To cool reactor effluent from 430.534 to 382.

093
CALCULATION OF HEAT DUTY
From Energy Balance
Q=77.409 kW

CALCULATION OF LOGARITHMIC MEAN TEMPERATURE

Using eqn. 12.4 page 655 (Coulson, 2005).
T lm=

( T 1t 2 )(T 2t 1 )

ln

T lm=

T 1t 2
T 2t 1

( 430.534 110 ) (382.093 30 )

( 430.534 110 )
ln
(382.093 30 )

T lm=336.067

Using eqn. 12.6 page 655 (Coulson, 2005).

R=

T 1T 2
t 2t 1

R=

430.534 382.093
11030
R= 0.605

Using eqn. 12.7 page 656 (Coulson, 2005).

S=

t 2t 1
T 1t 1

S=

110 30
430.534 30

S=0.1997

Using Eq 12.8 (Coulson, 2005)

R 2+1
R 2+1
R 2+1
[R+1+ ()]
2S
()
R+ 1

2S

( R1 ) ln
( 1S )
()ln [
]
( 1RS )

Ft =

Ft=0.994

Using eqn. 12.5 page 655 (Coulson, 2005).

T m=T lm x Ft
T m=336.067 x 0.9 94
T m=334.138

CALCULATION OF SURFACE AREA

Overall Heat Transfer
Coefficient estimated,
U
Tube Length, L

W
m2

200

1.5

Baffle Space, B

Mm

100

Using eqn. 12.1 page 635 (Coulson, 2005).

Q=UA T m

A=

77.409 kW x
A=
200

Q
U estimated T m

1000W
kW

W
x 329.346
m2
A=1.175 m2

Tube Data:
1 Tube OD 14 BWG, Using table 11-12 page 11-42 (Perry & Green, 2008)
outside diameter of tube ,d o =25.4 mm
inside diameter of tube , d i=21.18 mm
Type of pitch=Triangular pitch

Tube pitch , PT =1.25 d o=31 . 75 mm

No. of Tube Passes , n=2

Nt=

A estimated
do L
2

1.175 m
Nt=
x 0.0254 m x 1.5 m
N t =9.82
N t =10

Using table 9 page 842 (Kern, 1950)

N t =10

N t =16( Table)

Shell ID=8

Shell ID=8 x

0.0254 m

Shell ID=0.2032 m

Taken Heat Transfer Area

A= do L N t
A= x 0.0254 m x 1.5 m x 16

A=1. 915 m2
CALCULATION OF TUBE SIDE HEAT TRANSFER COEFFICIENT
Cross Section Area
N

A t = d i2 t
4
n

( )

16
A t = x 0.02118 2 m2
4
2

( )

A t =0.00 28186 m 2
Fluid Properties, at Arithmetic Mean Temperature
T ave=

430.534 +382.093
=406.314
2

Using ASPEN Plus V8.8

Toluen
e
Hydrog

Mass
(Kg/day)

Mass
Fraction

Density
(Kg/m3)

Viscosity
(Pa-s)
1.47E-05

Thermal
Conductivi
ty
5.26E-05

Heat
Capacit
y
2.30471

12005.89

0.2384

9.78613

1399.364

0.0278

0.214104

1.57E-05

0.00033625

14.5697

en
Benzen
e
Diphen
yl
Metha
ne
Total

24294.063

0.4823

8.29635

1.70E-05

2.22313

1.25E-05

0.00004974
7
3.69E-05

6405.493

0.1272

16.3786

6263.943

0.1244

1.7338

2.13E-05

9.20E-05

3.55494

50368.752

36.378564

8.14E-05

0.00056745

24.8578

kW/m K

kJ/Kg

2.20533

Density
kg
kg
kg
kg
kg
+ 1399.364
+24294.063
+6405.493
+6263.943
day
day
day
day
day
mx =
kg
kg
kg
kg
kg
12005.89
1399.364
24294.063
6405.493
6263.943
day
day
day
day
day
+
+
+
+
kg
kg
kg
kg
kg
9.78613 3
0.214104 3
8.29635 3
16.3786 3
1.7338 3
m
m
m
m
m
12005.89

mx =3.4276

kg
m3

Viscosity
mx = m f

mx =(0.2384)(1.47E-05 Pa . s)+(0.0278)(1.57E-05 Pa . s)+(0.4823)(1.70E-05 Pa . s)+(0.1272)( 1.25E-05 Pa . s

mx =1.638E-05 Pa. s

Thermal Conductivity
1
k mx

mf
k2

1
k mx

0.2384

0.0000525988

k mx =5.06 7E-05

W
m

0.0278

0.00033625

W
m

0.4823

0.000049747

W
m

0.1272
0.0000368909

W
m

0.1244
0.0000919636

W
m

Heat Capacity
Cp mx = mf Cp

Cp mx =0.2384 2.30471

Cp mx =2.749

kJ
kJ
kJ
kJ
+ 0.0278 14.5697
+ 0.4823 2.22313
+0.1272 2.20533
+ 0.12
kg
kg
kg
kg

kJ
kg

Velocity:
For tube side velocity, a limit of 1 m/ s2 m/ s is observed.
Section 12.7.2 page 660 (Coulson, 2005)
vt =

Mc
mx x A t

kg
hr
day
x
x
day 3600 s 24 hr
vt =
kg
3.4276 3 x 0.001761618 m 2
m
50368.752

v t =1.13

m
s