JEE MAINS Solved Paper 2011

Solved Paper 2011
All India Engineering Entrance Examination

Instructions
1.
This test consists of 90 questions.
2.
There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics
having 30 questions in each part of equal weightage. Each question is allotted 4 marks for correct
response.
3.
Candidates will be awarded marks as stated above for correct response of each question. 1/4 mark will
be deducted for indicating incorrect response of each question. No deduction from the total score will
be made if no response is indicated for an item in the answer sheet.
4.
There is only one correct response for each question. Filling up more than one response in any
question will be treated as wrong response and marks for wrong response will be deducted according
as per instructions.
Physics
1. The transverse displacement y ( x , t) of a
wave on a string is
2
2
y ( x , t) = e-( ax + bt + 2 ab xt).
given
by
This represents a
(a) wave moving in - x direction with speed
b
a
(b) standing wave of frequency b

1
(c) standing wave of frequency
b
(d) wave moving in + x direction with speed
a
b
2. A screw gauge gives the following

reading when used to measure the
diameter of a wire.
Main scale reading : 0 mm; Circular scale
reading : 52 divisions
Given that 1 mm on main scale
corresponds to 100 divisions of the
circular scale.
The diameter of wire from the above data

is
(a) 0.052 cm
(c) 0.005 cm
(b) 0.026 cm
(d) 0.52 cm
3. A mass m hangs with the help of a string

wrapped around a pulley on a frictionless
bearing. The pulley has mass m and
radius R. Assuming pulley to be a perfect
uniform circular disc, the acceleration of
the mass m, if the string does not slip on
the pulley, is
(a) g
(b)
2
g
3
(c)
g
3
(d)
3
g
2
4. Work done in increasing the size of a soap

bubble from radius of 3 cm to 5 cm is
nearly (surface tension of soap solution
=0.3 Nm -1 )
(a) 0.2 p mJ
(c) 0.4 p mJ
(b) 2p mJ
(d) 4 p mJ
AIEEE Solved Paper 2011

5. A thin horizontal circular disc is rotating
about a vertical axis passing through its
centre. An insect is at rest at a point near
the rim of the disc. The insect now moves
along a diameter of the disc to reach its
other end. During the journey of the insect,
the angular speed of the disc
(a) continuously decreases
(b) continuously increases
(c) first increases and then decreases
(d) remains unchanged
particles are executing simple

harmonic motion of the same amplitude A
and frequency w along the x-axis. Their
mean position is separated by distance
X0 ( X0 > A). If the maximum separation
between them is ( X0 + A), the phase
difference between their motions is
p
3
(b)
p
4
(c)
p
6
(d)
p
2
7. Two bodies of masses m and 4 m are placed

at a distance r. The gravitational potential
at a point on the line joining them where
the gravitational field is zero, is
(a) -
4Gm
6Gm
9Gm
(b) (c) (d) zero
r
r
r
8. Two identical charged spheres suspended

from a common point by two massless
strings of length l are initially a distance
d( d << l) apart because of their mutual
repulsion. The charge begins to leak from
both the spheres at a constant rate. As a
result charges approach each other with a
velocity v. Then, as a function of distance x
between them,
(a) v x-1 (b) v x1/ 2 (c) v x
(d) v x-1/ 2
9. A boat is moving due east in a region where

the
earths
magnetic
field
is
due
North
and
5.0 10 -5 NA -1m -1
horizontal. The boat carries a vertical aerial
2 m long. If the speed of the boat is 1.50
ms-1, the magnitude of the induced emf in
the wire of aerial is
(a) 075
. mV
(c) 0.15 mV
(b) 0.50 mV
(d) 1 mV
10. An object, moving with a speed of

6.25 m/s, is decelerated at a rate given
dv
by
= - 2.5 v , where v is the
dt
instantaneous speed. The time taken by
the object, to come to rest, would be
(a) 2 s
(c) 8 s
(b) 4 s
(d) 1 s
11. A fully charged capacitor C with initial
6. Two
(a)
81
charge q0 is connected to a coil of self

inductance L at t = 0. The time at which
the energy is stored equally between the
electric and the magnetic fields is
(a)
p
4
LC
(c) LC
(b) 2p
LC
(d) p LC
12. Let the xz-plane be the boundary

between two transparent media.
Medium 1 in z 0 has a refractive index
of 2 and medium 2 with z < 0 has a
refractive index of 3. A ray of light in
medium 1 given by the vector
A = 6 3 $i + 8 3 $j - 10 k$ is incident on
the plane of separation. The angle of
refraction in medium 2 is
(a) 45
(c) 75
(b) 60
(d) 30
13. A current I flows in an infinitely long

wire with cross-section in the form of a
semi-circular ring of radius R. The
magnitude of the magnetic induction
along its axis is
(a)
m0 I
2p2R
m I
(c) 0
4pR
(b)
(d)
m0 I
2 pR
m0 I
p2R
14. A thermally insulated vessel contains an

ideal gas of molecular mass M and ratio
of specific heat g. It is moving with speed
v and it suddenly brought to rest.
Assuming no heat is lost to the
surroundings, its temperature increases
by
(g - 1)
Mv 2K
2 gR
(g - 1)
(c)
Mv 2K
2R
(a)
gMv 2
K
2R
(g - 1)
(d)
Mv 2K
2(g + 1)R
(b)
82 JEE Main Solved Papers

15. A mass M, attached to a horizontal
18. Three perfect gases at absolute temperatures
spring, executes SHM with amplitude

A1. When the mass M passes through
its mean position, then a smaller mass
m is placed over it and both of them
move together with amplitude A2 . The
A
ratio of 1 is
A2
T1, T2 and T3 are mixed. The masses of

molecules are m1, m2 and m3 and the number
of molecules are n1, n2 and n3 respectively.
Assuming no loss of energy, the final
temperature of the mixture is
(a)
(c)
n1T1 + n2T2 + n3T3

n1 + n2 + n3
(c)
n12T12 + n22T22 + n32T32

(T + T2 + T3 )
(d) 1
n1T1 + n2T2 + n3T3
3
1/ 2
M+ m
M
M
(b)
M + m
1/ 2
M + m
(d)
M
M+ m
16. Water is flowing continuously from a

tap having an internal diameter
8 10 -3 m. The water velocity as it
leaves the tap is 0.4 ms-1. The
diameter of the water stream at a
distance 2 10 -1 m below the tap is
close to
(a) 7.5 10-3 m
-3
(c) 3.6 10
(b) 9.6 10-3 m

(d) 5.0 10-3 m
17. This question has Statement I and

Statement II. Of the four choices
given after the statements, choose the
one that best describes the two
statements.
Statement I Sky wave signals are
used for long distance radio
communication. These signals are in
general, less stable than ground wave
signals.
Statement II The state of ionosphere
varies from hour to hour, day to day
and season to season.
(a) Statement I is true, Statement II is true;
Statement II is the correct explanation of
Statement I
(b) Statement I is true, Statement II is true;
Statement II is not the correct
explanation of Statement I
(c) Statement I is false, Statement II is true
(d) Statement I is true, Statement II is false
n1T12 + n2T22 + n3T32

n1T1 + n2T2 + n3T3
(a)
(b)
19. A pulley of radius 2 m is rotated about its axis
by a force F = (20t - 5t2 ) N (where, t is

measured in seconds) applied tangentially. If
the moment of inertia of the pulley about its
axis of rotation is 10 kg-m2 , the number of
rotations made by the pulley before its
direction of motion if reserved, is
(a) more than 3 but less than 6
(b) more than 6 but less than 9
(c) more than 9
(d) less than 3
20. A resistor R and 2 mF capacitor in series is

connected through a switch to 200 V direct
supply. Across the capacitor is a neon bulb
that lights up at 120 V. Calculate the value of
R to make the bulb light up 5 s after the switch
has been closed. (log 10 2.5 = 0.4)
(a) 17
. 105 W
(b) 2.7 106 W
(d) 13
. 104 W
(c) 3.3 10 W
21. A
Carnot
engine
between
1
temperatures T1 and T2 has efficiency . When
6
T2 is lowered by 62 K, its efficiency increases to
1
. Then, T1 and T2 are respectively
3
(a) 372 K and 330 K
(c) 310 K and 248 K
operating
(b) 330 K and 268 K

(d) 372 K and 310 K
22. If a wire is stretched to make it 0.1% longer, its

resistance will
(a) increase by 0.2%
(b) decrease by 0.2%
(c) decrease by 0.05% (d) increase by 0.05%
83
23. This question has a paragraph followed
27. A water fountain on the ground sprinkles
by two statements, Statement I and

Statement II. Of the given four
alternatives after the statements, choose
the one that describes the statements.
A thin air film is formed by putting the
convex surface of a plane-convex lens over
a plane glass plate. With monochromatic
light, this film gives an interference
pattern due to light reflected from the top
(convex) surface and the bottom (glass
plate) surface of the film.
Statement I When light reflects from the
air-glass plate interface, the reflected
wave suffers a phase change of p.
Statement II The centre of the
interference pattern is dark.
water all around it. If the speed of water

coming out of the fountain is v, the total
area around the fountain that gets wet is

Statement I
Statement II is not the correct explanation of
Statement I
24. A car is fitted with a convex side-view

mirror of focal length 20 cm. A second car
2.8 m behind the first car is overtaking the
first car at a relative speed of 15 m/s. The
speed of the image of the second car as
seen in the mirror of the first one is
(a)
1
1
m/s (b) 10 m/s (c) 15 m/s (d)
m/s
15
10
25. Energy
required for the electron

excitation in Li2 + from the first to the third
Bohr orbit is
(a) 36.3 eV
(c) 122.4 eV
(b) 108.8 eV
(d) 12.1 eV
26. The electrostatic potential inside a

charged spherical ball is given by
f = ar 2 + b, where r is the distance from
the centre, a and b are constants. Then,
the charge density inside the ball is
(a) - 6 a e0 r
(c) - 6 a e0
(b) - 24 p a e0
(d) - 24p a e0 r
(a) p
v4
g2
(b)
p v4
2 g2
(c) p
v2
g2
(d) p
v2
g
28. 100g of water is heated from 30C to 50C.

Ignoring the slight expansion of the
water, the change in its internal energy is
(specific heat of water is 4184 J/kg/K)
(a) 8.4 kJ
(b) 84 kJ
(c) 2.1 kJ
(d) 4.2 kJ
29. The half life of a radioactive substance is

20 min. The approximate time interval
2
(t2 - t1) between the time t2 when of it has
3
1
decayed and time t1 when
of it had
3
decayed is
(a) 14 min
(c) 28 min
(b) 20 min
(d) 7 min
30. This question has Statement I and

Statement I. Of the four choices given
after the statements, choose the one that
best describes the two statements.
Statement I A metallic surface is
irradiated by a monochromatic light of
frequency
(the
threshold
n > n0
frequency). The maximum kinetic energy
and the stopping potential are Kmax and V0
respectively. If the frequency incident on
the surface is doubled, both the Kmax and
V0 are also doubled.
Statement II The maximum kinetic
energy and the stopping potential of
photoelectrons emitted from a surface are
linearly dependent on the frequency of
incident light.
Statement I
Statement II is not the correct explanation of
Statement I
Chemistry
31. The presence or absence of hydroxy
group on which carbon atom of sugar
differentiates RNA and DNA?
(a) 1st
(b) 2nd
(c) 3rd
(d) 4th
32. Among the following, the maximum

covalent character is shown by the
compound
(a) FeCl 2
(b) SnCl 2
(c) AlCl 3
(d) MgCl 2
33. Which of the following statements is

wrong?
(a) The stability of hydrides increases from NH3
to BiH3 in group 15 of the periodic table
(b) Nitrogen cant form dp-pp bond
(c) Single NN bond is weaker than the single
PP bond
(d) N2O 4 has two resonance structure
34. Phenol is heated with a solution of

mixture of KBr and KBrO3 . The major
product obtained in the above reaction is
35. A 5.2 molal aqueous solution of methyl

alcohol, CH3OH, is supplied. What is the
mole fraction of methyl alcohol in the
solution?
(b) 0.90
(c) 0.086
(d) 0.050
36. The hybridization of orbitals of N atom

in NO3- ,
NO2+
and NH4+
are respectively
2
(a) sp, sp , sp
(b) sp , sp, sp
(c) sp, sp3 , sp2
(d) sp2 , sp3 , sp
37. Ethylene glycol is used as an antifreeze

in a cold climate. Mass of ethylene
glycol which should be added to 4 kg
of water to prevent it from freezing at
- 6C will be
(Kf for water = 1.86 K kg mol-1 and molar
mass of ethylene glycol = 62 g mol-1)
(a) 804.32 g
(c) 400.00 g
half-cell will be negative if

(a) p (H2 )
(b) p (H2 )
(c) p (H2 )
(d) p (H2 )
=
=
=
=
1 atm and [H+ ] = 2.0 M

1 atm and [H+ ] = 1.0 M
2 atm and [H+ ] = 1.0 M
2 atm and [H+ ] = 2.0 M
39. Which of the following reagents may be

used to distinguish between phenol and
benzoic acid?
(a) Aqueous NaOH
(c) Molisch reagent
(b) Tollens reagent

(d) Neutral FeCl 3
40. Trichloroacetaldehyde was subjected to

Cannizzaros reaction by using NaOH. The
mixture of the products contains sodium
trichloroacetate
ion
and
another
compound. The other compound is
(a) 2, 2, 2-trichloroethanol (b) trichloromethanol
(c) 2, 2, 2-trichloropropanol (d) chloroform
41. Which one of the following orders present

the correct sequence of the increasing basic
nature of the given oxides?
(a) 2-bromophenol
(b) 3-bromophenol
(c) 4-bromophenol
(d) 2, 4, 6-tribromophenol
(a) 0.100
38. The reduction potential of hydrogen
(b) 204.30 g
(d) 304.60 g
(a) Al 2O 3 < MgO < Na 2O < K 2O

(b) MgO < K 2O < Al 2O 3 < Na 2O
(c) Na 2O < K 2O < MgO < Al 2O 3
(d) K 2O < Na 2O < Al 2O 3 < MgO
42. A gas absorbs photon of 355 nm and emits

at two wavelengths. If one of the emission is
at 680 nm, the other is at
(a) 1035 nm
(b) 325 nm
(c) 743 nm (d) 518 nm
43. Which of
the following statements

regarding sulphur is incorrect?
(a) S2 molecule is paramagnetic.

(b) The vapour at 200C consists mostly ofS8 rings.
(c) At 600C, the gas mainly consists of S2
molecules.
(d) The oxidation state of sulphur is never less than
+4 in its compounds.
44. The entropy change involved in the

isothermal reversible expansion of 2 moles
of an ideal gas from a volume of10 dm 3 to a
volume of 100 dm 3 at 27C is
(a) 38.3 J mol -1K -1
(c) 32.3 J mol -1K -1
(b) 35.8 J mol -1K -1

(d) 42.3 J mol -1K -1

45. Which of the following facts about the
complex [Cr(NH3 )6 ]Cl3 is wrong?
(a) The complex involves d 2 sp3 hybridization and
is octahedral in shape
(b) The complex is paramagnetic
(c) The complex is an outer orbital complex
(d) The complex gives white precipitate with silver
nitrate solution
46. The structure of IF7 is

(a) square pyramid
(c) octahedral
(b) trigonal bipyramid

(d) pentagonal bipyramid
47. The rate of a chemical reaction doubles

for every 10C rise of temperature. If the
temperature is raised by 50C, the rate of
the reaction increases by about
(a) 10 times
(c) 32 times
(b) 24 times
(d) 64 times
48. The strongest acid amongst the following

compounds is
(a) CH3COOH
(b) HCOOH
(c) CH3CH2CH(Cl)CO 2H
(d) ClCH2CH2CH2COOH
49. Identify the compound that exhibits

tautomerism
(a) 2-butene
(c) 2-pentanone
(b) lactic acid

(d) phenol
50. A vessel at 1000 K contains CO2 with a

pressure of 0.5 atm. Some of the CO2 is
converted into CO on the addition of
graphite. If the total pressure at
equilibrium is 0.8 atm, the value of Kp is
(a) 1.8 atm
(c) 0.3 atm
(b) 3 atm
(d) 0.18 atm
51. In context of the lanthanoids, which of the

following statements is not correct?
(a) There is a gradual decrease in the radii of the
members with increasing atomic number in
the series
(b) All the members exhibit + 3 oxidation state
(c) Because of similar properties the separation of
lanthanoids is not easy
(d) Availability of 4f electrons results in the
formation of compounds in +4 state for all the
members of the series
52. a and b are van der Waals constants for

gases. Chlorine is more easily liquefied
than ethane because
85
(a) a and b for Cl 2 > a and b for C 2H6

(b) a and b for Cl 2 < a and b for C 2H6
(c) a for Cl 2 < a for C 2H6 but b for Cl 2 > b for C 2H6
(d) a for Cl 2 > a for C 2H6 but b for Cl 2 < b for C 2H6
53. The magnetic moment (spin only) of

[NiCl4 ]2 is
(a) 1.82 BM
(c) 2.82 BM
(b) 5.46 BM
(d) 1.41 BM
54. In a face centred cubic lattice, atom A

occupies the corner positions and atom B
occupies the face centre positions. If one
atom of B is missing from one of the face
centred points, the formula of the
compound is
(a) A2 B
(b) AB2
(c) A2 B2
(d) A2 B5
55. The outer electron configuration of

Gd (At.no. 64) is
(a) 4f 3 5d 5 6s 2
(c) 4f 4 5d 4 6s 2
(b) 4f 8 5d 0 6s 2
(d) 4f 7 5d 1 6s 2
56. Boron cant form which one of the

following anions?
(a) BF63
(b) BH4
(c) B(OH)4 (d) BO 2
57. Ozonolysis of an organic compound gives

formaldehyde as one of the products. This
confirms the presence of
(a) two ethylenic double bonds
(b) a vinyl group
(c) an iso-propyl group
(d) an acetylenic triple bond
58. Sodium ethoxide has reacted with

ethanoyl chloride. The compound that is
produced in the above reaction is
(a) diethyl ether
(c) ethyl chloride
(b) 2-butanone
(d) ethyl ethanoate
59. The degree of dissociation (a ) of a weak

electrolyte, Ax By is related to vant Hoff
factor ( i) by the expression
i -1
( x + y - 1)
x+ y-1
(c) a =
i -1
(a) a =
i -1
x+ y+1
x+ y+1
(d) a =
i -1
(b) a =
60. Silver mirror test is given by which one of

the following compounds?
(a) Acetaldehyde
(c) Formaldehyde
(b) Acetone
(d) Benzophenone
Mathematics
61. The lines L1 : y - x = 0 and L2 : 2 x + y = 0
intersect the line L3 : y + 2 = 0 at P and Q
respectively. The bisector of the acute
angle between L1 and L2 intersects L3 at R.
Statement I The ratio PR : RQ equals
2 2 : 5.
Statement II In any triangle, bisector of
an angle divides the triangle into two
similar triangles.
Statement II is not a correct explanation for
Statement I
(b) Statement I is true, Statement II is false
(d) Statement I is true, Statement II is true;
Statement II is a correct explanation for
Statement I
62. If A = sin2 x + cos4 x , then for all real x

13
A1
16
3
13
(c) A
4
16
(a)
(b) 1 A 2
(d)
3
A1
4
63. The coefficient of x 7 in the expansion of

(1 - x - x 2 + x 3 )6 is
(a) - 132
(c) 132
(b) -144
(d) 144
1 - {cos 2 ( x - 2)}
x -2
64. lim
x 2
(a) equals 2
1
2
(c) equals
(b) equals - 2
(d) does not exist
65. Statement I The number of ways

distributing 10 identical balls in 4 distinct
boxes such that no box is empty is 9 C3 .
Statement II The number of ways of
choosing any 3 places from 9 different
places is 9 C3 .
Statement I

Statement I
2
66. d x2 equals
dy
d 2 y
(a) - 2
dx
-1
dy
dx
-3
d 2 y dy -3
(c) - 2
dx dx
d 2 y dy -2
(b) 2
dx dx
d 2 y
(d) 2
dx
dy
= y + 3 > 0 and
dx
y (log 2) is equal to
67. If
(a) 5
(c) -2
-1
y (0) = 2,
then
(b) 13
(d) 7
68. Let R be the set of real numbers.

Statement I A = {( x , y ) R R : y - x is an
integer} is an equivalence relation on R.
Statement II B = {( x , y ) R R : x = ay for
some rational number a} is an
equivalence relation on R.
Statement I
Statement I
69. The value of
18
p
log 2
8
(c) log2
(a)
log (1 + x )
dx is
1 + x2
p
log 2
2
(d) p log2
(b)
70. Let a , b be real and z be a complex

number. If z2 + az + b = 0 has two distinct
roots on the line Re ( z) = 1, then it is
necessary that
(a) b (-1, 0)
(c) b (1, )
(b)|b| = 1
(d) b (0, 1)

71. Consider 5 independent Bernoullis trials
each with probability of success p. If the
probability of atleast one failure is greater
31
, then p lies in the
than or equal to
32
interval
3 11
(a) ,
4 12
11
(c) , 1
12
1
(b) 0,
2
1 3
(d) ,
2 4
72. A man saves ` 200 in each of the first three

months of his service. In each of the
subsequent months, his saving increases
by ` 40 more than the saving of
immediately previous month. His total
saving from the start of service will be
`11040 after
(a) 19 months
(c) 21 months
(b) 20 months
(d) 18 months
73. The domain of the function

f( x ) =
1
is
|x| - x
(a) (0, )
(c) (-, ) - {0}
(b) (-, 0)
(d) (-, )
(b)
2
5
(c)
5
3
(d)
2
3
75. If a = 1 (3 $i + k$ )
10
1
and b = (2 i$ + 3 $j - 6 k$ ), then the value of
7
(2 a - b) [( a b) ( a + 2 b)] is
(a) -3
(c) 3
(b) 5
(d) -5
76. Equation of the ellipse whose axes are the

axes of coordinates and which passes
through the point ( -3, 1) and has
2
eccentricity
is
5
(a) 5 x2 + 3 y2 - 48 = 0
2
(b) 3 x + 5 y - 15 = 0
(c) 5 x2 + 3 y2 - 32 = 0
(d) 3 x2 + 5 y2 - 32 = 0
equipment and V (t) be the value after it

has been used for t years. The value V(t)
depreciates at a rate given by differential
dV (t)
equation
= - k (T - t), where k > 0
dt
is a constant and T is the total life in years
of the equipment. Then, the scrap value
V (T ) of the equipment is
(a) I -
k (T - t )2
2
1
(d) T 2 k
kT 2
2
(b) I -
(c) e - kT
78. The vectors a and b are not perpendicular

and c and d are two vectors satisfying
b c = b d and a d = 0. Then, the
vector d is equal to
a c
(a) c +
b
a b
bc
(b) b +
c
a b
a c
(c) c -
b
a b
bc
(d) b -
c
a b
two circles x 2 + y 2 = ax and

x + y = c2 ( c > 0) touch each other, if
2
the angle between the line

y -1 z - 3
and the plane
x=
=
2
l
5
x + 2 y + 3 z = 4 is cos-1
, then l
14
equals
3
2
77. Let I be the purchase value of an
79. The
74. If
(a)
87
(a)|a| = c
(c)|a| = 2c
(b) a = 2c
(d) 2|a| = c
80. If C and D are two events such that C D

and P( D) 0, then the correct statement
among the following is
(a) P (C| D) P (C )
P(D)
(c) P (C| D) =
P(C )
(b) P (C|D) < P (C )

(d) P (C|D) = P(C )
81. The number of values of k for which the

linear
equations
4 x + ky + 2 z = 0,
and
kx + 4 y + z = 0
2x + 2y + z = 0
possess a non-zero solution is
(a) 2
(b) 1
(c) zero
(d) 3
82. Consider the following statements

P : Suman is brilliant.
Q : Suman is rich.
R : Suman is honest.
The negative of the statement. Suman is

brilliant and dishonest if and only if
Suman is rich can be expressed as
(a) ~[Q ( PL ~ R )]
(c) ~(P ~ R ) Q
(b) ~ Q P ^ R
(d) ~ P (Q ~ R )

Statement I
83. The shortest distance between line

2
y - x = 1 and curve x = y is
(a)
3 2
8
(b)
8
3 2
(c)
4
3
(d)
3
4
84. If the mean deviation about the median of
87. If w( 1) is a cube root of unity and

(1 + w)7 = A + Bw. Then, ( A, B) equals
the numbers a, 2 a, ... , 50 a is 50, then | a|

equals
(a) 3
(b) 4
(c) 5
(d) 2
(a) (1, 1)
(c) (-1, 1)
(b) (1, 0)
(d) (0, 1)
88. The values of p and q for which the
85. Statement I The point A (1, 0, 7) is the
function
mirror image of the point B(1, 6, 3) in the

x y -1 z - 2
line =
=
.
1
2
3
sin ( p + 1) x + sin x , x < 0

x
f( x ) =
q,
x =0
2
x+x - x
, x >0
x3 /2
x y -1 z - 2
=
=
1
2
3
bisects the line segment joining A (1, 0 , 7)
and B(1, 6, 3).
Statement II The line

Statement I
Statement I
is continuous for all x in R, are

5
1
3
1
(a) p = , q =
(b) p = - , q =
2
2
2
2
1
3
1
3
(d) p = , q = (c) p = , q =
2
2
2
2
89. The area of the region enclosed by the

curves y = x , x = e, y =
X-axis is
86. Let A and B be two symmetric matrices of

are
Statement II AB is symmetric matrix, if

matrix multiplication of A with B is
commutative.
3
sq units
2
1
(d) sq unit
2
(a) 1 sq unit
order 3.
Statement I A ( BA) and ( AB)A
symmetric matrices.
1
and the positive
x
(c)
(b)
5
sq units
2
90. For x 0, 5 p , define f ( x ) = t sin t dt.

0
x
Then, f has

Statement I
(a)
(b)
(c)
(d)
local minimum at p and 2p

local minimum at p and local maximum at 2p
local maximum at p and local minimum at 2p
local maximum at p and 2p
Answers
1.
11.
21.
31.
41.
51.
61.
71.
81.
(a)
(a)
(d)
(b)
(a)
(d)
(b)
(b)
(a)
2.
12.
22.
32.
42.
52.
62.
72.
82.
(a)
(a)
(a)
(c)
(c)
(d)
(d)
(c)
(a)
3.
13.
23.
33.
43.
53.
63.
73.
83.
(b)
(d)
(b)
(a)
(d)
(c)
(b)
(b)
(a)
4.
14.
24.
34.
44.
54.
64.
74.
84.
(c)
(c)
(a)
(d)
(a)
(d)
(d)
(d)
(b)
5.
15.
25.
35.
45.
55.
65.
75.
85.
(c)
(c)
(b)
(c)
(c)
(d)
(a)
(d)
(a)
6.
16.
26.
36.
46.
56.
66.
76.
86.
(a)
(c)
(c)
(b)
(d)
(a)
(c)
(d)
(a)
7.
17.
27.
37.
47.
57.
67.
77.
87.
(c)
(b)
(c)
(a)
(c)
(b)
(d)
(a)
(a)
8.
18.
28.
38.
48.
58.
68.
78.
88.
(d)
(a)
(a)
(c)
(c)
(d)
(b)
(c)
(b)
9.
19.
29.
39.
49.
59.
69.
79.
89.
(c)
(a)
(b)
(d)
(c)
(a)
(d)
(a)
(b)
10.
20.
30.
40.
50.
60.
70.
80.
90.
(a)
(b)
(c)
(a)
(a)
(a,c)
(c)
(a)
(c)
Solutions
Physics
5. The diagram is given below vertical axis
1. Given wave is y ( x, t ) = e
-( ax 2 + bt 2 + 2 ab xt )
= e -(
ax +
Disc
b t )2
x
It is a function of type y = f(wt + kx) = f t -
v
R Insect
Diameter
where, v is the wave velocity.

\ y ( x, t ) represents wave travelling along - x
direction.
w
b
b
.
Speed of wave = =
=
k
a
a
2. Given that, mean scale reading (MSR)= 0
Clearly, as the insect moves along the diameter of

the disc, MI first decreases, then increases. As
firstly it approaches point O and secondly it
recedes point O.
By conservation of angular momentum, angular
speed first increases and then decreases.
(Q L = Iw)
and circular scale reading (CSR ) = 52

Diameter of wire,
d = MSR + CSR LC = 0 + 52
1
MR 2 + mx2
2
which is the total moment of inertia of the system.
where, m = mass of insect
and x = distance of insect from centre.
MI =
1
100
= 0.52 mm = 0.052 cm
3. For the motion of the block,
6. Let x1 = A sin(wt + f 1) and x2 = A sin (wt + f 2 )

The resultant wave giving the separation is
x2 - x1 = A[sin(wt + f 2 ) - sin (wt - f 1)]
2 wt + f2 - f1 f2 - f1
= 2 A cos
sin 2
2
R
m
T
T
m
(as, sinC - sin D = 2 cos
mg - T = ma
For the rotation of the pulley,
t = FR = Ia t =
(i)
1
mR 2 a
2
(Qfor the pully, I =
(ii)
mR 2
)
2
As string does not slip on the pulley.

(iii)
a = Ra
On solving Eqs. (i), (ii) and (iii),
2g
a=
3
As, the work done is stored as the surface energy.
4. Work done = Change in surface energy
W = 2T 4p
(R 22
R12 )
2
= 2 0.03 4p [(5) - (3)2 ] 10-4 J

= 0.4p mJ
C+ D C-D
)
sin
2
2
The resultant motion can be treated as a simple

f - f1
harmonic motion with amplitude 2 Asin 2
.
2
Given, maximum distance between the particles
= X0 + A
\ Amplitude of resultant SHM
= X0 + A - X0 = A
f2 - f1
\
2 A sin
= A
2
sin
f2 - f1 1
=
2 2
f2 - f1 p
=
2
6
p
f2 - f1 =
2

7. Let gravitation field is zero at P as shown in figure.
A
rx
Current,
Gm G(4m)
=
x2
(r - x)2
2
(Qfield at O at P)
4 x = ( r - x)
(q cos wt )2
1
L (wq 0 sin wt )2 = 0
2C
2
1
But
w=
tanwt = 1
LC
p
p
p
wt =
t =
=
LC
4
4w 4
r
3
Gm G (4m)
Vp = x
r- x
3Gm 6Gm
9Gm
==r
r
r
2x = r - x x =
12. / As refractive index for z > 0 and z 0 is

different xy-plane should be boundary between
two media.
8. At any instant,
T cos q = mg
T sinq = Fe =
(i)
kq 2
= mg tanq
x2
mg x 2
q2 =
x
k 2l
mg 3
q2 =
x
2 kl
1/ 2
Az
1
cos i =
=
2
2
2 2
A
A
A
+
+
y
z
x
\
Q tanq x
2l
(iii)
On differentiating with respect to t, we get

dq 3mg 2 dx
2q
x
=
2 kl
dt
dt
mg 3
x
2
2 kl
Angle of incidence,
kq 2
, where q = charge (ii)
x2
From Eqs. (i) and (ii),
Given,
q = q 0 cos wt
dq
i =
= - w q 0 sin wt
dt
2
1 2 q
Li =
2
2C
11. As initially charge is maximum.

\
4m
B
dq 3mg 2
=
x v
2 kl
dt
1/ 2
mg 3
Q q = 2 kl x , from Eq. (iii)
vx1/ 2 = constant
v x- 1/ 2
i = 60
3
sin i m 2
From Snells law,
=
=
sin r m1
2
sin 60
3
=
sin r
2
3 2
sinr =
r = 45
32
13. Consider the wire to be made up of large number

of thin wires of infinite length. Consider such wire of
thickness dl subtending an angle d q at the centre.
dq
Current through this wire, dl =
I,
p
\ Magnetic field at centre due to this portion,
dB sin
d
9. Induced emf
e = BH lv = 5.0 10-5 2 150
.
(Q axial is cutting the flux lines)
-3
= 015
. 10 V = 015
. mV
6. 25 v
-1/ 2
dB
dv = - 2.5 dt
0
- 2.5 [t ]0t = [2 v1/ 2 ]06. 25
t = 2s
dB cos
dB
m l
m 2dl
dB = 0
= 02 d q
4p R
2p R
dv
= - 2.5 v
dt
dv
= - 2.5dt
v
10. Given that,
Qdl = Idq
Net magnetic field at the centre,

p/ 2
m0 I
B=
dBcos q =
-p/ 2
2p2R
(QdBsinq due to all the elementary part of
conductor will be cancelled out by one another)
p/ 2
m0 I
- p / 2 cos qd q = p 2 R
Loss of kinetic energy
= Gain of internal energy of gas

1
1
m R
mv 2 = nC V DT
mv 2 =
DT
2
2
M g -1
2
Mv (g - 1)
DT =
K
2R
\ By conservation of linear momentum,

Mv1 = (M + m)v 2
Mw1 A1 = (M + m) w2 A2
M w2 A2
=
M + m w1 A1
(Q v = rw)
1/ 4
(Q A1v1 = A2 v 2 )
S
Now,
(Q A = 4pD2 )
=
1/ 4
2 10 0.2
1 +
(0.4)2
Vc = E (1 - e - t / RC )
120 = 200 (1 - e - t / RC )
2
t = RC ln 2.5
5
t
t
=
R=
C In 2.5 2.303C log 2.5
8 10-3
e - t / RC =
= 2.7 106 W
3.6 10-3 m
(QC = 2mF = 2 10-6 F )
17. Both the statements are true but there is no relation

between these two.
18. For adiabatic process i.e., no heat change,

F
F
F
F
n kT + n kT + n kT = (n + n2 + n3 ) kT
2 1 1 2 2 2 2 3 3 2 1
n T + n2T2 + n3T3
T = 11
n1 + n2 + n3
21. The efficiency is given by h1 = 1 -
FR
= 4t - t 2
I
where, R = radius of the pully

and
I = moment of inertia of pully
T2
T1
T
1
= 1- 2
T1
6
T2 5
=
T1 6
T - 62
h2 = 1 - 2
T1
(i)
T - 62
1
= 1- 2
3
T1
(ii)
19. Given that the force F = 20t - 5t 2

a=
2t 3 t 4
q=
12
3
0
D1 = 1 + 2 gh

D2
v12
2 gh
1 + 2
v1
[from Eq. (i)]
A1 = 1 + 2 hg

A2
v12
D2 =
(i)
infinite, hence no current flows through it.
A 2
1
gh = v12 1 - 1
2
A2
D1
) dt
1
rgh = r (v 22 - v12 )
2
v 2
1
gh = v12 2 - 1
2
v1
w = 2t 2 -
20. Neon bulb is filled with gas, so its resistance is
16. From Bernoullis theorem,
0 dw = 0 (4t - t
q = angular displacement = 144 - 108 = 36 rad

q
36
=
<6
\ Number of rotations, n =
2p 2p
k
k
and w2 =
M+ m
M
A1
m+ M
On solving, we get
=
A2
M
But w1 =
When direction is reversed,

w = 0, i .e.,t = 0, 6s
Now,
d q = wdt
q
6 2
t3
0 d q = 0 2t - 3 dt
15. At mean position, Fnet = 0
dw
= 4t - t2
dt
While w = angular speed of the pully
14. As no heat is lost, therefore
i.e.,
91
On solving Eqs. (i) and (ii),

T1 = 372 K and T2 = 310 K

22. The resistance, R = rl = rl
A
V
where, r = resistivity and V = volume
DR
Dl
\
= 2 = + 02
. %
l
R
(QV = Al )
29. Number of undisintegrated atom after first lot of

time
1
2
N = N
3 0 3 0
Number of undisintegrated atom after second lot
of time
2
1
N2 = N0 - N0 = N0
3
3
N1 1 n
=
N2 2
N1 = N0 -
23. Both statements I and II are correct but

Statement II does not explain Statement I.
QAt denser surface, phase changes by p.
24. The mirror 1 + 1 = 1
u v f
n=1
\ t 2 - t 1 = one half life = 20 min
On differentiating with respect to time t,

1 du
1 dv
- 2
- 2
=0
u dt
v dt
But
30. Maximum kinetic energy of ejected electron
dv
v 2 du
= - 2
dt
u dt
Kmax = eV0 = h(n - n0 )
v
f
=
u u -f
dv
f du
= -

dt
u - f dt
2
(by making frequency doubled, Kmax can be

increased only cant be doubled until its work
function is zero)
02
.
15 = 1 ms -1
=
15
.
-2.8 - 02
25. The energy, DE = 13.6Z 2 12 - 12

n1
So, Statement 1 is wrong.
n2
1
1
= 13.6(3)2 2 - 2 = 108.8 eV
1
3
26. Electric field, E = - df = - 2 ar
(i)
dt
By Gausss theorem,
q
E (4pr 2 ) =
e0
= eV0 = h(2 n - n0 )
Kmax
= 2Kmax + hn0
> 2 Kmax n0 > 2 n0

\ Kmax
n = 2n
If
Chemistry
31.
5
HOCH2
4
(ii)
q -8 pe0 ar
=
4 3
V
pr
3
= - 6e0 a
Now, the charge density, r =
Rm
2
=p
\ Total area around fountain, A = pR m
2 H
HO
OH
at 2nd carbon OH group is present.

5
HOCH2
4
4
v
g2
28. As work done = 0

Change in internal energy, DU = mCDT
(Qfirst law, Q = DU + W and Q = m CDt )
8.4 kJ
b-D-ribose used in RNA;
v2
=
g
= 100 10-3 4184 (50 - 30)
27. Maximum range of water coming out of the

fountain,
q = - 8p e0 ar 3
OH
OH
HO
2 H
H
b-D-deoxyribose used in DNA

at 2nd carbon OH group is missing.
Thus, correct answer is (b)

32. Covalent character is favoured by Fajans rule
Moles of solute
Mass of solvent (in kg)
5.2 mol CH3OH
=
1 kg(= 1000 g) H2O
35. Molality =
(i) larger the charge on the ions,

(ii) smaller the size of cations,
(iii) larger the size of anions,
(iv) cation with 18-electron structure (e. g ., Cu+ ),
then larger the polarizing power and the covalent
character is favoured.
In all the given compounds, anion is same (Cl - ),
hence polarizing power is decided by size and
charge of cation.
Al 3+ with maximum charge and smallest size has
maximum polarizing power hence, AlCl 3 is
maximum covalent.
Thus, correct answer is (c).
33. (a) Thermal stability of the hydrides decrease as
n1(CH3OH) = 5.2
1000
n2 (H2O ) =
= 55.56
18
n1 + n2 = 5.20 + 55.56 = 60.76 mol
XCH 3OH = Mole fraction of CH3OH
n1
52
.
=
=
= 0.086
n1 + n2 6076
.
\
\
36. Count s -bond, lone pairs and unpaired electron or

count number of atoms directly attached, lone
pairs and unpaired electrons.
we go down the group in periodic table for

group 15 (N-family)
This is = 2, then sp
= 3, then sp2
BiH 3 < SbH 3 < AsH 3 < PH 3 < NH 3
= 4, then sp3
Least stable
O
N
Thus, only (a) is wrong.

+ 6H 3Br2 + 3H2O
OH group is the activating group and there is SE

at o and p - positions giving yellowish white
precipitate of 2,4,6-tribromophenol.
OH
Br
Br
+ 3Br2
+ 3HBr
Br
Thus, correct answer is (d).
O
O == N == O
+
NO +2 (II)
H
NH+4 (III)
N
+
H
s-bond
Lone pair
I.
II.
III.
2
4
Unpaired
electron
Total
3 (sp2)
2 ( sp)
4 ( sp3 )
Alternate solution
OH
(I)
Thus, correct answer is (b) sp2 , sp, sp3 .
34. Br 2 is formed by a redox reaction

5Br +
Thus, it is correct.
BrO 3
O
NO -3
O
N
= 5, then sp3d
= 6, then sp3d 2
Most stable
M-H 255
247
322
391
Bond-energy
kJ mol -1
(b) Due to absence of d-orbital, nitrogen cant
form dp - pp bond, thus it is correct.
(c) The NN bond (BE 160 kJ mol -1) is weaker
than PP bond (BE 209 kJ mol -1). Thus, it is
correct.
(d) N 2 O 4 can form two resonance structures
93
Count the sum of outermost shell electrons of all

the atoms and charge present at molecule.
Now, divide the sum by eight and get the
hybridisation. If sum is eight or less than eight
then it is divided by two.
5 + 3 6 + 1 5 + 18 + 1 24
I. NO -3
=
=
= 3(sp2 )
8
8
8
5 + 2 6 - 1 5 + 12 - 1 16
II. NO +2
=
=
= 2(sp)
8
8
8
5 + 4 1- 1 5 + 4 - 1 8
III. NH+4
=
= = 4(sp3 )
2
2
2
Thus, correct answer is (b) sp2 , sp, sp3 .

37. Depression in freezing point (DTf ) can be given as
DTf = i K f m.To solve this problem, we will have to
first calculate the value of DTf and i. Finally, put all
the given valued and calculated value in the
expression of
mass of solute
molar mass of solute mass of solvent
to calculate the mass of solute.
DTf = i K f
DTf = Freezing point of H2O freezing point of

ethylene glycol solution = 0 - (-6 ) = 6
-1
K f = 1.86 kg mol
w1 = mass of ethylene glycol in grams
w2 = mass of solvent (H2O) in grams = 4000 g
m1 = Molar mass of ethylene glycol = 62 g mol -1

i = vant Hoff factor = 1
(ethylene glycol being non-electrolyte)
DTf =
\ 6=
1000 K f w1(i )
m1 w2
1000 186
. w1 1
62 4000
w1 = 800 g
Thus, correct answer is (a).
Salt
formation
(b) Tollens
reagent
(c) Molisch
reagent
(d) Neutral
FeCl 3
No effect
No effect
No effect
No effect
Violet
colour
Buffcoloured
precipitate
No specific
colour
change
Thus, FeCl 3
can be used
to
make
distinction
40. Cannizzaros reaction is given by aldehydes

(RCHO) lacking H at a-carbon or lacking a-carbon
(as in HCHO). With NaOH, there is formation of
acid salt (RCOO ) by oxidation and alcohol
(RCH2OH) by reduction.
Cl
|
2Cl C CHO + NaOH
|
Cl
C
Cl
||
Cl C CONa + Cl C CH2OH
+ Pressure ( p )
Cl
Cl
By oxidation
2H+ (aq ) + 2e - H2 (g )
41. Oxides when disolved in water form hydroxides.
0.0591
log Q
n
0.0591
=0log Q
2
0
Ered = Ered
-
Na 2O + H2O 2NaOH
MgO + H2O Mg(OH)2
Al 2O 3 + 3H2O 2 Al(OH)3
pH2
[H + ]
Ered
1 atm
2.0 M
0.25
+ ve
(b)
1 atm
1.0 M
1.0
(c)
2 atm
1.0 M
2.0
-ve
0.50
By reduction 2,2,2,
trichloroethanol
Reaction quotient = Q = pH 2 [H+ ]2 , n = 2
2.0 M
Conclusion
Half-cell reaction is
2 atm
Benzoic
acid
Phenol
(a) Aqueous Salt

NaOH
formation
Cl
H+ ( xM) | Pt(H2 )
(d)
Reagent
a -carbon without H
38. Reduction hydrogen half-cell is
(a)
39.
+ ve
Smaller the size of cation, larger the charge,

greater the polarizing power of cation, hence
greater the covalent character, hence smaller the
basic nature.
General
Oxides
Basic
Decreases in a period
0
Ered
= 0.00 V for standard hydrogen electrode
If Q > 1, then Ered = - ve.

Increases in a group
Charge Al 3+ > Mg 2+ > Na + = K+

Size Al 3+ < Mg 2+ < Na + < K+
Polarising power Al
3+
> Mg
2+
> Na
45.
+
>K
Basic nature of oxides

Al 2O 3 < MgO < Na 2O < K 2O
42. Energy values are always additive.
[Cr(NH3 )6 ]
14243
Cl
{3
3 6
Coordinate Ionisable
sphere
3+
j[Cr(NH ) ]
AgNO 3
[Cr(NH3 )6 ]3+ + 3Cl
95
+ 3Cl -
AgCl
White precipitate
Cr(24) [Ar] 3d 5 4s1

Cr 3+ [Ar] 3d 3 4s 0
4p
[Ar]
Cr 3+
[Ar]
[Cr(NH3 )6 ]3+
E2
Etotal = E1 + E2
hc hc hc
=
+
l
l1
l2
\
4s
3d
E1
d 2sp3
Indicates lone-pair of NH3 donated to Cr
1
1
1
,
=
+
l l1 l 2
1
1
1
=
+
355 680 l 2
l 2 = 742 .77 nm 743 nm
43. (a) S2 molecule is paramagnetic due to unpaired

electrons in MO and is blue-coloured
compound, thus true.
(b) The vapour at 200C consists mostly of S8
rings, thus correct.
(c) At 600C, the gas mainly consists of S2
molecules, thus correct.
(d) Oxidation states of sulphur are
-2
0
in
S8
+2
in
S2O 2
3
+4
in
SO 2
in
(a) d 2 sp3 -hybridization,

octahedral.
Thus,
correct.
(b) There are three unpaired electrons, hence
paramagnetic. Thus, correct.
(c) d 2 sp3 -inner orbital complex, thus incorrect.
(d) Due to ionizable Cl - ions, white precipitate with
AgNO 3 , thus correct.
Therefore, (c) is wrong.
46. IF7
5s2
In ground state
5s1
in SO 3
+6
Thus, incorrect. (Valency cannot be less than 4)
5p3
= 38.296 J mol K
Thus, correct option is (a).
44. Entropy change for n moles of isothermal
1 1
Inclined at 72
with one other
3
Seven sp3 d hybrid orbitals
forming -bonds with F-atoms,
Hence, correct option is (d).

expansion of an ideal gas from volume V1 to volume
V2 is
V
DS = 2.303 nR log 2
V1
100
= 2.303 2 8.3143 log
10
5d 3
sp 3d3 hybridization in excited state
H2 S
5d 0
5p5
I (53)
90
At 90 with
ABCDE plane
F
F
I 72
F
F
Pentagonal-bipyramidal structure

47. For every 10C rise of temperature, rate is doubled.
Thus, temperature coefficient of the reaction = 2
When temperature is increased by 50, rate
becomes
= 2( 50 / 10 )
= 2 5 times = 32 times
48. Electron-withdrawing group (-I effect) stabilizes

the anion, and thus increases acidic nature.
Thus, (c), (d) > (a), (b) acidic
C(s) being solid is not considered

Total pressure of CO 2 and CO gases.
pCO 2 + pCO = ptotal
0.5 - p + 2 p = 0.8, p = 0.3 atm
\
pCO 2 = 0.5 - 0.3 = 02
. atm
pCO = 2 p = 0.6 atm
p2
0.6 0.6
= 18
. atm
K p = CO =
02
.
pCO 2
51. (a) There is a gradual decrease in the radii of the
Further the electron withdrawing group from the

COOH group, its effect in increasing acid
strength decreases, thus (c) with Cl at a-position is
stronger than (d) with Cl at g-position.
CH3COOH
K a = 175
. 10-5
HCOOH
K a = 17.7 10-5
(c) Due to lanthanide contraction, Zr and Hf; Nb and

Ta, Mo and W have the same size and thus similar
properties and thus seperation is not easy, thus
true.
CH3CH2 C HCO 2 H K a = 1.4 10-3

|
Cl
(d) Formation of +4 state requires very high

energy, thus incorrect.
C H2CH2CH2CO 2 H K a = 2 . 96 10-5
|
Cl
Thus, option (d) is wrong.
52. van der Waals, constant a is due to force of
49. Tautomerism
is
due
to
spontaneous
interconversion of two isomeric forms with different
functional groups into one other. The term
tautomer means constitutional isomers that
undergo such rapid interconversion that cant be
independently isolated.
OH
lanthanoids with increasing atomic number

a case of lanthanoids contraction, thus
true.
(b) Ionisation potential for the formation of Lu3+ is
comparatively low, hence +3 state is
favourable, thus true.
attraction and b due to finite size of molecules.

Thus, greater the value a and smaller the value of
b, larger the liquefaction.
Thus, a (Cl 2 ) > a (C 2 H6 ) and b (Cl 2 ) < b (C 2 H6 )
Thus, option (d) is correct.
53. [NiCl 4 ]2 ; oxidation number of Ni, x - 4 = - 2

\
CH
x=+2
Ni(28) [Ar] 3 d 8 , 4s 2
H
Keto
3d 8
Enol
Ni 2+[Ar]
O
Keto
sp 3
Enol in phenol
Thus, (c) 2-pentanone and (d) phenol exhibit

tautomerism
4s 0
[NiCl4]
50. K p depends upon the partial pressure of reactants

and products so first calculate their partial
pressure and then, calculate K p
CO 2 ( g ) + C (s)
Initial
0.5 atm
At equilibrium (0.5 - p)
sp 3 sp 3 sp 3 sp 3
j2CO(g )
2 p atm
This is a case of heterogeneous equilibrium.
4p
Four sp 3 hybrid orbitals

3
sp -hybrid orbitals, tetrahedral

Cl - is a weak ligand and thus unpaired electrons
are not paired. Lone pairs from 4 Cl - are
accomodated in four sp3 hybrid orbitals.
57. Alkenes give carbonyl compounds on ozonolysis

O / Zn /H O
3
2
Alkene
N =unpaired electron = 2, paramagnetic

Magnetic moment (spin only)
= N (N + 2 ) BM =
Thus, (c) option is correct.
Vinyl group
To determine alkene, place carbonyl compounds

with their O-atom face to face. Replace O-atom by a
double bond
R1
C == O O == CH2
(B )
(A )
R2
atoms (or ratio) of

elements A and B as a
chemical
formula
represents the number of
atoms
of
different
elements in a compound.
Derive the formula
O-atoms face to face
1
Number of atoms ( A) per unit cell = 8 = 1
8
1 5
Number of atoms (B) per unit cell = (6 - 1) =
2 2
(one atom B is missing)
Replace

O -atom by(==) bond
||
4f 7
CH3 C Cl
[Xe]54
= CH C| Cl
3
||
CH3 C OC 2 H5 + Cl
CH3 C Cl
OC2 H5
All the electrons in 4f-orbital are unpaired, hence

stable. Thus, Gd (64) has EC as
[Xe]54 4f 7 5d 1 6s 2
This is by SN reaction. Cl - is a better leaving group

than C 2H5O and the ethyl ethanoate is formed.
59.
A x By
xA y + + yB x -
After dissociation, (1 - a)
xa
ya
i = n ( A x By ) + n ( A y + ) + n (B x - )
2p 1
Ground state
2s 1
C 2H 5O -
6s 2
Instead of [Xe]54 4f 8 6s 2 .
C == CH2
R2
nucleophilic substitution reaction with ethanoyl

chloride. Therefore, write the SN reaction and find out
the final product.
O
O
55. Gd (64)
5d 1
R1
58. Ethoxide ion is a better nucleophile and gives
Thus, formula is A1B5 / 2 = A2 B5

Therefor, correct option is (d).
1s 2 2s 2
C == O
R1
HCHO + other carbonyl compound
R
(A)
2
8 = 2.828 BM
54. Calculate the number of
56. B 5
97
= 1 - a + x a + ya
2p 2
Excited state
Fourth lone pair is accommodated

in this empty orbital
Maximum covalency = 4
Due to absence of 2d-orbital, maximum

covalency is four. Thus, BF63- is not formed,
Thus, option (a) is not formed.
BH4 (BH3 + H ),
B(OH)4 (B(OH)3 + OH ) and BO 2 are formed.
= 1 + a ( x + y - 1)
i -1
a=
( x + y - 1)
60. All aldehydes including reducing sugar (as glucose,

fructose)
give
(with Tollens reagent)
Silver-mirror
test
D
RCHO + 2[Ag(NH3 )2 ]+ + 3OH
RCOO + 2Ag + 4NH3 + 2H2O

Silver mirror
( R == H, CH3 )
Thus, (a) acetaldehyde and (c) formaldehyde give
silver-mirror test.
Mathematics
1 - cos 2 ( x - 2 )
( x - 2)
64. lim
x 2
61. Here, L1 : y - x = 0 and L2 : 2 x + y = 0

L3 : y + 2 = 0 shown as
Y
L1
X
L3
Q
2
R
(2, 2)
L2
Y
Angle bisector
|PO| =
y = 2
(1, 2)
2 sin2 ( x - 2 )
2 |sin ( x - 2 )|
=
( x - 2)
( x - 2)
lim
2 |sin ( x - 2 )|
( x - 2)
x 2
x 2
RHL at x = 2
2 |sin (2 + h - 2 )|
lim
(2 + h) - 2
h 0
O (0, 0)
P
y=x
lim
= lim
h 0
y = 2 x
LHL at x = 2
2 |sin (2 - h - 2 )|
lim
(2 - h) - 2
h 0
4+ 4 =2 2
|OQ| = 1 + 4 = 5
Since, OR is angle bisector.
OP PR
PR 2 2
=
\
=
OQ RQ
RQ
5
= lim
2 |sin (- h)|
-h
= lim
2 sin h
=- 2
-h
h 0
(using sine rule)
h 0
Statement I is true.
But, it does not divide the triangle in two similar
triangles.
62. A = sin2 x + cos 4 x

A = 1 - cos 2 x + cos 4 x
1 3
= cos 4 x - cos 2 x + +
4 4
2
1
3
2
= cos x - +
2
4
\ Limit does not exist.
65. We know that, the number of ways of distributing n
dx dy
=
dy dx
66. Here,
d2x
dy
= -
dx
dy2
3 6
63. Here, (1 - x - x + x ) = {(1 - x) - x (1 - x)}

6
dy
= -
dx
2 6
= (1 - x) (1 - x )
6
+ s
r = 0 s= 0
+ 2s
6C r 6C s xr
[Q r + 2 s = 7 ]
i .e., (s = 1, r = 5) or (s = 2, r = 3) or (s = 3, r = 1)
{(- 1)
3+ 2
C 5 C1} + {(- 1)
C3 C2}
1+ 3
+ {(- 1)
= (36) - (20) (15) + 6(20)
= 36 - 300 + 120 = - 144
C1 C 3 }
-2
d dy dx

dy dx dx
d dy dx

dx dx dy
-1
dx
\ Coefficient of x is
6
-2
d dy

dy dx
67. Here, dy = y + 3 > 0 and y(0) = 2
5+1
-2
d 2 y dy

dx2 dx
-3
d 2 y
dy
= - 2
dx
dx
dy
= -
dx
= (- 1)r 6C r xr (- 1) s 6C s x2 s
s= 0
r = 0
6
-2
dy
= -
dx
= {(1 - x) (1 - x2 )}6
= (- 1)r
-1
Differentiating both sides w.r.t. y, we get
1
1
Since, 0 cos 2 x -
2
4
3
A1
\
4
[Q|sin(- h)|= sin h]
identical objects among r persons such that each

person gets atleast one object is same as the
number of ways of selecting (r - 1) places out of
(n - 1) different places, i.e., n - 1C r - 1.
\ Statement II is false.
2 |sin h|
2 sin h
= 2
= lim
h
h
h 0
Since,
dy
y + 3 = dx
log| y + 3| = x + C
y(0) = 2
loge |2 + 3| = 0 + C
C = loge 5
loge | y + 3| = x + loge 5
When
When
x = loge 2
loge | y + 3| = loge 2 + loge 5 = loge 10
y + 3 = 10
y=7
x = 1 = tanq
p
q=
4
p / 4 8log [1 + tan q]
I=
sec 2 qdq
0
1 + tan2 q
68. / A relation R on set X (i.e., R X X) is said to be

(i) reflexive, if xR x for all x X.
(ii) symmetric, if xR y y R x, where x, y X.
(iii) transitive if xRy, yRz xRz, where
x, y, z X.
I=8
Using
p/ 4
0
log (1 + tan q) dq
(i)
0 f( x) dx = 0 f(a - x) dx, we get

p
log 1 + tan - q dq
p/ 4
1 - tan q
log 1 +
dq
=8
0
1 + tan q
p/ 4
2
dq
(ii)
=8
log
0
1 + tan q
I=8
Statement I
A = {( x, y) R R : y - x is an integer}
(a) Reflexive
( x, x) A: ( x - x) is an integer.
i.e., True
\ Reflexive
(b) Symmetric ( x, y) A : ( y - x) is an integer.
99
p/ 4
- ( y - x) is an integer.
( x - y) is an integer.
Adding Eqs. (i) and (ii), we get

p/ 4
2
dq
log {1 + tan q} + log
2I = 8
0
1 + tan q
( y, x) A
\ Symmetric
( y - x) + ( z - y) is an integer.
( z - x) is an integer.
( x, z) A
\ Transitive
So, relation A is an equivalence relation on R.
Statement II
B = {( x, y) R R : x = ay for some rational
number a}
(a) Reflexive Let x R, then
x=1x
( x, x) B
( x, x) B, " x R
B is reflexive.
(b) B is not symmetric. Note that (0, 1) B but
(1, 0) = B
As 0 = 0 1 and 1 x 0 for any rational number
x.
B is not an equivalence relation on R.
69. I =
1 8 log
0
Put
When
\
(1 + x)
(1 + x2 )
x=0
q=0
log 2 dq = 4 log 2(q)p0 / 4
70. Let z = x + iy, given Re( z) = 1

\ x = 1 z = 1 + iy
Since, the complex roots are conjugate of each
other.
\ z = 1 + iy and 1 - iy are two roots of
z2 + az + b = 0
Product of roots = b
(1 + iy) (1 - iy) = b
\
b = 1 + y2 1
b (1, )
71. n = 5and r 0, where r denotes number of failure.

\
P( x = r ) = nC r pn - r q r
(using binomial distribution)
P ( x 1) = 1 - P ( x = 0)
= 1 - 5C 0 p5 q 0
31
32
31
1
1
=
=
32 32 (2 )5
1
1
\ p and p 0 p 0,
2
2
p5 1 -
72. / If first term of an AP is a, common difference is
dx
x = tan q
p/ 4
0
p
= 4 log 2 - 0 = p log2
4
(c) Transitive ( x, y) A and ( y, z) A

( y - x) is an integer and ( z - y) is an integer.
I=4
d and number of terms is n.
dx = sec 2 qdq
tan q = 0
Then, sum of n terms, S n =
n
[2 a + (n - 1)d ]
2
Let the time taken to save ` 11040 be (n + 3)

months.

= (2a - b) {1 (b) - (0) a + 2 (0) b - 2 (1) a }
[as a b = 0 and a a = b b = 1]
For first 3 months, he saves ` 200 each month.

\ In (n + 3) months
n
3 200 + {2(240) + (n - 1) 40} = 11040
2
n
600 + {40 (12 + n - 1)} = 11040
600 + 20n (n + 11) = 11040

2
30 + n + 11n = 552
n2 + 11n - 522 = 0
n2 + 29n - 18n - 522 = 0
n (n + 29) - 18 (n + 29) = 0
(n - 18) (n + 29) = 0
\ n = 18, neglecting n = - 29
Hence, total time = (n + 3) = 21months
1
73. y =
| x| - x
= (2a - b) (b - 2a )
= - (4|a|2 - 4 a b + |b|2 )
= - {4 - 0 + 1} = - 5
x2
y2
+ 2 =1
2
a
b
76. Given,
Y
(3, 1) P
X
For domain,| x| - x > 0
| x| > x
i .e., only possible, if x < 0.
\
x (- , 0)
x - x1 y - y1 z - z1
and
74. Angle between a line
=
=
a1
b1
c1
the plane a2 x + b2 y + c 2 z + d 2 = 0 is
a1a2 + b1b2 + c1c 2
sin q =
2
a1 + b12 + c12 a22 + b22 + c 22
sinq =
=
1 1 + 2 2 + l 3
12 + 2 2 + l2 12 + 2 2 + 32
5 + 3l
9 (l2 + 5) = 9l2 + 30l + 25
9 l2 + 45 = 9l2 + 30l + 25
2
30l = 20 l =
3
75. a = 1 (3 $i + k$ ) and b = 1 (2 $i + 3 $j - 6 k$ )
10
It passes through P(- 3, 1) and e =
9
1
+ 2 =1
a2
b
b2
3a2
2
b2
and e 2 = 1 - 2 = 1 - 2 b 2 =
5
5
a
a
Put in Eq. (i), we get
9
5
+
=1
a2
3a2
2
b2
and
= 1- 2
5
a
27 + 5
b2 3
= 1 and 2 =
5
3a2
a
= (2a - b) {(a b) a + (a b) 2b}

= (2a - b) {(a a ) b - (b a ) a
+ 2 (a b) b - 2 (b b) a }
a2 =
32
32
and b 2 =
3
5
\ Equation of ellipse
3 x2
5 y2
+
=1
32
32
3 x2 + 5 y2 = 32
d {V(t )}
= - k (T - t )
dt
77. Given,
\
d {V(t )} = - k (T - t ) dt
On integrating both sides, we get
V(t ) = - k
(T - t )2
+C
2(-1)
k
(T - t )2 + C
2
V(t ) =
At t = 0, V(t ) = I
k
I = (T - 0)2 + C
2
k
C = I - T2
2
k
k
V(t ) = (T - t )2 + I - T 2
2
2
k
V(T ) = I - T 2
2
\ (2a - b) [(a b) (a + 2b)]
2
.
5
l + 5 14
5
14
3
sin q =
14
5 + 3l
3
=
2
14
l + 5 14
Given, cos q =
\
Now,
(i)
(ii)

a b 0, a d = 0
78. Given,
(i)
and b c = b d b (c - d) = 0
\
b|| (c - d) c - d = lb
Taking dot product with a.
d = c - lb
0 = a c - l (a b)
a c
l=
a b
d=c -
(a c )
b
(a b)
[using Eq. (i)]

(iii)
[using Eqs. (ii) and (iii)]
79. x2 + y2 - ax = 0 and x2 + y2 = c 2 touch each
(ii)
a1 x + b1 y + c1 z = 0
a2x + b2 y + c2 z = 0
and
a3x + b3 y + c3 z = 0
possess a non-zero solution,
a1 b1 c1
then a2 b2 c2 = 0.
a3 b3 c3
c
a/2
a/2
Since, equation has non-zero solution.
D=0
4 k 2
k 4 1 =0
2 2 1
\
Y
(i) Internally
c-
(i)
81. / The linear equations
(i) If circles touch internally.
P (C )
P (D)
From Eqs. (i) and (ii),

P (C )
C
P =
P (C )
D P (D)
other.
since, C D
\ P (C D) = P(C )
as, P (D) 1
1
\ P (D) 1
and P (C ) P(C )
P (D)
(ii)
a d = a c - la b
P (C D)
P (D)
80. As, P C =
101
a
a
a a
= c - = c = a, c > 0
2
2
2 2
\
|a| = c
(ii) If circles touches externally.
4 (4 - 2 ) - k (k - 2 ) + 2 (2 k - 8) = 0
8 - k 2 + 2 k + 4k - 16 = 0
k 2 - 6k + 8 = 0
(k - 2 ) (k - 4) = 0
k = 2, 4
\ Number of values of k is two.
82. Suman is brilliant and dishonest if and only if
Suman is rich, is expressed as (P ~ R ) Q

\ Negation of it will be
a/2
c
(0, 0)
~ [(P ~ R ) Q) = ~(Q (P ~ R )].

X
83. The shortest distance between y - x = 1

and x = y2 is along the common normal.
Y
Y
(ii) Externally
c+
1 Q
P (t 2, t)
a
a
a a
= c+ =
2
2
2 2
\ c = 0, i .e., not possible as c > 0

\ The circles should touch internally and
y=1+x
|a| = c.
Y
y2 = x

\ Tangent at P is parallel to
y= x+1
(i)
\ Slope of tangent at P (t 2 , t )
dy 1
1
=
=
dx 2 y ( t 2, t ) 2t
1
=1
2t
1
t =
2
1 1
P ,
4 2
(ii)
[using Eqs. (i) and (ii)]
3 2
8
84. Median of a, 2 a, 3a, 4a, K, 50a is

25a + 26a
= (25.5) a
2
50
| xi - Median|
i =1
N
1
{2|a| (0.5 + 15
. + 2.5 + K + 24.5)}
50
25
(25)
2500 = 2|a|
2
50 =
|a| = 4
85. / If two points are A (x1 , y1 , z1 ) and B(x 2, y2, z 3) ,

then the coordinates of the mid-point will be
x1 + x 2 , y1 + y2 , z1 + z 2
2
2
2
and if two lines with direction ratios a1 , b1 , c1
and
are
perpendicular,
then
a2, b2, c2
a1 a2 + b1 b2 + c1 c2 = 0.
Mid-point of AB is M (1, 3, 5).

A (1, 0, 7)
0 (1) + 6 (2 ) - 4 (3) = 12 - 12 = 0
\ Statement I is true.
AT = A and BT = B
Now, to check A (BA) is symmetric.

Consider [ A (BA)]T = (BA)T AT
= ( AT BT ) AT = ( AB) A = A (BA)
T
[ A (BA)] = A (BA)
A (BA) is symmetric.
Similarly, ( AB) A is symmetric.
\ Statement I is true. Also, Statement II is true, as
if A and B is symmetric.
( AB) are symmetric, iff ( AB = BA) i.e.,
AB commute.
87. (1 + w)7 = A + Bw, we know 1 + w + w2 = 0

\ 1 + w = - w2 (- w2 )7 = A + Bw
- w14 = A + Bw
- w2 = A + Bw (Q w14 = w12 w2 = w2 )
1 + w = A + Bw
On comparing, A = 1, B = 1
sin ( p + 1) x + sin x
, x<0
x
88. Here, f( x) = q
, x=0
2
x+ x - x
, x>0
x2
Since, f( x) is continuous for x R.
\ Continuous at x = 0.
RHL at x = 0
lim
x
1
y1 z2
2
3
B (1, 6, 3)
which lies on
as
(ii)
(1, 2, 3)
The two are perpendicular, if
Shortest distance =
(i)
and directions of straight line is
86. Since, A and B are symmetric matrix.
Shortest distance =|PQ|

1 1
- +1
4 2
3
=
=
4 2
1+ 1
MD (about median) =
\ Statement II is true.
Also, directions of AB is (1 - 1, 6 - 0, 3 - 7 )
i.e.,
(0, 6, - 4)
x y-1 z-2
=
=
1
2
3
1 3-1 5-2
=
=
1 = 1 = 1
1
2
3
h + h2 3
h2
h 0
= lim
h 0
h { h + 1 - 1}
h h
h+ 1-1
h + 1 + 1
= lim
h
h 0
h + 1 + 1
(h + 1) - 1
= lim
h 0 h { h + 1 + 1}
= lim
h 0
1
1
=
h+ 1+ 1 2
(i)

LHL at x = 0,
sin ( p + 1) (- h) + sin (- h)
lim
-h
h 0
= lim
h 0
sin ( p + 1) h sin h
+
h
h
= ( p + 1) + 1 = ( p + 2 )
(ii)
f(0) = q
(iii)
From Eqs. (i), (ii) and (iii),

1
=q = p+ 2
2
3
1
p= - ,q =
\
2
2
\ Area = Area of DODA + Area of DABCD

e 1
1
1
= (1 1) +
dx = + (log| x|)1e
1 x
2
2
1
= + {log|e| - log 1}
(Qlog|e|= 1)
2
1
3
= + 1 = sq units
2
2
90. / If f( x ) and y(x ) are defined on [a, b] and

differentiable for every x and f(t) is continuous,
then
d y (x )
f (t) dt
dx f ( x )
89. Given, y = x, x = e and y = 1, x 0

x
Since, y = x and x 0
= f [y( x )]
Here,
y0
\ Area to be calculated in I quadrant shown as
\
Y
y=x
D (1, 0) C (e, 0)
x=e
y = 1/x
X
5p
t sin t dt , where x 0,
f ( x) =
x sin x = 0
sin x = 0
x = p, 2 p
f ( x) =
A
O
f ( x) =
d
d
y( x ) - f [f(x )]
f(x )
dx
dx
(i)
f ( x) = { x sin x - 0}
(using Newton-Leibnitz formula)
103
x cos x +
1
sin x
2 x
At x = p, f (p ) = - p < 0
\ Local maximum at x = p.
at x = 2p, f (2 p ) = 2 p > 0
\ Local minimum at x = 2p.

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Solved Paper 2011

All India Engineering Entrance Examination

This test consists of 90 questions.

(b) standing wave of frequency b

2. A screw gauge gives the following

The diameter of wire from the above data

3. A mass m hangs with the help of a string

4. Work done in increasing the size of a soap

AIEEE Solved Paper 2011

particles are executing simple

7. Two bodies of masses m and 4 m are placed

8. Two identical charged spheres suspended

9. A boat is moving due east in a region where

10. An object, moving with a speed of

11. A fully charged capacitor C with initial

charge q0 is connected to a coil of self

12. Let the xz-plane be the boundary

13. A current I flows in an infinitely long

14. A thermally insulated vessel contains an

82 JEE Main Solved Papers

18. Three perfect gases at absolute temperatures

spring, executes SHM with amplitude

T1, T2 and T3 are mixed. The masses of

n1T1 + n2T2 + n3T3

n12T12 + n22T22 + n32T32

16. Water is flowing continuously from a

(b) 9.6 10-3 m

17. This question has Statement I and

n1T12 + n2T22 + n3T32

19. A pulley of radius 2 m is rotated about its axis

by a force F = (20t - 5t2 ) N (where, t is

20. A resistor R and 2 mF capacitor in series is

(b) 2.7 106 W

(b) 330 K and 268 K

22. If a wire is stretched to make it 0.1% longer, its

AIEEE Solved Paper 2011

23. This question has a paragraph followed

27. A water fountain on the ground sprinkles

by two statements, Statement I and

water all around it. If the speed of water

(a) Statement I is true, Statement II is true;

24. A car is fitted with a convex side-view

required for the electron

26. The electrostatic potential inside a

28. 100g of water is heated from 30C to 50C.

29. The half life of a radioactive substance is

30. This question has Statement I and

84 JEE Main Solved Papers

32. Among the following, the maximum

33. Which of the following statements is

34. Phenol is heated with a solution of

35. A 5.2 molal aqueous solution of methyl

36. The hybridization of orbitals of N atom

(c) sp, sp3 , sp2

(d) sp2 , sp3 , sp

37. Ethylene glycol is used as an antifreeze

half-cell will be negative if

1 atm and [H+ ] = 2.0 M

39. Which of the following reagents may be

(b) Tollens reagent

40. Trichloroacetaldehyde was subjected to

41. Which one of the following orders present

38. The reduction potential of hydrogen

(a) Al 2O 3 < MgO < Na 2O < K 2O