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Safety Data Sheet

according to Regulation (EC) No 1907/2006

Stellatex HC Hardener
Print date: 11.04.2013

Page 1 of 11

Product code: 92074806

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier

Stellatex HC Hardener
Further trade names
valid for all package sizes
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture

Reserved for industrial and professional use.


Coatings and paints, fillers, putties, thinners Curing agent (crosslinking agent)
Uses advised against

The product is intended for professional use.


1.3. Details of the supplier of the safety data sheet

Company name:
Street:
Place:
Telephone:
e-mail:

DSB Surebau GmbH


Knigswinter
Bachstrae 38
D-53639 Knigswinter
+49 2223 928 0
info@didiersb.de

Contact person:
e-mail:

Surebau Labor
msds@didiersb.de

Internet:
Responsible Department:

www.didiersb.de
+49 2223 928 321

Telefax: +49 2223 928 461


Telephone: +49 2223 928 321

(001) 352 3233500 Emtel-Customer-No. 99496

1.4. Emergency telephone


number:

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Indications of danger: T - Toxic, Xn - Harmful, N - Dangerous for the environment


R phrases:
May cause cancer.
Harmful by inhalation and if swallowed.
Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
May cause sensitisation by skin contact.
Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with
skin and if swallowed.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Possible risks of irreversible effects.
2.2. Label elements

Danger symbols:

T - Toxic

Revision No: 1,00

T - Toxic; N - Dangerous for the environment

N - Dangerous for the


environment
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Safety Data Sheet


according to Regulation (EC) No 1907/2006

Stellatex HC Hardener
Print date: 11.04.2013

Page 2 of 11

Product code: 92074806

Hazardous components which must be listed on the label


benzyl alcohol
4,4'-diaminodiphenylmethane, 4,4'-methylenedianiline
R phrases
45
20/22
39/23/24/25

43
48/20/21/22
51/53
68
S phrases
53
45

61

May cause cancer.


Harmful by inhalation and if swallowed.
Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
May cause sensitisation by skin contact.
Harmful: danger of serious damage to health by prolonged exposure through inhalation, in
contact with skin and if swallowed.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Possible risks of irreversible effects.
Avoid exposure - obtain special instructions before use.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
Avoid release to the environment. Refer to special instructions / Safety data sheets.

Special labelling of certain mixtures


Restricted to professional users.
2.3. Other hazards
Keep away from food, drink and animal feedingstuffs. Do not empty into drains or the aquatic
environment. Do not allow to enter into soil/subsoil.

SECTION 3: Composition/information on ingredients


3.2. Mixtures
Chemical characterization
Mixture related information:
amines.
Hazardous components
EC No
CAS No
Index No
REACH No

Quantity

Chemical name
Classification
GHS classification

50 - 55 %

202-859-9
100-51-6

benzyl alcohol
Xn - Harmful R20/22

603-057-00-5

Acute Tox. 4, Acute Tox. 4; H332 H302

202-974-4
101-77-9

4,4'-diaminodiphenylmethane, 4,4'-methylenedianiline
Carc. Cat. 2, Muta. Cat. 3, T - Toxic, Xn - Harmful, N - Dangerous for the environment
R45-68-39/23/24/25-48/20/21/22-43-51-53

612-051-00-1

Carc. 1B, Muta. 2, STOT SE 1, STOT RE 2, Skin Sens. 1, Aquatic Chronic 2; H350
H341 H370 ** H373 ** H317 H411

200-712-3
69-72-7

Salicylic acid
Xn - Harmful, Xi - Irritant R22-41

45 - 50 %

1-5%

Acute Tox. 4, Eye Dam. 1; H302 H318


01-2119486984-17

Full text of R and H phrases: see Section 16.


Further Information
4,4'-diaminodiphenylmethane, 4,4'-methylenedianiline:
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Safety Data Sheet


according to Regulation (EC) No 1907/2006

Stellatex HC Hardener
Print date: 11.04.2013

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Product code: 92074806

This substance is listed on the priority list of substances of very high concern (SVHC) that are subject
to authorization.

SECTION 4: First aid measures


4.1. Description of first aid measures
General information
First aid assistant: Pay attention to self-protection!
Move victim out of danger zone. Take off immediately all contaminated clothing.
If victim is at risk of losing consciousness, position and transport on their side.
After inhalation
Provide fresh air. In case of breathing difficulties administer oxygen. No mouth-to-mouth or
mouth-to-nose resuscitation.Use respiratory bag or oxygen resuscitation apparatus. Immediately get
medical attention. In the case of lung irritation: Primary treatment using corticoide spray, eg. Auxiloson
spray, Pulmicort-dosage-spray. (Auxiloson and Pulmicort are registered trademarks).
After contact with skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Immediately get medical attention.
After contact with eyes
If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for at
least 5 minutes. Subsequently consult an ophthalmologist.
After ingestion
Rinse mouth immediately and drink large quantities of water. Make affected person vomit if conscious.
Immediately get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Following inhalation: Harmful: possible risk of irreversible effects through inhalation.
After skin contact: Possible risks of irreversible effects. May cause sensitization by skin contact.
Following symptoms can occur: Skin corrosion/irritation: Erythema (reddening)
after ingestion: Harmful: possible risk of irreversible effects if swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: First Aid, decontamination, treatment of symptoms. Following decontamination of the skin,
pain treatment and shock prophylaxis.

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media
Extinguishing materials should be selected according to the surrounding area.
Suitable extinguishing media: Water spray. Extinguishing powder. Foam. Carbon dioxide (CO2).
Use caution when applying carbon dioxide in confined spaces. Carbon dioxide can displace oxygen.
Extinguishing media which must not be used for safety reasons
High power water jet.
5.2. Special hazards arising from the substance or mixture
Can be released in case of fire: Carbon monoxide. Carbon dioxide (CO2). Nitrogen oxides (NOx).
5.3. Advice for firefighters
Wear a self-contained breathing apparatus and chemical resistant suit.
Additional information
Use a water spray jet to knock down vapours/gases/mists. Collect contaminated fire extinguishing
water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures

Revision No: 1,00

GB - EN

Revision date: 11.04.2013

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Stellatex HC Hardener
Print date: 11.04.2013

Page 4 of 11

Product code: 92074806

6.1. Personal precautions, protective equipment and emergency procedures


Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eye and
clothing. Wear personal protection equipment.
6.2. Environmental precautions
Do not empty into drains or the aquatic environment.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the assimilated material according to the section on waste disposal.
6.4. Reference to other sections
See protective measures under point 7 and 8.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Advice on safe handling
In case of open handling equipment with built-in suction must be used. Do not breathe
gas/fumes/vapour/spray.
Advice on protection against fire and explosion
This material is combustible, but will not ignite readily. Keep away from sources of ignition - No
smoking.
Further information on handling
The regulations of the national employment safety and protection commission about the handling for
polyurethane/epoxy products have to be observed. Industry regulation acid protection observed.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed. Keep locked up. Store in a place accessible only to authorized persons.
Provide for sufficient ventilation and punctiform suction at critical points.
Floors should be impenetrable, resistant to liquids and easy to clean. Moreover, national legislation has
to be observed!
Recommended storage temperature: 2 - 40 C
Advice on storage compatibility
Do not store together with: acid. Food and animal feedingstuff
Further information on storage conditions
Keep container tightly closed and dry.
Storage class:
7.3. Specific end use(s)

Restricted to professional users. Observe technical data sheet.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters
Exposure limits (EH40)
CAS No

Substance

101-77-9 4,4'-Methylenedianiline

Revision No: 1,00

GB - EN

ppm

mg/m

0.01

0.08

fibres/ml

Category

Origin

TWA (8 h)

WEL

STEL (15 min)

WEL

Revision date: 11.04.2013

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Stellatex HC Hardener
Print date: 11.04.2013

Page 5 of 11

Product code: 92074806

Biological Monitoring Guidance Values (EH40)


CAS No

Substance

Parameter

101-77-9 4,4-Methylenedianiline (MDA)

Value

Test material

Sampling time

50 mol/mol urine

total MDA

Post shift for


inhalation and
pre-shift next
day for dermal
exposure

8.2. Exposure controls


Occupational exposure controls
In case of open handling equipment with built-in suction must be used. Do not breathe
gas/fumes/vapour/spray.
Protective and hygiene measures
Take off immediately all contaminated clothing. Protect skin by using skin protective cream. After work,
wash hands and face. When using do not eat or drink. Store work clothing separately. Wear personal
protection equipment.
Respiratory protection

Respiratory protection required in case of: insufficient ventilation. insufficient absorbtion.


Suitable respiratory protective equipment: Filter respirator (DIN EN 147). A 2-P 2
Only use breathing apparatus with CE-label including the four-digit identification number.
Hand protection
Tested protective gloves are to be worn:
Suitable material: NBR (Nitrile rubber). Butyl rubber. PVC (Polyvinyl chloride). CR (polychloroprenes,
Chloroprene rubber). FKM (fluororubber).
Before using check leak tightness / impermeability. Breakthrough times and swelling characteristics of
the material must be taken into consideration. When handling chemical substances, chemical
protective gloves must be worn with CE label including a four digit code.
Eye protection
Tightly sealed safety glasses.
Skin protection
Suitable protection of the body: Single-use suit.
Environmental exposure controls
refer to chapter 7. No further action is necessary.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties

Physical state:
Colour:
Odour:

liquid
light brown
like: phenol.
Test method

pH-Value:

not determined

Changes in the physical state


Melting point:

not determined
206 C benzyl alcohol

Boiling point:
Sublimation point:

not determined

Softening point:

not determined
> 200 C

Temperature of decomposition::
Flash point:
Revision No: 1,00

94 C benzyl alcohol
GB - EN

Revision date: 11.04.2013

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Stellatex HC Hardener
Print date: 11.04.2013

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Product code: 92074806

Explosive properties
Product is: not explosive.

Lower explosion limits:


Upper explosion limits:

1,22 vol. % benzyl alcohol


13 vol. % benzyl alcohol
435 C benzyl alcohol

Ignition temperature:
Oxidizing properties
Product is: Not oxidizing.

Vapour pressure:
(at 20 C)
Vapour pressure:
(at 50 C)
Density (at 25 C):
Bulk density:
Water solubility:
(at 20 C)
Solubility in other solvents
mixable with most organic solvent cleaners

0,027 hPa benzyl alcohol


0,67 hPa benzyl alcohol
1,12 g/cm DIN 53217
not applicable
not miscible

Viscosity / dynamic:
(at 25 C)
Flow time:

600 - 1000 mPas DIN 53018


not determined
50,00 %

Solvent content:
9.2. Other information

Solid content:

50,00 %

SECTION 10: Stability and reactivity


10.1. Reactivity

No ignition, explosion, self-heating or visible decomposition.


10.2. Chemical stability
The product is chemically stable.
10.3. Possibility of hazardous reactions
Exothermic reactions with: acid.
10.4. Conditions to avoid
Remove all sources of ignition.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
10.5. Incompatible materials
Strong acid Alkalis (alkalis). Oxidizing agents, strong.
10.6. Hazardous decomposition products
Carbon monoxide. Carbon dioxide (CO2). Nitrogen oxides (NOx).
Burning produces large quantities of soot.

SECTION 11: Toxicological information


11.1. Information on toxicological effects
Acute toxicity
Toxic. Acute toxicity, oral. Acute toxicity, inhalant. Acute toxicity, dermal. Danger of very serious
irreversible effects.

Revision No: 1,00

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Revision date: 11.04.2013

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Stellatex HC Hardener
Print date: 11.04.2013
CAS No

Chemical name
Exposure routes

100-51-6

101-77-9

69-72-7

Page 7 of 11

Product code: 92074806

Method

Dose

Species

Source

Rat

GESTIS

benzyl alcohol
oral

LD50

1230 mg/kg

inhalative vapour

ATE

11 mg/l

inhalative aerosol

ATE

1,5 mg/l

4,4'-diaminodiphenylmethane, 4,4'-methylenedianiline
oral

LD50

1700 mg/kg

Rat

dermal

LD50

2080 mg/kg

Rat

inhalative (4 h) aerosol

LC50

> 0,85 mg/l

Rat

oral

LD50

891 mg/kg

Rat.

dermal

LD50
mg/kg

> 2000

Rabbit.

Salicylic acid

Specific effects in experiment on an animal


product has not been tested. Toxicological data are not available.
Irritation and corrosivity
Irritating to eyes.
Sensitising effects
May cause sensitization by skin contact.
Severe effects after repeated or prolonged exposure
Danger of serious damage to health by prolonged exposure.
Carcinogenic/mutagenic/toxic effects for reproduction
May cause cancer. May cause heritable genetic damage.
Additional information on tests
The classification was undertaken in accordance with the calculation method governed by the
Preparations Directive (1999/45/EC).

SECTION 12: Ecological information


12.1. Toxicity

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
CAS No

Chemical name
Aquatic toxicity

101-77-9

69-72-7

Method

Dose

h Species

Source

4,4'-diaminodiphenylmethane, 4,4'-methylenedianiline
Acute fish toxicity

LC50

50 mg/l

96 Leuciscus idus (golden orfe)

Acute algae toxicity

ErC50

11 mg/l

72 Scenedesmus subspicatus

IUCLID

EC50

870 mg/l

48 Daphnia magna

GESTIS

Salicylic acid
Acute crustacea toxicity

12.2. Persistence and degradability


Not easily bio-degradable (according to OECD-criteria).
12.3. Bioaccumulative potential
No data available

Revision No: 1,00

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Safety Data Sheet


according to Regulation (EC) No 1907/2006

Stellatex HC Hardener
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Product code: 92074806

Partition coefficient n-octanol/water


CAS No
100-51-6
101-77-9
69-72-7

Chemical name

Log Pow

benzyl alcohol
4,4'-diaminodiphenylmethane, 4,4'-methylenedianiline
Salicylic acid

1,05
1,59
2,26

12.4. Mobility in soil


Toxicological data are not available.
12.5. Results of PBT and vPvB assessment
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
12.6. Other adverse effects
No data available
Further information
Do not empty into drains or the aquatic environment. The classification was undertaken in accordance
with the calculation method governed by the Preparations Directive (1999/45/EC).

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Advice on disposal
Do not empty into drains or the aquatic environment. Waste disposal according to official state
regulations. Evidence for disposal must be provided.
Waste disposal number of waste from residues/unused products
WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic
070208
rubber and man-made fibres; other still bottoms and reaction residues
Classified as hazardous waste.
Waste disposal number of contaminated packaging
WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
150110
CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal
packaging waste); packaging containing residues of or contaminated by dangerous substances
Classified as hazardous waste.
Contaminated packaging
Completely emptied packings can be re-cycled. Handle contaminated packaging in the same way as
the substance itself.

SECTION 14: Transport information


Land transport (ADR/RID)
14.1. UN number:

UN2810

14.2. UN proper shipping name:

TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-Diaminodiphenylmethane)

14.3. Transport hazard class(es):

6.1

14.4. Packing group:

III

Hazard label:
Classification code:
Special Provisions:
Limited quantity:
Transport category:
Hazard No:
Tunnel restriction code:

6.1
T1
274 614
5L
2
60
E

Other applicable information (land transport)


E1
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Safety Data Sheet


according to Regulation (EC) No 1907/2006

Stellatex HC Hardener
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Page 9 of 11

Product code: 92074806

Inland waterways transport (ADN)


14.1. UN number:

UN2810

14.2. UN proper shipping name:

TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-Diaminodiphenylmethane)

14.3. Transport hazard class(es):


14.4. Packing group:

6.1
III

Hazard label:
Classification code:
Special Provisions:
Limited quantity:

6.1
T1
274 614 802
5L

Other applicable information (inland waterways transport)


E1
Marine transport (IMDG)
14.1. UN number:

UN2810

14.2. UN proper shipping name:

TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-Diaminodiphenylmethane-Mixture)

14.3. Transport hazard class(es):

6.1

14.4. Packing group:

III

Hazard label:
Marine pollutant:
Special Provisions:
Limited quantity:
EmS:
Segregation group:

6.1
yes
223, 274
5L
F-A, S-A
alkalis

Other applicable information (marine transport)


E1
Air transport (ICAO)
14.1. UN number:

UN2810

14.2. UN proper shipping name:

TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-Diaminodiphenylmethane-Mixture)

14.3. Transport hazard class(es):

6.1

14.4. Packing group:

III

Hazard label:
Special Provisions:
Limited quantity Passenger:

6.1
A3 A4 A137
2L

IATA-packing instructions - Passenger:


IATA-max. quantity - Passenger:
IATA-packing instructions - Cargo:
IATA-max. quantity - Cargo:

655
60 L
663
220 L

Other applicable information (air transport)


E1
Passenger-LQ: Y642
14.5. Environmental hazards

Dangerous for the environment:

yes

14.6. Special precautions for user


May cause cancer. Possible risks of irreversible effects.
Keep away from food, drink and animal feedingstuffs.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not classified for this carrier.

Revision No: 1,00

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Revision date: 11.04.2013

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Stellatex HC Hardener
Print date: 11.04.2013

Page 10 of 11

Product code: 92074806

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information

1999/13/EC (VOC):

53 % (593,6 g/l)

Additional information
4,4'-diaminodiphenylmethane, 4,4'-methylenedianiline:
This substance is listed on the priority list of substances of very high concern (SVHC) that are subject
to authorization.
National regulatory information

Employment restrictions:

Water contaminating class (D):


Skin resorption/Sensitization:

Observe employment restrictions for young people. Observe employment


restrictions for child bearing mothers and nursing. Observe employment
restrictions for women of child-bearing age.
3 - highly water contaminating
Causes allergic hypersensitivity reactions.

Additional information
510
15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information


Changes

* Data changed from previous versions


Abbreviations and acronyms
ADR: Accord europen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Rglement international concernant le transport des marchandises dangereuses par chemin de
fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Associatio
Full text of R phrases referred to under Sections 2 and 3
20/22
Harmful by inhalation and if swallowed.
22
Harmful if swallowed.
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
41
Risk of serious damage to eyes.
43
May cause sensitisation by skin contact.
45
May cause cancer.
48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in
contact with skin and if swallowed.
51
Toxic to aquatic organisms.
51/53
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
53
May cause long-term adverse effects in the aquatic environment.
68
Possible risks of irreversible effects.
Full text of H statements referred to under Sections 2 and 3
H302
Harmful if swallowed.
H317
May cause an allergic skin reaction.
H318
Causes serious eye damage.
H332
Harmful if inhaled.
Revision No: 1,00

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Safety Data Sheet


according to Regulation (EC) No 1907/2006

Stellatex HC Hardener
Print date: 11.04.2013

Product code: 92074806

H341
H350
H370
H373
H411

Suspected of causing genetic defects.


May cause cancer.
Causes damage to organs.
May cause damage to organs through prolonged or repeated exposure.
Toxic to aquatic life with long lasting effects.

Page 11 of 11

Further Information
The above information describes exclusively the safety requirements of the product and is based on
our present-day knowledge. The information is intended to give you advice about the safe handling of
the product named in this safety data sheet, for storage, processing, transport and disposal. The
information cannot be transferred to other products. In the case of mixing the product with other
products or in the case of processing, the information on this safety data sheet is not necessarily valid
for the new made-up material.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

Revision No: 1,00

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Revision date: 11.04.2013