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Tutorial: Functions
1. The virial equation of a gas can be approximated at low pressure as
m = (1 +
( = [ m 1])
2. Kohlrauschs law for the molar conductivity, m of a strong electrolyte at
low concentration, is
m = om
where om is the molar conductivity at infinite dilution and is a constant.
Express c as an explicit function of m .
om m 2
( = [
] )
1 +
( = (1))
4. The acidity constant, a of a weak acid at concentration is
a =
2
1
a
2
[1 + 1])
a
5. Ammonia is synthesized by
N2 + 3H2 2NH3
Initially 1 bar of N2 and 3 bar or H2 are mixed with no NH3 present and
they become equilibrium at a given temperature. If bar of N2 is lost due
to the reaction, the equilibrium constant,
(2)2
=
3 = (1 )(3 3)3 = 977
N2 (H2 )
(NH3 )
of
identical
molecules,
the
(a) Show that the ratio of the populations of states and depends
( = = )
(b) What is the ratio for two states with the same energy (degenerate
states)
( = 1)
( =
exp [
])
(a) = 3 s 1
(1 0.2310 s)
2
(b) = 105 s 1
(1 0.6931 105 s)
2