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Problems statement

To Optimize the Benzene fractionator column reboiling and condenser duty using Distillation Grand Composite curve
(DGCC) in the Aspen plus Simulator Both Thermal and Hydraulic Analysis.
Current Operating Condition
Feed Temp 107 0C
Top Pressure 0.64 kg/cm2G
Feed Entry Stage 47
Total No. of Stage 84
Reflux rate 19142 kg/hr.
Shifted Operating Condition
Feed Temp 110 0C
To Adjust Purity Reflux Rate set @ 19500 kg/hr.

91

Block BZ: Column Grand Composite Curve (Stage-H)


Ideal Profile
Actual Profile

81
71

Stage

61
51
41
31
21
11
1
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00 1.05 1.10 1.15 1.20 1.25 1.30 1.35 1.40 1.45 1.50 1.55 1.60 1.65 1.70 1.75 1.80
Enthalpy Deficit Gcal/hr

145
140
135

Block BZ: Column Grand Composite Curve (T-H)


Ideal Profile
Actual Profile

Temperatu re C

130
125
120
115
110
105
100
95
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00 1.05 1.10 1.15 1.20 1.25 1.30 1.35 1.40 1.45 1.50 1.55 1.60 1.65 1.70 1.75 1.80 1.85
Enthalpy Deficit Gcal/hr

Above Both Graph generated @ 107 0C Feed temp having above reboiling and condenser duty. With desire product
specification. Below Table is Thermal Analysis of Column

Stage

Temperature
C

Pressure

kg/sqcm

Enthalpy deficit Exergy loss

Gcal/hr Gcal/hr

Carnot factor

Real enthalpy deficit

Gcal/hr

97.792749

1.71322745

1.75672127

0.000556795828

0.196237153

1.75672127

97.9365478

1.72009492

1.75657421

0.000911079395

0.196548617

98.0817884

1.72696239

1.75650653

0.000550353341

0.196862959

98.2266693

1.73382986

1.75646633

0.000548621529

0.197176278

98.3712226

1.74069733

1.75644241

0.000547186072

0.197488644

98.5164875

1.7475648

0.977419611

3.2629162

98.6605416

1.75443227

0.717271957

0.000542978454

98.8042295

1.76129974

0.588907988

0.00054064443 0.19842288

98.9476129

1.76816721

0.5135312

0.000538485391

0.198731758

10

99.090746

1.77503468

0.464670401

0.000536444903

0.19903986

11

99.2336864

1.78190215

0.430924372

0.000534503813

0.199347311

12

99.3764988

1.78876962

0.406570616

0.000532659157

0.19965425

13

99.5192585

1.79563709

0.388419376

0.000530916348

0.199960841

14

99.6620538

1.80250456

0.374550935

0.000529286334

0.200267274

15

99.8049903

1.80937203

0.363740129

0.000527784685

0.200573775

16

99.9481943

1.8162395

0.355167928

0.000526431511

0.200880614

17

100.091817

1.82310697

0.348265747

0.000525251798

0.201188114

18

100.236041

1.82997444

0.3426262

0.000524275977

0.201496663

19

100.381085

1.83684191

0.337949319

0.00052354068 0.201806726

20

100.527213

1.84370938

0.334008729

0.000523089619

0.202118861

21

100.674739

1.85057685

0.330629552

0.000522974564

0.202433737

22

100.824044

1.85744432

0.327673461

0.000523256364

0.202752156

23

100.97558

1.86431179

0.325028259

0.00052400594 0.203075075

24

101.12989

1.87117926

0.322600357

0.000525305135

0.203403635

25

101.287619

1.87804673

0.320309194

0.000527247246

0.203739194

26

101.44953

1.8849142

0.318082948

0.00052993699 0.204083359

27

101.616528

1.89178167

0.315855157

0.000533489549

0.197802304

0.198113107

0.204438024

28

101.789672

1.89864914

0.313561968

0.000538028227

0.204805408

29

101.970197

1.90551661

0.311139859

0.000543680077

0.205188091

30

102.15953

1.91238408

0.308523745

0.000550568763

0.205589051

31

102.359302

1.91925155

0.305645427

0.000558803774

0.20601168

32

102.571354

1.92611902

0.302432416

0.00056846514 0.206459795

33

102.797726

1.93298649

0.298807196

0.000579582984

0.206937617

34

103.040638

1.93985396

0.29468706

0.000592111807

0.207449709

35

103.302434

1.94672143

0.289984691

0.000605900447

0.20800087

36

103.585502

1.9535889

0.284609703

0.000620660318

0.208595956

37

103.89216

1.96045637

0.278471375

0.000635936859

0.209239624

38

104.224489

1.96732384

0.271482775

0.000651091717

0.209935995

39

104.584135

1.97419131

0.263566397

0.000665305441

0.210688227

40

104.97208

1.98105878

0.254661215

0.000677610984

0.211498043

41

105.388394

1.98792625

0.244730824

0.000686965678

0.212365233

42

105.832019

1.99479372

0.233771921

0.000692362204

0.213287213

43

106.3006

2.00166119

0.221822062

0.000692967756

0.214258721

44

106.790433

2.00852866

0.208965283

0.000688267619

0.215271728

45

107.296536

2.01539613

0.19533419

0.000678179731

0.21631564

46

107.812875

2.0222636

0.181107466

0.000663106443

0.217377808

47

108.488146

2.02913107

0.0105951738 0.000739803436

0.218762582

48

108.652385

2.03599854

0.014842607

0.000459852058

0.219098644

49

108.809577

2.04286601

0.0215218332 0.000460240363

0.219420018

50

108.979606

2.04973348

0.0315201326 0.000462565067

0.219767337

51

109.169424

2.05660095

0.0463771976 0.000468882632

0.220154716

52

109.388978

2.06346842

0.0682447431 0.000483605647

0.220602299

53

109.652923

2.07033589

0.0999996098 0.000515703852

0.221139699

54

109.982623

2.07720336

0.145238288

0.000582536225

0.221809937

55

110.408675

2.08407083

0.207979372

0.00071537332 0.222674341

56

110.973734

2.0909383

0.291851927

0.000964990498

0.223817813

57

111.734751

2.09780577

0.398648279

0.00140203342 0.225352527

58

112.762645

2.10467324

0.526540564

0.00210247851 0.227415831

59

114.135711

2.11154071

0.668935811

0.00310894776 0.230154919

60

115.922105

2.11840818

0.815216122

0.00437238525 0.233689602

61

118.149383

2.12527565

0.953639662

0.00570721807 0.238051443

62

120.769285

2.13214312

1.0749148

0.00681493858 0.243119057

63

123.64019

2.13901059

1.1743231

0.00740206371 0.248595335

64

126.550639

2.14587806

1.25157532

0.0073301101 0.254066743

65

129.281125

2.15274553

1.30925009

0.00667945402 0.259127882

66

131.66871

2.159613

1.35109296

0.00567981337 0.263497479

67

133.637931

2.16648047

1.38086534

0.00458105477 0.267062818

68

135.191778

2.17334793

1.40179801

0.00356269317 0.269851835

69

136.381867

2.1802154

1.41644417

0.00271299736 0.271973626

70

137.278749

2.18708287

1.42672961

0.00205117034 0.273564532

71

137.952185

2.19395034

1.43407464

0.00155880462 0.274754523

72

138.461705

2.20081781

1.43952674

0.00120358922 0.27565228

73

138.854037

2.20768528

1.44388066

0.00095249921 0.276342042

74

139.164018

2.21455275

1.4477819

0.000777363983

0.276886095

75

139.416782

2.22142022

1.45181844

0.000656229657

0.277329119

76

139.630074

2.22828769

1.45661041

0.000572854515

0.277702538

77

139.816252

2.23515516

1.46291075

0.000515602939

0.278028172

78

139.983845

2.24202263

1.4717364

0.000476311538

0.278321048

79

140.138707

2.2488901

1.48456077

0.000449335503

0.278591466

80

140.284848

2.25575757

1.50362402

0.000430816511

0.278846471

81

140.425019

2.26262504

1.53247436

0.000418151881

0.279090887

82

140.56111

2.26949251

1.57699327

0.000409651405

0.279328032

83

140.694443

2.27635998

1.64753413

0.000404603655

0.279560219

84

140.825959

2.28322745

1.7639795

0.00281616479 0.279789095

85

140.825959

2.28322745

1.7639795

3.20317309E-15

0.279789095

1.7639795

Hydraulic Analysis
Block BZ: Hydraulic Analysis (Molar Flow Rates)

400

Thermodynamic ideal minimum flow


Actual flow
Hydraulic maximum flow

Vapor Flow Rate kmol/h r

350
300
250
200
150
100
50
0

11

16

21

26

31

36

41

46

51

56

61

66

71

76

81

Stage

Stage

Ideal minimum vapor flow (Mole)


kmol/hr

kmol/hr

245.072474

Actual vapor flow (Mole)

kmol/hr

353.648839

0.0303054342 245.141978

353.749137

0.0397466724 245.213491

354.424662

0.0453555436 245.284204

355.094021

0.0486918601 245.352695

355.758788

108.846682

245.342953

357.174487

145.166247

245.332576

357.842865

163.078702

245.322062

358.510244

173.590058

245.311363

359.17579

10

180.397426

245.300422

359.839427

11

185.093072

245.289179

360.501061

12

188.476162

245.277559

361.160568

13

190.992148

245.265475

361.817796

14

192.909111

245.252822

362.472561

15

194.398123

245.239472

363.124638

16

195.573521

245.225273

363.773755

Hydraulic maximum vapor flow (Mole)

86

17

196.51464

245.210038

364.419583

18

197.278275

245.193545

365.061726

19

197.906186

245.175522

365.699705

20

198.429814

245.155648

366.33294

21

198.873363

245.133531

366.960737

22

199.255875

245.108709

367.582262

23

199.592682

245.080626

368.196514

24

199.89644

245.048626

368.802304

25

200.177903

245.011931

369.398217

26

200.446505

244.96963

369.982581

27

200.710821

244.92066

370.553435

28

200.978934

244.863791

371.108495

29

201.258745

244.797622

371.645123

30

201.558223

244.720568

372.160309

31

201.885616

244.630873

372.650667

32

202.249615

244.526631

373.112453

33

202.659467

244.405828

373.541615

34

203.125021

244.266411

373.933893

35

203.656694

244.106396

374.284974

36

204.265322

243.923998

374.590705

37

204.961876

243.717811

374.847391

38

205.757009

243.487005

375.052143

39

206.660423

243.231537

375.203283

40

207.680057

242.95235

375.300749

41

208.82112

242.651521

375.346467

42

210.085062

242.332337

375.344631

43

211.46861

241.999287

375.301849

44

212.963052

241.658031

375.227217

45

214.554011

241.315583

375.132584

46

216.22207

240.981424

375.03392

47

241.052003

242.434588

376.177318

48

240.53709

242.515792

374.596904

49

239.649322

242.559602

375.067205

50

238.282591

242.581772

375.530338

51

236.216217

242.572453

375.931836

52

233.141742

242.516849

376.242009

53

228.64749

242.393987

376.419044

54

222.220138

242.175097

376.404316

55

213.288681

241.822623

376.118503

56

201.34263

241.291345

375.460013

57

186.141371

240.53408

374.309511

58

167.970335

239.515096

372.545974

59

147.801989

238.232657

370.078591

60

127.181513

236.745545

366.891086

61

107.799654

235.186906

363.079771

62

90.972044

233.742836

358.856182

63

77.3357314

232.590286

354.501258

64

66.8808849

231.826799

350.297073

65

59.1901867

231.441891

346.476986

66

53.694615

231.346375

343.20447

67

49.8420561

231.427995

340.565044

68

47.1720224

231.593469

338.56659

69

45.3302028

231.783053

337.153899

70

44.0554895

231.966251

336.234667

71

43.158902

232.131493

335.705776

72

42.5030046

232.277124

335.471457

73

41.9844399

232.405642

335.451948

74

41.519539

232.520682

335.58527

75

41.0319297

232.625679

335.825413

76

40.440632

232.723416

336.139219

77

39.6467491

232.815934

336.503209

78

38.5161451

232.904492

336.90077

79

36.8539697

232.989268

337.319588

80

34.3635461

233.068074

337.748498

81

30.5745757

233.131927

338.171105

82

24.7072595

233.150426

338.547867

83

15.3900043

233.023977

338.759618

84

232.42773

85

338.42398

Product specification
Stage

BENZENE

TOLUENE

CYCLOHAX

METYLCYC

ETHYL-01

0.999744695

3.75593381E-06

0.000214229664

3.7319346E-05 6.22701414E-15

0.999762241

6.33242686E-06

0.000184350889

4.70760515E-05

1.27703435E-14

0.999771278

1.06734321E-05

0.000158667323

5.93812803E-05

2.61837578E-14

0.999770528

1.79855486E-05

0.00013658633 7.49004297E-05

0.999757629

3.02991697E-05

0.000117599408

9.44724467E-05

1.10010253E-13

0.999719985

5.67335726E-05

9.90725458E-05

0.000124209084

2.68631995E-13

0.999672177

8.90719119E-05

8.87626639E-05

0.000149988025

5.23478503E-13

0.999616027

0.00012860994 8.30312218E-05

0.999551533

0.000176924108

7.98510174E-05

0.000191692171

1.58980146E-12

10

0.999477513

0.000235931322

7.80924198E-05

0.000208463389

2.6442252E-12

11

0.999391927

0.00030796114 7.71258287E-05

12

0.999292002

0.000395842872

7.66002362E-05

0.000235554689

7.04840793E-12

13

0.999174244

0.000503010478

7.63198657E-05

0.000246425947

1.1397006E-11

0.000172331374

0.000222985781

5.36752975E-14

9.32756385E-13

4.33576107E-12

14

0.999034375

0.0006336287 7.61754338E-05

0.000255820982

15

0.998867219

0.000792744394

7.61058435E-05

0.000263931227

2.95284878E-11

16

0.998666534

0.000986467641

7.60768272E-05

0.000270921921

4.74030285E-11

17

0.998424808

0.00122218785 7.60690364E-05

0.000276935381

7.60126398E-11

18

0.998133004

0.00150883066 7.60713927E-05

0.000282093805

1.21784267E-10

19

0.997780259

0.00185716207 7.60773713E-05

0.000286501664

1.94978067E-10

20

0.997353523

0.00228014627 7.6082917E-05 0.000290247729

21

0.996837143

0.00279336422 7.60852684E-05

0.000293406778

4.98832897E-10

22

0.996212377

0.0034154986 7.60822872E-05

0.000296041012

7.97152925E-10

23

0.995456835

0.00416889018 7.6072066E-05 0.00029820121 1.27306467E-09

24

0.994543851

0.00508016676 7.60526906E-05

0.000299927665

2.03170487E-09

25

0.993441782

0.0061809416 7.60220856E-05

0.000301250906

3.23998388E-09

26

0.992113255

0.00750856987 7.59779054E-05

0.000302192253

5.16249321E-09

27

0.99051437

0.00910693977 7.59174506E-05

0.000302764219

8.21795748E-09

28

0.988593921

0.0110272578 7.58375987E-05

0.000302970813

1.30677068E-08

29

0.986292673

0.0133287641 7.57347472E-05

0.000302807777

2.0753819E-08

30

0.983542818

0.0160792812 7.56047705E-05

0.000302262824

3.29138783E-08

31

0.980267727

0.0193554619 7.54429961E-05

0.000301315958

5.21131414E-08

32

0.976382179

0.0232425541 7.524421E-05 0.00029993998 8.23552273E-08

33

0.971793314

0.0278334522 7.50027044E-05

0.000298101306

1.2986183E-07

34

0.96640256

0.0332267617 7.47123841E-05

0.000295761242

2.04253615E-07

35

0.960108852

0.0395235833 7.4366949E-05 0.000292877892

36

0.952813386

0.0468227442 7.39601718E-05

0.000289408831

5.00661911E-07

37

0.944426122

0.0552142977 7.34862811E-05

0.000285314662

7.79531247E-07

38

0.934873979

0.0647713089 7.29404535E-05

0.000280563452

1.20844962E-06

39

0.924110425

0.075540256

40

0.912125688

0.0875307995 7.16219895E-05

0.000269030819

2.8600728E-06

41

0.898956378

0.10070614

7.08498821E-05

0.000262270415

4.36156999E-06

42

0.8846929

0.114975579

7.00080045E-05

0.000254904348

6.60781189E-06

7.2319398E-05 0.000275135895

1.83656047E-11

3.11962744E-10

3.20322264E-07

1.86419499E-06

43

0.869482881

0.130191062

6.91048264E-05

0.000247011808

9.94063238E-06

44

0.85352909

0.146149213

6.81522979E-05

0.000238700701

1.48436005E-05

45

0.837081063

0.162599674

6.71654019E-05

0.00023010351 2.19940924E-05

46

0.820420767

0.179259369

6.61613267E-05

0.000221370007

3.23325266E-05

47

0.796044733

0.203638435

6.88667726E-05

0.000186026663

6.19392566E-05

48

0.795296348

0.204356724

6.01683345E-05

0.000224786792

6.1972984E-05

49

0.794167853

0.205444494

5.255271E-05 0.000273067683

50

0.792485064

0.207073827

4.58779127E-05

0.000333106477

6.21240055E-05

51

0.789977247

0.209512891

4.00178384E-05

0.000407579287

6.22641591E-05

52

0.786245519

0.213157534

3.48606827E-05

0.000499610913

6.24755969E-05

53

0.780708993

0.218585202

3.03067859E-05

0.000612707108

6.2791197E-05

54

0.772536029

0.226623914

2.62668667E-05

0.000750533357

6.32570413E-05

55

0.7605668

0.238430186

2.26608292E-05

0.000916417011

6.39356627E-05

56

0.743248509

0.255554767

1.9417455E-05 0.00111239835 6.49078557E-05

57

0.718633371

0.279946239

1.64754543E-05

0.00133764401 6.6270217E-05

58

0.684531129

0.313800787

1.37863628E-05

0.00158617374 6.81238945E-05

59

0.638938845

0.35913496

1.13192771E-05

0.00184432611 7.05496032E-05

60

0.580821266

0.41700679

9.06591477E-06

0.00208930887 7.35682738E-05

61

0.511087351

0.486537415

7.04209086E-06

0.00229109249 7.70991524E-05

62

0.433231794

0.564262645

5.28055807E-06

0.00241933732 8.09430806E-05

63

0.352955543

0.644502143

3.81401636E-06

0.00245368169 8.48184706E-05

64

0.276618534

0.72089875

2.65563275E-06

0.0023916153 8.84447746E-05

65

0.209333188

0.788324852

1.78889331E-06

0.0022485438 9.16270993E-05

66

0.153816197

0.844037847

1.17198219E-06

0.00205048946 9.42947146E-05

67

0.110412216

0.887665698

7.51082272E-07

0.00182484714 9.64869731E-05

68

0.0778657216 0.920441451

4.73392958E-07

0.00159403963 9.83140558E-05

69

0.0542071612 0.944319332

2.94772234E-07

0.00137329095 9.9921045E-05

70

0.0373907503 0.961336378

1.81977783E-07

0.00117122185 0.00010146789

71

0.0256253996 0.973279797

1.11676919E-07

0.000991566499

6.20321869E-05

0.000103125228

72

0.0174838322 0.981576092

6.82570929E-08

0.000834925887

0.000105081842

73

0.0118920768 0.987300194

4.16054781E-08

0.000700127696

0.000107560277

74

0.00807102928 0.991232967

2.53142949E-08

0.000585139082

0.00011083933

75

0.00546880853 0.99392827

1.53833095E-08

0.000487621929

0.000115284121

76

0.00370058282 0.995772779

9.34008747E-09

0.000405243013

0.000121386162

77

0.00250078429 0.997033562

5.66664308E-09

0.000335830668

0.000129817393

78

0.00168740812 0.997893643

3.43509163E-09

0.000277441418

0.000141503913

79

0.00113628653 0.998477607

2.07988569E-09

0.00022837677 0.000157727389

80

0.000762962714

0.998869597

1.25695734E-09

0.000187174268

0.000180265222

81

0.000510101677

0.999125726

7.57219901E-10

0.000152586596

0.000211584953

82

0.000338827719

0.9992825

4.53696317E-10

0.000123556257

0.000255115138

83

0.000222799445

0.999362384

2.69298106E-10

9.91895367E-05

0.000315627118

84

0.000144172048

0.999377305

1.57225878E-10

7.87309289E-05

0.000399792108

85

0.000144172048

0.999377305

1.57225878E-10

7.87309289E-05

0.000399792108

Now Feed Temp increased with same column condition to 110 0C

Block BZ: Column Grand Composite Curve (T-H)

145

Ideal Profile
Actual Profile

140
135

Temperatu re C

130
125
120
115
110
105
100
95
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00 1.05 1.10 1.15 1.20 1.25 1.30 1.35 1.40 1.45 1.50 1.55 1.60 1.65 1.70 1.75 1.80 1.85
Enthalpy Defic it Gcal/hr
Block BZ: Column Grand Composite Curve (Stage-H)

91

Ideal Profile
Actual Profile

81
71

Stage

61
51
41
31
21
11
1
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00 1.05 1.10 1.15 1.20 1.25 1.30 1.35 1.40 1.45 1.50 1.55 1.60 1.65 1.70 1.75 1.80
Enthalpy Deficit Gcal/hr

Stage

Temperature
C

Pressure

kg/sqcm

Enthalpy deficit Exergy loss

Gcal/hr Gcal/hr

Carnot factor

Real enthalpy deficit

Gcal/hr

97.7927493

1.71322745

1.79051132

0.000567505394

0.196237154

1.79051132

97.9365398

1.72009492

1.79036426

0.000921702069

0.1965486

98.0817803

1.72696239

1.79029657

0.00056093962 0.196862942

98.2266615

1.73382986

1.79025636

0.000559175513

0.197176261

98.3712154

1.74069733

1.79023244

0.000557714101

0.197488629

98.5164656

1.7475648

1.01120807

3.26292694

0.197802257

98.6605266

1.75443227

0.747553142

0.000553468433

0.198113075

98.8042315

1.76129974

0.616982118

0.000551114693

0.198422885

98.9476448

1.76816721

0.540273411

0.000548943452

0.198731827

10

99.0908246

1.77503468

0.490608915

0.000546900581

0.199040029

11

99.2338343

1.78190215

0.456386263

0.000544969249

0.199347629

12

99.3767463

1.78876962

0.431764435

0.000543149449

0.199654782

13

99.519646

1.79563709

0.413480488

0.000541450395

0.199961673

14

99.662635

1.80250456

0.399567441

0.00053988784 0.200268521

15

99.8058363

1.80937203

0.388768437

0.000538483387

0.200575588

16

99.9493983

1.8162395

0.380242512

0.000537264677

0.200883193

17

100.093501

1.82310697

0.373405471

0.000536266049

0.201191718

18

100.238364

1.82997444

0.367838504

0.000535529502

0.20150163

19

100.384252

1.83684191

0.363233

0.000535105894

0.201813492

20

100.531487

1.84370938

0.359355743

0.000535056322

0.202127988

21

100.680461

1.85057685

0.356026109

0.000535453656

0.202445944

22

100.831645

1.85744432

0.353100564

0.000536384116

0.20276836

23

100.98561

1.86431179

0.350461782

0.0005379488 0.203096438

24

101.143043

1.87117926

0.348010727

0.000540264941

0.203431628

25

101.304769

1.87804673

0.345660701

0.000543466601

0.203775664

26

101.471772

1.8849142

0.343332707

0.000547704339

0.204130613

27

101.645221

1.89178167

0.340951726

0.000553143216

0.204498928

28

101.826496

1.89864914

0.338443632

0.000559958262

0.204883497

29

102.017211

1.90551661

0.335732607

0.000568326275

0.205287693

30

102.219236

1.91238408

0.332738984

0.000578412593

0.205715408

31

102.434705

1.91925155

0.329377526

0.000590351351

0.206171082

32

102.666019

1.92611902

0.325556235

0.000604217906

0.206659683

33

102.915821

1.93298649

0.321175841

0.000619992729

0.207186659

34

103.186939

1.93985396

0.316130232

0.000637517526

0.207757812

35

103.482292

1.94672143

0.310308114

0.000656446884

0.208379084

36

103.804746

1.9535889

0.30359627

0.000676202389

0.209056251

37

104.156905

1.96045637

0.295884739

0.000695940763

0.209794477

38

104.54085

1.96732384

0.287074135

0.000714551726

0.210597768

39

104.957833

1.97419131

0.277085072

0.000730702932

0.211468332

40

105.407947

1.98105878

0.265869237

0.00074294555 0.212405916

41

105.889832

1.98792625

0.253421091

0.000749882237

0.213407208

42

106.400457

1.99479372

0.23978859

0.000750379737

0.214465444

43

106.935059

2.00166119

0.225080839

0.000743785827

0.215570323

44

107.487274

2.00852866

0.20947052

0.000730094535

0.216708346

45

108.049481

2.01539613

0.193189459

0.000710005219

0.217863572

46

108.613324

2.0222636

0.176516958

0.000706228055

0.219018744

47

109.246434

2.02913107

0.011196884

0.000610216571

0.220311766

48

109.401661

2.03599854

0.015954383

0.000394666422

0.22062814

49

109.569997

2.04286601

0.0229700492 0.000395916358

0.22097094

50

109.756198

2.04973348

0.0332820276 0.000399670545

0.221349769

51

109.968867

2.05660095

0.0483213321 0.000408589775

0.221781996

52

110.220554

2.06346842

0.0700175214 0.000428015525

0.222292904

53

110.529339

2.07033589

0.100842055

0.000468261257

0.222918803

54

110.920866

2.07720336

0.143709983

0.00054810407 0.223710971

55

111.430647

2.08407083

0.201603088

0.000698938496

0.224739979

56

112.106065

2.0909383

0.276781212

0.000967083532

0.22609914

57

113.006749

2.09780577

0.369602906

0.001408674

0.227904211

58

114.200771

2.10467324

0.477347725

0.00206982155 0.230284222

59

115.753125

2.11154071

0.593833334

0.00294972941 0.233356637

60

117.703864

2.11840818

0.710520333

0.00396053177 0.237182928

61

120.038925

2.12527565

0.818876449

0.00491758412 0.241713129

62

122.66733

2.13214312

0.912727768

0.005592382

0.246748494

63

125.424944

2.13901059

0.989331717

0.00581554909 0.251960002

64

128.113662

2.14587806

1.04896768

0.00556028478 0.256972339

65

130.558407

2.15274553

1.09376515

0.00494143245 0.261471907

66

132.649662

2.159613

1.12656192

0.00414028532 0.26527785

67

134.35294

2.16648047

1.15015755

0.00332129776 0.268348836

68

135.691443

2.17334793

1.16696013

0.00258940809 0.270744185

69

136.719649

2.1802154

1.17889081

0.00198938858 0.272573608

70

137.501213

2.18708287

1.18741891

0.00152500041 0.273958068

71

138.09566

2.19395034

1.19364778

0.00117930322 0.275007547

72

138.55262

2.20081781

1.19841041

0.000928641442

0.275812236

73

138.910743

2.20768528

1.20235875

0.000750062998

0.276441628

74

139.198849

2.21455275

1.20604366

0.000624300686

0.276947176

75

139.437836

2.22142022

1.20998912

0.000536373791

0.277365996

76

139.642574

2.22828769

1.21476859

0.000475152671

0.277724411

77

139.823518

2.23515516

1.22109486

0.000432603356

0.278040874

78

139.987958

2.24202263

1.22994106

0.000403036739

0.278328234

79

140.140958

2.2488901

1.24272278

0.00038247983 0.278595395

80

140.286025

2.25575757

1.26159683

0.000368191243

0.278848522

81

140.425594

2.26262504

1.28999252

0.000358308067

0.279091889

82

140.561365

2.26949251

1.33363886

0.000351621702

0.279328475

83

140.694539

2.27635998

1.40276263

0.000347682677

0.279560386

84

140.825991

2.28322745

1.5174552

0.00242251871 0.279789151

85

140.825991

2.28322745

1.5174552

0.279789151

1.5174552

Hydraulic Analysis

Block BZ: Hydraulic Analysis (Molar Flow Rates)

400

Thermodynamic ideal minimum flow


Actual flow
Hydraulic maximum flow

Vapor Flow Rate kmol/hr

350
300
250
200
150
100
50
0

11

16

21

26

31

36

41

46

51

56

61

66

71

76

81

Stage

Stage

Ideal minimum vapor flow (Mole)

kmol/hr

kmol/hr

Actual vapor flow (Mole)

kmol/hr

249.786183

353.648842

0.0303071597 249.857016

353.749128

0.0397491868 249.929911

354.424676

0.0453589846 250.002006

355.094063

0.0486961249 250.071887

355.758918

108.846943

250.063512

357.160424

145.65683

250.054479

357.828667

163.878069

250.045289

358.49588

174.575999

250.035889

359.161221

10

181.49616

250.026214

359.824605

11

186.258894

250.016194

360.485925

12

189.679905

250.005741

361.14504

13

192.214851

249.994751

361.801775

14

194.138399

249.983097

362.455912

15

195.62603

249.970626

363.107187

16

196.795122

249.957149

363.755274

Hydraulic maximum vapor flow (Mole)

86

17

197.727168

249.942437

364.399777

18

198.480528

249.926212

365.040212

19

199.098127

249.908133

365.675989

20

199.612315

249.88779

366.30639

21

200.048032

249.864685

366.930547

22

200.424971

249.838219

367.547404

23

200.75908

249.807673

368.155692

24

201.063653

249.772185

368.753886

25

201.35015

249.730735

369.340161

26

201.628821

249.682116

369.912353

27

201.909213

249.624918

370.467906

28

202.200579

249.557507

371.003838

29

202.512221

249.478018

371.516701

30

202.853783

249.384356

372.002568

31

203.235482

249.274216

372.457042

32

203.668283

249.145133

372.875306

33

204.163994

248.994564

373.252239

34

204.735259

248.820018

373.582589

35

205.395405

248.619234

373.861254

36

206.158108

248.39041

374.083649

37

207.036835

248.132474

374.246167

38

208.044019

247.845372

374.346705

39

209.189978

247.530336

374.385214

40

210.481597

247.190076

374.364176

41

211.920906

246.828861

374.288944

42

213.503726

246.452436

374.167859

43

215.218649

246.067817

374.012131

44

217.046664

245.683112

373.835639

45

218.961771

245.307835

373.655216

46

220.933031

244.955023

373.493048

47

206.232311

207.703088

372.423438

48

205.613269

207.745214

373.091934

49

204.669795

207.772875

373.567168

50

203.251375

207.777244

373.984835

51

201.152684

207.747752

374.32281

52

198.097379

207.669591

374.545994

53

193.732358

207.522554

374.605421

54

187.642734

207.280238

374.434946

55

179.407215

206.910441

373.949299

56

168.712847

206.378243

373.046187

57

155.52535

205.653781

371.616431

58

140.257217

204.726205

369.566177

59

123.81805

203.622086

366.851142

60

107.447577

202.419885

363.512918

61

92.3673709

201.245764

359.696231

62

79.4394624

200.240501

355.628709

63

69.0171543

199.508366

351.569352

64

61.015592

199.079906

347.755978

65

55.0924944

198.913646

344.373752

66

50.8193027

198.929742

341.541302

67

47.7885902

199.04757

339.305781

68

45.6603932

199.20713

337.648755

69

44.170491

199.372813

336.504521

70

43.1211299

199.527812

335.784027

71

42.3663079

199.666722

335.395353

72

41.7971164

199.789823

335.256315

73

41.3289042

199.899607

335.299664

74

40.8902611

199.999021

335.473469

75

40.4130424

200.090712

335.739144

76

39.8222515

200.176789

336.068736

77

39.0241681

200.258786

336.442284

78

37.890349

200.337635

336.845493

79

36.2335311

200.413392

337.267552

80

33.7680185

200.484122

337.69826

81

30.0392255

200.542084

338.121847

82

24.2875129

200.56113

338.499166

83

15.1579975

200.455498

338.711127

84

199.944927

85

338.37426

Product specification
Stage

BENZENE

TOLUENE

CYCLOHAX

METYLCYC

ETHYL-01

0.999744754

3.77077559E-06

0.000214194821

3.72803333E-05

6.90356912E-15

0.99976229

6.35693352E-06

0.000184328483

4.70245407E-05

1.41565307E-14

0.999771318

1.07138721E-05

0.000158654519

5.93134174E-05

2.90233015E-14

0.999770556

1.80522367E-05

0.000136580847

7.48112E-05

0.999757636

3.04090642E-05

0.000117599417

9.43553301E-05

1.21918412E-13

0.999720152

5.67928307E-05

9.91243374E-05

0.000123931314

2.96401949E-13

0.999672085

8.93574026E-05

8.872123E-05 0.000149836222

0.999615082

0.000129528151

8.28689335E-05

0.000172521285

1.03512802E-12

0.99954898

0.000179055274

7.95824624E-05

0.000192382035

1.7729943E-12

10

0.999472406

0.000240086651

7.77426319E-05

0.000209765024

2.96533859E-12

11

0.999383051

0.000315256713

7.67182806E-05

0.000224973765

4.89141794E-12

12

0.999277778

0.000407794671

7.6153358E-05 0.000238273925

13

0.999152599

0.000521656111

7.58469119E-05

14

0.999002583

0.00066168273 7.56854273E-05

15

0.998821696

0.000833795781

5.78670818E-13

8.00166283E-12

0.00024989787 1.30223162E-11

0.000260048619

7.56046709E-05

5.94908265E-14

2.11238383E-11

0.000268903297

3.41917869E-11

16

0.998602586

0.00104522975 7.5568168E-05 0.000276616112

5.52622637E-11

17

0.99833631

0.00130481374 7.5555054E-05 0.000283320937

8.92214279E-11

18

0.998012004

0.00162330895 7.55532113E-05

0.00028913352 1.43928346E-10

19

0.997616479

0.00201381156 7.55553841E-05

0.000294153368

2.3201579E-10

20

0.997133747

0.00249223075 7.55569717E-05

0.000298465323

3.7377537E-10

21

0.996544452

0.00307785174 7.55547654E-05

0.000302140878

6.0177449E-10

22

0.995825221

0.00379399262 7.55462146E-05

0.000305239236

9.68234476E-10

23

0.9949479

0.00466876128 7.55289899E-05

0.000307808135

1.55680211E-09

24

0.993878698

0.005735914

7.55007098E-05

0.000309884475

2.50129481E-09

25

0.992577234

0.00703580849 7.54587575E-05

0.000311494749

4.01548312E-09

26

0.990995507

0.00861643103 7.54001476E-05

0.000312655316

6.44028217E-09

27

0.989076839

0.0105344566 7.53214203E-05

0.000313372552

1.03182889E-08

28

0.986754851

0.0128562711 7.52185543E-05

0.000313642923

1.65110632E-08

29

0.983952589

0.0156588449 7.5086897E-05 0.000313453058

30

0.980581966

0.0190302905 7.49211177E-05

0.000312779913

4.20866632E-08

31

0.976543752

0.0230698751 7.47151945E-05

0.000311591167

6.700753E-08

32

0.971728406

0.0278871794 7.44624511E-05

0.000309846015

1.06442965E-07

33

0.966018151

0.0336000277 7.41556675E-05

0.000307496583

1.68639772E-07

34

0.959290694

0.0403307617 7.37872873E-05

0.000304490188

2.66356897E-07

35

0.951425017

0.0482004412 7.33497504E-05

0.000300772698

4.19194187E-07

36

0.942309549

0.0573206645 7.28359702E-05

0.000296293167

6.57016825E-07

37

0.931852763

0.0677829627 7.22399628E-05

0.000291009784

1.02491784E-06

38

0.919995785

0.0796461701 7.15576086E-05

0.000284896945

1.59029694E-06

39

0.906726002

0.0929228043 7.07874899E-05

0.000277952912

2.45279332E-06

40

0.8920899

0.107566204

6.99317039E-05

0.000270207105

3.75799738E-06

41

0.876202775

0.123460786

6.89965107E-05

0.000261725757

5.71609279E-06

42

0.859252745

0.140418021

6.7992655E-05 0.000252614492

43

0.841496868

0.158180268

6.69352219E-05

0.000243016605

44

0.823248429

0.176433457

6.58429496E-05

0.00023310646 1.9164191E-05

2.63828285E-08

8.6268788E-06
1.29130444E-05

45

0.804856232

0.194827757

6.47370325E-05

0.000223078413

2.81950106E-05

46

0.786678612

0.213003493

6.36395639E-05

0.000213132716

4.11222495E-05

47

0.765396388

0.2342751

6.22553146E-05

0.000195220009

7.10363918E-05

48

0.764347813

0.235291851

5.44163833E-05

0.000234822982

7.10964408E-05

49

0.762805046

0.236792188

4.7542629E-05 0.000284035414

50

0.76053499

0.239007129

4.15060359E-05

0.00034504836 7.13271685E-05

51

0.757199616

0.24227222

3.61933975E-05

0.000420436544

7.15346524E-05

52

0.752312263

0.247071265

3.15040982E-05

0.000513126051

7.18412839E-05

53

0.745182864

0.254091239

2.73483372E-05

0.000626259335

7.22895796E-05

54

0.734855234

0.26428531

2.36458411E-05

0.000762873235

7.29370344E-05

55

0.720050397

0.278930153

2.0325284E-05 0.000925266953

56

0.699149256

0.299644361

1.73247532E-05

0.00111391487 7.51433779E-05

57

0.670277471

0.328305209

1.45936359E-05

0.00132583537 7.6891208E-05

58

0.631583448

0.366772689

1.20960397E-05

0.00155257818 7.91893353E-05

59

0.581787429

0.416342118

9.81493916E-06

0.00177855501 8.2082326E-05

60

0.520956692

0.476968839

7.75456292E-06

0.00198118187 8.55319136E-05

61

0.451202064

0.546568133

5.93711741E-06

0.00213447662 8.93893312E-05

62

0.376764695

0.620921297

4.39132634E-06

0.00221620931 9.34064556E-05

63

0.303135091

0.694548866

3.13586708E-06

0.00221561113 9.72961192E-05

64

0.235509058

0.762250995

2.16644895E-06

0.00213696516 0.00010081543

65

0.177438807

0.820459035

1.45391265E-06

0.00199687876 0.000103825753

66

0.130344617

0.867730572

9.52674845E-07

0.00181755478 0.000106303715

67

0.0938669946 0.904403805

6.1266225E-07 0.00162027368 0.000108314348

68

0.0665933229 0.931874679

3.88494437E-07

0.00142163619 0.000109973634

69

0.0467294774 0.951926222

2.43834514E-07

0.00123263655 0.000111420041

70

0.0325345221 0.966293102

1.51928791E-07

0.0010594225 0.00011280099

71

0.0225264359 0.976454571

9.4184313E-08 0.000904626648

72

0.0155364352 0.98357887

5.81839342E-08

0.000768629209

73

0.0106860032 0.98854523

3.58591562E-08

0.00065051959 0.000118210952

7.11882772E-05

7.38581592E-05

0.000114272312
0.000116007016

74

0.00733512855 0.991994961

2.20647986E-08

0.000548743823

75

0.00502711133 0.994386217

1.3561686E-08 0.000461504418

76

0.00344053864 0.996041756

8.32827737E-09

0.000386989373

0.000130708145

77

0.00235129928 0.997186747

5.11034456E-09

0.000323492397

0.00013845631

78

0.00160409785 0.997977129

3.13277616E-09

0.000269467749

0.000149302091

79

0.00109177128 0.99852017

1.91779293E-09

0.000223547767

0.000164508716

80

0.00074057475 0.998889038

1.17138231E-09

0.000184540273

0.000185845677

81

0.00049985188 0.999132937

7.1280393E-10 0.000151415981

82

0.000334845762

0.999284026

4.31016221E-10

0.000123291602

0.000257836352

83

0.000221723964

0.999361998

2.57817527E-10

9.94115304E-05

0.000316866022

84

0.000144147496

0.999376931

1.51318844E-10

7.91289412E-05

0.000399792108

85

0.000144147496

0.999376931

1.51318844E-10

7.91289412E-05

0.000399792108

Note: Benzene product having side withdrawal from column 5th stage

Stage VS Temp Graph

0.000121144852

0.000125153983

0.000215794202

Stage

Liquid temp
C

Vapor temp
C

Pressure
kg/sqcm

97.792749

97.792749

1.71322745

97.9365478

97.9987692

1.72009492

98.0817884

98.1439285

1.72696239

98.2266693

98.2889555

1.73382986

98.3712226

98.4343968

1.74069733

98.5164875

98.5818649

1.7475648

98.6605416

98.725724

1.75443227

98.8042295

98.8692593

1.76129974

98.9476129

99.0125239

1.76816721

10

99.090746

99.1555729

1.77503468

11

99.2336864

99.2984673

1.78190215

12

99.3764988

99.4412773

1.78876962

13

99.5192585

99.5840853

1.79563709

14

99.6620538

99.7269889

1.80250456

15

99.8049903

99.8701051

1.80937203

16

99.9481943

100.013574

1.8162395

17

100.091817

100.157564

1.82310697

18

100.236041

100.302277

1.82997444

19

100.381085

100.447956

1.83684191

20

100.527213

100.594893

1.84370938

21

100.674739

100.74344

1.85057685

22

100.824044

100.894015

1.85744432

23

100.97558

101.047119

1.86431179

24

101.12989

101.203352

1.87117926

25

101.287619

101.363421

1.87804673

26

101.44953

101.528165

1.8849142

27

101.616528

101.69857

1.89178167

28

101.789672

101.875787

1.89864914

29

101.970197

102.061149

1.90551661

30

102.15953

102.256184

1.91238408

31

102.359302

102.462625

1.91925155

32

102.571354

102.682402

1.92611902

33

102.797726

102.917631

1.93298649

34

103.040638

103.170568

1.93985396

35

103.302434

103.443548

1.94672143

36

103.585502

103.738881

1.9535889

37

103.89216

104.058716

1.96045637

38

104.224489

104.40486

1.96732384

39

104.584135

104.778574

1.97419131

40

104.97208

105.180336

1.98105878

41

105.388394

105.609622

1.98792625

42

105.832019

106.064709

1.99479372

43

106.3006

106.542557

2.00166119

44

106.790433

107.03875

2.00852866

45

107.296536

107.547458

2.01539613

46

107.812875

108.061157

2.0222636

47

108.488146

108.569314

2.02913107

48

108.652385

108.723035

2.03599854

49

108.809577

108.887743

2.04286601

50

108.979606

109.069456

2.04973348

51

109.169424

109.27672

2.05660095

52

109.388978

109.522095

2.06346842

53

109.652923

109.823854

2.07033589

54

109.982623

110.208108

2.07720336

55

110.408675

110.711234

2.08407083

56

110.973734

111.381974

2.0909383

57

111.734751

112.281859

2.09780577

58

112.762645

113.481475

2.10467324

59

114.135711

115.049166

2.11154071

60

115.922105

117.029549

2.11840818

61

118.149383

119.414255

2.12527565

62

120.769285

122.117077

2.13214312

63

123.64019

124.973467

2.13901059

64

126.550639

127.776553

2.14587806

65

129.281125

130.336311

2.15274553

66

131.66871

132.528672

2.159613

67

133.637931

134.310581

2.16648047

68

135.191778

135.703778

2.17334793

69

136.381867

136.766123

2.1802154

70

137.278749

137.566534

2.18708287

71

137.952185

138.169633

2.19395034

72

138.461705

138.62907

2.20081781

73

138.854037

138.986298

2.20768528

74

139.164018

139.271925

2.21455275

75

139.416782

139.507897

2.22142022

76

139.630074

139.709657

2.22828769

77

139.816252

139.887952

2.23515516

78

139.983845

140.050252

2.24202263

79

140.138707

140.201888

2.2488901

80

140.284848

140.347181

2.25575757

81

140.425019

140.491242

2.26262504

82

140.56111

140.644526

2.26949251

83

140.694443

140.83669

2.27635998

84

140.825959

141.161162

2.28322745

85

140.825959

140.825959

2.28322745

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