Minor x 1. Write the version number of your question paper on the answer sheet 2. No clarifications or corrections will be provided during the exam. If you think there is an ‘error /inconsistency /omission in the paper, please state your assumptions about it. 4 (Ht) B= (BH) pat = 14s — Pav, (8), = (3), (H) = P, R= 8314) mol“? KE Information: « 2. (@) Arhas normal melting and boiling points of 83.80 K and 873K; the triple points at 83.606 K {and 068atm, and its critical temperature and pressure are 15087K and 483atm. State whether Ar is a solid, liquid, or gas under each of the following conditions: (a) (09atm, 90K); (&) (07 atm, 80K); (c) (Baim, 88K); (A) (1-2atm, 635K); @) (OSatm, 84K). ro} (©) One kilomole of an ideal gas is compressed isothermally at 400K from 100kPa to 1000kP.. Cateulate the entropy change of the gas, ofthe surroundings, and the total entropy change resulting from the process, if (a) the process is mechanically reversible; (b) the process is mechanically irreversible, requiring 20% more work than the mechanicelly reversible compression. hs] 2. The isomerization fans-2-C,H(g) == cis-2-C,H, (g) was performed with the following initial umber of moles: n(trans-2C,Hg) = 2,n®(cisCyH) = 0, and ?(N,) = 2. Here nitrogen is an inert gas () Calculate the equilibrium constant for this isomerization at 298.15K. 6) (©) What isthe Gibbs energy of the mixture at equilibrium, if the reaction occurs at a pressure of bar? [ro] (©) What is the equilibrium constant ofthe reaction at 600K? 0} ‘The relevant thermodynamic data at 298.15 K (Cp is temperature independent) is given below: Species Ce G/mmol K) AH; (Ki/mol) AG} I /mot) trans--C Hi (@) 7891 “a7 95 cisaC Fg (@) 8782 699 63.06 3: A reversible adiabatic process is an isentropic (constant entropy) process (@) Show that the isentropic expansvity, as = (34). is 8 Lo} (b) What sas for an ideal gas? bl (© Consider the isentropic expansion of an ideal gas from (Ty,¥i) to (Ty, Vs). Derive an expression forthe final temperature Ts starting from the expression for as You got in the previous part uo} 4 Decide, with a short justification, whether the following statements are true of false, Correct the false statements. 5x5} 4) The chemical potential of any species that can be exchanged between two phases will always be equal. (©) 15 system isin equilibrium with a constant temperature reservoir and constant pressure reservoir then that systom is in equilibrium if hete is atleast one process that increases Gibbs energy (6) Only ina closed system is dtl = dg +d. {@) In. one-component system, when three phases coexist, one ofthe phases must be a gas, one must be a liquid, and one must bea sold (©) The entropy of an isolated system increases when it undergoes en expansion