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11
(2)
Decreases
(4)
Remains same
Mass
Volume
On moving down the group atomic mass increases as well as due to addition of shells, there is an increase
in volume. But mass increases at a rate faster than volume.
2.
(2)
(4)
(2)
(4)
All of these
(2)
+1, +2 and +3
(3)
+2, +3 and +4
(4)
+1 and +4
40
5.
Which one of the following elements of group 13 can react with alkali solutions to give H2 gas?
(1) Boron
(2)
Aluminium
(3)
Gallium
(4)
All of these
(2)
(4)
Cl
Cl
Cl
Al
Al
Cl
Cl
Cl
Aluminium forms coordinate bonds with chlorine to complete its octet.
8.
When we heat borax strongly then it will yield the following compound
(1) NaBO2
(2)
B2O3
(3)
Na2B4O7
(4)
(3)
(4)
Pt
Loop
Na2B4O7.10H2O
Na2B4O7 + 10H2O
Anhyd Borax
NaBO2 + B2O3
Glassy bead
9.
(2)
O
O
H
H
+ H2O
H+[B(OH)4]
It does not lose 3H+ but accepts one lone pair from H2O.
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(2)
Acidic nature
(3)
Hydrogen bonds
(4)
Co-ordinate bonds
(2)
(4)
All of these
(3)
Four bonds
H
B
B
H
(2)
Three bonds
(4)
Five bonds
(4)
Aluminium carbide
(2)
Boron carbide
(3)
Aluminium oxide
(2)
12, 3
(3)
3, 3
(2)
Poor conductivity
(3) Heaviness
(4)
All of these
(4)
12, 12
H
H
N
B
H
Borazine
+
N
N+
B
N+
42
(1) ns
(2)
ns np
(3)
ns np
(4)
ns np
(2)
High
(3)
Zero
(4)
Negative
(2)
(4)
(2)
Germanium
(3)
Aluminium
(4)
Arsenic
(2)
Germanium
(3)
Lead
(4)
All of these
Germanium Metalloid
Lead Metal
21. On moving down the group, acidic nature of oxides of group 14
(1) Decreases
(2)
Increases
(4)
(2)
Silicon
(3)
Germanium
(4)
Tin
43
(1) sp hybridisation
(2)
sp hybridisation
(3)
sp hybridisation
(4)
3 2
sp d hybridisation
(3) sp hybridised carbon linked with other three carbon atoms in hexagonal planar structure
(4) All of these
Sol. Answer (4)
In graphite each carbon is sp2 hybridised. It has a layered structure. These layers are attracted by van der
Walls forces.
26. In graphite, the bond is
(1) Ionic
(2)
Covalent
(3)
Co-ordinate
(4)
Metallic
(2)
It is an odourless gas
(4)
All of these
(2)
(4)
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+
H 2CO 3 (aq) + H 2O(l)
HCO 3 (aq) + H 3O (aq)
2
+
HCO 3 (aq) + H 2O(l)
CO 3 (aq) + H 3O (aq)
It is called dibasic because it has two hydrogen ions to donate to a base in an acid base reaction.
29. Organosilicon polymers containing SiOSi linkage is called
(1) Silicates
(2)
Silicones
(3)
Glass
(4)
Silica
30.
Si
monomer.
(2)
Tetrahedral
(4)
Linear
Si
(Tetrahedral geometry)
SECTION - B
Objective Type Questions
1.
(2)
Covalent nature
(4)
(2)
AlCl3
(3)
PCl3
(4)
SnCl4
Borax is
(1) Na2[B4O5(OH)4].8H2O
(2)
Na2[B4O5(OH)6].7H2O
(3) Na2[B4O3(OH)8].6H2O
(4)
Na2[B4O2(OH)10].5H2O
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H
H
H
120 B 97
B
H
H
H
(2)
B2H6
(3)
B2O3
(4)
BO2
(4)
B + HNO3
Red hot
H 2B 4O 7
2B 2O 3 + H 2O
6.
In which of the following reaction boron does not act as reducing agent?
(1) B + CO2
(2)
B + Mg
(3)
B + SiO2
46
8.
(2)
(4)
9.
Na2B4O7
740C
2NaBO2 + B2O3
X + Y
Transparent
Z + CuO(s) Cu(BO2)2
Blue Bead
(2)
(4)
Na2B4O7
740C
2NaBO2 + B2O3
Glass bead
CuO + B2O3
Cu(BO2)2
CuO + NaBO2
NaCuBO3
Blue bead
10. Reaction of ammonia with diborane gives initially B2H6.2NH3 which can also be written as
(1) [BH2(NH3)2]+[BH4]
(2)
[BH4]+[BH2(NH3)2]
(3)
[BH3NH3]+[BH4]
(4)
[B2N2H6]+[H3]
(2)
NaBH4 + I2
(3)
BF3 + LiAlH4
(4)
BF3 + NaH
(2)
(4)
47
(2)
Five
(3)
Six
(4)
Ten
OH
B
O
O
HO
+1
2Na
B
O
OH
.8H2O
O
B
OH
14. The correct match is
(1) C60 Buckminster fullerene
(2)
Na2B4O7.4H2O Kernite
(4)
All of these
(2)
(4)
(2)
CO2
(3)
CO
(4)
CO32
Bond Order
O
O
1
Bond Length
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(2)
Solid CO2
(3)
Solid SO2
(4)
Solid C6H6
(2)
(4)
(2)
Pb < Sn < Ge
(3)
Sn < Ge < Pb
(4)
Sn < Pb < Ge
(2)
(4)
Producer gas
H2O + C
H2 + CO
( H = +131 kJ/mol)
(2)
(4)
Si(OH) 4 + 4HCl
(Silicic acid)
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(2)
(4)
(2)
(4)
(3)
Octahedral
(2)
Square planar
(4)
Planar triangular
Cl
Si
Cl
Cl (Tetrahedral geometry)
Cl
(2)
Ortho silicates
(4)
Pyrosilicate
Si
(Tetrahedral geometry)
50
28.
Cu Powder
CH3Cl Si
2H2O
y
570 K
(2)
(CH3)2Si(OH)2, (CH3)2SiCl2
(4)
Si(OH)4, SiCl4
(1)
Si
Si
CH3
(3)
Si
CH3
(2)
Si O
Si
Si
CH3 CH3
CH3
O
(4)
Si
Si
CH3 CH3
CH3
Polymerisation of silicones
R
HO
Si
R
OH + HO
Si
R
OH + HO
Si
R
OH
Polymerisation
H2O
Si
R
R
O
Si
R
R
O
Si
Silicon
(2)
(4)
All of these
51
(2)
SiF4, Na2SiO3
(3)
Na2SiO3, SiF4
(4)
Na2SiO4, H2SiF6
(3)
Methane
(4)
Propyne
(3)
C3O2
(4)
CO
(2)
Acetylene
(2)
C2O3
SECTION - C
Previous Years Questions
1.
The stability of +1 oxidation state among Al, Ga, In and Tl increases in the sequence
(1) TI < In < Ga < Al
(2)
(4)
[Re-AIPMT-2015]
52
2.
(2)
B4C
[NEET-2013]
(3)
B2H6
(4)
BN
Which of these is not a monomer for a high molecular mass silicone polymer?
(1) Me2SiCl2
(2)
Me3SiCl
(3)
PhSiCl3
[NEET-2013]
(4)
MeSiCl3
Me 3SiOH + HOSiMe 3
Me 3Si O OSiMe 3
4.
(2)
BF3
[NEET-2013]
(3)
PF3
(4)
CO
(2)
SiO32
[NEET-2013]
(3)
SiO24
SiO
(4)
Si
O
6.
[SiO4]4
(2)
(BH3)2
[NEET-2013]
(3)
PH3
(4)
(CH3)2
Which of the following species contains three bond pairs and one lone pair around the central atom ?
[AIPMT (Prelims)-2012]
(1) NH2
(2)
PCl3
(3)
H2O
(4)
BF3
When Cl2 gas reacts with hot and concentrated sodium hydroxide solution, the oxidation number of chlorine
changes from
[AIPMT (Prelims)-2012]
(1) Zero to 1 and zero to +3
(2)
(4)
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6NaOH + 3Cl 2
NaCl + NaClO 3 + 3H 2O
In Cl2, the oxidation number of Cl is O but in NaClO3 the oxidation number of Cl is +5 and 1 in NaCl.
9.
(2)
(1) OH
H2O
(3)
NH3
[AIPMT (Prelims)-2011]
(4)
BF3
(2)
Sheet silicate
(4)
Pyrosilicate
Si
Si
O O
(Si2O7 ) Pyrosilicates
(2)
CO2
[AIPMT (Mains)-2011]
(3)
SnO2
(4)
CaO
(2)
H2O
(3)
B2H6
[AIPMT (Prelims)-2010]
(4)
CH4BF3
(2)
(3)
(4)
(2)
(CH3)3P
[AIPMT (Prelims)-2009]
(3)
(CH3)3N
(4)
(CH3)3B
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(2)
Si2O76
(3)
SiO
2
3
[AIPMT (Prelims)-2007]
(4)
Si O
2
2
5
(2)
+4, +2
(3)
+2, +4
(4)
+4, +4
[AIPMT (Prelims)-2006]
(2)
(4)
(2)
Sb2O3
[AIPMT (Prelims)-2006]
(3)
Bi2O3
(4)
SeO2
(2)
SO24
[AIPMT (Prelims)-2006]
(3)
PO34
(4)
NH4
(2)
BF3
(3)
AlF3
[AIPMT (Prelims)-2006]
(4)
NF3
(2)
C2H6
(3)
[AIPMT (Prelims)-2005]
PH3
(4)
SiH4
55
23. Carbon and silicon belong to (IV) group. The maximum coordination number of carbon in commonly occurring
compounds is 4, whereas that of silicon is 6. This is due to
(1) Availability of low lying d-orbitals in silicon
(2)
(4)
+ H2O
H+[B(OH)4]
(2)
(4)
Cl
Cl
Al
Cl
Cl
Al
Cl
Cl
(2)
(4)
Covalent nature
(2)
(4)
56
(2)
Metaborate
(3)
Double oxide
(4)
Tetraborate
Na 2B 4O 7
2NaBO 2 + B 2O 3
Sodium
metaborate
CuO + B 2O 3
Cu(BO 2 ) 2
Cupric
metaborate
29. Which one of the following statements about the zeolite is false?
(1) They are used as cation exchangers
(2) They have open structure which enables them to take up small molecules
(3) Zeolites are aluminosilicates having three dimensional network
(4) Some of the SiO44 units are replaced by AlO45 and AlO69 ions in zeolites
Sol. Answer (4)
Fact
30. The straight chain polymer is formed by
(1) Hydrolysis of (CH3)2 SiCl2 followed by condensation polymerisation
(2) Hydrolysis of (CH3)3 SiCl followed by condensation polymerisation
(3) Hydrolysis of CH3 SiCl3 followed by condensation polymerisation
(4) Hydrolysis of (CH3)4 Si by addition polymerisation
Sol. Answer (1)
Hydrolysis of (CH3)2 SiCl2 followed by condensation polymerisation forms a straight chain polymer.
Reactions(CH3)2SiCl2 + 2H2O (CH3)2Si(OH)2 + 2HCl
n(CH3)2Si(OH)2 [(CH3)2SiO]n + nH2O
31. The metal oxide which cannot be reduced to metal by carbon is
(1) Fe2O3
(2)
Al2O3
(3)
PbO
(4)
ZnO
(2)
CO2 only
(3)
CO2 + H2O
(4)
CO + CO2 + H2O
COOH
+ H2SO4
COOH
Oxalic acid
CO + CO2 + H2O
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(2)
CaOCl2
(3)
CaCO3
(4)
COCl
SECTION - D
Assertion-Reason Type Questions
1.
H
H
B
N
H
H
Benzene
H
Borazine
2.
A : In Diborane containing eight BH bonds only four BH bonds are on the plane.
R : Boron in B2H6 is sp2 hybridised.
H
B
H
B
Total BH bonds = 8
The bridge bonded hydrogens are out of the plane. Hybridization of boron is sp3.
3.
A : All the oxides of boron family with the general formula M2O3 are basic.
R : From B2O3 to Tl2O3 basic character decreases.
58
4.
Na2B4O7.10H2O
Pt
Loop
Na2B4O7 + 10H2O
NaBO2 + B2O3
Glassy bead
A : Al forms [AlF6]3.
R : It is octahedral complex.
F
F
F
3
Al
F
Octahedral
geometry
F
8.
59
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