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ISSN 1818-4952
IDOSI Publications, 2010
Gas hold-up
Liquid circulation
INTRODUCTION
Airlift reactors are one of the most important of two
phase contactors which are increasingly used in chemical
industries, biological processes, aerobic fermentation,
wastewater treatment and other gas-liquid contacting
applications [1, 2]. Approximately 25% of all chemical
processes occur between a gas phase and a liquid phase
[3]. There are some advatages such as suitable heat and
mass transfer and shorter reaction time because of closer
contact between the phases, low shear rate, high mixing
performance, high and flexible capacity. For optimizing
such reactor operations many different geometric
configurations of airlift reactors were described [4, 5].
Surfactants are the materials consist of molecules
containing both polar and non-polar parts (amphiphilic).
These molecules locate their hydrophilic head groups
in the aqueous phase and allow the hydrophobic
hydrocarbon chains to escape from water phase [6].
These materials are widely using as antifoam agent,
Mixing time
1004
CMC(mM.L 1)
HLB
MW(kg.kmol 1)
Type
Formula
36.955
0.955
364.5
Cationic
C19H42BrN
HCTBr
37.373
0.08
15.7
1123.5
Nonionic
C16H33(OCH 2CH2)20OH
Brij 58
37
0.5
17.6
1968.5
Nonionic
C94H182O41
TritonX-405
38.83
0.027
15.5
1283.8
Nonionic
C62H122O26
Tween 40
1005
Surfactant
Inverted
U-tube
manometers
Computer
Dissolved
oxygen
electrode
Riser
Downcomer
Measuring
module
Baffle
Conductivity
electrode
Sparger
Nitrogen
Rotameter
Drain
Air
Filter and
pressure
regulator
Compressor
Airlift reactor
3.8
3.3
2.8
2.3
1.8
0
50
100
150
200
Number of bubbles
250
300
e tkL a
k L ae (t
tE
tE )
tE
1 t Ek L a
(1)
Where, tE is the electrode response time, C* is the
saturation concentration of oxygen in water at the
operating temperature and CL is the instantaneous
concentration of dissolved oxygen at time t.
1006
di3
=
i
1
d ave =
i= N
i =1 di2
(2)
1007
3.2
3.1
3
2.9
2.8
2.7
2.6
2.5
2.4
2.3
0
2
3
4
Surfactant concentration (ppm) .
90
Homogenous
80
Transition
70
60
50
40
Transition
30
20
0
0.2
0.4
0.6
0.8
Ug (cm/s) .
1.2
Fig. 4: Experimental characterization of flow regimes in unpacked reactor containing pure water and surfactant (5ppm).
: pure water, :HCTBr, :TritonX-450, :Tween40, :Brij58,
0.06
0.05
Packed
0.04
0.03
Unpacked
0.02
0.01
0
0
0.2
0.4
0.6
0.8
Ug (cm/s)
1.2
0.014
0.012
Unpacked
0.01
0.008
0.006
Packed
0.004
0.002
0
0
Fig. 6;
0.2
0.4
0.6
0.8
Ug (cm/s)
1.2
12
Packed
9
6
3
0
0
Fig. 7:
0.2
0.4
0.6
Ug (cm/s)
0.8
1.2
120
Packed
90
60
Unpacked
30
0
0
Fig. 8:
0.2
0.4
0.6
Ug (cm/s)
0.8
1.2
kLa (1/s)
0.012
0.009
Unpacked
0.006
0.003
0
0
Fig. 9:
0.2
0.4
0.6
0.8
Ug (cm/s)
1.2
Overall volumetric oxygen mass transfer coefficient (kLa) versus superficial air velocity (Ug) in riser.
: HCTBr, : TritonX-405, : Tween40, : Brij58. : water (packed)
:HCTBr, :TritonX-405, :Tween40, :Brij58. - : water (unpacked)
0.007
0.006
kLa (1/s)
0.005
0.004
0.003
0.002
0.001
0
0
1
2
3
Surfctant concentration (ppm)
Fig. 10: Overall volumetric oxygen mass transfer coefficient (kLa) versus surfactant concentration at Ug =0.6 cm/s.
:HCTBr, :TritonX-405, :Tween40, :Brij58.
0.035
+15%
0.03
0.025
-15%
0.02
0.015
0.01
0.005
0
0
0.035
Fig. 11: The predicted gas hold up data versus experimental gas hold-up
:Akita and Yoshida (1974), :Sada et al (1984), :Mouza et al (2005).
1010
0.8
0.6
0.4
0.2
Re number (unpacked)
803
777
687
627
566
Re number (packed)
1015
975
838
810
687
Remarks
Correlations
db >2.5mm
(1 g )
Sada et al (1984)
0.3<u <30cm/s
_
g
(1 g )
Mouza et al (2005)
= 0.2 Bo 8 Ga
1
12 Fr
d sp
db
2/3
1011
Remarks
Correlations
Asgharpour et al (2010)
0.118<u <2.35cm/s
Sh = 0.15Re 2 3 Sc1 2 Bo 2 3
Bird et al (2002)
Higbies model
Akita et al (1974)
Homogeneous flow
Predicted Sherwood
.
10000
1000
100
10
10
100
1000
Experimental Sherwood .
10000
Fig. 12: The predicted Sherwood number versus the experimental Sherwood numbers.
: Akita and Yoshida (1974), :Mehrnia et al (2010), : Bird et al (2002).
Figure 12 shows the predicted data versus
experimental data. Akita and Yoshidas equation [24]
and Asgharpour et al.s equation showed better
agreement with experimental data than Birds equation
which highly depends on the Bo number.
Nomenclature
Bo:
CL:
[kg/m3]
C 0:
[kg/m3]
CONCLUSIONS
C *:
[kg/m3]
dave:
Fr:
Ga:
kLa:
[mm]
N:
Re:
Sh:
Sc:
UG:
[s 1]
[m/s]
Greek Symbols
:
Gas holdup
:
[k/Pa.s]
Viscosity of phase
:
[kg/m3]
Density of phase
:
[mN/m]
Surface tension
Subscript
k
Phase, k= G: gas phase, k=L: liquid phase
1012
REFERENCES
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hydraulics
and
transport
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1014