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(LIQUID-LIQUID
EXTRACTION)
Perrys Chemical
Engineers Handbook
8th Edition
7th Edition
Section 15
Pages 15-6 to 15-21
Pages 15-58 to 15-92
Section 15
Pages 15-4 to 15-47
CLASSIFICATION:
Single Solvent System
A. Stage-wise Contact:
1. Single Contact (analogous to Equilibrium
Distillation)
2. Co-current Multiple Contact or Simple Multistage contact
3. Counter-Current Multi-stage or Multiple
Contact
a. Without Reflux
b. With Reflux (analogous to Fractional Distillation)
k = distribution coefficient
extract branch
plait point
raffinate branch
AB
A
B
Type I
extract
raffinate
B
A
A
B
Type II
Rectangular Coordinates:
Right Triangle diagram (weight basis)
S
xs
BA
Xs
orny s
Ys
s vs y (extract)
plait point
A B S
AB
S
s
B A S
s vs x (raffinate)
AB
x AB or y AB
Type I
X Bor YB
B
B A S
S
xs
or
extract
ys
ate
n
i
f
f
a
r
AB
B
A
x AB or y AB
Type II
extract branch
s'
plait point
raffinate
X, Y
Type I
S
A
s'
A B
X or Y
B
B A
s' vs Y
extract
s'
s' vs X
raffinate
X, Y
Type II
Wt. %
acetic acid
100%
Water
Isopropyl
ether
Acetic acid
100%
Water
Isopropyl
ether
0.69
1.41
2.89
6.42
13.30
25.50
36.70
44.30
46.40
98.1
97.1
95.5
91.7
84.4
71.1
58.9
45.1
37.1
1.2
1.5
1.6
1.9
2.3
3.4
4.4
10.6
16.5
0.18
0.37
0.79
1.93
4.82
11.40
21.60
31.10
36.20
0.5
0.7
0.8
1.0
1.9
3.9
6.9
10.8
15.1
99.3
98.9
98.4
97.1
93.3
84.7
71.5
58.1
48.7
(a) Type I, one immiscible pair; (b) Type II, two immiscible
pairs