Академический Документы
Профессиональный Документы
Культура Документы
Search
Collections
Journals
About
Contact us
My IOPscience
This content has been downloaded from IOPscience. Please scroll down to see the full text.
2013 Sci. Technol. Adv. Mater. 14 014205
(http://iopscience.iop.org/1468-6996/14/1/014205)
View the table of contents for this issue, or go to the journal homepage for more
Download details:
IP Address: 116.228.68.226
This content was downloaded on 29/09/2016 at 03:30
IOP PUBLISHING
doi:10.1088/1468-6996/14/1/014205
1. Introduction
The development of advanced steels with high strength,
good ductility and toughness has been long pursued.
Typical examples of those steels are categorized as
advanced high-strength steel including dual-phase steels,
transformation-induced plasticity (TRIP) steels and
high-manganese austenitic steels for automotive applications.
In recent years, another concept of advanced steel has gained
a great deal of attention led by the necessity for further
reducing the vehicle weight. Traditionally, the high level of
specific strength of advanced steels has been sought to be
achieved mainly by increasing the strength of the steels [14].
Content from this work may be used under the terms of the
Creative Commons Attribution-NonCommercial-ShareAlike
3.0 licence. Any further distribution of this work must maintain attribution to
the author(s) and the title of the work, journal citation and DOI.
1468-6996/13/014205+11$33.00
Printed in the UK
H Kim et al
2. Phase constitution
Phase identification within the FeAlMnC system dates
back to the earlier work of Koster and Tonn on FeAlMn
phase equilibria in 1933 [18]. After Schmatz 1959 discovery
of -manganese formation in Mn-rich FeAlMnC
alloys [19], the phase equilibria study was continued by
Krivonogov et al [20], Ishida et al [21] and Acselrad
et al [22]. Depending on the chemistry and temperature,
there are reported at least five equilibrium phases in the
FeAlMnC system: -austenite, -ferrite, -carbide,
M3 C carbide () and -Mn. -carbide is L12 ordered fcc
carbide of the type (Fe, Mn)3 AlC [12]. Recently, Chin
et al [23] and Lee et al [24] constructed a CALPHAD-type
thermodynamic description for the FeAlMnC quaternary
system by combining a newly assessed MnAlC ternary
H Kim et al
(a)
(b)
(c)
(d)
Figure 1. Phase diagrams of Fe5Mn(09)AlC alloys calculated based on the CALPHAD approach (adapted using data from [23]).
Phase boundaries show -austenite, -ferrite, -cementite and -carbide (at a fixed 5% Mn concentration) as a function of carbon content at
Al concentrations of (a) 0%, (b) 3%, (c) 6% and (d) 9%.
3.0
(a)
(b)
C a rbo n c ont ent , m ass%
3.0
2.5
2.0
1.5
1.0
0.5
2.5
2.0
1.5
1.0
0.5
0
0
10
12
14
16
18
10
12
14
16
18
Figure 2. Phase relations in Fe20MnAlC alloys (a) at 900 C and (b) 1200 C calculated based on the CALPHAD approach (adapted
using data from [23]), in comparison with experimental information [21].
H Kim et al
(58)Al, (00.3)C,
(08)Mn
Ferrite + -carbide
(-carbide
precipitates when
C and Mn
are added)
RA (Rockwell hardness)
Ferrite based
75
Austenite based
Fe-34Mn-11Al-0.98C
70
Fe-31Mn-7.8Al-0.88C
65
60
Fe-29Mn-4.9Al-0.98C
55
Fe-34Mn-7.1Al-0.5C
50
45
0
500
1000
1500
2000
H Kim et al
TE, %
110
100
90
80
70
60
50
40
30
20
10
0
200
400
600
800
1000
1200
1400
TS, MPa
Figure 4. Total elongation in tension as a function of the ultimate tensile strength in FeAlMnC-base alloys. All the data are from
solution-treated and water-quenched specimens except for high-Al TRIP steels, which were annealed at around 800 C after cold rolling,
among austentic and duplex steels. Open symbols stands for the air cooling after solution treatment at 1100 C. (TS and TE stand for
ultimate tensile strength and total elongation, respectively.)
H Kim et al
70
TE
600
60
50
500
20
0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2
200
TE
70
1100
60
1000
50
900
TS
40
700
600
30
YS
500
20
400
+ +
300
80
60
50
TS
40
30
YS
20
10
Fe-Al Binary
YS / TS, MPa
(b)
800
90
10
12
14
0
16
Al content, wt.%
1000
500
300
70
600
30
TE
700
400
Fe-(20~22)Mn-0.6C
800
40
400
1200
YS / TS, MPa
900
100
(a)
100
(b)
Fe-30Mn-0.9C
TS
900
10
70
60
TE
700
50
600
40
500
30
20
YS
300
+
200
0
0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2
10
200
0
90
80
800
400
Fe-20Mn-1C
TE, %
700
1100
90
80
YS
800
200
1000
TE, %
YS / TS, MPa
900
100
YS / TS, MPa
TS
1000
300
1100
110
(a)
TE, %
1100
TE, %
1200
10
12
14
0
16
Al content, wt.%
110
100
(C)
TE, %
90
80
Fe-(28-30)Mn-(8.5-9.4)Al-C
Fe-20Mn-(9-10)Al-C
0.8
70
60
1.0
2.0
0.6
40
1.2
0.26
30
20
10
1.06
0.6
50
0.5
1.5
0.25
0
750
800
850
900
Al content over 3%. This is possibly due to the fact that the
deformation mechanism is changed from twinning to planar
glide originating from the shearing of ordered particles. This
will be further discussed in the following section.
Figure 6(b) shows the change of mechanical
properties of single-phase austenitic Fe30Mn0.9CAl
and Fe20Mn1CAl alloys [13, 17] as a function of Al
content. Compared with Fe(2022)Mn0.6CAl alloys,
both alloys presented in figure 6(b) show the single-phase
austenitic matrix in the whole Al range considered owing
to higher contents of C and Mn. It is interesting that
there is continuity between the mechanical behavior of
Fe30Mn0.9CAl alloys and Fe20Mn1.0CAl alloys
with respect to the Al content despite a remarkable difference
in Mn content. This seems to be contrary to figure 5(c) that
indicates a beneficial influence of Mn on total elongation.
However, as mentioned, such an effect of Mn is very
sensitive to the strength level, so a direct comparison will be
difficult. Propensity of mechanical properties is comparable
with Fe(2022)Mn0.6CAl alloys, indicating that the
ultimate tensile strength has gradually decreased to show a
minimum, followed by increasing, although the Al content
with the lowest tensile strength is shifted when compared
to figure 6(a). Meanwhile, figures 5 and 6 indicate an
increase of strength and a deterioration of ductility beyond
TS, MPa
Figure 5. Effect of carbon content on the mechanical properties
of FeAlMnC alloys. Alloys were solution-treated and
rapidly cooled by oil quenching or water quenching.
(a) Fe(2830)Mn(8.59.4)AlC alloys [43, 46, 48],
(b) Fe20Mn(910Al)C alloys [17, 29] and (c) the alloys in
panels (a) and (b). Numbers in the symbols stand for the carbon
content in wt%. (YS, TS and TE stand for yield strength, ultimate
tensile strength and total elongation, respectively.)
H Kim et al
YS / TS, MPa
900
800
1300
90
1200 YS(11Al-1.8C)
60
80
1100
50
700
600
500
70
YS
60
400
300
200
100
16
50
70
TS(11Al-1.8C)
TS(10Al-1.5C)
40
1000
YS(10Al-1.5C)
30
900
800
TE, %
TS
100
YS / TS, MPa
1000
TE, %
1100
20
TE(10Al-1.5C)
10
700
TE
18
20
22
24
26
28
40
30
Mn content, wt%
TE(11Al-1.8C)
600
Cr content, wt%
Figure 7. Effect of manganese content on the mechanical
properties of Fe10Al1CMn (solid symbols) [17, 48] and
Fe3Si3AlMn (open symbols) [4]. All the alloys were
solution-treated at temperatures above 1000 C and water quenched.
Tensile tests were carried out at strain rates from 1 104 to
3.3 104 s1 at room temperature.
(a)
8.2
H Kim et al
y = -0.009x + 8.135
2
R = 0.997
8.0
Fe-Mn
7.8
7.6
Fe-5Al-Mn
7.4
y = -0.008x + 7.553
2
R = 0.994
7.2
7.0
20
24
28
32
36
40
44
48
7.4
(b)
7.3
Fe-23Mn-5Al-C
7.2
y = -0.426x + 7.339
R2 = 0.998
7.1
Fe-30Mn-5Al-C
y = -0.393x + 7.288
2
R = 0.999
7.0
6.9
0.0
0.2
(c)
Fe-30Mn-1C-Al
7.4
y = -0.101x + 7.402
R2 = 0.999
7.2
7.0
6.8
6.6
6.4
2
8.2
0.8
1.0
(d)
8.0
7.8
7.6
7.4
Fe-Mn
Fe-5Al-Mn
Fe-30Mn-5Al-C
Fe-23Mn-5Al-C
7.2
7.0
6.8
6.8
6.2
0
0.6
Mn content, wt%
7.6
0.4
10
7.0
7.2
7.4
7.6
7.8
8.0
8.2
Al content, wt%
Figure 9. Density of austenite assessed based on the lattice parameter decided by Charles et al [49]. The effect of each alloying element is
shown in panels (a)(c): (a) manganese, (b) carbon and (c) aluminum. Densities from equation (2) are compared with those from the lattice
parameter using XRD (x-ray diffraction) in panel (d).
Martensite
formation
Twinning
Dislocation
gliding (planar
gliding is
observed in
many high-Al
steels)
(2)
5. Deformation mechanism
5.1. Austenitic steels
Deformation behavior of austenitic steels is strongly
dependent on the stacking fault energy as summarized
in table 2. Strain-induced martensitic transformation
and mechanical twinning are deformation mechanisms
competitive with dislocation glide. Strain-induced martensitic
transformation is known to be dominant when the stacking
fault energy of austenite is less than about 20 mJ m2
8
8.0
8.2
H Kim et al
(a)
FCC
0 = 8.1
7.8
7.6
Lattice expansion
7.4
7.2
7.0
6.8
6.6
6.4
Fe-30Mn-1C-Al
6.2
6.0
0
10
8.0
(b)
XRD
Levitation
Picnometric
7.6
7.4
7.2
Slope: -0.097
7.0
6.8
6.6
6.4
Fe-30Mn-1C-Al
Slope: -0.101
6.2
0
12
7.8
10
12
Al content, wt.%
Al content, wt.%
Figure 10. Density as a function of the aluminum content. (a) Austenitic density of Fe30Mn1CAl alloys calculated by equation (2) with
different aluminum contents (010%). The lower linear curve represents the overall decrease in density. The upper one shows the density
reduction due to the lattice dilatation of austenite. (b) The calculated density of Fe30Mn1CAl austenitic alloys is compared with the
density of FeAl ferritic alloys [16].
H Kim et al
100 nm
Figure 11. TEM dark-field image showing the shearing of -carbide particles by slip band [32] (reproduced with permission from [32]
2010 Elsevier).
6. Conclusion
H Kim et al
References
[1] Bhadeshia H K D H 2010 Proc. R. Soc. Lond. A 466 318
[2] Fan D W, Kim H S and De Cooman B C 2009 Steel Res. Int.
80 2418
[3] Jang J H, Lee C H, Heo Y U and Suh D W 2012 Acta Mater.
60 20817
[4] Grassel O, Kruger L, Frommeyer G and Meyer L W 2000 Int.
J. Plast. 16 1391409
[5] Lee P Y, Chiu C S, Gau Y J and Wu J K 1992 High Temp.
Mater. Proc. 10 1414
[6] Shih S T, Tai C Y and Perng T P 1993 Corrosion 49 1304
[7] Saxena V K, Krishna M S G, Chhaunker P S and
Radhakrishnan V M 1994 Int. J. Press. Vessels Pip.
60 1517
[8] Zhu X M and Zhang Y S 1998 Corrosion 54 312
[9] Herrmann J, Inden G and Sauthoff G 2003 Acta Mater.
51 284757
[10] Hamada A S and Karjalainen L P 2006 Can. Metall. Q.
45 418
[11] Morris D G, Munoz-Morris M A and Requejo L M 2006 Acta
Mater. 54 233541
[12] James P 1969 J. Iron Steel Inst. 207 547
[13] Lai H J and Wan C M 1989 J. Mater. Sci. 24 244953
[14] Chen F C, Li P, Chu S L and Chou C P 1991 Scr. Metall.
Mater. 25 58590
[15] Kim Y G, Han J M and Lee J S 1989 Mater. Sci. Eng. A
114 519
[16] Frommeyer G and Brux U 2006 Steel Res. Int. 77 62733
[17] Sutou Y, Kamiya N, Umino R, Ohnuma L and Ishida K 2010
ISIJ Int. 50 8939
[18] Koster W and Tonn W 1933 Arch Eisenhuttenwes. 7 3656
[19] Schmatz D J 1959 Trans. AIME 215 1213
[20] Krivonogov G S, Alekseyenko M F and Solovyeva G G 1975
Phys. Metals Metall. 39 8692
[21] Ishida K, Ohtani H, Satoh N, Kainuma R and Nishizawa T
1990 ISIJ Int. 30 6806
[22] Acselrad O, Kalashnikov I S, Silva E M, Simao R A, Achete
C A and Pereira L C 2002 Metall. Mater. Trans. A
33 356972
[23] Chin K G, Lee H J, Kwak J H, Kang J Y and Lee B J 2010
J. Alloys Compounds 505 21723
11