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Abstract
A self-lubricant Ni-based composite coating was fabricated
on the H13 steel substrate by laser cladding a mixture of
Ni-coated MoS2 particles and NiCrBSi particles using a CO2
laser. The microstructure, microhardness and wear
properties of the clad coating were investigated. The results
showed that the laser clad coating was composed of
sphere-like CrxSy particle, net-like eutectic of the compound
of sulfide of iron, and chromium, and dendritic -Ni solid
solution. A metallurgical bonding between the laser clad
coating and substrate was obtained. The micro-hardness of
the coating is 350~420 HV0.2. The friction coefficient of the
coating is 0.10~0.20 at room-temperature in air. The wear
mass loss of the coating is reduced to 17.4% of that of the
substrate in wear testing.
Keywords
Laser Cladding; Composite; Microstructure; Micro-hardness; Wear
Property
Introduction
Many tribological systems are required to work in
high-temperature, vacuum, strong radiant and
chemical-pollution aggressive environments. Under
these conditions, the presence of liquid lubricant is
inevitably contaminated. Self-lubricating metal matrix
composites combine both high wear resistance/
toughness of metal matrix and excellent lubricating
characteristics of lubricants, exhibiting excellent
tribological characteristics and good suitability to
different environments. Metal sulfide (WS2, MoS2, etc.),
graphite, hexagonal BN, CaF2 are chosen as lubricants
because of their special structure [Wu et al. (1997),
Xiong (2001), Renevier et al. (2000), Chen et al. (2008)].
At present metal matrix lubricant composite coating is
generally applied instead of bulk composite. In
addition, plasma spraying [Huang et al. (2009)] and
laser cladding are familiar surface technologies.
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(a)
(a)
(b)
Microhardness (HV0.2)
700
B
A
10m
(b)
600
500
400
300
200
0.0
0.5
Substrate
HAZ
CL
1.0
1.5
2.0
2.5
Substrate
Laser clad coating
Substrate
20m
Friction cofficient
1.0
0.8
0.6
0.4
0.2
0.0
10
15
20
25
30
Time (min)
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20
17.8
15
1145 1152.
Du, Ling Z., Zhang, Wei G., Liu, Wei: Preparation and
10
5
3.1
0
Surface
and
Coating
Technology
205
(2010):2419-2424.
Substrate
Conclusions
In the present study, in situ self-lubricant Ni-based
composite coating was produced by laser cladding
Ni-coated MoS2 and Ni60 mixture powders using a
CO2 continuous wave laser. The laser clad Ni-based
composite coating had a microstructure consisting of
spherical and like-spherical CrxSy, net-like eutectic of
Huang, Chuan B., Du, Ling Z., and Zhang, Wei G.:
Preparation
and
plasma-sprayed
coating.
characterization
of
atmospheric
NiCr/Cr3C2-BaF2CaF2
composite
Surface
and
Coating
Technology
203
(2009):3058-3065.
Majumdar, Jyotsna D., Li, Lin:Development of titanium
boride (TiB) dispersed titanium (Ti) matrix composite by
direct laser cladding. Material Letters 64 (2010):
10101012.
Renevier,
N.M.,
Fox,
V.C.,
Teer,
D.G.:
Coating
characteristics
and
sputter-deposited
tribological
MoS2/metal
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properties
composite
of
coatings
Xu, Jiang, Liu, Wen J., Zhong, Min L.: Microstructure and
2437.
Wang,
A.H.,
Zhang,
X.L.,
Zhang,
X.F.:
Ni-based
Wu, Yun X., Wang, Fu X., Chen, Yin Q. et al: A Study of the
(2010): 119124.
Zhang, Shi T., Zhou, Jian S., Guo, Bao G. et al: Friction and
6470.
composite coating.