Chapter Practice Problems

Subject: Chemistry

Topic: CE

NAME:

1. The equilibrium constant KC for the reaction SO2(g) + NO2(g)

SO3()g) + NO(g) is 16. If 1 mole
3
each of all four gases is taken in 1 dm vessel the equilibrium concentration of NO would be
(A) 0.04
(B) 0.6 M
(C) 4.4 M
(D) 1.6 M
2. When a mixture of N2 and H2 in the volume ratio of 1:5 is allowed to react at 100K and 10 3 atm
pressure,0.426 mole fraction of NH3 is formed at equilibrium. The Kp for the reaction is
(A) 2.8 104
(B) 6.6 104
(C) 3.0 104
(D) 6 104
3. For the reaction
CO2(g) + H2(g)
CO(g) + H2O(g)
The Kp for the reaction is 0.11
If the reaction was started with 0.45 moles of CO 2 and 0.45 moles of H2 at 700K, the
concentration of CO2 when 0.34 mole of CO2 and 0.34 mole of H2 are added when the first
equilibrium is attained, is
(A) 0.52M
(B) 0.17M
(C) 0.34M
(D) 0.26M
4. For the given reaction:
2A(s) + B(g)
C(g) + 2D(s)+ E(s)
the degree of dissociation of B was found to be 20% at 300K and 24% at 500K the rate of
backward reaction
(A) increases with increase in pressure and temperature
(B) increases with increase in pressure and decrease in temperature
(C) depends on temperature only and decreases with increase in temperature
(D) increases with increasing the concentration of B and increasing the temperature
5. For the given equilibrium
L(g)
M(g)
The Kf = 5 104 mole/litre/seconds
and Kb = 3 102 litre/mole/seconds
the equilibrium concentration of M is
(A) 0.13M
(B) 0.3M
(C) 0.8M
(D) Cant be calculated
6. Given the standard enthalpies at 298K in kJ/mol for the following two reactions
3
3
C(s) CO2(g) 2Fe
2
2
O2(g) CO 2(g)

Fe2O3(s)

H 234

...(1)

C(s)

H 393

(2)

the value of H for 4Fe(s) 3O2(g) 2Fe2O3 is

3
( 393) 2 234
2
(C) 3( 393) 2 234

(A)

3
( 393) 234
2
(D) 3( 393) 2(234)

(B)

7. K c for the reaction

A (g) B(g) C(g) D(g) , is 20 at 25C. If a container contains 1, 2, 4, 5 moles per litre of
A (g) , B(g) , C(g) and D(g) respectively at 25C, then the reaction shall

(A) proceed from left to right

(C) be at equilibrium

(B) proceed from right to left

(D) None

Chapter Practice Problems

8. K c for the reaction
[Ag(CN)2 [ 1 Ag 2CN , the equilibrium constant at 25C is 4 10 19 , then the silver ion
concentration in the solution which was originally 0.1M in KCN and 0.03 M in AgNO3 is:

(A) 7.5 1018

(B) 7.5 1018

(C) 7.5 1019

(D) 7.5 1019

9. The K p value for certain reaction is 0.5 atm at 300K. Which of the following is incorrect about
the reaction.
(A) K c can be calculated
(B) From this data, it is not possible to determine about the H value of the reaction.
(C) K p K c
(D) Neither possible to calculate K c nor the relation between K p and K c
10. The K p of a reaction is 10 atm at 300K and 4 atm at 400K. The incorrect statement about the
reaction is
(A) The reaction is exothermic.
(B) The Ea of forward reaction is more than that of backward reaction.
(C) The rate of backward reaction increases more than that of forward reaction with increase of
temperature.
(D) The difference between heat of reaction at constant pressure and that at constant volume is
RT.

1Ans. D

Chapter Practice Problems

2Ans. B
3.Ans. B
4.Ans. C
5.Ans. A
6.Ans. D
7.Ans. A
8.Ans. B
9.Ans. A
10.Ans.