luyn thi THPT quc gia

Mn Ha Hc

5
Cho bit nguyn t khi (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al =
27; S = 32; F =19, Si =28, P=31, S=32, Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Zn = 65; Br = 80;
Ag = 108; Ba = 137.
Cau 1. Etylbenzen tc dng vi brom khan theo t l 1 : 1 khi a ra nh sng to ra sn phm chnh c cng
thc cu to l:
CH 2

CH2

CHBrCH3

CH 2Br

CH2

CH3

CH3
Br

Br
A.
B.
C.
D.
Cau 2. Ngi ta sn xut kh nit trong cng nghip bng cch no di y?
A. Nhit phn dung dch NH4NO2 bo ha.
B. Dng photpho t chy ht oxi khng kh.
C. Chng ct phn on khng kh lng.
D. Cho khng kh i qua bt ng nung nng.
Cau 3. Cho hn hp X gm Al,Fe,Cu,Ag. Ly 9,94g X ho tan trong lng d HNO3 (l) th thot ra 3,584
kh NO (kc).Tng khi lng mui khan to thnh l:
A. 29,7 gam
B. 39,3 gam
C. 3,97 gam.
D. 39,7 gam
Cau 4. Cho a gam hn hp gm HCHO , HCOOH tc dng dd AgNO 3 /NH3 d th c 54 gam Ag kt ta.
Nu cho a gam hn hp tc dng Na2CO3 d th c 0,56 lit kh bay ra KC. Gi tr ca a l :
A. 7,6 gam
B. 9,4 gam
C. 12,7 gam
D. 5,3 gam
Cau 5. Cho Ba(OH)2 d vo dung dch cha FeCl2 , CuSO4 , AlCl3 th thu c kt ta. Nung kt ta trong
khng kh n khi lng khng i, thu c cht rn X. Trong cht rn X c cha:
A. FeO , CuO , Al2O3
B. Fe2O3 , CuO , BaSO4
C. FeO , CuO , BaSO4
D. Fe2O3 , CuO , Al2O3
Cau 6. Hp th hon ton 2,24 lt CO2 (ktc) vo 100 ml dung dch gm K2CO3 0,2M v KOH x mol/lt ,
sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch BaCl 2 (d),
thu c 11,82 gam kt ta. Gi tr ca x l:
A. 1,0
B. 1,2
C. 1,6
D. 1,4
Cau 7. Cho 3,38g hn hp X gm CH3OH, CH3COOH, C6H5OH tc dng va vi natri thy thot ra 672
ml kh (ktc). C cn dung dch ta c hn hp rn Y. Khi lng Y s l:
A. 4,04 gam
B. 3,61 gam
C. 4,7 gam
D. 4,76 gam
Cau 8. Kim loi M phn ng c vi: dung dch HCl, dung dch Cu(NO 3)2, dung dch HNO3 (c, ngui).
Kim loi M l
A. Al.
B. Zn.
C. Fe.
D. Ag.
Cau 9. Cho este c cng thc (C2H4O)n.Bit rng thu phn trong mi trng kim cho ta mui natri m khi
nung kh mui natri vi vi ti xt cho khi metan.Cng thc ph hp nht l:
A. HCOOC2H5
B. CH3COOC2H5
C. CH3COOCH3
D. HCOOC3H7.
Cu 10 : Khi nh t t n d dung dch KOH vo dung dch hn hp cha AlCl 3 v HCl,kt qu th
nghim c biu din trn th sau (s liu tnh theo n v mol)

nAl(OH)

a
0,4

0,6

2,1 b

T l x : a v b:a ln lt l:
A.4,8 v 4,4
B. 5,2 v 4,4

C. 5,0 v 2,6

nOH

D.5,4 v 4,6

Cau 11. s iu ch axit monocloaxetic no sau y ng?

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Mn Ha Hc

A. CH4C2H2 C2H5OH CH3CHO CH3COOH CH2Cl-COOH

B. C3H8 CH4C2H5OHCH3COOH CH2Cl-COOH
C. CH4 C2H2C2H4C2H5OHCH3COOHCH2Cl-COOH
D. C3H8C2H4CH3COOHCH2Cl-COOH
Cau 12. Cho 200 ml dung dch E gm AlCl 3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 700 ml dung dch
NaOH 1M, sau khi cc phn ng kt thc thu c 7,8 gam kt ta. Mt khc, khi cho 200 ml E tc dng vi
dung dch BaCl2 (d) th thu c 27,96 gam kt ta. Gi tr ca x , y ln lt l
A. 0,2 v 0,4
B. 0,3 v 0,4
C. 0,3 v 0,6
D. 0,2 v 0,6
Cau 13. Hn hp X gm MgSO4 , FeSO4 v CuSO4 c thnh phn % khi lng ca lu hunh trong X l
21,505%. C th iu ch c ti a bao nhiu gam hn hp ba kim loi Mg, Fe, Cu t 37,2 gam X?
A. 10,6 gam
B. 13,2 gam
C. 7,8 gam
D. 3,6 gam
Cau 14. Mt hirocacbon mch h A tc dng vi HCl sinh ra 2 - clo - 3 metylbutan. Tn gi ca A l:
A. 2 metylbut-1en
B. 2 metylbut-2en
C. 3 metylbut-1en
D. 3 metylbut-2en
Cau 15. Khi ly 14,25g mui clorua ca mt kim loi ch c ho tr hai v mt lng mui nitrat ca kim
loi c cng s mol, thy khc nhau 7,95g. Cng thc 2 mui l:
A. CaCl2; Ca(NO3)2
B. MgCl2; Mg(NO3)2.
C. CuCl2; Cu(NO3)2
D. FeCl2; Fe(NO3)2
Cau 16. A,B l 2 axit n chc khng no (1 lin kt C=C) ng ng k tip . Hn hp X cha A,B c
chia lm 2 phn bng nhau. Phn I tc dng va vi 0,5 lit dung dch Br2 0,1M. Phn II t chy cho ra 7,92
gam CO2. Xc nh cng thc v s mol ca A ,B trong hn hp X.
A. 0,02mol C2H3-COOH, 0,03mol C3H5-COOH
B. 0,03mol C2H3-COOH, 0,02mol C3H5COOH
C. 0,04mol C2H3-COOH ,0,06 mol C3H5-COOH
D. 0,04mol C2H3-COOH, 0,06mol C3H5COOH
Cau 17. Thc hin cc th nghim sau:(a) Nung AgNO 3 rn. (b) Nung Cu(NO 3)2 rn. (c) in phn dung
dch NaCl (d) in phn NaOH nng chy. (e) Cho dung dch AgNO3 vo dung dch Fe(NO3)2. (g) Nung kim
loi Al vi bt MgO (h) Cho kim loi Na vo dung dch CuSO 4 . (i) Cho kim loi Cu vo dung dch AgNO 3.
S th nghim sinh ra kim loi l:
A. 2
B. 6
C. 4
D. 5
2+
Cau 18. Cu hnh electron no sau y l ca cation Fe (Bit Fe c s th t 26).
A. 1s22s22p63s23p63d6
B. 1s22s22p63s23p63d5
C. 1s22s22p63s23p63d64s2
D. 1s22s22p63s23p63d54s1
Cau 19. C bao nhiu phn ng c th xy ra khi cho cc ng phn mch h ca C2H4O2 tc dng ln lt
vi Na, NaOH, Na2CO3.
A. 4
B. 3
C. 2
D. 5
Cau 20. Ha tr ca nguyn t R trong oxit cao nht bng ha tr ca nguyn t R c trong hp cht kh vi
hydro. Bit phn t khi ca oxit cao nht ny bng 1,875 ln phn t khi ca hp cht kh vi hydro. Nguyn
t R l nguyn t no sau y?
A. Si
B. C
C. S
D. N
Cau 21. em un nng 18,8 gam Cu(NO3)2 sau 1 thi gian dng li lm ngui ri cn thy khi lng cht
rn thu c nng 13,4 gam. Khi lng mui Cu(NO3)2 b nhit phn l:
A. 9,4 gam
B. 5,4 gam
C. 1,88 gam
D. 4,7 gam.
Cau 22. hidro ho 1 hidrocacbon cha no mch h thnh no phi dng 1 th tch H2 bng th tch hi
hidrocacbon ny.Mt khc t chy 1 th tch hi hidrocacbon ny thu c 10 th tch hn hp CO2 v hi
nc (cc kho cng iu kin). Hidrocacbon l:
A. C2H4
B. C3H6
C. C5H8
D. C5H10.
Cau 23. Mt hn hp X gm ru etylic v phenol tc dng vi Na d cho ra hn hp 2 mui c tng khi
lng l 25,2g.Cng lng hn hp y tc dng va vi 100ml dd NaOH 1M. S mol ca cht trong hn
hp X v th tch H2 (kc) bay ra trong phn ng gia X v Na l:
A. 0,1mol ru; 0,1mol phenol; 2,24lt H2
B. 0,2mol ru; 0,2mol phenol; 4,48lt H2
C. 0,2mol ru; 0,1mol phenol; 3,36lt H2
D. 0,18mol ru; 0,06mol phenol; 5,376lt H2.
Cau 24. Cho cc cn bng ho hc: N2 (k) + 3H2 (k) 2NH3 (k) (1) H2 (k) + I2 (k) 2HI (k) (2) 2SO2 (k) +
O2 (k) 2SO3 (k) (3) 2NO2 (k) N2O4 (k) (4) Khi thay i p sut nhng cn bng ha hc b chuyn dch l:
A. (1), (2), (3).
B. (2), (3), (4).
C. (1), (3), (4).
D. (1), (2), (4).

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Mn Ha Hc

Cau 25. Polime no sau y l sn phm do phn ng trng hp : (1) Cao su buna_S , (2) nha PVC , (3)
nilon 6,6 , (4) nha phenolfomandehit , (5) t olon , (6) t visco .
A. (1), (2), (5)
B. (1), (3), (6)
C. (3), (5), (6)
D. (2), (3), (5).
Cau 26. Ho tan m gam hn hp A gm Fe v kim loi M (c ho tr khng i) trong dung dch HCl. Sau
khi 2 kim loi tan ht, thu c 8,96 lt kh iu kin tiu chun v dung dch B. C cn dung dch B thu
c 39,6 gam mui khan. Gi tr ca m l:
A. 11,2 gam
B. 1,11 gam
C. 11,0 gam
D. 0,11 gam
Cau 27. t chy hon ton hai ancol X, Y l ng ng k tip nhau, ngi ta thy t s mol ca H 2O so
vi CO2 tng dn. Vy X, Y thuc loi ancol no di y?
A. Ancol no
B. Ancol khng no
C. Ancol thm
D. Phenol
Cau 28. Cho cc cht kh sau: SO2, NO2, Cl2, CO2.Cc cht kh khi tc dng vi dung dch natri hidroxit (
nhit thng) lun to ra 2 mui l:
A. NO2, SO2
B. CO2, Cl2
C. Cl2, NO2
D. SO2, CO2
Cau 29. Trng hp no di y hn hp cht rn khng b ha tan ht (gi thit cc phn ng xy ra
hon ton)
A. Cho hn hp cha 0,10 mol Cu v 0,10 mol Ag vo dung dch HNO3 c cha 0,5 mol HNO3.
B. Cho hn hp cha 0,10 mol Fe2O3 v 0,10 mol Cu vo dung dch HCl d.
C. Cho hn hp cha 0,10 mol Mg v 0,10 mol Zn vo dung dch cha 0,5 mol HCl.
D. Cho hn hp cha 0,15 mol K v 0,10 mol Al vo nc.
Cau 30. Nhm cc dung dch u c pH < 7 :
A. Na2CO3 , (NH4)2SO4 , HCN
B. HNO3 , FeCl2 , KNO2
C. HF , NH4HSO4 , CuSO4
D. Na2S , KHSO4 , HClO
Cau 31. Cho 119 gam oleum vo 200 gam dd H 2SO4 29,6% ta c dd mi c nng 80%. Cng thc
ca oleum l :
A. H2SO4 .2SO3
B. H2SO4 .3SO3
C. H2SO4 .5SO3
D. H2SO4 .4SO3
Cau 32. Cho cc pht biu sau v cacbohirat: (a) Glucoz v saccaroz u l cht rn c v ngt, d tan
trong nc. (b) Tinh bt v xenluloz u l polisaccarit (c) Trong dung dch, glucoz v saccaroz u ha tan
Cu(OH)2, to phc mu xanh lam. (d) Khi thy phn hon ton hn hp gm tinh bt v saccaroz trong mi
trng axit, ch thu c mt loi monosaccarit duy nht. (e) Khi un nng glucoz (hoc fructoz) vi dung
dch AgNO3 trong NH3 thu c Ag. (g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to
sobitol. S pht biu ng l:
A. 6
B. 3
C. 5
D. 4
Cau 33. Phn ng ha hc no sau y sai?:
A. O2 + 2H2S 2H2O + 2S.
B. O3 + 2KI + H2O 2KOH + I2 + O2.
C. Cl2 + 2NaOH NaCl + NaClO + H2O.
D. FeCl2 + H2S FeS + 2HCl.
Cau 34. Khi iu ch C2H4 t C2H5OH v H2SO4 c 170oC th kh sinh ra c ln SO2. Cht no sau y
c th loi b c SO2 thu C2H4 tinh khit.
A. dung dch KOH
B. dung dch Br2
C. dung dch K2CO3 \
D. dung dch thuc tm
Cau 35. Cho 9,3 gam mt ankylamin tc dng vi dung dch FeCl 3 d thu c 10,7 gam kt ta.
Ankylamin c cng thc nh th no?
A. C2H5NH2
B. C3H7NH2
C. C4H9NH2
D. CH3NH2
Cau 36. un nng hn hp gm 28g bt st v 3,2g bt lu hunh thu c hn hp X. Cho hn hp X p
hon ton vi dd HCl thu c hn hp kh Y v dd Z ( hiu sut p t 100%).Thnh phn % theo th tch ca
hn hp kh Y l:
A. 60% v 40%
B. 20% v 80%
C. 55% v 45%
D. 75% v 25%.
Cau 37. Cho 12,8 gam kim loi A ha tr II phn ng hon ton vi kh clo ta c mui B. Ha tan B vo
nc ta c 400ml dd C. Cho thanh Fe d vo dd C, sau khi phn ng mt thi gian ta thy khi lng thanh
Fe tng 0,8gam v nng FeCl2 trong dd l 0,25M. Xc nh kim loi A v nng mol/l ca mui B trong
dd C.
A. Cu, 0,25M
B. Ni, 0,5M
C. Ni, 0,25M
D. Cu, 0,5M
Cau 38. Phn ng gia: Cl2 + 2NaOH
A. Phn ng oxi ha-kh lin phn t
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NaClO + NaCl + H2O thuc loi phn ng ha hc no sau y?

B. Phn ng axit-baz
3

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Mn Ha Hc

C. Phn ng t oxi hakh

D. Phn ng oxi hakh ni phn t
Cau 39. X , Y l 2 cht ng phn. X tc dng Na, cn Y th khng tc dng. Khi t 13,8 gam hn hp
X,Y ta c 26,4 CO2 v 16,2 gam nc. X, Y c tn ln lt l:
A. ancol propylic v etylmetyl ete
B. ancol etylic v dimetyl ete
C. ancol butylic v dietyl ete
D. ancol butylic v metylpropyl ete
Cau 40. Chia m gam Al thnh hai phn bng nhau: - Phn mt tc dng vi lng d dung dch NaOH,
sinh ra x mol kh H2; - Phn hai tc dng vi lng d dung dch HNO3 long, sinh ra y mol kh N2O (sn phm
kh duy nht). Quan h gia x v y l
A. x = 2y.
B. x = 4y.
C. y = 2x.
D. x = y.
Cau 41. Cho t t dung dch NaOH 1M vo dung dch cha 26,05 g hn hp FeCl 2 v AlCl3 cho n khi
thu c kt ta c khi lng khng i th ngng li. em kt ta ny nung trong khng kh n khi lng
khng i th c 8g cht rn. Th tch dung dch NaOH 1M dng l:
A. 0,5 lt
B. 0,6 lt
C. 0,2 lt
D. 0,3 lt
Cau 42. Cho 13,4 gam hn hp gm 2 mui cacbonat kim loi nhm II ( ACO3 v BCO3) tc dng dung
dch HCl 2M th ta c 15,05 gam hn hp 2 mui clorua . Th tch dung dch HCl 2M dng l :
A. 50 ml
B. 100 ml
C. 150 ml
D. 200 ml
Cau 43. t chy 4,4 gam hn hp CH4,C2H4,C3H6,C4H10 cn a mol O2 thu c b mol CO2 v 7,2 gam
H2O. Gi tr a, b ln lt l
A. 0,5 v 0,8
B. 0,6 v 0,3
C. 0,5 v 0,4
D. 0,5 v 0,30
Cau 44. in phn dung dch cha x mol CuSO 4 v y mol NaCl (vi in cc tr, mng ngn xp).
dung dch sau in phn lm cho phenolphtalein chuyn sang mu hng th iu kin ca x v y l:
A. 2y = x
B. y > 2x
C. x > 2y
D. y < 2x
Cau 45. Hn hp kh A gm hidrocacbon X v H2 nung nng c Ni,thu c kh B duy nht.t chy
0,1mol B to ra 0,3mol CO2.Bit VA=3VB (o cng iu kin).Cng thc phn t ca X s l:
A. C3H4
B. C2H4
C. C5H8
D. C3H6.
Cau 46. Trong cc phn ng ho hc sau, phn ng no sai?
t0
t0
A. 3CO+Fe2O3 3CO2+2Fe
B. CO + Cl2 COCl2
t0
t0
C. 2CO + O2 2CO2
D. 3CO+Al2O3 2Al+3CO2
Cau 47. Thc hin cc th nghim vi hn hp X gm Fe v Cu nh sau: (a) Cho X vo bnh cha mt
lng d kh O2 un nng (b) Cho X vo mt lng d dung dch HNO 3 c, ngui (c) Cho X vo mt lng
d dung dch HCl c mt kh O2 (d) Cho X vo mt lng d dung dch FeCl3 Th nghim m Fe v Cu u b
oxi ha l:
A. (a), (c), (d)
B. (a), (b), (d)
C. (b), (c), (d)
D. (a), (b), (c)
Cau 48. Pht biu no sau y l sai?
A. Khi un nng nhit cao tt c hydroxit ca kim loi kim th u b phn hy.
B. nhit thng, tt c kim loi kim th u tc dng c vi nc.
C. Nhm bn trong mi trng khng kh v nc l do c mng oxit Al2O3 bn vng bo v
D. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim gim dn
Cau 49. Thm t t tng git n ht dung dch cha 0,04 mol K 2CO3 v 0,02 mol KHCO3 vo dung dch
cha 0,075 mol HCl. Lng kh CO2 thu c (ktc) bng :
A. 1,68 lt.
B. 0,84 lt.
C. 1,008 lt
D. 0,672 lt.
Cau 50. Cho cc pht biu sau:(a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c s mol
CO2 bng s mol H2O th X l anken. (b) Trong thnh phn hp cht hu c nht thit phi c cacbon. (c) Lin
kt ha hc ch yu trong hp cht hu c l lin kt cng ha tr. (d) Nhng hp cht hu c khc nhau c
cng phn t khi l ng phn ca nhau (e) Hp cht C 9H14BrCl c vng benzen trong phn t S pht biu
ng l
A. 4
B. 2
C. 3
D. 5

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