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PRESEMESTER 1
CHAPTER 3
CHEMICAL
BONDING
Practice : Draw the Lewis dot and cross diagram for these ionic
compound
Sodium chloride
Magnesium fluoride
2+
+
Na
Mg
Cl
_
F
2
Na
Cl
Mg
2+
Aluminium oxide
3+
2O
Al
Al
3+
2
23
Chlorine molecule
Oxygen molecule
Nitrogen molecule
Cl
Be
Cl
Boron trifluoride
Aluminium trichloride
Phosphorous pentachloride
Sulphur hexachloride
Iodine pentachloride
However, not all compounds can have more or less than 8 electrons
in the center of the atom. There are certain limitation towards the
application of the expansion of center atom
For example, nitrogen (N) and phosphorous (P) are both from
15
Group @@@
but phosphorous can exist as PCl3 and PCl5 while
nitrogen can only have NCl3 but not NCl5. This is because
nitrogen
which only have
2 shell, do not have empty dd-orbital
@@@@.....................@@@@@@@@@@@@@@@@@@@@
@@@@.....................
@@@@@@@@@@@@@@@@@@@@
available,
but phosphorous contain dd-orbital to fill in more electron
@@@@@@@@@@@@@@@@@@@@..................................
SiCl
+ 2 H O SiO + 4 HCl
4
2
2
@@@@@@@@@@@@@@@@@@@@@@@@@@.
while CCl4 cannot. Despite the factors that they are from the same
14
group (Group @@@),
CCl4 cannot undergoes hydrolysis as
carbon which only have 2 shell, do not have empty dd-orbital
@@@@@@@@@@@@@@@@@@@@...@@@@@@@@@
available, so water cannot form coordinative with carbon hence
@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@
cannot undergoes hydrolysis.
HCN
CH3COOH
C2H2
NH3
CO32-
SO42-
C3H6
6.2.1
Dative bond
Now, try drawing the Lewis structure for these molecules : SO2,
SO3, NO3- or CO.
SO2
SO3
NO3-
CO
NH4+
BF3.NH3
Cl
Be
Cl
Cl
Be
Cl
Cl
3.
2-
O
C
O
2-
O
C
2-
O
C
Resonance hybrid
2-
O
C
O
CH4
SO42-
silicon tetrachloride
SiCl4
Perchlorate ion
ClO4-
14
For example, in methane, CH4, since carbon is in Group _____so
2s2 2p2
the valance electron of C is _______
State of
molecules
Orbital diagram
____
2s
Excited
state
____
2s
Hybridisati
on state
Illustration / Explanation
109.50
tetrahedral
SO3
Boron trifluoride
BF3
Nitrate ion
NO3-
Carbonate ion
CO32-
13
Since boron is Group ______
element so the electron valance
2s2 2p1
of B is _________
State of
molecules
Orbital diagram
Illustration / Explanation
Excited
state
Hybridisati
on state
____
2s
____
2s
____
pz
Shape of molecule
Trigonal planar
Angle between
bond pair
120o
6.3.4 sp hybridisation
The term sp gives an impression of the hybridisation involved
_____
p orbitals
1 s orbital and _____
1
Examples of molecules which give sp hybridisation are
Carbon dioxide
CO2
Beryllium chloride
Cyanic acid
HCN
Ethyne
BeCl2
C2H2
2
Since beryllium is Group ______
element so the electron
2s2
valance of Be is ___________
State of
molecules
Ground
state
Excited
state
Orbital diagram
____
2s
___ ___
py pz
Illustration / Explanation
Shape of molecule
Linear
Angle between bond pair
180o
6.4
Hybridisation in organic molecules
In this subtopic, were going to witness how is the formation of the
bonding that exist in some organic molecules. The 3 organic
molecules which will be discussed in this subsub-topic are :
methane, CH4
ethene,, C2H4
ethene
ethyne
ethyne,, C2H2
All of the molecules above has carbon in it
14 element. It has the electronic configuration
Carbon is a group _____
2s2 2p2
of ______________
The orbital diagram
Ground state of carbon : _____
_____ _____ _____
2s
2p
Methane, CH4
Type of hybridisation :
_____
2s
Hybridised state
2p
Molecular shape
tetrahedral
@@@@@@@@@@@@@
Angle between the bonding pair :
0
109.5
@@@@@@@@@..
Ethene,, C2H4
Ethene
Type of hybridisation :
Hybridised state
sp2
Molecular shape
Trigonal planar
sp2
_____
pz
Ethyne,, C2H2
Ethyne
Type of hybridisation :
sp
sp
Molecular shape
Linear
py pz
10.5
10.5
10.5
Ground State
Hybridised State
Ground State
Hybridised State
From the 2 examples above, we can tell how the lone pair
electrons affecting the angle between the bonding pair and
bonding pair. In ammonia, not only that there is the repulsion
between bonding pair and bonding pair but theres also the
repulsion between bonding pair and lone pair.
Since the angle between the bonding pair and bonding pair
decrease, theres a probability that its due to the effect of
stronger repulsion between the bonding pair and lone pair
electron. This statement is supported as in the repulsion
between the H
HOH in water is smaller than in ammonia,
NH3. as a conclusion, we can conclude that
VSEPR
Class
# of atoms
bonded to
central atom
# lone
pairs on
central atom
Arrangement of
electron pairs
Molecular
Geometry
AB2
linear
linear
trigonal
planar
AB3
trigonal
planar
AB4
tetrahedral
tetrahedral
AB5
trigonal
bipyramidal
trigonal
bipyramidal
AB6
octahedral
octahedral
VSEPR
Class
# of atoms
bonded to
central atom
# lone
pairs on
central atom
AB3
AB2E
Arrangement of
electron pairs
Molecular
Geometry
trigonal
planar
trigonal
planar
trigonal
planar
bent
VSEPR
Class
# of atoms
bonded to
central atom
# lone
pairs on
central atom
AB4
tetrahedral
tetrahedral
AB3E
tetrahedral
trigonal
pyramidal
Arrangement of
electron pairs
Molecular
Geometry
VSEPR
Class
# of atoms
bonded to
central atom
# lone
pairs on
central atom
AB4
Arrangement of
electron pairs
Molecular
Geometry
tetrahedral
tetrahedral
AB3E
tetrahedral
trigonal
pyramidal
AB2E2
tetrahedral
bent
O
H
VSEPR
Class
AB5
AB4E
# of atoms
bonded to
central atom
5
4
# lone
pairs on
central atom
Arrangement of
electron pairs
Molecular
Geometry
trigonal
bipyramidal
trigonal
bipyramidal
trigonal
bipyramidal
See-saw
VSEPR
Class
AB5
# of atoms
bonded to
central atom
# lone
pairs on
central atom
AB4E
AB3E2
Arrangement of
electron pairs
Molecular
Geometry
trigonal
bipyramidal
trigonal
bipyramidal
trigonal
bipyramidal
trigonal
bipyramidal
distorted
tetrahedron
T-shaped
F
F
Cl
F
10.1
VSEPR
Class
AB5
# of atoms
bonded to
central atom
# lone
pairs on
central atom
AB4E
AB3E2
AB2E3
Arrangement of
electron pairs
Molecular
Geometry
trigonal
bipyramidal
trigonal
bipyramidal
trigonal
bipyramidal
trigonal
bipyramidal
distorted
tetrahedron
trigonal
bipyramidal
T-shaped
linear
I
I
I
VSEPR
Class
# of atoms
bonded to
central atom
# lone
pairs on
central atom
AB6
octahedral
AB5E
octahedral
Arrangement of
electron pairs
Molecular
Geometry
octahedral
square
pyramidal
F
F
F
Br
F
VSEPR
Class
# of atoms
bonded to
central atom
# lone
pairs on
central atom
AB6
octahedral
octahedral
AB5E
octahedral
AB4E2
octahedral
square
pyramidal
square
planar
Arrangement of
electron pairs
Molecular
Geometry
F
Xe
6.6
Electronegativity and Polar Molecules
Electronegativity are measurement of ability of an atom in
molecules to attract a pair of electron
For 2 identical atoms, since they have same electronegativity so
they have no difference in electronegativity
electronegativity.. These molecules are
called polar molecules
While if 2 not identical form a covalent bond, the bonding electrons
will attracted more strongly by more electronegative element. We
can indicate the polarity of hydrogen chloride molecules in 2 ways.
Cl
electron poor
region
electron rich
region
=Qxr
Q is the charge
r is the distance between charges
1 D = 3.36 x 10-30 C m
dipole moment
polar molecule
dipole moment
polar molecule
H
no dipole moment
nonpolar molecule
H
no dipole moment
nonpolar molecule
Methane, CH4
Ethene, C2H4
Benzene, C6H6
Ammonia, NH3
Ethane, C2H6
Chloroethane, C2H5Cl
N
H
H
H
Cyclohexane, C6H12
Chlorocyclohexane,
C6H11Cl
2-
O
C
O
Phosphorous
trichloride, PCl3
Phosphorous
pentachloride, PCl5
cisbut-2-ene
transbut-2-ene
H3C
H
C
C
CH3
Nitrogen dioxide,
Cyanide acid,
Sulphur dioxide,
Ammonia,
Chloroethane,,
Chloroethane
Chlorocyclohexane,,
Chlorocyclohexane
Phosphorous trichloride
CisCis-but
but--2-ene
Methane, ethene
ethene,, benzene,
Sulphur trioxide,
Ammonium ion,
Ethane, cyclohexane
cyclohexane,,
Carbon dioxide,
Carbonate ion,
Phosphorous pentachloride
pentachloride,,
Trans--but
Trans
but--2-ene
Fig. 9.18
3.6.1
A+
B+
Polarisability of anion
3.6.1.1
Polarisation Power of Cation
Polarisation Power of Cation measure the ability of a cation
to polarise the electron cloud of the anion.
2 factors determining the polarisation power of cation
Charge of cation
Size of cation
Greater the charge of ion, higher the
Smaller the size of cation, closer the
effective nuclear charge of cation,
neighboring anion to the nucleus of
hence it will be able to attract the
cation, hence easier for the cation to
neighboring electron density of anion.
polarise the anion and result an
This will caused the polarization power
increment in the polarization power of
of cation increase, hence increase the
cation, and increase the covalent
covalent characteristic of cation.
characteristic of cation.
Both factors can be explained in another term called as charge density where
Charge Density = Charge / Ionic Radius
From the equation above, Charge Density will have a greater value, provided that
cation has a high charge and small cationic radius.
Greater the charge density, higher the polarization power, greater the covalent
characteristic of the cation.
3.6.1.2
Polarisability of Anion
Polarisability of an anion ~ ability of the anion to allow the electron
density to be polarised by cation.
cation.
2 factors determining the polarisability of an anion
Charge of anion
Size of anion
Unlike cation
cation,, anion does not have a term that combined both
factors of charge and ionic radius. However, information of
polarisability of anion enable the prediction of the covalent
characteristic of a molecule, since in order to form a covalent bond,
it depend on both polarisation power of cation and polarisability of
the anion
3.6.2
Prediction of Chemical Bond ::Fajans
Fajans Rule
In 1923,
1923, Kazimierz Fajans formulated an easy guidance to predict
whether a chemical bond will be covalent or ionic, and depend on
the charge on the cation and the relative sizes of the cation and
anion. They can be summarized in the following table
Ionic compound
Large cation
Small anion
Covalent compound
Small cation
Large anion
Cl
Br
Li+
Metallic Bonding
The properties of metals cannot be explained in terms of the
ionic / covalent bond. In ionic / covalent compound, electron
are not free to move under the influence of applied potential
(charge) difference. Therefore, ionic solid and covalent
compound are insulator
insulator..
In metal, electron are delocalised and metal atoms are
effectively ionised
ionised..
Metallic bond ~ electrostatic attraction between the positively
charged metal ion and the electron delocalised
delocalised..
Because of this, electron now can freely move from cathode
to anode when a metal is subjected to an electrical potential.
The mobile electron can also conduct heat by carrying the
kinetic energy from a hot part of the metal to a cold part. This
electron delocalised can also use to explain the electrical
and thermal conductivities of metal
Electrical Conductors
Molecular orbital model == 2 group of energy level.
But there are some case where valence band can also serve
as conduction band (caused by the movement of delocalised
molecular orbital)
Electrical conductivities decrease when temperature
increase vibration of the lattice of ion impedes the free
movement of electron in conduction band.
conduction band
valence band
Insulator
Difference between conductors, semisemi-conductors, and
insulator depend on the energy gap between the 2 bands.
Conductor 2 bands overlaps so conduction band always
partly filled.
Insulator gap between the band is large and no electron
exist in the conduction band. E.g. insulator diamond
When 2s and 2p orbital of C is combine to form 2 energy
bands, valence band is filled with electron.
In insulator, the energy gap between the band is large. Under
normal condition, few electrons in valence band can jump
across to conduction band. If electron cannot reach
conduction band across the gaps, the electrical conduction
cannot take place.
Semiconductor
Theres still energy gaps between 2 bands in semiconductor,
but it is smaller than insulator.
In semiconductor, some electrons have sufficient energy to
jump across the energy gaps and electron can move freely
in conduction band thus enable electrical conduction.
Still, the electrical activity is not as good as metal (conductor)
Increasing temperature can help to improve the conductivity
because electron gain thermal energy and are able to reach
conduction band.
It can also improve its effectiveness by adding small amount
of substance. This adding is what we called doping. It can
help to increase electrons to fill in valence band.
Example of doping is Si dope P (n(n-type). Si dope Ge (p(p-type)
Depend on the needs, this process can help to create the
various type of semiconductor in electronic characteristic.
7.1
Van der Waals forces
Van Der Waals forces are the intermolecular forces formed
between covalently bond molecules which exist as simple
molecules.
There are 2 types of Van Der Waals forces namely
Permanent Dipole Permanent dipole forces
Temporary dipole induced dipole forces
RMM
44
44
50.5
41
DM
0.1
1.3
1.9
3.9
Hydrogen chloride, H Cl
36.5
Melting
point (C)
- 114
Hydrogen bromide, H Br
81.0
- 87
- 66
Hydrogen iodide, H I
128
- 51
- 35
RMM
Boiling
point (C)
- 85
Structure
RMM
Boiling point
(C)
2,2dimethyl
propane
72
2-methylbutane
72
18
72
36
npentane
7.3
Hydrogen Bonding
Hydrogen bond is a special dipole
dipoledipole interaction between
H atom with other atom with high electronegativity
electronegativity.. ( N, O, F )
Decreasing
molar mass
Decreasing boiling point