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Fundamentals of
Analytical Chemistry
3,
99-15 odd, 18, 19, 21, 25, 27, 32, 34, 38,
43, 44, 45
Chapter 14
Principles of Neutralization
Titrations
Indicators
Acid/Base
indicators
Indicators
Titration
Table
1414-1
List of indicators
pKa can be used to chose correct indicator
Match pKa with pH of equivalence point
Titrations
Error
To
I starting conditions
How much stuff do we have before any reaction
occurs
stoichiometric relationships
HOW will the system react
Must follow the stoichiometry
F final conditions
What
Whats in solution after the reaction has gone to
completion
50.0 mL of
0.10 M HCl is titrated with 0.10M NaOH
mL of titrant is added:
Cl0
~~
~~
mL of titrant is added:
Cl0
~~
~~
mL of titrant is added:
Cl0
~~
~~
mL of titrant is added:
Cl0
~~
~~
After 50.02
mL of titrant is added:
mL of titrant is added:
After 70.0
Cl0
~~
~~
Titration Curve
pH
Strong acid/base
Consider the following titration:
50.0 mL of
a 0.10 M solution of a weak acid (HA, Ka =
1.0 x 10-5) titrated with 0.10 M NaOH.
NaOH.
14
12
10
8
6
4
2
20
40
60
Volume
80
100
is added
[ H + ] = K a C HA = (0.10)(1.0 x105 )
mL of titrant is added
titration
or a strong base
mL of titrant is added
mL of titrant is added
6
[OH ] = 7.1x10 ; pOH = 5.15; pH = 8.85
[OH ] = K b C B =
Titration Curve
Strong Acid/
Strong Base
Titration Curve
20
40
60
Volume
80
100
80
100
Titration Curve
20
40
60
Volume
80
100
Weak Acid/
Strong Base
Titration Curve
pH
pH
pH
Strong acid/base
Titration Curve
14
12
10
8
6
4
2
14
12
10
8
6
4
2
0
20
40
60
Volume