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  • Activity No. 3 - Justin Guillano ChE 4102

    Загружено:

    Justin Guillano
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    This document provides information about a contact sulfuric acid plant that produces 98% sulfuric acid. The plant absorbs SO3 into a 97.3% sulfuric acid solution in an absorption tower. A gas containing 8% SO3 at a rate of 28 lb mol/hr enters the tower, where 98.5% of the SO3 is absorbed. 97.3% sulfuric acid is introduced at the top of the tower and 95.9% sulfuric acid is used as make-up acid. Calculations are provided for the tons/day of 95.9% make-up acid required, 97.3% acid introduced, and 98% acid produced.

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    Activity No. 3 - Justin Guillano ChE 4102.xlsx

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    This document provides information about a contact sulfuric acid plant that produces 98% sulfuric acid. The plant absorbs SO3 into a 97.3% sulfuric acid solution in an absorption tower. A gas containing 8% SO3 at a rate of 28 lb mol/hr enters the tower, where 98.5% of the SO3 is absorbed. 97.3% sulfuric acid is introduced at the top of the tower and 95.9% sulfuric acid is used as make-up acid. Calculations are provided for the tons/day of 95.9% make-up acid required, 97.3% acid introduced, and 98% acid produced.

    Авторское право:

    © All Rights Reserved
    Скачайте в формате XLSX, PDF, TXT или читайте онлайн в Scribd
    Отметить как неприемлемый контент
    502 просмотров4 страницы

    Activity No. 3 - Justin Guillano ChE 4102

    Загружено:

    Justin Guillano
    This document provides information about a contact sulfuric acid plant that produces 98% sulfuric acid. The plant absorbs SO3 into a 97.3% sulfuric acid solution in an absorption tower. A gas containing 8% SO3 at a rate of 28 lb mol/hr enters the tower, where 98.5% of the SO3 is absorbed. 97.3% sulfuric acid is introduced at the top of the tower and 95.9% sulfuric acid is used as make-up acid. Calculations are provided for the tons/day of 95.9% make-up acid required, 97.3% acid introduced, and 98% acid produced.

    Авторское право:

    © All Rights Reserved
    Скачайте в формате XLSX, PDF, TXT или читайте онлайн в Scribd
    Отметить как неприемлемый контент
    из 4

    Problem 1

    A contact sulfuric acid plant produces 98.0 % sulfuric acid, by absorbing


    SO3 into a 97.3 % sulfuric acid solution. A gas containing 8.00 % SO3
    (remainder inerts) enters the SO3 absorption tower at the rate of 28 lb mol
    per hour 98.5 % of the SO3 is absorved in this tower. 97.3 % sulfuric acid is
    introduced into the top of the tower and 95.9 % sulfuric acid from another
    part of the process is used to make-up acid. The flow sheet is given in the
    figure with all of the known data on it.
    Calculate the
    a. Tons/day of 95.9 % H2SO4 make-up acid solution required.
    b. Tons/day of 97.3% H2SO4 solution introduced into
    the top of the tower.
    c. Tons/day of 98 % H2SO4 solution
    produced.

    Basis:

    H2O

    100

    mol S1

    SO3

    mol SO3 fed at S1 =


    8
    mol SO3
    SO3 absorbed in the tower =
    7.88
    0.12
    mol SO3
    SO3 in S2 =
    92
    mol Inerts
    Inerts in S2 =

    H2SO4

    mol SO3

    Composition of S2
    SO3 = 0.001303
    Inerts = 0.998697
    Basis:

    S1 =

    28

    MW H2SO4 =

    MW H2O =

    98
    18

    lb/ lb mol
    lb/ lb mol

    Overall
    H2SO4
    H2O

    F
    0.959
    0.041

    P
    -0.98
    -0.02

    constant
    -216.2272
    39.7152

    F=
    P=

    2059.307
    2235.819

    lb/hr
    lb/hr

    P2
    1
    0.98

    constant
    -2059.307
    -1974.875

    6177.92
    4118.613

    lb/hr
    lb/hr

    at B
    Total
    H2SO4

    -1
    -0.973
    G=
    P2 =

    lb mol/hr
    % SO3 absorbed =

    -216.2272
    39.7152

    -2059.307
    -1974.875

    0.985

    S2
    SO3
    Inerts

    S1
    SO3
    Inerts

    0.0013
    0.9987

    28
    0.08
    0.92

    lb mol / hr

    a.
    b.
    c.

    F=
    G=
    P=

    ABSORPTION
    TOWER

    P1
    A

    24.71168
    74.13504
    26.82982

    ton/day
    ton/day
    ton/day

    G
    H2SO4
    H2O
    P2
    4118.613

    P
    H2SO4
    H2O

    2235.819
    0.98
    0.02

    6177.92
    0.973
    0.027

    lb/hr

    lb/hr

    F
    H2SO4
    H2O

    2059.307
    0.959
    0.041

    lb/hr

    Problem 1
    Given that the vapor pressure of n-butane at 350 K is 9.4573 bar, find the
    molar volumes of (a) saturated-vapor and (b) saturated-liquid n-butane at
    these conditions as given by the Redlich/Kwong equation.
    T=
    Tc =
    Tr =

    350
    425.1
    0.823336

    =
    =

    0.42748
    0.08664

    q=
    =

    6.604378
    0.026217

    K
    K

    Saturated-Vapor
    Z
    0.83049
    Z'
    0.83049
    V=

    2555.319 cm3/mol

    Saturated-Liquid
    Z
    0.043312
    Z'
    0.043312
    V=

    133.2663 cm3/mol

    P=
    Pc =
    Pr =

    9.4573
    37.96
    0.249139

    R=

    83.14

    bar
    bar

    cm3 bar / mol K

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