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There are lifty questions in this paper. For each question,four suggestedanswers are given. Choose
one correct answer and indicute it on the multiple-choice answer sheet.Answer all questions.Marlcc
will not be deductedfor wrong answers.
SectionA:
Four suggested
answerslabelledA" B, C andD are given./breachquestionChooseone corect answer.
1.
2.
3.
Lyman Series
Balmer Series
A) s 4
n=5
B)
(-)
^\
D) 3
n=4
;=l
n:
4.
When compared at the same pressure and temperature,which of the following properties has the same
value for H2 and for iDr?
A) Density
C) Average kinetic energy
B) Average molecular speed
D) Rate of intermolecular collision
5.
Which of the following statementsregarding propertiesof ionic and covalent compoundsis correct?
A) Ionic compounds are crystalline solids at room conditions due to the strong ionic bonds between the
oppositely chargedions.
B) A compound cannot contain both ionic and covalent bonds.4
C) Any covalent compound that contains both oxygen and hydrogen in its molecule forms intermolecular
hydrogen bonds.
D) The only covalent compoundswith high melting points are those which hydrogen bonds occur..
6.
Sodium metal is a good conductor of electricity, Which statementis true of the metal?
A) The electronsin ls, 2s and 2p orbitals are delocalised.
,..B) The 3s orbital forms the valence and conduction bands.
C) The valence band is full and the conduction band is empty.
D) The conductivity is lower in solid statethan in gaseousstate.
7.
Under suitable conditions, xenon forms XeFa molecules.What is the shapeof the XeF+ molecule?
A) Tetrahedron
B) Pyramidal
c) octahedron
D) Squareplanar
8.
:
An aqueoussolution of a monobasic acid
\as pH 2.9. A 25.00 cm3 volume of an aqueoussolution of the
acid is completely neutralized by 27.5A cm3 of a 0.1 mol dm-3 sodium hydroxide solution. The value of the
dissociation constantof the acid is
A) 1.26x 10-3mol dm-3
B) 1.39x iOa mol dm*3 C) 1.44x 10-5mol dm-3 D) 1.58x l0{ mol dm-3
g.
Which of the following statementsabout the rate constantfor a chemical reaction is true?
A) It remains constantat a constanttemperature.
C) It does not changeif a catalyst is added. _
B) It decreasesas the concentrationsof the reactantsdecrease. Di The unit is S-r
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10. The concentration of a reactant, R, was plotted against time as it reacted exothermically with S to reach
equilibrium. The graph below shows the results.
Which of the following graphs could be obtained if the reaction was repeatedat a higher temperaturebut
with the sameinitial concentrationof R and S?
A)
B)
Time
Time
D)
c)
Time
Time
I 1. A sample of I mol of NzOawas place<lin an empty I dni3 container and was allowed to reach equilibrium
2NO, (g)
according to the following equation: N2OaJg)
At equilibriurn, x mol of the NzO+had dib=6ciated.
The
?[uilibrium constant,Kc, at the temperatureof the
--experiment is
4x2
A) 3lL
B ) 2x .
D)
l -x
t -x
(1 - x)'
1-x
q +r
12. Hardnessin tap watercanbe determinedby titratinga sampleagainsta reagentwhich forms complexions
with dissolvedmetal ions. 'Ihe indicatorf<rrthe titration requiresthe pH to be maintainedat about 10.
Which of the following,in aqueoussolution,couldbe usedfbr this purpose?
A) Ammonia and ammonium chloride
B) Ammonium chloride and hydrochloric acid
13. Public swimming pools are often chlorinatedto kill bacteria.As an alternativeto chlorination,a
concentrationof silver ions not more than 10{ mol dm*3and not lessthan l0-7 mol dm-3can be used.
Which of the following compoundswould, in a saturatedsolution,providethe necessaryconcentration
of
silverions?
Solubility Product
Compound
A)
B)
AgBr
Ag2CO3
5 x lo-r3 mol2dmj
5 x lo-12 mol3 dm-e
C)
AgCl
D)
AgIOr
2 x http://edu.joshuatly.com/
1or mol2dm-6
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14. A solution mixture of 2.2 mol A and 1.8 mol B obeys Raoult's law. The vapour pressureof pure A and
pure B arc 42.AkPa and 58.0 kPa respectively.What is the mole ftaction of B in the vapour phase?
A)
0,3e
D) 0.s3
c) 0.47
B) 0.43
15. The circuit shown in the diagram was set up. The anodeis made of a metal alloy containing copperand
zinc. Which electrodereactionswill occur when the switch is closed?
Platinum
Dilute sulphuric,acid
Anode reaction
Cathode reaction
A)
Copperdissolves
preferentially
Hydrogen is evolved
B)
Copperdissolves
preferentially
Oxygen is evolved
c)
Zinc dissolves
preferentially
Hydrogen is evolved
Copper is precipitated
dissolves
Electrons flow from the cathodeto the anodethrough the external circuit.
Electricity is conductedthrough the electrolyte by electrons.
The easeof dischargeof metallic cations is inversely proportional to the reactivity of the metals.
The amount of substanceproduced during electrolysis is directly proportional to the amount of current
and the chargeofthe ions.
Fe
12
Ilalf- reaction
n+lv
It is expectedthat:
+ e --->
+ 4.77
+ 0.54
+ 2e- ---l 2I
Brz + Z;
--> 2Br
cd" + 2e-1
Cd
+1.0 7
20. Nitrogen is the first element of Group 15. Which of the following is true about nitrogen compounds?
A)
B)
C)
D)
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D^-^
Whatis theproperty?
A) Electronegativity
B) tronicradius
C) First ionizationenergy
D) Meltingpoint
rs r6
il".,lL"'"o-
Cation
Mg'*
Observation
No precipitation
which statement
explainsthe aboveobservations
on descending
the Group2 elements?
A) The reactivityof the elementsincreases.
Smallamountof
white precipitation
B)
Whiteprecipitation
c)
White precipitation
D)
The decrease
in the hydrationenergyof the cationsis
greaterthanthedecrease
in their latticeenergy.
24. Fruit juices and fizzy drinks such as lemonadeare often sold in aluminium
cans. What is the most
importantreasonwhy aluminiumis a suitablemetal?
A) Aluminium canbe recycled
C) Aluminiumhasa very low density
B) Aluminiumis resistant
to corrosionby acid D) Aluminiumis a goodconductorofheat
D) thermal stabilitv
27. Which of the following statementshelps to explain why nickel can act
as a catalyst in the hydrogenation
etheneto form ethane
A) Nickel can exhibits variable oxidation srate
B) Nickel has d orbitals that can form temporary bonds
C) Nickel can form stable intermediatewith the reactants
D) Nickel has a high affinity for hydrogen
of
instead
of cyanideion,thecomplexwili havea formulaor lpt(wir.)oir . wtruiir ihe uatu"or
A)2B )3 ^r
c)2 +
D) 3+
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D) [Co(NHr)rCl]'*
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30. Substituent groups affect the acidity of organic compounds. Which of the following is the correct
arrangementof some compoundsin descendingorder of acid strength?
C) CHr COOH, CH2CICOOH, CHjOH, C6H5OH ,'(
A) CH2CICOOH, CH3COOH,C6H.OH,CHrOI{
B) CH2CICOOII, CHICOOH, CH1OFI, C6I{5OH D) CHTOH,CF{3COOH,CH2CICOOH, C6H5OH./{
(DBCP) has been used in the control of earthworms in agricultural land.
31. 1,2-dibromo-3-chloropropane
Which of the following could be the best synthesisof this compound?
-*->
DBCP + 2HBr
A) CH3CH2CH2CI + 2Brz
----)
+ HCI
+
DBCP
B) CH3CHBTCH2BT Cl2
gltatBr2
+
DBCP
C) CHr=
HCI
--+
DBCP
D) CI{2: CHCH2C| + Br7
32. Which is an electrophilicsubstitutionreaction?
A)Hc)
/;\
t?/- cHor HCN
/ 1
p|
-.*
I + NaoH----*>@."'oH
S.u,c
+ Nact
OH
D)
B) _
cHr- crz-----+
fd-.",cr
+ HCr
+NH3
---+$co*H2
Scoct
+ HCr
A)
C) CHICI{2OH
D) (CH3),C(OH)CH2CH3
I
I
cHr- cH* oH
I
C-CFI,]
cI{2
I
OH
35. Phenol is used to prepare the compound CHTCOOC6H5through an intermediate X as shown in the
following scheme
ReagentII
ReagentI
c6l{soH -.--->
------+
c}l3cooc6H5
Reagent II
A)
PCl5
CHjCOCI
B)
Na
CHiCOCI
C)
NaOH
CHICOOH
D)
PCl5
CHTCOOH
36. A compound reducesFehling's solution and forms triiodomethanewith alkaline iodine solution,
The compound could be
C) 3--hydroxybutanal
D) Propanone
A) ethanol
B) butanal
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D) Bri 1uo;
39. Which of the following pairs of compoundsarld reagentswill reactto form benzenediazonium
chloride
under suitable conditions?
A) Phenoland HzSO+/ HCI
B) Phenylamineand HNOr / IIL'I
C) Nitrobenze'neand Sn / IICI
D) Phenylamineand NaN02 / I{Cl
B
I
2
"rd
"rrb,
are correct
only2 and3
are cot'rect
D
1 , 2 a n d3
are correct
ls
2s
2o
Nru M IIIN
Which of the frjllowing statementsis / are true?
l. The distributionof electronsobeysHund's rule.
2. The nitrogen atom is paramagnetic"
3. The filling of electronsinto ls and 2s orbitalsfollows Pauli ExclusionPrinciple.
42. Carbonic acid, H2CO3,and hydrogen carbonate,HCOr-, fonn a buffer systemin the blood. Which reactions
occur when the level of acidity in blood increases.
3. [I2COr
H2COr
l. HCOr- ----> H* + COr2- 2. HCO3- -1-H" ---*
43. In a reversible reaction, the equilibrium position is unaffected by the change in temperature. Which
statement(s)about the reaction is I are true?
l. The enthalpychangeof the reactionis zero.
2. The value of the equilibrium constantdoesnot change.
3. The concentrationsof the reactantsand the products are tlte sarne.
44. Chromium and nickel are used in the electroplating industry" Which of the following statementsis /are true
of electroplating?
l. The electroplatingmetal is the anode.
2. The electrolyte used containsthe electroplating metal ions.
3. Reduction occurs at the cathode.
45. The paper chromatogramof samplesW, X, Y and Z which is obtained using ethanol as an eluent is shown
below.
\
Solvent
fionl.
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SMJKKATHOLIKP.JAY.A;STPMTRIALEXAMINATION
2010:CHEMISTRYI
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cHlco(cHz)scH:cHCo2H
From the structure shown, which of the fbllowing statementsis / are true?
l. It gives a positive test with Fehling's solution.'
2. It gives a positive iodoform test.
3. It would exist as cis-transisomers.
49. Ethyl butanoateis usedas an artificial pineappleflavouring.Which of the following pairs can be usedto
produce the ester?
l. CH3CH2CH2COOFIand CHTCHTOH
2. CHiCH2CH2COCI and CI{ICI{2OH
3. CHjCOOH and CI{TCHzCH2CH2OH
50. The repeatingunit ol'a polymer is shown below
CH3H
t ll t
Clr
C H 2 -C F I2 -C :
Il
-
C -C
I
r{
lol
\-/
-'\-r
It is elastic.
[t can be vulcanised.
3.
Its monomersare
fl\:-/
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SMJKKATHOLIK P.JAYAT
STPMTRIAL EXAMINATION20101CHEMISTRYPAPER2
s. (a)
(3)
(1)
Experiment
0 .001
0.001
7 xl0-6
0 .001
0.002
14x 10-6
a
J
0 .001
0.003
21 x 10-6
0.002
0.003
84x10-6
0.003
0.003
189x10-6
(1)
(i) Explain what is meantby the term order of reaction.
(ii) Based on the above data, determine the order of reaction, with respect to nitrogen monoxide and
(4)
with respectto oxygen and hence,write the rate equation for the reaction.
(iii) Calculate the value of the rate constant,k, for the reaction.
(1)
(d)
6. (a)
(5)
5
3.
The acid dissociationconstant,Ku , of nicotinic acid HC6IIaNO2is 1.40 x l0 - mol dm- Nicotinic
acid ionises in water according to the equationshown below.
HC6HaNO2 (aq)
+ HrO 0)
3
3
In an experiment,25.0 cm3 of 0.800 mol dm- nicotinic acid is titrated with 80.0
0.500 mol dm"m3
aqueoussodium hydroxide
(i) Write an equationto show the reaction between nicotinic acid and aqueoussodium hydroxide.
(ii) Calculate the initial pH of the nicotinic acid and sodium hydroxide solutions.
(iii) Sketch the titration curve of pH versus volume of aqueoussodium hydroxide for the titration.
(9)
(b)
A buffer systemin human blood is the HzPO+-/ HPO42-system.The normal pH of blood is 7.40.
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(6)
' 7. (a)
(b)
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The halide ions Cl-, Br- and tr differ in their reactionswith concentratedsulphuric acid.
Describe what you would seeif concentratedsulphuric acid is addedto separatesamplesof the solids
KCl, KBr and KI.
Suggestan explanation for the difference in reaction and write equationsillustrating the types of
(6)
reaction undergone.
t
(c) 100 cm3of 0.50 mol dm- 3 AgNO1 (aq) is mixed with 100 cm3of 0.50 mol dm- NaCl (aq). The
temperatureof the mixture increasesby 7.8"C.
.
AgCl (s)
Calculatetheenthalpyofthereaction Ag. (aq) + Cl-(aq) +
profile
ofthe
reaction.
and sketch the energy
8.
(a)
(5)
(4)
(8)
(2)
and |Co(NH2CH2CH2NH2)313+.
(c) Cobalt(III) forms many colourful complexessuch as [Co(NH3)aCl2]*
Identify the type of isomerismshown and draw the
Both thesecomplexesexhibit stereoisomerism.
(5)
isornersfor boththesecomplexes.
9.
(a) Using the compound as the starting material, statesuitable reagentsand conditions to carry out the
following type of reaction:
(i) Nucleophilicaddition
(ii) Reduction
(iii) Oxidation of the aldehydegroup
(iv) Oxidation of the alkene group
For each reaction, draw the structural formula of the organic compound formed.
(8)
(b) Phenylethenecan undergo addition polymerization in the presenceof chloric (VII) acid, HCIOa , as
catalyst. Describe the mechanismof this polymerization.
(7)
10. (a)
(b)
exhibits geometricalisomerismand
CH3CH: CHC(CH1)(Br)CH2CH3
4-bromo-4-methyl-2-hexene,
optical isomerism
(i) What do you understandby the terms geometricalisomerism and optical isomerism?
(ii) Draw the structureand name the geometrical isomersfor 4-bromo-4-methyl-2-hexene.
(7)
(iii) Draw the structure of the optical isomers for 4-bromo-4-methyl-2-hexene.
(i) Statethe functional groups in an amino acid molecule.
(ii) Alanine or 2-aminopropanoicacid is a solid with a high melting point. It is soluble in water but
insoluble in ether. Draw the full structural formula of alanine and explain the given observations.
(iii) Indicate, with a balancedequation,how a peptide bond is formed betweentwo alanine molecules.
(iv) Write equationsfor the reaction of alanine with hydrochloric acid and aqueoussodium carbonate.
.- THE END
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