HINTS/SOLUTIONS for UTC3041401

(Some Basic Concepts of Chemistry)

1.

(d)

2.

(c)

3.

(b)

4.

(d)

It contains 4 6.022 1023 atoms

5.

(a)

24 g of carbon contains 2 moles

6.

(b)

7.

(c)

8.

9.

(b)

(a)

Equivalent mass =
17. (b)

CaCO3 + 2HCl CaCl2 + CO2 +H2O

1 mole CaCO3 2 mole of HCl
1 mole CO2
1 L 1 M HCl
11.2 L CO2
1
1
mole CaCO3 1 mole HCl

mole CO2
2
2

% of C in C6H12O6 =

18. (b)

No. of atoms in a g of X =

1 mole of hydrogen gas is 2 g

6.023 1023 molecules of silver is 108 g
4.48 L of N2 gas is 5.6 g

19. (c)

Valency =

6 12
100
180
= 40%

Number of atoms present in 14 g CO

14
2 NA
=
28

20. (d)

1.12 L 2.2 g
22.4
2.2 = 44 g
1.12
Hence the gas could be N2O

Hence, M
11. (c)

22. (b)

PO 4 M3(PO4)2

No. of electrons in 18 g H2O = 6.023 1023 10

6.023 10 23 10 10 3
18
= 3.35 1026

23. (a)

H2 + Cl2 2HCl
1 : 1
:
2
11.2 L of Cl2 2 11.2 L of HCl

15. (c)

32 g S 120 g MgSO4

M
O
Ist oxide 1
3
IInd oxide 1
2
For determining x,

Formula
MxOy
M3O2
For determining y,

1 x

3 y

1 3

2 2
32
y=
=3
2

x=3

13. (a)
14. (d)

1000 u of CO2 = 103 1.6 1024 g

1 mole of Ag = 108 g
2 gram atom of Mg = 2 24 g
4.48 L of N2= 5.6 g

x g S 150 g MgSO4
150 32
x=
= 40 g
120

In 1 L (1000 g) H2O =

12. (b)

At. mass
24
=
=2
Eq. mass 12

21. (a)

From MCO3, valency of M is 2

2

a
=Z
25
4a
No. of atoms in 4a g of Y =
= 2Z
50

Its nitrate is M(NO3)2

22.4 L

10. (d)

M
5

MxOy = MO
1 mole Al2(PO4)3 contains 12 mole oxygen atoms
1
0.25 mole oxygen atoms is present in
mole
48
of Al2(PO4)3

24. (b)

1 L 2 M H2SO4 2 mole H2SO4

4 mole H+ ions

25. (c)

Mole ratio

26. (a)

Molarity =

249 g of CuSO4.5H2O 5 6.023 10

H2O molecules

23

2.5 g of CuSO4.5H2O

5 6.023 10 23
100
= 3 1022

A:B
1 5
:
1 15
No : of moles
volume of solution in L

2.45 1000
98 250
= 0.1 M

16. (a) When KMnO4 is used as an oxidising agent in

acidic medium it gets converted to Mn2+.

change in oxidation state is +7 + 2

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27. (a)

H2O(l) H2(g)
1 mole

1
O2(g)
2

No. of moles in 20g of N2 =

37. (d)

NaCl + AgNO3 NaNO3 + AgCl

58.5 g of NaCl produce 143.5 g of AgCl.
Amount of NaCl producing 2.870 g of AgCl
58.5
=
x 2.870 = 1.17 g
143 .5
1.17 x 100
% purity =
= 97.5
1. 2

38. (c)

1.435 g AgCl = 0.01 mole

= 1.08 g Ag
1.08 100
Percentage of Ag =
= 54%
2

39. (d)

The reaction is

1
mole
2

1 mole

18 mL 22.4 L + 11.2 L
18 mL 33.6 L
1.8mL 3.36 L
28. (b)

29. (c)

2 at. wt of M + 3 16 = 342
342 48
At. wt of M =
= 147
2
147
= 49
Eq. wt of M =
3
con.H SO

4
C12H22O11 2
12C + 11H2O

dehydratio n

1 mole sucrose 11 6.022 1023

molecules of H2O
342 g sucrose 11 6.022 10
molecules
23

0.513 g sucrose

30. (b)

11 6.022 10 23 0.513
342
= 0.099 1023
22
= 10

0.1 mole 0.4 g H2

1 mole 4 g H2
Hence MF = 2 EF
= C2H4N2O6

Soda lim e
CH3COOH
CH4 + CO2
0.5 mol acetic acid give 0.5 mol CH4. (8 g CH4)
Since the yield is 50%, 4 g CH4 is obtained

40. (a)

Resultant molarity, M =
=

V1M1 + V2M2
V1 + V2
300 2 + 200 3
1000 mL

= 1.2 M

31. (d)
32. (b)

20
= 0.714
28
Total number of moles in mixture i.e., in 19.2 L
19.2
=
= 0.857
22.4
No. of moles of oxygen in the mixture
= 0.857 0.714 = 0.143
Mass of oxygen = 0.143 x 32 = 4.6g

36. (c)

Zn + 2 NaOH Na2ZnO2 + H2
Zn + H2SO4 ZnSO4 + H2

33. (b)

4.44 mol C2H5OH in 1000 g water. Hence

4.44
molefraction of C2H5OH =
1000
4.44 +
18
= 0.074

34. (a)

Mole ratio C
3
12

35. (d)

0.180 g 22.414 mL

H
1
1

180 g 22414 mL 1 mole

E.F mass = 30
180
n=
=6
M.F = C6H12O6
30

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