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CHAPTER 1
Significant Figures and Calculations
A. Rules for Counting Significant Figures
Number Rule Example
Nonzero integers Always significant 6.34 m (3 sig figs)
Leading zeroes Never significant 0.00634 m ( 3 sig figs)
Captive zeroes Always significant 6.0034 (5 sig figs)
Trailing zeroes Significant if after a decimal 63400 (3 sig figs)
0.63400 (5 sig figs)
Exact numbers Infinite significance e.g. There is 1 star at the center of our solar system.
There is no doubt about the number "1"
Scientific notation All digits are significant 6.3400 x 106 (5 sig figs)
B. Multiplication and Division
1. Keep as many sig figs in your answer as are in the piece of data with the least number of
sig figs:
2.37 cm x 15.67 cm x 7.4 cm = 274.82046
(keep two sig figs) = 2.7 x 102 cm3
C. Addition and Subtraction
1. Keep the same number of decimal places as the least precise measurement in your
calculation
34.039 m + 0.24 m + 1.332 m + 12.7 m = 48.311 m
(keep one decimal place) = 48.3 m
CHAPTER 2
The Modern View of Atomic Structure: An Introduction
A. Nucleus
1. Protons - positively charged
2. Neutrons - no charge
3. Small size, high density
a. The mass of all of the cars in the United States in an object that would easily fit in
a teaspoon
b. A pea with the mass of 250 million tons
B. Electrons
1. Negatively charged
2. The source of varying reactivity of different elements
3. Provide most of the atomic volume
C. Atomic Number
1. Number of protons
D. Mass Number
1. Number of protons + number of neutrons
E. Isotopes
1. Atoms with the same number of protons (same element) but different numbers of neutrons
(mass numbers)
1. Photosynthesis
2. Combustion of fuels
3. Oxidation of sugars, fats, proteins for energy
C. Characteristics of Oxidation-Reduction Reactions
1. the oxidized substance:
a. loses electrons
b. increases oxidation state
c. is the reducing agent
2. the reduced substance
a. gains electrons
b. decreases oxidation state
c. is the oxidizing agent
D. Balancing Oxidation-Reduction Equations
CHAPTER 5
A. Properties of gases
1. Gases uniformly fill any container
2. Gases are easily compressed
3. Gase
s mix completely with any other gas
4. Gases exert pressure on their surroundings
B. Units
a. mm Hg (torr)
(1) 760 torr = Standard pressure
b. newtons/meter2 = pascal (Pa)
(1) 101,325 Pa = Standard pressure
c. atmospheres
(1) 1 atmosphere = Standard pressure
The Gas Laws of Boyle, Charles, and Avogadro
A. Boyle's Law
B. Charles' Law
Gas Stiochiometry
A. Standard temperature and pressure (STP)
1. 0 C, 273 K
2. 760 torr, 1 atm
B. Molar volume
1. One mole of an ideal gas occupies 22.42 liters of volume at STP
C. Mole Fraction
B. Diffusion
1. The mixing of gases
2. Diffusion is complicated to describe theoretically and mathematically
CHAPTER 6
A. Chemical Energy
1. Exothermic reactions
a. Reactions that give off energy as they progress
b. Some of the potential energy stored in the chemical bonds is converted to thermal
energy (random KE) through heat
c. Products are generally more stable (stronger bonds) than reactants
2. Endothermic reactions
a. Reactions in which energy is absorbed from the surroundings
b. Energy flows into the system to increase the potential energy of the system
c. Products are generally less stable (weaker bonds) than the reactants
Enthalpy and Calorimetry
A. Enthalpy
1. In systems at constant pressure, where the only work is PV, the change in
enthalpy is due only to energy flow as heat (H = heat of rxn)
a. H is negative for exothermic rxns
b. H is positive for endothermic rxns
Hess's Law
A. Statement of Hess's Law
1. In going from a particular set of reactants to a particular set of products, the
change in enthalpy (H) is the same whether the reaction takes place in one step or
in a series of steps
B. Using Hess's Law
1. Work backward from the final reaction
2. Reverse reactions as needed, being sure to also reverse H
3. Remember that identical substances found on both sides of the summed equation
cancel each other
C. Calculating enthalpy change
1. When a rxn is reversed, the magnitude of H remains the same, but its sign
changes
2. When the balanced eqn for a rxn is multiplied by an integer, the value of H must
be multiplied by the same integer
3. The change in enthalpy for a rxn can be calculated from the enthalpies of
formation of the reactants and products
1. G0 is the change in free energy that will occur if the reactants in their standard states are
converted to the products in their standard states
2. G0 cannot be measured directly
3. The more negative the value for G0, the farther to the right the reaction will proceed in
order to achieve equilibrium
a. Equilibrium is the lowest possible free energy position for a reaction
B. Calculating Free Energy Change
1. Method #1, for reactions at constant temperature:
CHAPTER 8
Types of Chemical Bonds
A. Ionic Bonding
1. Electrons are transferred
2. Metals react with nonmetals
3. Ions paired have lower energy (greater stability) than separated ions
B. Bond Length (covalent)
1. Distance at which the system energy is at a minimum
2. Forces at work
a. Attractive forces (proton - electron)
b. Repulsive forces (electron - electron, proton - proton)
3. Energy is given off (bond energy) when two atoms achieve greater stability
together than apart
C. Covalent Bonds
1. Electrons are shared by nuclei
2. Pure covalent (non-polar covalent)
a. Electrons are shared evenly
3. Polar covalent bonds
a. Electrons are shared unequally
b. Atoms end up with fractional charges
Bond Polarity and Dipole Moments
A. Dipolar Molecules
1. Molecules with a somewhat negative end and a somewhat positive end (a dipole
moment)
B. Sizes of Ions
1. Anions are larger than the parent atom
2. Cations are smaller than the parent atom
3. Ion size increases within a family
4. Isoelectronic ions
a. Ions with the same number of electrons
b. Size decreases as the nuclear charge Z increases
Covalent Bond Energies and Chemical Reactions
A. Multiple Bonds
Lewis Structures
A. Electrons and Stability
1. "the most important requirement for the formation of a stable
compound is that the atoms achieve noble gas configurations
2. Duet rule
a. Hydrogen, lithium, beryllium, and boron form stable molecules
when they share two electrons (helium configuration)
3. Octet Rule
a. Elements carbon and beyond form stable molecules when they
are surrounded by eight electrons
B. Writing Lewis Structures
1. Rules
a. Add up the TOTAL number of valence electrons from all atoms
b. Use a pair of electrons to form a bond between each pair of
bound atoms. Lines instead of dots are used to indicate each
pair of bonding electrons
c. Arrange the remaining atoms to satisfy the duet rule for
hydrogen and the octet rule for the second row elements
Resonance
1. When more than one valid Lewis structure can be written for a particular molecule
2. The actual structure is an average of the depicted resonance structures
Molecular Structure: The VSEPR Model
A. Valence Shell Electron Pair Repulsion (VSEPR)
1. The structure around a given atom is determined principally by
minimizing electron-pair repulsions
2. Non-bonding and bonding electron pairs will be as far apart as possible
B. VSEPR and Multiple Bonds
1. For the VSEPR model, multiple bonds count as one effective electron
pair
2. When a molecule exhibits resonance, ANY of the resonance structures
can be used to predict the molecular structure using the VSEPR model
CHAPTER 9
Hybridization and the Localized Electron Model
A. Hybridization
1. The mixing of two or more atomic orbitals of similar energies on the
Phase Diagrams
1. Triple Point
a. Solid and liquid have identical vapor pressure
b. All three phases exist together in equilibrium
2. Critical temperature
a. The temperature above which the substance cannot exist as a liquid, regardless of how
great the pressure
3. Critical pressure
a. The pressure required to produce liquefaction at the critical temperature
4. Critical point
a. Point defined by the critical temperature and critical pressure
CHAPTER 11
Solution Composition
A. Molarity
B. Mass Percent
C. Mole Fraction
D. Molality
A. Catalysts
1. A substance that speeds up a reaction without being consumed itself
B. Effects of Catalysis
1. Catalysts lower activation energy but do not change DE for the reaction
2. Catalysts provide alternate reaction pathways
3. Catalysis results in a higher percentage of effective collisions
CHAPTER 13
A. Chemical Equilibrium
1. The state where the concentrations of all reactants and products remain
constant with time
2. All reactions carried out in a closed vessel will reach equilibrium
a. If little product is formed, equilibrium lies far to the left
b. If little reactant remains, equilibrium lies far to the right
The Equilibrium Constant
A. The Law of Mass Action
B. Equilibrium Position
1. A set of equilibrium concentrations
2. There is only one value of K for a reaction at a given temperature, but an
infinite number of possibilities for equilibrium positions
Relationship between K and Kp
1.
Applications of the Equilibrium Constant
A. Extent of a Reaction
1. Reactions with large equilibrium constants (K>>1) go essentially to completion
a. Equilibrium position is far to the right
b. Generally large, negative E
2. Reactions with small equilibrium constants (K<<1) consist of mostly reactants
a. Equilibrium position is far to the left
B. Reaction Quotient (Q)
1. Apply the law of mass action to initial concentrations in order to determine what direction
the rxn must move in order to achieve equilibrium
2. IF Q is equal to K
a. The system is at equilibrium, no shift will occur
3. IF Q is greater than K
a. The system shifts to the left, consuming products and forming reactants to reach
equilibrium
4. IF Q is less than K
a. The system shifts to the right, consuming reactants and forming products until
equilibrium is reached
Le Chatelier's Principle
A. Strong Acids
1. Acids for which the equilibrium lies far to the right
a. Strong acids yield weak conjugate bases
2. Common strong acids
a. sulfuric, hydrochloric, nitric, perchloric
B. Weak Acids
1. Acids for which the equilibrium lies far to the left
a. Weak acids yield relatively strong conjugate bases
C. Water as an Acid and a Base
1. Water can act as an acid or as a base
2. Ion-product constant, Kw (dissociation constant)
a. At 25C, [H+] = [OH-] = 1.0 x 10-7
b. Kw = 1.0 x 10-14
3. Solution characteristics
a. Neutral solution, [H+] = [OH-] = 1.0 x 10-7
b. Acid solution, [H+] > [OH-]
c. Basic solution, [H+] < [OH-]
The pH Scale
A. pH and pOH
1. pH = -log[H+]
2. pOH = -log[OH-]
3. pH + pOH = 14
Bases
A. Strong Bases
1. Group 1A metal hydroxides
2. Group 2A metal hydroxides
a. Less soluble than Group 1A hydroxides; allows use as antacids
B. Weak Bases
1. Ammonia and other covalent bases
2. Compounds with low values of Kb
Acid-Base Properties of Salts
A. Salts That Produce Neutral Solutions
1. Salts that consist of the cations of strong bases and the anions of strong
acids have no effect on pH, ([H+]), when dissolved in water
B. Salts that Produce Basic Solutions
1. For any salt whose cation has neutral properties and whose anion is the
conjugate base of a weak acid, the aqueous solution will be basic
C. Salts that Produce Acidic Solutions
1. Salts in which the anion is not a base and the cation is the conjugate acid
acid of a weak base produce acid solutions
CHAPTER 15
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