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09.09.2012 (PT-02)
PHYSICAL CHEMISTRY
Sol.
[Ag+] =
4 10 16
10 10
10 10
0.06
= 2.4 107
Sol.
3.
(D) Zero
Sol.
0.01 M CaCl2 gives maximum Cl ions. To keep Ksp of AgCl constant, decrease in [Ag+] will be maximum
4.
A weak base BOH (0.1 mole) is titrated with strong acid HCl (0.08 mole) than the number of H+ ion is (Kb for
BOH = 104)
(A*) 24.08 203
(B) 4 1010
(C) 6.02 1013
(D) None
Sol.
BOH
+
HCl
BCl + H2O
t=0
0.1 mole
0.08 mole
t= eq. 0.02 mole
0.08 mole
as
solution
is
buffer
so
[OH] = 104
0.02
0.08
[OH ] = 104
1
mole
4
[H ] =
10 14 4
10 4
[H+] = 4 1010
No. of H+ ion = 4 1010 6.02 1023
= 24.08 10+13
Page # 1
[HX]
5.
[X ]
= 0.2
If the value of Kb at 25C for X is 109, pH of the buffer at 25C is : (log 2 = 0.3)
Sol.
(A*) 5.7
(B) 8.3
Kb for X = 109 Ka for HX = 105
pH = pKa + log10
6.
The pH of a
(C) 9.7
pKa = 5
(D) 4.3
[X ]
= 5 + 0.7 = 5.7
[HX]
M
solution of a weak base, if its Kb value at 25C is 2.5 103, will be : [Given log 11.18 = 1.05]
20
(A) 11.95
(B*) 12
(C) 12.05
(D) 1.95
Sol.
7.
C
= 0.2
1
[OH] = C= 0.05 0.2 = 0.01
Kb =
pH = 14 2 = 12
If equal volume of following solutions are mixed, precipitation of Hg2I2 (Ksp = 2.5 1026) will occur only with :
(A) 104 M Hg22 + 10111 M I
Sol.
pOH = 2
24
10 9
10 6
= 10
IP =
= 1.25 1025 > Ksp
8
2
2
In which of the following solutions, the degree of dissociation of H2O is less than 1.8 107 % at 25 C :
Sol.
9.
Sol.
10.
Three sparingly soluble salts M2X, MX and MX3 have their solubility product in the ratio of 4: 1 : 27. Their
solubilities will be in the order :
(A) MX3 > MX > M2 X
(B*) MX3 > M2X > MX
(C) MX > MX3 > M2X
(D) MX > M2X > MX3
For
M2X , 4S13 = 4x ;
S1 = x1/3
For
MX ,
4S22 = x ;
S2 = x1/2
4
For
MX3 , 27S3 = 27x ;
S3 = x1/4
S3 > S1 > S2
Calculate the pH of a 0.1 M K3PO4 solution. The third dissociation constant of phosphoric acid is 1012.
Given (0.41)1/2 = 0.64 ; log 3 = 0.48
(A) 12.5
(B*) 12.44
(C) 12.25
(D) 12
Page # 2
Sol.
Kh =
10 14
Kw
=
= 102
K a3
10 12
Kh
=
C
as 1 h = 1, h =
Kh =
Ch 2
(1 h)
10 2
= 0.316
0.1
as h > 0.1 1 h 1
102 =
10 1 h 2
or 0.1 (1 h) = h2
(1 h)
11.
The pKa of HCN is 9.3. The pH of a solution prepared by mixture 2.5 mole of KCN and 2.5 mole of HCN in
water and making up the total volume to 500 ml is
(A*) 9.3
(B) 7.3
(C) 10.3
(D) 8.3
Sol.
12.
[Salt]
Ag+ + 2NH3
K sp
.... (1)
s2
13.
Sol.
[Ag(NH3)2]+
Kf = [ Ag ](2.5 2s)2
or,
Ag+(aq) + Cl (aq)
AgCl(s)
[Ag+] =
s
= 1012
2 . 5 2s
or, Kf Ksp =
s2
2
( 2 .5 2 s )
or, 102 =
s
2.5 2s
0.025
0.025 mol/L
1.02
What is the concentration of acetic acid which can be added to 0.5 M formic acid so that the % dissociation
of neither acid is changed by the addition. Ka for acetic acid is 1.85 10-5, Ka for formic acid = 2.4 10-4.
(A) Any concentration
(B) There can not be any concentration
(C*) 6.66 M
(D) 3.33 M
C1 1 = C2 2
K a1 C1 =
K a2 C 2
Page # 3
14.
CH3NH2 (Kb = 5 104) 0.1 mole of CH3NH2 (Kb = 5 104) is mixed with 0.08 mole of HCl and diluted to one
litre. What will be the H+ concentration in the solution? is mixed with 0.08 mole of HCl and diluted to one litre.
What will be the H+ concentration in the solution?
(A) 8 102 M
Sol.
(B*) 8 1011 M
(D) 8 105 M
so
|H+|
[Base]
.02
= 5 x 104 x
[Salt]
.08
5
x 104
4
10 14
4
= 4
= x 1010 = 8 x 10111 M Ans.
4
5
x10
5
15.
102 mole of NaOH was added to 10 litre of water. The pH will change by
Sol.
(A*) 4
Initially pH = 7
finally [NaOH] = 103
So,
(B) 3
(C) 11
(D) 7
so pOH = 3
pH = 11
(pH) = 4
16.
The sum of negative logarithm of hydrogen ion and hydroxide ion concentration at 37C : [Kw = 2.5 104]
(A) 14
(B*) Less than 14
(C) greater than 14
(D) Data insufficient.
Sol.
17.
Sol.
2 [Ag(CN)2] + Zn [Zn(CN)4]2 + 2 Ag
Tetrahedral
18.
Sol.
All the following complexes show a decreases in their weights when placed in a magnetic balance. Then
which of the these has square planar geometry :
(A) Ni(CO)4
(B*) K[AgF4]
(C) Na2[Zn(CN)4]
(D) None of these
K [AgF4] is square planar because Ag() is 4d8 and complex is diamagnetic.
19.
Sol.
The complex is
Page # 4
20.
Sodium nitroprusside is a diamagnetic substance and a important laboratory reagent for the testing of
sulphide ions. The metal involved in the complexation in this is present in which of the following hybridisation
state :
(A) sp3
(B) dsp2
(C*) d2sp3
(D) sp3d2
Sol.
21.
Sol.
22.
Sol.
23.
The octahedral complex [Rh(NO2) (SCN) (en)2]+ can exist in a total number of isomeric forms including
stereoisomers :
(A) 2
(B) 4
(C) 8
(D*) 12
Sol.
(9)
(10)
(11)
(12)
24.
Sol.
Ni2+ + 4 NH3
k=
[Ni(NH3)4]2+
[Ni (NH3 ) 4 ] 2
[Ni 2 ] [NH3 ] 4
[Ni 2 ]
But
= 1.6 106
Ni 2
or
[Ni (NH3 ) 4 ] 2
k=
1.6 106
10 6
1.6 (0.5)4
= 107
Page # 5
25.
6
0
In which of the following complex ion, the metal ion will have t 2g , e g configuration according to CFT::
Sol.
(A) [FeF6]3
(B) [Fe(CN)6]3
(C*) [Fe(CN)6]4
In [Fe(CN)6]4 ; Fe() is t2g6 , eg0 due to strong ligands.
26.
Spin only magnetic moment of a complex having CFSE = 0.6 0 and surrounded by weak field ligands can
be
(A) 1.73 BM
(B) 4.9 BM
(C*) both (A) & (B)
(D) None of these
Sol.
The options can give CFSE = 0.6 0 with weak field ligands
27.
Sol.
28.
d4 and d9.
OH
H3C
C = N
CoCl2
is :
C=N
H3C
OH
29.
Which of the following pair of complexes have the same EAN of the central metal atoms/ions?
(A) [Cu(NH3)4]SO4 and K3[Fe(CN)6]
(B) K4[Fe(CN)6] and [Co(NH3)6]Cl3
(C) K3[Cr(C2O4)3] and [Ni(CO)4]
(D*) all of the above
Sol.
(A) [Cu(NH3)4]2+ = 29 2 + 8 = 35
[Fe(CN)6]3 = 26 3 + 12 = 35
(B) [Fe(CN)6]4 = 26 2 + 12 = 36
[Co(NH3)6]3+ = 27 3 + 12 = 36
(C) [Cr(C2O4)3]3 = 27 3 + 12 = 36
[Ni(CO)4] = 28 + 8 = 36
30.
In the reaction [CoCl2(NH3)4]+ + Cl [CoCl3(NH3)3] + NH3 only one isomer of product is obtained .
Hence the initial complex must be
Sol.
(C) both
Cl
symmetrical
Page # 6
Cl
replacable positions
Aq.
31.
AgNO 3
(A)
' X'
(Major )
product :
(B)
Sol.
32.
(C*)
(D)
SOCl
2
ether
In the above reaction which phenomenon will take place :
(A) Inversion
(B*) Retention
(C) Racemisation
Sol.
33.
Sol.
(A*) CH3 S
Nucleophilicity size
(B)
(in a group).
(D) Isomerisation
(C) Et3N
(D)
O
||
(C) S O CH3
||
O
O
||
(D*) O S CH3
||
O
NaCN
34.
(A) OH
(B)NH2
Sol.
35.
Page # 7
(A)
(B*)
Sol.
36.
Sol.
(C)
(D)
[3RX] 21 OH
r2
=
r1
[RX] [OH ]
r2 = 1.5 r1
37.
Sol.
In which of the following reaction the product obtained is t-butyl methyl ether ?
conc.H2SO4
(A) CH3OH + HO CH2CH3
(B)
(C*)
(D)
t-butyl methyl ehter is a mixed ether and for the preparation of mixed ethers in high yield the essential
condition is the use of primary alkyl halide.
Thus,
NaBr
Sol.
PCl
alc KOH
CH3CH2CH2OH
A B
B is identified as :
(A) propanal
(B) propane
(C) propyne
(D*) propene
PCl or SOCl or
5
2 RCl
ROH
5
CH3 CH CH2
CH3CH2CH2OH
HCl
Alkene
B is an alkene (propene)
Page # 8
39.
Sol.
The only alcohol that cannot be prepared by the indirect hydration of alkene is :
(A) ethyl alcohol
(B) propyl alcohol
(C) isobutyl alcohol
(D*) methyl alcohol
Methyl alcohol cannot be prepared by hydration of alkene as simplest alkene has two carbons so alcohol of
at least two carbon atoms can be formed.
H
H2C = CH2
(H2SO 4 )
H3 C
HSO4
|
H2 C
H3 C
HOH
|
H2SO 4 CHCH2OH
CH2OSO 3H
Ethanol
H2C = CH CH3
HOH
H2SO4
(Markowniko ff 's
rule)
40.
Sol.
H3 C CH CH3 HO CH 2 CH 2 CH3
|
Minor product
OH
Major product
(D) 2methylpropanol1
(a)
(b)
(c)
(d)
choice (C) is the answer as it is 3 alcohol and rate of reaction is fastest for 3 alcohol.
Page # 9
2.
Sol.
3.
Sol.
Sol.
5.
10
[(x + 1) + (x + 28)] = 155 x = 1
2
If the arithmetic and geometric means of a and b be A and G respectively, then the value of A G will be
ab
(A)
a
Sol.
ab
Then A G =
Sol.
a b
(C*)
2
ab
(B)
2
6.
(D) 8
If the 9th terms of an A.P. be zero, then the ratio of its 29th and 19th term is
(A) 1 : 2
(B*) 2 : 1
(C) 1 : 3
(D) 3 : 1
Given that 9th term = a + (9 1) d = 0 a + 8d = 0
Now ratio of 29th and 19th terms
=
4.
(D) multiple of 5
(D)
2ab
ab
ab
2
ab
a b 2 ab
( a ) 2 ( b ) 2 2 ( a )( b ) a b
=
=
=
ab
2
2
2
th
position
(D) 12
7.
(A)
n (n 2 1)
2
n n 1
1
2
1 1 1
(B*)
2
2
1 2 2
n (n 1)
2
2(n n 1)
3
2
1 3 34
(C)
......... to n terms is
n (n 2 1)
2
2(n n 1)
(D)
n2 n
2
Page # 1
Sol.
1
2
1 1 1
Then Tn =
2
2
1 2 2
3
2
1 3 34
.........
n
2
1 n n
2 2
(1 n ) n
(n n 1)(n n 1)
1
1
1
2
2 n n 1 n n 1
1
1
1
= 2 1 (n 1) n 1 n(n 1)
Now
r 1
1 1
1
1 1 1 .2 +
1
2
1 1
1
1 1 .2 1 2 . 3 +
1
1
1
1
1
1 2.3 1 3.4 +...+ 2 1 (n 1) n 1 n(n 1)
n (n 1)
1
1
= 2 1 1 n (n 1) =
2(n 2 n 1)
8.
Sol.
9.
Sol.
The number of common terms to the sequence 17, 21, 25, .......417 and 16, 21, 26,.....466 is
(A) 21
(B) 19
(C*) 20
(D) 22
Common terms are 21,41,61,......(d = LCM of 4,5 = 20)
tn 417
21 + (n 1)20 417
n 20.8
max value of n = 20
If a, b, c are in A.P. as well as in G.P., then
(A) a = b c
(B) a b = c
ac
2
As given b =
(C) a b c
(D*) a = b = c
......(i)
and b2 = ac
(a + c)2 = 4ac (a c)2 = 0 a = c
putting a = c in (i) we get b = c
a=b=c
1
10.
(A) G2
Sol.
(B*)
As given G =
xy
G2 x 2
1
= xy
11.
Sol.
G2 y 2
1
G
(C)
G2 x 2
1
G2 y 2
2
G2
(D) 3G2
xy x 2
xy y 2
1 1
1
1
=
= 2
xy
x
y
G
If a1, a2, a3,........ are in A.P. such that a1 + a5 + a10 + a15 + a20 + a24 = 225, then
a1 + a2 + a3 + ..... + a23 + a24 is equal to
(A) 909
(B) 75
(C) 750
(D*) 900
a1 + a5 + a10 + a15 + a20 + a24 = 225
3 (a1 + a24) = 225
24
[a1 + a24] = 12 75 = 900
2
Page # 2
12.
There are n distinct points on the circumference of a circle. The number of pentagons that can be formed
with these points as vertices is equal to the number of possible triangles. Then the value of n is(A) 7
(B*) 8
(C) 15
(D) 30
Sol.
C5 = n C3
C 5 = n Cn 3
5=n3
n=8
13.
Sol.
14.
Sol.
15.
Sol.
A question paper consists of two parts A and B. Part A has 4 questions in which each question has an
alternative and part B has 3 questions without any alternative. The number of ways to attempt paper when
at least one question must be attempted for each part is (are)
(A) 561
(B*) 560
(C) 648
(D) 127
Required ways = (34 1)(23 1) = 560
Number of ways such that 6 boys and 3 girls can be seated such that there is exactly one boy in between
any two girls
(A) 50400
(B*) 21600
(C) 10800
(D) 36000
Number of ways = 6! 5 3!
All letters of the word 'RACHIT' are permuted in all possible ways and the words so formed (with or without
meaning) are written as in dictionary, then the 484th word is(A) RACHIT
(B*) RACITH
(C) RACTHI
(D) RACIHT
ACHIRT
5!
CAHIRT
5!
HACIRT
5!
IACHRT
5!
RACHIT
is 481th word RACHIT
RACHTI is 482th word
RACIHI is 483th word
RACITH is 484th word
16.
The number of ways in which 6 different red roses and 3 different white roses can form a garland so that all
the white roses come together is
(A*) 2160
(B) 2165
(C) 2155
(D) 4320
Sol.
ways =
17.
There are 10 points in a plane of which no three points are collinear and 4 points are concyclic. The number
of different circles that can be drawn through at least 3 of these points is
(A) 116
(B*) 117
(C) 120
(D) 115
Total number of solutions = 10C3 4C3 + 1 = 117.
Sol.
18.
(7 1)! 3 !
= 2160
2
How many different arrangements can be made out of the letters in the expansion A2B3C4, when written
in full length ?
9!
(A*) 2! 3 ! 4 !
Sol.
Sol.
9!
2. 3 . 4
(C) 2 ! 3 ! 4
9!
(D) 2! 3 ! 4 !
19.
(B)
No. of arrangements =
(2 3 4)!
9!
2! 3 ! 4 ! = 2! 3 ! 4 !
20.
Sol.
21.
Sol.
22.
Sol.
Total number of ways in which 15 identical blankets can be distributed among 4 persons so that each of
them gets at least two blankets, equal to
(A*) 10C3
(B) 9C3
(C) 11C3
(D) none of these
Let 4 persons recieve B1, B2 , B3, B4 number of blankets
B1 + B2 + B3 + B4 = 15
{B1,B2 , B3 ,B4 2}
Thus number of ways = 10C3
Let S (k) = 1 + 3 + 5 +.......+ (2k 1) = 3 + k2. Then which of the following is true ?
(A) S(1) is correct
(B*) S(k) S (k + 1)
(C) S(k)
S(k + 1)
(D) Principle of mathematical induction can be used to prove the formula
S(k) = 1 + 3 + 5 + ..... + (2k 1) = 3 + k2
put k = 1 in both sides, we get
LHS = 1
and
RHS = 3 + 1 = 4
LHS RHS
Put
(k + 1) in both sides in the place of k
LHS = 1 + 3 + 5 + .... + (2k 1) + (2k + 1)
RHS = 3 + (k + 1)2 = 3 + k2 + 2k + 1
Let
LHS = RHS
1 + 3 + 5 + .......... + (2k 1) + (2k + 1)
= 3 + k2 + 2k + 1
1 + 3 + 5 + ...... + (2k 1) = 3 + k2
If S(k) is true, then S(k + 1) is also true.
Hence,
S(k)
S(k + 1).
If the coefficients of second, third and fourth terms in the expansion of (1 + x)2n are in A.P., then which of the
following is TRUE.
(A) n2 9n + 7 = 0
(B) 3n2 9n + 7 = 0
(C) 3n2 + 9n + 7 = 0
(D*) 2n2 9n + 7 = 0
2n
2n
2n
C1 , C2 , C3 are in A.P.
2n2 9n + 7 = 0
9
23.
3 2 1
is
The term that is independent of x in the expansion of x
3x
2
5
3 1
9
(A) C 6
2 3
9
Sol.
3 2 1
x
=
3x
2
r 0
1
9
(B*) C3
6
3
Cr x 2
2
9 r
3x
3 1
9
(C) C 4
2 3
3 13
9
(D) C 6
2 3
3 1
1
Required term = C 6 = 9 C 6
2
3
24.
(A) 21
Sol.
Tr+1 =
=
20
20
Cr (21/5)20r ( 3 )r
Cr . 2
r
5
. 32
r
r
and
are integers
s
5
2
r is multiple of 10
0 r 20
r = 0 ,10, 20
Thus sum of rational terms = T1 + T11 + T21 = 20C0 24 + 20C10 22. 35 + 20C20 . 310
This is more than 21, 84, 97
Page # 4
25.
3 2003
The value of 28 where {.} denote the fractional part, is equal to
15
28
2003
3
= 32001.32
= 9(27)667
= 9(28 1)667
(A)
Sol.
(B)
= 9[ 667 C0 28667 +
5
28
19
28
(C*)
(D)
9
28
667
28
26.
10
1
x
(A)
10
C1
1
x
(B*)
T10 2
10
is
C5
(C)
1
x
10
C6
(D)
10
C 7x .
= T5 + 1 = 10C5x10 5 = 10C5.
Sol.
Middle term =
27.
Sol.
1
= (1 x)2
(1 + x + x + ...) =
1 x
2
Tr
+1
(2)(3)......(2 (r 1))
(x)r
r!
coefficient of xr = r + 1
coefficient of xn = n + 1
2m
28.
If a2m =
2m
1
2m
r 0
Cr
, then
r 0
Sol.
E=
r 0
29.
Sol.
2m
Cr
r
2m
Cr
equals
(B) 2ma2m
2m
r 0
2m
2m r
2m
Cr
(C*) ma2m
2E =
r 0
r 2m r
2m
Cr
(D)
2m
= 2m
r 0
m
am
2
1
2m
Cr
(D*) 000
Page # 5
30.
If the lines represented by x2 2pxy y2 = 0 are rotated about origin through an angle , one in clockwise
direction and other in anticlockwise direction, then the equation of the bisectors of the angle between the
lines in new position is
(A) px2 + 2xy + py2 = 0 (B) px2 2xy + py2 = 0 (C) px2 2pxy py2 = 0 (D*) px2 + 2xy py2 = 0
Sol.
Bisectors of x2 2pxy y2 = 0 is
xy
x2 y2
=
p
2
31.
If 3a + 2b + 6c = 0, then the family of straight lines ax + by + c = 0 passes through a fixed point whose
coordinates are given by
1 1
(A*) ,
2 3
Sol.
32.
(B) (2, 3)
(C) (3, 2)
1 1
(D) ,
3 2
3a 2b
=0
ax + by +
6
6ax + 6by 3a 2b = 0
a(6x 3) + b(6y 2) = 0
x = 1/2, y = 1/3
15
2
3
10
Sol.
Distance =
33.
A ray of light passing through the point A (1, 2) is reflected at a point B on the x-axis and then passes
through C (5, 3) . Then the equation of AB is(A*) 5x + 4y = 13
(B) 5x 4y = 3
(C) 4x + 5y = 14
(D) 4x 5y = 6
32 42
Sol.
34.
equation of AB is
4y + 5x = 13
y+3=
5
(x 5)
4
If bx + cy = a, where a, b, c are the same sign, be a line such that the area enclosed by the line and the
axes of reference is
1
unit2, then
8
a
, c are in A.P..
2
Page # 6
]Sol.
bx + cy = a
b
c
x+ y=1
a
a
x
y
+
=1
a
a
b
c
Area of OAB =
1
(given)
8
1
1 a a
. .
=
8
2 b c
a2
1
=
bc
4
35.
In a ABC if A is (1, 2) and equation of the medians through B and C are x + y = 5 and x = 4 respectively
then B is
(A) (1, 4)
(B*) (7, 2)
(C) (4, 1)
(D) (2, 7)
Sol.
1 b 4
=4
3
b=7
So B (7, 2)
36.
Sol.
Let B1 = 3x + 4y 7 = 0 & B2 4x 3y 14 = 0 are angle bisectors of the angle between the lines L1 = 0 &
L2 = 0 in which L1 is passes through the point (1, 2) then
(A*) B1 is acute angle bisector
(B) B2 is acute angle bisector
(C) B1 & B2 both are right angle bisector
(D) Data is insufficient
Let d1 & d2 are the distance of point (1, 2) from the bisector B1 & B2.
d1 =
d2 =
387
5
4 6 14
4
5
16
5
5
d1 < d2
If P is a point (x, y) on the line y = 3x such that P and the point (3, 4) are on the opposite sides of the
line 3x 4y = 8, then
(A*) y <
8
5
(B) y >
8
5
(C) y >
11
5
(D) y <
1
5
Page # 7
Sol.
38.
Sol.
3x 4y 8 > 0
5y < 8
y
3 4y 8 > 0
3
y<
8
5
If the lines ax + 12y + 1 = 0, bx + 13y + 1 = 0 and cx + 14y + 1 = 0 are concurrent, then a, b, c are in(A) H.P.
(B) G.P.
(C*) A.P.
(D) None of these
Since the given lines are concurrent,
a 12 1
b 13 1
=0
c 14 1
c b
1
2
(B)
3
3
Equation of the line through the point (2, 2)
Its y-intercept =
Sol.
(D*)
4
3
4
. [Putting x = 0]
3
The line segment joining the points (1, 2) and (k, 1) is divided by the line 3x + 4y 7 = 0 in the ratio
4 : 9, then k is(A*) 2
(B) 2
(C) 3
(D) 3
L : 3x + 4y 7 = 0
L (1, 2) : L (k, 1) = 4 : 9
(3 + 8 7) : (3k + 4 7) = 4 : 9
4 : (3k 3) = 4 : 9
k = 2.
Sol.
(C) 1
1
(x 2)
3
x 2 3x
41.
=0
3y 6 = x 2
x 3y + 4 = 0
40.
A line passes through the point (2, 2) and is perpendicular to the line 3x + y = 3. Its y-intercept is(A)
Sol.
13 1
39.
a b 1 0
x 1 x 3
x 1
2x
x3
x4
x 3 then t is equal to
3x
(B) 20
px + qx + rx + sx + t =
(C) 15
x 2 3x
x 1 x 3
x 1
2x x3
x3
x4
(D*) 21
3x
Putting x = 0
t=
42.
3
3 = 21
0
Sol.
=0
Applying R2 R2 R1, R3 R3 R1
1
2a
0 3b 2a b a = 0
0 4c 2a c a
2ac = bc + ab
log a p 1
43.
If a, b, c are pth, qth and rth, terms of a G.P., then log b q 1 equals log c r 1
(A*) 0
Sol.
(B) 1
(D) pqr
log A q 1
log A
= 0 + log R
r 1
(p 1) logR p 1
(q 1) logR q 1
(r 1) log R
p 1 p 1 1
q 1 q 1 1
r 1
=0
[by C2 C1]
r 1 r 1 1
44.
logx y log x z
logz x logz y
(A*) 0
(B) 1
1
Sol.
(C) 2
logx y log x z
logz x logz y
45.
log y z
1
r2
(B*) 2
The number of values of ' r ' satisfying the equation, 39 C3r 1 39C
(A) 1
log y z is
(C) 3
= 39 Cr 2 1 39C3r is
(D) 4
Page # 9
Sol.
39
C 3r 1 39 Cr 2 39 C r 2 1 39 C 3r
40
C2r =
40
r2 = 3r or
39
C 3r 1 39C3r =
39
C r 2 1 39 Cr 2
Cr 2
r = 0, 3
or r + 3r = 40 r = 5, 8
Page # 10
BITSAT(XII)_PT-2_Pg.No # 1
BITSATXII/XIII
PT02
1.
(B)
3 RT
M
(C)
8RT
M
(D)
2RT
M
Sol.
Average velocity of a molecule at any temperature is zero because of its random motion.
2.
The ratio of r.m.s. speed to the r.ms. angular speed of a diatomic gas at certain temperature is:
(assume m = mass of one molecule, M = molecular mass, = moment of inertia of the molecules)
(A)
Sol.
3
2
(B)
3I
2M
(C*)
3I
2m
(D) 1
1
3
mV 2 kT
2
2
1 2 2
kT
2
2
V
3
2m
3.
A gas mixture consists of 2 moles of oxygen and 4 moles of argon at temperature T. Neglecting all
vibrational modes, the total internal energy of the system is:
(A) 4 R T
(B) 5 R T
(C) 15 R T
(D*) 11 R T
Sol.
4.
Sol.
f
nRT
2
5
3
RT + 4 RT = 11 RT.
T.
2
2
Maxwells velocity distribution curve is given for the same quantity at two different temperatures. For
the given curves.
(A) T 1 > T 2
(B*) T 1 < T 2
(C) T1 T2
Higher is the temperature greater is the most probable velocity.
(D) T 1 = T 2
5.
In a process the density of a gas remains constant. If the temperature is doubled, then the change in
the pressure will be:
(A*) 100 % Increase
(B) 200 % Increase
(C) 50 % Decrease
(D) 25 % Decrease
Sol.
We have
PM
RT
P1M
P2M
=
RT1
RT2
P1 P2
T1 2T1
P2 = 2P1
6.
BITSAT(XII)_PT-2_Pg.No # 2
Sol.
PV = n RT
12 4
8.31 300
nRT
P=
= 4 2
= 6.25 105 Pa
V
20 10 3
7.
In an experiment the speeds of any five molecules of an ideal gas are recorded. The experiment is
repeated N times where N is very large. The average of recorded values, is :
8RT
2RT
3RT
RT
(B)
(C)
(D)
M
M
M
M
Sol. When speed of 5 molecules which are selected randomly, then the average is most likely to be equal to
the most probable speed.
(A*)
Sol.
9.
2 RT
.
M
P-V diagram of a cyclic process A B C A is shown in figure. The temperature of the gas will be
maximum at :
(A) A
(B) B
(C*) a point between A and B
(D) a point between B and C
Temperature at points A and B are equal. A to B temperature first increases then decrease.
On an X temperature scale, water freezes at 125.0 X and boils at 375.0 X. On a Y temperature
scale, water freezes at 70.0Y and boils at 30.0Y. The value of temperature on X-scale equal to the
temperature of 50.0Y on Y-scale is :
&
(A) 455.0 X
Sol.
10.
Sol.
(B) 125.0 X
(C*) 1375.0 X
(D) 1500.0 X
X ( 125 )
Y ( 70 )
=
500
40
For
Y = 50
X = 1375.0X
The amount of heat supplied to decrease the volume of an ice water mixture by 1 cm 3 without any
change in temperature, is equal to : (ice = 0.9, water = 80 cal/gm)
(A) 360 cal
(B) 500 cal
(C*) 720 cal
(D) None
x gm ice convert into x gm water
x
0 .9
x=1 x=
=9
0 .9
0 .1
Q = 9 80 = 720 cal
11.
n moles of a gas filled in a container at temperature T is in equilibrium initially. If the gas is compressed
slowly and isothermally to half its initial volume, the work done by the atmosphere on the piston is:
BITSAT(XII)_PT-2_Pg.No # 3
nRT
2
(A*)
Sol.
(B)
nRT
2
(C) n R T n 2
(D) n R T l n 2
As ;
&
V
................(i)
2
Initially gas in container is in thermodynamic equilibrium with its surroundings.
Pressure inside cylinder = Patm
PV = nRT
PatmV = nRT
Patm
nRT
V= P
atm
or
Putting in (1),
W=
12.
nRT
2
(A)
63
P
25 0
(B*)
73
P
25 0
(C)
48
P
25 0
Sol.
AN = 3v0 cos2 37
PB =
P0
v0
16
v 0 3v 0
25
48
= 1
25
= P0(73/25) Ans.
13.
(B)
A vessel contains an ideal monoatomic gas which expands at constant pressure, when heat Q is given
to it. Then the work done in expansion is:
(A) Q
(B)
3
Q
5
(C*)
2
Q
5
(D)
2
Q
3
BITSAT(XII)_PT-2_Pg.No # 4
.Sol.
14.
A therm odynam ic process of one m ole ideal m onoatom ic gas is shown in figure. The
efficiency of cyclic process ABCA will be :
(A) 25%
Sol.
2
5
nR T and W= PV = nRT = Q
5
2
W=
(B) 12.5%
(C) 50%
(D*)
100
%
13
1
1
P V =
RT 0 .
2 0 0
2
13
RT 0
2
1
P0 V0
2
13
13
P0 V0
RT0
Efficiency = 13
100
2
2
P0 V0
2
=
15.
Sol.
16.
1
100 = 7.7 %
13
Ans.
1 mole of an ideal gas undergoes an isothermal expansion as energy is added to it as heat Q. Graph
shows the volume V versus Q. The gas temperature is nearly equal to : (use R = 8.31 J/K.mole)
(A) 208.4 K
(B) 268.2 K
For isothermal process
v2
Q = nRT n
v1
1800 = 1 8.3 T n z
get
T = 312.6 K
(C*) 312.6 K
(D) 353.8 K
Curve in the figure shows an adiabatic compression of an ideal gas from 15 m3 to 12 m3, followed by an
isothermal compression to a final volume of 3.0 m3. There are 2.0 moles of the gas. Total heat supplied to
the gas is equal to : (n2 = 0.693)
BITSAT(XII)_PT-2_Pg.No # 5
p(Pa)
400
3
Sol.
V(m )
12 15
(A) 4521 J
(B) 4521 J
(C*) 6653 J
(D) 8476 J
There is no heat transfer in adiabatic compression. In isothermal process
pwafd : ) ks"e laihMu esad ksbZm"ekLFkkukUrj.k ughagksrk gSA lerkih izf ;k esa
Q=W
= P1V1 ln
= 400 x 12 ln
17.
1
= 6653 J
4
V2
V1
Two bodies A and B have emissivities 0.5 and 0.8 respectively. At some temperatures the two bodies
have maximum spectral emissive powers at wavelength 8000 and 4000 respectively. The ratio of
their emissive powers at these temperatures is:
5
5
(B) 10
(C)
(D) None of these
128
16
Let the body have temperatures T 1 and T 2 respectively at wavelength 1 = 8000 and 2 = 4000.
1T1 = 2T2
or
8000 T 1 = 4000T 2
(A*)
Sol.
T1
1
T2 = 2
Emissive power = e AT 4
18.
e1T14
0 .5
1
4 =
0 .8
e 2 T2
2
5
128
N(< 100) molecules of a gas have velocities 1, 2, 3........ N km/s respectively. Then
(A) rms speed and average speed of molecules is same.
(B) ratio of rms speed to average speed is (2N + 1)(N + 1)/6N
(C) ratio of rms speed to average speed is (2N + 1)(N + 1)/6
(D*) ratio of rms speed to average speed of molecules is 2 ( 2N 1)
Sol.
Vrms =
Vrms =
Vavg =
12 22 .......... N2
N
N(N 1) (2N 1)
6N
(N 1) ( 2N 1)
6
N (N 1)
N1
V1 V2 ........ VN
1 2 ........ N
=
=
= 2
2
N
N
N
Vrms
Vavg =
( 2 N 1)
6 (N 1)
6(N 1)
BITSAT(XII)_PT-2_Pg.No # 6
19.
A solid spherical black body of radius r and uniform mass distribution is in free space. It emits power
P and its rate of colling is R then
(A) R P r2
Sol.
(B*) R P r
(C) R P 1/r2
(D) R P
1
r
P AT 4
P r 2.
Also
ms
dT
AT
T4
dt
dT
1
=R
dt
r
A black body emits radiation at the rate P when its absolute temperature is T. At this temperature the
wavelength at which the radiation has maximum spectral emissive power is 0. If at another temperature
T the power radiated is P and wavelength at maximum spectral emissive power is 0 then
2
(A*) P T = 32PT
(B) P T = 16PT
(C) P T = 8PT
(D) P T = 4PT
Sol.
&
P T4
T
1
P
P = 16 P.
P T = 32PT
4
21.
Thermal coefficient of volume expansion at constant pressure for an ideal gas sample of n moles having
pressure P0, volume V0 and temperature T 0 is
R
(A) P V
0 0
Sol.
(B)
P0 V0
R
1
(C*) T
0
1
(D) n T
0
[Easy]
PV = nRT
PdV = nRdT
=
1 dV
V dT
and
dV nR
dT
P
1
T
1
= T
0
22.
A solid sphere of iron at 2C is lying at the bottom of a bucket full of water at 2C. If the temperature of
the water is increased to 3C, the buoyant force on the sphere due to water will
(A*) Increase
(B) Be unchanged
(C) Decrease
(D) Increase or decrease depends upon the numerical values of coefficient of expansion of water and
iron.
Sol.
As the temperature of water is increased from 2C to 3C the density of water increases (remember
anamolous behaviour of water), also the volume of sphere increases. Therefore bouyant force on sphere
due to water shall increase.
23.
The lengths of two metallic rods at temperatures are LA and LB and their linear coefficient of expansion are
A and B respectively. If the difference in their lengths is to remain constant at any temperature then
(A) LA/LB=A/B
(B*) LA/LB=B/A
(C) A=B
(D) AB=1
Change in LA = change in LB
i.e.
LA = LB
AT LA = BTLB
or
ALA = BLB .
Sol.
BITSAT(XII)_PT-2_Pg.No # 7
24.
Two identical long, solid cylinders are used to conduct heat from temp T 1 to temp T 2. Originally the
cylinder are connected in series and the rate of heat transfer is H. If the cylinders are connected in
parallel then the rate of heat transfer would be :
(A) H /4
(B) 2H
(C*) 4H
(D) 8H
Sol.
25.
A pendulum clock (fitted with a small heavy bob that is connected with a metal rod) is 5 seconds fast
each day at a temperature of 15C and 10 seconds slow at a temperature of 30C. The temperature at
which it is designed to give correct time, is
(A) 18C
(B*) 20C
(C) 24C
(D) 25C
Sol.
R
. It has reduced by a factor of
2
1/4 so rate of heat transfer would be increased by a factor of 4, keeping other parameters same.
Therefore
1
T
2
1
(T 0 15) (24 hrs) = 5
2
1
(30 T 0) (24 hrs) = 10
2
on solving T 0 = 20C
and
26.
10 9
(-m)1, has thickness t = 2 mm and radius R = 10 cm.
In an arrangement, its inside surface is kept at a lower potential than its outside surface. The resistance
offered by the shell is equal to A shell, made of material of electrical conductivity
+
(A) 5 x 1012
(C) 5 x 1012
t
1
.
4R 2
Using values R = 5 x 1011
Sol.
R=
27.
(A) 20
Hint :
(D*) 5 x 1011
(B) 5.4
(C) 12
(D*) 4.5
BITSAT(XII)_PT-2_Pg.No # 8
28.
Sol.
29.
Sol.
30.
< 18
The terminal voltage across a battery of emf cannot be:
(A) 0
(B) >
(C) <
(D*) none of these is correct
Termianal potential across battery is :
ir
Ideal battery or if i = 0.
In the circuit shown the readings of ammeter and voltmeter are 4A and 20V respectively. The meters are nonideal, then R is
(A) 5
(C*) greater than 5
20
= 5
4
Also in parallel effective resistance is less than the individual resistance.
31.
For an adiabatic process graph between PV & V for a sample of ideal gas will be :
(A)
Sol.
32.
Sol.
(B*)
(C)
(D)
PV T
for adiabatic process,
TV1 = constant
The maximum current in a galvanometer can be 10 mA. Its resistance is 10. To convert it into an ammeter
of 1 Amp. a resistor should be connected in
(A) series, 0.1
(B*) parallel, 0.1
(C) series, 100
(D) parallel, 100.
G = 10 mA
G = 10
S ( G) = G G
S=
G G 10 10 3 10
= 0.1
G
1 10 10 3
BITSAT(XII)_PT-2_Pg.No # 9
33.
Sol.
34.
Battery of internal resistor ' r ' and e.m.f. is connected to a variable external resistance AB. If the sliding
contact is moved from A to B, then terminal potential difference of battery will :
(A)
remain constant & is independent of value of external resistance
(B*)
increase continuously
(C)
decrease continuously
(D)
first increase and then will decrease.
Terminal potential difference across battery will be
= ir
If resistance increases then i will decrease
So, potential will increase.
Two cells of emf 1 and 2 (2 < 1) are joined as shown in figure :
When a potentiometer is connected between x and y it balances for 300 cm length against 1. On connecting
2
the same potentiometer between x and z it balances for 100 cm length against 1 and 2. Then the ratio
1
is :
(A)
Sol.
(B)
3
4
(C)
(D*)
2
3
2
2
1 = 3 .
A B
15
(A) 22.5
(C)
Equivalent circuit is
10
10
15
30
20
20
Ans.
Sol.
1
4
1 = 300
..........(i)
2 + 1 = 100
..........(ii)
where, is the potential gradient
35.
1
3
(B) 25
30
(C*) 37.5
(D) 75
BITSAT(XII)_PT-2_Pg.No # 10
10
10
15
20
30
20
30
15
= 37.5
36.
In the circuit shown in figure find the current in branch AB of the circuit :
B
20 V
(A*) 5 A
(B) 0.5 A
11
A
3
Here in this circuit its equivalent
resistance across battery can be given as
(C)
Sol.
Req
40
=
11
B
20
40
20 V 4A
1.5A
5.5A
= 5.5 A.
11
Thus current 1.5A (from figure) will be divided in 10 & 5 in inverse ratio thus
I5
1.5 10
= 1A
15
37.
(A*) 10 V
Sol.
E 10
=
20
(B) 5 V
(C) 15 V
(D) 20 V
BITSAT(XII)_PT-2_Pg.No # 11
E 10
5
20
40 = 4E E + 10
30 = 3E
E = 10 V.
10 = E
38.
Sol.
In the circuit shown in the figure, the potential difference between B and C is :
(A) 0.1 V
(B) 2V
Apply K.V.L.
K.V.L.
i.5 + 2 + i.3 + i.6 + i.2 4 = 10
16i = 12
(C) 0.5 V
(D*) 4.25 V
3
A
4
Potential difference between B and C is
i=
2+3
39.
An ideal gas is taken through cyclic process as shown in the figure. The net work done by the gas is:
(A) zero
40.
3
= 4.25 V
4
(B*) PV
(C) 2 PV
(D) 3 PV
Heat energy absorbed by a system in going through a cyclic process is shown in the figure [ V in litres
and p in kPa ] is:
BITSAT(XII)_PT-2_Pg.No # 12
(A) 107 J
a
T2
2
(B) 104 J
n4
T=
1/ 2
(C*) 102 J
(D) 107 J
n2 =
2.
He is a candid politician
(A*) frank
(B) faithful
(D) fearless
(C) delegating
(D) postponing
4.
Quell
(A) Anger
(B) Query
(C) Suppress
(D*) Aggravate
Soporific
(A) Inducing
(B) Inciting
(C) Consoling
(D*) Vigorous
Instructions(Q 5 & 6) Fill in the blanks with the most appropriate word from the given options.
5.
They have decided to meet the prime minister in order to have their _______ heard.
(A) agony
(B) suffering
(C) sorrow
(D*) woes
6.
The pleasures of the world are _________ as they are not permanent.
(A) tangible
(B) existent
(C) corporeal
(D*) illusory
8.
9.
Facsimile
(A) laughter
(C) epithet
Tenable
(A) actual
(B) valuable
(C*) defensible
(D) ever-lasting
Stellar
(A) glorious
(B) stolen
(C) outstanding
(D*) starry
Instructions(Q 10 to 13) Read the following passage and answer the questions carefully.
The world of today has achieved much, but for all its declared love for humanity it has based itself far more
on hatred and violence than on the virtues that make man human. War is the negation of truth and
humanity. Sometimes, war may be unavoidable but its progeny are terrible to contemplate. Not mere
killing, for man must die, but the deliberate and persistent propagation of hatred and falsehood, which
gradually become the normal habits of the people.
It is dangerous and harmful to be guided in our life's course by hatreds and aversions, for they are
wasteful of energy and limit and twist the mind, and prevent if from perceiving the truth.
10.
11.
12.
(B) true
(C) non-existent
PT-02_XII_BITSAT_PAGE # 1
1
13.
(D) materialism
Instruction (Q. 14 & 15) Select the option which has same relation as the given pair of words.
14.
15.
(D) Air
(D) Pointing
(B*) 1885
(C) 1925
Sol.
17.
CK
10
5
JR
OF
7
3
TX
KM
?
?
PV
(A) 4, 6
(B) 6, 8
(C*) 6, 11
Sum of alphabets numbers and then add their digits.
Sol.
(D) 1980
(D) 10, 12
10 54 ?
18.
45 32
24 144 68
Sol.
19.
Sol.
20.
Sol.
21.
Sol.
(A) 42
(B) 36
(C) 6
(D*) 4
(D) Half of the difference of top & bottom is the middle number in that column.
At a dinner party every two guests used a bowl of rice between them, every three guests used a bowl of
dal between them and every four used a bowl of meat between them. There were altogether 65 dishes.
How many guests were present at the party?
(A) 60
(B) 65
(C) 90
(D) None of these
(A) Let the number of guests be x. Then,
x
x
x
number of bowls of rice = ; number of bowls of dal = ; number of bowls of meat = .
3
2
4
65 12
x x x
6x 4x 3x
60.
65
65 13 x 65 12 x
2 3 4
12
13
If the following scrambled letters are rearranged to form the name of a city, the city so formed is famous
for its :
ACGHHIORRTT
(A) Locks
(B*) Cement Plant
(C) Temples
(D) Pottery
(B) The city is CHITTORGARH and it is famous for Cement Plant.
DRAMA is coded as 73 and STAGE as 25. How will you code ACTOR ?
(A) 56
(B) 50
(C*) 75
(D) 67
(C) DRAMA = (4 + 18 + 1 + 13 + 1) = 37
STAGE = (19 + 20 + 1 + 7 + 5) = 52.
ACTOR = (1 + 3 + 20 + 15 + 18) = 57
PT-02_XII_BITSAT_PAGE # 2
2
22.
23.
(D) Friday
Three positions of the same dice are given below. Observe the figures carefully and tell which number will
come in place of ?
5
6
(i)
(ii)
(A) 1
24.
(C) Thursday
(iii)
(B*) 3
(C) 2
(D) 6
Ram is to the South-East of Mukesh, Shyam is to the East of Mukesh and North-East of Ram. If
Suresh is to the North of Ram and North-West of Shyam, in which direction of Mukesh is Suresh
located ?
(A) North-West
(B) South-West
(C*) North-East
(D) South-East
Directions : (25) In the following questions, some figures are given in a sequence. Find out the figure from the
alternatives, which will come in place of the question mark to continue the sequence.
Problem Figure
25.
(1)
(2)
(3)
(4)
(5)
Answer Figure
Ans.
(A)
(B)
(C)
(D)
BITSAT_PT-02 (CLASS-XII)
Ques.
10
11
12
13
14
15
Ans.
Ques. 16
17
18
19
20
21
22
23
24
25
Ans.
PT-02_XII_BITSAT_PAGE # 3
3