Useful Data :

(A) (B)
(C) (D)
Ans. (C)
Sol.
= 1 and molecule will be diamagnetic.
N = 2
= N(N? 2) = 2(2 ? 2) B.M. = 8 B.M. = 2.82 B.M.
CHEMISTRY
RESONANCE Page # 6
6. The packing efficiency of the two dimensional square unit cell shown below is
:
(A) 39.27% (B) 68.02% (C) 74.05% (D) 78.54%
Ans. (D)
Sol.
4R = L 2
so, L = 2 2 R
Area of square unit cell = ( 2 2 R)2 = 8R2
Area of atoms present in one unit cell = ?R2 + ?
?
?
?
? ?
?
? ?
4
R
4
2
= 2?R2
so, packing efficiency = 2
2
8R
2?R
100
=
4
?
100 = 78.54%
SECTION - II
(Integer Type)
This section contains 5 questions. The answer to each question is a single-digit
integer, ranging
from 0 to 9. The correct digit below the question number in the ORS is to be bub
bled.
CHEMISTRY
RESONANCE Page # 7
7. One mole of an ideal gas is taken from a and b along two paths denoted by the
solid and the dashed lines
as shown in the graph below. If the work done along the solid line path is ws an
d that along the dotted line
path is wd, then the integer closest to the ratio wd / ws is :
Ans. 2
Sol. Process shown by solid line is reversible isothermal
So, work Ws = ? 4 0.5 ln (5.5/0.5)
= ? 2 ln 11 L atm.
For dotted process (three step irreversible) work done will be

Wd = ? {4 1.5 + 1 1 + 3
2
2.5} L atm.
= ? {6 + 1 + 3
5
} L atm. = ? 3
26
L atm.
so, 3 2 ln11
26
W
W
s
d
?
? ? 2.
8. Among the following, the number of elements showing only one non-zero oxidati
on state is :
O, Cl, F, N, P, Sn, Tl, Na, Ti
Ans. 2
Sol. Only Na & F will show one non-zero oxidation state. These are
Na+ & F?.
CHEMISTRY
RESONANCE Page # 8
9. Silver (atomic weight = 108 g mol?1) has a density of 10.5 g cm?3. The number
of silver atoms on a surface
of area 10?12 m2 can be expressed in scientific notation as y 10x. The value of
x is :
Ans. 7
Sol. Volume of onemole of silver atoms
=
10.5
108
cm3/mole
volume of one silver atom =
10.5
108
6.022 1023
1
?
cm3
so,
3
4
?R3 =
10.5
108
6.022 1023
1
?
= 1.708 10?23 [neglecting the void space]
R3 = 0.407 10?23 cm3
R3 = 0.407 10?29 m3
Area of each silver atom
?R2 = ? (0.407 10?29 m3)2/3
so, number of silver atoms in given area.
= 29 3 2 / 3
12
(0.407 10 m )
10

?
?
?
=
( 2)
108
? ?
= 1.6 107 = y 10x
x = 7
10. Total number of geometrical isomers for the complex [RhCl(CO)(PPh3)(NH3)] is
:
Ans. 3
Sol. [M(abcd)] complex is square planar, so will have 3 geometrical isomers.
(i) (a T b) (c T d) ; (ii) (a T c) (b T d) ; (iii) (a T d) (b T c)
; ;
11. The total number of diprotic acids among the following is :
H3PO4 H2SO4 H3PO3 H2CO3 H2S2O7
H3BO3 H3PO2 H2CrO4 H2SO3
Ans. 6
Sol. H2SO4 , H3PO3 , H2CO3 , H2S2O7 , H2CrO4 , H2SO3
All are diprotic acids
CHEMISTRY
RESONANCE Page # 9
SECTION - III
(Comprehension Type )
This section contains 2 Paragraphs. Based upon the first paragraph 3 multiple ch
oice questions
have to be answered. Each of these question has four choice (A), (B), (C) and (D
) out of which ONLY
ONE is correct.
Paragraph for Question Nos. 12 to 14
Two aliphatic aldehydes P and Q react in the presence of aqueous K2CO3 to give c
ompound R, which upon
treatment with HCN provides compound S. On acidification and heating, S gives th
e product shown below :
12. The compounds P and Q respectively are :
(A) and (B) and
(C) and (D) and
Ans. (B)
13. The compound R is :
(A) (B)
(C) (D)
Ans. (A)
CHEMISTRY
RESONANCE Page # 10
14. The compound S is :
(A) (B)
(C) (D)
Ans. (D)
Sol. + (cross aldol)
??aq.?K2C?O?3? ??HC?N?
??Intr?am?olec?ula?r e?ster?ific?at?ion?
Paragraph for Question Nos. 15 to 17
The hydrogen-like species Li2+ is in a spherically symmetric state S1 with one r
adial node. Upon absorbing
light the ion undergoes transition to a state S2. The state S2 has one radial no
de and its energy is equal to
the ground state energy of the hydrogen atom.
15. The state S1 is :
(A) 1s (B) 2s (C) 2p (D) 3s

Ans. (B)
CHEMISTRY
RESONANCE Page # 11
Sol. For lower state (S1)
No. of radial node = 1 = n ? ? ? 1
Put n = 2 and ? = 0 (as higher state S2 has n = 3)
So, it would be 2s (for S1 state)
16. Energy of the state S1 in units of the hydrogen atom ground state energy is
:
(A) 0.75 (B) 1.50 (C) 2.25 (D) 4.50
Ans. (C)
Sol. Energy of state S1
= ? 13.6 ?
?
?
?
? ?
?
?
2
2
2
3
eV/atom
=
4
9
(energy of H-atom in ground state)
= 2.25 (energy of H-atom in ground state).
17. The orbital angular momentum quantum number of the state S2 is :
(A) 0 (B) 1 (C) 2 (D) 3
Ans. (B)
Sol. For state S2
No. of radial node = 1 = n ? ? ? 1 ....... (eq.-1)
Energy of S2 state = energy of e? in lowest state of H-atom
= ? 13.6 eV/atom
= ? 13.6 ?
?
?
?
? ?
?
?
2
2
n
3
eV/atom
n = 3.
put in equation (1) ? = 1
so, orbital ? 3p (for S2 state).
SECTION - IV
(Matrix - Type)
This section contains 2 questions. Each question has four statements (A, B, C an
d
D) given in Column-I and five statements (p,q,r,s and t) in Column-II. Any given
statement inColumn-I can have correctmatchingwithONEORMOREstatement(s)
in Column-II. For example, if for a given question, statement B matches with the
statements given in q and r, then for that particular question against statement
B,

darken the bubbles corresponding to q and r in the ORS.

CHEMISTRY
RESONANCE Page # 12
18. Match the reactions in Column I with appropriate options in Column II.
Column I Column II
(A) +
0C
??NaO?H/?H2?O? (p) Racemic mixture
(B) ??H2S?O?4 ? (q)Addition reaction
(C) ?
? ??? ?
2. H O
1. LiAlH
3
4 (r) Substitution reaction
(D) ??Bas?e? (s) Coupling reaction
(t) Carbocation
intermediate
Ans. (A) - r,s ; (B) - t ; (C) - p, q ; (D) - r
Sol. (A) ??NaO??H?
(B) ????
H? ???H?O? 2
????
(?H? )
CHEMISTRY
RESONANCE Page # 13
(C) ??LiAl?H?4 ? ????
H O? 3 (racemic mixture)
(D) ??Bas?e? ??Intra?mo?lec?ula?r su?bst?itut?io?n?
19. All the compounds listed in Column I react with water. Match the result of t
he respective reactions with the
appropriate options listed in Column II.
Column I Column II
(A) (CH3)2SiCl2 (p) Hydrogen halide formation
(B) XeF4 (q) Redox reaction
(C) Cl2 (r) Reacts with glass
(D) VCl5 (s) Polymerization
(t) O2 formation
Ans. (A ? p, s) ; (B ? p, q, r, t); (C?p, q) ; (D?p)
Sol. (A) (CH3)2SiCl2 + H2O ??? (CH3)2 Si(OH)2 + HCl
?
(polymer)
(B) 3XeF4 + 6H2O ???XeO3 + 2Xe +
2
3
O2 + 12HF
(C) Cl2 + H2O ??? HCl + HOCl
(D) VCl5 + H2O ???VOCl3 + 2HCl (First step of hydrolysis)
VCl5 + 2H2O ??? VO2Cl + 4HCl (Complete hydrolysis)
CHEMISTRY
RESONANCE Page # 14
PART-II MATHEMATICS
SECTION - I
Single Correct Choice Type
This section contains 6multiple choice questions. Each question has four choices
(A), (B), (C) and
(D) out of which ONLY ONE is correct.
20. Let f be a real-valued function defined on the interval (?1, 1) such that e?
x f(x) = 2 + ? ?
x

0
t4 1 dt , for all
x ? (?1, 1) and let f?1 be the inverse function of f. Then (f?1)? (2) is equal t
o
(A) 1 (B)
3
1
(C)
2
1
(D)
e
1
Ans. (B)
Sol. f(x) = ex ?
?
?
?
? ?
?
?
? ??
x
0
2 t4 1 dt
Let g(x) = f?1(x) ? g(f(x)) = x
? g? (f(x)) f?(x) = 1
? g?(2) = f (0)
1
? (?f(0) = 2)
Now f?(x) = ex ?
?
?
?
? ?
?
?
? ??
x
0
2 t4 1 dt + ex x4 ?1 (Applying Leibinitz Rule)
? f?(0) = 2 + 1 = 3
? g?(2) =
3
1
? (f?1)? (2) =
3
1
21. Asignal which can be green or red with probability
5
4
and
5
1
respectively, is received by stationAand then
transmitted to station B. The probability of each station receiving the signal c
orrectly is
4
3
. If the signal

received at station B is green, then the probability that the original signal wa
s green is
(A)
5
3
(B)
7
6
(C)
23
20
(D)
20
9
Ans. (C)
RESONANCE Page # 15
MATHEMATICS
Probability (P) = P(GGG) P(GRG) P(RGG) P(RRG)
P(GGG) P(GRG)
? ? ?
?
? P =
4
1
4
3
5
1
4
3
4
1
5
1
4
1
4
1
5
4
4
3
4
3
5
4
4
1
4
1
5
4
4
3
4
3
5
4
? ? ? ? ? ? ? ? ? ? ?
? ? ? ? ?

? P =
36 4 3 3
36 4
? ? ?
?
=
46
40
=
23
20
22. If the distance of the point P(1, ?2, 1) from the plane x + 2y ? 2z = ?, whe
re ? > 0, is 5, then the foot of the
perpendicular from P to the plane is
(A) ?
?
?
??
? ?
3
7
,
3
4
,
3
8
(B) ?
?
?
??
? ?
3
1
,
3
4
,
3
4
(C) ?
?
?
??
?
3
10
,
3
2
,
3
1
(D) ?
?
?
??
? ?
2
5

,
3
1
,
3
2
Ans. (A)
Sol. D = 3
1? 4 ? 2 ? ?
= 5
? + 5 = 15 (? ? > 0)
? ? = 10
? plane is x + 2y ? 2z ? 10 = 0
for positive be (?, ?, ?)
1
? ?1
=
2
? ? 2
=
2
1
?
? ?
= ? ?
?
?
??
? ? ? ?
9
1 4 2 10
=
3
5
? a =
3
8
, ? =
3
4
, ? = ? 3
7
23. Let S = {1, 2, 3, 4}. The total number of unordered pairs of disjoint subset
s of S is equal to
(A) 25 (B) 34 (C) 42 (D) 41
Ans. (D)
Sol.
S = {1, 2, 3, 4}
Each element can be put in 3 ways either in subsets or we don?t put in any subse
t.
So total number of unordered pairs =
2
3 ? 3 ? 3 ? 3 ?1
+ 1 = 41. [Both subsets can be empty also]
24. For r = 0, 1, ...., 10, let Ar, Br and Cr denote, respectively, the coeffici
ent of xr in the expansions of
(1 + x)10 , (1 + x)20 and (1 + x)30 . Then ?
?
?
10

r 1
Ar (B10Br C10Ar ) is equal to
(A) B10 ? C10 (B) A10 (B2
10 ? C10A10) (C) 0 (D) C10 ? B10
Ans. (D)
RESONANCE Page # 16
MATHEMATICS
Sol. B10 ? ?
? ?
?
10
r 1
2
10 r
10
r 1
ArBr C (A ) = 20B10 (30C20 ? 1) ? 30C10 (20C10 ? 1) = 30C10 ? 20C10 = C10 ? B10
[By sum of series of product of two binomial coefficients]
25. Two adjacent sides of a parallelogramABCD are given by
AB = k ?11 j ?10 i ?2 ? ? and AD = k ? 2 j ? 2 i ? ? ? ? . The side AD is rotate
d by an acute angle ? in the plane of the
parallelogram so that AD becomes AD? . If AD? makes a right angle with the side
AB, then the cosine of the
angle ? is given by
(A)
9
8
(B)
9
17
(C)
9
1
(D)
9
4 5
Ans. (B)
Sol. cos ? =
15 3
2 20 22
?
? ? ?
=
9
8
[Using dot product]
? + ? = 90
? = 90 ? ?
cos ? = sin ? =
9
17
SECTION - II
(Integer Type)
This section contains 5 questions. The answer to each question is a single-digit
integer, ranging
from 0 to 9. The correct digit below the question number in the ORS is to be bub
bled.
26. Let k be a positive real number and let
A=
? ? ? ?

?
? ? ?
?
?
? ?
?
?
2 k 2k 1
2 k 1 2k
2k 1 2 k 2 k
and B =
? ? ?
?
?
? ? ?
?
?
? ?
?
?
k 2 k 0
1 2k 0 2 k
0 2k 1 k
. If det (adj A) + det (adj B) = 106, then [k]
is equal to
(Note : adj Mdenotes the adjoint of a squarematrix Mand [k] denotes the largest
integer less than or equal
to k].
Ans. 4
RESONANCE Page # 17
MATHEMATICS
Sol. det (A) =
2 k 2k 1
2 k 1 2k
2k 1 2 k 2 k
? ?
?
?
C2?C2 ? C3
=
2 k 2k 1 1
2 k 1 2k 2k
2k 1 0 2 k
? ? ?
? ?
?
R2?R2 ? R3
=
2 k 2k 1 1
4 k 0 1 2k
2k 1 0 2 k
? ?
?
?
= (2k + 1)3
? B is a skew-symmetric matrix of odd order therefore det(B) = 0
Now det (adj A) + det (adj B) = 106
? {(2k + 1)3}2 + 0 = 106
? 2k + 1 = 10, as k > 0
? k = 4.5

? [k] = 4
27. Let f be a function defined on R (the set of all real numbers) such that
f?(x) = 2010 (x ? 2009) (x ? 2010)2 (x ? 2011)3 (x ? 2012)4, for all x ? R.
If g is a function defined on R with values in the interval (0, ?) such that f(x
) = ?n (g(x)), for all x ? R, then the
number of points in R at which g has a local maximum is
Ans. 1
Sol. f?(x) = 2010 (x ? 2009) (x ? 2010)2 (x ? 2011)3 (x ? 2012)4
f(x) = ?n (g(x))
? g(x) = ef(x)
? g?(x) = ef(x) . f?(x)
only point of maxima [Applying first derivative test]
28. Let a1, a2, a3, ....., a11 be real numbers satisfying a1 = 15, 27 ? 2a2 > 0
and ak = 2ak?1 ? ak?2 for k = 3, 4, ...., 11.
If
11
a a .... a2
11
22
2
1 ? ? ?
= 90, then the value of
11
a1 ? a2 ? ... ? a11
is equal to
Ans. 0
Sol. a1 = 15
2
ak ? ak?2
= ak?1 for k = 3, 4, ...., 11
? a1 , a2 , ......., a11 are in AP
a1 = a = 15
11
a a ..... a2
n
22
2
1 ? ? ?
= 90 ?
11
(15)2 ? (15 ? d)2 ? .... ? (15 ? 10d)?
= 90
RESONANCE Page # 18
MATHEMATICS
? 9d2 + 30d + 27 = 0 ? d = ? 3 or ?
7
9
Since 27 ? 2a2 > 0 ? a2 <
2
27
? d = ? 3
11
a1 ? a2 ? .... ? a11
=
2
11
11
[30 ?10(?3)]
= 0
29. Consider a triangle ABC and let a, b and c denote the lengths of the sides o

pposite to vertices A, B and C

respectively. Suppose a = 6, b = 10 and the area of the triangle is 15 3 . If ?A
CB is obtuse and if r denotes
the radius of the incircle of the triangle, then r2 is equal to
Ans. 3
Sol. Area of triangle =
2
1
ab sin C = 15 3
?
2
1
. 6 . 10 sin C = 15 3
? sin C =
2
3
? C =
3
2?
(C is obtuse angle)
Now cos C =
2ab
a2 ? b2 ? c2
? ?
2
1
=
2.6.10
36 ?100 ? c2
? c = 14
? r =
s
?
=
2
6 10 14
15 3
? ? = 3
? r2 = 3
30. Two parallel chords of a circle of radius 2 are at a distance 3 ?1 apart. If
the chords subtend at the center,
angles of
k
?
and
k
2?
, where k > 0, then the value of [k] is
[Note : [k] denotes the largest integer less than or equal to k]
Ans. 3
RESONANCE Page # 19
MATHEMATICS
Sol. Since distance between parallel chords is greater than radius, therefore bo
th chords lie on opposite side of
centre.
2 cos
2k
?
+ 2 cos
k

?
= 3 + 1
Let
2k
?
= ?
? 2 cos ? + 2 cos 2? = 3 + 1
? 2 cos ? + 2 (2 cos2? ? 1) = 3 + 1
? 4 cos2? + 2 cos ? ? (3 + 3 ) = 0
? cos ? =
2(4)
? 2 ? 4 ? 16(3 ? 3 )
=
2(4)
? 2 ? 2 1? 12 ? 4 3
= ? ?
4
1 12 1
2
? ? ?
=
4
?1? (2 3 ?1)
? cos
2k
?
=
2
3
,
2
? ( 3 ? 1)
Rejected
?
2k
?
=
6
?
? k = 3 ? [k] = 3
SECTION - III
Paragraph Type
This section contains 2 Paragraphs. Based upon the first paragraph 3 multiple ch
oice questions
have to be answered. Each of these question has four choice (A), (B), (C) and (D
) out of which ONLY
ONE is correct.
Paragraph for Question Nos. 31 to 33
Consider the polynomial
f(x) = 1 + 2x + 3x2 + 4x3
Let s be the sum of all distinct real roots of f(x) and let t = |s|
31. The real number s lies in the interval.
(A) ?
?
?
??
?
, 0
4
1 ? (B) ?

?
?
??
?
4
3
, 11 ? (C) ?
?
?
??
?
2
1 , ?
4
3 ? (D) ?
?
?
??
?
4
1
0,
Ans. (C)
Sol. f(x) = 1 + 2x + 3x2 + 4x3
f?(x) = 2 + 6x + 12x2 > 0 [as a > 0, D < 0]
f(x) is increasing function so it can atmost one real root.
Using intermediate value theorem
3 ?1/2?1/4
?3/4
f ?
?
?
??
??
4
3
. f ?
?
?
??
?
2
1 ? < 0
? (C) is correct
RESONANCE Page # 20
MATHEMATICS
32. The area bounded by the curve y = f(x) and the lines x = 0, y = 0 and x = t,
lies in the interval
(A) ?
?
?
??
?
, 3
4
3
(B) ?
?
?
??

?
16
11
,
64
21
(C) (9, 10) (D) ?
?
?
??
?
64
21
0,
Ans. (A)
Sol. By estimation of integration
? ? ? ? ?
3 / 4
0
t
0
1/ 2
0
f(x) dx f(x)dx f(x) dx
?
16
15
<?
t
0
f(x)dx <
256
525
Hence option (A) is correct
33. The function f?(x) is
(A) increasing in ?
?
?
??
?
4
1
, t ? and decreasing in ?
?
?
??
?
, t
4
1 ?
(B) decreasing in ?
?
?
??
?
4
1 ? , t ? and increasing in ?
?
?
??

?
, t
4
1 ?
(C) increasing in (?t, t)
(D) decreasing in (?t, t)
Ans. (B)
Sol. f?(x) = 2 + 6x + 12x2
? f??(x) = 6 + 24x
? f??(x) = 6 (4x + 1) > 0 ? x > ?
4
1
Paragraph for Question Nos. 34 to 36
Tangents are drawn from the point P(3, 4) to the ellipse
4
y
9
x2 2
? = 1 touching the ellipse at point A and B.
34. The coordinates ofAand B are
(A) (3, 0) and (0, 2) (B) ?
?
?
?
? ?
?
?
15
2 161
,
5
8 ? and ?
?
?
??
?
5
8
,
5
9 ?
(C) ?
?
?
?
? ? ?
?
15
2 161
,
5
8 ? and (0, 2) (D) (3, 0) and ?
?
?
??
?
5
8
,
5

9 ?
Ans. (D)
RESONANCE Page # 21
MATHEMATICS
Sol. Equation of chord of contact
3
x
+ y = 1
x = 3(1 ? y)
Solving with ellipse
4
y
9
x2 2
? = 1 (3, 0)
(?9/5, 8/5) P(3, 4)
(1 ? y)2 +
4
y2
= 1
4(y2 + 1 ? 2y) + y = 4
4y2 ? 8y = 0
y = 0 &
5
8
? x = 2 & 3 ?
?
?
??
?
5
8 1? ? x = 3,
5
9 ?
? Points are (3, 0) and ?
?
?
??
?
5
8
,
5
9 ?
35. The orthocentre of the triangle PAB is
(A) ?
?
?
??
?
7
8
, 5 (B) ?
?
?
??
?
8
25
,

5
7
(C) ?
?
?
??
?
5
8
,
5
11
(D) ?
?
?
??
?
5
7
,
25
8
Ans. (C)
Sol. y coordinate of the orthocentre must be
5
8
36. The equation of the locus of the point whose distances from the point P and
the line AB are equal, is
(A) 9x2 + y2 ? 6xy ? 54x ? 62y + 241 = 0 (B) x2 + 9y2 + 6xy ? 54x + 62y ? 241 =
0
(C) 9x2 + 9y2 ? 6xy ? 54x ? 62y ? 241 = 0 (D) x2 + y2 ? 2xy + 27x + 31y ? 120 =
0
Ans. (A)
Sol. (x ? 3)2 ? (y ? 4)2 =
1 9
x 3y ? 3
?
?
? 10 ?(x2 ? 9 ? 6x) ? [y2 ?16 ? 8y] ?= (x + 3y ? 3)2
= x2 + 9y2 + 9 + 6xy ? 6xy ? 6x ? 18y
? 9x2 + y2 ? 6xy ? 54x ? 62y + 241 = 0
RESONANCE Page # 22
MATHEMATICS
SECTION - IV (Matrix - Type)
This section contains 2 questions. Each question has four statements (A, B, C an
d
D) given in Column-I and five statements (p,q,r,s and t) in Column-II. Any given
statement inColumn-I can have correctmatchingwithONEORMOREstatement(s)
in Column-II. For example, if for a given question, statement B matches with the
statements given in q and r, then for that particular question against statement
B,
darken the bubbles corresponding to q and r in the ORS.
37. Match the statements in Column-I with those in Column-II.
[Note : Here z takes values in the complex plane and Im z and Re z denote, respe
ctively, the imaginary part
and the real part of z.]
Column-I Column-II
(A) The set of points z satisfying (p) an ellipse with eccentricity
5
4

|z ? i| z|| = |z + i|z|| is contained in

or equal to
(B) The set of points z satisfying (q) the set of points z satisfying Im z = 0
|z + 4| + |z ? 4| = 10 is contained in
or equal to
(C) If |w| = 2, then the set of points z = w ?
w
1
(r) the set of point z satisfying |Im z| ? 1
is contained in or equal to
(D) If |w| = 1, then the set of points z = w +
w
1
(s) the set of points z satisfying |Re z| ? 2
is contained in or equal to
(t) the set of points z satisfying |z| ? 3
Ans. (A) - (q,r), (B)-(p), (C) - (p,s,t), (D) - (q,r,s,t)
Sol. (A) |z ? i| z|| = |z + i|z||
? |x + iy ? i x2 ? y2 | = |x + iy + i x2 ? y2 |
? x2 + (y ? x2 ? y2 )2 = x2 + (y ? x2 ? y2 )2
? 4y x2 ? y2 = 0 ? y = 0 ? Im z = 0
RESONANCE Page # 23
MATHEMATICS
(B) |z + 4| + |z ? 4| = 10
Ellipse with 2a = 10 ? a = 5
P(x, y)
S (?4, 0) S(4, 0)
ae = 4 ? e =
5
4
(C) Let w = 2(cos? + isin?)
z = 2(cos? + isin?) ?
2
(cos? ? isin?)
=
2
3cos? ? 5isin?
?
2
3cos?
, y =
2
5sin?
=
9 / 4
x2
+
25 / 4
y2
= 1 e =
5
4
|z| =
4
25sin
4
9cos2 2 ?
?
?
=

4
9 ?16sin2 ?
=
2
5
4sin
4
9 ? 2 ? ?
|Re z| = cos ?
2
3
?
2
3
(D) z = cos? + isin? + cos? ? isin? = 2 cos?
? |z| ? 2
? Im(z) = 0
(Re z) ? |2cos ?| ? 2
|z| ? 2
RESONANCE Page # 24
MATHEMATICS
38. Match the statements in Column-I with those in Column-II.
Column-I Column-II
(A) A line from the origin meets the lines (p) ? 4
1
x ? 2
=
? 2
y ? 1
=
1
z ?1
and
2
3
8 x ?
=
? 1
y ? 3
=
1
z ? 1
at P and Q respectively. If length PQ = d, then d2 is
(B) The values of x satisfying (q) 0
tan?1(x + 3) ? tan?1(x ? 3) = sin?1 ?
?
?
??
?
5
3
are
(C) Non-zero vectors a
? , b
? and c
? satisfy a
? .b
? = 0, (r) 4
(b ? a).(b ? c) ? 0 ? ? ? ?
and 2|b c | | b ? a |

? ? ? ?
? ? . If a b 4c
? ? ? ? ?
then possible value of are
(D) Let f be the function on [??, ?] given by (s) 5
f(0) = 9 and f(x) =
??
?
??
?
??
?
??
?
2
x
sin
2
9x
sin
for x ? 0. The value
of ?
2 ?
?
??
f(x)dx is
(t) 6
Ans. (A) ? (t), (B) ? (p, r), (C)?(q,s), (D)?(r)
Sol. (A) Let the line through origin is ?
x
=
y
=
1
z
? x = ?z , y = z ...........(1)
To find point of intersection of line (1) and line
1
x ? 2
=
? 2
y ? 1
=
1
z ?1
..........(2)
we have
1
?z ? 2
=
? 2
z ? 1
= z + 1
? z =
? 1
3
? = 2
? 1
?
? ???+ 3 + 5 = 0 ..........(3)

RESONANCE Page # 25
MATHEMATICS
To find point of intersection of line (1) and line
2
3
8 x ?
=
? 1
y ? 3
=
1
z ? 1
........(4)
we have
2
3
8 ?z?
=
? 1
?z ? 3
=
1
z ? 1
? z = 3( ? 2)
2
? = 1
? 2
?
? 3??+ = 5 ............(5)
Solving (3) and (5), ? =
2
5
and =
2
5 ?
?? z = 2, x = 5, y = ? 5 for point P
and z =
3
4
, x =
3
10
, y =
3
10 ? for point Q
?? PQ2 =
9
4
+
9
25
+
9
25
= 6
(B) tan?1 (x + 3) ? tan?1 (x ? 3) = sin?1 (3/5)
? tan?1 ? ?
?
?
? ??

?
?
? ?
1 x ? 9
x 3 ? x 3
2 = tan?1 (3/4)
?
x ? 8
6
2 =
4
3
? x2 = 16
? x = 4
(C) Since a
? .b
? = 0
? Let b
? = ?1 i ? , a
? = ?2 j ?
Now 2|b
? + c
? | = |b
? ? a
? | & a
? = b
? + 4c ?
?
4
b ? j ?
i ?
2 2 1
1
?
? ?
? ? = | j ? ? i ? | ?1 ?2
| j ?
i ?
) ? 4 ( | 2 1 ? ? ? = 2 | j ?
i ?
| ?1 ? ?2
squaring
2
2
2 2
?1 (4 ? ) ? ? = 2
2
2
4?1 ? 4?
? 2
3?2 = (12 + 2 ? 8) 2
?1 .........(1)
Also (b
? ? a
? ).(b
? + c
? ) = 0
? )j ? ? i ? (?1 ?2 . ?
?
?

?
? ?
?
? ? ?
? ?
4
i ?
? j ?
i ?
2 1
1 = 0
RESONANCE Page # 26
MATHEMATICS
?
4
(4 ? ) ? 2
2
2
?1 ?
= 0
? 2(4 ? )
1
2
?2 ? ? ..............(2)
from (1) & (2)
12 + 2 ? 8 = 12 ? 3
? 2 ? 5 = 0 ? = 0, 5
(D) I = ?
2 ?
?
??
dx
2
x
sin
2
9x
sin
= ?
4 ?
?
0
dx
2
x
cos
2
x
sin
2
x
cos
2
9x
sin
= ?
8 ?
?
0
sinx

2
x
cos
2
9x
sin
dx
I = ?
4 ?
? ?
0
sin x
sin5x sin4x
dx ......(i)
(using?
b
0
f(x)dx = ? ?
b
0
f(a b ? x)dx )
= ?
4 ?
? ?
0
sin x
sin5x sin4x
dx ......(ii)
Add (i) and (ii)
I = ?
4 ?
?
0
sin x
sin5x
dx
Consider
Ik ? Ik?2 = ?
4 ?
? ? ?
0
sin x
sinkx sin(k 2) x
= ?
8 ?
? ?
0
sin x
cos(k 1)x sin x
Ik = Ik?2
so I5 = I3 ? I5 = I1 = ?
4 ?
?
0
dx = 4
Aliter
Let I = ?
2 ?
?
? ?

sin(x / 2)
sin(9x / 2)
dx
I = ?
4?
?
0
sin(x / 2)
sin(9x / 2)
dx .......(1) (? f(x) is even function)
RESONANCE Page # 27
MATHEMATICS
I = ?
4?
?
0
cos(x / 2)
cos(9x / 2)
dx .......(2)
(using?
b
0
f(x)dx = ? ?
b
0
f(a b ? x)dx )
Add (1) & (2)
I = ?
4 ?
?
0
2sin(x / 2)cos(x / 2)
sin5x
dx = ?
4?
?
0
sin x
sin5x
dx
???I = ?
8 ?
? / 2
0
sin x
sin5x
dx
??? I = ?
8 ?
?
? ?
?
?
? ?
?
? ? / 2
0
5 3
dx
sinx

16sin x ? 20sin x 5sinx

??? I = ?
8 ?
?
?
/ 2
0
(16sin4 x ? 20sin2 x 5)dx
??? I = ?
8
??
?
??
? ?
?
?
? ?
?
? ?
? ? ?
2
5
2 2
1
? 20
4 2 2
3 1
16x
?? I = ?
8
??
?
??
? ?
? ?
2
5 3 ? 5 ?
??? I = 4
RESONANCE Page # 28
PART-III PHYSICS
SECTION - I
Single Correct Choice Type
This section contains 6multiple choice questions. Each question has four choices
(A), (B), (C) and
(D) out of which ONLY ONE is correct.
39. A biconvex lens of focal length 15 cm is in front of a plane mirror. The dis
tance between the lens and the
mirror is 10 cm. A small object is kept at a distance of 30 cm from the lens. Th
e final image is
(A) Virtual and at a distance of 16 cm from mirror
(B) Real and at distance of 16 cm from the mirror
(C) Virtual and at a distance of 20 cm form the mirror
(D) Real and at a distance of 20 cm from the mirror
Ans. (B)
Sol.
First image,
u
1
v
1 ? =

f
1
30
1
v
1
?
? =
15
1
v = 30, image in formed 20 cm behind the mirror.
Second image, by plane mirror will be at 20 cm infront of plane mirror.
For third image,
10
1
v
1 ? =
15
1
15
1
10
1
v
1 ? ? =
30
3 ? 2
=
30
5
v = 6 cm
Ans. Final image is real & formed at a distance of 16 cm from mirror.
RESONANCE Page # 29
PHYSICS
40. A uniformly charged thin spherical shell of radius R carries uniform surface
charge density of ? per unit area.
It is made of two hemispherical shells, held together by pressing them with forc
e F (see figure). F is
proportional to
F F
(A)
2 2
0
R
1 ?
? (B) R
1 2
0
?
? (C) R
1 2
0
?
? (D) 2
2
0 R
1 ?
?
Ans. (A)
Sol.

Electrostatics repulsive force ; Fele =

2
0
2
R
2
? ?
?
?
?
? ?
?
?
?
?
; F = Fele =
0
2 2
2
R
?
? ?
41. A block of mass 2 kg is free to move along the x-axis. It is at rest and fro
m t = 0 onwards it is subjected to
a time-dependent force F (t) in the x direction. The force F (t) varies with t a
s shown in the figure. The kinetic
energy of the block after 4.5 seconds is :
N
O
F(t)
3s t
4.5s
(A) 4.50 J (B) 7.50 J (C) 5.06 J (D) 14.06 J
Ans. (C)
Sol. ?Fdt ? ?p
?
2
1
4 3 ?
2
1
1.5 2 = pf ? 0
? pf = 6 ? 1.5 =
2
9
K.E. =
2m
p2
=
4 2 2
81
? ?
;K.E. = 5.06 J Ans.
RESONANCE Page # 30
PHYSICS
42. Ahollow pipe of length 0.8 m is closed at one end.At its open end a 0.5 m lo
ng uniform string is vibrating in
its second harmonic and it resonates with the fundamental frequency of the pipe.
If the tension in the wire is
50 N and the speed of sound is 320 ms?1, the mass of the string is :

(A) 5 grams (B) 10 grams (C) 20 grams (D) 40 grams

Ans. (B)
Sol. Fundamental frequency of close organ pipe =
1
1
4
V
?
Second harmonic frequency of string =
2
2
2
2V
?
So,
1
1
4
V
? =
2
V2
?
=
4 0.8
320
? =
0.5
1
?
50
2500 = ?
50
? =
50
1
=
0.5
m
m = 10 gm.
43. A vernier calipers has 1 mm marks on the main scale. It has 20 equal divisio
n on the Vernier scale which
match with 16 main scale divisions. For this Vernier calipers, the least count i
s :
(A) 0.02 mm (B) 0.05 mm (C) 0.1mm (D) 0.2mm
Ans. (D)
Sol.
0.8 mm
0
1 mm
0 10
Main scale
20 VSD = 16 MCD
1 VSD = 0.8 MSD
Least count = MSD ? VSD
= 1 mm ? 0.8 mm
= 0.2 mm
RESONANCE Page # 31
PHYSICS
44. A tiny spherical oil drop carrying a net charge q is balanced in still air w

ith a vertical uniform electric field of

strength 105
7
81 ?
?
Vm?1. When the field is switched off, the drop is observed to fall with terminal
velocity
2 10?3 m s?1. Given g = 9.8 m s?2, viscosity of the air = 1.8 10?5 Ns m?2 and th
e density of oil = 900 kg
m?3, the magnitude of q is :
(A) 1.6 10?19 C (B) 3.2 10?19 C (C) 4.8 10?19 C (D) 8.0 10?19 C
Ans. (D)
Sol. In equilibrium,
mg = qE
In absence of electric field,
mg = 6??rv
? qE = 6?qrv
m =
3
4
?Rr3d. = g
qE
d
6 v
qE
3
4 3
? ??
?
? ??
?
??
? = g
qE
After substituting value we get,
q = 8 10?19 C Ans.
SECTION - II
(Integer Type)
This section contains 5 questions. The answer to each question is a single-digit
integer, ranging
from 0 to 9. The correct digit below the question number in the ORS is to be bub
bled.
45. To determine the half life of a radioactive element, a student plots a graph
of dt
dN(t)
?n versus t. Here
dt
dN(t)
is the rate of radioactive decay at time t. If the number of radioactive nuclei
of this element decreases by a
factor of p after 4.16 years, the value of p is :
Ans. 8
RESONANCE Page # 32
PHYSICS
Sol.
dt
dN ? = ?N
dt
dN ? = ?N0e??t
dt

dN
?n = ??t + ?n(?N0)
y = mx + c
m = ??
? =
2
1
[slope by graph =
2
1
]
T = ?
?n2
= 2 0.693 =
n
4.16
n = 3 = no. of half life.
p = z3 = 8. Ans.
46. Image of an object approaching a convexmirror of radius of curvature 20m alo
ng its optical axis is observed
to move from
3
25
m to
7
50
m in 30 seconds. What is the speed of the object in km per hour.
Ans. 3
Sol. R = 20 m, f = 10 m
Formirror,
f
1
U
1
V
1 ? ?
10
1
U
1
25 / 3
1
1
? ?
25
3
10
1
U
1
1
? ? =
50
1 ? ? U1 = ? 50 cm
&
U2
1
50 / 7
1 ? =
10

1
?
U2
1
=
25
1 ? ? U2 = ?25 cm
So, speed = t
U
?
?
=
30
25
m/sec. =
6
5
m/sec.
& in km/hr =
6
5
5
18
= 3 km/hr.
RESONANCE Page # 33
PHYSICS
47. A large glass slab (? = 5/3) of thickness 8 cm is placed over a point source
of light on a plane surface. It is
seen that light emerges out of the top surface of the slab from a circular area
of radius R cm. What is the
value of R?
Ans. 6
Sol. 8 cm C C
tanC =
8
R
............(i)
3
5
sinC = 1.sin90
sinC =
5
3
C = 37
4
3
=
8
R
R = 6 cm.
48. At time t = 0, a battery of 10 V is connected across points Aand B in the gi
ven circuit. If the capacitors have
no charge initially, at what time (in seconds) does the voltage across them beco
me 4 V?
[Take : ?n 5 = 1.6, ?n 3 = 1.1]
Ans. t = 2 sec
Sol. Equation of charging of capacitor,
V = ? t /ReqCeq ?
V0 1 e? ?
Ceq = 2 + 2 = 4 ?F

Req = 1 M?
4 = ?
?
?
?
? ?
?
?
? ? ? ?
? 106 4 10 6
t
10 1 e
e?t/4 = 0.6
RESONANCE Page # 34
PHYSICS
? et/4 =
3
5
?
4
t
= ?n 5 ? ?n 3
? t = 0.5 4
t = 2 sec. Ans.
49. A diatomic ideal gas is compressed adiabatically to
32
1
of its initial volume. If the initial temperature of the
gas is Ti (in Kelvin) and the final temperature is aTi, the value of a is :
Ans. a = 4
Sol. For adiabatic process,
TV??1 = constant
T2 =
1
2
1
1 V
V
T
??
? ??
?
? ??
?
T2 = ? ? 1
5
7
T1 32 ?
T2 = 4T1 ? a = 4 Ans.
SECTION - III
Paragraph Type
This section contains 2 Paragraphs. Based upon the first paragraph 3 multiple ch
oice questions
have to be answered. Each of these question has four choice (A), (B), (C) and (D
) out of which ONLY
ONE is correct.
Paragraph for questions 50 to 52.
When liquid medicine of density ? is to be put in the eye, it is done with the h
elp of a dropper. As the bulb on
the top of the dropper is pressed, a drop forms at the opening of the dropper. W

e wish to estimate the size

of the drop. We first assume that the drop formed at the opening is spherical be
cause that requires a
minimum increase in its surface energy. To determine the size, we calculate the
net vertical force due to the
surface tension T when the radius of the drop is R.When this force becomes small
er than the weight of the
drop, the drop gets detached from the dropper.
50. If the radius of the opening of the dropper is r; the vertical force due to
the surface tension on the drop of
radius R (assuming r << R) is :
(A) 2?rT (B) 2?RT (C)
R
2?r 2T
(D)
r
2?R2T
Ans. (C)
RESONANCE Page # 35
PHYSICS
Sol.
R
F
r
R
Due to surface tension, vertical force on drop = Fv = T2?r sin? = T2?r
R
r
=
R
T2?r 2
51. If r = 5 10?4 m, ??= 103 kgm?3, g = 10 ms?2,T = 0.11 Nm?1, the radius of the
drop when it detaches from
the dropper is approximately :
(A) 1.4 10?3 m (B) 3.3 10?3 m (C) 2.0 10?3 m (D) 4.1 10?3 m
Ans. (A)
Sol. Equating forces on the drop :
R
T2?r 2
= R g
3
? 4 ? 3 (Assume drop as a complete sphere)
R =
2 1/ 4
2 g
3Tr
? ?
?
?
? ?
?
?
?
=
1/ 4
3
8
2 10 10
3 0.11 25 10
? ?

?
?
? ?
?
?
? ?
? ? ? ?
= 14.25 10?4 m = 1.425 10?3 m
52. After the drop detaches, its surface energy is :
(A) 1.4 10?6 J (B) 2.7 10?6 J (C) 5.4 10?6 J (D) 8.1 10?6 J
Ans. (B)
Sol. Surface energy of the drop
U = TA
= 0.11 4? (1.4 10?3)2
= 2.7 10?6 J
RESONANCE Page # 36
Paragraph for questions 53 to 55 PHYSICS
The key feature of Bohr?s theory of spectrum of hydrogen atom is the quantizatio
n of angular momentum
when an electron is revolving around a proton. We will extent this to a general
rotational motion to find
quantized rotational energy of a diatomic molecule assuming it to be rigid. The
rule to be applied is Bohr?s
quantization condition.
53. A diatomic molecule has moment of inertia ?. By Bohr?s quantization conditio
n its rotational energy in the nth
level (n = 0 is not allowed) is :
(A) ?
?
?
?
? ?
?
?
?2?
2
2 8
h
n
1
(B) ?
?
?
?
? ?
?
?
?2?
2
8
h
n
1
(C) ?
?
?
?
? ?
?
?

?2?
2
8
h
n (D) ?
?
?
?
? ?
?
?
?2?
2
2
8
h
n
Ans. (D)
Sol. ?? = 2?
nh
Rotational kinetic energy = 2
2
1 ?? =
?2?
2 2
4
n h
2
1
=
?2?
2 2
8
n h
Ans. (D)
54. It is found that the excitation frequency
tate of rotation for the CO molecule
is close to 1011
4 ?
? Hz. Then themoment of inertia of COmolecule
o (Take
h = 2? 10?34 J s )
(A) 2.76 10?46 kg m2 (B) 1.87 10?46 kg m2
m2
Ans. (B)
Sol. hf = change in rotational kinetic energy
hf =
?2?
2
8
3h
? =
8 f
3h
?2
= 2 11
34
10
4
8

from ground to the first excited s

about its centre ofmass is close t

(C) 4.67 10?47 kg m2 (D) 1.17 10?47 kg
(f = frequency)

3 2 10
?
?
? ?
? ? ? ?
= 0.1875 10?45
? = 1.875 10?46 kg m2 .
55. In a CO molecule, the distance between C (mass = 12 a.m.u.) and O (mass = 16
a.m.u.), where 1 a.m.u. =
10 27
3
5 ? ? kg, is close to :
(1 a.m.u. = 10 27
3
5 ? ? kg) :
(A) 2.4 10?10 m (B) 1.9 10?10 m (C) 1.3 10?10 m (D) 4.4 10?11 m
Ans. (C)
RESONANCE Page # 37
PHYSICS
Sol.
m1r1 = m2r2
12r1 = 16r2
3
4
r
r
2
1 ? ?
?
r1
=
7
4
r1 =
7
4
?
Now, ? = m1r1
2 + m2r2
2
=m1r1(?)
= ? ?
7
4
m1 ?
?
?
??
?
? =
1 2
7
4m
? ?
?
?
??
?
? ? =
4m1

7?
? = 27
46
10
3
5
4 12
7 1.87 10
?
?
? ? ?
? ?
= 0.128 10?9 m = 1.28 10?10 m
SECTION - IV (Matrix - Type)
This section contains 2 questions. Each question has four statements (A, B, C an
d
D) given in Column-I and five statements (p,q,r,s and t) in Column-II. Any given
statement inColumn-I can have correctmatchingwithONEORMOREstatement(s)
in Column-II. For example, if for a given question, statement B matches with the
statements given in q and r, then for that particular question against statement
B,
darken the bubbles corresponding to q and r in the ORS.
RESONANCE Page # 38
PHYSICS
56. Two transparent media of refractive indices ?1 and ?3 have a solid lens shap
ed transparent material of
refractive index ?2 between them as shown in figures in column ??. A ray travers
ing these media is also
shown in the figures. In Column ? different relationships between ?1, ?2 and ?3
are given.Match them to the
ray diagrams shown in Column ??.
Column ? Column ??
(A) ?1 < ?2 (p)
(B) ?1 > ?2 (q)
(C) ?2= ?3 (r)
(D) ?2 > ?3 (s)
(t)
Ans. (A) ? p,r ; (B) ? q,s,t ; (C) ? p,r,t ; (D) ? q, s
Sol. (A)
?2 = ?3
As there is no deviation. As the light bends towards normal in denser medium ?2
> ?1
p ? A & C
RESONANCE Page # 39
PHYSICS
(B)
As light bends away from normal
?2 < ?1
& ?3 < ?2
q ? B & D
(C)
?2 = ?3 (As no deviation)
?2 > ?1 (As light bends + towards normal)
r ? C & A
(D)
?2 < ?1
?3 < ?2
As light bends away from normal
s ? B, D
(E)

?2 = ?3 As no deviation of light
?2 < ?1 As light bend away from normal
t ? C & B
RESONANCE Page # 40
PHYSICS
57. You are given many resistances, capacitors and inductors. These are connecte
d to a variable DC voltage
source (the first two circuits) or anAC voltage source of 50 Hz frequency (the n
ext three circuits) in different
ways as shown in Column ??.When a current ? (steady state for DC or rms forAC) f
lows through the circuit,
the corresponding voltage V1 and V2. (indicated in circuits) are related as show
n in Column ?. Match the
two
Column ? Column ??
(A) ? ? 0,V1 is proportional to ? (p)
V
(B) ? ? 0,V2 > V1 (q)
(C) V1= 0, V2 = V (r)
(D) ? ? 0,V2 is proportional to ? (s)
(t)
RESONANCE Page # 41
PHYSICS
Ans. (A) ? r,s,t ; (B) ? q,r,s,t ; (C) ? p,q ; (D) ? q,r,s,t
As per given conditions, there will be no steady state in circuit ?p?, so it sho
uld not be considered
in options of ?c?.
Ans. (A) ? r,s,t ; (B) ? q,r,s,t ; (C) ? q ; (D) ? q,r,s,t
Sol. (p)
V
As ? is steady state current
V1 = 0 ; ? = 0
Hence, V2 = V
So , answer of P ? C
(q)
In the steady state ;
V1 = 0 as
dt
d?
= 0
? V2 = V = ?R
or V2 ???
an