the pipe. The soil is wet with assumed thermal
conductivity of 1.38 W m1 K1 and thermal diffusivity
2.01 mm2 s1.
Liquid-to-Wall
For nucleate boiling, the heat flux q is given by:
g(rl rg ) 0:5
q ml (hg hl )
s
[100cpl (Tw Tl )=(hg hl )]3
Prl5:1
DTmin
!"
#0:667
rg s(rl rg )
0:127(hg hl )
kg g(rl rg )
"
#0:5 "
#0:333
g
m
(rl rg )
(rl rg )
(A2c)
(A3)
REFERENCES
Haque, M.A., Richardson, S.M., Saville, G. and Chamberlain, G., 1990,
Rapid depressurisation of pressure vessels, J Loss Prev Proc Ind, 3: 47.
Haque, M.A., Richardson, S.M. and Saville, G., 1992a, Blowdown of
pressure vessels. I. Computer model, Trans IChemE, Part B, Proc Safe
Env Prot, 70(B1): 39.
Haque, M.A., Richardson, S.M., Saville, G., Chamberlain, G. and Shirvill, L.,
1992b, Blowdown of pressure vessels. II. Experimental validation of
computer model and case studies, Trans IChemE, Part B, Proc Safe Env
Prot, 70(B1): 1017.
Richardson, S.M. and Saville, G., 1991, Blowdown of pipelines, in Offshore
Europe 91 (Society of Petroleum Engineers, Aberdeen), paper SPE 23070.
Richardson, S.M. and Saville, G., 1992, Blowdown of vessels and pipelines,
in Major Hazards Onshore and Offshore (IChemE, Rugby, UK), Symposium Series no. 130, pp 195210.
Richardson, S.M. and Saville, G., 1996, Blowdown of LPG pipelines, Trans
IChemE, Part B, Proc Safe Env Prot, 74(B): 235244.
The manuscript was received 16 May 2003 and accepted for publication
after revision 5 September 2003.
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B1): 6168