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Introduction
In the systems, containing strongly basic anion
exchanger and solution of some electrolytes, besides
anion exchange processes formation of solid metal
compounds can take place in the polymer phase. As
known, strongly basic cross-linked polymers do not
contain negatively charged or electron donor atoms in
their matrix and, theoretically, they cannot interact
with metal cations. However, in certain conditions, in
M2(SO4)3 solutions, where M is Fe3+, Al3+ or Cr3+, they
can interact with metal cations. The retention of cations
by these polymers takes place through the formation
in their phase of jarosite mineral-type compounds:
R4N[M3(OH)6(SO4)2] and H3O[M3(OH)6(SO4)2], where
R4N+ are functional groups of the polymer. Being
modified with metal compounds, strongly basic resins
become selective sorbents and catalysts. Recently it
was observed that in the systems, containing strongly
basic resins and solution of three-charged metallic
cations, besides anion exchange and formation of the
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CODE
FACTOR
X1
X2
40
50
X3
pH of Fe2(SO4)3 solution
1.7
1.9
X4
0.01
0.02
X5
X6
AV-17(Cl) mass, g
0.2
0.4
X7
X1
X2
X3
X4
X5
X6
X7
Y1
Y2
Y3
Y4
Y5
Y6
Y7
Y8
Y9
51.18
0.61
50.55
0.046
0.58
6.25
0.0102
0.005
0.018
0.029
47.88
0.076
47.79
0.051
1.42
7.075
0.0127
0.0104
35.37
0.0
35.37
0.075
3.68
7.0
0.0204
0.0102
0.029
11.26
0.0
11.26
0.022
1.86
7.175
0.0083
0.0026
0.0085
37.56
0.83
36.77
0.034
0.63
6.375
0.0102
0.0
0.0165
0.017
13.32
0.0
13.32
0.044
2.19
7.0
0.0165
0.0
20.89
1.047
19.84
0.032
1.87
7.075
0.0204
0.0
0.017
9.045
0.0
9.045
0.021
1.103
6.95
0.0083
0.005
0.0085
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Y5 = 1.66-0.46X2 +0.22X3+0.22X5-0.62X6-0.42X7.
bsig = 0,18;
(5)
(6)
(7)
(8)
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21.
Gutsanu, V., Schitco, C., Lisa, G., and Turta, C. Ultra dispersed
particles of Fe(III) compounds in the strongly basic
crosslinked ionic polymer precursors for new sorbents
and catalysts. Mater. Chem. Phys.130 (2011): 854 - 862.
Gutsanu, V., and Rosca, I. Process for selective removal of
cyanide, thiocyanate, cyanate ions from solutions. Pat.
MD 2746. BOPI, 4 (2005): 33.
Lurie, A.A. Sorbents and Chromatographic Carriers. Nauka,
Moscow.1972. (In Russian).
Marchenco Z. Photometrical Determination of Elements. Mir,
Moscow, 1972.
STAS 11581-83. Produse de legume, fructe i legume cu carne.
Determinarea coninutului de nitrii i nitrai. Aprobat de
Institutul Romn de Standartizare. 1983. 02.01, 4p (in
Romanian).
VasileGutsanu was born in Shendreni,
Moldova in 1944. In 1970 he was
graduated at Chisinau State University,
Chemistry
Faculty,
Departmentof
Physical Chemistry. In 1974 he was
awarded a PhD degree, and in 1993 the
degree of doctor habilitate and professor
in physical chemistry. Many years he
worked as researcher and a lecturer in the Institute of
Chemistry of Academy of Sciences, Agricultural University
and Technical University of Chisinau. Now he is working at
Moldova State University as a professor.Aria of expertise:
Sorption of substances by ion exchangers, metallicions
complexion with electron donor groups of cross-linked
ionic polymers, polymers modified with metallic compounds,
obtaining of nanoparticles of the metallic compounds in the
polymer phase, obtaining of new selective sorbents and
catalysts, Ecological Chemistry, water and gazes purification.
He is the author of eight books, the last being "Unusual
processes on ion exchangers (in Romanian) and "Secondary
processes on ion-exchanging polymers".
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