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Introduction
Modeling
intrinsic kinetics.
Results
them can be achieved. Intrinsic kinetics are of paramount importance. They are required for catalyst screening and necessary for comparing different reactor configurations. The real value for the reaction rate constant allows the evaluation of
Laminar
mass transfer which is the main factor dictating the performance of a reactor.
flow!
catalyst thickness
Convection/Diffusion
The relative effectiveness factor quantifies the ratio between the reaction rate in the
Experimental
Diffusion/Reaction
A previously cleaned silicon substrate was spin coated with a TiO2 commercial
o
dispersion and sintered at 500 C. The film has a uniform porous structure. The
absorption coefficient
presence of both diffusion and light limitation and the reaction rate affected only by
diffusion. Consequently, it shows how the reaction rate diminishes due to the attenua-
LIM
LDM
tion of light. The asymptotic trend suggests the equivalence between the two models
thickness, porosity and optical absorption coefficient of the film are investigated
using ellipsometry.
Models for both light independent (LIM) and light dependent (LDM) ki-
evaluate catalyst
netics were built. The conversion rates are very encouraging with reaction
coverage
rate constants orders of magnitude higher than previously reported values. The models describe very well the experimental data for multiple res-
maximum conversion
The model is
user friendly
and complete!
thickness
Outcome
The relative effectiveness factor gives the optimum catalyst thickness for a certain absorption coefficient and incident light intensity, while the model predicts
the necessary residence time for certain reactor dimensions and degradation requirements. Rational technological improvements are additional benefits of the
mathematical representation. Reverse engineering can be applied to identify
sensitive parameters worth tuning.
Visan, A., Rafieian, D., Ogieglo, W., & Lammertink, R. G. H. (2014). Modeling intrinsic kinetics in immobilized photocatalytic microreactors. Applied Catalysis B: Environmental, 150-151, 93100.