APENDIKS

Pembuatan larutan HCl 0,5 N

. .10
M = BM
=

1,18 gr /cm 3. 37 . 10
36,5

= 11,9 ml
M1 . V1 = M2 . V2
11,9 . V1 = 0,5 . 250
V1
= 10,5 ml

Perhitungan Energi bebas Gibbs dengan menggunakan rumus :

Go = - Z . F . Eo
1. Pada larutan HCl 0,17 N
Logam Cu-Cu
Go = - Z . F . Eo
= -1 . 96.500 . 0
=0
Logam Cu-Fe
Go = - Z . F . Eo
= -1 . 96.500 . 0,385
= - 37.152,5
Logam Cu-Zn
Go = - Z . F . Eo
= - 1 . 96.500 . 0,59
= - 56.935
Logam Cu-Al
Go = - Z . F . Eo
= - 1 . 96.500 . 0,855
= - 82.507,5
2. Pada Larutan HCl 0,15 N
Logam Cu-Cu
Go = - Z . F . Eo
= -1 . 96.500 . 0
=0
Logam Cu-Fe
Go = - Z . F . Eo
= -1 . 96.500 . 0,365
= - 35.222,5
Logam Cu-Zn
Go = - Z . F . Eo
= - 1 . 96.500 . 0,58

= - 55.970
Logam Cu-Al
Go = - Z . F . Eo
= - 1 . 96.500 . 0,84
= - 82.507,5
3. Pada larutan HCl 0,13 N
Logam Cu-Cu
Go = - Z . F . Eo
= -1 . 96.500 . 0
=0
Logam Cu-Fe
Go = - Z . F . Eo
= -1 . 96.500 . 0,36
= - 34.740
Logam Cu-Zn
Go = - Z . F . Eo
= -1 . 96.500 . 0,365
= - 54.522,5
Logam Cu-Al
Go = - Z . F . Eo
= - 1 . 96.500 . 0,83
= - 80.095
4. Pada larutan HCl 0,11 N
Logam Cu-Cu
Go = - Z . F . Eo
= -1 . 96.500 . 0
=0
Logam Cu-Fe
Go = - Z . F . Eo
= -1 . 96.500 . 0,345
= - 33.292,5
Logam Cu-Zn
Go = - Z . F . Eo
= -1 . 96.500 . 0,58
= - 55.970
Logam Cu-Al
Go = - Z . F . Eo
= -1 . 96.500 . 0,84
= - 81.060
5. Pada Larutan 0,09 N
Logam Cu-Cu
Go = - Z . F . Eo
= -1 . 96.500 . 0
Logam Cu-Fe
Go = - Z . F . Eo
= -1 . 96.500 . 0,35
= - 33.775
Logam Cu-Zn

Go

= - Z . F . Eo
= -1 . 96.500 . 0,575
= - 55.487,5
Logam Cu-Al
Go = - Z . F . Eo
= -1 . 96.500 . 0,825
= - 79.612,5