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Abstract
Biodiesel is double sided Sword. Due to depletion of fossil diesel, the Biodiesel have taken same position in the fossil fuel category.
Thats why now a day the world is taking step towards the biodiesel because the depletion of fossil diesel. Biodiesel is basically Fatty
Acid methyl ester based fuel, a long chain of triglycerides and the alcohol in the presence of catalyst forms ethyl esters and the
glycerol that process is known as Transesterification, if the free fatty acid content percentage in the oil is more than 2.5 % then the
process by which the oil is converted to ethyl esters is known as Esterification followed by Transesterification. In this study we mostly
concentrate on the physio chemical properties; The Physio chemical properties like Density, Kinematic Viscosity, Flash Point,
Cetane Number, are having statistical correlations with the Gross Calorific Value of Karanja Oil Methyl Ester (KOME). We have
also shown in the paper, the individual properties how much percent statistical correlation have with the gross calorific value, we
have calculated it by Least square Approximation of Linear Regression.
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Formula
C16H32O2
C18H36O2
C20H40O2
C18H34O2
C18H32O2
Structure
16:0
18:0
24:0
18:1
18:2
Weight in %
3.7 7.9
2.4 8.9
1.1 3.5
44.5 71.3
10.8 18.3
Graph1
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(Neat Biodiesel).
The below graph is showing how the flash point of Karanja oil
Methyl Ester blends increases as the percentage of fossil diesel
decreases or the percentage of biodiesel increases in the
blends.
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Graph4
Graph6
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Graph 8
Graph7
Graph 9
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4. CONCLUSIONS
4.1 Statistical Correlation between Density & Gross
Calorific Value:
The below given equation gives the statistical correlation
between the density & the gross calorific Value of Karanja Oil
Methyl Ester,
Gross Calorific Value (kJ/kg) = 95.5058 - 0.0661777x
Density (kg/m3)
.... (Equation 1)
There isastrong statistical correlation between Density & the
Gross Calorific Value because after the statistical analysis R2
shows the value 97.78% only, it means that the Density &
Gross Calorific Value have 97.78% Correlation between them.
This correlation we have shown the Calculated Gross Calorific
Value versus Measured Gross Calorific values on the graph.
Graph 11
Graph 10
4.2
Statistical
Correlation
between
Kinematic
Graph 12
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REFERENCES
[1]
[2]
[3]
[4]
Graph 13
[5]
K.
Shivaramakrishnan
and
P.
Ravikumar.
Determination of Cetane Number of Biodiesel and its
Influence on Physical Properties. Arpan Journals of
Engineering and Applied Sciences. 2012; 2: 205 211.
K. Anand, R.P. Sharma, Pramod S. Mehta. A
Comprehensive Approach for Estimating Thermo Physical Properties of Biodiesel Fuels. Applied
Thermal Engineering. 2011; 31: 235 242.
K.
Shivaramakrishnan
and
P.
Ravikumar.
Determination of Higher Heating Value of Biodiesels.
International Journal of Engineering Science and
Technology (IJEST). 2011; 3: (11) 7981 7987.
Avinash Kumar Agarwal, K. Rajamanoharan.
Experimental Investigations of Performance and
emissions of Karanja oil and Blends in a Single
Cylinder Agricultural Diesel Engines. Applied Energy.
2009; 86: 106 112.
National Renewable energy Laboratory (NREL)
Innovation for Our Energy Future. Biodiesel Handling
and Use Guide Fourth Edition. Revised January 2009;
NREL/TP 540 43672.
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