Академический Документы
Профессиональный Документы
Культура Документы
Lecture 3
Flash Distillation
Prepared by:
Jonas Karl Christopher N. Agutaya
Assistant Professor
1
2
F L V
z1 F x1 L y1V
Equilibrium:
3
4
K1 y1 x1
K 2 y2 x2
Mole fractions
5
6
7
z1 z2 1
x1 x2 1
y1 y2 1
Energy Balance
FhF Qflash
VHV LhL
*equilibrium conditions
L
F
y x z
V
V
1 f
z
y
x
f
f
In terms of q:
1
q
y
x
z
1 q
1 q
L
F
x z
V
V
slope
L
1 f
q
V
f
1 q
y-intercept
F
1
1
z z
z
V
f
1 q
Solution:
1. z = 0.50
2. f = V/F = 60/100 = 0.6
1 f
1 0.6 2
f
0.6
3
1
1
5
y-intercept z
0.5
f
0.6
6
slope
Operating equation
2
5
y x
3
6
Equilibrium curve
(Wilson equation)
McCabeThiele
Diagram
slope = 2/3
Operating line
(Material balance)
Example 3.01c
Given:
1. P = 101.3 kPa
2. z1 = 0.40
3. F = 100 kmol/h
4. V/F = f = 2/3
Operating equation
y1 0.5 x 0.6
Intersection of OL and EC is at
x1 = 0.1783
y1 = 0.5109
Example 3.01c
+ = +
From the enthalpy of the feed, its temperature
can be determined from hF = hF(TF, z)
For ideal solutions,
drum , = 1 ,1 ref + 2 ,2 ref
, = 1 ,1 ref + 2 ,2 ref
drum , = 1 1 + ,1 ref
+ 2 2 + ,2 ref
Example 3.01c
At z1 = 0.40,
hF = 34.4581 kJ/mol
Size Calculation
1. Calculate the permissible vapor velocity, uperm
perm =
Size Calculation
Empirical Constant, Kdrum
For vertical drums the value has been correlated
graphically by Watkins (1967) for 85% of flood with no
demister.
Blackwell (1984) fit Watkins correlation to the equation
= . exp + ln + ln
+ ln
+ ln
= 0.1870744085
= 0.0145228667
= 0.0010148518
Size Calculation
2. Using the known vapor rate V, convert uperm
into a horizontal area. From the vapor flow rate
3600
2
the area is =
3600
For a vertical drum, the diameter is = 4 , which is usually
increased to the next largest 6-in. increment.
Size Calculation
3. Set the length/diameter ratio either by rule of
thumb or by the required liquid surge volume.
For vertical flash drums, htotal/D = 3.0 to 5.0.
Size Calculation
Flash Drums as Liquid Surge Tanks
The height of the drum above
the centerline of the feed
nozzle,
hV = 36 in. + the diameter
of the feed line
(min. = 48 in.)
The height of the center of the
feed line above the maximum
level of the liquid pool,
hf = 12 in. + the diameter of
the feed line
(min. = 18 in.)
Size Calculation
Flash Drums as Liquid Surge Tanks
The depth of the pool, hL, can
be determined from the desired
surge volume:
Vsurge
=
D2 4
Size Calculation
Flash Drums as Liquid Surge Tanks
The geometry can now be
checked:
htotal hV + hf + hL
=
D
D
If htotal/D < 3, a larger liquid
surge volume should be
allowed.
If htotal/D > 5, a horizontal
flash drum should be used.
Size Calculation
Horizontal Flash Drums
Horizontal flash drums are used for large flow
rates because additional disengagement area is
formed by making the column larger.
Size Calculation
Horizontal Flash Drums
If h/D = C is arbitrarily chosen (typically 3-5), the
diameter is
=
3600
3600
According to Blackwell:
= 1.25
Quiz
1. A flash distillation column operating at
101.325 kPa is separating an ethanol-water
mixture. The feed mixture is 50 mol% ethanol.
If 60% of the feed remains as liquid, determine
composition of liquid and vapor products.
2. The feed to a flash drum has a concentration of
40 mol% ethanol and 60% water. Its enthalpy
has been determined to be 25 kJ/mol. The
drum operates at 101.325 kPa. From this
information, determine the following:
a. Composition of the liquid and vapor phases
b. The L to V ratio