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PHYSICAL SETTING
CHEMISTRY
Wednesday, June 22, 2011 1:15 to 4:15 p.m., only
This is a test of your knowledge of chemistry. Use that knowledge to answer all
questions in this examination. Some questions may require the use of the Reference
Tables for Physical Setting/Chemistry. You are to answer all questions in all parts of
this examination according to the directions provided in the examination booklet.
The answers to all questions in this examination are to be written in your
separate answer booklet. Be sure to fill in the heading on the front of your answer
booklet.
All work should be written in pen, except for graphs and drawings, which should
be done in pencil. You may use scrap paper to work out the answers to the questions,
but be sure to record all your answers in your answer booklet.
When you have completed the examination, you must sign the statement printed
on the first page of your answer booklet, indicating that you had no unlawful
knowledge of the questions or answers prior to the examination and that you have
neither given nor received assistance in answering any of the questions during the
examination. Your answer booklet cannot be accepted if you fail to sign this
declaration.
Notice. . .
A four-function or scientific calculator and a copy of the Reference Tables for Physical
Setting/Chemistry must be available for you to use while taking this examination.
The use of any communications device is strictly prohibited when taking this
examination. If you use any communications device, no matter how briefly, your
examination will be invalidated and no score will be calculated for you.
DO NOT OPEN THIS EXAMINATION BOOKLET UNTIL THE SIGNAL IS GIVEN.
PS/CHEMISTRY
Part A
Answer all questions in this part.
Directions (130): For each statement or question, write in your answer booklet the number of the word or
expression that, of those given, best completes the statement or answers the question. Some questions may
require the use of the Reference Tables for Physical Setting/Chemistry.
8 At STP, both diamond and graphite are solids
composed of carbon atoms. These solids have
(1) the same crystal structure and the same
properties
(2) the same crystal structure and different
properties
(3) different crystal structures and the same
properties
(4) different crystal structures and different
properties
P.S./Chem.June 11
[2]
2NO2(g)
[3]
[OVER]
C C C C
H H H
H H O
C C C H
H H
H H O
C C C OH
H H
(1)
(3)
O H
C C
C H
H
(2)
H O
C C O
C H
(4)
P.S./Chem.June 11
[4]
Part B1
Answer all questions in this part.
Directions (3150): For each statement or question, write in your answer booklet the number of the word
or expression that, of those given, best completes the statement or answers the question. Some questions may
require the use of the Reference Tables for Physical Setting/Chemistry.
31 Compared to the atoms of nonmetals in Period 3,
the atoms of metals in Period 3 have
(1) fewer valence electrons
(2) more valence electrons
(3) fewer electron shells
(4) more electron shells
Formula A
CH3
P.S./Chem.June 11
Formula B
C2H6
[OVER]
(1)
(3)
(2)
(4)
42 During a laboratory activity to investigate reaction rate, a student reacts 1.0-gram samples of solid zinc with
10.0-milliliter samples of HCl(aq). The table below shows information about the variables in five
experiments the student performed.
Reaction of Zn(s) with HCl(aq)
Experiment
Description of Zinc
Sample
HCl(aq)
Concentration (M)
Temperature
(K)
lumps
0.10
270.
powder
0.10
270.
lumps
0.10
290.
lumps
1.0
290.
powder
1.0
280.
Which two experiments can be used to investigate the effect of the concentration of
HCl(aq) on the reaction rate?
(1) 1 and 3
(3) 4 and 2
(2) 1 and 5
(4) 4 and 3
P.S./Chem.June 11
[6]
(2)
14N
7
(3)
239Pu
94
(4)
238U
92
94
1
+ 10n 144
58Ce + 36Kr + 20n
4
234
90Th + 2He
P.S./Chem.June 11
[7]
[OVER]
Part B2
Answer all questions in this part.
Directions (5165): Record your answers in the spaces provided in your answer booklet. Some questions
may require the use of the Reference Tables for Physical Setting/Chemistry.
51 Explain, in terms of protons and neutrons, why U-235 and U-238 are different isotopes
of uranium. [1]
Base your answers to questions 52 through 54 on the information below.
The bright-line spectra for three elements and a mixture of elements are shown below.
Bright-Line Spectra
lithium
cadmium
strontium
mixture
750
700
650
600
550
500
450
400
Wavelength (nm)
52 Explain, in terms of both electrons and energy, how the bright-line spectrum of an
element is produced. [1]
53 Identify all the elements in the mixture. [1]
54 State the total number of valence electrons in a cadmium atom in the ground state. [1]
P.S./Chem.June 11
[8]
Atomic Number
Be
44
Mg
12
66
Ca
20
99
Ba
56
134
55 On the grid in your answer booklet, mark an appropriate scale on the axis labeled Ionic
Radius (pm). [1]
56 On the same grid, plot the data from the data table. Circle and connect the points. [1]
57 Estimate the ionic radius of strontium. [1]
58 State the trend in ionic radius as the elements in Group 2 are considered in order of
increasing atomic number. [1]
59 Explain, in terms of electrons, why the ionic radius of a Group 2 element is smaller than
its atomic radius. [1]
P.S./Chem.June 11
[9]
[OVER]
Concentration (mol/L)
Concentrations of
Reactants and Products
1.00
CO2(g) or H2(g)
0.73
Reactant
0.50
CO(g) or H2O(g)
0.27
0
Product
t0
t1
t2
Time
62 Determine the change in the concentration of CO2(g) between time t0 and time t1. [1]
63 What can be concluded from the graph about the concentrations of the reactants and
the concentrations of the products between time t1 and time t2? [1]
Br2 + H
C
H
Br Br
P.S./Chem.June 11
[10]
Part C
Answer all questions in this part.
Directions (6685): Record your answers in the spaces provided in your answer booklet. Some questions
may require the use of the Reference Tables for Physical Setting/Chemistry.
Base your answers to questions 66 through 68 on the information below.
Ozone, O3(g), is produced from oxygen, O2(g), by electrical discharge during thunderstorms. The unbalanced equation below represents the reaction that forms ozone.
O2(g)
electricity
O3(g)
66 Balance the equation in your answer booklet for the production of ozone, using the
smallest whole-number coefficients. [1]
67 Identify the type of bonding between the atoms in an oxygen molecule. [1]
68 Explain, in terms of electron configuration, why an oxygen molecule is more stable than
an oxygen atom. [1]
Boiling Point at
Standard Pressure
(C)
butane
0.5
ethane
88.6
methane
161.6
propane
42.1
P.S./Chem.June 11
[11]
[OVER]
Mixture 2
Composition
NaCl in H2O
Fe filings in H2O
Student
Observations
colorless liquid
no visible solid on
bottom of beaker
colorless liquid
black solid on bottom of
beaker
Other Data
mass of NaCl(s)
dissolved = 2.9 g
74 Classify each mixture using the term homogeneous or the term heterogeneous. [1]
75 Determine the volume of the Fe filings used to produce mixture 2. [1]
76 Describe a procedure to physically remove the water from mixture 1. [1]
P.S./Chem.June 11
[12]
Observation
77 State one observation that indicates Cu2+ ions became Cu atoms. [1]
78 Describe one change in the procedure that would cause the reaction to occur at a faster
rate. [1]
79 State one safety procedure the student should perform after completing the laboratory
activity. [1]
P.S./Chem.June 11
[13]
[OVER]
1
1000
P.S./Chem.June 11
[14]
PS/CHEMISTRY
PS/CHEMISTRY
PHYSICAL SETTING
CHEMISTRY
Wednesday, June 22, 2011 1:15 to 4:15 p.m., only
ANSWER BOOKLET
Student . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I Male
Sex: I Female
Teacher. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
School . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Maximum
Score
Part
A
30
B1
20
B2
15
20
Students
Score
Grade . . . . . . . . .
Raters Initials:
Rater 1 . . . . . . . . . . Rater 2 . . . . . . . . . .
Part B1
Part A
1 ............
11 . . . . . . . . . . . .
21 . . . . . . . . . . . .
31 . . . . . . . . . . . .
41 . . . . . . . . . . . .
2 ............
12 . . . . . . . . . . . .
22 . . . . . . . . . . . .
32 . . . . . . . . . . . .
42 . . . . . . . . . . . .
3 ............
13 . . . . . . . . . . . .
23 . . . . . . . . . . . .
33 . . . . . . . . . . . .
43 . . . . . . . . . . . .
4 ............
14 . . . . . . . . . . . .
24 . . . . . . . . . . . .
34 . . . . . . . . . . . .
44 . . . . . . . . . . . .
5 ............
15 . . . . . . . . . . . .
25 . . . . . . . . . . . .
35 . . . . . . . . . . . .
45 . . . . . . . . . . . .
6 ............
16 . . . . . . . . . . . .
26 . . . . . . . . . . . .
36 . . . . . . . . . . . .
46 . . . . . . . . . . . .
7 ............
17 . . . . . . . . . . . .
27 . . . . . . . . . . . .
37 . . . . . . . . . . . .
47 . . . . . . . . . . . .
8 ............
18 . . . . . . . . . . . .
28 . . . . . . . . . . . .
38 . . . . . . . . . . . .
48 . . . . . . . . . . . .
9 ............
19 . . . . . . . . . . . .
29 . . . . . . . . . . . .
39 . . . . . . . . . . . .
49 . . . . . . . . . . . .
10 . . . . . . . . . . . .
20 . . . . . . . . . . . .
30 . . . . . . . . . . . .
40 . . . . . . . . . . . .
50 . . . . . . . . . . . .
Part B1 Score
Part A Score
The declaration below must be signed when you have completed the examination.
I do hereby affirm, at the close of this examination, that I had no unlawful knowledge of the questions or answers prior to
the examination and that I have neither given nor received assistance in answering any of the questions during the examination.
Signature
For Raters
Only
Part B2
51
51
52
52
53
53
54
54
[2]
For Raters
Only
55 and 56
55
56
10
20
30
40
50
60
Atomic Number
57
57
pm
58
58
59
59
[3]
[OVER]
For Raters
Only
60
60
61
61
62
mol/L
62
63
63
64
64
65
65
Total Score
for Part B2
[4]
For Raters
Only
Part C
66 __________ O2(g)
electricity
__________ O3(g)
66
67
67
68
68
69
69
70 ______________
Weakest
intermolecular
forces
______________
______________
71
______________
Strongest
intermolecular
forces
70
71
72
72
73
73
[5]
[OVER]
For Raters
Only
74 Mixture 1:
74
Mixture 2:
75
75
cm3
76
76
77
77
78
78
79
79
80
80
81
81
82
82
[6]
For Raters
Only
83
83
84
210Po
84
42He + ____________
84
85 _________ mg
85
Total Score
for Part C
[7]
PS/CHEMISTRY
PS/CHEMISTRY
PSCH
PHYSICAL SETTING/CHEMISTRY
Wednesday, June 22, 2011 1:15 to 4:15 p.m., only
Part A
3
1 ............
2 ............
3 ............
4 ............
5 ............
6 ............
7 ............
8 ............
9 ............
10 . . . . . . . . . . . .
11 . . . . . . . . . . . .
12 . . . . . . . . . . . .
13 . . . . . . . . . . . .
14 . . . . . . . . . . . .
15 . . . . . . . . . . . .
16 . . . . . . . . . . . .
17 . . . . . . . . . . . .
18 . . . . . . . . . . . .
19 . . . . . . . . . . . .
20 . . . . . . . . . . . .
21 . . . . . . . . . . . .
22 . . . . . . . . . . . .
23 . . . . . . . . . . . .
24 . . . . . . . . . . . .
31 . . . . . . . . . . . .
32 . . . . . . . . . . . .
33 . . . . . . . . . . . .
34 . . . . . . . . . . . .
35 . . . . . . . . . . . .
36 . . . . . . . . . . . .
37 . . . . . . . . . . . .
38 . . . . . . . . . . . .
39 . . . . . . . . . . . .
40 . . . . . . . . . . . .
25 . . . . . . . . . . . .
26 . . . . . . . . . . . .
27 . . . . . . . . . . . .
28 . . . . . . . . . . . .
29 . . . . . . . . . . . .
30 . . . . . . . . . . . .
1
2
3
3
4
41 . . . . . . . . . . . .
42 . . . . . . . . . . . .
43 . . . . . . . . . . . .
44 . . . . . . . . . . . .
45 . . . . . . . . . . . .
46 . . . . . . . . . . . .
47 . . . . . . . . . . . .
48 . . . . . . . . . . . .
49 . . . . . . . . . . . .
50 . . . . . . . . . . . .
[2]
Part B2
Allow a total of 15 credits for this part. The student must answer all questions in this part.
51 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
A U-235 atom has 92 protons and 143 neutrons, and a U-238 atom has 92 protons and
146 neutrons.
A U-235 atom and a U-238 atom have the same number of protons but a different number
of neutrons.
52 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
When electrons in an excited state return to a lower energy state, specific amounts of energy are
emitted. These energies are associated with specific wavelengths of light that are characteristic
of the bright-line spectrum of an element.
Energy is emitted when excited electrons fall back to lower shells.
53 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
lithium and strontium
Sr and Li
[3]
55 [1] Allow 1 credit for marking an appropriate scale. An appropriate scale is linear and allows a trend to
be seen.
56 [1] Allow 1 credit for plotting all four points correctly 0.3 grid space. Plotted points do not need to be
circled or connected.
Example of a 2-credit response for questions 55 and 56:
120
100
80
60
40
20
10
20
30
40
50
60
Atomic Number
57 [1] Allow 1 credit for 117 pm 2 pm or for a response consistent with the students graph.
58 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
As the atomic number of elements in Group 2 increases, the ionic radius increases.
The ionic radius increases.
[4]
59 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
The valence electron shell of a Group 2 atom is lost when it becomes an ion.
A Group 2 ion has two fewer electrons than the atom from which it was formed.
60 [1] Allow 1 credit for +5.
61 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
The gaseous product is more disordered than the solid reactant.
The solid reactant is more ordered than the products.
62 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
0.27 mol/L
0.27 mol/L
63 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
Between time t1 and time t2, the concentrations of the reactants and the concentrations of the
products are no longer changing.
The concentrations of the reactants and the products remain constant.
The concentration of each reactant is 0.73 mol/L, and the concentration of each product is
0.27 mol/L.
64 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
addition
halogenation
bromination
[5]
Part C
Allow a total of 20 credits for this part. The student must answer all questions in this part.
3
O2(g)
66 [1] Allow 1 credit for __________
electricity
2
__________
O3(g).
67 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
nonpolar covalent
covalent
double covalent
68 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
Both atoms in an O2 molecule have achieved a noble gas electron configuration.
An oxygen atom does not have a stable octet of valence electrons.
69 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
fractional distillation
distillation
70 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
methane
______________
ethane
______________
propane
______________
Weakest
intermolecular
forces
CH4
______________
Strongest
intermolecular
forces
C2H6
______________
Weakest
intermolecular
forces
butane
______________
C3H8
______________
C4H10
______________
Strongest
intermolecular
forces
[6]
H N H
H
H
N H
H
74 [1] Allow 1 credit for two acceptable responses.
Mixture 1: homogeneous
Mixture 2: heterogeneous
75 [1] Allow 1 credit for 2.02 cm3. Significant figures do not need to be shown.
76 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
Heat mixture 1 until all the water evaporates.
Allow the water to evaporate.
[7]
77 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
The solution is no longer blue green.
A reddish-brown solid is formed.
78 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
Heat the solution before adding the aluminum foil.
Increase the concentration of the CuCl2 solution.
Cut the Al foil into even smaller pieces.
79 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
Thoroughly wash the lab equipment and return it to its proper storage place.
Dispose of the chemicals as directed by the teacher.
Wash hands before leaving the lab room.
80 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
The beverage is acidic because its pH value is below 7.
A pH of 3 is in the acid range on the pH scale.
81 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
bromthymol blue
bromcresol green
thymol blue
[8]
83 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
Polonium-210 is used to eliminate static electricity in machinery.
removes dust from camera lenses
84 [1] Allow 1 credit. Acceptable responses include, but are not limited to:
206 Pb
82
lead-206
[9]
[10]
Part A
Standard 1
Part B
Part C
66
75, 85
67, 68, 72, 73
78, 79
66, 68, 69, 70, 71,
74, 77, 81
83
Standard 6
Key Idea 1
Key Idea 2
Key Idea 3
Key Idea 4
Key Idea 5
82
63
Standard 7
Key Idea 1
Key Idea 2
Key Idea 3
Key Idea 4
Key idea 5
Key Idea 3
Key Idea 4
Key Idea 5
2002 Edition
83, 84, 85
70, 73
66, 69, 74, 75, 76,
77, 78, 79, 80, 81,
82
83, 84, 85
67, 68, 70, 71, 72,
73
68, 71, 72, 73, 80,
81, 85
Scale
Score
100
98
96
94
93
91
90
89
87
86
85
84
83
82
81
80
79
78
77
76
76
75
Raw
Score
63
62
61
60
59
58
57
56
55
54
53
52
51
50
49
48
47
46
45
44
43
42
Scale
Score
74
73
72
72
71
70
70
69
68
67
67
66
66
65
64
63
63
62
61
61
60
59
Raw
Score
41
40
39
38
37
36
35
34
33
32
31
30
29
28
27
26
25
24
23
22
21
20
Scale
Score
59
58
57
57
56
55
54
53
53
52
51
50
49
48
47
46
45
44
43
42
40
39
Raw
Score
19
18
17
16
15
14
13
12
11
10
9
8
7
6
5
4
3
2
1
0
Scale
Score
38
36
35
34
32
30
29
27
25
23
22
20
17
15
13
11
8
6
3
0
To determine the students final examination score, find the students total test raw
score in the column labeled Raw Score and then locate the scale score that
corresponds to that raw score. The scale score is the students final examination score.
Enter this score in the space labeled Final Score on the students answer sheet.
Beginning in June 2011, schools are no longer permitted to rescore any of the
open-ended questions on this exam after each question has been rated once,
regardless of the final exam score. Schools are required to ensure that the raw
scores have been added correctly and that the resulting scale score has been
determined accurately.
Because scale scores corresponding to raw scores in the conversion chart change from
one administration to another, it is crucial that for each administration, the conversion
chart provided for that administration be used to determine the students final score.
The chart above is usable only for this administration of the Regents Examination in
Physical Setting/Chemistry.