2016 01 05 12 45 16 PDF

SUBJECT : CHEMISTRY
PART TEST-1(PT-1)
Code
(JEE ADVANCED PATTERN)

TARGET : JEE (MAIN+ADVANCED) 2018
COURSE : VIKAAS (JA**2+)
P05-15
Date : 03-01-2016
Time: 2 Hours
Maximum Marks : 160
1.
The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2.
The question paper CODE is printed on the right hand top corner of this sheet.
3.
Use the Optical Response Sheet (ORS) provided separately for answering the question.
4.
Blank spaces are provided within this booklet for rough work.
5.
Write your Name and Roll Number in the space provided on the below cover.
6.
After the open booklet, verify that the booklet contains all the 40 questions along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :

7.
This questions paper consists of Two sections.
8.
Carefully read the instructions given at the beginning of each section.
9.
Section 1 contains 22 multiple Choice questions with one or more than one correct option.
Marking scheme: +4 for correct answer, 0 if not attempted and 2 in all other cases.
10.
Section 2 contains 18 questions. The answer to each question is a single digit integer ranging from 0 to 9 (both
inclusive).
Marking scheme: +4 for correct answer, 0 if not attempted and 1 in all other cases.
OPTICAL RESPONSE SHEET :

11.
Darken the appropriate bubbles on the original by applying sufficient pressure.
12.
The original is machine-gradable and will be collected by the invigilator at the end of the examination.
13.
Do not tamper with or mutilate the ORS.
14.
Write your name, roll number and the name of the examination centre and sign with pen in the space provided for
this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS :

15.
Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
16.
Darken the bubble COMPLETELY.
17.
Darken the bubble ONLY if you are sure of the answer.
18.
The correct way of darkening a bubble is as shown here :
19.
There is NO way to erase or "un-darkened bubble.
20.
The marking scheme given at the beginning of each section gives details of how darkened and not darkened
bubbles are evaluated.
NAME OF THE CANDIDATE : ..
ROLL NO. : ..
I have read all the instructions
and shall abide by them
------------------------Signature of the Candidate
I have verified the identity, name and roll number

of the candidate.
------------------------Signature of the Invigilator
Resonance Eduventures Ltd.

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P5
DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %
CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION 1 : (Maximum Marks : 88)
This section contains TWENTY TWO questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases
1.
The weight of 350 ml of a diatomic gas at 0 C and 2 atm pressure is 1 gm. The weight of one
atom in gram is : (N = Avogadro's number)
(A)
2.
16
N
(B)
32
N
(C) 16 N
(D) 32 N
Analysis of chlorophyll shows that it contains 2.64 percent magnesium. How many atoms of
magnesium does 1.00 gm of chlorophyll contains ?
23
(A) 6.62 10
21
(B) 6.62 10
24
(C) 6.62 10
20
(D) 6.62 10
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.aca.in
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PLC024029
JA**++PT1030116C0-1
CHEMISTRY
CHEMISTRY
CHEMISTRY
Select the correct statements for (NH4)3PO4 :
CHEMISTRY
3.
(A) Ratio of number of oxygen atom to number of hydrogen atom is 1 : 3

(B) Ratio of number of cation to number of anion is 3 : 1
(C) Ratio of number of nitrogen atom to number of oxygen atom is 3 : 4
(D) Total number of atoms in one mole of (NH4)3PO4 is 20
4.
The number of neutrons present in 7 gm of phosphonium (PH4 ) ion is

(A) 8 NA
5.
(C) 4 NA
(D) 5 NA
16 g of S2 ion has amount of charge equal to : (NA = 6.02 1023, e = 1.6 1019 C)
(A) 5 NAe
6.
(B) 3.2 NA
31 1
15 P,1 H
(B) 2 NAe
(C) NAe
(D)
1
Ne
2 A
A gas XH2 has molar mass 34 g/mol. What is the molar mass of XO3 (nearly) ?
(A) 64 g/mol
(B) 82 g/mol
(C) 80 g/mol
(D) cannot be found
JA**++PT1030116C0-2
CHEMISTRY
An element has two isotopes of atomic mass number 16 and 18. Then which of the following is
false.
(A) The average atomic mass of the element can not be less than 16 amu.
(B) If the natural abundance of the heavier isotope is negligible, then the average atomic mass will
be close to 16 amu.
(C) If both isotopes are equally abundant, then mass of 3 atoms of the element will be 51 amu
(D) If the natural abundance of the lighter isotope is 75%, then the average atomic mass will be
closer to 16 amu.
8.
Tom measured the pressure of gas sample A as 1 bar, while Jerry measured the pressure of
another gas sample B as 1 Pascal. Which of two gas samples exerts greater pressure :
9.
(A) Sample A
(B) Sample B
(C) Both gas samples have same pressure.
(D) Cannot be predicted.
Which the following order represents correct increasing order of mass for given samples.
(i) 1 g-atom of C
(ii) 0.5 mole of CH4
(iii) 10 mL of water (d= 1g/ml)
(iv) 3.011 1022 atoms of oxygen
(A) ii < i < iii < iv
(B) ii < iv < iii < i
(C) iv < ii < iii < i
(D) ii < i < iv < iii

JA**++PT1030116C0-3
CHEMISTRY
7.
CHEMISTRY
Which of the following statement/s is (are) INCORRECT ? (At mass of
= 4.00260244)
CHEMISTRY
10.
4He
(A) Mass of one sodium atom in gram is 23 g.

(B) 4 g of 4He contain exactly avogadro number of atoms.
(C) The gram atomic mass of chlorine is nearly 35.5 g.
(D) The relative atomic mass of sulphur is exactly 32.
11.
Which of the following contain maximum number of molecules?

(A) gas mixture of O2 and H2 having pressure 2 atm at 300 K and 4 L volume.
(B) gas mixture of CO2 and H2 having pressure 1 atm at 240 K and 8 L.
(C) 1.8 g water
(D) 3.2 g CH4.
12.
Which of the following compounds are aromatic (homocyclic) ?

NH2
(A)
(B)
(C)
(D)
OH
JA**++PT1030116C0-4
CHEMISTRY
Which of the following groups are attached to the cyclohexane ring in the following compound:
H3CHCH2C
CHCH3
CH3
CH3
CH2CH3
(A) Methyl
14.
(D) Neo-pentyl
(B)10
(C) 15
(D) 20
Which of the following has/have all 1, 2 and 3 carbon atoms only.
(A)
16.
(C) Iso-propyl
How many 1 hydrogens are present in iso-octane.

(A) 5
15.
(B) n-propyl
(B)
(C)
(D)
Which of the following are possible strcutures for the molecular formula C4H6 ?
(A)
(B)
(C)
(D)
JA**++PT1030116C0-5
CHEMISTRY
13.
CHEMISTRY
Which of the following is not alicyclic hydrocarbon
(A)
18.
(B)
(C)
CHEMISTRY
17.
(D)
For the following statements, incorrect option/s is/are :

S1 : Empirical formula of cyclopropane and butene are same.
S2 : General formula of cycloalkene is CnH2n.
S3 :
is an unsaturated Heterocyclic compound.
S4 : Pyridine
(A) TTTT
19.
is a homocyclic aromatic compound.

(B) TTFF
(C) FTFT
(D) TFTF
What is the empirical formula of following structure :
(A) C2H5
(B) C3H4
(C) CH4
(D) C2H3
JA**++PT1030116C0-6
CHEMISTRY
What is the hybridisation of underlined atom of Ketene CH2=C=O ?

2
(A) sp
21.
(B) sp
(D) dsp
Which of the following has/have similar general formula?
(A)
22.
(C) sp
(B)
(C)
(D)
What is the IUPAC name of the following compound?
(A) Oct-2, 4-diene-6-yne
(B) Oct-4, 6-diene-2-yne
(C) Oct-6-yne-2, 4-diene
(D) Hept-2,4-diene-6-yne
JA**++PT1030116C0-7
CHEMISTRY
20.
CHEMISTRY
This section contains EIGHTEEN questions.
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
1 In all other cases
23.
What is the ratio of weights of O2 and He, the mixture of which contains equal number of
molecules of each gas ?
24.
16 gm of an ideal gas SOx occupies 5.6 lt. at STP. The value of x is
25.
How many statements are incorrect ?

(a) Mass number can not be fractional
(b) Gram atomic mass of Cl35 is 35.5 g
(c) Both heavy water and normal water have same molar mass.
(d) The numerical value of R is independent of units, as it is universal gas constant.
JA**++PT1030116C0-8
CHEMISTRY
SECTION 2 : (Maximum Marks : 72)
CHEMISTRY
An element exist in three isotopic form :

40
X and
42
X. Relative abundance of
X = 30% by mole. If average atomic mass of X' is 41.25 u, find out the ratio of %
abundance (by mole) of
27.
X,
41
40
X to % abundance (by m ole) of
41
X.
If the mass of 0.25 mole of an element X is 4.5 g, then the mass of one atom of X is about
p 1023 g. Find the value of p.
28.
Two sealed containers of the same capacity are filled with 88 gram N2O (container-I) and 44 gram
CO2 (container-II) at the same temperature. If the pressure of CO2 in second container is 1 atm,
the pressure of N2O gas in the first container (in atm)would be:
29.
Find the weight of a sample (in g) which contains 0.2 mole Ne gas and about 1.08 1024
molecules of an unknown gas X, if the sample has average molar mass 38 g/mol. Report your
answer after dividing the weight of sample by 9.5.
JA**++PT1030116C0-9
CHEMISTRY
26.
40
CHEMISTRY
How many of the following is/are correctly related ?
CHEMISTRY
30.
(i) 1 torr > 1 bar

(ii) 10 L > 1 dm3
(iii) 0.4 atm > 100 torr
(iv) 1 m = 106 m
(v) 1 = 1010 m
(vi) 1 fm = 1012 m.
31.
From 196 g H2SO4, 6.023 1023 H2SO4 molecules are removed, x moles of H2SO4 are left.
From 1.96 g H3PO4, 12.046 1021 H3PO4 molecules are removed, y moles of H3PO4 are left.
Give value of 'x + y'.
32.
Calculate the 3 hydrogens in the following compound :
JA**++PT1030116C0-10
CHEMISTRY
How many total number of -bonds present in following compound.

CH2=C=CH-CCH
34.
Calculate the sum of numbers appearing in IUPAC naming of following compound :
35.
How many carbon atoms are sp hybridised in following compound.
CH2 = C = CH CH2 C C CH2 NH2
36.
Calculate the total number of -bonds in following structure.

CN
NC
37.
In buta-1,3-diene ; if X is number of hydrogen atoms and Y is number of -bonds present.

Calculate (X + Y).
JA**++PT1030116C0-11
CHEMISTRY
33.
CHEMISTRY
2
How many sp -sp bonds are present in the given compounds:
39.
Calculate the degree of unsaturation in the following structure :
40.
In the given structure; if number of sp C-atoms are M and number of sp -sp C-C -bonds are N.
CHEMISTRY
38.
Find the value of (MN).
JA**++PT1030116C0-12

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SUBJECT : CHEMISTRY

(JEE ADVANCED PATTERN)

COURSE : VIKAAS (JA**2+)

Maximum Marks : 160

QUESTION PAPER FORMAT AND MARKING SCHEME :

This questions paper consists of Two sections.

Carefully read the instructions given at the beginning of each section.

OPTICAL RESPONSE SHEET :

Darken the appropriate bubbles on the original by applying sufficient pressure.

Do not tamper with or mutilate the ORS.

DARKENING THE BUBBLES ON THE ORS :

Darken the bubble COMPLETELY.

Darken the bubble ONLY if you are sure of the answer.

The correct way of darkening a bubble is as shown here :

There is NO way to erase or "un-darkened bubble.

------------------------Signature of the Candidate

I have verified the identity, name and roll number

------------------------Signature of the Invigilator

Resonance Eduventures Ltd.

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

SECTION 1 : (Maximum Marks : 88)

This section contains TWENTY TWO questions

Space for Rough Work

Select the correct statements for (NH4)3PO4 :

(A) Ratio of number of oxygen atom to number of hydrogen atom is 1 : 3

The number of neutrons present in 7 gm of phosphonium (PH4 ) ion is

(D) cannot be found

Space for Rough Work

(C) Both gas samples have same pressure.

(D) Cannot be predicted.

(ii) 0.5 mole of CH4

(iii) 10 mL of water (d= 1g/ml)

(iv) 3.011 1022 atoms of oxygen

(A) ii < i < iii < iv

(B) ii < iv < iii < i

(C) iv < ii < iii < i

(D) ii < i < iv < iii

Which of the following statement/s is (are) INCORRECT ? (At mass of

(A) Mass of one sodium atom in gram is 23 g.

Which of the following contain maximum number of molecules?

Which of the following compounds are aromatic (homocyclic) ?

Space for Rough Work

Which of the following has/have all 1, 2 and 3 carbon atoms only.

How many 1 hydrogens are present in iso-octane.

Space for Rough Work

Which of the following is not alicyclic hydrocarbon

For the following statements, incorrect option/s is/are :

is an unsaturated Heterocyclic compound.

is a homocyclic aromatic compound.

What is the empirical formula of following structure :

Space for Rough Work

What is the hybridisation of underlined atom of Ketene CH2=C=O ?

Which of the following has/have similar general formula?

What is the IUPAC name of the following compound?

(A) Oct-2, 4-diene-6-yne

(B) Oct-4, 6-diene-2-yne

(C) Oct-6-yne-2, 4-diene

Space for Rough Work

Space for Rough Work

This section contains EIGHTEEN questions.

16 gm of an ideal gas SOx occupies 5.6 lt. at STP. The value of x is

How many statements are incorrect ?

Space for Rough Work