Antoine Lavoisier established that elements were the fundamental building
blocks of chemical substances. He examined their properties and organised materials into four groups or elements. Lavoisier defined element as a substance that could not be decomposed into simpler substances. His classification identified four groups of elements: metals, non-metals, elastic fluids (gases) and earths in 1789. Some of these elements (earths) were much later shown to be compounds. Lavoisier also outlined the importance of gravimetric analysis and the idea of conservation of mass. Johann Dobereiner (1780-1849) Between 1817 and 1829 he observed chemical similarity between groups of 3 elements, known as triads, arranged by atomic weight. He noticed that the properties of the element in the middle were intermediate between the other two and that the atomic weight of the middle element was approximately an average of the other 2. E.g. Lithium, Sodium and Potassium (he noticed that reactivity increases from left to right). Alexandre-Emile Beguyer de Chancourtois Alexandre-Emile Bguyer de Chancourtois, a French geologist, was the first person to notice the periodicity of the elements similar elements occurring at regular intervals when they are ordered by their atomic weights. In 1862 he devised an early form of periodic table, which he named Vis tellurique, after the element tellurium. With the elements arranged in a spiral on a cylinder by order of increasing atomic weight, de Chancourtois saw that elements with similar properties lined up vertically. John Newlands (1837-1898) After Dobereiner not much classification was done due to limited data on atomic weight. In 1864 Newlands published a table in increasing atomic weight, leaving spaces for undiscovered elements. In 1866 his table was divided into 8 columns and 7 rows with some elements in the same position. He described his observation (an element was chemically and physically similar with that 8 positions away) as the law of octaves. This law was inaccurate as non-metals and metals were not differentiated and it wasnt all accurate. Awarded Davy medal. Lothar Meyer (1830-1895) Around the same time as Mendeleev, Meyer also developed a periodic system of classification. Meyers table consisted of 56 elements, and their periodic nature was visually displayed in his graphs of physical property vs atomic weight as a function. More generalisations could be made with Mendeleevs table as he incorporated chemical properties hence it was superior. Both scientists were awarded a Davy Medal in 1882. Dmitri Mendeleev (1834-1907) He organised the elements based on atomic weight and in terms of physical and chemical properties. He also left spaces for undiscovered elements, and if the atomic mass wasnt accurate he would organise it based on chemical/physical property. He believed that the gaps, of the undiscovered elements, that their
properties could be determined based on trends. In 1871 a table was published
with 8 groups and 12 series. Elements with similar chemical properties were in the same group and there was gradation of physical properties down a group. He noticed the periodic relationship between the elements (repeating every series/period). He was known to make predictions of undiscovered elements based on trends and its neighbouring elements for e.g. germanium (eka-silicon). Its properties were determined in 1871 but when germanium was first discovered in 1886 its properties were very close to those proposed by Mendeleev. Henry Moseley (1887-1915) In 1913 Dutch physicist Anton van den Broek suggested that elements be arranged based on the charge of their nucleus and to test this Moseley undertook many experiments in 1912 and 1913, investigating the X-Ray spectra of ten consecutive elements. He noticed a mathematical relationship between the X-ray frequency and a fundamental quantity of each element. He stated that There is in the atom a fundamental quantity, which increases by regular steps as we pass from one element to the next. This fundamental quantity later became the atomic number.