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ih
p2
=
+V
t
2m
(momentum operator)
(potential energy operator)
k
=
m
H=
xf, g = xf (x)g(x)dx
= f (x)xg(x)dx
= f, xg.
By integration by parts, p is self-adjoint. Moreover, by the product rule,
[x, p] := xp px = ih.
Dene the ladder operators
)
(
m
i
a+ =
(raising operator)
x m p
2h
(
)
m
i
a =
(lowering operator)
x + m p
2h
Then a+ and a are adjoints of each other. Using the fact that [x, p] = ih,
it is straightforward to show that
[a , a+ ] = 1
h
H=
(2a+ a + 1)
2
+
[H, a+ ] = ha
(1)
(2)
Proof: Use the raising and lowering operators. See the last page of this
document or [3], page 594.
Let E0 be the smallest eigenvalue of H. Let 0 be a corresponding normalized eigenfunction. Then
a 0 = 0
(3)
<
because otherwise a 0 would be an eigenfunction with eigenvalue E h
E0 . Thus, by (2),
0 = ha
a
( + 0)
h
0
= H
2
(
)
h
= E0
0
2
is given by
so E0 = h
. An eigenfunction with eigenvalue En = (n + 12 )h
2
n
n
a+ 0 (if a+ 0 = 0). Let n be a corresponding normalized eigenfunction
with eigenvalue En . Then, for some constant Cn+1 ,
n+1 = Cn+1 a+ n .
But,
1 = n+1 , n+1
= |Cn+1 |2 a+ n , a+ n
= |Cn+1 |2 n , a a+ n
)
(
1
H
2
= |Cn+1 | n , +
n
h 2
)
(
(n + 12 )h
1
2
= |Cn+1 | n ,
+
n
2
h
so
Cn+1 = (n + 1)1/2 .
It follows that
a+ n =
Similarly,
a n =
n + 1n+1 .
nn1 .
(4)
(5)
Therefore
1
n = an+ 0 .
(6)
n!
This is sucient for computing expectation values of powers of x and p
of the eigenfunctions because
h
x=
(a+ + a )
2m
hm
p=i
(a+ a )
2
h
=
n , (a2+ + a2 + a+ a + a a+ )n
2m
h
=
n , (a2+ + a2 + a+ a + (a+ a a+ a ) + a a+ )n
2m
h
=
n , (a2+ + a2 + 2a+ a + 1)n
2m
h
n , (2n + 1)n
=
2m
h
=
(2n + 1)
2m
0 can be found explicitly by solving the separable ODE (3). Let =
In terms of the variable y = x, (3) says
m/h.
)
(
d
y+
0 (y) = 0
dy
For any constant N0 , a solution is
0 (y) = N0 ey
i.e.
0 (x) = N0 e
4
2 /2
2 x2 /2
By (6),
(
n (x) =
n
2 n!
)1/2
e
2 x2 /2
Hn (x)
References
[1] Agnolet, G. Physics 412 Lecture Notes.
[2] Bransden, B.H. and C.J. Joachain. Quantum Mechanics.
[3] Kreyszig, E. Introductory Functional Analysis with Applications.
h
H=
(2a+ a + 1)
2
+
[H, a+ ] = ha
(7)
(8)
(9)
Then, by (8),
a+ a = E.
Applying a to each side,
).
a a+ (a ) = E(a
By (7), a a+ = a+ a + 1, so
a+ a (a ) = (E 1)a .
Repeating the last two steps j 1 times yields
a+ a (aj ) = (E j)aj .
(10)
i.e.
aj+1 2
E j = j
0
a 2
(11)
E = h n +
for some n {0, 1, 2, 3, ...}.
2
6