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Chapter # 02
Long Questions
MATTER
Q.1
What is matter ? How many states of matter ? Write down the properties of Gases,
Liquids and Solids ?
Structure of Matter
Modern physics has revealed successively deeper layers of structure in ordinary matter. Matter is composed, on a
tiny scale, of particles called atoms. Atoms are in turn made up of minuscule nuclei.
State of Matter:
Matter exists in four states. The smallest structural unit of all these states
of matter is molecule.
(1)
Gas
(2)
Liquid
(3)
Solid
(4)
Plasma
1. Properties of Gas:
(i)
(ii)
(iii)
(iv)
(v)
(vi)
2. Properties
(i)
(ii)
(iii)
(iv)
(v)
(vi)
Shape:
A gas has no shape of its own but it acquires the shape of the container.
Volume: It has no volume. It can be compressed or expanded.
Diffusion: The gas molecules can be diffused from one place to another place easily.
Compression: It can be compressed due to large space between the gases molecules.
Expansion: It can be expanded. This is because they are lighter particles than others.
Motion: They move freely from one place to another.
of Liquid:
Shape:
A liquid has no shape of its own but it acquires the shape of the container.
Volume: It has fixed volume. It is slightly compressible.
Diffusion: The molecules of liquids move away from each other. It can be diffused slowly
Compression: It can be compressed to negligible extent.
Expansion: It can be expanded by heating.
Motion: The molecules of liquids move away from each other.
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3. Properties of Solid:
(i)
(ii)
(iii)
(iv)
(v)
Shape:
A solid has definite shape of the container.
Volume: It has definite volume. It cannot be compressed but appreciably by high pressure.
Diffusion: The diffusion in solid is negligible.
Compression: It cannot be compressed but appreciably by high pressure.
Motion: They cannot move away from each other and they vibrate to and fro about their
mean position.
Introduction:
Kinetic molecular theory of gases deals with the study in which particles of
liquid in random motion and collide with each other and with the walls of
container. They possess special type of energy known as Kinetic energy.
Maxwell and Boltzmann discussed the distribution of velocities and
energies among the molecules. The summary of the behaviour of gases is
called Kinetic molecular theory of gases. It is given in the form of following
postulates.
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2) Definition of Temperature:
The degree of hotness and coldness of body is called Temperature.
Unit of Temperature:
The S.I unit of temperature is degree Absolute (A0) or K0.
3) Definition of Volume:
The space occupied by substance is called Volume.
Unit of Volume: The S.I unit of volume is cubic decimeter (dm3).
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4) Definition of Diffusion:
The spreading out of the gases molecules throughout the vessel is called Diffusion.
OR
The spontaneous mixing of molecules of different gases by random motion and collisions to form a
homogenous mixture is called Diffusion.
OR
The spontaneous flow of molecules from a region of higher concentration to a region of low concentration
is called Diffusion.
Explanation:
If there are two gases NO2 and O2, when separated by partition are allowed to mix by removing the partition, then
they diffuse into each other. They generate a homogenous mixture.
5) Definition of Effusion:
The passage of gas molecules one by one without collisions through a pin hole in their container into an
evacuated space is called Effusion.
OR
The process in which a gas passes through the pores or tiny holes in the vessel is called Effusion.
Explanation:
The reality is that the molecules of the gas are habitual in colliding with the walls of the vessel. When they reach
the wall and find a hole in that then they pass through the hole.
6) Definition of Compressibility:
The decrease in volume with a rise of pressure is called Compressibility.
7) Definition of Expansibility:
The increase in volume with the decrease of pressure is called Expansibility.
GASEOUS STATE
Q. 6
The gases molecules are widely separated from each other. They have more kinetic energy than liquid and solid.
(2) Diffusibility:
According to Kinetic Molecular Theory the gases molecules have large space between them. Due to space they
move freely and mixed with each other and spread out easily the space available in the container. For example
ammonia gas is liberated in room; its odour soon spreads through out the room.
(3) Compressibility:
The large empty spaces are present between the molecules of gases in gaseous state. Therefore when a gas is
subjected to compress by pressure these empty spaces reduced.
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LIQUID STATE
Q.7
(1) Diffusibility:
According to Kinetic Molecular Theory the liquid molecules are in cluster form, they are very close to one
another. They are obtained by strong intermolecular force. The intermolecular distance is smaller and collision
frequency is higher as a result, the diffusion.
(2) Expansion:
According to Kinetic Molecular Theory when temperature is applied on the liquid the kinetic energy increases as a
result, their motion increase and the attraction between them weaken, then they can expand.
(3) Contraction:
According to Kinetic Molecular Theory when liquid is cooled, it contracts and solidifies. This is because its kinetic
energy is lowered.
(4) Compressibility:
When pressure is applied on liquid molecules they can be compressed from little space between the molecules.
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BOYLES LAW
Q.9
State and explain Boyles Law. How Boyles Law can be represented graphically
and mathematically ?
Introduction:
Boyles law is a quantitative relationship between volume and pressure of a gas at constant temperature.
Statement:
"The volume of a given mass of a gas is inversely proportional to pressure if temperature remains constant ".
Explanation:
According to Boyles Law if pressure is increased of a gas at constant temperature then the volume of a given mass
is decreased and at constant temperature if pressure is double on a gas its volume decreases to one-half. If pressure
is reduced to half the volume of gas will be double.
Example:
Take three vessels and provided with moveable piston. Now introduce equal volume and applying pressure on gas
by keeping different weights on each of the pistons.
We have observed the vessel No:3 has small volume due to more pressure i-e time when vessel No:2 has greater
volume than vessel No:3 when vessel No:1 has larger volume due to small pressure. It has verified V is inversely
proportional to P.
Statement:
The product of pressure and volume of a fixed amount of a gas is a constant quantity at constant temperature.
Let the initial pressure and initial volume are P1 and V1. final pressure and final volume are P2 and V2.
Since
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V
volume V1
P1V1
V2
P2 V2
Pressure
1/p
If the volume of a gas is plotted against the pressure a parabolic curve is obtained showing the decrease in volume
with increase in pressure. If the volume of a gas is plotted against 1/p a straight line is obtained.
CHARLESS LAW
Q. 10 State and explain Charless Law. Explain. How Charless Law can be represented
graphically and mathematically ?
Introduction:
It is quantitative relationship between volume and absolute temperature of a gas at constant pressure.
First Statement:
The volume of the given mass amount of the gas is directly proportional to its absolute temperature when the
pressure is kept constant.
Second Statement:
"The volume of a given mass of a gas increases or decreases by 1/273 times of its original volume at 0 0C for
every degree fall or rise of temperature at given pressure."
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Explanation:
According to Charless law the variation in volume takes
place due to temperature. When pressure of the given mass
of gas kept constant, if more temperature is provided to
system or gas the volume is increased and if temperature is
low then its volume would be small.
Mathematical representation:
Let the volume of a gas at T Kelvin is V
Then according to Charless law
V T (Pressure and number of moles are constant)
V=k T
V/T=k
Where k is the proportionality constant. Its value is different for different amounts of the same gas. The value of k
also depends upon the temperature maintained.
Third Statement:
The ratio of the volume to the absolute temperature of a fixed amount of gas remains constant
at constant pressure
V1/T1 = k ---------------(1)
V2/T2 = k ---------------(2)
Thus
V1/T1 = V2/T2
In order to verify this law, let us consider a fixed amount of gas enclosed in a cylinder with a movable piston. Let
the initial volume is V1 at temperature T2. When the cylinder is heated the volume and temperature of the gas will
rise. During this change pressure is kept constant because the piston moves upwards and final volume and
temperate are V2 and T2.
According to Kinetic Molecular Theory a decrease in temperature, the decreases the average kinetic energy of the
gas molecules, that is, average molecular velocity decreases. At constant pressure, the decreased velocity causes the
sample of gas to shrink and occupy a smaller volume.
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Muhammad Zia-ul-Haque Rathore, Lecturer in Chemistry , szabist intermediate college mirpurkhas
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Long Questions
AVOGADROS LAW
Q.11 State and explain Avogadros Law.
Introduction:
In 1811 Avogadro gave a relationship between volume and number of molecules of gas is called Avogadros Law.
Statement:
Equal volume of all gases at same temperature and pressure contain equal number of molecules.
Explanation:
According to Avogadros law, 1 cubic meter of oxygen at STP contains the same number of particles as 1 cubic
meter of nitrogen at STP. Restated, Avogadro's law says that one mole of any gas at STP occupies a volume of 22.4
liters. A mole is 6.02 1023 basic particles (atoms or molecules) of a substance. The extremely large number
6.02 1023 is called Avogadro's number.
1 mole H2 at S.T.P
Volume= 22.4dm3
Mass = 2gm
1 mole N2 at S.T.P
Volume= 22.4 dm3
Mass = 28gm
1 mole O2 at S.T.P
Volume= 22.4 dm3
Mass = 32gm
1 mole He at S.T.P
Volume= 22.4 dm3
Mass = 4gm
Examples:
1 mole of N2 = 22.4 dm3 at S.T.P
= 28gm of N2
= 6.02 x 1023 molecules.
Mathematical Representation:
It can be represented as
V n
Where v is volume and n is number of moles at constant temperature and pressure.
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Second Statement:
The comparative rates of diffusion of two gases are inversely proportional to the square root of their densities.
Explanation:
Graham established a relationship between the rate of diffusion of gases and their densities. Intermixing of two or
more gases to form a homogeneous mixture without any chemical change is called "DIFFUSION OF GASES".
Diffusion is purely a physical phenomenon. Gases diffuse very quickly due to large empty spaces among
molecules. Different gases diffuse with different rates (velocities).
Graham's law is a quantitative relation between the density and rate of diffusion of gases.
Mathematical Representation:
Consider two gases A and B having mass densities d1 and d2 and their rates of diffusions are r1 and r2 respectively.
According to Graham's law of diffusion:
For gas A:
OR
For gas B:
OR
Dividing equation (i) by equation (ii)
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Since the molecular mass of a gas is directly proportional to its density therefore we may use molecular mass
instead of densities.
Hence.STssqwsdqwdATEMENT
Second Statement:
The sum of partial pressure of all the different gases in a mixture is equal to the total pressure of the mixture.
Explanation:
In a mixture of different gases which do not react
chemically each gas behaves independently of the
other gases and exerts its own pressure. This
individual pressure that a gas exerts in a mixture of
gases is called its partial pressure.
Based on this behaviour of gases, JOHN DALTON
formulated a basic law which is known as "The
Dalton's law of partial pressure".
Whenever ideal gases are mixed, they collide on the
walls of the container independently so the total
pressure is contributed by all the gases.
Example:
Air is a mixture of several gases ,like N2 = 78 %, O2
= 21% , Ar = 0.93%, CO2 = 0.03% and many other
gases. The total pressure of the atmosphere is equal
to the sum of individual partial pressure.
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Mathematical Representation:
Consider a mixture of three non-reacting gases a , b and c .Partial pressures of these gases are Pa ,Pb and Pc
According to Dalton's law of partial pressure, their total pressure is given by:
Ptotal = Pa + Pb + Pc
Where P is total pressure exerted by all gases and Pa, Pb and Pc are partial pressure exerted by each gases a, b and c
respectively. According to General gas equation:
PV = nRT
P1V = n1RT
P2V = n2RT
P3V = n3RT
Adding above three equations
V (P1 + P2 + P3) = (n1 + n2 + n3) RT
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VISCOSITY
Q.17 Define and explain Viscosity. What the factors which affect on Viscosity of
molecules ?
Definition:
The measure if internal resistance of liquid to its flow is called Viscosity.
OR
Internal friction present between two layers of a liquid which resists the flow of liquid is commonly
known as Viscosity.
Explanation:
Unlike gas, liquid molecules having property to flow due to Vander Waals force, which is weak temporary force of
attraction between liquid molecules.
A liquid in a tube is considered as made of a series of molecular layers. The layers of liquid in contact with the
walls of tube remain stationary. The layer in the center of the tube has high velocity.
A liquid with high viscosity is thick and flows slowly when a liquid with low viscosity is thin and flows quickly.
Different liquids have different viscosities.
Units of Viscosity:
Most common unit is "POISE"
Small unit is "CENTI POISE" 1Centipoise = 10-3 NS/m2 or 0.001 NS/m2
In S.I system unit is N.S/m2
(4) Temperature:
Viscosity of liquid decreases with increase in temperature. Because an increase in temperature, reduces the forces
of attraction between molecules.
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SURFACE TENSION
Q.18 Define and explain Surface Tension. What the factors, affecting on surface
tension?
Definition:
"Perpendicular force acting on the unit length of the surface of a liquid is called Surface Tension
Surface Tension = Force / Length
OR
Energy per unit area on the surface of liquid is called Surface Tension
Explanation:
= energy /area
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CAPILLARY ACTION
Q.19 Write down the short note on Capillary Action.
Definition:
The rise of liquid in a capillary tube against the force of gravity or fall of liquid due to force of gravity
is called Capillary Action.
OR
The rise of liquid in a small capillary tube is called Capillary Action.
Explanation:
It is the common property of all liquids.
The fall
or rise of liquid in capillary tube is called capillary
action. If capillary tube is placed in liquids which
wet the walls of container, the surface area of liquid
is decreased by rising in the tube because of surface
tension, such liquids will rise in the capillary tube
until the upward force due to the surface tension is
balanced by downward gravitational pull.
VAPOUR PRESSURE
Q.20 Define and explain Vapour Pressure. What the factors affecting on Vapour
Pressure ?
Definition:
Pressure exerted by the vapour of a liquid at equilibrium is called Vapour Pressure of liquid.
OR
Pressure exerted by the vapours of a liquid when rate of evaporation and the rate of condensation becomes
equal is called Vapour Pressure.
Explanation:
There are two types of liquids. Volatile
and non-volatile liquids. Volatile liquids
evaporate quickly, having high vapour
pressure.
Consider a liquid closed in a container at
a certain temperature. High energy
molecules leave the surface of liquid and
gather above the surface in the empty
space in the form of vapours.
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(2) Temperature:
Temperature is directly proportional to vapour pressure because at higher temperature, the kinetic energy of the
molecules is increased. Molecules of higher kinetic energy will escape from the liquid more quickly. Thus it causes
increase in the vapour pressure.
BOILING POINT
Q.21 Define and explain Boiling Point. What is Normal Boiling Point ?
Definition:
Temperature at which the vapour pressure of liquid becomes equal to atmospheric pressure is called Boiling
Point.
Explanation:
When the liquid is heated, bubbles begin to form throughout its volume. The bubbles contain vapours, which begin
lighter than the liquid rise to the surface and burst there. The vapour pressure in the bubbles will be equal to the
atmospheric pressure. At this, all the bubbles contain in vapours will rise to the surface of liquid and burst there
and it appears that water is boiling. Boiling point of liquid varies with atmospheric pressure. If atmospheric
pressure is less then 760 torr then the boiling point of a liquid will decrease from its standard boiling point. Boiling
point of a liquid decreases with the decrease in pressure and vice versa. Boiling point of liquid varies with
atmospheric pressure.
CLASSIFICATION OF SOLIDS
Q.22 What are solids ? How are they classified ? Write down the fundamental properties
of Crystalline and Amorphous Solids ?
Solids substances are hard, rigid having definite shape and volume. In solid state atoms, molecules or ion are very
closely packed and have well-ordered arrangement.
Solids are classified into two types:
(1) Crystalline Solids.
(2) Amorphous Solids.
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The smallest part of in the crystal lattice which shows all the characteristics of the entire crystal is known as unit
cell.
What is Face ?
The arranged particles in solids are bounded by plane surface called Face.
TYPES OF CRYSTALS
Q.23 How many types of crystals ? Write down the characteristics of each type.
Introduction:
Crystalline solid is made up of atoms, ions or molecules which are held together by various types of cohesive
forces. These cohesive forces may be chemical bonds or interaction between particles. These interactions are
between atoms, ions or molecules of crystalline solid.
(1) Metallic Crystals
(2) Ionic Crystals
(2) (3) Covalent Crystals
(4) Molecular Crystals
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They are soft, volatile and easily compressed, due to very weak force of attraction.
They have low melting point and boiling point.
They are bad conductor of electricity.
They have low values of heat of fusion and lattice energy.
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ISOMORPHISM
Q.24 What is Isomorphism ? Write down its characteristics.
Definition:
The phenomenon in which two different substances exit in the same crystalline
form is known as Isomorphism.
OR
The substances, which have same type of chemical formula and crystalline with same lattice are Isomorphous
and this phenomenon is called as Isomorphism.
Characteristics of Isomorphism:
Different substances having same crystalline shape are called isomorphic.
They have different chemical and physical properties but same empirical formula.
Isomorphism found in various compounds is mostly due to same atomic ratio.
Examples:
(1) Both NaNO3 and CaCO3 have Isomorphous and exits in rhombohedral form and ratio of 1:3
(2) ZnSO4 and NiSO4 have cubic crystal and ratio of 1:4
POLYMORPHISM
Q.25 What is Polymorphism ? Write down its characteristics.
Definition:
The phenomenon in which a compound exits in more than one crystalline form is called Polymorphism.
OR
When a single substance is crystallized in two or more forms under different conditions is called Polymorphous
and this phenomenon is called Polymorphism.
Characteristics of Polymorphism:
They have same chemical formula but different structural arrangement of particles.
They do not grow together in al proportions.
Examples:
(1) AgNO3 exit in rhombohedral and orthorhombic forms.
(2) Silica (SiO2) exits in the forms of quartz and tridymite.
MELTING POINT
Q.26 Define and Explain Melting Point.
Definition:
The temperature at which both liquid and solid phases or states co-exist at equilibrium.
Explanation:
The particles of solid weakly vibrate back and forth al all temperature. When the solid is heated, its particles vibrate
more vigorously about their average position and their kinetic energy is increased. When heating is continued
vibration of molecules becomes much more vigorous until the force between molecules becomes weak. Hence
molecules at the surface of crystal begin to disengaged themselves from their neighbour that is solid begins to melt.
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