Report PDF

Thermodynamic Properties
of Minerals and Related

Substances at 298.15 K and
1 Bar (105 Pascals) Pressure
and at Higher Tern peratures
U.S.
GEOLOGICAL
SURVEY
BULLETIN
1452
Thermodynamic Properties
of Minerals
and Related Substances at 298.15 K
and 1 Bar ( 105 Pascals) Pressure
and at Higher Temperatures

By RICHARD A. RoBIE, BRuc: S. HEMINGWAY, and .JAMES R.
U.S.
GEOLOGICAL
SURVEY
FrsHI-:R
BULLETIN
1452
A summary of the thermodynamic data for minerals

at 298.15 K together with calculated values for
the functions G.T' 4Hr.T' 4Gr.T' s~, (H~ - H~gs)/T'
and (GT- H~98 )/T at temperatures up to 1,800 K
Reprinted with corrections 1979
UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1978
DEPARTMENT OF THE INTERIOR

WILLIAM P. CLARK, Secretary
U.S. GEOLOGICAL SURVEY

Dallas L. Peck, Director
First printing 1978

Second printing 1979
Third printing 1984
For sale by the Superintendent of Documents, U.S. Government Printing Office

Washington, D.C. 20402
CONTENTS
Page
Abstract
Introduction
Physical constants and atomic weights ---------------------------------------Reference states and transitions---------------------------------------------Sources of data __ ______ __ ____ ____ __ _________ ___ _______________ _____ _______ _
Methods of calculation ____________________________________________________ - _
2
3
8
9
Thermodynamic properties at 298.15 K -------------------------------------- 12

Thermodynamic properties at high temperatures ---------------------------- 30
References and notes ______________________________________________________ 428
Index of names ------------------------------------------------------------ 447
Index of formulas ---------------------------------------------------------- 452
TABLES
Page
TABLE I. Symbols, constants, and conversion factors -------------------------2. Atomic weights for 1975 ------------------------------------------
3
4
Ill
THERMODYNAMIC PROPERTIES OF
MINERALS AND RELATED SUBSTANCES AT
298.15 K AND 1 BAR (105 PASCALS) PRESSURE
AND AT HIGHER TEMPERATURES
By RICHARD
A. RoBIE, BRUCE S. HEMINGWAY, and jAMES R.
FISHER
ABSTRACT
Selected values for the entropy (S0 ), molar volume (V0 ), and for the enthalpy and Gibbs
free energy of formation (~H, and ~Gr) are given for the elements, 133 oxides~ and 212
other minerals and related substances at 298.15 K. For those materials for which hightemperature heat-capacity or heat-content data are also available (H.j. - Hi98)/T, S;., (G.j. H;98)/T, c~. ~Hr.T. ~Gr.T and log Kr.T are tabulated at 100 K intervals for temperatures up to
1,800 K. For substances that have solid-state phase changes or whose melting or boili~g
point is less than 1,800 K, we have also tabulated the properties listed above at the
temperature of the phase change so that the enthalpy or entropy changes associated with
the transformation form an integral part of the high-temperature tables.
INTRODUCTION
The purpose of these tables of thermodynamic properties is to present

a critical summary of the available thermodynamic data for minerals and
related substances in a convenient form for the use of earth scientists. To
make the tables as useful as possible, we have tried (1) to include enough
auxiliary data so that a single set of tables would suffice for most calculations, (2) to insure internal consistency, and (3) to provide the means for
rapid revision and expansion as new data become available.
This compilation is divided into two sections. In the first section, we
give values for the entropy (8; 98), molar volume (v; 98), the enthalpy of
formation (.~H r, 298 ) and Gibbs free energy of formation (aG r, 298), and the
logarithm of the equilibrium constant of formation (log K1, 298) for the
reference elements, minerals, several oxides, and other substances of
geological interest, where the subscript 298 implies 298.15 K. The tables
in the second section contain values for the thermodynamic properties at
100 K intervals for temperatures up to 1,800 K. The data are arranged in
order of their conventional mineralogical groups. Within each group (for
example, the oxides), the listing is by alphabetical order of the chemical
symbol of the principal cation.
The data have been taken from recent critical evaluations or have been
evaluated by the present authors, and uncertainties have been assigned
to the 298.15 K properties. The sources of data are indicated numerically
0
THERMODYNAMIC PROPERTIES OF MINERALS
in the tables and listed in complete form following the tables. These tables
entirely supersede those of an earlier report on the same subject matter
by Robie and Waldbaum (1968).
The true differential heat c'apacity, CJ,, is rarely measured at temperatures above 400 K because of the ease with which the heat content, H~ H; 98 , may be determined. From the heat-content measurements, one
may derive approximate values for c;, at high temperatures by differentiation of the H~ - H; 98 versus temperature curve. Because many
users find it more convenient to use analytical expressions for heat
capacities rather than tabulated values, we have also provided equations
for the heat capacities at high temperatures.
In order to derive values of CJ, from the experimental heat-content
measurements, the measured values of H~ - H; 98 were fitted to polynomials having six or fewer terms, and constrained so that at. 298.15 K,
H~ - H; 98 was identically equal to 0 and that the first derivative of the
fitted equation at 298.15 K had to equal the value of the heat capacity
obtained by low-temperature calorimetry. This procedure forces the
values of CJ, derived from the heat-content measurements to join
smoothly with the more accurate directly measured values of CJ, determined by low-temperature calorimetry.
The least-squares fitting was done by computer, using either the
program HINC written by D. W. Osborne of Argonne National Laboratory (D. W. Osborne, written com., 1975) or PHAS20 (Haas and Fisher,
1976). The equation used to fit the heat-content data was that suggested
by Haas and Fisher (1976).
H~ - H;98 = A + BT + CT 2 + D/T + ETI~ + FT 3
The first four terms of this equation are those used by Kelley (1960). For
most phases, only four or five terms have been used. In fitting the data,
we have followed a general rule that the number of experimental points
should be approximately three times the number of constants used in the
equation. The tabulated values of the heat capacity, CJ,, at temperatures
above 400 K were obtained by differentiation of the heat-content equation. The derived CJ, equation, and its range of validity, is listed at the
bottom of each high-temperature table.
Thermodynamic properties of gases at high pressures have not been
included in these tables. High pressure-high temperature functions of the
most geologically important gases, H 2 0 and C0 2 , have been given by
Bain (1964), Hilsenrath and others (1955), Robie (1966), and Burnham
and others (1969).
PHYSICAL CONSTANTS AND ATOMIC WEIGHTS
The symbols and constants used in these tables are listed in table 1. The
units adopted for reporting the thermodynamic properties are those of
the International System of Units (81) (Page and Vigoureux, 1972).
REFERENCE STATES AND TRANSITIONS

TABLE
T
K
J
mol
(H.f- H;9s)/T
s:r
(G.f - H;98)/T
c~
Kr
R
F
A
log
1n
V
1.-Symbols, constants, a,nd conversion factors
Temperature in kelvins.
Kelvin, the unit of temperature. It is the fraction 11273.16 of the
thermodynamic temperature of the triple point of water.
Joule, theunitofenergy(orwork). Onejoule = 1/4.1840thermochemical calories or 10 cm3 bar.
Amount of substance of a system that contains as many elementary
entities as there are atoms in 0.012 kilograms of carbon 12. It is
identical with the gfw (gram formula weight).
Pressure in bars. One bar = 105 pascals or 0.1 MPa. The standard
atmosphere is equal to 101325 pascals. The kilogram cm- 2 is equal to
98065.5 pascals.
Superscript indicates that the substance is in its standard state, 1 bar
(105 pascals) for a condensed phase.
Enthalpy at temperature T relative to 298.15 K inJ mol-t, also called
the heat content.
Enthalpy function in J moi- 1 K-l.
Entropy at temperature T, in J moi- 1 K- 1
Gibbs energy function in J mol- 1 K- 1
Heat capacity at constant pressure in J mel- 1 K- 1
Volume of 1 mol of a substance at 1 bar pressure and at 298.15 K, in cm3 ,
or J bar- 1
Enthalpy of melting at 1 bar pressure in J moi- 1
Enthalpy of vaporization to the ideal gas at 1 bar pressure at the
normal boiling point in J mol- 1
Enthalpy of formation from the elements in their 1>tandard reference
states in J mol- 1
Gibbs free energy of formation from the elements in their reference
states in J mol- 1
Equilibrium constant of formation.
Gas constant, 8.3143 0.0008 J K- 1 mol- 1
Faraday constant, 96,487.0 l.OJV- 1 mol- 1
Avogadro's number, (6.022094 0.000008) x l023 mol- 1
Common logarithm, base 10.
Naturallogarithm, base e = 2. 71828 ...
Volt.
Values for the gas constant (R) and the Faraday constant (F) used i~
the calculations are those adopted by the CODATA Task Group (1976),
although their values differ slightly from the most recent least-squares
evaluation of the physical constants by Cohen and Taylor (1973). For
Avogadro's number (used in calculating molar volumes from X-ray cell
dimensions), we have used the value of Deslattes and others (1974)
6.022094 0.000008 x 1023 moi- 1
For convenience, we also give values for the atomic weights for 1975
(scale C12 = 12.000) (Commission on Atomic Weights, 1976) in alphabetical order by their chemical symbol in table 2.
The reference states for ~Hor, ~Gor, and log Kr of the compounds are the
elements in their standard states at 1 bar pressure (10 5 pascals) and the

TABLE :?..-Atomic weight.<; for 197.5
---~--
--
Element
-~
Symbol
Actinium
Silver
Aluminum
Americium
Argon
Arsenic
Astatine
Gold
Boron
Barium
Ac
Ag
Al
Am
Ar
As
At
Au
Beryllium
Bismuth
Bromine
Carbon
Calcium
Cadmium
Cerium
Chlorine
Cobalt
Chromium
Be
Bi
Br
Ba
Ca
Cd
Ce
Cl
Co
Cr
Cesium
Copper
Dysprosium
Erbium
Europium
Fluorine
Iron
Francium
Gallium
Gadolinium
Cs
Cu
Dy
Er
Eu
Germanium
Hydrogen
Helium
Hafnium
Mercury
Holmium
Iodine
Indium
Iridium
Potassium
Ge
Krypton
Lanthanum
LHh i urn
Lutetium
Magnesium
Kr
La
Manganese
Molybdenum
Nit,rogen
Fe
Fr
Ga
Gd
He
Hf
Hg
Ho
In
Ir
K
Li
Lu
Mg
Mn
Mo
Atomic
weight
-------- -
------------
Element
Symbol
------ -
Atomic
weight
227.0278
107.868
26.98154
(243)
39.948
74.9216
( 210)
196.9665
10.81
137.33
Sodium
Niobium
Neodymium
Neon
Nickel
Neptunium
Oxygen
Osmium
Phosphorus
Protactinium
Na
Nb
Nd
Ne
Ni
Np
0
Os
9.01218
208.9804
79.904
12.011
40.08
112.41
140.12
35.453
58.9332
51. 996
Lead
Palladium
Polonium
Promethium
Praseodymium
Platinum
Plutonium
Radium
Rubidium
Rhenium
Pb
Pd
Po
Pm
Pr
Pt
Pu
Ra
Rb
Re
207.2
106.4
(209)
( 145)
140.9077
195.09
(244)
226.0254
85.4678
186.207
132,Q054
63.546
162.50
167.26
151.96
18.9984
55.847
(223)
69.72
157.25
Rhodium
Radon
Ruthenium
Sulfur
Antimony
Scandium
Selenium
Si 1 icon
Samarium
Tin
Rh
Rn
Ru
102.9055
(222)
101.07
32.06
121.75
44.9559
78.96
28.0855
150.4
118.69
72.59
1.0079
4.0026
178.49
200.59
164.9304
126.9045
114.82
192.22
39.0983
Strontium
Tan ta 1 urn
Terbium
Technetium
Tellurium
Thorium
Titanium
Thallium
Thulium
Uranium
83,80
138.9055
6. 941
174.97
24.305
Vanadium
Tungsten
Xenon
Yttrium
Ytterbium
54.9380
95.94
14.0067
Zinc
Zirconium
Pa
Sb
Sc
Se
Si
Sm
Sn
Sr
Ta
Tb
Tc
Te
Th
Ti
Tl
Tm
w
Xe
Yb
Zn
Zr
22.98977
92.9064
144.24
20.179
58.70
237.0482
15.9994
190.2
30.97376
231.0359
87.62
180.9479
158.9254
(97)
127.60
232.0381
47.90
204.37
168.9342
238.029
50.9414
183.85
131. 30
88.9059
173.04
65.38
91.22
stated temperature. The standard states for the condensed elements are
the most stable form at 1 bar pressure and the stated temperature. For
gaseous elements, the standard state is the ideal gas at 1 bar pressure.
The reference pressure for the standard state adopted for these tables is
the bar, that is, 10:; pascals. The reasons for this choice are:
a. In most modern high-pressure-high-temperature equilibrium
studies on minerals, the pressure is measured in bars.
b. The use of the bar as the standard pressure in conjunction with the
joule for energy (or work) simplifies conversion of the Pv term
(cm 3 bar) in high-pressure calculations of mineral equilibria. Thus,
1 joule= 10.0 cm 3 bar in contrast with 1 calorie= 41.2929 cm 3 atm
in terms of older (non-81) units.
c. The standard atmosphere used as the reference pressure for most
thermochemical measurements, with the frequent exception of the
PvT properties of gases, is an arbitrarily adopted unit. In terms of
the 8I base unit of pressure, the standard atmosphere is equal to
101325 pascals.
d. The effect of the change of reference pressure from 1 atmosphere, as
used in an earlier edition of these tables (Robie and Waldbaum,
1968), to the present choice of 1 bar has an insignificant effect upon
the tabulated values of the thermodynamic functions for the condensed phases and only a minor and constant effect for the gas
phases.
All data listed in these tables have been corrected to the standard state
P= 1 bar. For a condensed phase (liquid or solid), it can be readily shown
that the effect of changing the reference state from 1 atmosphere to 1 bar
has only a trivial effect upon all the thermodynamic properties tabulated
in this report except for ~Gor
For a gaseous phase, the reference state is the ideal gas, that is, one
that obeys the equation of state Pv= RT. From the equation of state, it
follows that:
v=RTIP
from which
(OvlaT)p= RIP, and (0 2 vlaT 2 )p= o,
Then from standard thermodynamic rAlations
(OCplaPh=T(0 2 vlaT2 )p=0
and
(08/aPh= -(avlaT)p=- RIP
from which
d8= -(RIP)dP
For the change in pressure from P= 1 atm (1.0135 bar) to 1.000 bar
1.000
~8=- R J (liP)dP=O.ll J mol-' K-'
1.013
Also, for an ideal gas,

dH=TdS+vdP=T(- R/P) dP+(RT/P)dP=O.
Thus, for a gaseous phase, C~, (H~- H; 911 )/T, and .:lHor are independent of
pressure, but the numerical values of .:lGor, and (G~- H; 98 )/T depend
upon the choice of pressure. Similarly it can be shown that the change of
the standard state from a pressure of 1 atmosphere to 1 bar does not affect
the enthalpy of formation (from the elements in their reference states)
but will cause a change in the Gibbs free energy of formation of a
condensed phase if and only if one of the reference elements (usually
oxygen) is a gas.
The entropies of the gaseous elements and compounds were converted
to the standard state P= 1 bar, using the above relations, before entering
the various thermodynamic data into the data bank. Inasmuch as the
computer program calculates .:lG r.T from .:lHor and the entropies or Gibbs
energy functions of the constituent elements, the values of .:lG r,T are
automatically corrected to the 1 bar standard state.
The National Bureau of Standards Technical Note 270 series, the
JANAF thermochemical tables, and the CODATA tables have retained
the use of the standard atmosphere as the reference pressure. The
authors hope that in the near future the General Conference of Weights
and Measures of the International Bureau of Weights and Measures will
recommend the elimination of the standard atmosphere as the reference
pressure.
Data are listed for the elements in their standard reference states, and
for a few in nonstandard states; for example, S2 gas and the diamond form
of carbon. Melting and boiling points and their associated enthalpy
changes are listed at the bottom of each table of high-temperature properties. A horizontal dashed line in the tables indicates a transition in the
phase. A dashed line in the columns .:lHor, .:lG r, and log Kr, indicates a
transition in one of the reference elements. Transitions in the reference
elements are also listed separately at the bottom of each table. Inasmuch
as most of the high-temperature "heat-capacity" d_ata are actually heatcontent measurements and not true heat capacities (C~), we have followed the practice of Kelley (1960) and have treated all the high-temperature transitions as first order at a single temperature. At the transition
temperature, the functions (H~- H; 911 )/T, S~, and .:lHor:r make a s~epwise
change; .:lG r,T and (G~ - H; 911)/T, are continuous, but their temperature
derivatives change abruptly. For those elements (and their compounds)
for which we have, of necessity, adopted a nonequilibrium phase as the
reference state (for example, S2 gas above 716.9 K), ther" will also be a
discontinuity in both .:lGor.T and (G~- - H; 9 H)/T at the transition temperature. These properties of the functions must be borne in mind when
interpolating in the tables.
s:
The reference state adopted for an element above its normal boiling or
sublimation temperature is not necessarily its equilibrium state. Thus, at
equilibrium, liquid sulfur boils at 1 bar pressure and approximately 716.9
K to a gas composed of S, 8 2, 8 4 , 8 6 , SH, etc., but for our reference table,
we have assumed the gas phase to be only 82. In these ambiguous cases,
we have chosen either the dominant species in the gas or that species for
which the best thermodynamic data are available as the reference state.
Enthalpies and Gibbs free energies of formation for multiple-oxide
phases using the binary oxides as reference states have also been computed and tabulated, inasmuch as many mineralogical equilibria involve
only binary or multiple-oxide phases; for example:
2CaSi03 + CaAl2Si 20H = Ca3Al2Si3012 + Si02
wollastonite anorthite
grossular quartz
and because the enthalpies of formation of most multiple-oxide phases are
determined using the binary oxides as the reactants. Tables of the thermodynamic functions for temperatures above 298.15 K for multiple-oxide
phases calculated using the binary oxides as the reference phases immediately follow the appropriate table calculated from the elements
and are differentiated by the heading "FORMATION FROM THE
OXIDES" above the columns for ~Hor, ~Gor, and log Kr and by asterisks
immediately to the right of the entries for ~Hor and ~Gor
When using the binary oxides as the reference states, one must remember that in this convention, ~H~ and ~G~ for these reference oxides
are zero at all temperatures. For example, ~G~ooo for the reaction
2 wollastonite + anorthite = grossu,lar + quartz
may be calculated from either the tabulated values of ~G r, 1000 (elements
as reference states), or ~G~ooo (oxides as reference states) for each of the
phases in the above reaction. Thus:
0
~G~ooo
(oxides)={[ -304.53+0]-[ -136.25+2( -91.18)]}= 14.08 kJ
or
~G~ooo
(elements)={[ -5448. 79+( -729.98)]-[ -3488.51 +2( -1352.17)]}

=14.08 kJ
Both calculations must obviously give the same result within the rounding error. However, in estimating the uncertainty in the resulting value
of ~G~ for a reaction involving onty oxide phases, one should use the
uncertainties associated with the ~G~ values calculated from the oxides,
inasmuch as this value usually corresponds more closely to the actual
calori:Dletric reaction scheme from which the individual ~G~ values were
obtained.
The user is cautioned ~ot to mix values of ~G~ calculated from the
elements for one phase with those obtained from the oxides for another in
calculating ~G~ of a reaction involving the two phases, because a mean-
THERMODYNAMIC PROPERTIES OF
MINE~ALS
ingless result ensues. If a reaction involves both multiple-oxide phases

and nonoxide phases, as in
CaF 2 + 2H20 = Ca(OH) 2 + 2HF
fluorite steam portlandite
AG~ for the reaction must be calculated using only values from the
tabulated values of AG r,T calculated from the elements.
0
SOURCES OF DATA
Many critical evaluations of thermochemical data have been particularly helpful in constructing these tables. For the thermodynamic functions of the elements at high temperatures, we have adopted the values
selected by Hultgren and others (1973). The CODATA (1976) key values
have been adopted when they differed significantly from those of
Hultgren and others (1973). For the sulfides, arsenides, tellurides,
selenides, and sulfosalts, the summaries by Mills (1974) and by Barton
and Skinner (1977) have been very helpful. The tabulations by Kelley
(1960) and by Kelley and King (1961) were particularly useful as a source
of the pre-1960 heat-content and heat-capacity data. We have also relied
heavily upon the critical evaluations of the National Bureau of Standards
Technical Note 270 series (Wagman and others, 1968, 1969, 1971; Parker
and others, 1971; Schumm and others, 1973) and of the JANAF thermochemical tables (Stull and Prophet, 1971; Chase and others, 1974,
1975).
In evaluating the data for the silicates, we have accepted the revised
values for AHor for those silicates given by Hemingway and Robie (1977),
which include corrections for the effect of the particle size of quartz and
for the incorrect value of AHor of gibbsite (Al(OH)a) used in earlier HF
solution calorimetry studies. For those aluminum silicates for which
definitive structural evidence of Al!Si disorder was available we have
corrected the s;98 values for the configurational terms, that is, s~ ~ 0,
arising from frozen-in Al!Si disorder at 0 K, using the summary of Ulbrich
and Waldbaum (1976) as a guide. We have also added a correction to the
entropy of several manganese and iron compounds for which the accepted
value of S;98 was based upon measurements of the heat capacity only
above 50 K and for which other evidence indicated the existence of an
unextracted magnetic contribution to S; 98 below 50 K (see, for example,
Robie, 1965, or Ulbrich and Waldbaum, 1976).
Values for the thermodynamic properties at 298.15 K for the more
common aqueous ions are also listed in order to facilitate calculations of
aqueous equilibria. The reference state for the free energies of the
aqueous ions is the hypothetical ideal solution ofunit molality. Values for
AGor are listed on the basis of the usual convention that AG r, AH r, So, and
C~ are identically 0 for aqueous H+ ion in the hypothetical 1 molal ideal
solution. A more complete discussion of the conventions adopted for
0
METHODS OF CALCULATION
tabulating the thermodynamic properties of aqueous ions has been given

by F. D. Rossini (1950, Chemical thermodynamics: New York, John
Wiley, p. 320-370).
The molar volumes of the condensed phases are principally from the
summary by Robie and others (1967), augmented by more recent precise
X-ray measurements of unit-cell parameters. Although our principal
sources of data for ~Hor, or aG r, have been solution or combustion
calorimetry, for many compoupds the best available data are values of
aGor, calculated from solubilities, electrochemical cells, reduction equilibria, or decomposition pressure data; we have used these equilibrium
studies to supplement the calorimetric data whenever possible. For the
simpler gases, the thermodynamic constants calculated from spectroscopic data are usually the most precise.
In order to insure internal consistency in these tables and because of
the complex nature of many of the reaction schemes used to obtain aH r,
or aG r, we have corrected all the older data to the values adopted here.
For multiple-oxide compounds, the heats of formation are most commonly measured utilizing the binary oxides as reference phases. However, stoichiometric K20 cannot be prepared reproducibly, and FeO is
thermodynamically unstable. Furthermore, a- Al 20:h corundum, is insoluble in all common aqueous calorimetric solvents. Consequently, mixed
sets of reactants such as the alkali halides, aluminum hydroxide
(gibbsite), or an element have frequently been used as the reference
phases in HF solution calorimetry for determining ~Hor of aluminosilicates. For example, Barany (1964) measured the enthalpy change for
the reaction
3Si02+3Al(0Hh+ KC1+9. 731H 20= KA12[A1Si3 0w](0H)2
+ HC112. 731H 20
and by utilizing literature data for the enthalpies of formation of the other
phases, he calculated aH r, 298 for muscovite. Accordingly, any improvement of aHor of quartz, gibbsite, sylvite, or aqueous HCl would alter the
enthalpy of formation of muscovite. Recent measurements of ~H r, 298 of
gibbsite by Hemingway and Robie (1977) have shown that the value of
aH r,298 of gibbsite used by Barany (1964) to calculate the enthalpy of
formation of muscovite was in error by 11230 J mol-, and accordingly we
have corrected Barany's (1964) calorimetric value for aH r, 298 of muscovite, and also several other aluminosilicates for which gibbsite was one of
the reactants, to accord with this new aH(. 298 of gibbsite.
0
Having chosen what we believe are the currently "best available"

values for H.j.- H; 98 , or C~(T), 8;98 , and either aH r, 298 or aG r, 298 , we have
calculated the Gibbs free energy function, and the enthalpy, free energy,
and the equilibrium constant of formation at 100 K intervals using the
following relations:
0
10
(1)
<G~-
H;!JH>tT = <H~- H;!JH>tT- s~

AH f.T = AH f.2!JH + A(H~ - H;!JH)
AG f.T = AH f.2!JH + TA[(G~ - H;!JH)/T]
0
(2)
(3)
and
0
log Kr:r = - AGor.T/2.30258 RT = - AG r,:z!JJ19.1444T
(4)
These values together with C~, S~ and (H~ - H; 98 )/T are tabulated in the
second section.
A Fortran IV program was used for the above calculations. The essential feature of the progr3:m is that internally consistent thermodynamic
functions can be calculated for several hundred compounds in a single run
of the computer. This consistency is accomplished by first calculating the
thermodynamic functions for the reference elements and oxides and then
holding these data in storage for later computations involving substances
having these elements or oxides as reference phases. As new thermodynamic data become available, only a minimum number of changes in
the data base are needed to prepare a completely revised set of internally
consistent tables.
The input data supplied to the computer are the identifying name of the
substance, the entropy, the enthalpy, and Gibbs free energy of formation
at 298.15 K and their uncertainties, and the entropy and enthalpy increments, S~ - 8;98 and H~ - H; 98 , at 100 K intervals, together with the
number of atoms of each element in the chemical formula. Auxiliary data
such as the melting and boiling points and enthalpies of melting and
vaporization are also included. The program computes the formula
weight of the compound on the basis of the atomic weights of the elements
(1975 scale) and values forST, .dHI.T, AGI,T, log Kr,T, Cp, (HT - H29s)/T,
and (GT- H298)/T at 100 K intervals up to 1,800 K.
Although the absolute value of AG r,T or .dH r,T of the more complex
compounds is rarely known more .accurately than 1,000 joules, these
quantities are tabulated to the nearest 10 joules. This procedure is
justified because the temperature derivatives of aGar, and AHor,
0
(d.dGor/dT)p = - asor
(5)
and
(dAHor/dT)p=
(6)
AC~
are calculated from the heat-content data, which are known independently of the enthalpy or Gibbs free energy of formation. The practice of
rounding tabulated values of AGor or AHer on the basis of the uncertainty in
the absolute value does not utilize the full accuracy of the heat-capacity
information and destroys the necessary internal consistency between
.dH r. 29 Hand the Gibbs free-epergy function (eq. 3). Furthermore, in many
instances, the differences between AH r or .dGor for polymorphs are often
known more accurately from phase-equilibria or calorimetric investigations than are the individual AH r or aGor values for a phase, so that
0
11
rounding off again tends to obscure small differences of major importance

in calculations of geological interest.
The uncertainties assigned to the properties apply only to the values at
298.15 K and were taken principally from the original sources of experimental data. By convention, the uncertainty interval reported for
calorimetric measurements is twice the standard deviation of the mean
(Rossini, 1956, p. 319); that is,
8 = 2[L(xi- x) 2/n(n- 1)]'12
(7)
where xi is the value for an individual measurement, xis the arithmetic
mean of all the measurements, and n is the number of observations.
For substances where AH r. 298 is the directly measured quantity, the
free energy was calculated from
AG t,z9s = AH t.29s - 298.15AS f.298
(8)
and the uncertainty in the free energy was calculated from
aG = [(aH) 2 + (298as) 2 + L (298nias) 2 J';.
(9)
where as is the uncertainty in the entropy of the substance, the asi are
the uncertainties in the entropies of the i reference elements, and the ni
are the number of moles of each element in the chemical formula of the
substance. Uncertainties derived in this manner were rounded upward to
the nearest 10 joules.
For substances in which aG is less than a", the basic quantities used in
the calculation were AG r, 298 and aG derived from electrochemical cell
measurements, solubilities, or phase-equilibrium data. Hence, AHor. 298 is
a more indirectly derived quantity having a larger uncertainty. For these
substances, a" was calculated from
a"= [(aG) 2 + (298as) 2 + L (298niasYJ'I:!
(10)
I
Camera-ready copy of the tables of the thermodynamic properties, and
of the bibliography, were prepared from the output file (tape) of the
FORTRAN IV program, using the WYLBUR text editor and the extended print facility at the Computer Center of the National Institutes of
Health.
Several of the tables in the second section are incomplete because of the
lack of adequate data on the enthalpies of formation or entropies at 298.15
K of these substances. The tables are nonetheless included, so that when
such data become available, one may readily calculate the remaining
functions using equations 2, 3, and 4 given above, or use equilibrium data
and the third-law method to obtain the standard state enthalpy or Gibbs
free energy change for the reaction (AH~, or AG~), following the procedures illustrated, for example, by Robie (1965).
0
THEBIIOD!IlftiC PIIOPIITIIS or ftUIULS
12
Jae and forula
rorla
veigllt
Entliopy
s 298
ftolar
Yolua
611;. 298
aGf, 298
Log Kf
References
as:
---------------------------------------~-----~~~~:~----~~~------~~~~~-----~~~~:------------~--~:!__
ELEI!EITS
S1LYIR ( RIPIIIIICI STATE)

Ag
107.868
112.55
o. 21
aq
AQUEOUS 101
STD. ST&TI,
1
107. 8&8
73.38
0.110
lLUft1111ll! ( IIIPIIIICI STATE)
26.982
ll
28.35
o. 08
Al +++
AQUEOUS 101
STD. STATE, = 1
26.982 -3118.00
15.00
&IGOJ ( RIPIIIIJCI STATE)

Ar
( IDI&L G&S)
39.9118
AISIIIC (IIPIIIICI ST&TI)

As
711.922
15.69
0.811
196.96&
GOLD (RIFIIIICI STATE)

Au
BOBOI (IIPBRIICE ST&TB)
85
0 107
9.999
0.001
-5310011
11000
-11891100
11100
85.7111
o. 2115
911
107
911
117.119
0.21
10.215
0.002
0 107
107
10.810
5.90
0.08
II. 186
0.007
ll 107
107
137.3110
&2.112
0.811
0 107
107
137.3110
38.21
0.02
-5376110
120
9.611
o. 85
9.511
O. DB
8 i +++
AQUEOUS 101
STD. 51' ATE, = 1
208.980
BIOIIIME ( IIBFEBEMCE STAT!)

Br 2
(LIQUID)
159.8011
152.32
o. 011
BROIIIME (IDEAL GAS)

Br 2
159.808
2115.116 211789.2
0.05
3.'1
BrAQUEOUS 1011
STD. STATE, = 1
79.9011
CARBOM ( REFEBEICE STATE)
12.011
c
12.011
5.H8
0.001
2.38
3.1117
0.001
C&LCIUI! ( BEPBIEICE STATE)

Ca
110.080
111.61
o. 112
ca++
AQUEOUS 101
STD. STATE, = 1
110. 080
- 5l.l0
2.00
CADII1011 ( IIFEBBICE Sl'&l'B)

Cd
112.1100
51.80
Cd++
AQUEOUS 101
STD. Sl'&l'l, = 1
112.110(1
-73.211
o. 85
CEliO II ( BIPEIEICE ST&l'll)

ce
1110. 120
69.116
1!.37
ce
AQUEOUS 101
STD. STATE,
1
1Q0.1211 -2115.1111
ce++
AQUEOUS 101
STD. STATE,
1
1110.120 -301.011
o. 17
10.906
ClAQUEOUS 101
STD. STATE,
1
15. 1151
107
-0.550
0.053
J5
JS 1U7
121500
150
-1011010
170
1ti.U~
J5
35
1895
112
HOO
811
-553511(1
1.200
U.OJII
0 107
107
-0.50d 107
0.015
87 107
0 107
107
96.978 2111 2111

0.021
107
0 107
tJ.005
O.OOJ
-7591111
120
-175811
120
13.59.! 2&2 262

0.021 .
107
0 107
20.71
0.02
-691>21111
850
-&7201111
850
117.732 262 262

0.1119
-537 2110
850
-50381111
850
88.2611 2&2 2&2

0.1119
107
0 107
223.08 211789.2
0.011
3.11
56.71
o. 16
-111.511&
0.1119
31110
)00
-51128311
1200
s.oo
7f>
30910
200
26.19
0.011
s.oo
&1>.522 2111 2111

0.1119
0 107
511.58
0.20
5. 711
0.01
107
0 107
828110
1150
o.o 1
CHLOBIIB ( RBPEBBICE Sl'il'IJ

Cl 2
(IDEAL GAS)
-37971111
850
21.309
0.011
82.811
o. 20
98.2110 :l111 2111

0.021
0 107
-381000
1!50
208.980
5&.711
o. 112
-5&117110
120
11.880
0.002
BISIIUTH (RIPER liCE STATE)

Bi
35
107
9.(112 -130.0(1
0.85
35
0 107
AQUEOUS 101
STD. STATE, = 1
-13.51111
0.0111
12.961
0.015
9.012
DI&IIOID
711177
10D
1511.811 211789.2
0.02
3.11
BER'ILLIUII ( B!FBRBICE STATE)

Be
Be++
1osno
107
107
Ba
Ba ++
AQU IOUS 101
STD. STATE, = 1
0 107
0 107
B&IIIUft ( BBPBRIICE STAtE)
10.272
0.002
-1&7U80
88
-131270
110
22.999
0.019
35
35
PROPERTIES AT 298.15
For~ula
lae and forula
we1.ght
Eot~OpJ
s 298
1J
J(
llolar
Yolue
.e.H;_ 298
AG~. 298
Log Itt
References
.e.H:
-------------------------------------- ~---- _:~~~= ~----~~: __ --__:~~:--___ :~~~~------ ---- ---~--~:! __ : f

ELEJIEHTS
101
58. 9 33
co
AQUEOUS IOJ
STD. ST&TI!! 0 = 1
58. 9Jl -113. (I (I

5.00
-582(1(1
500
-54400
500
9.531 263 263

0.088
co
AQUEOUS 101
STD. ST&T! 0
1
58.933 -lOS. CICI
92011(1
5000
13110011
5000
-21.1176 263 2&J

0.876
CHROIIIUII ( BEFEB!JCI!! STATE)

cr
51.996
Cr + +
AQUEOUS 1 ON
STD. STATI!! 0 = 1
51.996
30. 04
0.112
0 107
COBALT ( BEFEREIC! STATE)

Co
s.oo
23.611
o. 21
132.905
85.23
o. 40
cs
lQU!OOS ION
STD. ST&T 0 = 1
132.9115
132.84
o. 40
63.546
ll.15
o.o8
162.500
74.89
o. 84
EBBIUII (REFERENCE STATE)

Er
167. 260
73. 18
o. 15
EUROPIUII (REFERENCE STATE)

Eu
151.960
80.79
o. 16
FLDORUE ( BEFEREMCE STATE)

P2
(IDEAL GAS)
37.997
202.79 24789.2
0.04
3.4
FAQUEOUS IOM
STD. STATE 0 = 1
18.998
-11.18
o. 54
IRON (REFERENCE STATE)

Fe
55.847
27.28
o. 1 l
DYSPROSIUII ( BEPER!HCI! STATE)

Dy
AQUEOUS I UN
-283625
150
49.6911
0.026
35
35
107
0 107
1.113
0.003
-99.6(1
0. 42
107
0 107
-.<581140
130
63.546
107
263
69.73
0.10
Cu +
AQUEOUS ION
STD. STATE 0 = 1
cu
AQUEOUS ION
STD. STAT 0 = 1
0 107
7.231
0.001
-1411(10(1
1000
C!SIUJI ( RBFEREJC! STAT!)

cs
COPPER ( BEFEBI!JCE STATE)

cu
6.670
0.002
71670
100
5011011
100
-8.7611 2tll 263

0.01!1
64170
100
&55211
100
-11.1179 261 :.!63

0.018
19.01
0.02
28.97
0.02
-HSJSO
650
-2817115
670
1.on
0 107
107
0 107
107
0 107
107
0 107
107
49.354
0.117
35
35
107
0 101
0.004
55.847 -138.00
o. 85
-891011
1000
-781no
1000
13.11111 261 2&3

0.021
Fe +
AQUEOUS ION
STD. STATE 0 = 1
55.847 -316.(1(1
o. 85
-485ov
1000
-111>0(1
1000
t.o.8116 .l6J 26J

0.021
GlLLIUII ( BEFEIEICE STATE)
69.720
40.83
o. 21
11.79
0.01
0 107
101
157.250
68.45
1.15
19.89
0.02
0 107
107
72.590
31.09
o. 21
11.63
0.005
u 107
107
0 107
107
Fe++
STD. STATE 0
Ga
G&DOLIIIU II ( BEPEIEICE STAT E)

Gd
GERII&MIUII ( REPER!MCE STU!)

Ge
HYDROGEl ( BEFEREICI! STATE)
Hz
(IDEAL GAS)
2.016
H+
AQUEOUS 1011
STD. ST&TE 0 = 1
1.008
HEUUII ( BEFEREIC STArE)

He
( lDE&L G&S)
4.00]
130.68 247119.2
0.04
1.4
126. 15 247119.2
o.o 1
J. 4
35
35
0 107
107
H&PIIUII ( REPEREICE STATE)

Hf
178.490
43.56
o. 21
1J.479
0.1110
0 107
107
IIEBCURT (BEFEREICE ST&TE)

(LIQUID)
200. 590
75.90
o. 08
111. 8l2
0.002
0 107
107
200.5911
-32.Ci0
o. 85
171000
850
16411110
120
-28.80 2 :.!63 21> l

0.021
401.18(1
84.511
o. tiS
112(1(,0
850
153611(1
120
-26.910 263 26]

0.021
Hg
Hg
STD. ST&r 0
Hg 2 + +
STD. STAT 0
lQUEOOS 101
= 1
AQU BOOS I 011
= 1
14
THERIIODYNAIIIC PROPERTIES OF KIN!RALS
Forula
we1ght
Nae and for1ula
Ent~opy
s 298
llolar
volu1e
aH;, 298
AGL 2 ~ij
Log Kf
Refereoces
t.H:
---------------------------------- -----~-----~:~~~:~----~~~- ---- -~:~~:___ --~:~~: _____ ----- ---~--~ :!__ :!:
ELEIIENTS
HOLIIIUII (REFERENCE STATE)
Ho
164.930
75.02
1. ~7
18.74
0.01
0 107
107
IODINE ( RUERENCE STATE)
253.809
116.15
o. 08
51.29
0.06
0 107
107
253.809
2H.~8
126.905
106.70
o. 20
r,
IODINE
1 2 (IDEAL GAS)
STD.
AQUEOUS ION
STATE, = 1
INDIUII (REFERENCE STATE)
POTASSIUM ( PEFERENCE STATE)
AQUEOUS ION
STATE, 1 = 1
KRYPTON (REFERENCE STATE)

Kr
(IDEAL GAS)
62420
80
19129
80
- l.38b
0.001
32
32 107
5~900
-51915
860
9.096
0.151
35
35
840
57.84
o. 84
15.753
0.005
0 107
107
192. 220
35.48
o. 17
8. 519
0.005
0 107
107
39.098
64.68
o. 20
0 107
107
)9.~98
101.04
o. 25
83.800
164.08 24789.2
o. 02
3. 4
K+
STD.
24789.2
3. 4
114.820
In
IRIDIUII (REFERENCE STATE)
Ir
o. 06
45.36
0.09
-252170
100
-2112490
120
49.492
0.021
35
35
0 107
107
138.906
56.90
2. 51
22.47
0.01
0 107
107
LITHIUM (REFERENCE STATE)

Li
6.940
29.12
o. 02
13.011
0.01)7
0 107
107
AQUEOUS ION
STATE, m
1
6.941
11.30
o. 35
174.970
50.96
o. 84
17.17
0.01
\) 107
107
IIAGNESIUII (REFERENCE STATE)

llg
24. lOS
32.68
13.996
o. 007
0 107
107
llg++
AQUEOUS ION
STD. STATE, a = 1
24.305-138.011
4.20
!!ANGANESE (REFERENCE STATE)

lin
54.938
lin
AQUEOUS ION
STD. STATE, m
1
54.9)8
-13.60
o. 85
IIOLYB!l!NUII (REFERENCE STATE)

llo
95.940
28.66
o. 21
NITROGEN (REFERENCE STATE)

N2
( I DEAL GAS)
28.013
191.~1
SODIUII (REFERENCE STATE)

Na
22.990
51.30
o. 02
N a+
22.990
58.111
o. 20
92.906
36.40
o. 42
10.828
71.09
4. 18
20.57
0.01
LANTHANUK (REFERENCE STATE)

La
Li+
STD.
LUTETIUII ( BEFEUNCE STATE)

Lu
STD.
AQUEOUS
STATE,
ION
o.
N!ODYKIUII (REFERENCE STATE)

Nd
12.01
o. 08
o. 02
MIOBlUII (REFERENCE STATE)

Nb
1]
144.240
NEON ( REFBRUCE STATE)

Ne
(IDEAL GAS)
20. 179
NICKEL ( REPEBEICE STATE)

Ni
58. 700
Mi++
58. 1011 - 12 9. 00
o. 85
STD.
AQUEOUS ION
STATE, 1
= 1
-4!>6850
840
-2921>211
110
-454ij(lll
1670
1. 354
29. 87
o. 08
31.999
OSIIIUII ( BEPI!RI!NCE STATE)

Os
190.200
32.64
0.06
30.974
22.85
o. 08
51.267
0.019
35
35
79.679 214 214

0.149
0 107
107
0.007
-2207(10
120
-22811110
850
9. 387
o. 005
24789.2
3. 4
23.812
o. 010
-2403110
65
-261900
85
39.945 2b3 263

0.149
0 107
107
0 107
107
0 107
107
45.884
0.015
35
35
0 107
107
0 107
107
0 107
107
0 107
107
o.oos
1116.32 24789.2
0.02
3.4
OXYGEN ( B!PER!ICE STAT!)

02
(I DElL GAS)
PHOSPHORUS ( REP!REIC STATE)

p
-278455
90
6.588
0.003
-541100
850
205.15 24789.2
0.04
3.4
8.423
0.005
17.2
0.3
-456011
850
1. 989 263 263
0.1119
JS
107
0 107
107
0 107
107
15
PIOPBIITIBS AT 298. 15 II
Por~11la
llaae and fora11la
ve19bt
llltiopy
s 298
Bolu
oluae
aaf, 298
aG!, 298
LOCJ Kf
References
aH:
0
---------------------------------------~----=~~~=~----~~: ______ ::~:-----=~~~~-------------~--~=!
__:!
ELEIIII'l'S
0 107
207.200
65.06
o. 42
Pb++
AQUEOUS 101
STD. STAT!, a c 1
207.200
10. (/(/
0.85
PALLADIUII ( UUB!IC! STATE)

Pd
106.1100
37. 82
o. 21
PRAS IODfiiiUII ( II!PEREICE STATE)

Pr
1110. 908
73.9 3
II. 18
PLATUUB ( BEF!BEIC! STATE)

Pt
195.090
41.63
o. 21
PLUTOKIUII ( IEP!BIICE STATE)

Pll
21111.002
51. 46
8.37
12.011
0.01
IUBIDIUII ( IIPI!IIIC! STAT!)

Rb
85.1168
76.78
0.30
55.85
o. 10
Rb +
AQUEOUS ION
STD. ST lTI, a 1
85.1168
1211.46
o. 40
186.207
36.53
o. 38
8.860
0.004
0 107
107
RHODIUII ( REPIRERCJ STATE)

Rb
102.906
31.511
o. 21
11.2112
0.002
0 107
107
RADOI ( IEF!BEICE STAT!)

Rn
(IDEAL GAS)
222.000
0 107
107
RUTHEUU II ( R!P!IBICE STATE)
101.070
28.53
o. 21
11.171
o. 0011
0 107
107
32.060
31. 80
o. 21
15.511
0.005
0 107
107
s-AQUEOUS 101
STD. STAT!, a
1
32.060
-15.00
o. 85
DUTOIIIC SULPU B
( lDI&L GlS)
611.120
OCTA-ATOIIIC SULFUR
(ID!&L GAS)
256. 1180
AIITIIIOif ( IIPEBI!IIC! STATE)
121.750
45.52
o. 21
411.956
78.960
IBEJIU II ( RBPIREIC! ST\TE)
Re
811
SULFUR ( UPI!UICE STAT!)
S1
s.
Sb
SCUDIOII ( BEPEBEICE STATE)
sc
S ELEIIIU II ( BI!PEBEIIC! STATE)
Se
18.267
0.006
107
LUD ( BEPBI!ICI STATE)

Pb
-1700
850
-211110(1
120
8.862
0.005
20.110
0.01
9.091
0.0011
4. 275
0.021
26~
~62
0 107
107
0 107
107
0 107
107
107
0 107
-251120
110
-291715
no
176.23 24789.2
o. 00
3. 3
51.108
o.o26
35
107
35
lliiOU
850
8581111
850
-15.0 32 262 262

0.149
228.17 24789.2
o.os
3.11
1281190
500
791153
669
-13.920 107
0.117
430. 32 211789.2
1. 67
l.4
101250
630
118835
9l0
-a. 556
107
1 01
107
18.178
o. 009
0 107
107
311.611
o. 21
15.038
0.008
0 107
107
112. 27
o. 05
16.112
0.007
129000
850
0.161
75
JO
-22.600
0.1119
Se
AQUEOUS IOI
STD. STAT 1 1 a 1
78.960
SILICOI ( IEriiEICE STATE)

Si
28.086
18. 81
o. 08
12.056
0.002
0 107
107
150.1100
69.50
2. 09
19.98
0.03
0 107
107
118. 690
51. 20
o. 112
16.289
0.005
0 107
107
87.620
55.o
0.17
ll.921
0.020
87.620
-lJ.OO
o.85
TliT&LUB ( IIPIIIICI STATE)

Ta
180.9118
"1. 51
o. 17
10.851
0.005
0 107
107
TIIBIUII (IIPIIIICI S'l'&TI)

Tb
158.925
73.30
0.811
19.29
0.03
0 107
107
TILLUIIUII (IIPII!ICI STlTI)

Te
127.600
.,.so
0.112
20.476
0.008
0 107
107
S lii&BIUII ( IIPIIEICI STATE)

Sa
Til ( IIPIIIICI STl1'1)
sn
STIOil'IUII ( BIPIIIICE STAT!)
sr
SrH
lQUIOUS IOI
STD. STATI 1 a 1
l62
107
-54580(1
120
-5591111(1
120
98.012 2111 2111

0.021
16
THERIIODYIIUIC. PROPERTIES OP IIIIIULS
For~ul a
Maae and foraula
we1gbt
En t~opf
s 298
llolar
voluae
6H;, 298
ali~, 2911
Log Kf
References
ad:
---------------------------------- -----~-----~:~~~: ~----=~: __ --- _::~~:--- __ ::~~:__ --------- --~-- ~ :!_ -~~
ELEIIEITS
THORIUII ( BEPERENCE STATE)

Th
232. 0)8
51.19
0.84
19.788
0.010
0 107
107
47.900
30.61
o. 08
10.631
0.010
0 107
107
THALLIUII (REFERENCE STATE)

Tl
2011.370
64. 18
o. 21
17.21
0.02
II 107
107
THULIUII (REFERENCE STATE)

Ta
168.934
711.01
o. 00
18.126
0.005
0 107
107
UBANIUII ( REFEREIICE STATE)
238.029
50.29
o. 13
12.1197
0.020
0 107
107
TITUIOII ( RI!FERBIICE STATE)
Ti
u
u+++
AQUEOUS ION
STD. STATE,fa = 1
238.029 -126.1111
1.00
-5111&110
200
-52051111
200
91.190
0.035
911
911
u++++
238.029 -32&.00
1.00
-& 13800
200
-579100
200
111 1. liSt>
0.035
911
94
AQUEOUS lOll
STD. STATE, a = 1
VAIIlDIUII ( BI!FEREMC! STATE)
50.9111
v
TUNGSTEN (REFERENCE STATE)
181.850
w
XENON (REFERENCE STATE)
Ie
(IDEAL GAS)
131.300
28.91
0.112
a. 1so
32.64
0.42
9.5115
0.0011
0 107
107
0 107
107
0 107
107
0.004
169.68 24789.2
0.02
1."
8~.906
44.4)
o. 25
15.018
0.007
0 107
107
173.0110
59.83
0.17
211.83
0.01
0 107
107
ZIIC ( BI!FEREHC E STATE)

Zn
65.380
111.63
0 107
107
Zn ++
AQU IOUS lOR
STD. STArE, a = 1
65. 380 -1 09. bll

o. 70
ZIRCONIU II ( BEFEBEMCE STATE)
91.220
YTTRIUII (REFERENCE STATE)

y
JTTERBIUII (REFERENCE STATE)

Yb
Zr
16.043
IIETHAME (IDEAL GAS)

CH
179.552
COHENITE
Fe,c
All !IONIA (IDEAL GAS)
o. 1)
38.99
0.17
9.162
0.007
-15H911
200
~5.8011
220
0.019
111.016
0.007
186.26 211789.2
o. 21
1.11
1011.43
3. 35
-1117~&11
2).2)
0.01
107
-74810
)35
-507011
177
8.8811 262 262 247

0.06&
24937
19912
1715
-3.1189 108 lOll 115
-16410
350
.1.1175 247 215 21t7

0.061 215
II .660 262 262
1339
192.78 211789.2
0.08
3.11
IH
ON-IONIZED
STD. STATE, a = 1
17.031
111.00
o. 85
-80290
120
-26600
120
N H4 +
AQUEOUS IOM
STD. STATE, a = 1
18.039
111.17
o. 75
-13321>11
:.!50
-791157
301
SULFIDES,
JS
0 107
17.030
""
35
O.JOU
0.0~1
1J.9~1
JS
35
1J 115
0.051
ARSEUDES, TELLURIDES, SELEIIDIS, UD SDLFOSALTS
ACAITHITE (ARGENTITE)
AgzS
2117.796
1112.811
0.112
111.19
0.011
-123116
879
-110080
817
7.022
0.1117
80
REALGAR
AsS
106.982
63.51
0.63
29.8
0.24
-713110
2090
-70120
2100
1..!.120
0.1611
~74
OBPIREMT
As 2 SJ
2116.021
163.60
0.110
70.51
0.25
-16~030
-1681110
11220
~~-505
4200
262 262
230
BISIIUTHI NIT E
514. 1111
200.110
1.10
75.52
0.011
-1111090
1050
-1110560
1070
211.626 210 262

0.187 262
72.1110
56.65
1. 25
27.72
0.09
-1174880
2100
-1169850
2100
112.116 120
0.1611 l l
l:l
1114.1160
70.29
1.67
29.9111
0.015
-149600
1255
-1115610
1381
25.514 120
0.2112
2
65
Bi 2 S 3
OLDHAIIIT E
cas
GREEIOCXIT E
CdS
o. 719
2&2
12
17
PBOPBRT:U!S AT 298.15 K
l'or~ula
lae and forula
ve1.ght
_______________________________________:_____
Ent~opy
llolar
s 298 voluae
~~~~~:~----~~:
aa'f, 298
aG;, 298
Log Kt
References
au:
______:~~~~-----~~~~~------------~--~~~--=~
SllLFIDES, ABSEIIIDES, TELLllRIDES, SBLEIIIDES, .I.BD SllLFOSALTS
COYBLLITE
20.42
0.02
-48575
4184
-49080
4226
27.475
0.016
-80115
1255
-86868
1423
8.599 120 65
o. 740
114
95.606
66.65
1.67
CHALCOCITE
Cu 2 S
159.152
120.75
2.09
C HlLCOPYBIT E
183.513
209
501.817
209
cus
15.219 120 26 115

0.249 266 219
cures,.
BORIIITB
Cu 5 FeS 0
87. 907
60. 33
o. 17
18.2
0.03
81.038
60.79
o. 21
17.58
o. 03
PYRITE
FeS 2
119.967
52.93
o. 13
23.94
0.007
-171544
1674
-160229
1715
28.072
0.300
80 255
39
lllRClSITE
l'eS 2
119.967
53.89
0.11
24.58
0.02
-169450
2090
-158421
2090
27.755
0.366
81
81
1'BRBOSELITE
FeSe 2
213.767
86.86
o. 25
29.96
0.05
80
l'BOHBEBGITE
FeTe 2
311.047
100.20
o. 20
38.43
0.05
280
TBOILITE
PeS
BJDBOGBB SDLl'lDE (IDEAL GAS)
H.076
B2 S
BSlQOEOllS IOI
STD. STATE, a = 1
205.80 24789.2
o. 21
3.4
-100960
1464
-101333
1506
17.753
0.264
82 220
2
39
82
81
-20627
628
-33543
669
5.877 262 262 247

0.117
-16999
850
12100
850
-2. 1211 262 262

0.149
33.070
62.80
0.85
CllllBlB
BqS
232.650
82.51
2. 09
28.416
0.015
-58155
2092
-50645
2218
8.873 137 114

0.389
65
IIET&CIJIRABAR
BqS
232.650
96.23
4.18
30.169
0.016
-46735
1506
-43315
837
7.589 120
0.147
72
86.998
78.20
1. 67
21.46
0.01
-213865
837
-218155
1004
38.220 120
0.176
2
49
39
BAll BRITE
IIDSz
119.058
99.91
o. 10
3<1.20
0.01
IIOLJBDEIIITB
lloS 2
160.060
62.57
o. 21
32.02
0.02
-275300
5000
-266454
5000
46.682 165 286

0.880
61
90. 760
66. 11
4.18
16.89
0.01
-84868
4184
-86192
4393
15.101 80 231 115

0.770 274
BBAZLBIOODITB
li 3 S 2
240.220
133.90
o. 90
40.95
0.02
-202920
1000
-197070
1020
GALE Ill
PbS
239. 260
91. 38
1. 25
31.49
0.01
-91709
962
-96075
837
CLlllST BALIT B
PbSe
286. 160
102.51
2.09
34.61
0.01
-102925
2218
-101577
2092
17.796 120 262

0.367
ALT&ITB
PbTe
334.800
110.04
2. 09
40.60
0.01
-70710
1425
-69360
1255
12.152 120 262

0.220
COOPBBITB
PtS
227.150
55.06
0.13
22.15
o. 01
-82425
3350
-76948
3390
13.481
0.594
339. 680
182.00
3. 30
73.41
0.04
-174890
4180
-173470
4200
30.391 138 262

0.736
150.750
76.82
o. 84
29.01
0.02
-106541
1464
-104698
1506
18.343 120 220 192

0.264
182.810
87.45
o. 18
40.96
0.02
247.970
94.98
8. 37
32.07
0.02
-298320
840
-297945
2680
52.199
0.469
97. 440
58. 66
0.84
23.83
0.01
-206900
1700
-202496
1780
35.476 248 217 208

0.312
262
ALABlliDlTE
liDS
IIILLEBITB
II iS
BBllZ BliBBBGirB
sns
STAIIIIC SllL1'IDB
sns,.
TOIGSTBIIIT B
IIS 2
SPBALBBUB
zns
282
34.526 274 262

0.179
16.832 120 245 115
0.147
144
80
80
120
80
192
65
18
THERIIODYHAIIIC PROPEBTIES OF IIIIIBBlLS
For~ula
!lame and foraula
veJ.ght
Ent~opy
s 298
llolar
volue
aH,~, 298
AG~, 298
Log Kf
References
as:
---------------------------------------~-----:~~~~:~----~~~------:~~~~-----~~~~-------------~--~=!__ ~!'
SULFIDES, ARSI!UDES, TELLURIDES, SELEIIIDES, AID SULFOSALTS
WURTZITE
97. 440
zns
58.84
0.12
23.846
o. ou
-194570
1520
-190220
1520
33.326 248 215 208

0.266
2
-1675700
1300
-1582228
1320
277.201
0.231
50 35 285
66 159 50
-165J511
1260
-1562702
1300
27J.780
0.228
32
OXIDES AIID HYDROXIDES
CORUIIDU II
25.575
o. 001
101.962
50.92
o. 10
101.962
59. OJ
6. 28
BOEHIIITE
AlO( OH)
59.989
48. 45
o. 21
19.535
0.026
-993054
2110
-918400
2090
160.900 120 94 115

0.366
216
DIASPORE
AlO( OH)
59. 989
J5. 27
o. 17
17.76
0.026
-1000585
5000
-922000
5000
161.5JO 120 94
0.51J 1J5 216
GIBBSITE
Al(OHJ.
78.004
68. 44
o. 14
31.956
0.015
-129J128
1192
-1154889
1213
202.333
0.213
95
197.841
107.41
0.13
51.118
o. 069
-656970
1674
-575964
1883
100.907
0.330
29 262
197.841
113. JJ
o. 1J
47.26
O.OJ
-654795
1715
-575554
1046
100.8J5
0.183
29 262
69.618
53.97
o. OJ
27.22
o. 06
-1273500
1400
-1194J25
1715
15J. JJ9
72.07
o. J8
25.59
0.01
-548100
2090
-520394
2100
BRO!!ELLITE
BeO
25.012
13.77
o. 04
8.309
0.03
-609400
2500
-580078
2500
101.628 215 215 32

0.43 8
261
BERYLLIUII OXIDE (BETA)

Beo
25.012
16.54
O.OJ
-601785
JSOO
-573289
3500
100.438
0.613
465. 959
151. 46
2. 09
-57J877
1255
-49J453
1464
86.451 262 262 115

0.256
161
u.o.
ALUIIJNUII OXIDE ( GAJIBA)
11 2 0 3
CLAUDETITE
As 2 o,
BORIC OXIDE
Bzo.
BARIUII OXIDE
sao
49. 7J
0.06
209.242 J5
0.300 262
91.111
0.368
33
32
32
93
32
95
35 247
J3 33
58 155
J2
32
CARBON ~ONOIIDE
CO (IDEAL GAS)
28.010
197.67 24789.2
0. OJ
J.4
-110530
170
-137171
170
24.032 215 215 247

0.030
CARBON DIOXIDE
C0 2 (IDEAL GAS )
44.010
213.79 24789.2
0.04
3.4
-39J510
130
-J94J75
167
69.093 215 215 247

0.029 96
C0 3 ;
AQUEOUS ION
STD. STATE, 11 ; 1
60.009
-56.90
0.85
-677140
120
-527900
120
92.486 262 262

0.021
HCO ~AQUEOUS I Oil

STD. STATE, 11 ; 1
61.011
91.20
0.85
-691990
120
-586850
120
102.814 262 262

0.021
H2 C0 3
UN-IOIIIZED
STD. STATE, 11 = 1
62.025
187.00
o. 85
-699650
120
-623170
120
109.117 .262 262

0.021
CALCIUII OXIDE
56.079
38. 21
o. 1J
16.764
o. 005
-635089
879
-60J487
900
105.729
0.158
J3
3J
J3
PORTLANDITE
Ca( OH) 2
74.095
OJ. J9
o. 42
JJ.056
o. 016
-986085
1255
-898408
1300
157.398
0.228
J2
86
32
86
32
IIOIITEPOIIIT.E
CdO
128. J99
54.81
1. 25
15.585
0.010
-258200
837
-228515
920
CERIANlTE
Ceo 2
17 2. 119
6 2. JO
o. 08
23.853
o. 026
-1088680
1464
-1025380
2929
179.643 279 235 130

0.513
8
CEBIUII SESQUIOXIDE ( HEXAGOIIAL, 11)
J28. 238
150.62
4.18
47.75
0.05
-1196200
8400
-1707940
81100
299.225 113 235 202

1.1172
105
cao
ce 2 o 3
CERIUII SESQUIOXIDI! (HEIAGOIIAL, II)
Ce 2 0 3
COBALTOUS OIIDE
coo
ESKOL.UTE
40.035 120 262

0.161
158
J28. 2J8
202
74. 93J
52.97
o. 34
11.64
0.02
151.990
81.17
1. 25
29.09
o. 032
-2J7940
1255
-21111911
1297
-11311700
8370
-1053056
8400
37.526 120 263 129

0.227
184.492
1.1172
3J
J3
158
33
19
PROPIBTIES AT 298.15 K
ror~ula
laae and foraula
veLght
Entfi"PY
s 298
llolar
Yoluae
"!, 298
6G~, 298
Log Kt
Referegces
6H
______________ ---------------__________:_____:~~~~: ~----~~:- _____ :~ ~~ ~ ____ .:~~~~---- ______ ---~- _~=E- -~ E

0
OIIDES AND HYDROXIDES
DICESIUII 110101 IDE

Cs 2 0
281.810
1116.87
0.1111
CESIUII H!DBOI IDE

CsOH
1119.91J
98.74
4. 18
-3115975
1170
-308360
1190
SII.OB
0.208
59 236
59
-4167.!6
837
-370690
850
64.91111
o. 149
3.!
32
79.545
42.63
o. 21
12.22
o. 0 l
-157320
1255
-1295611
1297
22.699 120 261 164

0.227
1611
CUPRITE
Cu 2 0
143.091
93.111
1.67
21.1137
0.016
-168610
6276
-1116030
6318
25.584 263 263 H4

1.107
164
DYSPROSIOII SISQUIOXlDE (CUBIC)
372.998
1119.79
o.a5
45.683
0.010
-1863130
3930
-1771385
11000
J10.341 235 2J5 20.l

0.701
.101
382.518
155.64
0.85
44.171
0.010
-1897860
1920
-1808879
2000
316.909 235 235 207

0.350
EUROPIOII OIIDE
EuO
167.959
62.76
20.1175
0.008
-592040
8370
-556082
6370
97.1124 235 235 166

1.1166
EUROPIOII S ESQUIOIIDE ( IIOWOCLIMIC)

Eu 2 0,
351.918
-1651420
8400
-1555158
8400
27.2.1158 281 :.!35 210

1.1172
57
EOROPIUII SISQUIOIIDE (CUBIC)

Eu 2 0,
]51. 918
TEIORITE
cuo
Dy 2 o,
J!RBIUII SESQUIOXIDE (CUBIC)
Er,o,
o.a5
liUSTITE
a. so
57.59
o. 42
12.011
0.04
-266270
837
-2115155
879
11.!.950 120 109

0.154 247 2117
71.8116
59.80
1. 67
12.00
0.05
-272043
2092
-251156
2176
114.001 247 247 247

0.381
159.692
87.40
o. 21
JO. 274
0.012
-82116110
1255
-711~683
1116.111
44.524
0.008
-1115726
2092
-1012566
21311
-559330
730
-488550
750
0.112
GALLIUII SJ!SQUIOIID!
116
1!11
44
78
79
84
247
1111
79
85.591139
1J
177.398
0.374
20.82
o. 04
187.1138
811.98
211.941
0.006
-1089100
850
-998342
1!50
174.906 120 262 203

0.1119
145
43.11
0.011
-1819620
3600
-1732lld
3600
303.500 281 235 210

0.611
GADOLIJIUII SISQUIOIIDE ( IIOIOCLINIC)

Gd 2 o,
362.1198
GADOLIIIUII SESQUIOXlDE (CUBIC)

Gd 2 0,
]62. 1198
GERIIUIUII DIOXIDE (QUARTZ TYPE)
104.589
55.27
0.27
1011.589
611.50
0.10
18.015
69.95
o. 08
Geo,
H2 0
OH
AQUEOUS ION
STD. STATE,
1
17.007
STEll!
H 2 0 (IDEAL GAS)
18.015
HAPIIOI! DIOIIDE
Hf0 2
210. 1189
1101! BOY Dlt II

HqO
BOLIIIUI! SIISQUIOIID! (CUBIC)
Ho 2 0 1
130.267 711
O.l27 2117
60. 38
0.63
0.112
VATER
(LIQUID)
1297
44
88.8511
Ga 2 o,
G ERIIAMIO II DIOI :u>E GLASS

Geo 2
210
48.29
68.887
231.539
GOETHITE
FeO(OH)
411.02
0.05
12
o.o1
f'e. 70
FERROUS OXIDE ( STOICHIOIIETRIC)
FeO
146.411
59.62
o. 07
151.88
O. 85
117.585
0.008
-1
~-
210
-551030
800
-497074
900
1!7.086 1l0 262 119

0.158
83
5
28.6
0.1
-526350
630
-1175180
710
83.250
0.124
18.069
0.003
-285830
42
-237141
84
111.546
0.015
35
35 2117
191>
-230025
liS
-157328
90
27.51>3
0.016
35
35
-241814
42
-228569
811
110.0411
0.015
35
-114117110
1255
-1088276
1297
190.662 120 2611 188
71
o. 20
188.72 211789.2
0.011
3.11
163 119
35 247
196
59.33
0.112
20.823
216.589
70.27
0.]11
19.12
0.02
-90789
50
-58528
60
10.2511 2117 2117 2117

0.011
251!
377.859
158. 16
o. 32
114.90
o. 02
-1880700
11850
-1791373
5000
313.8112 235 235 207

0.876
DIPOUSSIUII IIOIOIIDE
120
911. 195
911. 1Q
6. 28
110.38
o. 20
-161171
2092
-322087
28115
56.1129 2167 2117 2167

0.498
POUSSIOII SOPIIOIIDE
KOz
71.097
122.50
II. 18
32.811
-2811512
2092
-240586
2800
112.150
0.1191
12
32
32
o.oli
POT .lSS IU I
KOH
56. 105
78.91
0.811
27.115
0.02
-11211676
418
-378932
500
66.188
0.088
32
32
12
HJ DIOX IDII
o.ooa
0.221
20
TREBIIODYiiAKIC PROPERTIES OF IIIJIEBALS
For~ula
Naae and formula
ve1ght
Ent~opy
s 298
llolar
volue
t.H~, 29 R
t.G;, 298
Log Kf
References
t.H:
--------------------- ------------------~-----~:~~::~----~~~------::~:-- ---~~~:-------------~--~:~__:f

LANTHANUII SESQUIOIIDE
La 2 0 3
DILITHIU II !IOIIOXIDE
Li 2 0
325. 809
127. 32
0.84
49.56
0.02
-1793680
1590
-1705963
1600
298.879 235 235 142

0.280
29.879
37. 57
0.08
111.76
0.01
-598730
2092
-561985
2134
98.458 247 247 247

0.374
16.44
o. 05
-484926
159
-438941
159
76.901 215 215

0.028
42.22
0.01
-1878200
7530
-1788849
6280
313.400 281 235 202

1.100
LIT HIUII HI DROI IDE

LiOH
LUTETIU!I SESQUIOIIDE (CUBIC)
Lu 2 0 3
32
397.938
109.96
o. 85
PEBICLAS E
II gO
40.304
26.94
0.17
11.248
o. 004
-601490
290
-569196
300
99.721 215 215 261

0.053
24'1- 2~!1
BRUCITE
llq( OR) 2
58.320
63. 18
o. 13
24.63
o. 07
-924540
440
-833506
440
146.027 214 214 131

0.077
102
IIAIIGANOSITE
KnO
70.937
59.71
o. 42
13.221
o. 004
-385220
460
-362896
502
63.578 120 263 242

0.088
PYROWSITE
86.937
53. 05
o. 42
16.61
o. 02
-520030
837
-465138
879
81.491 120 263 168

0.154
157.874
110.46
2.09
31.37
0.05
-958970
2092
-881068
2218
154.360 120 263 115

0.389
197 191
228.612
153.97
~. 18
46.95
0.06
-1387830
1674
-1282774
2092
224.738 197 263 241

0.367
197
IIOLYBDENUII DIOXIDE
llo0 2
127.939
50.02
o. 30
19.58
0.02
-587850
2090
-533053
2510
93.389 247 247 247

0.440
159
IIOLYBDITE
llo0 3
143.938
77.74
0.42
30.56
0.04
-745170
418
-668055
460
117.041 247 247 247

0.081
159 140
33095
418
51251
460
-8.979 247 247 247

0.081
-207400
420
-111500
400
19.534
0.070
lln0 2
BIXBYITE
l!nzOll
NITBOGEII DIOXIDE
110 2 (I DElL GAS)
46.005
240.06 24789.2
0.08
3.4
110 3
AQUEOUS ION
STD. STATE, 11 = 1
62.005
141>.94
o. 85
DISODIU II IIONOXIDE
61.979
75.27
o. 84
25.88
0.08
-414820
280
-376089
290
65.890 247 183 247

0.051
265 63
39.997
64.43
o. 84
18.78
0.06
-425800
85
-379651
125
66.514
0.022
32 215
32
32
NIOBIUII IIOHOXIDE
NbO
108.906
46.02
8. 40
14.97
0.01
-419660
12 550
-391945
12 550
68.667
2.199
33
33
33
HIOBIUII DIOXIDE
Hb0 2
124.905
54.51
o. 30
45.02
0.04
-794960
8370
-739194
8370
129.504
1.466
33
33
33
130
DI HIOBIU II PEIITOXIDE
Nb 2 0 5
265.810
137. 32
1. 26
93.42
0.10
-1899536
4184
-1765859
4200
309.373
0.736
JJ
JJ 189
NEODY!IIUII SESQUIOXIDE ( HEXAGONlL)

Nd 2 0 3
336.478
158.57
4. 20
45.92
o. 02
-1807910
1000
-1721048
1020
301.522 235 l35 210

0.179
BUIISENITE
NiO
74.699
37.99
0.17
10.97
0.02
-239743
418
-211581
460
37.068 120 23 129

0.081
263
PHOSPHORUS IIONOIIDE
PO (IDEAL GAS)
46.973
- 12134
4184
-41157
4200
Ha 2 0
SODIUII HYDROXIDE
RaOH
222.77 24789.2
0.02
3.4
7.211
o. 736
35
32
35
32
32
PROS PHORUS PENTOXIDE

PzOs
141.945
115.50
o. 40
59.4
0.2
-1470000
4200
-1337897
4200
234.396 215 215 24 7

0.736
PHOS PROBUS P ENTOXIDE ( Dill ERIC)

( PzOs lz
283. 889
231.00
0.80
118.8
0.4
-2940000
8400
-2675794
8400
468.791 215 215 247

1 .470
-1259550
850
-1001550
850
175.469 262 21>2

0.149
-1266920
2090
-1112290
2510
194.869
0.440
32
32
32
-1254200
2090
-1111700
2510
194.766
0.44 0
32
32
32
-219409
830
-189202
900
33.148
0.158
32
32
32
P0 4
AQUEOUS IOB
STD. STATE, 11 = 1
94.971 -222.00
4. 20
ORTBOPHOSPHORIC ACID ( CRYSTlL)

H,P0 4
97. 995
1 10.54
o. 42
ORTHOPHOS PHOBIC ACID (LIQUID)
97.995
150.78
4. 20
223. 199
66.32
o. 84
H 3 P0 4
LITHARGE (RED)
PbO
48.52
0.01
23.91
0.05
PROPERTIES AT 298.15 K
lae and forula
Fornla
Ve1gbt
Ent~opy
S298
llolar
21
All~ , 298
aGL 298
Log Kt
References
YOlUU
&H:
---------------------------- -----------~ ---- _:~~~~~~----~~:------=~~~:__ --- =~~~: _____________ ~- -~ :~--~f

0
lllSSICOT ( ti!LLOII )
PbO
223.199
68.70
o. 21
23. 15
0.03
-218070
630
-188573
700
l l ;0]7
0.123
32
32
32
PLATTIIERIT E
Pbo,
239.199
71.80
o. 42
25.01
0.01
-27111170
2929
-215314
3000
37.722
0.526
32
32
32
686.598
211.96
6. 69
76.81
0.09
-718686
6276
-601358
6300
105.356
1.104
32
32
32
329.8111
158.57
II. 20
46.51
0.05
-1809580
6690
-1721025
6700
301.5111 2111 .BS 200

1.114
170.235
79.91
4. 20
24.6
O.l
-1904560
6690
-1796610
6700
314.760 281 281 200

1.174
BHEHIUII DIOXIDE ( ORTHOBHOIIBIC)

Reo,
218.206
117.82
0.05
18.80
0.01
-451870
3l50
-394070
ll60
69.040 249 1]3 249
BHEIIIIJII TRIOXIDE
234.205
69.24
0.09
31.78
o. 01
-593710
2930
-511700
29110
89.646 249 1]] 249

0.515
484.4.10
207.30
o. 40
71.95
0.09
-1.l711030
6280
-1099980
6290
192.713 2119 131 249

1.102
PRlSEODYniiJII SESQIJIOXIDE (HEX)
Pr,o,
PBAS EODtiiiUII OXIDE
Pro 1 3 ~
Reo,
DIRHEIIIDII HEPTOIIDE
Re 2 0 7
0.511~
SULFUR DIOXIDE
S0 2 (IDEAL GAS)
611. 059
248. 22 24789.2
0.06
3.4
-296810
200
-300170
251
52.589
0.044
SULFUR TRIOXIDE
S0 1 (IDEAL GAS)
80.058
256.76 24789.2
0.84
3. 4
-395722
711
-371046
795
65.006 247 247 247

0.139
S0 1
AQUEO OS ION
STD. STATE, = 1
80.058
-29.1111
4. 20
-bl5b(l(l
850
-48f>f>(l(l
850
85.251
0.149
S0 4
AQUEOUS I Oil
STD. STATE, 11 = 1
96.058
20. (I (I
0.85
-909270
120
-7QQb3(1
120
13(1.457 262 2&2

O.Ol1
291.498
123.01
2. 51
50.01
o.os
-708560
2930
-626345
3054
109.733 262
0.535 120
76.99
o. 42
35.91
o. 01
-1906820
2510
-1819371
2520
318.748 281 264 203

0.441
162
- 1.00416
836ij
-127305
8500
22.304 l47 247 2Q 7

1.Qij9
-910700
1000
-ij56288
1100
150.019 35 35 247
0.193 278 284
-1460000
1700
-1308000
1700
YALEIITINITE
sb,o 1
SCANDIUII S ESQUIOXIDE
137.910
sc,o.
35
~62
35 247
21>2
~62
SILICON IIOMOXIDE
SiO (IDEAL GAS)
44.085
QUARTZ
60.085
41.46
o. 20
H 4 Si0 4
UN-IONIZED
STD. STATE, o = 1
96.115
180.00
~. 20
CRISTOBALIT E
sio,
60.085
43.40
0.1 J
25.719
O.OJJ
-90834&
2090
-8511512
2130
149.70<1 247 247 247

0.371 l78
172
TRI DYIIIT E
60.085
43.93
o. 42
26.53
O .lO
-9071188
2385
-85Jll12
21127
149.585 285 h8 172

0.425
COESITE
sio,
60.065
40.38
o. 42
20.641
0.001
-90558~
2092
-8501150
21311
149.066 101 101 285

0.3711
STISHOYITE
60.085
27.78
o. 4 2
14.014
0.009
-861318
2092
-110211.!7
2134
1110.653 101 101 .!85

0.374
60.085
47.40
o. 21
l7.21
o. 10
-903200
- ijS0559 149 .u15 2 ss 1118

2134 27ll0.374 278 2811
151.04
4. 20
45.04
O.Ol
-1822970
2010
sio,
sio 2
SiOz
SILICON DIOXIDE GLASS

Si0 2
SAIIARIUII S ESQUIOXIDE ( IIONOCLINIC)
348.798
SzOJ
SAIIARIUII SESQUIOXIDE (CUBIC)
211.57 24789.2
o. 84
1. 4
348.798
DITAIITALUII PENTOXIDE (BETA)
314.77- 235 .lJ5 210

O.J54
7 193
52.30
1. 25
21.55
0. OJ
-5807110
&28
-519902
753
91.085 120 262 115

0.132
103.619
55.52
o. 42
20.686
0.005
-5901190
920
-560353
98.17.l
0.163
33
~30
-2045976
41114
-1910984
4.!00
JJ4. 7911
o. 7Jb
JJ
sro
Ta 2 0s
-1796690
2020
52
150.689
sno 2
STROIITIUII OXIDE
lO~.l
229.157 262 171

0.298
259
49.10
0.01
s.,o.
CAS SIT ERIT E
22.688
0.001
441. 89]
14]. 11
1. 26
53. 17
0.05
24
33
155
)J
33
189
22
THEBIIODYNAIIIC PROPERTIES OF !liBERALS
For~ula
Name and formula
Ent~opy
ve1.ght
s 298
llolar
volume
411~, 298
6G;, 298
Log Kf
References
6H:
__:f
---------------------------------------~-----::~~:~----:~~------::~~~-----=:~~~-------------:__ ~:!
OXIDES AND HYDROXIDES
-1865230
8370
-1776553
8400
311.2116 281 235 200

1.1172
80.75
II. 20
-953950
11180
-938980
11200
164.506 281 235 200

0.736
187.916
81.17
4. 20
-960230
11180
-942180
11200
165.067 281 235 200

0.736
159.599
79.50
II. 20
27.75
0.02
-322590
850
-270370
850
2611.037
65.23
o. 21
26.373
0.007
-1226410
3510
-1168715
3510
TITANIUII MONOXIDE
TiO
63.899
311.77
2.10
13.00
0.01
-5112660
12550
-513312
12550
89.931
2.199
33
33 176
RUTILE
Ti0 2
79.899
50.29
0.17
18.82
0.008
-91111750
1260
-889446
1030
155.828
0.180
33
33 33
215 176
ANATASE
Ti0 2
79.899
119.91
0.29
20.52
o. 0 3
-938720
2090
-883303
2090
154.752
0.366
33
33 176
DITITANIUII TRIOXIDE
Ti 2 0 3
1113.798
77.25
0.21
31.113
o. 02
-1520884
8368
-11133903
8370
251.215
1.1166
33
33
TRITITANIUI! PENT OXIDE (ALPHA)

Ti 3 0s
223.697
129.37
1.67
52.69
0.03
-21159150
11180
-23171111
11600
1106.003
0.806
33
33 176
TETRATITANIUM HEPTOXIDE
Ti 4 0 7
303.596
198.711
12.00
-31104520
6280
-3213166
6280
562.936
1.100
33
33
THULIUM SESQUIOX IDE
385.867
139.75
0.85
113.42
o.o 1
-1888660
850
-179111146
850
314.381 235 235 207

0.1119
270. 028
77. 03
o. 211
211.618
0.0111
-1084910
1000
-1031770
1000
180.763 110 111

0.175 215 215
286.027
98.62
o. 25
35.56
0.011
-1223800
800
-111161161
1000
200.856 112 215 170

0.175 215
66.9111
39.01
0.85
10.26
0.03
-1131790
6280
-4011219
6280
70.818
1.100
33
33 115
191
1119.881
98.07
1. 25
29.85
o. 03
-1218800
6280
-1139052
6500
199.558
1 .139
33
33
38
165.880
103.52
2.09
-1427162
6276
-13181157
6500
230.989
1.139
33
33
38
DIVANADIUM PENTOXIDE
VzOs
181.880
130.54
2. 09
53.911
0.011
-1550590
6276
-11119435
6300
2118.680
1.104
33
33
38
TUNGSTEN DIOXIDE
215.849
50.53
o. 29
19.92
0.03
-589690
880
-533858
960
93.530 247 2117 140

0.168
231.8118
75.91
1. 26
31.61
0.10
-8112909
837
-7611062
879
133.861 2117 247 140

0.1511
YTTRIUM S ESQUIOX IDE (CUBIC)

y 203
225.810
99.08
II. 20
411.88
0.02
-1905310
2260
-1816609
21100
318.264 2611 2611 210

0.1120
YTTERBIU!'I SESQUIOXIDE (CUBIC)

Yh 2 03
3911.078
133.05
0.85
112.76
o.o 1
-18111600
850
-172681111
850
302.537 235 235 207

0.1119
81.379
113.64
o. 110
111.338
0.005
-3501160
270
-3201177
300
56.1116 120 111 115

0.053 215 215
123.219
50.38
o. 34
21.15
0.01
-1100560
1674
-10112790
1715
TERBIUM SESQUIOXIDE (CUBIC)
365.8119
156.90
II. 20
TERBIU!'I OXIDE
TbOt. 714
186.3118
TERBIU!'I OXIDE
TbOt.alz
TELLURITE
Tb 2 0
Te0 2
THORIANIT E
Th0 2
Tm 2 0 3
U RANI NIT E
uo,
URANIUII TRIOXIDE ( GAIIMA)
uo.
VANADIUII MONOXIDE
vo
KARELIANIT E
V2 0 3
DIVANADIUII TETROXIDE
V 2 0,.
wo.
TUNGSTEN TRIOXIDE
wo.
ZINCITE
zno
BADDELEY!~
ZrOz
116.118
0.02
47.370 262 262

0.149
2011.765 215 215 260
0.615
182.693 264 264

0.300
1011
33
176
33
77
60
113
IIULTIPLE OXIDES
TIALITE
Al 2 Ti0 5
181.861
109.62
0.84
118.75
0.05
CHRYSOBERYL
126.974
66.28
0.13
3'1. 32
o. 023
120
-2300780
2800
-21781160
2800
381.659 2111 2111

0.149 67
21
23
PROPERTIES lT 298.15 K
Por~ula
Naee and forula
we1gbt
EntfiOPf
s 298
!lolar
voluee
6H;. 298
6G; 9298
Log Kf
References
6H:
----------------------------- ----------~-----~~~~:~~----~~: ______ :~~~:-- --- :~~~:-------------=--~~!- -=~

!IULTIPLE OIIDES
CALCIO II PERRIT E
215.772
145.35
o. 64
44.911
0.05
1520140
1l0
-1412666
120
247.494 214 214

0.021
20
271.851
18~.78
P.18
0.10
-2139280
850
-2001560
1150
350.667 214 214

0.149
20
33.626
0.01
-16606)0
1115
-1575256
1757
275.980 120 214 117

0.308
135.349 263 263 129
CaFP 2 0 4
DICA LCIU II FEBR IT E
1. l6
Ca 2 fEl 2 0s
PEllOVSKITE
CaT io,
135.978
93.64
o. 42
COBALT SPINEL
coJ0 4
240.797
102.51
o. 84
39.77
0.02
-891190
8500
-712553
8500
HERCYNITE
FeAl 2 0 4
113.609
106.27
0.114
40.75
0.05
-1966480
8500
-1850795
<1500
CHROIHTE
P'eCr 2 0
223.837
146.02
1. 67
44.01
o. 10
ILIIEMITE
151.7115
105.86
1. 25
31.69
o. 011
T ITA 8011AGNET IT E
Pe 2 Tio.
223.592
168.87
2. 51
46.82
o. 05
120
21
PSEUDOBROOKITE
Pe 2 Tio 5
239.591
156. 48
1. 25
54.53
0.-()5
120
21
65.921
53.35
2. 10
25.21
0.01
-1188670
4180
-1126276
4180
197.320
0.732
32
32
142.267
80.63
o. 42
39.71
0.03
-2299320
750
-21141160
760
381.0211214 237
0.1lJ
31
22
192.295
106.02
o. 84
43.56
o. 05
-1183640
850
-1669U79
850
292.411
0.149
199.997
123.85
o. 84
44.57
o.os
-14281120
1841
-1317004
2J0.735 120 214

o.JJo
146
120. 203
74.56
o. 42
30.86
0.07
-1572765
1130
-14811371
1172
TREVORITE
Ni Fe 2 0 4
234.392
131.80
o. 84
43.65
0.05
-1081150
850
-972940
850
170.1156 120 263

0.149
ZINC TITANIO!I SPINI!L
242.658
143.09
o. 28
45.58
-1U7f>60
2510
-ISJQOJS
.2510
268.758 2611 2611

o.440
253
28.991
0.008
- 100580
180
-97121
180
17.015 120 215 115

0.032 215
FeTiO,
LITIIIOII ALU!IIRATE
(ALPHA)
Lillo,
PICROCHROIIITE
llgcr 2 0 4
IIAGMESIOFERRITE
llgFe 2 o
GEIKELITE
!lgT io,
zn 2 Ti0 4
o.o~
324.253 120 26J

1.489
120
-1236622
1590
-1159110
lb32
1~83
114
203.083 120 122 117

0.286
32
21~
214 174
20
260.057 120 214 177

0.205
21
HALIDES
BRO!IARGY BITE
187.772
AgBr
POTASSIU!I BRO!IIDE
KBr
11~.
002
95.90
o. 20
41.28
o. 01
-393460
180
- 380061
11:11)
66.585 215 215 247

0.032
173
STRONTIO II BBO!IIDE
247. 42!1
135. 10
o. 20
58.31
0.06
-7115fo0
850
695908
850
121.921 250 214 250

0.149
287.612
116. 44
3. 35
67.8
0.09
-595380
8370
-570732
81150
99.990 247 247 141

1.1180
143. 321
96.23
o. 20
25.72 7
0.007
-127070
85
- 109819
85
19.2110 120 215 115

0.015 215
110.986
104.60
50.75
0.005
-795800
650
-748063
750
131.058 214 2U 115

0.131
169
-302172
420
52.9110 215 215 169

0.0711
147
-3992110
ll20
- 3))7511
11120
58.1173 215 215 169

o.249
n1
-92312
130
-95299
130
16.69fl 215 215 2117

0.023
- 132610
1255
-1051115
1339
SrBr
T ITA NIU II T RIBRO!IIDE
TiBr >
CHLORARGIRITE
Agel
HYDROPHILITE
1. 2S
CaC1 2
LliBENCIT!
126.753
P'eCl 2
IIOLISIT!
162.206
57.86
0.10
reel,
HYDROGEl CIU.ORIDE
HCl ( IDUL G&S)
36. 461
236. 0113
186.90 24789.2
o. 0 3
3.4
96. 23
1. 25
u. 93 9
o. 075
18.469 263 263

0.235
TH~RBODYN.I.IIIC
Maae and fonula
PROPERTIES OF IIINEULS
':~:~~ En~~::y v:~!:~
6H~,HII
6G~,2911
Log Kf
Refe::~ces
--------------------------------------- ~---- -~:~~~~~----~~: ______ ::~~: _____ :~~~~-------------~--~:!_ _:f

HALIDES
S YLVITF.
KCl
74.551
82.59
o. 20
37. 52 4
0.004
-416470
140
- 4085S4
140
71.571 215 215 247

0.025
173
CHLOROIIAGH ES IT E
llgClz
95.211
89.1:>2
o. 84
110.81
0.10
-6111320
460
-591785
51111
103.679 120 2111 169

0.095 247 2117
118.24
o. 21
112.11
0.17
-481290
837
-111101188
1179
71.172
o. 1511
SCACCHIT E
llnClz
J4 2111 169
1117
SALAIIIIOHIAC
MH.Cl
SJ. 491
95.02
o. 40
35.06
0. OS
- J 15190
290
-201776
290
15.701, 215 215 2117

0.051
HALITE
SB. 441
72. 12
o. 21
27. 01S
0.001
-411260
110
-31111:.!12
110
67.313 215 215 247

0.1119
HICKEL CHLORIDE
HiClz
129. 606
97.66
o. 21
16.7
0.01
- J053JO
80
-259010
. t!O
45.1111 261 263

0.014
COTU NNITE
2711. 10&
115.98
2. 09
47.09
0.05
-3!>91100
293
- 3140J3
711
55.01tl 1:.!b 247 11S

0.125 215 215
1S4. 2S9
139.75
1. 26
57.1
o. J
-7217110
4180
-654507
5020
114.667 247 247 141

0.1179
URA NIU II TRICHLORIDE

UCl 3
]44.]811
158.95
o. 40
62.04
o. 06
-891190
4000
-821820
5000
1411.J10
o. d76
70
t19
2 jJ
70
URANIUII TETRACHLORIDE
UCl
319.841
196.60
o. 50
77.6
O.OJ
-10163911
3000
-9288SO
11100
162.111
0.526
70
89
.IH
70
VANADIUII DICHLORIDE
VClz
121.847
97.07
1. 26
-451!170
8500
-4056d1
8500
71.074 120 264 125

1.4tl9
VAMADIUII TRICHLORIDE
157.]00
130.96
1. 70
54.48
0.1
-580740
850
-511399
1150
t1'1.595 120 264 125

0.149
ALUIIINUII TRIFLUORIDE
Al F 3
8 3. 977
66. 48
o. 42
26.15
0.1
-1510400
UOO
-11131076
1100
250.720 .!117 247 51

O.L2d 21:0 215 181
FLUORITE
CaP,
78.077
68.87
o. 14
24.542
0.007
-1229260
420
-1116920
420
206.192 120 21S 115

0.074
-27JJOO
700
-2751100
700
-1124200
1200
-1071(1&4
1.!00
-576550
670
-S46J19
670
95.713 215 .!15 181

0.117
HaCl
PbCl,
40
I
TITANIUII TRICHLORIDE
hC1
vc1,
HYDROGEN FLUORIDE
HF (IDEAL GAS)
20.006
173.78 24789.2
0.04
3.4
411.249
0.12J
35
3:0 2117
SELLAITE
llql'z
&2.302
57.25
o. 42
19.61
0.01
V ILLIAU II IT E
Hal'
41. 988
51. 10
0.08
14.9811
0.005
CRYOLITE
Na 3 All' 6
209.942
238.45
1. 67
70.81
0.20
-33095114
4180
-31114915
4300
5511.978 2117 241 181

0.753
UUNIUII TETRAFLUORIDE
114.023
151.67
o. 17
116.tlll
0.08
-185JSUO
5000
-176211011
5100
308.837
0.1194
IODA RGY BITE

Agi
2J4. 772
1 15. 48
1.67
111.101
0.04
-61tl40
1674
-66254
1757
11.607 120 .163 115

0.3011 .1&3
COCCINITE
Hglz
454. 399
1111. 3J
~- 211
71.114
0.10
-1054J7
1674
-10UOJ
2552
17.90b 2&3 263 115

0.447 32 241 Ji
WIT HER IT E
197.3119
112.13
2. 09
45.61
o.o6
-1210850
2210
-1132210
2240
19!1.159 120
o.J9<
100.0119
87.99
o. 20
14.15
0. OS
-1207410
1421
-1127793
11164
197.58& 241 214 115

0.256
100. 089
9 1. 7 1
o. 20
16.9]4
o. 015
-1207370
1 JJ9
-1128842
1Jt11
197.769 l4J 2111 115

0 .1112
-1125540
1500
197.191
0.263
256
106
ur.
187.&47 247 .115

0 .!10
70 213
17~
70
CARBONATES AND NITRATES
Baco,
ARAGONITE
CaCU 1
CALCITE
caco,
VATERITE
100.0119
]7.&1
0.01
118. 1011
48.7
caco~
IIONOHY DROC lLCIT E

CaC0 3 H 2 0
DOLOIIITE
Callg{co,),
184. 403
155. 18
o. 29
4 155
o. 4
-11198290
1110
-1361600
1130
218.548
0.198
64.]4
o.oJ
-2J21lll80
11160
-2161672
1&7o
118.718 2114 225 151

o.293
PROPERTU:S AT 298.1S K
Por~ula
lae anct forula
111119bt
BnttoPJ
s 298
llolar
voluu
25
AH;, 298
4G;, 298
Log
Kt
References
aH:
---------------------------------------~-----~~~~:~----~~: ______:~~~~--- --~~~~~-- -------- ---~-- ~=!--~
!'
ClRBOilTI!S UD IITBATES
BUITITB
Callg 1 ( co 1
3S3. 032
299.53
0.88
IU. 58
0.10
IIS29600
1S70
420JII2S
1610
112.409
92.117
2. 51
311.3
0.02
-7S0610
2510
66911110
2636
OTlYITB
cctco 1
736.1126
0.286
91
92
117.2811 12.0262
0.1162
lllL&CHIT!
Cu 2 (C01 )(0H).
221. 116
54.86
0.08
-1053950
2090
218
AZURITE
OH ) 2 ( C0 1
31111.671
91.01
0.13
-1632180
2000
263
cu 1 (
) 2
S lDBBIT!
reco,
11S.8S6
IOS.O
2. s
IIAGIESir!
sqco,
29.3 78
0.0111
- 736985
2259
- 66669!1
2092
116.!103 220 263

0.167
117
2!1.018
0.013
-1113280
1339
10291180
1381
11:10.160
0.2112
75.117
o.o5
1977260
260
-11237116
5oo
101.9911 223 2211

o.o8a
-65111860
1 060
-58611166 1027.382 223 2211

1090
0.1 91
2920610
710
-25683116
750
ll89270
1211
8160117
1381
19&3970
2930
1785990
2950
95 220 115
IESQUBHOIIT!
llqC0 1 3H 2 o
138. 360
19 5. 62
o. 59
HtDIOIIlGIESIT E
SllgOIiC0 2 58 2 0
1167.637
503.67
1. 55
AITUITE
llgz( OH) 2 C0 1 3H 2 0
196.679
232.92
o. 67
96.113
0.10
RHODOCHIOS Ir!
IIDC0 1
1111.9117
100.0
2.1
11.073
0.0111
DliiSONIT!
NaUC0 1 ( OH)z
1113.996
132.00
o. 50
59.1
o. 3
CERUSSITE
PbC0 1
267.209
130.96
3. JS
110.59
0.0&
-699150
1172
-625J37
15111:1
STBONTI.UITE
1117.629
97.07
1. 67
39.01
0.06
1.218680
14SO
-11376110
11160
125. 389
82.112
1. 2S
28.275
0.013
-812780
2910
-731480
.!970
128.151 120 .2111

0.521
UTIOBlBIT!
Ba( 10 1 ) 2
261.350
213.!10
0.811
80.S8
0.08
992070
2100
79b579
2SOO
139.558 214 2111 238

0.438
CALCIUII NITRlT!
Ca( N0 1 h
1611.090
193. 30
0.110
66.09
0.03
-918390
1510
-7112985
171>0
130.168 2111 214 2311

0.101:1
101.103
1JJ.09
o. 67
118.011
0.06
11941160
11.!0
-39115114
420
69.123 120 215 115

0.074 21S
1118. liS
1611.01
1. 60
6l.93
0.03
-790650
1300
-589181
1420
103.221 l111 214 238

0.2119
80.0113
1S1.08
0.21
116.119
0.10
-36S560
817
183t10J
879
32 ..!02 262 .26.2 115

0.1SII
811.995
116.52
0.68
37.6
0.02
11611020
1120
-3&7151
4120
611.1211 120 215 115

0.0711 215
211.630
191i.SI'
o. 50
70.9J
0. 011
-978220
1000
-779086
1JOO
136.1191 l14 .!111 250

O .l2tl
309985~
5113.0811 262
O.J2CJ
srco,
SlllTHSOIIT!
znco,
IIAG IES IU II NITRATE

llg( Mo 1 >z
AIIIIONUUT EB
MHo M0 1
SODA-NITER
NaN0 3
STBONTIU II NITRATE
Sr( N0 1 ) 2
211.1
0.1
11119.966
0.131
91
92
142.968 220 220 168

0.2112
&a
312.900
0.517
55
55
55
109.557 120 2111

0.271
199.311 120
0.256
II 155
SULFATES .UD BOBlTES
lLUIIlllllll SULFATE
u,cso.>.
BUITE
196. 182
CHALCOCY lilT!
1880
~6~
2 JCJ
13 2. 2 1
0.811
52.1
o. 06
11173190
1000
-1162186
1300
lJB.650 120 .!111 115

0.22 8
136. 138
106. 69
1. 67
45.911
0.06
111311110
11226
1321696
111811
231.557 120 2U 115

0.7l1 214
112. 168
1911. 111
1. 25
711.69
o. 22
-2022628
4follll
-1797197
1160l
3111.86J 2111 2111

0.806
109. so
o. 60
110.88
0.03
771360
1300
662310
11100
116.0111 511
1
0.2115 <171 263
caso.
cuso.
-3111108110
1800
2JJ. J9B
aaso.
UHIDIITE
239. 32
1. 20
159.6011
Sll
26
TBEBIIODYII.li!IC PBOPEB%IES OF IIIIEBALS
Foraula
weight
Raae and foraula
Entropy
s~ 98
llolar
voluae
-------------------------------------~----::~~:~~----~~:
411~, 298
aGt 298
Log Kt
References
aH:
______::~:_____ ::~~=-------------~--~:~__ ':g
SULFATES liiD BOJUTES
CH.lLC.liiTHITE
CuS0 4 5H 2 o
249.680
BBOCH.liiTITE
Cu 4 S0 4 ( OH ) 6
452.285
FERRIC SULl'lTE
:Pe 2 (S04 )3
453.912
SZOIIOLHOIUTE
FeS0 4 H 2 0
169.920
IIEL.lHrEBITE
FeS0 4 7H 2 0
278.011
300".41
4.18
108.97
0.22
-2279650
3347
113.6
o. 2
329.334 263 263

0.630
-1817950
2510
318.499
0.440
-2249555
3010
394.114 212
0.527
439.681 120
0.228
263
11
130.17
0.15
-2576930
2930
55.9
0.4
-1243900
500
409.20
1. 30
146.5
0.3
-3014400
600
-2509641
1300
98.073
156.90
o. 21
53.57
0.07
-813990
418
-689995
1160
114.254
175.56
0.35
65.5
0.07
-1437700
540
-1319662
540
231.200 215 215 239

0.095
294.226
204.60
1. 26
92.33
o. 08
-2470150
1300
-2239790
1380
392.404 265 265 265

0.242
900. 467
656.05
3. 77
29 3. 6
0.4
EPSOIIITE
llgS047H 2 0
246.469
372.00
4.00
146.8
0.2
-3388700
120
-2871240
850
lllHGlHESE SULFATE
150.996
112.13
0.85
43.62
0.04
-1065250
1050
-957326
1300
167.720 263 263 242

0.228
132. 134
220.08
1.25
74.68
o. 09
-1180850
12 55
-901677
1339
157.971 120 262 121

o. 235 262
239
SULFURIC ACID (LIQUID)

H 2 S04
POTASSIUII lLUIIIIUII SULFATE
Kll( so. )2
lLUlliTE
Kz.ll( OH h z(S0 4
) 4
l!nso ..
IIASCAGHITE
( JH 4
)2
so.
282.84
0.85
-1879796
3598
111110111011 BISULFATE
IIH 4 BS0 4
115.104
TBEIIABDITE
Ha 2 S0 4
142.037
149.58
0.08
IIIRABILITE
Ra 2 S0 4 10H 2 0
322.189
591.90
0.60
RETGEBSITE (ALPHA, GREER)

lliS0 4 6B 2 0
262.849
IIOREIIOSITE
14 212
120.885 69 262
0.081 262 74
120
121
503.032 214 214

0.149
239
65.07
0.08
-1387790
42 0
-1269985
420
222.497 215 215

0.074
219.8
o. 4
-4327250
3970
-3646540
3350
638.861
0.587
334. so
0.110
126.6
o. 2
-2682800
120
-2224542
120
389.732 26J 263

0.021
280.864
378.90
o. 40
143.8
o. 5
-2976300
120
-2461735
120
1131.288 263 263

0.021
303.258
148.57
o. 29
47.95
0.06
-919940
1088
-813026
1046
183.678
118.00
4.20
46.25
0.06
-1453170
4200
-1340970
4000
161.438
110.116
1. 25
41.57
0.07
-982820
837
-871530
962
BIAIICBITE
znso.6H 2 0
269.529
363.60
1.30
130.2
o. 5
-2777460
120
-2324372
120
1107.222 262 262

0.021
GOSLABITE
znS0 4 7H 2 0
287.544
388.70
1. 30
145.8
0.1
-3017800
120
-2562652
120
4118.968 262 262

0.021
BORAX
381.367
222.7
o. 2
-6278900
8500
Hiso.7H 2 0
AIIGLESIT E
Pbso.
CELESTITE
srso.
ZIIIKOSITE
znso.
lla 2 B4 0 7 10H 2 0
53.33
0.06
42
25 265
142.439 262 262 115

0.183
234.933 120 214
0.701
114
152.689 271 262 115
0.169
3
265
PHOSPHATES, IIOLYBDATES, CHROIIATES, ORlHATES, UD TUliGSTATES
BERLiliiTE
11P0 4
121.953
90.79
o. 21
116.58
0.10
-1716400
2092
-1605875
2134
281.344 262 262 151

O.J74
WHIT LOCKIT E
Ca 3 ( PO )z
346.213
235.98
0.84
97.62
0.09
-4085925
2100
-3860760
2200
676.394 2111 214 115

0.385
HIDBOIIAPATITE
Ca 5 (P0 4 hOH
556.367
390.37
1.67
-6669259
5000
-6286093
5000
159.6
o. 2
1101.302 120 214

o. 876
15 0
52
27
Name and formula
!'or~ula
Ent~opy
ve1gbt
s 298
Molar
volume
411~, 298
4G~ 0298
Log Kf
References
4H:
---------------------------------------~-----:~~~~=~----~~: ______ :~~=-----:~~~=-------------~--~:~--~!!

PHOSPHATES, !!OLYBDATES 0 CHRO!!ATES 0 URAIIATES 0 lHD TUIIGSTAT.l!S
FLOORAPATIT E
Ca 5 ( P0 4 J.F
558.358
387.86
1.67
157.56
o. 12
-6819860
5000
-6455778
5000
STRENGITE
20~.86~
171.25
1. 25
64.54
0.30
-1870790
-1645483
850
-15~1390
FeP0 4 2H 2 0
POWELLIT E
Callo0 4
200.018
122.59
0.8~
47.0
0.09
WULFENITE
Pb!loo.
367.138
166.10
2.09
53.86
0.10
DICESIU!I URANATE
567.837
219.66
3~8.
oo6
370.996
Cs 2 uo.
DISODIUII URANATE (ALPHA)
Na 2 U0 4
TRISODIUil URANIU!I OXIDE

Na 3 U0 4
SCHEELITE
cawo.
287.928
FERBERITE
Fewo.
85~
1131.033 120
0.876
288.284
0.1119
21~
52
53 263
53
850
-1434652
850
251.3116 276 214

0.149
10
-1051860
850
-951108
850
166.631 275 263

0.149
~7
-1920000
3500
-1797300
3800
31~.881
193 185
0.666
89
64
0.~2
85.4
0.8
166. n
0.33
58.5
o. 3
-1887000
3000
-1768600
3600
309.853 195 89
0.631
18ll
64
198.20
-2021500
o. ~0
~000
-1897400
4200
332.418
o. 736
126.40
19~
89
186
0.8~
47.05
0.09
-1645150
850
-1538361
850
269.516 214 214

0.149 13~
303.695
131.80
1.67
40.38
0.05
-1154780
8500
-1053880
8500
184.636 272 263

1.489 157
HUEBNER IT .I!
Mnwo.
302.786
132.
so
o. 20
41.89
0.06
154
STOLZITE
Pbwo.
455.048
168.20
2.09
54.1
0.06
275
S ANMARTINIT E
znwo.
313.228
119.29
o. 30
39.79
o. 04
-1232610
1300
62
-1123700
1400
196.868 153 156 153

0.245
ORTHO AND RING STRUCTURE SILICATES

162.047
83.76
o. 34
44.09
o. 07
-2591730
1900
-2441276
1920
427.703 120
0.336
ANDALUSIT E
Al 2 Si0 5
162.047
93.22
0.42
51.53
0.04
-2587525
2100
-2ll39892
2100
427.458 120 99 205

0.368
267
SILLIIIANIT E
Al 2 SiOs
162.047
96. 11
o. 42
49.9
0.011
-2585760
17110
-2ll38988
1750
427.302 120 31 205

0.307
267
IIULLIT E ( 3-2)
3Al 2 0 3 2Si0 2
426.056
269.57
4.18
134.55
0.07
-6810421
2200
-6431286 1126.739 99 99 213

2220
0.389 213 267
PHENACIT E
Be 2 Si0 4
110.108
64.31
o. 34
37.19
0.04
L ARNIT E
112.244
127.61
o. 84
51.6
o. 27
-2305980
322 0
-2191264
3225
383.902 120 126

0.565
115
172.244
120.50
o. 84
59.11
o. 18
-2316620
3930
-219978ll
3 950
385.395 120 93
0.692
229
45
GEHLEIIIT E
Ca 2 Al 2 SiO,
274.206
209.80
1.64
90.24
o. 09
-ij007570
2820
-3808705
2900
667.272 273
0.508 268
93 206
11
GROSSULAR
450.ll55
255.50
0.51
125.30
0.03
-6643140
6000
-6281359
6100
1100.475 283
1.069
286152
88
3111.2ij2
237.61
2.09
101.32
0.12
-ll879060
4600
-11525611
4700
792.873 136
0.823
IIONTICELLIT E
Cal!qsio.
156.469
102.51
4.18
51.36
o. 07
-2262705
3305
-21ij3174
3556
375.ll77 285 179

0.623
MERWINITE
328.712
253.13
2.09
-ll566790
5310
5397
760.249 273 179 206

0.946
116
Ca 2 Si0 4
CALCIUM OLIVINE
ca 2 sio.
Ca 31 Al 2 Si 30 1 z
LAWSONITE
CaAl 2 Si 2 0 7 ( OH ) 2
H2 0
Ca 3 Kq(sio. )z
AKER~ANITE
104.4
1.0
99 205
98
120
~3391103
27 2. 633
209. 33
2. 09
92.81
o. 09
-3876520
2830
-3679069
2850
611ll.560 273 178 206

0.499
116
TITANITE (SPHENE)
CaTiSi0 5
196.063
129.20
0.84
55.65
o. 17
-2601400
2380
-2~59855
430.958 120 93 132

0.426
253
FAYALITE
203.778
148.32
1.67
ll6.39
0.09
-1ij79360
2410
-1379375
2470
Ca 2 11qSi 2 0
Fe 2 sio.
2ij30
2~1.662
252 93 190
0.432 120 127
28
TBBRIIODYHAIIIC PROPERTIES OP IIINERALS
Por~ula
Maae and formula
ve1ght
Ent~opy
s 298
llolar
volu11e
aH~, 298
aG~, 298
Log Kf
References
aH:
---------------------------------------~-----:~~~~=~----=~: ______ :~~~~-----:~~~~-------------:__ ~:~__
:f
ORTHO AND RING STRUCTOIIE SILICATES
PORSTERITE
llg 2 sio 4
140.694
95.19
0.84
43.79
0.03
-2170370
1325
-2051325
1345
PYROPE
llg 3 Al 2 Si 3 o 12
403.130
260.76
10.00
113.27
0.05
-6284620
6000
-5932412
7000
CORDIERITE
llg 2 Al,( A1Si 5 0 1
359.385 120 93 190

0.236
128
1039.341 285
1.226
31 252
5811.957
407.2
3.8
233.22
o. 13
-916152li
5850
-8651112 1515.6115 273 180 206

5900
1.025
TEPHROITE
lln 2 Si0 4
201.960
163.2
4. 2
li8.61
0.07
-1728070
3180
-1629695
3430
285.517 120 93 160

0.601
111
IIILLEIIITE
Zn 2 sio 4
222.844
131.38
0.84
52. li2
0.08
-1636530
2469
-1522936
2510
266.813 120 126

0.4li0
ZIRCOR
zrsio 4
183.304
84.03
1. 25
39.26
0.07
-203lli00
1000
-1918890
1040
336.183 120 264 115

0.182
2311
8 )
CHllll AND BAND STRUCTURE SILICATES
liOLLASTOIIIT E
casio 3
116.164
82.01
0.84
39.93
0.10
-1635220
1435
-1549903
1455
271.538 120 254 240

0.255
19
PSEUDOliOLLASTOliiT E
casio 3
116.164
87.45
0.84
40.08
o. 111
-1628650
2 594
-15411955
2636
270.669 120 116 115

0.1162
CA-AL PYBOXEIIE
CaA1 2 5i0 6
218.126
156.00
4.00
63.5
0.09
-3275680
2761
-3103770
2971
DIOPSIDE
Callg( SiO 3 )z
216.553
143.09
0.84
66.09
0.10
-3210760
9120
-303655li
9160
531.9911 120 148 115

1.605
17tl
ALPHA SPODOIIENE
LiAlsi 2 o 6
186.090
129.30
0.80
58.37
0.02
-3053500
2790
-2880203
2800
504.602 211
0.490
93 211
15
BETA SPODOIIENE
LiA1Si 2 0 6
186.090
154.110
1. 20
78.25
0.04
-3025300
2790
-2859li87
2805
500.972 211
0.490
93 211
15
EUCBYPTITE
LiA1Si0 4
126.006
103.80
o.8o
53.63
0.05
-2123300
1980
-20091711
1990
352.000 211
0.348
93 211
15
CLIIIOENSTATITE
llgSi0 3
100.389
67.86
0.42
31.47
0.05
-15117750
1215
-)q60883
1225
255.942 120 93 115

0.215
254
RHODONITE
llnSi0 3
131.022
102.5
2.1
35.16
0.02
-1319350
1310
-1243081
1440
211.7811 285 93 115

0.252
127 241
JADEITE
II all( SiO 3 )z
202.140
133.117
1.25
60.4
0.1
-3029400
11180
-28508311
li230
499.li56 120 97 115

o. 7li1
1li9
TREIIOLITE
Cazll9s[ Si 8 0zz]( OH }z
812.374
548.90
1.25
272.92
0.73
543.770
0.521
88 286 28 5
-12355080-11627910 2037.170 228 270 151

17320
17360
3.041
PBAIIEWORK STRUCTURE SILICATES
.liiORTHITE
CaU 2 Si 2 0 8
278.211
199.30
o. 30
100.79
0.05
-4229100
3125
-4003326
3145
HEXAGONAL ANORTHITE
CaA1 2 Si 2 0a
278.211
2111.80
1.30
99.85
0.79
-4222575
-4001420
3125
32 7 5
CaAl 2 Si 2 0 8 GLASS
CaA1 2 Si 2 0a
278.211
237.30
2.50
103.0
0.15
-4157300
3300
-3942856
3320
LEONHABDIT E
Ca 2 Al.si 8 0 24 7H 2 0
922. 867
922.2
10.9
404.li
2.0
IIICROCLIHE
KA1Si 0 o 8
278.333
214.20
0.41
108.72
0.10
-3967690
3370
-37li2330
3400
655.6411 187 93
0.596 123 269
90
HIGH SAHIDIIIE
KllSi,0 8
276.333
232.90
0.118
109.05
o. 10
-3959560
3370
-3739176
3400
655.196 187
0.596
90
KUSi 0 0 8
KA1Si 3 0 8
278.333
261.60
1. 78
116.5
1.0
-3914740
3370
-3703513
3500
6118.843 227 93 152

0.613
269
158. 164
133.26
1.25
-2121920
1435
-2005975
1450
351.1140 120
0.2511
GLASS
KALIOPHILLIT E
59.69
0.05
701.371
0.551
227
257
286
93
701.035 136
93
o.
152
56
57 4 25 7
690.777 227
o. 581
-1421161160 -13197115 2312.078 136

9635
10170
1.782
286 152
93
56
93
93
93 201
15
29
Naae and foraula
For~ula
ve~qht
Ent~opy
s 298
Bolar
voluae
1111; , 298
;~Gt 298
Log Kf
References
AB:
_______________________________________:_____::~~~~~----=~:------~~~=-----~~~~~-------------~--~=!__~!
0
FBAIIEIIORK STRUCTURE SILICATES
LEUCITE
KA1Si 2 0 6
218.2118
200.20
1. 70
88.39
o.os
-3038650
2755
-2875890
2850
503.8116 93
0.1199 120
93 201
15
LOll ALBITE
NaAlSi 3 0 8
262.225
207.110
o. 110
100.07
0.13
-3935120
31115
-3711722
JUS
650.281 187
0.602 123
9J 115
90
ANAL BITE
262.225
226.110
0.110
100.113
0.09
-392112110
36110
-3706507
3660
649.367 76 93
0.6111 187 100
262.225
251.90
1. so
110.086
o. 19
-38751160
3700
-3665330
3720
6112.153 227 93 152

0.652
269
1112.055
124.35
1.25
511.16
o. 06
-2092110
2420
-19171198
21150
3116.4119 120 93 115

0.363
229
Ha &lsi 3 0 8
Na AlSi 3 0 8
NaUSi 3 0a
GLASS
NEPHELINE
!laAlsio 4
NEPHELIIIE
Na. 18 K. 22 AlSi0 4
1115.277
-2110290
20110
AIIALCIIIE
Na AlSiz0 6 H2 0
220. 155
234.113
2. 51
DEHYDRATED ANALCIIIE
NaAlSi ~0 6
202. 140
175.110
1. 70
97.49
0.1
-3309839
3598
90
93
229
-3091730
3682
5111.661 120
0.6115
201
136
SHEET STRUCTURE SILICATES
DICKITE
Al 2 Si 2 0 5 ( OH ) 4
258. 162
197.07
1.25
99.3
0.07
-4118840
3766
-3796305
3807
665.100 135
0.667
KAOLIIIITE
AlzSi 2 0 5 ( OH ) 4
258. 162
203. OS
1.25
99.52
0.26
-4120114
3975
-37993611
4017
665.636 135 93
o. 7011
1113
HALLOYSITE
Al 2 Si 2 0 5 (0H ) 4
258. 162
203.00
1. 30
-41011180
2930
-3780713
3010
662.368 135
0.527
93
16
IIUSCOVITE
Kllz[A1Si 3 0 10 )(OH )z
398.311
334.6
-59767110
3225
-5600671
3290
981.219 226
0.576 277
93 152
12 199
PHLOCOPITE
Kllq 3 [ A1Si 3 0 1 0
)(
l. 0
140.71
0.18
1117.262
319.66
11.18
149.91
0.36
421.21111
336.30
2.10
1116.37
0.18
OH }z
FLUORPHLOGOPITE
Kllq 3 ( AlSi 3 0 10 )F 2
ILLITE
( Al 7 11q )( Si 14 Al 2 )0 40 ( OH )a
93
16
285
-6392880
3660
-6053067 1060.1177 118 93 118

3800
0.666 257 118
226
1553.675 1104.20
(1.60
379.268
260.83
o. 63
136.25
o. 26
-5915900
11330
-55360118
11350
PYROPHYLLI TE
l l 2 Si 4 0 1 0 ( OH ) 2
360.317
239.40
o. 110
127.82
0.29
-5639800
3950
-5265884
3960
922.567 226 286 152

0.694 139
CHRYSOTILE
llq 3 Si 2 0 5 ( OH ) 4
277.113
221.311
o.8o
108.5
o.6
-4361660
31180
-403110211
3500
706.7117 128 93 128

o.613
128
TALC
llq 3 Si 4 0 1 0 (
oe )z
969.897 228
o. 762
93 151
11
30
THERIIODYI!IA!HC PROPERTIES OF MINERALS
SILVER (REFERENCE STATE)
Ag:
FORMULA WEIGHT
Face-cente[ed cubic C[JStals 298.15 to melting point 1234 K.
107.!168
LiqYid 1234
to 1800 K.
-------------------------------------------------------------------------------FORMATION FRO II THE ELEI!ENTS

TEI!P.
H;-H~ 98
so
)/T
J/llolK
-(G;-H~ 98 )/T
J/11olK
J/mol K
cp
ENTHALPY
J/molK
GIBBS
FREE EIIEBGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.uoo
42.55
0.000
o.oou
42.55
25.40
0.000
UNCERTAINTY
0. 21
0.21
400
500
600
700
800
900
1000
6.530
10.444
13.135
15.144
16.736
1ll.058
19.196
50.08
55.90
b0.75
64.94
68.66
72.04
75.14
43.55
45.46
4 7 .b 1
49.80
51.92
53.98
55.94
25.87
26. JJ
26.88
27.52
28.24
29.03
29.86
.ooo
.000
.000
.ooo
.000
000
.000
000
.uoo
000
.000
1100
1200
1234
20.205
21.120
21.411
78.02
80.74
81.73
57.82
59.62
60.32
30.73
31.64
31.96
.000
.ouo
.ooo
.ooo
.uoo
1300
1400
1500
1600
1700
1800
30.714
30.911
J 1.082
31.231
31.363
31.480
92.52
95.(10
97.31
99.47
101.50
103.41
61.81
64.09
66.23
b8.24
70. 14
71.93
33. 47
33.47
33.4 7
33.4 7
33.47
33.47
.000
.ouo
ouo
.000
.ouo
.000
.000
000
.000
.ooo
.uoo
.ooo
000
000
.IillO
.OliO
.ooo
.000
.000
.ooo
.oou
.ooo
.ooo
.ooo
.uOCi
.ooo
-------------------------------------------------------------------------------1234
30.566
.ooo
90.88
33.47
.000
.000
60. 32
1234
IIELTII!IG POINT
ENTHALPY OF MELTING
11.945 kJ
5. 745 kJ
.ooo
.ooo
.ouo
.(J(j(j
.ooo
.000
BOILING POII!IT
2436
ENTHALPY OF VAPORIZATION
254. 303 kJ
IIOLl R VOLUIIE
1. 0 27 2 J/ba[
10.272 cm 3
TRANSITIONS Il!l REFERENCE STATE ELEIIENTS
HEAT CAPACITY EQUATION
11.255 +
1.1692x1u-z T
(EQUATION VALID FBOII
REFEBE NCE
107
35
2. 2534:1102 T-o s
298 - 1234 K)
COI!PILED
4-10-7b
31
PROPERTIES lT HIGH T EI!PBUTURES

lLUIUIIIUI! (REFEREIIICE STATE)
Al:
FORI! ULl WEIGHT
Face-centered cubic crystals 298.15 to aeltinq point
933 K.
26.982
Liquid
933
to 1800 K.
-------------------------------------------------------------------------------PORI!lTIOIII PBOI!I THE ELBI!IBIIITS

-(G;-u~ 98 )/T
J/aolK
J/aol K
0.08
0.08
6. 372
10.338
13.165
15.363
11.195
18.1110
19.321
35.70
41.54
4&.51
50.91
54.92
58.65
60.02
29. ]J
31.20
33.34
35.55
37.72
39.114
40.70
27.89
29.25
30.83
32.67
33. 34
.ooo
.ooo
.ooo
.qoo
1000
30.946
13.61
42. 6&
1100
1200
1300
1400
1500
1600
1700
1800
31.019
31.081
31. 132
31.117
31.215
31.249
31.219
31.306
76.64
79.40
81.95
84.30
86.49
88.54
90.46
92.28
45.62
48.12
50.82
53.12
55. 27
57.29
59. 18
60.97
( u;-u~ 98 )/T
J/llolK
cop
GIBBS
PBEE EIIIEIGY
so
TEilP.
EIIITHALPY
J/IIOlK
kJ/aol
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
28.35
28.35
24.31
0.000
o.oou
o.ooo
UNCI BTAI NTY
400
500
600
100
800
900
933.25
25.65
2&.13
.000
.000
.ooo
000
000
.000
.000
.ooo
.000
.ooo
000
.000
.000
.000
.000
.000
31.75
.(JOO
.000
.O(JO
31.75
31.75
31.75
31.75
31.75
31.75
31.75
31.75
000
.000
.000
.000
.000
000
.000
000
.ooo
.ooo
.ooo
-------------------------------------------------------------------------------.(JOO
71.59
000
933.25
30.888
40.70
31.75
.ouo
.ooo
.000
.ooo
.000
.ooo
.ooo
.000
.000
.000
.ooo
.ooo
.ooo
.000
.ooo
llELTIIIG POIIIIT
933.25 K
BOIL IIIG POIBT
2793
ENTHALPY OP I!ELTIJG
10.711 kJ
EIIITHALPY OP VAPORIZATION
290.775 kJ
4. 565 kJ
I!OLAB VOLUI!E
0.9999 J/bar
9.999 ca 3
TRAIISITIOIIIS IN REPEBEIIICE S'UTB ELEilEIIITS
HEAT CAPACITY EUUATION

27.237 - 6.5674x10-3 T
(EQUATION VALID FRO!!
REFERENCE
107
35
1.4310x10-5 TZ
298 - 933.25 K)
1.9916x105 T- z
COI!PILED
4-10-76
32
THERIIODY'NliiiC PROPERTIES OF IIIUBALS
FOBIIULA WEIGHT
ARGON (REFERENCE STATE)
Ar:
Ideal gas 298.15 to
39.948
1800 K.
-------------------------------------------------------------------------------FORIIATION FROII THE ELEIIEMTS

TEIIP.
H~-H~98
)/T
J/molK
so
-(G;-H~ 9 a)/T
J/aol K
JjaolK
cp
ENTHALPY
J/aolK
GIBBS
FREE EHBBGY
kJ/mol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
154.84
0.000
o.ooo
154.ll4
20.79
o.ooo
UNCERTAINTY
(1.02
0.02
400
500
600
700
80(1
90(1
1000
5.292
a. 392
10.457
11.933
13.(14(1
13. 90(1
14.589
160.95
165.59
169. 38
172.58
175.36
177.80
179.99
155.66
157.20
158.92
160.65
162.32
163.90
165.40
20.79
20.79
20.79
20.79
20.79
2(1.79
20.79
1100
120(1
1300
1400
1500
1600
1700
181.1(1
15. 152
15.622
16.(119
16.359
16.655
16.912
17.141
17. 3 43
181.98
183.78
185.45
186.99
188.42
189.76
191.02
192 .21
166.83
16d.16
169.43
170. 63
171.77
172.85
17 3. 88
174.87
20. 79
20.79
20.79
20.79
20.79
20. 79
20.79
20.79
liE LTI NG
POI NT
ENTHALPY OF IIELT ING
83.8(1 K
.(J(J(j
.000
000
000
000
.ouu
000
000
000
000
000
.000
1. 176 kJ
IIOL&a VOLUIIE
.uoo
.000
.000
000
.ooo
.uoo
.ooo
6. 197 kJ
.000
.000
.ooo
.ooo
.ooo
.ooo
.oou
.oou
.oou
BOIL I NG POI liT
.uuo
.uoo
.ooo
.(1(1(1
.(100
.000
.GOO
.000
.ooo
.ouo
.000
.000
.000
.000
000
.ooo
.ooo
87. 30 K
6.561 kJ
2478.9200 J/tlar
24789.200 cal
TRANSITIONS IN REFERENCE STATE ELEIIEHTS
REFERENCE
107
35
COIIPILED
3-11-76
PBOPEBTIBS lT HIGH TBBPBBlTUBBS
ARSBRIC ( RBPBBBNCB STATE)
&s:
33
FOIIIOLl lEIGHT
Rhoabohedral crystals 298.15 to subliaatioa point 875 K.
711.922
Ideal
tetratoaic gas 875 to 1800 K.
-------------------------------------------------------------------------------PORIIlTIOI PROII THE BJ.B!BITS

TBIIP.
(H;-8~98 )IT
J/aol K
so
T
J/aolK
-(G;-a~ 98 )/T
JtaolK
cop
BITHlLPY
J/aolK
GIBBS
PilE UBIGY
kJ/aol
Log Kt
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
35.69
35.69
24.65
o.ooo
o.ooo
o.ooo
UNCBRTliBTt
400
500
600
70(1
80(1
875
6.375
10.2311
12.902
14.883
16.1139
17.111
0.811
0.811
113.011
48.77
53.55
57.68
61.33
63.82
36.66
38.511
110.65
42.80
1111.89
116.51
25.38
25.96
26.51
27. OS
27.60
28.03
.ooo
.ooo
.ooo
.000
000
.0(10
.ooo
.ooo
.ooo
.000
.ooo
.(10(1
.ooo
.ooo
.ooo
.ooo
.000
.(100
-------------------------------------------------------------------------------875
57.1111
46.51
.00(1
.0(10
10 3. 62
20.60
.ooo
900
1000
56.141
52.590
104.14
106.31
48.00
53.72
20.61
20.64
000
.ooo
.000
.ooo
.ooo
.ooo
1100
1200
49.686
47.269
108. 28
110.08
58.59
62.81
20.67
20.69
.0(1(1
.000
.ooo
.(10(1
.ooo
.ooo
IIBJ.TING POINT
BOI LI BG POINT
875
ENTHALPY OF IIELT ING
kJ
ENTHALPY OF YlPOIIZlTION
]4.828 JtJ
5.130 kJ
!lOLli YOLUBE
It
1.2963 J/tar
12.963 ca 3
TRANSITIONS IN RBFEBENCE STATE BLEIIEBTS
BElT CAPACITY EQUlTIOIIS
20.845 +
6.326Sz10-3 T
( EQU AT IOII YlL ID FRO II
4!1.139 -
9.1839z1o-s T
(!QUlTIOII VALID FROB
RBFBBBBCB
107
107
,-os
52.398
298 - 875 K)
,-os
9.1807
875 - 1200 K)
CO!PILED
5-15-76
34
THERIIODYKAIHC PROPERTIES OF fUNERALS
GOLD (REFERENCE STATE)
Au:
FOBIIULA WEIGHT
Face-centered cubic crystals 298.15 to melting point 1336.15 K.
196.966
LiquJ.d
1336.15 to 1800 K.
--------------------------~----------------------------------------------------
(H;-H~ 98 )/T
TEI!P.
K
JjaolK
-ca;-H~ 98 )/T
cop
JjmolK
J/IIOlK
J/mol K
o. 21
0.21
sr
PORIIATlOll FRO II THE ELEIIENTS

GIBBS
Log Kf
ENTHALPY
FiEE ENERGY
kJ/liOl
kJ/1101
-------------------------------------------------------------------------------298. 15
0.000
o.ooo
o.ooo
47.49
47.49
25.32
0.000
UNCERTAl NTY
400
500
600
700
800
900
1000
6.512
10.428
13. 093
15.043
16.554
17.784
18.835
55.00
60.82
65.64
69.76
7 3. 38
76.63
79.61
48.49
50.39
52.55
54.72
56. 8]
58.85
eo. 11
25.88
2!>.27
26.57
26.92
27.16
27.94
28.67
1100
1200
1300
1336.15
19.769
20.631
21.452
21 .805
82.39
85.01
87.51
88.55
62.62
64. 38
66.06
66.74
1400
1500
1600
1700
1800
31.231
31.275
31.252
31.212
31.189
99.34
101.54
103. 54
105. 39
107.15
66.11
70.26
1J..Z,9
74. 18
75.96
.000
.000
.000
000
.000
000
.000
.000
.uoo
.uoo
.ooo
.uoo
.ooo
000
.000
.ooo
.ooo
.000
.ooo
29.56
30.67
31.95
32.47
.000
.000
000
.000
.000
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.000
32.75
31.49
3o. 81
30.81
30.81
000
.ooo
.ooo
.uoo
.000
.QCIO
.ooo
.ooo
.000
-------------------------------------------------------------------------------1336.15
000
000
.000
31.199
97.94
33.54
66.74
!!ELTING POIIIT
1336. 15 K
ENTHALPY OF IIELTIIIG
12.364 kJ
6. 017 .kJ
.ooo
000
.000
.000
.000
.uOO
.000
000
BOIL UIG POINT
3130
335.054 kJ
IIOLA R VOLUI!E
1.0:.!15 J/bar
10.215 ca 3
TRUSITIOIIS Ill REFERENCE STATE ELEIIEIITS
HEAT CAPACITY EQUATIONS
41.9681.7b96x10-2 T
(EQUATION VALID FROII
-1.3492x10 +
3.7585 T
1.1232x1o-s T2
298- 1336.15 K)
5. 22491l 1 o- T2
-1.8431x10'~
T-2
EQUATION VALID FROII 1336. 15 -
REFERENCE
107
107
1800 K)
COIIPILED
5-03-76
35
PBOPIBTIBS Ar HIGH rBMPEBATOBBS
BOBOR (BEPEBERCE STATE)
POBIIULA lEIGHT
10.810
Bhoabohedral crystals 298.15 to aelt:iag poiat 2300 K.
B:
-------------------------------------------------------------------------------FOBftlTIOR PBOil TBB BL.E.IIERTS

TEIIP.
cu;-H~ 98
so
)/T
J/aolK
-(G;-H; 98 );T
J/aolK
J;aolK
cop
EIITHALP I
J;aolK
GIBBS
PBBE .ENEBGI
kJ/aol
Log Kf
kJiaol
-------------------------------------------------------------------------------298.15
o.ooo
5.90
11.09
o.ooo
5. 90
o. 000
o. 000
U NCEBT AIJITY
0.08
0.08
400
500
600
700
800
900
1000
3.400
6.142
8.393
10.261
11.832
13.170
14.323
9.79
13.60
17. 17
20.48
23.53
26.34
28.94
6.39
7.46
8.78
10.22
11.70
13.17
14.62
15.49
18.53
20.66
22.21
23.39
24.32
25.08
.ouo
000
.ooo
.ooo
000
.000
000
.ooo
.uoo
.ooo
.ooo
.000
.000
.000
.000
.ooo
.000
.ooo
.ooo
.ooo
.ooo
1100
1200
1300
1400
1500
1600
1700
1800
15.331
16.222
17.020
17.742
18.405
19.019
19.595
20.141
31.36
33.62
35.75
37.76
39.67
41 .. 49
43.24
44.92
16.03
17.40
18.73
20.02
21.27
22.47
23.65
24.78
25.73
26.31
26.86
27.40
27.95
28.52
29.11
29.75
.ooo
000
000
.000
.ooo
.oou
.000
000
.000
000
.000
.000
.ooo
.000
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.000
2300
IIELTING POINT
.ENTHALPY OF IIELT UIG
BOlLING POINT
22. 552 kJ
1. 222 kJ
IIOLAB VOLUIIE
4275
kJ
0.4386 J/bar
4. 386 ca 3
TRANS! TIONS IN REFERENCE STATE ELEilENTS
66.520 -
1.7059x1o-z T
2.8390x105 r-z
REFERENCE
107
107
298 -
1800 K)
COilPILED
5-04-76
36
THBBftODYBlBIC PROPERTIES OF ftiBERlLS
B&BI 0 II ( RBP EBEIIC B

Ba:
FORBULl IIEIGHr
STU~B)
137.330
Body-centered cubic crystals 298.15 to secood-order laabda-anoaaly in

heat capacity at 582.53 K. Beta crystals 582.53 to second-order laabdaanoaaly in heat capacity at 768.13 K. Gaaaa crystals 768.13 to aelting
point 1002 K. Liquid 1002 to boiling point 2169 K.
FORftATIOB FROB THE BLBBBBTS
GIBBS
FREE BURGY
EBTHALPY
Log If
TBIIP.
K
2 98.15
o.ooo
OIICERTliMTY
62.42
0.84
62.42
0.84
28.09
o.ooo
o.ooo
o.ooo
.0(10
400
500
582.53
7.617
13.174
18.190
71.24
79.72
86.71
o3. 56
65.94
68.52
33.23
.ooo
.ooo
43.74
54.43
000
.000
.0(10
.000
582.53
600
7011
768.13
18.614
19.183
21.894
23.640
87.13
88.16
94.02
98.02
68.52
68.97
72.13
74.38
32.47
33.94
42.36
48.10
.000
.000
.000
.000
768.13
80(1
900
1000
1002
23.964
24.565
26.173
27.464
27.876
98.34
99.81
104.41
108.52
109. 34
74. 38
75. 24
78.24
81.06
81.46
39.07
39.07
39.117
39.07
39.07
.000
.000
000
.IIUU
.000
.000
.ooo
.000
.uoo
.000
.ooo
000
.(100
.(1(10
.ooo
.ooo
.000
.ooo
.uoo
.ooo
.000
.000
.000
.(1(10
.000
-------------------------------------------------------------------------------1002
35.610
111.07
.ooo
.ooo
81.46
40.62
000
1100
1200
1300
1400150(1
16(10
170(1
1800
36.127
36.568
36.864
37.079
37.199
37.295
37.371
37.440
120.60
124.20
127.44
1 JO. 38
1JJ.08
135.58
137.92
140.13
84.48
87.64
90.58
93.30
95.88
98.28
100.55
1112. 69
40.37
40.12
39.86
39.61
)9.36
39.10
38.85
38.60
.00(1
.00(1
.000
000
.ooo
000
.000
.ooo
.CICIO
.uoo
1100
.(10(1
.000
000
.000
.01111
.000
.(100
.(100
.000
.000
.ooo
.000
.000
-------------------------------------------------------------------------------I!ELTIBG POIBT
1002
BOILING POIBT
2169
K
K
ENTHALPY OF IIELTIIfG
H~98
Ho
0
7.749 kJ
EIITHALPY OF VAPORIZAT I Oil
6.912 kJ
IIOLAB VOLOIIE
kJ
3.8210 J/bar
38.210 ca 3
TRAMSITIOIIS IN R BPBB EIICB STATE ELEBEIITS
HEAT CAPACITY EQOATIOHS

c;
43.154- 2.5318x10-3 T
(EQOATIOB VALID FROB 1002 - 1800 K)
REFEBEIICE
107
107
COBPILBD
7-27-76
PIOPBRriBS lt HIGH tBBPBilrOIBS

BBR!I.LIOB ( IBFBBBICB StlTB)
Be:
l7
POIIIJLl IBIGIIT
He&agonal close packed crrstals 298.15 to 1527 1.

aelting point 1560 1.
9.012
Beta crJStals 1527 to
Liquid 1560 to 1800 K.
-------------------------------------------------------------------------------PORIIl!IOI PIOII THB BLBIIII'l'S

T!IIP.
I
so
-cc;;-s~ 98 >tT
cop
J/aoll
Jtaoll
J/aoll
(B;-a;98 )/T
J/aoll
GIBBS
BITHlLPI
Pill IlliG I
kJ/aol
Log 't
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
9.54
9. 54
16.41
o.ooo
o.ooo
o.ooo
0 IC BIT lilt!
o.o8
0.08
400
500
600
700
800
900
1000
4.652
7.906
10.368
12.314
13.907
15.250
16.1111
14.88
19.54
23.68
27.37
30.72
33.78
36.61
10.23
11.63
13.31
15.06
16.81
18.53
20.20
19.81
21.90
23.39
24.55
25.54
26.1111
27.28
1100
1200
1300
1400
1500
1527
17.438
18.363
19.213
20.005
20.755
20.964
39.25
111.73
44.08
116.33
118.48
49.00
21.81
23.37
24.87
26.33
27.73
28.03
28. 12
28.97
29.85
30.77
31.74
31.84
000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.(ICJO
.OOCJ
.000
000
.0(10
.ooo
.0(10
.ooo
.000
.ooo
.ooo
.ooo
.ooo
.(10(1
.ooo
.ooo
.000
.000
.ooo
.ooo
.000
.000
.0(1(1
.000
.CJOO
.OCJO
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.OCJO
.ooo
.ooo
.ooo
.ooo
.ooo
.OCJO
-------------------------------------------------------------------------------1527
.ooo
22.638
50.67
.ooo
28.03
32.22
.ooo
156(1
22.8110
28.49
51.311
32.22
-------------------------------------------------------------------------------156(1
30.669
.OOCJ
59.16
28.49
29.46
.ooo
.ooo
1600
1700
1800
30.638
30.569
30.507
29.36
J 1. 22
32.96
60.00
61.79
63.47
II! LTI IG POI IT
1560
!l'l'HlLPY OP ftEL'l'IIG
12. 213 tJ
1. 954 kJ
29.45
29.45
29.45
.00(1
.ooo
.000
BOI LI IG POI IT
271f5
!l'l'BlLPI OP VlPOIIZlTIOI
326.519 tJ
IIOLlB VOLOIIB
0.11880 .JAar
4.880 ca 3
TllRSITIOIS II B!PBB!ICE STATE EL!!BI'l'S
BElT CAPACITY EQOlTIOI
,-z
-1.2262&105
( EQUl'l'IOI VALID PBOft
BBPBIBICI
107
107
298 - 1527 I)
CO!PIJ.ID
5-03-76
38
'tHERIIODHIAIUC PROPERTIES OP III IIEBALS
BISIIUTH ( BEPEBEIICE STATE)
Bi:
POBIIUL.l WEIGHT
Rhobolledral crystals 298.15 to aeltiog point 544.5 K.
208.980
Liquid 544.5 to
1800 K.
-------------------------------------------------------------------------------FORIIATION PRO I! THE I!LEIIEIIT S

TEIIP.
(H;-H;9 8 )/T
J/IIOlK
so
J/IIOlK
-(~-H~ 98 )/T
J/IIOlK
co
p
EBTHALPY
J/llolK
GIBBS
FREE ENERGY
kJ/aol
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
0.000
56.74
25.41
56.74
0.000
0.000
o.ooo
UNCERT AIBTY
0.42
0.42
6.607
10.800
12.393
64.36
70.50
73.40
57.75
59.70
61.01
26.62
2d.66
29.83
ouu
.ooo
.ooo
000
.000
.000
.000
.000
.000
600
700
800
900
1000
32.763
32.236
31.742
31.308
30.931
96.64
101.l3
104.90
108.18
111.08
63.88
&8.89
73.16
76.87
80. 15
29.61
28.61
28.02
27.67
27.45
.000
.0(10
OOu
.000
000
.000
.000
.ooo
.000
.000
000
.ooo
.ouo
.ooo
.ooo
1100
1200
1300
1400
1500
160(1
1700
1800
30.608
30.330
30.090
29.882
29.701
29.544
29.405
29.283
113.69
116.07
118.25
120.26
122.13
123.89
125.54
127.09
83.08
85.74
88.16
90.38
92.43
94.35
96.14
97.81
27.31
27.24
27.19
27.17
27.17
27.18
27.19
27.21
ouu
.OOu
.ooo
.000
.000
000
.OOu
.uOO
000
.000
.uoo
.000
000
.000
.000
.000
.000
.000
.000
.ooo
.ooo
.000
.ooo
.ooo
400
500
544.52
-------------------------------------------------------------------------------544.52
31.140
94.15
30.48
.000
000
.ooo
61.01
!!ELTING POIBT
544.52 K
EIITHALPY OF IIELTING
11. 297 kJ
BOILI IIG POINT

6. 427 kJ
IIOLA R VOL Ul! E
1835
ltJ
2.1309 J;bar
21.309 cm 3
TRABSITIONS IB BEFEBENCE STATE ELEliENTS
26.8521.7289x1o-z T
( EQUATION VALID FRO II
c;
4.180lx1o-s rz
298 544.52 K)
29.8271.3600x102 T-os
1.9213x10 T-z
EQUATION VALID FliOft 544.52 - 1800 K)
REFERENCE
76
107
COil PILED
4-10-76
39
PBOPEBTIIS AT HIGH TEI!IPBilTUBES
BBOKIIE (BEFEBEBCB STATE)
Br 2 :
FOBIIUU IIBIGHT
Liquid 298.15 to boiling point 332 K.
159.808
Ideal diatoic gas 332 to
1800 K.
TEI!P.
H~-H;g 8
JtolK
so
)/T
J/aol.K
cop
-cc;;-H~ 98 >tT
J/olK
POBUTIOI FBOft THE BLEil BITS

GIBBS
FREE EIIBBGY
Log Kf
DTHALPY
J/olK
kJ/ol
kJ/ol
-------------------------------------------------------------------------------298.15
o.ooo
152.32
0.000
o.ooo
0.000
152.32
36.06
U!IC BBT .&I IITY
0.04
0.04
332
1.831
160.36
152. 53
96.69
.000
.ouo
332
400
500
600
700
800
900
1000
96.694
86.535
76.618
70.040
65.371
61.886
59.184
57.032
249.33
256.16
264.40
271.17
276.93
281.94
286.36
290.33
152.53
169.63
187.78
201.13
211.56
220.05
227. 18
233.30
36.33
36.73
37.07
37.29
37.45
37.57
31.67
37.76
.000
.000
.000
.000
.ooo
.ooo
.uoo
.000
.000
.000
.000
.000
000
1100
1200
1300
1400
1500
1600
1100
1800
55.278
53.820
52.593
51.544
50.640
49.852
49.159
48.546
293.93
297.22
300.25
3 03.06
305.68
308. 13
310. 44
312.62
238.65
243. 40
247.66
251. 51
255.(14
258.28
261.28
264.07
37.84
37.91
37.98
38.05
38. 11
38.18
38.24
38. 31
.000
.CJOCJ
.000
.000
.000
.000
.000
.000
.000
.oou
.ooo
.ooo
.ooo
.ooo
.000
000
.ooo
.ooo
.000
.000
.ooo
.ooo
.ooo
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.ooo
.ooo
.oou
!!ELTING POI!IT
265.90 K
BOlLI !IG POINT
332
ENTHALPY OF IIELTI!IG
10.573 kJ
29.556 kJ
24.520 kJ
MOLAR VOLUI!IB
5.4580 J/bar
54.580 cm 3
TRANSITIONS Ill REFERERCE STATE ELEIIENTS
38.426 +
1.36631:10-7 TZ
( EQUATION VALID FROII
REl"ERENCE
107
107
22.423 T-os
332- 1800 K)
COI!PILED
J-11-76
40
THERIIODYIIIlaiC PROPERTIES OP IIIIIIERALS
CARBOR ( RBPERBIIICE STATE)
c:
POBftULl WEIGHT
12.011
Graphite 298.15 to 1800 K.
-------------------------------------------------------------------------------PORIIATIOR PROII THE ELEIIEIIITS

TEIIP.
so
cu;-a; 98 )/T
J;aolK
-(G;-u; 98 );T
J/aolK
J/aolK
cop
EIIITH&LPY
J/aaol K
GIBBS
FREE EIIIERGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
u.ooo
5.74
5.74
8.53
o.uoo
0.000
o.ooo
URCERTAI RTY
0.01
o. 01
400
500
600
700
800
900
1000
2.610
4.762
6.607
8.196
9.570
10.767
11.812
8.13
11.70
14.58
11.31
19.87
22.26
24.5(1
6.12
6. 94
7.97
9.11
10.30
11.49
12. 69
11.92
14.70
16.86
18.53
19. 81
20.82
21.60
.ooo
.000
.000
.ooo
000
.ooo
.000
.000
000
.(100
000
.ooo
.ooo
.000
.ooo
.000
.000
.0(10
.000
.ooo
.ooo
1100
1200
1300
1400
1500
1600
1700
1800
12.712
13.544
14.266
14.910
15.488
16.008
16.479
16.908
26.59
28.54
30.38
32.11
33.73
35.27
36.72
38.11
13.86
15.00
16. 11
17. 20
18.24
19.26
20.24
21.20
22.H
22.72
23. 12
23.44
23.70
23.92
24.11
24.27
.00(1
.000
.000
.ooo
000
.00(1
.000
.ooo
.ooo
.ooo
.ooo
000
.ooo
.uoo
.ooo
.(100
.ooo
.ooo
.000
.000
.000
.ooo
.ooo
.0(1(1
IIELTIRG POIRT
BOIL IHG POINT
ENTHALPY OP IIELTIIIIG
EIIITHALPY OP VAPORIZATIOR
kJ
1. 050 kJ
IIOLl R YO LUliE
kJ
o. 5298 J/bar
5.298 ca 3
TRAIISITIOIIIS 1111 REFERENCE STATE ELEIIEIIITS
63.160 -
1.1468x1o-z T
1.8079J:10- TZ
7.4807x10 r-z
(EOUATIOIII VALID PROII
REPEBBNCE
107
107
298- 1800 K)
CO!PILED
3-11-76
41
PROPERTIES AT HIGH TE!PERATUBES
FOR!ULA IIEIGHT
Dlli!OND
C:
12.011
Oiaaond 298.15 to 1800 K..
-------------------------------------------------------------------------------FORIIlTIOII FRO!! THE ELE!!EIITS

TEIIP.
H;-H~ 98 }/T
J;molK
-(G;-8~ 98 )/T
so
J;molK
cop
ENTHALPY
J/olK
J/olK
GIBBS
FREE EIIERGY
kJ/mol
Log Kf
kJ/mol
--------------------------------------------------------------------------------0.5(18
2.900
298.15
&.13
1.895
0.000
2. 38
2.38
0.01
o. 01
900
1000
2.087
4.066
5.873
7.479
8.890
10.132
11.233
4.76
7.112
10. 13
12.76
15.27
17.63
19.86
2.67
3.35
4.26
5.28
6. 38
1. 50
8.63
1100
1200
1300
1400
1500
1600
1700
1800
12.218
13.110
13.929
14.693
15.416
16.111
16.788
17.457
21.96
23.95
25.86
27.68
29.44
31.15
32.83
34.47
9.74
10.84
11.93
12.99
14.02
15.04
16.04
11.01
UMCB RTAI liT I
1100
500
bOO
100
BOO
IIELri IIG POI IT
H~
0.084
0.015
10.23
13.59
16.12
1 a. 01
19.47
20. ()4
21.62
1.686
1.547
1. 455
1.393
1.351
1.324
1. 316
3.274
3.687
4.125
4.578
5.031
5. 491
5.956
-0.428
-0.385
-0.359
-0.342
-0.328
-0.319
-0.311
22.50
23.34
24.18
25.07
26.02
27.06
28.21
29.49
1.]]0
1. 374
1.457
1.591
1.787
2.059
2.419
2.883
6.1123
6.882
1. 333
7.793
8.222
8.651
9.032
9.1135
-0.305
-0.300
-0.295
-0.291
-0.286
-0.282
-0.278
-0.274
BOI LI 11G POI liT
EIITHlLPI OP VAPORIZATION
ENTHlLPI OP !!ELTING
8~98
0.042
o. 523
kJ
kJ
0.3417 J/tla r
3. 417 cm 3
IIOLAR VOLUIIE
TRUSITIONS IN REFERENCE STATE ELE!ElfTS
1. 0977x 1 o-s T2
1.2166x10 T-z
( BQUATIOII VALID PRO!!
REPBBEMCE
107
107
298 -
1800 K)
87
CO!PILED
5-19-76
42
THERMODIBAftiC PROPERTIES OF ftiVERALS
CALCIUI! ( BEFEREI!ICE STATE)
Ca:
TEIIP.
FOBftDLA II EIGHT
40.080
Alpha crystals (face-centered cubic) 298. 15 to 720 K. Beta crystals

(body-centered cubic) 720 to elting point 1112 K. Liquid 1112 to boiling
point 1755 K.
Ideal onato~c gas 1755 to 1800 K.
( H;-H~ 98 )/T
JjmolK
- (G ;-H ~ 98 )/T
ST
J/llolK
JjllolK
cop
FORftATIOB FRO II THE ELEIIEBTS

GIBBS
Log
FREE EIIERGY
EIITHALPY
JjaolK
kJ/aol
Kt
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
41.63
0.0(10
o.ooo
41.63
o.ooo
25.30
Ul!ICERTAI VTY
o. 42
0.42
400
500
600
700
720
6.552
10.62a
13.620
16.056
16.462
49.19
55.19
60.40
65. 12
66.3a
42.64
44.56
46.78
49.06
49.92
26.26
27.68
29.55
31.85
3.<!. 3 5
000
000
.000
.oou
.000
000
000
.ooo
.ooo
.uull
.000
.000
.oou
.ooo
.000
800
90(1
1000
19.101
20.836
22.636
70.56
74.65
7a.74
51. 46
53.a1
56.10
32.65
36.77
40.90
.000
000
000
000
.000
.uoo
.000
.ouu
1100
1112
24.485
24.709
a2.a3
a3. 50
sa. 35
5a.79
45.03
45. 52
.ooo
.000
.000
000
.000
.ooo
1200
1300
1400
1500
1600
1700
1755
32.157
31.937
31.748
31. Sa3
31.440
31.314
31.251
93. 23
95.57
97.74
99.76
101.65
103.43
104.1a
61.07
63.63
65.99
6a. 1a
70 .21
7J..12
72.93
29.29
29.29
29.29
29.29
29.29
29.29
29.29
.000
.000
.000
.000
000
.ooo
.000
.ooo
.uoo
.000
.000
000
.uuo
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.ooo
.ooo
1aoo
116.479
192.25
75.77
20.a4
.000
.ooo
.000
-------------------------------------------------------------------------------720
17.367
67.29
.000
49.92
.000
.000
29.34
.ooo
-------------------------------------------------------------------------------1112
32.384
.ooo
91.17
sa.79
.ooo
ouo
29.29
-------------------------------------------------------------------------------1755
11a.a15
.000
191.75
72.93
.000
.ooo
20. a3
IIELT IIIG POINT
1112
a. 535
EHTHALPI OF ftELTING
kJ
5.707 kJ
BOlLI VG POUlT
1755
153. &75 kJ
BOLAR VOLUME
2.6190 J/ba r
26.190 c 3
TRANSITIONS IN REFERENCE STATE ELEIIENTS
10.786 +
a.7646x1o-:~
-1.2a77x105 T-2
C~
29a -
720 K)
-0.34497 + 4.1256x10-2 T
a.S2a5x103 T-2
( ~UATIOB VALID FROft 720 - 1112 K)
REFEilEBCE
107
107
COMPILED
4-10-76
43
PROPERTIES AT HIGH TE!PEBlTURES
CADIIIUI! ( REFEREIICE STATE)
Cd:
FOB!ULl IIEIGHT
Hezagonal close packed crystals 298.15 to aelting point 594.18 K.

594.18 to boiling point 1039 K.
112.410
Liquid
Ideal aonatoaic gas 1039 to 1800 K.
-------------------------------------------------------------------------------FORIUTION FRO! THE ELBI!EMTS

TEIIP.
so
( H;-a; 98 )/T
J/aol K
-( ~-H~98 )/T
cop
BITHALPY
GIBBS
FREE EIERGY
JtaolK
J/aolK
0.17
o. 17
6.760
10.958
13.811
59.59
65.78
70.79
52.83
54.82
56.98
27.14
28.37
29.53
000
600
700
800
900
1000
1039
24.285
25.059
25.640
26.092
26.453
26.52 9
81.48
86.06
90.03
93.53
96.66
97.97
57.19
61.00
64.39
67.44
70.21
71.44
29.71
29.71
29.71
29.71
29.71
29.71
.000
.000
.000
.000
000
.000
.ooo
.'ooo
1100
1200
1300
1400
1500
1600
1700
1800
116.817
108.814
102.043
96.239
91.209
86.807
82.924
79.472
194.88
196.69
198.35
199.89
201. 33
202.67
203.93
205.12
78.06
87.88
96.31
1 OJ. 65
110.12
115.86
121. 01
125.65
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
000
000
.000
.001.1
.000
.000
000
.000
.000
000
.000
.001.1
000
JfaolK
kJ/aol
Log Kt
kJ/aol
-------------------------------------------------------------------------------298.15
0.000
0.000
51.80
51.80
25.98
0.000
0.000
UMCERT lliiTY
400
500
594.18
.ooo
.ooo
.000
.000
.000
.000
.ooo
.000
-------------------------------------------------------------------------------594.18
24.232
000
.000
81.21
56.98
29.71
.000
000
.000
.000
.000
.000
.000
.000
.000
.000
.ooo
-------------------------------------------------------------------------------20.7'J
1039
71.44
.ooo
122.455
193.90
.000
.000
IIELTI NG POI NT
594.18 K
EIIITHALPY OF IIELTIHG
BOIL DIG POINT
6. 192 kJ
6.251 kJ
IIOLAR VOLUIIE
.000
.000
.000
.000
.000
.ooo
.ooo
.ooo
.000
.ooo
.000
1039
99.667 kJ
1.3005 J/bar
13.01.15 ca 3
TRliiSITIOIIS IN REFERENCE STATE ELEIIENTS
J.8115x1o-z T
1.3402x105 T-z
(EQUATION VALID FRO!
REFERENCF.
107
107
298-
594.18 K)
COli PILED
5-06-76
44
THBRIIODYllllUC PROPERTIES OF lliNERlLS
CERIUII (REFERENCE STATE)
Ce:
FORIIOLl IIBIGHT
Alpha crystals (face- centered cubic) 298. 15 to 999 K.

to aeltinq point 1071 K.
140.120
Beta crystals 999
------------------------------------------------------------------------------FOR!ATIOH FROII THE ELEIIEHTS

TEIIP.
(H;-H~98 )/T
J/aolK
soT
-(G;-u~ 98 )/T
J/aolK
J/aolK
cop
EITHALP I
J;aolK
GIBBS
PBEE EIEBGI
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
0.000
o.ooo
69.46
69.46
26.93
0.000
o.ooo
UNCERT liHTY
400
500
600
700
800
9(1(1
999
7.030
11.422
14.592
17.076
19. 139
20.927
22.344
8.37
8. 37
77.56
84.03
89.57
94 .so
98.98
103.13
106. 81
70. 53
72.61
74.98
77.42
79.84
82.20
84.47
.000
.ooo
000
000
.000
.0(1(1
.ooo
28.29
29.70
31.20
32.77
34.4(1
3&. ()7
37.76
.ooo
.ooo
.000
.000
.ooo
.000
.ooo
.ooo
.000
.ooo
.000
.000
.ooo
000
-------------------------------------------------------------------------------999
25.452
37.61
.ooo
109.92
84.47
.000
.ooo
1000
1071
25.519
26.318
11 o. 01
112.65
84.49
86.33
37.61
37.6l
.ooo
000
.000
.ooo
.ooo
.ooo
-------------------------------------------------------------------------------1(171
31.416
117.75
.000
.ooo
86.33
37.70
.ooo
11(10
1200
1300
1400
1500
1600
1700
180(1
31.582
32.092
32.523
32.892
33.213
33.493
]]. 741
]]. 960
118.70
121.98
124.99
127.79
130.39
132.82
135.11
137.26
1(171
IIELTI HG POI NT
ENTHALPY OF IIELTIHG
87.12
89.89
92.47
94.90
97.18
99. 33
101. 37
103.30
37.70
37.70
37.70
37.70
37.70
37.70
37.70
37.70
.000
.000
.ooo
.000
.ooo
.ooo
.000
000
.ooo
.ooo
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.ooo
.ooo
.ooo
.oou
.ooo
.000
BOILIIIG POINT
5. 460 kJ
BIITHlLPY OF VAPORIZATIOM
kJ
7. 280 kJ
IIOLAR VOLUIIE
2.0770 J~ar
2u. 770 ca 3
TRAIISITIOMS IM BEFEREMCE STATE ELEIIERTS
HEAT CAPACITY !Q UATIOIIS
14.017 +
1.9292x1o-z T
( !QUAT ION VALID FBOII
BBFBBBHCE
107
107
1.44691102
298 999 K)
r-os
COIIPILBD
4-26-76
PROPERTIES AT HIGH TE!PEBATOBBS

CJLOBINE (BEPEBENCE STATE)
Cl 2 :
45
POBIIULA WEIGHT
70.906
Ideal diatoaic qas 298.15 to 1800 K.
-------------------------------------------------------------------------------.P'OBIIATIOII PBOII THE i.LEIIEIIITS

TEIIP.
so
( H~-H~ 98 )IT
J/aolK
-(G;-H~ 98 )/T
J;aolK
J/ao1 K
cop
EIIITHlLPY
J/aolK
GIBBS
.P'BEE EIEBGY
kJ/aol
Loq Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
223.08
223.08
33.98
0.000
0.000
0.000
0.04
o. 04
400
500
600
700
800
900
1000
8.830
14.198
17.882
20.574
22.629
24.251
25.565
233.26
241.22
247.84
253. so
258.44
262.82
266.76
224.43
227.02
229.96
232.93
235.81
238. 57
241. 19
35.26
36.03
16.54
36.88
37.13
37.31
37.45
.000
.000
.ooo
.ooo
.000
.000
000
.000
000
.000
000
.000
.ooo
.ooo
1100
1200
1300
1400
1500
1600
1700
1800
26.650
27.563
28.342
29.016
29.603
30.123
30.585
31.001
270.34
213.61
276.63
279.42
282.03
284.48
286.78
288.96
243.69
246.05
248.29
250.40
252.43
254.36
256.19
257.96
37.56
37.65
31.13
37.80
37.87
37.95
38.03
38.11
.000
.000
.ooo
000
000
.000
.ooo
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
UICEBTAI NTY
IIELTIHG POIIIT
112. 16 K
BOILING POUT
EIIITHALPY OP IIELTI IIIG
6.406 kJ
EIIITHALPY OP YAPOBIZATIOH
H~ 98 - H~
9.180 kJ
IIOLAB YOLUIIE
.ooo
.ooo
.ooo
.000
.ooo
.ooo
.000
.000
.000
.000
.000
.000
.000
.000
.000
239.10 K
20.410 kJ
2478.9200 J/bar
24789.200 ca 3
TBUSiriOIS II BEPEBEHCE STATE ELEIIEBTS
HEAT CAPACITY EQUATIOIII

46.956 4.0158x1o-~ T
(BQUATIOH VALID PBOII
BBPBBBICB
107
35
9.9274x10-7
298 - 1800 l)
TZ
COIIPILED
J-11-76
46
THER llODYIIAiliC PROPERTIES OF III NERALS
FORKU LA il EIGHT
COBALT (REFERENCE STATE)
Co:
58.933
Alpha crystals (hexagonal close packed) 298.15 to 700 K. Beta crystals

(face-centered cubic) 700 to elting point 1768 K.
curie point at 1394 K.
-------------------------------------------------------------------------------FORKATION FBOK THE ELEKENTS

TEKP.
(H;-H~ 98 )/T
J/olK
-(G;-H~ 98 )/T
co
J/IIOlK
J;aol K
J/llol K
o. 42
0.42
so
T
ENTHALPY
GIBBS
FREE EHEBGY
kJ/aol
Log Kt
kJ/aol
-------------------------------------------------------------------------------0.000
u.uoo
298.15
o.ooo
30.04
3u.o4
24.31
0.000
UIICEBTU IITY
400
500
600
700
6.542
10.710
13.752
16.138
37.58
43.68
48.9&
53.&4
31.04
32.97
35.21
J7 .49
26.56
28.19
29.70
31.05
.000
.uou
.ooo
.ouu
000
000
.uuo
.uou
.ooo
.ooo
.000
.0011
800
900
1000
18.625
.lu.283
21.820
58.5(1
&2.45
6&.20
39.88
42.17
44.]8
32. 58
34.55
3&.85
.000
000
.000
.000
.000
.oou
.000
.000
.ooo
1100
1200
1300
1394
1400
1500
1600
1700
17&8
23.313
24.834
2&.44&
28.150
28.236
29.115
29.727
]0. 213
30.500
69.84
73.46
77.12
80.67
80.88
83.72
86.23
88.53
90.00
46.53
48.63
50.67
52.52
5.2.&4
54.60
56.50
58.32
59.50
39.77
43. 52
48.26
53.7(1
44.22
39.75
38.211
37.78
J7. 74
000
.000
.000
.000
.ooo
000
000
.000
000
000
.000
.000
.ouo
.000
.000
.ooo
000
.000
.000
.000
.ooo
.000
.uoo
.uoo
.000
.000
.000
1800
39.678
99.98
&u.3o
40.50
.000
.ooo
.000
-------------------------------------------------------------------------------.ooo
700
000
16.780
54.27
37.49
30.58
.000
-------------------------------------------------------------------------------.ouo
.000
17&8
39.660
99.16
59.5(1
4(1.50
.000
KELTING POINT
1768
EBTHALPY OF llELTIBG
1&.192 kJ
i!OILING PO.IBT
3201
37&. 551 kJ
IIOLlB VOLUKE
4.766 kJ
11.&670 J/bar
6.670 c 3
TBUSITIOIIS IN BEFERE!ICE STATE ELEliEIITS
2.6875x1oz T-o5
1. 5b46x 105 T- z
(EQUATION VALID FBOil
2.8332x10Z 0.19791 T
BBFEBENCE
, 07
107
l98 -
70u K)
7.9727x10-5 TZ
700 - 1394 K)
COIIPIL.ED
S-12-76
PBOPIBTIES AT HIGH
CHRO~IU~
cr:
47
TE~PERATUBES
FOR~ULA
(REFERENCE STATE)
WEIGHT
51.996
Body-centered cubic crystals 298.15 to aelting point 2130 K.
-------------------------------------------------------------------------------FORI!ATION FRO II THE

ELE~EITS
TE~P.
{H;-s;98 )/T
J/aolK
so
-(G;-H; 98 )/T
J/aol K
J/aolK
0.21
0. 21
ENTHALPY
Cp
J;aolK
GIBBS
FREE EJERGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------o.ooo
298.15
o.ooo
23.64
23.37
0.000
o.ooo
23.64
UNCERTAINTY
400
500
600
700
800
900
1000
6.257
10.206
12.993
15.117
16.841
18.313
19.624
30.85
36.64
41.55
45.85
49.70
53.25
56.56
24.59
26.43
28.56
30.7]
32.86
34.94
36.94
25.45
26.48
27. 38
28.36
29.47
3u. 73
32.13
.000
.000
000
.000
000
.ooo
.000
.ouu
.ooo
.ooo
.000
.000
000
.000
.ooo
.ooo
.ooo
.000
.000
.ooo
.00(1
1100
1200
1300
1400
1500
1600
110(1
1800
20.8]0
21.969
23.065
24.136
25.193
26.247
27.304
28.368
59.69
62.69
65.59
68.41
71.17
73.88
76.56
79.21
38.86
4(1.72
42.53
44.27
45.98
47.63
49.26
so. 84
33.67
35.33
37.12
39.(11
41.01
43. 12
45. 32
47.61
.ooo
.oou
.oou
.ooo
.uuo
.000
.000
000
.000
.ooo
.ooo
.000
.ouu
.ooo
.000
000
.ooo
.000
.000
.ooo
.000
.ooo
.000
.000
~ELTING
213(1
POI NT
ENTHALPY OF !!ELTING
16.933 kJ
4.058 kJ
BOlLING POIIIT
2945
344.314 kJ
I!OLAR
VOLU~E
0. 7231 J/t_lar
7.231 cm 3
TRANSITIONS Ill REFERENCE STATE ELEI!ENTS
HEAT CAPACITY
EQUATION
3. 4687x 1 o- TZ
8.6742x1os T-z
( EQUATIOII VALID
REFERENCE
107
107
PRO~
298 -
1800 K)
COitPILEQ
5-19-76
48
THERfiODYIIAIUC PROPERTIES OP IIINEBALS
CESIUII (REFERENCE STATE)
Cs:
132.905
POBIIULA WEIGHT
Body-centered cubic crystals 298.15 to 111elting point 301.55 K.

Liquid
Ideal onato11ic gas 942 to 1800 K.
-------------------------------------------------------------------------------PORIIATION PRO!! THE ELEIIENTS

TEIIP.
(H;-H; 98 )/T
so
J/llolK
J/olK
cop
-(~-H~ 9 a)/T
EITHALPY
J/IIOlK
J/IIOlK
GIBBS
FREE BIIERGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
0.000
85.23
o.ooo
85.23
3.2. 18
0.000
o.ooo
0.40
0.40
0.361
85.43
85.06
32.46
.OliO
.000
.ooo
800
900
942
15.175
18.746
2(1. 390
21.250
21.896
22.636
23.024
1 v3.68
111.07
116.30
120.31
123.90
127.26
128.69
88.50
92.32
95.91
99.12
102.00
104.62
105.67
35.94
30.45
21.14
26.06
27.14
30.31
3.2.35
.ooo
.000
.000
.000
.000
.ooo
.ouo
.ooo
.000
.000
.ooo
.000
000
.000
.ooo
.000
.ooo
.ouo
.000
.ooo
.000
1000
89.606
200.75
111. 14
20.79
.000
.ooo
.000
1100
1200
1300
1400
1sou
1600
1700
1800
83.350
78.137
13.726
69.945
66.668
63.800
61.270
59.021
2112.73
204. 54
206.21
207.75
2u9.15
210.50
211.17
212.97
119.38
126. 40
112.48
111. ao
142. 118
146.70
150. so
153.95
2 o. 79
20.79
20.80
20.80
20.80
20.80
20.80
20.81
.uoo
.000
.000
.ooo
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.(1(10
.ooo
.000
.000
.ooo
.o11u
.000
.ooo
.000
.000
.000
.000
.000
.ooo
UNCERTAINTY
301.55
-------------------------------------------------------------------------------301.55
7.298
92.37
.000
85.06
42.75
.0000
.ooo
400
500
600
1ou
-------------------------------------------------------------------------------942
93.844
199.51
.ouo
.ooo
105.67
20.H
.000
BOILIIIIG POINT
942
2. 092 kJ
BIITHALPY OP VAPORIZATIOII
67.712 kJ
7.711 kJ
!lOLl R VOLUIIE
301.55
IIELTUIG POINT
ENTHALPY OP IIELTIIIG
6.9730 J;bar
69.730 Cll3
TRANSITIOIIIS lit REFEREIICE SlATE BLEIIEIITS
8.6400x1o-s
rz
1. 3896x1o ,- z
EQUATION VALID PRO!!
c;
20.783 +
7.1922x10-
107
35
942 K)
rz
(EQUATIOII VALID PBOft
REPEREIIICE
301.55-
942 - 1800 I)
COli PILED
5-12-76
PROPERTIES AT HIGH TE!IPBRATOBBS

FOB!IULA WEIGHT
COPPER (REFERENCE STATE)

cu:
49
Pace-centered cubic crystals 298.15 to aelting point 1356 K.
63.546
Liquid 1356
to 1800 K.
-------------------------------------------------------------------------------l'OB!IA TION PRO !I THE E.LE!IEirl'S

TE!IP.
so
-(G;-H; 9 8 )/T
cop
J;aollt
J/aolK
J/aol K
<H;-H~ 98 )IT
J;aolK
EIITHALPY
GIBBS
PBEE EBEBGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
33.15
24.45
o.ooo
o.ooo
33.15
0.000
0.08
o. 08
6.357
10.246
12.948
14.957
16.522
11.790
18.845
40.48
46.24
51.06
55.22
58.89
62.18
65.16
34. 12
35.99
38.11
40.26
42. 37
44.39
46. 32
25.43
26.15
26.74
27.25
27.71
28.14
28.53
1100
1200
1300
1356.55
19.743
20.522
21.211
21.695
67.90
70.43
72.79
74.13
48.16
49.91
51.58
52.43
28.92
29.28
29.64
29.85
1400
1500
1600
1700
1800
3 1.320
31.324
31.327
31.331
31.333
84.70
86.87
88.88
90.76
92.56
53.38
55.55
57.55
59.43
61.23
32.64
32.64
32.64
32.64
32.64
UMCEBTAIIITY
400
500
600
700
800
900
.1000
.000
.ooo
.000
.000
.ooo
.ooo
.ooo
.000
.000
.000
.ooo
.000
000
.0(10
.000
.000
.000
.000
.(100
.000
.ooo
.ooo
.ooo
.000
.ooo
.000
.ooo
.ooo
.ooo
.000
.000
.000
.ooo
.000
.ooo
.ooo
.oou
.ooo
-------------------------------------------------------------------------------1356.55
31.318
.ooo
.000
83.75
52.43
32.64
.ooo
!IELTING POIIT
1356.55 K
EMTHALPY OP !IELTING
H;9a - "~
13.054 kJ
.ooo
.000
.000
.000
.000
.000
.ooo
.000
BOILING POIIT
2836
300.340 kJ
!IOLAR VOLU!IE
5. 004 kJ
.ooo
.ooo
o. 7113 J/bar
7.113
ca 3
TRANSITIONS IN REPEREKCE STATE ELE!IEITS
HEAT CAPACITY EQUATIOH

29.764 +
1.6124x10-~
(EQUATIOK VALID PRO!I

RBFEREKCB
107
35
3.4110:~10-7
TZ
298 - 1356.55 K)
CO!IPILED
5-12-76
50
THER~ODYNl~IC
DYSPBOSIU~
Dy:
PROPERTIES OF !INERlLS
FOBIIULA II EIGHT
(REFERENCE STATE)
162.500
Alpha crystals (.hexagonal close packed) 298.15 to 1657 K. Beta crystals

(body-centered cubic) 1657 to aelting point 1682 K.
Liquid 1682 to
1800 K.
-------------------------------------------------------------------------------FORIIlTIOII I' BOll THE ELEMENTS

TEIIP.
so
H~-H~ 98 )/T
JjaolK
-(G;-H~ 98 )/T
J/11ol K
J;aol K
0.84
(1.84
cop
GIBBS
EIITHALPY
PBEE ENERGY
kJ/aol
J/aol K
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
74.89
74.89
28.11
o.ooo
o.ooo
0.000
UNCEBTAI NTY
.ooo
.ooo
400
500
6(10
700
800
900
1000
7.160
11.358
14.17 3
16.224
17.835
19.186
20.387
!13. 15
89.44
94.58
98.98
102.87
106.40
109.68
75.99
78.08
8(J. 41
82.76
85.03
87.21
89.29
28.14
28.17
28.35
28.77
29.49
30.54
31.93
000
.oou
.CJOO
.ooo
.000
.000
.000
.000
.ooo
.000
.000
.000
.000
1100
1200
1300
1400
1500
1600
1657
21.514
22.613
23.721
24.863
26.057
27.318
28.076
112.81
115.83
118.79
121.73
124.68
127.66
129.41
91. 30
93.22
95.07
96.87
98.62
100.34
101.34
33.68
35.80
38.30
41. 18
44.44
48.09
50.17
.ooo
000
.ooo
.uOO
.ooo
.ooo
.ooo
.O(JO
.000
000
000
000
.000
.000
.000
.000
.uoo
.000
.ooo
1682
30.549
132.34
101.76
28.03
.000
.000
.000
1700
1800
3 7. 2 57
37.960
139.41
142.29
102.15
104.33
49.91
49.91
.ooo
000
.000
.ooo
.000
.OO(J
.ooo
.(JOO
.ooo
.(JUO
.000
.ooo,
.ooo
.ooo
-------------------------------------------------------------------------------1657
30.588
131.92
101. 34
.000
.000
.000
2S. 03
-------------------------------------------------------------------------------.(JO(J
1682
37.124
.ooo
138.91
101.76
OOu
49.92
1682
IIELTING POINT
ENTHALPY OF
~LTING
BOI LIIIG
11.058 kJ
8. 866 kJ
TRANSITIONS IN
POI NT
2835
230.(195 kJ
IIOLAR VOLUIIE
1.9010 J/bar
19.010 cm 3
REFEREICE STATE ELEIIENTS
45.108-
2.7561x1o-z T
REI'EREIICE
107
107
2.0181110-S TZ
298- 1657 K)
COIIPILED
4-27-76
PBOPBBTIES AT HIGH TEBP!BATOBES
E.IBIOII ( BEl'EBEIICE STATE)
Er::
51
PORBOLA WEIGHT
Huagoaal close packed crystals 298. 15 to Elting point 1795 11:.
167.260
Liquid
1795 to boiling point 3136 11:.
-------------------------------------------------------------------------------POBUTIOII !'BOB THE BLEB !ITS

TEBP.
(u;-u~ 98 )/T
J/BolK
-<~-H~98)/T
so
T
J/BOlK
JtaolK
co
EliTHlLPY
J/110111:
GIBBS
!'BEE .UEBGY
kJ/aol
Log Kf
kJ/BOl
-------------------------------------------------------------------------------298.1S
o.ooo
o.ooo
13.18
13. 18
28.0S
o.ooo
o.ooo
OIICEBTAIIITY
0.1S
0.1S
600
700
800
900
1000
7.190
11.468
14.385
16.539
18.229
19.623
20.823
81.48
87.8S
93.13
97.67
101.69
105.31
108.64
74.29
76.38
78.74
81. 1]
83.46
85.69
87.82
28.41
28.76
29. 19
29.74
30.40
31.18
32.08
1100
1200
1300
1400
1500
1600
170(1
1795
21.892
22.872
2]. 791
24.671
25.529
26.372
27.213
28.(111
111.7S
114.67
117.46
120. 14
122.72
12S.24
127.71
130.04
89.86
91.80
93.67
95.47
97.19
98.87
100.50
102 .OS
33.09
34.22
35.46
3&.80
38.26
39.83
41. 50
43.22
1800
39.099
141.20
102.10
311.70
400
soo
.000
000
.000
.ooo
.ooo
.000
000
000
.000
.ooo
.ooo
.ooo
.000
.000
.000
.ooo
.ooo
.ooo
.000
.ooo
.ooo
.000
000
.000
.000
.000
.000
.000
OOCJ
.000
.000
.ooo
.ooo
.ooo
.oou
.ooo
.000
.ooo
.ooo
.000
.ooo
000
.ooo
.000
.000
.(JO(J
.(J(J(I
.ooo
-------------------------------------------------------------------------------1795
.0(1(1
39.099
141.13
38.70
102 .us
.000
.CJOO
BELTING POINT
ENTHALPY OF BELTING
1795
19.903 kJ
7. 392 kJ
BOILING PO.DIT
3136
EIITHALPY OP VAPOBIZATIOII
261.350 kJ
IIOLAB VOLUME
J/bar
TRANSITIONS IN BEFEBEIICE STATE ELEIIENTS
71.1S5 T-os
24.717
S.22S2x10- TZ
(EQUATION VALID FROM 298 - 179S K)
BEFEREIICE
107
107
CO!lPILED
4-15-76
52
THEBBODYIABIC PBOPEBTIES OP BIIEBALS
POBBULA WEIGHT
EUROPIUII (REPEBEMCE STATE)
Eu:
Body-centered cubic crystals 298.15 to
~~eltillq
point 1090 1.
151.960
LiCJuid
1090 to boiling point 1870 K.
-------------------------------------------------------------------------------FOBBATIOI PBOB THE BLEB BUS

TEIIP.
(H;-H~ 9 8
so
)/T
J/aolK
-(G;-H~ 98 )/T
JjaolK
J/aolK
cop
EIITHALPY
Jjaol K
GIBBS
FIIBB BURGI
kJ/aol
Loq
If
kJ/aol
-------------------------------------------------------------------------------O.QOO
0.000
o.ooo
298.15
0.000
80.79
80.79
27. 12
UNCERTliMTY
0.16
o. 16
400
500
600
700
800
900
1000
1090
6.990
11.334
14.457
16.800
18.721
20.429
22.048
23.476
88.85
95.25
100.74
1 OS .49
109.79
113.80
117.65
121.06
81.86
83.92
86.28
88.69
91.07
93.37
95.60
97.58
27.96
29.55
30.30
31.44
33.02
35.26
38.07
40.92
.000
.ooo
.000
.ooo
000
.000
.ooo
.000
.ooo
.ooo
.ooo
000
.ooo
.ooo
.ooo
000
.ooo
.ooo
.ooo
.ooo
.000
.ooo
.ooo
.ooo
1100
1200
1300
1400
1500
1600
1100
1800
31.985
32.496
32.928
33.299
33.620
33.901
34.149
34.369
129.84
133. 16
136.21
139.04
141.67
144.13
146.44
148.62
97.86
100.66
103.28
105.74
108.05
110.23
112.29
114.25
38.12
38.12
38.12
38.12
38.12
38.12
38.12
38.12
.000
.ooo
.000
.ooo
000
000
.000
.00(1
.ooo
.ooo
.0(10
.000
.ooo
.ooo
.(100
.ooo
.ooo
.ooo
.ooo
.000
.ooo
.ooo
.000
.(1(10
-------------------------------------------------------------------------------1090
31.928
.ooo
.000
.ooo
129.51
9 7. 58
38.12
1090
MELTING POINT
9. 213 kJ
ENTHALPY OF MELTING
kJ
BOILING POUT
1870
EITHALPY OF VlPOBIZlTIOII
143.5(10 kJ
!lOLA B VOLOIIE
2.8970 J/bar
28.970 ca 3
TRAIISITIONS IN REFERENCE STATE BLEIIEIITS
HEAT CAPACITY EQUATIOHS
c~
3.1897x1o-z
3.0408x1oz r-os
298- 503.15 K)
-1.9919x107 r-z
EQUATION VALID FROB
REFEBE!ICE
107
107
503.15- 1090 K)
COBPILBD
4-15-76
53
PBOP!BTIBS AT HIGH TEIIPEI&TURBS

FOBIIULA WEIGHT
FLUOBIIE (B!PEBEICE STATE)
P2 :
37.997
Ideal diatoaic gas 298.15 to 1800 K.
-------------------------------------------------------------------------------PORI!lTIOII FBOII THE ILEIIEIITS

TEIIP.
K
so
-(G;-a~ 98 )/T
cop
J/aolK
J/aol K
J/aol K
( H;-H; 98 )/T
J/aolK
EIITHALPI
kJ/aol
GIBBS
PBEE EHEBGI
Log '
kJ/aol
-------------------------------------------------------------------------------(1.000
o.ooo
298.15
o.ooo
202.79
202.79
31.32
o.ooo
0.1)4
0.04
400
500
600
700
800
900
1000
8.210
13.312
16.893
19.567
21.6117
23.319
211.&95
212.25
219.77
226.11
231.60
236.44
240.76
244.66
204.04
206.46
209.22
212.03
214.79
217.44
219.97
33.07
34.32
35.211
35.93
36.47
36.90
37.24
.000
.ooo
.{100
.ooo
.000
.000
.000
000
.ooo
.ooo
00{1
.ooo
.000
.ooo
.ooo
.000
.000
.000
.ooo
.000
.ooo
1100
1200
1300
11100
1500
1600
1700
1800
25.849
26.832
27.683
28.426
29.083
29.670
30.198
30.676
248.23
251.50
2511.54
257.36
260.00
262.48
264.82
267.04
222.38
224.67
226.86
228.93
230.92
232.81
234.62
236. 36
31.53
.ooo
000
000
000
000
.ooo
.ooo
.000
.ooo
.ooo
.ooo
000
.000
.ooo
.ooo
000
.ooo
.ooo
.000
.000
.ooo
.000
.000
.000
UIIC!BTli IT!
37.78
37.99
38.19
38.38
38.55
38.73
38.90
BOILU.G POIIIT
IIELTIIG POIIT
53.48
EIITHALPI or IIELTI IIG
0.510 kJ
EIITHALPI or VlPOBIZlTIOII
8~ 98 - H~
8. 825 kJ
!lOLli VOLUIIE
Jll:
84.95 K
6. 535 kJ
2478.920(1 J/bar
24789.200 ca 3
TBliSITIOIS Ill BBrEBEICE STATE ELEIIBITS
BElT ClPlCITY EQUlTIOII

53.265 -
5.1095x1o- T
1.2226x1o- TZ
,-z
1.8029x10S
(EQUlTIOII YlLID FBOII
BBrBIEICB
107
35
298 - 180{1 K)
COIIPILED
3-11-76
54
THEBIIODYIIAIUC PIOPEBTIES OF IIIIIEBALS
IB 0111 ( BEFEBEIICE STATE)
Fe:
T!ftP.
FOBIIULA
WEIGHT
55.847
Alpha crystals (body-centered cubic) 298.15 to 1184 K.

Curie point
1042 K. Ga1111a crystals (face-centered cubic) 1184 to 1665 K.
Delta
crystals (body-centered cubic) 1665 to 11elting point 1809 K.
Liquid fro11
1809 K.
(H;-u~ 98
)/T
JtaolK
D
ST
-(G;-u~ 98 )/T
J/11ol K
J/llolK
CD
FOBftlTION FRO II THE ELEftEIITS

GIBBS
FREE EIIEBGY
Log Kf
EIITHALPY
J/IIOlK
kJ/1101
kJ/1101
-------------------------------------------------------------------------------298.15
0.000
27.28
0.000
27.28
24.98
o.ooo
0.000
0.13
o. 13
400
500
600
700
800
900
1000
1042
6.642
10.962
14.225
16.916
19.351
21.757
24.435
25.345
34.94
41.25
46.82
51.88
56.73
61.59
66.69
66.84
28.29
30.29
32.59
34.97
37.36
39.83
42.26
43.50
27.36
29.71
32.05
34.60
37.95
43.10
54.43
83.68
1100
1184
27.462
28.376
72.22
75.19
44.75
46. 81
46.40
41.42
.ooo
120(1
130(1
1400
1500
1600
1665
29.253
29.642
30.035
30.404
30.779
31.036
76.44
79.16
81.76
64.22
86.57
88.09
47. 19
49.52
51.72
53.82
55.79
57.06
34.02
34.85
35.69
36.53
37.36
37.91
.000
.000
.(1(10
.0(1(1
00(1
000
1700
1800
31.648
32.379
89.54
91.92
57.69
59.54
41.46
42.47
.ooo
UNCEBT AINTY
.ooo
000
.000
000
.ooo
.ooo
.ooo
.000
.000
.000
.000
.000
.000
.00(1
.000
.uuo
.uoo
.000
.000
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
-------------------------------------------------------------------------------1042
26.265
69.76
.000
43.50
.000
000
54.25
.000
.ouo
-------------------------------------------------------------------------------1184
29.136
75.95
.000
46.81
33.69
.000
.ooo
.000
.ooo
.ooo
.000
.ooo
.000
.(100
.00(1
000
.ooo
.uoo
.ooo
.00(1
.0110
.(1(10
.000
-------------------------------------------------------------------------------1665
31.646
88.70
.0(10
.000
57.06
41.13
.000
ftELTING POINT
ENTHALPY OF ftELTING
u;98 -
H~
1 6(19
13.807 kJ
4.489 kJ
.00(1
BOlLI IIG POINT
3135
349.590 kJ
ftOLAB VOLUftE
u. 7092 J/bar
7.092 c11 3
TRANSITIONS Ill REFERENCE STATE ELEMENTS
REFERENCE
107
107
COitPILED
6-13-66
PROPBITIES A'l' HIGH TEIIPBRATUBBS
GlLLIU II ( REPEBENCE STATE)
Ga:
55
FORMULA WEIGHT
orthorhoabic crystals 298.15 to aelting point 302.9 K.
6 9.72 0
Liquid 302.9 to
boiling point 2478 K.
-------------------------------------------------------------------------------l'ORIUTION PRO!l THE ELE llE liTS

TEilP.
K
J/llolK
-(G;-u~ 98 )/T
so
T
( H;-u;98 )IT
co
ENTHALPY
GIBBS
FREE EIERGY
Log Kf
J/IIOl!K
J/aolK
o. 21
0.21
0.428
41.25
4 o. 83
21. 36
.000
.000
400
500
600
700
800
900
1000
21.000
22.192
22.943
23.464
23.852
24.156
24.398
67.39
73.41
78.28
82.38
85.93
89.06
91.86
46.39
51.22
55.34
58.92
62.08
64.90
67.46
27.23
26.78
26.63
26.57
26. 57
26.57
26.57
.000
.000
.ooo
.ooo
.000
.000
000
.000
.000
.000
000
.000
.000
.000
.000
.000
.000
.000
1100
1200
1300
1400
1500
1600
1700
180(;
24.597
24.763
24.905
25.025
25.128
25.217
25.295
2 5. 362
94.39
96.71
98.84
100.81
102. 64
104.35
105.96
107.48
69.79
71.95
73.94
75.78
77.51
79. 13
80.67
82. 12
26.57
26.57
26.57
26.57
26.57
26.57
26. 57
26.57
.000
000
.000
.ooo
.ooo
.ooo
J/aol K
kJ/1101
kJ/1101
-------------------------------------------------------------------------------298.15
0.000
40.83
o.ooo
40.83
26.22
0.000
o.ooo
UNCERTAINTY
302.9
.000
-------------------------------------------------------------------------------302.9
18.883
59.70
40.83
28.49
.ooo
.000
.000
llELTING POINT
ENTHALPY OF llELTI!IG
302.90 K
.ooo
.000
.ooo
.000
.000
.000
.000
000
.000
.000
.000
.000
.000
.ooo
.000
.000
.000
.1100
.000
.000
.000
BOILING POINT
2478
5,590 kJ
258.720 kJ
5, 573 kJ
I!OLAB VOLUIIE
1.1790 J/bar
11.790 ca 3
TRANSITIONS IN REFERENCE STATE ELEIIEITS
31.1551.0116x10-~ T
1.2666x10Z T-os
EQUATION VALID FRO! 302.90- 700 K)
REF~BEICE
107
107
COIIPILED
4-13-76
56
THERilODYNUIIC PROPERTIES OF lllNERALS
GADOLI VIU!l (REFERENCE STATE)
Gd:
POR!ULA WEIGHr
157.250
Alpha crystals (aexagonal close packed) 298.15 to 1533 K. Beta crystals

(body-centered cubic) 1533 to aelting point 1585 K. Liquid 1585 to
1800 K.
-------------------------------------------------------------------------------PORilATION PROft THE ELEftEHTS

TEltP.
s;-a~ 98 );T
JjaolK
so
JjaolK
-(G;-s~ 98 )/T
cop
J;aol K
Jjaol K
E!IITHALPY
GIBBS
FREE EHERGJC
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------o.ooo
298.15
0.000
68.45
0.000
0.000
68.45
26.15
1. 25
1.25
400
500
600
700
800
900
1000
7.871
11.932
14.728
16.844
18.540
19.953
21.167
71.53
83.80
89.12
93.68
97.74
101.42
104.77
69.65
71.87
74.39
76.84
79.20
81.47
83.60
27.15
26.82
26.69
26.57
26.57
26.57
26.57
1100
1200
1300
1400
1500
1533
22.2 36
23.214
24.125
24.994
25.829
26.106
107.95
110.88
113.68
116.40
118.99
119.33
85.71
87.66
89.55
91.41
93.16
93.22
26.57
26.57
26.57
26.57
26.57
38.70
.000
.000
000
.000
000
00(1
.00(1
.000
000
.000
.(100
.ooo
1585
28.654
122.80
94.14
28. 28
.ooo
.000
.000
1600
1700
1800
35.017
35.143
35.255
130.00
132. 26
134.39
94.98
97.11
99.13
37.15
37.15
37.15
000
.000
.000
.ooo
.ooo
.ooo
UIICERTAIHTY
.000
.000
.ooo
.000
.000
.ooo
.ooo
.ooo
.ooo
.ooo
000
.ooo
.ooo
.000
.000
.ooo
.(100
.000
.000
.000
.ooo
.00(1
.oou
.uoo
.ooo
.ooo
.000
-------------------------------------------------------------------------------.ooo
.000
.ooo
1533
28.658
121.88
93.22
28.28
-------------------------------------------------------------------------------.000
.000
129.16
94.14
.ooo
1585
34.998
37.15
ltELTIVG POINT
ENTHALPY OP !!ELTING
1585
10.054 kJ
9. 079 kJ
.ooo
.000
.ooo
BOI Ll HG POI NT
3539
EHT HALPY OP VAPORIZATION
359.380 kJ
KOLAR VOLUIIE
1.9890 J/bar
19.890 ca 3
TRANSITIONS IN REFERENCE STATE ELEftENTS
REPE RE NCE
107
107
CO.IIPILED
5-15-73
57
PROPERTIES AT HIGH TEIIPEUTORES
FORIIO LA II EIGHT
GERIIANIOII (REFERENCE STATE)
Ge:
12.590
Face-centered cubic crystals (diaaoud structure) 298.15 to 1210.4 K.

Liquid 1210.4 to boilinq point 3107 K.
-------------------------------------------------------------------------------FORIIATION .FROII THE ELEIIENTS

TEIIP.
so
(H;-H~98 )/T
JjaolK
cop
-{G;-H~ 98 )/T
Jtaol K
JfolK
ENTHALPY
Jjaol K
GIBBS
FREE EHERGY
ltJ/ol
Loq Kf
ltJtol
-------------------------------------------------------------------------------o.ooo
2 98.15
o.ooo
0.000
31.09
31.09
23.39
0.000
UNCERTAINTY
0.21
0.21
400
500
600
700
800
900
1000
6.100
9.810
12.355
14.223
15.670
16.844
17.839
38. 12
43.62
48.19
52.11
55.56
58.65
61.47
32.02
33.81
35.83
37.89
39.89
41.81
43.63
24.38
24.89
25.25
25.60
26.01
26.50
27.11
.0(10
.000
.000
000
000
.000
.ooo
.(100
.ooo
.000
.000
000
.ooo
.ooo
.ooo
.uuo
.000
.ooo
.000
.ooo
.ooo
1100
120U
1210.4
18.715
19.511
19.595
64.09
66.55
66.93
45.38
47.04
47.33
27.85
28.73
28.83
.ooo
.000
.ooo
.000
.ooo
.ooo
.ooo
.000
.ooo
1300
1400
1500
1600
1700
1800
48.567
47.070
45.773
44.638
43.637
42.747
99.29
101.34
103.25
105.03
106.70
108. 28
50.72
54.27
57.48
60.39
63.06
65.53
27.61
27.61
27.61
27.61
27.61
27.61
.000
.000
000
.000
.000
.000
.000
.000
.000
.ooo
.ooo
.ooo
.uoo
.000
.000
.000
.ooo
.ooo
-------------------------------------------------------------------------------.000
1210.4
.000
50.118
97.45
47. 33
2 7. 61
.000
IIELTI NG POI NT
1210.4
ENTHALPY OF IIELTING
36. 945 ltJ

4.627 kJ
BOILING POI liT
3107
330.915 ltJ
IIOLAR VOLOIIE
1.3630 Jft!ar
13.630 ca 3
37.798 -
1.3888x1o-z T
-7.6972x10 T-Z
(EQUATION VALID PRO!!
REPEREHCE
107
107
8. 8359x 10-. TZ
298- 1210.4 K)
COIIPILED
4-12-76
58
THERIIODYIIAIUC PROPERTIES OF lliiiERlLS
HYDROGEN (REFERENCE STATE)
H2
FOBIIULA WEIGHT
2o016
Ideal diatoaic gas 298o15 to 1800 Ko
-------------------------------------------------------------------------------FORIUTION FRO!! THE BLEIIEIITS

TEll Po
H~-H~ 98
so
)/T
J/aolK
-(~-H~ 98 )/T
J/aol K
J/aolK
cop
ENTHALPY
Jtao lK
GIBBS
FREE EIIE&GY
kJ;aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298o15
OoOOO
130o 68
OoOOO
OoOOO
130o 68
2tlo84
OoOOO
0 NCBRT AINTY
Oo04
Oo04
400
500
600
700
800
900
1000
7o407
11o 774
14o690
16.783
18.3 75
19o639
20.681
139 23
145o75
151.09
155.61
159.55
163.06
166. 22
131o 82
133.98
136. 40
138.83
141o17
1H.42
145.54
29o22
29.25
29.29
29.42
29o62
29.90
30.22
1100
1200
1300
1400
1500
1600
1700
1800
21.564
22. 332
23.012
23.626
24.185
24.702
25.184
25.635
169.12
171o80
174.29
116o 63
118o84
180.94
182o93
184o83
147.56
149.47
151.28
153.00
154. 65
156.24
157.75
159.19
30.58
30.98
31.39
31.81
32.24
3.2. 67
33.10
33.52
oOOO
.ooo
.ooo
000
000
(100
.ooo
oOOO
.000
.000
.000
000
.ooo
oOOO
oOOO
.ooo
.ooo
.ooo
.000
.ooo
.ooo
000
.ooo
.0(10
.ooo
.ooo
.000
.ooo
.ooo
000
.ooo
.ooo
.(100
.ooo
oOOO
.ooo
.ooo
.000
.000
oUOO
.000
.000
.000
.ooo
oOOO
IIELTI JIG POI liT
13.80 K
BOI I.I IIG POI liT
20.27 K
o. 117 kJ
ENTHALPY OP VAPORIZATION
Oo904 kJ
8.468 kJ
IIOLAB VOLU!IE
2478o9200 J/bar
24789.200 ca3
TRANSITIONS Ill REFERENCE STATE ELEI!EIITS
7o4424 +
1o1707x1o-z T
-So1041x105 T-z
REFEREIICE
107
35
1o3899x1o- TZ
298 -
1800 K)
COI!PILKD
3-11-76
59
PROPERTIES AT HIGH TE!PERATURES
HELIU8 ( REFEREICE STATE)
He:
FORIIU LA II EIGHT
Ideal qas 298.15 to 1800 K.
-------------------------------------------------------------------------------l'OR!UION FROll THE ELEllEITS

TEllP,
K
( H;-H; 98 )/T
Jtol K
so
-(G;-H;ga)/T
Jtol K
J/aolK
Cp
ENTHALPY
J/olK
GIBBS
FllEE EHEJlGY
kJtol
Loq
't
kJ/aol
-------------------------------------------------------------------------------o.ooo
298.15
126.15
126.15
0.000
o.ooo
o.ooo
20.79
OICERTAINTY
o. 01
0.01
400
500
600
700
800
900
1000
5.292
8.392
10.457
11.933
13.04CI
13.900
14.589
132.26
136.90
140.69
143.89
146.67
149.11
151.30
126.97
128.51
130.23
131. 96
133.63
135.21
136.71
20.79
20.79
20.79
20. 79
20.79
20.79
20.79
1100
1200
1300
1400
1500
1600
1700
1800
15.152
15.622
16.019
16.359
16.655
16.912
17.141
17.34,3
153.29
155.09
156.76
158.30
159.73
161.07
162.33
163.52
138.14
139.47
140.74
141.94
143.08
144. 16
145. 19
146.18
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
.ooo
.ooo
.CIOO
.CICIO
.000
000
000
OOCI
000
.000
.ooo
000
000
.000
.ooo
.ooo
000
.ooo
.000
.ooo
000
000
.000
.000
.ooo
.ooo
SOIL! IIG POINT
kJ
liOLUI VOLUI!IE
.ooo
.ooo
.000
ftELTI NG POI NT
6.197 kJ
.ooo
.ooo
.ooo
.ooo
.000
.000
.ooo
.ooo
.000
.ooo
.ooo
.000
.ooo
.ooo
.ooo
.ooo
4. 21 K
kJ
2478.9200 J/llar
24789.200 c 3
TRANSITIONS IN REFERENCE STATE ELEMENTS
REFERENCE
107
35
COMPILED
3-11-76
60
THERBODYIA!IC PROPERTIES OP ftiHERALS
HAFHIUI! (REFERENCE STATE)
Hf:
PORBULA II EIGHt
Alpha crystals (kexagonal close packed) 298.15 to 2013 K.
178.490
Beta crystals
-------------------------------------------------------------------------------PORBATIOI FBOB THE ELEBEHTS

TEMP.
<H;-H~98
so
)/T
J/aol K
J/aolK
-(~-8; 98 )/T
J/aolK
cop
EHTHALPY
J/aolK
GIBBS
PBEE ERERGY
kJ/ilol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
43.56
43.56
25.64
o.ooo
o.ooo
o.ooo
UNCERTAIIITY
0.21
0.21
400
500
600
700
800
900
1000
6.645
10.698
13.528
15.657
17.349
18.747
19.941
51.22
57.22
62.27
66.65
70.55
74.07
77.30
44.57
46.52
48.74
50.99
53.20
55.32
57.36
26.52
27.30
28.06
28.81
29.56
30.31
31.07
1100
1200
1300
1400
1500
1600
1100
1800
20.987
21.922
22.772
23.554
24.284
24.971
25.621
26.243
80.30
83.10
85.74
88.24
90.62
92.90
95.08
97.18
59.31
61.18
62.97
64.69
66.34
67.93
69.46
70.94
31.83
3.2.59
33.35
34.12
34.88
35.65
36. 42.
37.19
MELTING POIIIT
EIITHALPY OF MELTIIIG
2500
24.058 kJ
5. 845 kJ
.ooo
.ooo
.ooo
.ooo
000
.ooo
.ooo
.ooo
.ooo
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.OOCI
.{100
.000
.ooo
.ooo
000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.000
.ooo
.ooo
.ooo
.ouo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
BOlLI IIG POIIT
4876
EBTHALPY OP VlPORIZATIOH
575.141 kJ
IIOLAR VOLUIIE
1.3479 J/llar
13.479 ca 3
TRUISITIOIIS Ill REPERBMCE STATE ELEBENTS
HEAT CAPACITY EQUATIOII

22.465 + 7.8597x10-3 T
( EQOATIOH VALID FROII
"REF.EBEIICE
107
107
25.261 T-OS
298 - 1800 K)
COIIPILBD
4-11-76
61
PROPERTIES AT HIGH TEIIPERATUBES
FOR KULA IIEIGHT
IIERCURY ( REPEREIICE STATE)
Hg:
Liquid 298.15 to boiling point 629.0 K.
20 0. 590
Ideal aonatoaic gas 629.0 to
1800 K.
-------------------------------------------------------------------------------P'OBIIATION PRO II THE ELEIIENTS
(a;-a~ 98 )/T
-(G;-H~ 98 )/T
Cp
J/molK
J/mol K
J/aol K
0.08
o. 08
7.042
11.088
13.763
14.380
84.03
90.12
95.07
96.35
76.99
79. OJ
81.31
81.97
27. 41
27.17
27.14
27.17
.000
.000
700
800
900
1000
99.622
89.768
82.104
75.972
192.71
195.48
197.93
200.12
93.09
105.71
115.83
124.15
20.79
20.79
20.79
20.79
.000
.000
.000
1100
120{1
1300
1400
1500
1610
1700
1800
70.956
66.775
63.238
60.206
57.579
55.279
53.250
51.447
202. 10
203.91
205.58
207.12
208.55
209.89
211.15
212.34
141. 14
137.14
142.34
146.91
150.97
154.61
157.90
160.89
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
TEIIP.
K
J/aolK
ST
ENTHALPY
kJ/1101
GIBBS
PREE EIIIEBGY
Log
Kt
kJ/aol
-------------------------------------------------------------------------------298. 15
27.96
0.000
0.00(1
o.ooo
75.90
75.90
0.000
UNCERTAINTY
400
500
600
629.0
.ooo
.ooo
.000
.ooo
000
.000
.000
.000
.ooo
.ooo
-------------------------------------------------------------------------------629.0
.000
108.520
190.49
81.97
20.79
.000
000
!!ELTING POIIT
ENTHALPY OP IIELTING
234.29 K
.ooo
.000
.000
.00{1
.000
.000
000
.000
.000
.ooo
.ooo
.000
.000
.000
.000
.oou
.oou
.ooo
.ooo
.ooo
.000
000
.oou
.ooo
.ooo
.ooo
.uoo
.000
.0{10
.00{1
.ouo
.000
.000
BOILIHG PODT
629.0
2. 297 kJ
ENTHALPY OF VAPORIZATIOI
59.214 kJ
9. 343 kJ
IIOLA R VOLUIIE
1.4822 J/bar
14.822 ca 3
TRARSITIOBS II REFERENCE STATE ELEIIEITS
HEAT CAPACITY EQUATIOI
2.1681x10- TZ
-7.9563x10 r-z
(BQUATIOI VALID FBOII
BEFEREICE
107
107
298 -
629 K)
COIIPILED
4-10-76
62
THER!ODY NAIUC PROPERTIES OF KIN ERALS
HOLIIIUII (REFERENCE STATE)
Ho:
FORMULA WEIGHT
164.930
Alpha crystals (hexagonal close packed) 298.15 to 1701 K.

Beta crystals
Liquid 1743 to
-------------------------------------------------------------------------------FORIIATION FROM THE ELEIIENTS

TEIIP.
so
( H~-H; 98 )/T
Jjaol K
-( G~-H;9 8 )/T
JjmolK
JjmolK
1.67
1. 67
cop
ENTHALPY
JjaolK
GIBBS
FREE ENERGY
kJ/mol
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
0.000
75.02
75.02
0.000
o.ooo
0.000
27. 11
UNCERTAINTY
400
500
600
700
800
900
1000
7.0]7
11.224
14.028
16.070
17.674
19.023
20.232
83.14
89.38
94.49
98.86
102.71
106.23
109.50
76.10
78. 16
80.46
82.79
1!5.u4
87.21
89.27
27.91
28.00
28. 14
28.55
29.30
30.41
31.88
.0(1(/
000
.000
000
.ooo
.0(10
110(1
1200
1300
1400
1500
1600
1700
1701
21.371
22.488
23.616
24.777
25.989
27.264
28.611
28.634
112.62
115.65
118.62
121.57
124.54
127.53
130.57
13 0.58
91.25
93.16
95.00
96.79
98.55
100. 27
101.96
101.96
33.71
35.90
38.45
41.36
44.61
48.22
52. 17
52. 13
.000
.000
.000
.OCiO
.000
Q(J(j
000
.000
.ooo
.ooo
.uoo
.voo
.ooo
.ooo
.000
.ooo
1743
31.309
134.06
102.74
28.03
.ooo
.ouo
.uoo
1800
38.476
142.45
103.97
43.93
.000
.000
.000
.ooo
.ooo
.000
.000
000
.0(1(1
.000
.000
.000
.ouo
.oov
.ooo
.ooo
.ooo
.000
.000
.000
.ooo
.ooo
.ooo
.CiOO
.CJ(JO
.000
-------------------------------------------------------------------------------.(1(10
1701
.000
31.391
133.34
101.96
.ooo
28.03
-------------------------------------------------------------------------------1743
.000
38.297
141.04
.000
.000
102.74
43.93
MELTING POI NT
1743
ENTHALPY OF KELTING
H;98 -
H~
12. 180 kJ
7.996 kJ
BOILING POINT
2968
240.9HO kJ
KOLAR VOLUI!E
1.8740 Jjbar
18.740 cm 3
TRANSITIONS IN REFERENCE STATE ELEI!ENTS
19.256 -
1.J024x10 z T
-6.8162x10S T-z
REFERENCE
107
107
298- 1701 K)
COI!PILED
4-27-76
PROPERTIES AT HIGH
IODINE (REFERENCE STATE)
2:
FORI!ULA WEIGHT
Crystals 298.15 to melting point 386.75 K.

point 458 K.
63
TEI!PEBATURES
253.809
Liquid 386.75 to boiling
Ideal diato11ic gas 458 to 1800 K.
-------------------------------------------------------------------------------l"ORI!AT ION FRO!! THE ELEI!ENTS

TEIIP.
a;-H~qa
)/T
J/molK
ST
-(G;-H~q 8 )/T
J/aolK
J/aolK
0.08
0.08
Cp
ENTHALPY
J/IIOlK
GIBBS
FREE EIIERGi'
lr.J/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
116.25
54.44
0.000
o.ooo
116.25
0.000
UNCERTAINTY
38b.75
13.220
131.21
117.99
61.67
.000
0(10
.000
400
458
54.642
58.108
114.49
185.58
119.85
127.47
82.01
82.01
.000
.000
.ooo
.000
.000
.000
500
600
700
800
900
1000
139.771
122.729
110.598
101.473
94.405
88.759
279.91
286.76
292.56
2 97.60
302.06
330.30
140.14
164.03
181.98
196. 13
207.b0
217.30
37.45
37.60
37.71
37.81
37.9(1
37.99
.ooo
.000
000
.000
.000
.uoo
.ouo
.000
.000
.000
.ooo
.uou
.oou
.000
.000
.000
.ooo
110(1
120(1
130(1
140(1
1500
1600
1700
1800
84.147
80.310
309.68
31 3. 00
31b.06
318.89
321.54
324.02
326.35
32 8. 56
225. 53
232.69
238.99
244.59
249.64
254.21
258.38
26 2. 22
38.07
38. 15
38.23
38.31
38.39
38.47
3t!. 56
38.64
.000
000
.000
.0(10
.000
.000
000
000
.000
.000
.000
.ooo
.000
.ouo
.000
.000
.000
.000
.uuo
.000
.000
.000
-------------------------------------------------------------------------------3 86.75
.000
53.681
171.67
117.99
82.84
.000
.000
-------------------------------------------------------------------------------458
149.158
276.63
127.47
37.38
.000
.000
.oou
17.(11(1
74.299
71.902
69.810
67.969
66.337
IIELTING
POINT
()(j(J.
.ooo
.000
386.75 K
BOILING POINT
458
15.648 lr.J
41.700 kJ
13.196 kJ
IIOLAR VOLUIIE
5.1290 Jjbar
51.290 cm 3
HEAT CAPACITY
EQUATION
37.872 +
3.4318x1o- T
-4.8784x104 T-Z
EQUATION
REFERENCE
107
VALID FROII
35
45t! -
1800 K)
COMPILED
5-24-76
&4
THERftODYNAftlC PROPERTIES OF ftiNEBALS
INDIUI'I (REFERENCE STATE)
In:
FOBI'IULA WEIGHT
Tetraqonal crystals 298.15 to 11elting point 429.76 K.
114.820
Liquid 429.76 to
boiling point 234& K.
-------------------------------------------------------------------------------FOBI'IATION fBOft THE ELEftENTS

TEI'IP.
( H;-H2' 98 )/T
J;aolK
-(G;-H~ 98 )/T
ST
J/aaol K
J;aolK
Co
p
ENTHALPY
J;aolK
GIBBS
fREE ENERGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
57.84
57.84
0.000
o.ooo
0.000
26.73
UNCERTAINTY
0.84
0.84
7.030
8.632
65.94
68.78
58.91
60. 15
28.97
30.33
.000
.000
.ooo
.ooo
.ooo
.uuo
sou
&uu
700
800
900
1000
18.076
19.9&2
21.293
22.280
23.040
23.645
80.14
85.50
90.02
93.91
97.34
100.41
62.06
&5.54
&8. 73
71.&3
74.30
76.76
29.44
29.33
29.23
29.15
29.10
29.07
000
.ooo
.oou
.000
ouu
.oou
.000
.000
.(1(1(1
.uuo
.oou
.ouo
.ooo
.000
.ooo
.ouo
.uoo
.(1(1(1
1100
12(1(1
1100
1400
1500
1&00
1700
1800
24. 137
24.548
24.895
25.194
25.453
25.&81
25.882
2&.061
103.18
1(15.71
108.0 3
110. 19
112.20
114.07
115.84
117.50
79.04
81.1&
83.13
85.00
86.75
88.39
89.96
91.44
29.06
29.06
29.07
29.08
29.09
29. 10
29.1(1
29.10
.ouo
.000
.ooo
ouo
000
.ooo
000
.000
000
.000
.ouu
000
.000
.000
000
.ooo
.ooo
.oou
.oou
.ooo
.000
.ooo
.000
.uoo
400
112 9. 76
-------------------------------------------------------------------------------42 9. 76
16.227
76.38
.000
.ooo
.000
60. 15
29.47
liE LTI NG
POI 1fT
BOlLI HG POUlT
234&
J. 264 kJ
231.450 kJ
6. 602 kJ
ftOLAR VOLUftE
1.5753 J;bar
15.753 Cll)
429.76 K
l.9024x102-
0.48417 T
8.2737x105 T-2
(EQUATION VALID FROft
1&.334 +
5.4841x10-, T
-4.4951x105 T-2
REFERENCE
107
107
4. 5808x 1 o- T2
298 -
1129.76 K)
1.0873x1o- r2
429.76 - 1800 K)
COftPILED
5-CJ&-76
65
PROPERTIES AT HIGH TE!PER.lTORBS
FOR!ULA WEIGHT
IRIDIU! (REFERENCE STATE)
Ir:
192.220
Face-centered cubic crystals 298.15 to 1800 K.
-------------------------------------------------------------------------------fOR!UION FRO!! THE ELE!EifTS

TEI'IP.
H~-H~9 8 )/T
J/olK
-(G~-H~ 98 )/T
cop
JtolK
J/mol K
J/1101 K
0.17
0.17
so
ENTHALPY
kJ/ol
GIBBS
FREE ENERGY
Loq Kf
kJ/1101
-------------------------------------------------------------------------------298. 15
35.118
35.118
211.93
0.000
0.000
0.000
0.000
UNCERTAINTY
1100
500
600
700
800
900
1000
6.1127
10.296
12.963
111.9511
16.530
17.832
18.9117
112.89
48.64
53.1111
57.58
61.26
611.59
67.64
36.116
38.34
110.48
112.63
1111.73
116.76
118.69
25.52
26.03
26.59
27.22
27.90
28.61
29.35
1100
1200
1300
11100
1500
1600
1700
1800
19.926
20.807
21.609
22.351
2 3. 01111
23.697
211.316
211.907
70.117
73.12
75.62
77.99
80.25
82.112
811.49
86.119
so. 511
52. 31
511.01
55.64
57.21
58.72
60.17
61.58
30.10
30.86
31.62
32.38
33.12
33.86
311.59
35.30
2716
!!ELTING POIIfT
26. 137 kJ
5.268 kJ
.ooo
.ooo
.000
.000
.000
OliO
.000
.000
.000
.000
.000
.ooo
.ooo
.uoo
.000
.000
.000
.ooo
.ooo
.ooo
.000
.000
000
.000
000
.000
.OliO
.000
.000
.1100
.OliO
.ooo
.ooo
.000
000
.000
.ooo
000
.000
.000
.ooo
.000
.000
.000
.000
BOILING POINT
11701
604.075 kJ
I'IOLAB VOLUIIE
0.8519 J/bar
8.519 c11 3
TRUISITIONS IN REFERENCE STATE ELEIIENTS
10.073 +
1.31172x10-Z T
-2.3329x105 T-Z
REFE BENCE
107
107
1.3835x10-6 TZ
298- 1800 K)
CO!PILED
ll-17-7&
66
THERMODYNAMIC PROPERTIES UF MINERALS
POTASSIUM (REFERENCE STATE)
K:
FORI!ULA WEIGHT
39.098
Body-centered cubic crystals 298.15 to melting paint 336.4 K.

L~quid
Ideal monatomic gas 1030 to 18110 K.
-------------------------------------------------------------------------------FORMATION FRUit THE ELEI!ENTS

0
TEIIP.
( HT-H298)/T
J ;molK
-(G;-H~ 9 a)/T
sr
Cp
ENTHALPY
GIBBS
FREE ENERGY
k.J/mol
Log Kf
k.J/1101
J/molK
J/molK
o. 20
0.20
68.38
64.92
32.2 5
.000
.000
.000
J/molK
-------------------------------------------------------------------------------0.1100
298.15
0.1100
64.68
11.000
64.68
29.55
o.ooo
UNCERTAINTY
336.3 5
].483
-------------------------------------------------------------------------------336.35
.ooo
10.424
75.32
32.14
.1100
uvo
b4. 92
400
500
600
700
800
900
100(1
1030
1 3. 8 30
17.284
19.465
20.961
22.065
22.934
2 J. 6 58
21.855
80.83
87.78
93.31
97.93
101.91
105.43
108.61
109.51
67.00
70.50
7 3. 85
76.97
79.85
82.50
84.95
85.65
31.55
30.69
30.10
29.82
29.81
30.00
311.36
30.51
.ooo
.ooo
.000
.000
000
.000
000
0011
.OliO
.000
.000
.000
.000
.000
.ouo
.1100
.IIIlO
.1100
.ooo
.ooo
.ooo
.ooo
.0011
.IIUO
1100
1200
1300
1400
150(1
1600
1700
1t!OO
96.312
90.019
84.694
tl0.129
76.173
72.712
69.657
66.943
187.47
189. 2t!
190.94
192.49
193.92
195.26
196.53
197.72
91.16
9 9. 26
106.25
112. )6
117.75
122.55
126.87
1311.78
20.79
20.79
20.79
20.80
20.80
20.81
2u.82
20.82
.oou
ouo
.000
000
.000
.000
.000
.000
.1100
.lluO
.IIUII
.000
.000
.ooo
.OU(J
.vvll
.ouo
.ooo
.000
.ooo
.ooo
.ooo
.ooo
.UOII
-------------------------------------------------------------------------------.ooo
1030
101.445
187. 10
000
.000
85.65
20.79
!!ELTING POINT
336.35 K
BOILING
~OINT
2. 334 k.J
7. 088 ltJ
MOLAR VOLU liE
1030
79.918 ltJ
4.53611 J/bar
45.360 cm 3
-8.9054 + 1.5236x1o-z T
7.t!457x10Z T-os
(EQUATION VALID FBOII 336.4- 1030 K)
c~
20.801 5.1832x10 -s T
3. 5737x 10 a TZ
(EQUATION VALID FRO II 1UJII - 1 diiO K)
REFERENCE
107
J5
COM PI LED
5-03-76
PROPERTIES
AT
KBYPTOll ( iiEFEREHCE STATE)
Kr:
Ideal gas 298.15 to
67
HIGH TEMP EB ATUB ES
FOB ftU LA II EIGHT
83.800
1800 K.
-------------------------------------------------------------------------------lOBIIATIOM FBOII THE ELEIIEIITS

TEftP.
a;-a~ 98 )/T
J/olK
-(G;-a~ 98 )/T
ST
JfolK
J/8olK
0.02
o. 02
cop
EITHALPY
J/aolK
GIBBS
FREE EIERGY
ltJjaol
Log Kf
kJjaol
-------------------------------------------------------------------------------298. 15
164.08
o.ooo
164.08
20.79
o.ooo
0.000
0.000
UJCEBTliNTY
400
500
600
700
800
900
1(100
5.292
8.392
10.457
11.933
13.040
13.900
14.589
170.19
174.83
178.62
181.82
184.60
187.04
189.23
164. 90
166.44
168.16
169.89
171. 56
173. 14
174.64
20.79
20.79
20.79
20.79
20.79
20.79
20.79
1100
1200
1300
1400
1500
16(10
1700
1800
15.152
15.622
16.019
16.359
16. 655
16.912
17.141
17.343
191.22
193.02
194.69
196 .2]
197.66
199.00
200.26
201.45
176.07
177.40
178.67
179.87
181.01
182. (J9
183.12
184. 11
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
liE LT I NG POI lilT

115.78 K
.ooo
.000
.000
.ooo
.(100
.ooo
.ooo
.ooo
.000
000
.ooo
.ooo
.ooo
.ooo
.ouo
.000
.000
.000
.000
.00(1
.000
.000
.000
.000
.000
.0 110
.000
.000
000
.ooo
.ooo
.000
000
0(10
.000
.000
000
.000
000
.ooo
.000
.000
.000
.ooo
.ooo
BOlLING POI lilT
1. 6]6 kJ
EIIITH lLPY 01' VAPORIZlTIOIII
6. 197 kJ
MOLAR VOLUME
kJ
2478.9200 Jjbar
24789.200 ca 3
TRAIIISITIOHS 1111 BEFEBEIIICE STATE ELEMENTS
REFEBE IIICE
107
35
COl! PILED
3-11-76
68
THERIWDYNAIUC PROPERTIES OF IUIIEBALS
FORI'IULA WEIGHT
LAIITHAIIUI'I (REFER EIICE STATE)
La:
TEI'IP.
138.906

Beta crystals
(face-centered cubic) 55u to 1134 K.
Gamma crystals (body-centered
cubic) 1134 to melting point 1193 K.
Liguid 1193 to 1800 K.
H~-H~ 98 )/T
J/molK
-( G;-H~ 98 )/T
ST
J;molK
J;molK
2. 51
2.51
cop
POBI'IATIOII FRO !'I THE ELE liE !ITS

GIBBS
Log Kf
ENTHALPY
FREE ENERGY
J/mol K
kJ/mol
kJ;mol
-------------------------------------------------------------------------------298. 15
0.(100
u.ooo
56.90
56.90
27.10
u.uOO
o.ooo
UIICERTAI IITY
40U
suo
550
6.950
11.056
12.560
64.92
71.05
73.68
57.97
59.99
61. 13
27.40
27.58
27.72
.ooo
.000
.ouo
000
000
.000
.000
.000
.(J(J(J
600
700
BOO
900
1000
14.412
1b.409
18.061
19.489
20.777
76.73
81.11
85.06
88.21
9 2. 11
62.32
64. 70
67.00
68.72
71. J3
27.79
29.00
30.28
31.63
JJ. 04
.000
000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.uoo
.ouo
1100
1134
21.959
22.340
95.33
96.40
73.37
74.(16
34.52
35.02
.000
.ouo
000
000
.000
.000
119]
25.812
101. 17
75.35
39.54
.uoo
.0(10
.ouo
1193
120(1
1300
140(1
1500
1600
1700
180(1
31.006
31.024
31.277
31.494
31.681
31.846
31.991
32. 11 9
106. 36
106.54
109.29
111.83
114.20
116.41
118.49
12U.45
75. 35
75.52
78.01
8u.34
82.52
811.56
86.50
88.33
34. 31
34.31
34.31
34.31
34.31
34. 31
34.31
34. 31
.000
.000
.uoo
.000
.000
.ooo
.000
000
.000
000
.ooo
.(J(JO
.OUu
.00(1
.ooo
.000
.ooo
.ooo
.000
.ooo
.uuO
.oou
.ooo
.ooo
-------------------------------------------------------------------------------550
13.221
74.35
.000
.000
61. 13
27.19
.000
-------------------------------------------------------------------------------1134
.(100
25.093
99.16
74.06
.uoo
.ooo
39.54
--------------------------------------------------------------------------------
IIELTING POINT
1193
BOI LI IIG POINT
3730
6. 197 kJ
1113.670 kJ
6.665 kJ
I'IOLAR VOLUIIE
2.2470 J/bar
22.470 cm 3
TRANSITIONS Ill REFERENCE STATE ELEIIENTS
cop
1.6025x10-2 T
4.8183x1(J2 T- os
(EQUATION VALID FRO !'I 298 550 K)
4.9617x10S T-2
co
p
1. 9885x 10-2 T
4.4020x102 r-os
(EQUATION VALID FBOII 550 - 11311 K)
7. 6150x10S T- 2
REFERENCE
107
107
COli PILED
4-30-76
69
PROPERTIES AT HIGH TEftPEJUTURES
FOBIIULA WEIGHT
LITHIUft (REPEBEICE STATE)
Li:
6.940
crystals 298.15 to melting point 453.69 K. Liquid 453.69 K to boiling

point 1618 K.
-------------------------------------------------------------------------------FORI'IlTION FRO II THE ELEMENTS

<H;-H~ 98
TEftP.
K
)/T
J/aolK
-(G;-u~ 98 )/T
ST
J/mol K
J/aolK
Cp
GIBBS
FREE ENERGY
ENTHALPY
J/aolK
Log Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------0.000
0.000
298.15
o.ooo
29.12
29. 12
24.76
0.000
UNCERT liiiTY
0.02
0.02
6.655
9.262
36.78
40.77
30.12
31. 51
27.61
29.38
.ooo
.ooo
.OCJO
.000
.(100
.000
700
800
900
1000
17.158
19.255
20.690
21.732
22.528
23.155
49.89
55.31
59.83
63.71
67. 11
70.14
32.73
36.06
39.14
41.98
44.58
46.98
30. OS
29.48
29.14
28.94
28.83
28.78
.000
.ooo
.ooo
.000
.ooo
.ooo
.000
000
.ooo
.ooo
.000
.000
.000
.ooo
.ooo
.000
.ooo
.ooo
1100
1200
1300
1400
1500
1600
1618
23.665
24.089
24.447
24.754
25.018
25.247
25.285
72.89
75.39
77.69
79.82
81.80
83.65
83.97
49.22
51.30
53.24
55.07
56.78
58.40
58.68
28.76
28.75
28.74
28.73
28.71
28.67
28.65
.ooo
.ooo
.ooo
.000
000
000
.000
.000
.ooo
.000
.ooo
000
.000
.000
.000
.ooo
.000
000
.000
.000
.000
1700
1800
110.757
105.761
114.96
176.15
64.20
70.39
20.81
20.82
.000
.000
.ooo
.000
000
.000
400
453.70
-------------------------------------------------------------------------------.000
453.70
15.874
47.38
31. 51
30.44
.000
.000
500
bOO
-------------------------------------------------------------------------------1618
115.245
173.93
.000
58.68
.000
.000
20.80
ftELTING POIIIT
BOI LI IIG POINT
1618
3. 000 kJ
ENTHALPY OF VAPOBIZATIOII
145.554 kJ
4. 632 kJ
ftOLAR VOLUftE
1. 3017 J/bar
13.017 ca 3
453.70 K
-38.655 + 6.7350x1o-z T
B.5537x10Z T-os
298- 453.70 K)
5. 5142x105 T-Z
11.835 + 9.1183x10-3 T
2.2265l[10-6 TZ
EQUATION VALID FBOft 453.70- 1618 K)
REFERENCE
107
35
COIIPILED
5-12-76
70
T HERIIODY NAIUC PROPERTIES OF IIlii ERALS
LUTETI Ull (REFERENCE STATE)
Lu:
FORIIULA WEIGHT
174.97(1
Hexagonal close packed crystals 298.15 to 11eltinq point 1936 K.
-------------------------------------------------------------------------------l'ORIIATIOII FRO II THE ELE liE !ITS

TEIIP.
H;-H~ 98 )/T
J/molK
So
T
J/molK
-(G;-H~ 98 )/T
J/olK
CD
ENTHALPY
J/aolK
GIBBS
FREE ENERGY
kJ/mol
Log Kf
kJ/mol
-------------------------------------------------------------------------------298.15
o. 000
5(1.96
50.96
26.76
o.ooo
0.000
o.ouo
UNCERTAIIITY
o. 84
o. 84
400
500
600
700
800
900
1ouo
6.830
10.844
13.550
15.536
17.097
18.39B
19.533
58.84
64.84
69.78
74.01
77.75
81. 14
84.28
52.01
54 .oo
56.23
58.47
60.65
62.74
64.75
26.86
26.96
27.23
27.71
28.38
29.24
30.29
000
.ooo
.uoo
.000
.000
.000
.ooo
000
.000
.ooo
.ooo
.000
.ooo
000
.000
.000
.000
.ooo
.uuo
.000
.ooo
1100
1200
1300
1400
1500
16(10
1700
1800
20.565
21.533
22.466
23.382
24.296
25.217
26.155
27.113
87.22
90.02
92.71
95.33
97.89
100.41
102.90
105.38
66.66
6a. 49
70.24
71.95
73.59
75.19
76.75
78.27
31.51
32.90
34. 45
36.17
38.04
40.07
42.25
44.58
.uuo
.000
.000
000
000
.000
.uoo
000
.ouo
.ooo
.ooo
.000
.000
.ouo
.000
.0(10
.uou
.000
.000
.000
.000
.000
.uoo
.000
!!ELTING POINT
1936
18.648 kJ
6.389 kJ
BOILING POINT
J66tl
355.910 ltJ
!lOLl R VOLUIIE
1. 7770 J/bar
17.770 ca 3
2.04J8I10Z T-05
17.027 + 7.0407x1U-6 TZ
(EQUATION VALID FROII 298- 18(10 K)
REFERENCE
1(17
107
COftPILED
4-17-76
IIAGliESIUII ( REl"BBEIICE STATE}
llg:
71
FOIIIU LA II BIGHT
Hexagonal close packed crystals 298.15 to melting point 922 K.

922 to boiling point 13&1 K.
24.305
Liquid
Ideal onatomic gas 13&1 to 1800 K.
-------------------------------------------------------------------------------FORIIATIOII FROII THE ELEIIEIITS

TEIIP.
( a;-H~ 98 )/T
JtolK
so
cop
-(G;-H~ 98 )/T
JtolK
J/olK
0.13
0. 1 J
40. 17
46.13
51.21
55.68
59.71
&3.Q1
64.41
33. &7
35.58
31.78
Q0.02
Q2.23
44.39
45.07
EIITHALPY
J/olK
GIBBS
FREE EIIEBGY
kJ/ol
Log Kf
ltJ/ol
-------------------------------------------------------------------------------298.15
2Q.8Q
o.ooo
32.68
32.68
o.ooo
0.000
0.000
UIICEBTAIITY
400
500
600
700
8uu
900
922
6.497
10.546
1J.Q33
15.&&1
17. Q79
19.02Q
19.338
26.15
27.31
28.45
29. 61
30.79
32.00
32.27
.000
.000
.ooo
000
000
:ouo
.ouu
.000
.oou
.000
000
.000
000
uuo
.000
.000
.000
.000
.000
.oou
.uoo
-------------------------------------------------------------------------------922
29.050
74.12
45.07
.000
32.64
.000
.000
1000
29.329
76.55
47.22
32.64
000
000
.ooo
1100
1200
1300
1361
29.629
29.880
30.092
30.2(16
79.66
82.50
85.11
86.37
50.03
52.62
55.02
56. 37
32.64
32.64
32.64
32.64
.ooo
.000
000
.000
.(100
.000
.ooo
.000
.000
.000
.000
1400
1500
1600
1700
1800
120.959
114.281
108.438
101.282
98.698
180.79
182.22
183.57
184.83
186.01
59. ill
67.94
75. 13
81.55
87.31
20.79
20.79
20.79
20.79
20.79
.000
.000
000
000
.000
.uoo
000
.000
.000
.000
.000
.ouo
.000
.000
.000
.(J(I(J
-------------------------------------------------------------------------------1361
123.678
180.20
5&.37
.ooo
.000
20.79
.000
liE LTI NG
POI IT
EKTHALPY OF IIELTING
u;98 -
SOILING PO Ill T
1361
8. 954 ltJ
127.421 kJ
5.000 ltJ
110LAB VOLUIIE
1 .3 996 Jftla r
13.996 cm 3
922
H~
TRAJSITIOJS I I REFERENCE STATE ELEIIENTS
HEAT CAPACITY EQUATIOMS
16.095 + 1.3795x1o-z T
REFEilENCB
107
107
1.1053x102 T-05
298 922 K}
COIIPILEO
4-10-76
72
FORIIULA IIEIGHT
MANGANESE (REFERENCE STATE)
Mn:
TEIIP.
54.938
Alpha crystals 298.15 to 98(J K.

Beta crystals 980 to 13&u K.
Gaa
crystals 1360 to 1410 K.
Delta crystals 1410 to melting point 1517 K.
Liquid 1517 to boiling point 2335 K.
H;-H~ 98
so
)/T
J/molK
-(G;-H~ 98 }/T
J/molK
J/molK
cop
FORIIATIOIII FBOII THE ELEIIEIITS

GIBBS
FREE ENERGY
Log Kf
ENTHALPY
JjmolK
kJ/mol
kJ/1101
-------------------------------------------------------------------------------0.000
298.15
0.000
32.01
32.01
0.000
o.ooo
26. 19
UNCERTAINTY
400
500
6.945
11.404
14.677
17.251
19.374
21. 173
22.349
f>OO
700
800
900
980
0.08
0.08
40.01
46.53
52.18
57.22
&1. 79
&5.98
69.05
33.07
35. 13
37.50
39.97
42.42
44.81
46.70
28.30
30. 1&
31.89
]]. 49
34.93
36.18
37.04
.ooo
.000
.000
.ooo
000
.ouo
.000
.000
.000
.000
.000
.000
.000
.ooo
.000
.000
.ooo
.000
.ooo
.000
.000
-------------------------------------------------------------------------------980
24.696
71.40
46.70
.ooo
.000
37. 59
.000
100(1
24.960
72.12
47. 16
37.68
.000
.000
.000
1100
1200
1300
1360
26.136
27.152
28.044
28.516
75.73
79.07
82. 17
84.01
49.59
51.92
54. 13
55.49
38.11
38. 54
38. 97
39. 15
00(1
.000
.000
.000
.ouo
.000
.ooo
.000
.000
.ooo
.ooo
.ooo
1400
1410
30.468
3 0. 5 61
86.75
87.07
56.28
56.51
43.43
43. 51
.OOu
.000
.ouo
.000
.000
.000
150(1
1517
32.716
32.1165
91.21
91.86
5il. 49
59.(JO
45.97
46. 11
000
000
.000
.000
.000
.000
1(>00
1700
1800
41.084
41.375
41.633
102. 1 J
104.92
107.55
&j. 05
6 J. 55
46.02
46.02
46.02
.OO(J
.000
000
(J(JO
.000
.ooo
.uoo
.oou
.000
-------------------------------------------------------------------------------1360
29.476
.000
84.97
55.49
42.41
.uuo
.ouo
-------------------------------------------------------------------------------1410
31.893
81:1.41
.000
.000
56.51
45.23
.000
-------------------------------------------------------------------------------1517
40.814
99.81
.000
.ooo
59.00
46.02
.000
65.92
1517
!\ELTING POINT
12.058 kJ
4.996 kJ
BOILING POINT
2335
EHTHlLPY OF VlPORIZATIOH
226.065 kJ
IIOLlR VOLUIIE
0. 7354 J/bar
7.354 ca 3
TRANSITIONS IN REFERENCE STATE ELE!IENTS
0
HEAT CAPACITY
EQUATIONS
cp
2. 7217x1os
r-z
c;
33.387 +
107
980 K)
980 -
1160 K)
4.29J6x10-3 T
( EQUlTIOH VALID FROII
REFERENCE
298 -
107
CO!! PILED
5-12-7o
73
PROPERTIES IT HIGH TEIIPEBlTUiBS
FORIIULl llilGHT
IIOLIBDEIIUII ( BEPEREICE STATE)
Ito:
95.940
Body-centered cubic crystals 298.15 to aeltiag point 2890 K.
-------------------------------------------------------------------------------PORIIlTIOI FROII THE ELEIIEMTS

TEIIP.
It
a;-a~ 98 )/T
Jtaollt
so
-(G;-a~ 98 )/T
Jtaollt
J/aol K
cop
EMTHlLPY
kJ/aol
J/aolK
GIBBS
FREE EIIERGY
Log Kf
kJtaol
-------------------------------------------------------------------------------o.ooo
298.15
28.66
o.ooo
o.ooo
o.ooo
28.66
24.02
0.21
0.21
400
500
600
700
800
900
1000
6.260
10.098
12.762
14.740
16.286
17.544
18.601
35.88
41.55
46.31
so. 41
54.03
57.28
60.24
29.62
31.45
33.55
35.67
37.74
39.74
41.64
25.07
25.79
26.36
26.87
27.36
27.85
28.38
000
.ooo
.ooo
.000
.ooo
.ooo
.ooo
.000
000
000
.ooo
.ooo
000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.ooo
1100
1200
1300
1400
1500
1600
1700
1800
19.515
20.324
21.058
21.736
22.372
22.978
23.564
24.136
62.97
65.51
67.90
70.17
72.32
74.39
76.39
78.32
43.46
45.19
46.84
48.43
49.95
51.41
52.83
54. 18
28.94
29.54
30.19
30.90
31.67
32.50
33.38
34.34
.ooo
.000
.ooo
.000
000
.ooo
.(100
.0(10
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.OCIO
.000
.ooo
.ooo
.ooo
.ooo
.ooo
UNCERTli IT!
IIELTIMG POIIT
EKTHlLP! OF ftELTIKG
2890
32. 540 tJ
4. 594 tJ
BOILIIIG POIIT
4912
EJTBlLP! OP VlPOBIZlTIOI
598.070 tJ
!lOLli VOLUIIE
0.9387 J/bar
9.387 ca 3
TRUSITIOIIS Ill REFEREICI STATE ELEIIEJTS
BElT CAPACITY EQUATIOI
34.139- 4.4926z1o-~ T
(EQUlTIOJ VALID PBOII
BEPEBEIIC!
107
107
J.7012z1o-
298 - 1800 It)
rz
COli PILED
4-23-76
74
THER!!ODYIAIUC PROPERTIES OF ftiiERlLS
NITROGEN ( BIPEREHCE STATE)
PORI!D LA If BIGHT
28.013
================================================================================
N2 :
Ideal diatoaic gas 298.15 to 180(1 11:.
-------------------------------------------------------------------------------PO Ill U' 10 N FROII THE ELEI!EITS

TEI!P.
J/aolK
II:
soT
a;-H~ 98 )/T
-(G;-H~ 98 )/T
J/aolK
J/aolK
cop
ENTHALPY
J/aolK
GIBBS
FREE EIIBBGY
ltJ/aol
Log
't
kJ/aol
-------------------------------------------------------------------------------2 98.15
o.ooo
191.61
0.000
o.ooo
191.61
29. 12
0.000
DNCERTAIIITY
0.02
0.02
400
500
600
700
800
900
1000
7.407
11.796
14.812
17.054
18.816
20.2 54
21.465
200.16
206.71
212.15
216.86
221.01
224.76
228.16
192.75
194.91
197.34
199.81
202.19
204.51
20o.69
29.15
29.60
30. 19
30.83
31.46
32.(17
32.65
1100
1200
1300
1400
1500
1600
170(1
1800
22.506
23.417
24.225
24.946
25.598
26.188
26.725
27.216
211.10
234.21
2 36.92
239.47
241.86
244.13
246.27
248.30
208.79
210.79
212.70
214.52
216.26
217.94
219.54
221.08
33.19
33.68
34.13
34.53
34.89
35.19
35.45
35.65
.000
.000
.ooo
.ooo
.ooo
.000
000
.000
.000
.ooo
.ooo
.ooo
000
.ooo
.oou
.000
.000
.000
.000
.ooo
.ooo
.ouu
.000
.0(10
000
000
.000
.000
.ooo
.OUII
.000
.000
.000
.000
.ooo
.uoo
.uoo
.ooo
000
000
.000
000
.000
.000
.ooo
ftELTI NG POI NT
63.14 K
BOlLI IIG POINT
77.35 II:
o. 720
5. 586 kJ
kJ
8.669 kJ
I!OLAR VOLUIIE
2478.9200 J;bar
i4789.2011 cal
23.941 +
1.1068x1o-z T
REFERENCE
107
24 7
35
247
2.5518x10- TZ
298 - 1800 K)
CO!! PILED
J-11-76
PBOPEBTIES IT HIGH TEllPEBATURES

SODIU! (BEPEBENCE STATE)
Na:
75
FOB!ULA WEIGHT
22.990
Body-centered cubic crystals 298.15 to melting point 37~.98 K. Liquid

370.98 to fictiYe boiling point 1175 K.
Ideal aonatoic gas 1175 to
1800 K.
The equilibrium boiliog point of the real gas is 1154 K.
-------------------------------------------------------------------------------FOB!ATIOII PROM THE ELE!EMTS

TEMP.
soT
( H;-H~ 98 )/T
J/ol K
-(c;;-H~ 98 )/T
cop
ENTHALPY
GIBBS
FREE ENERGY
kJ/aol
J/olK
J/olK
0.02
0.02
5.808
57.63
51.82
31.97
0~~
u~o
.000
67.15
711.07
79.57
811.13
88.01
91.111
911.45
52.96
5&.52
59.91
63.07
&5. 94
68.59
71.02
31.51
30.55
29.80
29.27
28.95
28.84
28.911
000
.ooo
.ooo
.ooo
600
700
800
900
1000
111.1 88
17.554
19.655
21.063
22.066
22.823
23.1128
.000
.000
000
1100
1175
23.943
211.295
97.23
99. 15
73.29
74.85
29.26
29.&5
105.5611
99.0113
9 3. 1153
88.609
84.370
80.630
182 .6&
184.32
185.86
187.30
188.611
189.90
191.09
17.10
85.28
92.111
98.&9
104. 27
109.27
113.78
20.79
20.79
20.79
20.79
20.79
20.90
20.79
J/olK
kJ/ol
Log Kf
-------------------------------------------------------------------------------298.15
o.ooo
0.000
o.ooo
51.30
51.30
28.23
o.ooo
UNCERTAINTY
370.98
-------------------------------------------------------------------------------370.98
12.811
64.63
51.82
31.84
000
.000
.000
400
50~
-~~0
.o~o
.o~o
.IJOO
.000
000
.ooo
-~0~
.000
.000
0~0
.000
.0~0
.~00
00~
.ooo
.000
000
.00~
.ooo
.000
.000
000
.0~0
000
000
.000
.ooo
.ooo
00~
.000
.ooo
.ooo
-------------------------------------------------------------------------------1175
107.367
.000
182.22
74.85
.000
20.79
.000
120~
1300
1110~
1500
1600
1700
1800
77.3~6
MELTING POI liT
BOlL IIIG POIHT
370. 98 K
ENTHALPY OP MELTING
.ooo
2. 598 kJ
6.1160 kJ
MOLAR VOLUIIE
1175
.000
.ooo
.ooo
.ooo
.ooo
.000
.000
97.610 kJ
2.3812 J/bar
23.812 c 3
TRl NSI TI OMS IN REFERENCE STATE ELEllEHTS

37.482 -
1.9183z1o-z T
(EQUATION VALID FROll

REFERENCE
107
35
1.06114x1o-s TZ
370.98 - 1175 K)
COli PILED
7-24-7&
76
TH!RIIODYiliUC PROPERTIES OP !IJIBlLS
POB!OLl IIBIGHT
HIOBIU!t ( BIPEBEICE STATE)
Hb:
92.906
Body-centered cubic crystals 298.15 to .. ltiog point 2740 K.
-------------------------------------------------------------------------------POB!ATIOI PBO!t THE ELE!EITS

TEI!P.
so
T
( H;-u; 98 )/T
J/aolK
-(G;-u; 98 )/T
J/aolK
J/aolK
cop
EITHlLPY
J/aolK
GIBBS
PBEB EIIBBGY
kJ/aol
Log
't
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
o.ooo
36.40
36.40
o.ooo
o.ooo
24.70
UNCERTAINTY
0.42
0.42
400
500
600
700
800
900
1000
6.387
10.244
12.890
14.840
16.152
17.573
18.591
43.71
49.49
54.26
58.34
61.94
65.16
68.08
37.38
39.25
41.37
43.50
45.59
47.59
49.49
25.42
25.91
26.33
26.74
27.14
27.55
27.96
.000
000
.000
000
000
.ooo
.000
.ooo
.ooo
.000
000
.ooo
.000
.ooo
.000
.ooo
.000
.ooo
.ooo
.000
.000
1100
12ou
1300
1400
1500
1600
1700
1800
19.461
20.221
20.896
21.505
22.061
22.575
23.054
23.503
70.17
73.25
75.58
77.76
79.81
81.71
83.63
85.41
51.31
53.03
54.68
56.26
57.75
59. 19
60.58
61.91
28.37
28.79
29.21
29.63
30.06
30.50
30.93
31.37
.000
.ooo
.000
.ooo
.000
000
.000
.000
.000
.000
.000
.uoo
.000
.ooo
.000
.ooo
.000
.000
.000
.ooo
.000
.ooo
000
.000
liE LT I NG
2740
POI NT
26. 368 kJ
5. 251 kJ
BOlLI IIG POINT
5017
682.004 kJ
IIOLAB VOLUI!E
1.0828 J~ar
10.828 ca 3
TRANSI TIOHS Ul REFERENCE STATE ELEitENTS
HEAT CAPACITY I')JUATION
21.778 +
4.6709x1o-~
( I')JUATION VALID PBO!t
REFERENCE
107
107
51.793 T-os
298 - 1800 K)
COIIPILBD
4-17-76
77
PROPERTIES AT HIGH TEIIPEBATUBES
NEODYIIIUII (REFERENCE STATE)
Nd:
FOBIIULA WEIGHT
144.240
Alpha crystals (double hexagonal close packed) 298.15 to 1128 K.

Beta
crystals (body-centered cubic) 1128 to melting point 1289 K.
Liquid
1298 to 1800 K.
-------------------------------------------------------------------------------FOBIIATION FBOII THE ELE!H!NTS

T!IIP.
H;-B~ga )/T
J/aolK
so
-(G;-u~ 9 a)/T
J/aolK
J/aolK
4.18
4. 18
cop
ENTHALPY
J/IIOlK
GIBBS
FREE ENERGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
0.000
71.09
27.45
71.09
o.ooo
o.ooo
0.000
UIICERT llHTY
400
500
600
700
800
900
1000
7.147
11.616
14.872
17.471
19.696
21.700
23.576
79.33
85.90
91.58
96.67
101.38
105.82
110.08
72. 18
H.28
76.71
79.20
81.68
84.12
86.50
28.74
30.28
32.07
34. 13
36.45
39. OS
41.93
.ooo
000
000
.000
000
.000
.ooo
000
.OO(J
.000
.000
.ooo
.000
.000
.000
.(100
110(1
1128
25.386
25.890
114.22
115.35
88.83
89.45
45.09
45.98
000
.ooo
.000
.000
.000
.000
1200
1289
29.537
30.546
120.82
118.44
91.28
87.89
44.56
44. 56
.000
.000
000
.(J(I(J
.(J(I(I
1300
1400
1500
1600
1700
1800
36.195
37.094
37.874
38.556
39.158
39.692
124.93
133.55
136.91
140.06
143.02
145.81
88.74
96.46
99.04
101.50
103.86
106. 12
48.78
48.78
48.78
48.78
48.78
48.78
.ooo
.000
.000
.000
.000
.000
.OCI(J
.000
.000
.000
.ooo
-------------------------------------------------------------------------------1128
28.576
118.03
89.45
44.56
.0(10
.(100
.000
.ooo
-------------------------------------------------------------------------------1289
36.087
123.98
87.89
48.78
000
000
.000
I!! LTI NG POI NT
BOlLING POIIIT
3341
7.142 .k.J
273.040 kJ
7.134 kJ
IIOLAB VOLUI!E
2.0570 J/tlar
2(1.57(1 ca 3
1289
ENTHALPY OF !ELTING
.ooo
.000
.000
.00(1
.000
.000
.000
.000
000
.000
.0(10
000
TBliiSITIOIIS Ill REFEBEIICE STATE !LE!I!NTS
61.399 T-os
29.171 + 1.4652x1o-s T2
( EQUATIOH VALID l"BOII 298 - 1128 K)
BEl"BBEIICE
107
107
COli PILED
4-26-76
18
THEa!IODYillllC PaOPERTUS OP ll.IIEBALS
IEOI ( REPEBBICE STATE)
le:
POBIIULl WEIGHT
2 0.119
Ideal gas 298.15 to 1800 K.
-------------------------------------------------------------------------------POB!IATIOI PRO!! THE ELEIIBIITS

TEIIP.
H;-H~98 )/T
J/aolK
so
-(G;-H~ 98 )/T
JjaolK
JjaolK
cop
EITHALPY
J/aol K
GIBBS
PBBE EIBBGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------0.0(1(1
0.0(10
298. 1 5
o.ooo
146.32
o.ouo
146.32
20.79
UICEBTli NTY
0.02
0.02
400
500
600
100
800
900
1000
5.292
8.394
10.460
11.930
13.039
13.900
14.590
152.42
151.06
160.85
164.06
166.83
169.28
111.47
147.13
148.61
150.39
152.13
153.80
155.38
156.88
20.79
20.79
20.79
20.19
20.19
20.79
20.79
1100
1200
1300
1400
1500
1600
1100
1800
15.154
15.620
16.018
16.359
16.655
16.914
17.139
17.343
113.36
175.26
116.86
118.47
179.85
181.24
182.47
183.69
158.21
159.64
160.84
162. 11
163.20
164.33
165.33
166.35
20.79
20.79
20.19
20.79
2(1. 79
20.79
20.79
20.79
.ooo
.000
.000
.000
.000
.ooo
.ooo
.ooo
.ooo
000
.000
000
.ooo
.000
.ooo
IIELTIIIG POINT
24.55 K
BOIL.ING POIIIT
EIITHALPY OP !!ELTING
o. 331
EIITHALPY OF VAPORIZATION
kJ
6.197 .kJ
IIOLAB VOLUIIE
.000
000
000
.ooo
.uoo
.ooo
.000
.oou
.00(1
.000
.000
.ooo
.(100
.ouu
.ooo
.000
.ooo
.0(10
.ooo
.ooo
.ooo
.ooo
.uoo
.oou
.000
.000
.000
.000
.000
.uoo
kJ
2478.9200 J/bar
24789.200 CIDJ
TBANSITIOIIIS 1111 REFERENCE STATE ELE!IEIIITS
REFERENCE
107
107
COilPILED
3-11-76
PROPERTIES A7' HIGH TE!!PERATURES
!IIICKEL ( REFEREIICE STATE)
79
PORI!ULA WEIGHT
58.7 00
================================================================================
Ni:
Face-centered Curie crystals (aagnetic) to Curie point 631 K.

Nonaagnetic 631 to aelting point 1726 K.
-------------------------------------------------------------------------------l'OR!!ATIOII FRO!! THE EI..EI!ENTS

TE!!P.
( H;-a; 98 )/T
J/IIOlK
s,
0
-( G;-H~ 98 )/T
J/aolK
J/aolK
cop
ENTHALPY
J/aol K
GIBBS
PBEE EIIIERGY
ltJ/aol
Log Kf
ltJ/aol
-------------------------------------------------------------------------------298. 15
0.000
29.87
29.87
26.06
0.000
o.ooo
o.ouo
UNCERTAINTY
0.08
0. 08
40(J
500
600
631
700
800
900
1000
6.962
11.484
15.022
16.066
17.614
19.274
20.622
21.804
37.89
44.48
50.43
52.30
55.56
59.68
63.38
66.80
30.93
33.00
15.41
36.23
37.95
40.41
42.76
45.00
28.45
30.88
34.89
38.91
31.01
31.00
31.89
33.00
1100
1200
1300
1400
1500
1600
1700
1726
22.872
23.842
211.723
25.517
26.227
26.856
27.409
27.535
69.99
73.00
75.82
78.118
80.97
83.31
85.51
86.19
47. 12
49.16
51. 10
52.96
54.74
56.45
58.10
58.66
37.879
98.12
60.25
000
.ooo
000
.000
.000
.ooo
.000
000
.000
000
.000
.ooo
.000
.000
.ooo
34.06
311.911
35.60
36.03
36.26
36.30
36. 18
36.19
000
.000
000
000
000
.OI'JO
000
.000
.ooo
43.10
.000
.ooo
.ooo
.ooo
.ooo
.000
.ooo
000
000
.000
.000
.000
.000
.000
.O(JO
000
.ooo
.ooo
.000
.000
.uoo
.ooo
.ooo
000
.000
000
.ooo
-------------------------------------------------------------------------------1726
37.658
96.32
58.66
113.10
.000
.ooo
.000
1800
!!ELTING POI NT
1726
17.472 ltJ
4.786 ltJ
BOlLING POINT
3187
370.380 kJ
!lOLli VOLUIU:
0.6588 J/l;>ar
6.588 ca 3
TRAIISITIONS Ill REFERENCE STATE ELEI!ENTS
1.5135x102 0.20499 T
( EQUATION VALID FRO!!
3.0548x102 -
7.0339x1o-z T
2. 5697x107 T-z
(EQUATION VALID FBOft
REPEREIICE
107
1. 7 4111t 1 0- T2
298 631 K)
107
631 - 1726 K)
CO!!PILED
5-11-76
THER!ODYRA!IC PROPERTIES OF !IIEBALS
80
FOI!U LA II EIGHT
OIYGER ( REFBBERCE STATE)
02
Ideal diatomic gas 29B.15 to 1BOO
31.999
K.
-------------------------------------------------------------------------------POBUTIOR PRO! THE ELEI!ERTS

TEI!P.
so
-(G;-a~ 9 B)/T
J/aolK
J/aolK
0.04
0.04
< a;-a~ 9 B )/T

J;aolK
cop
EBTHALPY
J/aolK
GIBBS
PIE! EIERGY
kJ/aol
Log 't
kJ/aol
-------------------------------------------------------------------------------o.ooo
o.ooo
29B.15
o.ooo
205.15
205. 15
29.37
0.000
UNCERT AIRTY
311.82
.0(10
.000
.000
.ooo
000
.00(1
.ooo
.ooo
.(100
.ooo
.000
.000
.0(10
.(100
.ooo
.000
.000
.000
.ooo
.000
.(100
35.29
35.69
36.05
36.36
36.64
36. B9
37.11
37.31
.ooo
.0(10
.(100
.00(1
.ooo
000
.000
000
000
.000
.000
.ooo
.(100
.ooo
.ooo
.ooo
.ooo
.ooo
.0(10
.000
.ooo
.ooo
.ooo
.000
400
500
600
700
BOO
90(1
1000
7.560
12.176
15.420
17. B67
19.799
21.376
22.694
213. B7
220.70
226.47
231.4B
235.93
239.94
243. sa
206. 31
20B. 52
211.05
211.61
216.13
218.56
220.89
30.13
31. 16
32.12
32.95
33.67
34.29
1100
1200
1300
1400
1500
1600
1700
1800
23. B1B
24.792
25.644
26.399
27.072
27.67B
2B. 226
2B. 726
246.92
250.01
252.88
255.56
2SB.OB
260.45
262.69
264.82
223. 10
225.22
227.24
229.16
231.01
232.77
234. 46
236.09
liE LTI
NG POI NT
ENTHALPY OF !ELTING
54.35 K
BOILING POINT
9(1. 1B K
o. 444 kJ
6.816 kJ
B. 6B2 kJ
IIOLAR VOLUIIE
2478.9200 J,lbar
247B9.200 cal

4B.31B - 6.9132xlo- T
{EQUATION VALID PROI!
REFE BE liCE
107
35
4.2066x102 T-OS
29B - 1BOO K)
CO!PILED
3-11-76
81
PROPERTIES 11' HIGH TE!PEJUTUBES

OSIIIUII (RBPBR!IfCE STATE)
os:
FOB!ULA WEIGHT
190.200
Hezagonal close packed crystals 298.15 to 1800 K.
-------------------------------------------------------------------------------FOBIIATIOif FROII THE ELEIIEITS

TEIIP.
so
( H;-H; 98 )/T
J/aolK
-(~-H~ 98 )/T
J/aolK
J/aolK
0.06
0.06
cop
ElfTHALPI
J/aolK
GIBBS
FREE Elf!RGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------o.ooo
2 98.15
0.000
o.ooo
32.64
32.64
24.71
o.ooo
UICERTAIIfTt
400
500
600
700
800
900
1000
6.340
10.130
12.718
14.623
16.099
17.288
18.278
39.95
45.60
50.27
54.29
57.82
60.97
63.811
33.61
35.47
37.55
39.67
41.72
43.68
45.56
25.09
25.48
25.86
26.24
26.62
27.00
27.38
.ooo
.000
000
.ooo
000
.000
.ooo
.000
.ooo
000
.000
.ooo
.000
.ooo
.000
.ooo
.000
.000
.ooo
.000
.000
1100
1200
1300
1400
1500
1600
1700
1800
19.123
19.858
20.511
21.096
21.629
22.120
22.575
23.001
66.47
68.90
71.16
7 3. 29
75.30
77.20
79.01
80.74
47.35
49.04
50.65
52.19
53.67
55.08
56.44
57.74
27.76
28.14
28.52
28.90
29.28
29.66
30.05
30.113
000
.000
.ooo
.ooo
.ooo
.000
.000
.ooo
.000
.uoo
.000
.000
.000
.000
.000
.ooo
.ooo
.ooo
.000
.ooo
.ooo
IIELTIIfG POIIfT
ENTHALPY OF IIELTIIfG
3300
31.757 kJ
kJ
000
.000
.ooo
80 ILl IIIG POI NT
5285
ElfTHALPY OP VAPORIZATION
746.080 kJ
IIOLlR YOLUIIE
0.8423 J~ar
8.1123 ca 3
TRAISITIONS IN REPEREifCI! STATE ELEIIEITS
c;
23.571 + 3.808Jz1o-~ T
( EQUATIOII ULID PROII
REFERENCE
107
107
298 - 1800 K)
COil PILED
4-17-76
82
THER!lODY MAiliC PROPERTIES OF !liM ERALS
PHOSPHORUS (REFERENCE STATE)
P:
FOR!lULA IIEIGHT
Crystals (red tri9linic, v) 298.15 K to subliaation point 704 K.
3 0.974
Ideal
diatomic gas 70'+ to 1800 K.
-------------------------------------------------------------------------------l'ORilATIOM FROM THE EJ.EilE MTS

TEMP.
c u;-H~ 98 )/T
J/II01K
so
J/II01K
-(G;-u~ 98 )/T
J/II01K
co
ENTHALPY
GIBBS
FREE EIIIERGY
kJ/1101
J/1101 K
Log Kt
kJ/1101
-------------------------------------------------------------------------------298. 15
0.000
22.85
0.000
22.85
21.21
o.ooo
0.000
o.o8
o. 08
400
500
&00
700
704
5.&70
9.314
11.952
14.029
14.104
29.38
34.70
39.28
43. 3&
43.52
23.71
25.39
27.33
29.33
29.42
23. 16
24.51
25.79
27.19
27.25
.000
.ooo
.ooo
.000
.000
.000
.ooo
.ooo
.ooo
.ooo
.000
.ooo
000
.oou
800
900
1000
122.539
110.950
101.692
126.14
128.29
130.22
3.60
17.34
28.53
18. 18
18.31
18.41
.ooo
000
.ovo
.ooo
.000
uoo
.ooo
.000
.000
1100
1200
1300
1400
1500
1600
1700
1800
94.125
87.826
82.498
77.936
73.984
70.529
67.483
64.775
131.98
133.59
135.08
136.46
137.75
138.96
140.09
141.17
31.86
45.77
52.58
58.53
63.71
68.43
72.61
76. 39
18.50
18. 59
18.&8
18.78
18.90
19. OJ
19. 18
19.36
.000
000
.000
.ooo
.ooo
.000
000
.ooo
.ooo
.000
.ooo
.000
.ooo
.000
.000
000
.000
.ooo
.000
.000
.ooo
.ouo
.ooo
.ooo
UNCERTAINTY
.CICIO
-------------------------------------------------------------------------------704
136.781
123.83
000
-12.95
.000
.ooo
18.01
!!ELTING POINT
BOILING POIM T
ENTHALPY OF llELTI NG
kJ
J. 607 kJ
IIOLAR VOLUME
1. 7200 J/bar
17.200 c11 3
35.859 -
1.60J1x1o-z T
-2.0482x105 T-2
30.350 -
6.J500x10-3 T
1.1167x105 T-2
REFERENCE
107
107
298 -
704 K)
1. 8664x 1 o-
rz
704 - 1800 K)
COIIPILED
8-18-76
83
PIOPIHIBS l! HIGH TIIIPBBlTUBIS
LBlD ( BBPUIICI STl1'1)
Pb:
POIIIUI.l liBIGHT
race-ceutered cubic crystals 298.15 to aelting point 600.6 K.
2 07.2 00
Liguid
-------------------------------------------------------------------------------l'OIIIlTIOI PRO II THE ILBIIBITS

TBIIP.
a;-H~ 98 )/T
JjaolK
so
-(G;-u; 98 );T
J;aolK
J/aolJt
cop
BITHlLPI
J/aolK
GIBBS
IBBB BIBIGI
ltJ/aol
Log
't
ltJ;aol
-------------------------------------------------------------------------------298.15
o.ooo
65.06
26.61
o.ooo
65.06
o.ooo
0.000
UICEBTli IT I
400
500
600
600.6
6.872
11.070
14.033
14.088
0.112
0.112
72.99
79.20
84.46
85.14
66.12
68.13
70.43
71.06
27.40
28.33
29.39
29.110
.000
.000
.000
.ooo
.ooo
.000
.ooo
.ooo
.ooo
.000
.000
.000
-------------------------------------------------------------------------------600.6
22.078
93.13
.000
.000
71.06
30.58
.ooo
700
800
900
1000
23.233
24.1(15
211.743
25.220
97.14
101.17
1011.69
107.80
73.91
77.07
79.95
82.58
30.37
30.03
29.68
29.35
.000
.ooo
.000
.ooo
.ooo
000
.ooo
.ooo
.000
.000
.000
.ooo
1100
1200
1300
11100
1500
1600
1700
1800
25.584
25.866
26.090
26.273
26.1126
26.557
26.674
26.779
110.58
113.10
115. 41
117.53
119.50
121. 34
123.07
124.71
85.00
87.23
89.32
91.26
93.07
94.78
96.40
97.93
29.08
28.87
28.71
28.60
28.54
28.52
28. 55
28.60
.000
.000
.000
.000
.000
.000
000
.000
.ooo
.ooo
.000
.uoo
.ooo
.ooo
.ooo
000
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.000
.ooo
600.6
IIELTIIIG POIIT
ERTHALPY Ol' IIELTIIG
BOILIIG POIIT
2021
4.799 ltJ
EITHALPY OP VlPOBIZlTIOI
117.699 ltJ
6. 874 ltJ
!lOLli VOLUIIB
1.8267 J/bar
18.267 ca 3
TBliSITIOIS II RBPIBEICB STlTE BLEIIEITS
BElT CAPACITY BQUlTIOIS
13.743 + 1.5675x1o-z T
(BQUlTIOI VALID FBOII
c;
1.5920x10Z T-05
298 600.6 K)
5.J727x1o-:~ T
RBPBRBICB
8.3501x10Z r-o5
2.4248x106 T-z
( BQUlT 101 VlL ID PaOli 600. 60 - 1800 K)
107
107
COIIPILED
4-10-76
84
THERllODYIIliUC PROPERTIES or lliiiEBll.S
rORllULA WEIGHT
PALLADIUI! (REFERENCE STATE)
Pd:
106.400
Face-centered cubic crystals 298.15 to melting point 1825 K.
-------------------------------------------------------------------------------FORIIATION FROI! THE ELE!ENTS

TEI!P.
(H;-H~g 8 )/T
J/IIOlK
-(~-H~g 8 )/T
ST
J/aolK
J/IIOlK
0.21
o. 21
Co
p
ENTHALPY
J;aolK
GIBBS
FREE EIIERGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
o.ooo
o.ooo
37.82
37.82
o.ooo
25.93
UNCERTAINTY
400
500
600
700
800
900
1000
6.710
1 o. 774
13.575
15.647
17.260
18.569
19.665
45.56
51.59
56.61
60.94
64.75
68.17
71.28
38.85
40.82
43.04
45.29
47.49
49.&CJ
51.61
2&.73
27.32
27.83
28.32
28.79
29.28
29.79
1100
12CJCJ
1300
1400
1500
1600
1700
1800
2CJ.61(J
21.443
22.193
22.881
23.522
24.127
24.705
25. 26 3
74.15
76.81
79.31
81.67
83.91
86.05
88.11
90.09
53.54
ss. 37
57.12
58.79
60.39
61.92
63.41
64.83
30.33
30.90
31.51
32.15
32.84
33.57
34.34
35.1&
IIELTING POINT
ENTHALPY OF !ELTING
1825
17.560 kJ
5.469 kJ
.OOCJ
.ooo
.000
.ooo
000
.OCJO
.OOCJ
.000
.OCJO
OOCJ
.000
.ooo
000
.ooo
.000
.OCJCJ
.CJOO
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
000
.000
.000
.ooo
.ooo
.ooo
000
.000
000
.OCJO
.ooo
.ooo
.CJCJO
.OOCJ
.ooo
.ooo
.ooo
.ooo
.000
.ooo
BOILING POINT
3237
ENTHALPY or VAPORIZATION
357.510 kJ
I!OLA R VOLUME
0.8862 J/bar
8.862 CIIJ
31.6151.3625:~10-J T
REFERENCE
107
107
2.5427:~10-6
TZ
298- 1800 K)
COl! PILED
4-17-76
85
PIOPEBTIBS AT HIGH TBftPEIATOBBS
FOBftULl II EIGHT
PBASBODYIIIO! ( IEPBBDCE STUB)
Pr:
Alpha crystals (double laexagonal close packed) 298.15 to 1068 K.

crystals (body-centered cubic) 1068 to 1204 K.
140.908
Beta
-------------------------------------------------------------------------------FOBftlTIOIII FBO!t THE BLEil BITS

TEitP.
K
ca;-H; 98 )/T
J/aolK
-(~-H~ 98 )/T
so
T
J/aolK
J/llolK
co
EliiTRlLPJ
J/aol K
GIBBS
FREE EIEBGJ
kJ;aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
0.000
o.ooo
73.93
27.44
o. 000
o.ooo
73.93
OICERTAUTY
400
500
600
700
800
900
1000
1068
7.092
11.480
14.670
17.213
19.377
21.307
23.082
24.099
4.18
4.18
82. 11
88.58
94. 16
99.16
103.77
108.09
112. 21
114.85
75.02
77.10
79.49
81.95
84.39
86.78
89.13
90.75
28.37
29.77
31.50
33.41
35.62
37.88
40.24
41.90
91.49
93.92
94.26
38.45
38.45
38.45
.000
.000
.ooo
.000
000
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.000
.ooo
.000
.ooo
.ooo
.000
.ooo
.ooo
.ooo
.ooo
.000
.ooo
.000
-------------------------------------------------------------------------------1068
38.45
.ooo
.ooo
27.183
117.93
90.75
.000
1100
1200
1204
27.512
28.427
28.1163
119.00
122.35
122.73
.000
.000
.ooo
.000
.ooo
.000
.ooo
.ooo
.000
000
.ooo
.ooo
.ooo
.ooo
.ooo
.000
-------------------------------------------------------------------------------1204
34.183
128.45
.ooo
94.26
42.97
.ooo
.000
1300
1400
1500
1600
1700
1800
34.832
35.413
35.917
36.357
36.746
31.092
131.50
134.68
137.64
1110.42
143.0 2
145.48
IIELTIIG POIIT
EITHALPY OP llBLTIRG
96.67
99.27
101.72
104.06
106.27
108. 39
42.97
42.97
42.97
42.97
42.97
42.97
.ooo
.000
.000
.ooo
.000
.000
.000
.000
.ooo
.ooo
.000
BOlLI IG POI IT
3785
6.887 ltJ
EITHALPY OP VAPOBIZATIOI
296. 780 k.J
7.418 kJ
!lOLl B YOLUIIE
2.0800 J/bar
20.800 ca 3
1204
TRANSITIONS II REPERBICE STATE BLEitEHTS
c:
2.9291x10-Z T
3.5092x10Z T-os
(BQUATIOI VALID FRO! 298- 1068 K)
B.BPBBEICE
107
107
1.4325x105 T-z
COIIPILBD
4-26-76
THERI!ODYIIAIUC PROPERTIES OF I!IIIEBlLS
86
PLATINUI! (REFERENCE STATE)
Pt:
FOBI!ULA MEIGHT
195.090
Face-centered cubic crystals 298.15 to melting point 2042 K.
-------------------------------------------------------------------------------FOBIUTION P.BOI! THE El.EIIEITS

TEIIP.
so
-(G;-H~ 98 )/T
J/II01K
J/1101 K
( H;-a~ 98 )/T
J;ao1K
cop
EITHALPY
J/II01K
GIBBS
F.BEE EURGY
kJ/1101
Log Kf
kJ/1101
---------------------------------------------------------,---------------------298.15
o.ooo
41.63
41.63
25.81
0.000
o.ooo
u.ouu
UHCE BTU NTY
o. 21
0.21
400
500
600
700
800
900
1000
6. 665
10.684
13.450
15.4 97
17.097
18.400
19.494
49.32
55.29
60.26
64.54
68.32
71.71
74 .8o
42.65
44.61
46.81
49.04
51. 22
53. 31
55. 31
26.49
27.02
27.53
28.04
28.56
29.08
29. 61
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
000
000
000
.uou
.o.oo
000
.000
.000
.ooo
.00(1
.ooo
.uoo
.000
.ooo
1100
1200
1300
1400
1500
1600
1700
1800
20.439
21.270
22.015
22.691
21.313
23.891
24.431
24.941
77.65
80.30
82.77
85.11
87.32
89.42
91. 42
93.34
57. 21
59.03
60.76
62.42
64.01
65.53
66.99
68.40
30.15
30.69
31.22
31. 76
32.29
32.82
33.34
33.86
.ooo
000
.ooo
.ooo
000
.ooo
.ooo
.000
.ouo
.ooo
.ooo
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.000
I'IELTING POINT
2042
ENTHALPY OF KELTING
19.648 kJ
5. 724 kJ
BOILIMG POINT
4100
EHTHALPY 01 VlPOBIZATIOH
509.820 kJ
!lOLl B VOLUIIE
0.9091 J/bar
9.091 ca 3

20.046 +
7.4148x10-3 T
-1.2980x105 T-2

REFERENCE
107
107
298- 1800 K)
COIIPILED
4-17-76
PBOPUTIBS AT HIGH TEI!PBBATUBIS
PLUTONIUft ( BIPEBEHCI STATE)

Pu:
87
POBIIDLl lEIGHT
2114.002
Alpha crystals (onoclinic, siple) 298.15 to 395 K.

Beta crystals
(body-centered onocliDic) 395 to 1180 K. Gaaa crystals (face-centered
orthorhobic) 480 to 588 K. Delta crystals (face-centered cubic) 588 to
730 K.
Delta priae crystals {body-centered tetragonal) 730 to 753 K.
Epsilon crystals {bee) 753 to 913 K.
POBI!ATIOH PBOI THB BLBftBITS
GIBBS
IRTHALPY
PBEB BUlGY
TlftP.
K
J/olK
298.15
o.ooo
UHCERTli HTY
kJ/aol
51.46
8. 37
51.46
8.37
31.97
o.ooo
kJ/ol
o.ooo
o.ooo
395
8. 177
60.811
52.68
34.31
000
.ooo
.ooo
395
400
480
16.651
16.862
19.848
69.33
69.74
76.11
52.68
52.88
56.28
33.47
28.46
35.98
.ooo
.ooo
.000
.000
.ooo
.ooo
.000
.ooo
.ooo
480
500
588
21.068
21.632
24.037
77.32
78.74
84.85
56.28
57.11
60.84
34.73
35.69
39.75
.000
000
000
.000
.000
000
.000
588
600
700
730
24.962
25.215
26.993
27.431
85.77
86.52
92.34
93.93
60.84
61.31
65. 35
66.53
37.66
37.66
37.66
37.66
.ooo
.000
.000
000
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.ooo
.000
.000
.ooo
-------------------------------------------------------------------------------7 30
27.546
94.06
66.53
37.66
.ooo
000
.000
753
27.854
95.19
67.32
37.66
.000
000
.000
800
900
913
30.585
31.092
11. 162
99.74
1 03.89
104.86
69. 16
72.79
73.70
35. 15
35. 15
35.15
.ooo
.ooo
.000
000
000
.000
.000
.000
913
1000
34.278
34.936
107.98
111.29
73.70
76.35
41.84
41.84
.ooo
CJOO
.000
.000
.000
1100
1200
1300
1400
1500
1600
1700
1800
35.564
36.087
36.529
36.909
37.057
37.525
37.779
38.004
115.10
118.91
122.15
125.39
128.17
130.96
133.42
135.89
79.54
82.82
85.62
88.48
91.12
93.43
95.65
97.89
41.84
41.84
41.84
41.84
41.84
41.84
41.84
41.84
.000
.000
000
.ooo
.ooo
.ooo
.oou
.oou
.ooo
.ooo
.000
.000
.ooo
-------------------------------------------------------------------------------753
30.299
97.61
67.32
35.15
.ooo
.ooo
000
.OCJO
.ooo
.000
.000
.000
.ooo
.000
.ooo
.ooo
.ooo
(100
OOCJ
.000
-------------------------------------------------------------------------------ltELTI NG POI !IT

913
K
BOlLI IIG POI liT
3503
K
EIIT HALPY OF !!ELTIIIG
2.845 kJ
ENTHALPY OP VAPOBIZATIOII
343.670 kJ
8 ~98 - Ho0
6.485 kJ
IIOLAB VOLUitE
1.2040 J/bar
12.04(1 ca3
TBl HSI TI OilS IN REPERIHCE STATE ELEftlliTS
REPEBEHCE
107
107
COl! PILED
5-15-73
88
THEBIIODYUIIIC PBOPEBTIES OF IIIIIBBALS
FOBIIDLA IIBIGHT
RUBIDIUII ( BEP'BBBIICE STATE)
Rb:
Body-centered cubic 298.15 to aeltiag point 312.64 K.

85.468
Liquid 312.64 to
-------------------------------------------------------------------------------POBIIATIOII PBO! THE ELEIIEH'l'S

TEIIP.
K
H;-H~ 98 )/T
J/aolK
-( G;-H~ 98 )/T
so
cop
EIITHALPY
GIBBS
PBBB EIIEBGY
J/IIOlK
J/1101 K
o. 30
u.3o
1.472
78.28
76.80
32.40
000
.000
.000
400
500
600
700
800
900
959
13.977
17.610
19.818
21.257
22.2 52
22.988
23.341
93.59
100.77
106.40
111.01
114.92
118.31
120.1J
79.61
83. 16
86.58
89.75
92.67
95.32
96.79
32.88
31.45
30. 33
29.51
28.99
28.79
28.67
.ooo
.ouo
.ooo
.000
.000
000
.000
.ooo
.000
.ooo
.ooo
.000
.000
.(100
.uoo
.ooo
.00(1
.000
.000
.ooo
.OliO
1000
94.428
195.24
100.81
20.79
.000
.000
.ooo
1100
1200
1300
1400
1500
1600
1700
1800
87.735
82.156
77.435
73.389
69.88]
66.814
64.107
61.701
197.22
199.03
200.69
202.23
203.66
205.01
2(16.27
207.45
109.48
116. 87
123. 26
128.84
13l. 78
138.20
142.16
145.75
20.79
2U. 79
20.79
20.79
20.79
20.79
20.79
20.79
.uuu
.ouo
.000
.000
.000
.000
.000
.000
.ouu
.ooo
.uou
.000
.000
000
.(1(1(1
.ooo
.oou
.ooo
.uoo
.000
.000
.000
.uoo
.uou
J/1101 K
kJ/aol
Log Kf
kJ/1101
-------------------------------------------------------------------------------u.ooo
o.oou
298. 15
o.ooo
76.78
76.78
u.ouu
31.06
OIICERTli liT Y
312. 64
-------------------------------------------------------------------------------.(100
312.64
8.485
76.80
34.4(1
.ouu
.000
85.30
-------------------------------------------------------------------------------.0(1(1
.0(1(1
.oou
959
97.577
194.37
96.79
20.79
BOILIIIG POIIIT
959
2.192 kJ
71.192 kJ
7. 489 kJ
IIOLAB VOLUilE
312.64 K
IIELT IIIG POIIIT

EIITHALPY OF IIELTIIIG
5. 5850 J/bar
55.850 c11 3
TBANSITIOIIS Ill RBFERBIICB STATE ELE!EI!ITS
c~
41.678-
2.8113x1u-z T
(EQUATIOII VALID FRO!
REFERENCE
107
35
1.5J20x1o-s TZ
312.64 959 K)
COIIPILED
4-1 o-76
89
PROPERTIES AT HIGH TEftPEBATURES
BHEIIUft (BEFEREICE STATE)
Be:
FOII!ULA li.BIGIIT
186.2u7
Hexagonal close packed crystals 298.15 to 1800 K.
-------------------------------------------------------------------------------POBUTIOI FBOft THE EL!IIEITS

TEI'IP.
It
<H;-a; 98 )/T
J/olK
so
-(G;-H~ 98 )/T
cop
J/molK
J/ol K
J/ol K
EITHALPY
ltJ/ol
GIBBS
FREE ! I ERG!
Log ltf
ltJ/ol
-------------------------------------------------------------------------------298.15
0.000
36.53
36.53
25.16
o.ooo
0.000
0.000
o. 38
0.38
400
500
600
100
800
900
1000
6.510
10.450
13.168
15.183
16.757
18.01l1
19.121
44.04
4 9.88
Sll.76
58.96
62.67
66.01
69.01l
37.53
39.43
ll1.59
ll3.18
ll5.91
ll1. 91
ll9.92
25.92
26.49
27.01
27.53
28.05
28.57
29. 10
.ooo
.ooo
.ooo
1100
"200
1300
lllOO
1500
1600
1700
1800
20.052
20.873
21.609
22.280
22.898
2l.ll73
21l.011l
21l.526
71.81l
11l. 41l
76.88
79.18
81.35
83.43
85.41
87.31
51.79
53.57
55.27
56.90
58.1l5
59.96
61.40
62.78
29.63
30. 17
30.72
31.27
31.83
32.38
32. 91l
33. 51
.ooo
UICERTAI IT!
!ELTING POIIT
EITHALP! OF ftELTI IIG
Jll53
33. 229 kJ
s. 355
kJ
.000
.000
.ooo
.ooo
000
.000
.ooo
000
.00(1
.ooo
.000
000
.000
.ooo
.(100
.000
.ooo
.000
.(100
.ooo
.ooo
.ooo
.ooo
.000
.000
.000
.0(10
.000
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.000
.000
.000
.ooo
.ooo
.ooo
BOILING PODT
5869
EITHALP! OF VAPOBIZATIOH
714.840 kJ
!lOLli VOLU!IE
0.8860 J/bar
8.860 ca 3
TBAISITIOIS IN REFEREICE STATE ELEftEITS
HEAT CAPACITY EQOATIOII
21.1l70 + 5.9728x10-3 T
(BQUATIOI VALID FBO!I
REFBBEICE
107
107
56.132 T-os
298- 1800 K)
CO!IPILID
4-17-76
90
THEBBODYJA!IC PROPERTIES OP KIHERALS

FORMULA WEIGHT
BHODIOK (REFERENCE STATE)
Rb:
102.906
Face-centered cubic crystals 298.15 to aelting point 2233 K.
-------------------------------------------------------------------------------POR!lATION FRO!l THE ELE!lEit'l'S

TEftP.
so
T
( H;-H;98 )/T
J/aolK
J/aolK
-(G;-u~ 98 )/T
J/aolK
cop
EJTHALPY
J/aolK
GIBBS
FREE EMERGY
kJ/aol
Log Kt
ltJ;aol
-------------------------------------------------------------------------------31.5ij
31.5ij
2ij.95
o.ooo
298. 15
o.ooo
o.ooo
0.000
OIICERTAI liT!
o. 21
0.21
800
900
1000
6.515
10.540
11.388
15.560
17.311
18.780
20.049
39.05
ij4.99
50.03
54. ij]
58.)8
61.97
65.29
32.53
34.45
36.6ij
38.87
41.07
43. 19
45.24
26. 15
27.14
28.11
29.(18
30.05
31.01
31.93
.ooo
.ooo
.000
.ooo
.00(1
000
.ooo
.000
.ooo
000
.ooo
.uuu
000
.000
.ooo
.000
.ooo
.(10(1
.ouo
.000
.ooo
1100
1200
1300
140(1
15(10
16(10
1700
1800
21.171
22.177
23.095
23.936
24. 714
25 ... 37
26.112
26.743
68.37
71.27
74.00
76.58
79.04
81. 38
83.61
85.76
ij7.20
49.09
50.91
52.64
54.33
55.94
57.50
59.02
32.113
33.68
H. ij9
35.25
35.96
36.61
37.20
37.73
.oou
.000
.000
.000
000
0(10
.0(10
.000
.ouo
uuo
.000
.ooo
.000
.(1(10
.uuo
.oou
.0(1(1
.000
.ooo
.000
.000
.ooo
.ouo
.ouo
400
500
600
100
22]]
BELTIIG POIIIT
EITHALPY OF ftELTIIIG
21.489 kJ
4. 92(1 ltJ
BOIL Ill G PO DIT
3970
EITHALPY OF VAPORIZATION
493.26(1 ltJ
ftOLAR VOLOBE
0. 8282 J/bar
11.282
ca 3
TRABSITIOBS IN REFERENCE STATE ELB!lEITS

8.9772 +
1.9571J:lo-z T
3.6535x10- TZ
-2. 5759x 105 T-z
(EQUATION VALID FROM

REFBREIICE
107
107
298 - 180(1 K)
COMPILED
4-17-76
91
PBOPEBT.U:s l1' HIGH TI!IPERATURES
FORMULA WEIGHT
BADON (BEFEBEIIICE STATE)
Rn:
222.000
-------------------------------------------------------------------------------FOBUTIOIII FBO!l THE ELE!lEITS

TEIIP.
K
H;-H~98 )/T
J/aolK
-(G;-H~ 9 a)/T
so
T
J/aolK
J/aolK
co
J/aol K
ENTHALPY
ltJ/aol
GIBBS
FBEE EIIIEBGY
Log Kf
ltJ/aol
-------------------------------------------------------------------------------0.000
0.000
298.15
o.ooo
176.23
176.23
20.79
0.000
o. 00
o.oo
400
500
600
700
800
900
1000
5.292
8.392
10.457
11.933
13.040
13.900
14.589
182.34
186.98
190.77
193.97
196.75
199.19
201.38
177.05
178.59
180.31
182.04
183.71
185. 29
186.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
000
.000
000
1100
1200
1300
1400
1500
1600
1700
1800
15.152
15.6 22
16.019
16.359
16.655
16.912
17.141
17.343
203.37
205. 17
206.84
208.38
209.81
211.15
212.41
213.60
188.22
1ij9. 55
190.82
19.2.02
193.16
194.24
195.27
196.26
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
.000
000
UIIICEBTAIHTY
!!ELTING POIIIIT
ENTHALPY OF MELTING
202
2. 887 kJ
kJ
.ooo
.000
.000
.000
.ooo
.000
000
.ooo
.ooo
.ooo
.ooo
.000
.000
.uoo
.ooo
.ooo
000
.000
.ooo
.ooo
000
000
.000
.ooo
BOILING POIHT
MOLAR VOLUME
.000
211
.000
.ooo
.000
.ooo
.ooo
.ooo
.000
.ooo
.ooo
.ooo
.000
.ooo
.ooo
.ooo
.ooo
16.405 .kJ
2478.9200 J/bar
24789.2 00 c 3
TRANSITIOIS IN REFEBENCE STATE ELE!lEITS
REFER ElliCE
107
107
CO!lPILED
4-17-76
THEBl!ODY IIAIIIC PROPERTIES OP l!IIIBBlLS
92
PORl!OLl WEIGHT
RUTHEIIIUII (REPEBEIICB STATE)
Ru:
101.070
Hexagonal close packed crystals 298. 15 to 1800 K.
-------------------------------------------------------------------------------POR!lTIOlll PRO! THE ELB!IEIITS

TEIIP.
so
T
(H;-H; 98 )/T
J/olK
J/aol K
-(a;-8; 98 )/T
JtaolK
co
p
EIITHlLPY
JtaolK
GIBBS
FREE EBEBGY
kJIol
Log Kf
kJ/aol
-------------------------------------------------------------------------------0.000
0.000
o.ooo
298.15
o.ooo
28.53
28.53
211.05
UNCERTAiliiTY
0.21
o. 21
1100
500
600
700
800
900
1000
6.155
9.8118
12.1100
111.307
15.812
17.056
18.115
35.63
111. 12
115.71
119.68
53.20
56.37
59.29
29.117
31.27
JJ. 31
35. 37
37.39
39.31
111.18
211.31
211.88
25.115
26.05
26.67
27.32
28.00
.ooo
.000
.000
.000
000
.000
.(1(10
.000
.ooo
.000
000
000
.000
.000
.ooo
.oull
.ooo
.000
.000
.ooo
.000
1100
120(1
1300
11100
1500
1600
1700
1800
19.046
19.883
20.651
21.367
22.0115
22.6911
23.322
23.936
61.99
64.52
66.91
69. 18
71.36
73.115
75.117
42.94
1111.64
46.26
47.81
119.32
50.76
52. 15
53.50
28.72
29.117
30.26
31.10
31.98
32.90
33.87
311.88
.000
.ooo
.000
.ooo
.ooo
.000
.000
000
.ooo
000
.ooo
.000
.(100
.000
.ooo
OQO
.000
.000
.OliO
.000
.ooo
.ooo
.000
.ooo
11.1111
IIELTI NG POI NT
2523
24. 280 kJ
4.602 kJ
80 ILI liiG PO lilT
4423
EIITHALPY OP VAPORIZATIOII
595.5110 kJ
I!OLlR VOLUIIE
0.8171 J11!ar
8.171 c 3
1.23&8x10Z T-os
29.062 + 2.6805x1o- TZ
(EQUATION VALID PRO!! 298 - 1800 K)
REFERENCE
107
107
COl! PILED
4-17-76
PROPERTIES AT HIGH TEIIPEBATURES

SULFUR (REFERENCE STATE)
S:
93
FORIIULA WEIGHT
32.0&0
Orthorho8bic crystals 298.15 to 3&8.54 K. llonoclinic crystals 368.54 to

aelting point 388.36 K. Liquid 388.36 to boiling point 716.9 K. Ideal
diatomic gas 716.9 to 1800 K.
-------------------------------------------------------------------------------FORIIATIOIII FROll THE ELEI!ENTS

TEftP.
so
-(~-H~ 98 )/T
cop
Jj8ol K
J/olK
J/olK
0.21
o. 21
( H;-u; 98 )/T
J/aolK
ENTHALPY
GIBBS
FREE EIIERGY
kJ/aol
Log Kt
k.J/801
-------------------------------------------------------------------------------298.15
31.80
0.000
o.ooo
31.80
22.72
0.000
0.000
UtiCERT AIIJTY
368.54
4.484
36.76
32.28
24.18
.000
.ooo
.000
388.36
6.561
39.75
33.19
25.33
.000
000
.000
11. f> 20
17.146
20.285
22.146
22.382
45.09
53.94
60.43
65.59
66.34
33.47
36.80
40. 14
43.45
43.96
32.27
38.05
34.33
32.61
32.19
.0(10
.ooo
.ooo
.ooo
.000
.000
.000
000
.000
800
900
1000
91.676
83.527
77.019
131. 27
133.44
135.38
39.59
49.91
58. 36
18.28
1 tl. 3 9
18.48
.ooo
.ooo
.000
.000
000
1100
1200
1300
1400
1500
1600
1100
1800
71.7 03
67.275
63.532
60.330
57.558
55. 132
52.994
51.096
137.14
138.76
140.26
141.64
142.93
144.14
145.28
146. 36
65.44
71.49
76.73
81. J 1
85. 37
89.01
92.29
95.26
18.56
18.62
18.67
18.70
18.74
18.78
18.80
18.83
.000
-------------------------------------------------------------------------------368.54
5.574
37.85
Mooo
32.28
24.74
000
.000
------------------------------------------------------------------------------388.36
44.17
.00(1
10.978
33.19
31.71
OCHI
.ooo
400
500
600
700
716.9
.ooo
.000
.000
.ooo
.ooo
.000
-------------------------------------------------------------------------------716.9
100.238
129.26
29.02
18.14
.ooo
.000
.ooo
IIELTIIIG POitiT
.ooo
.ooo
.000
000
.000
.000
.000
.000
.000
.000
.ooo
BOILIIIG POitiT
388. 36 K
ENTHALPY OF IIELTitiG
1.715 kJ
ENTHALPY OF VAPORIZATlOtl
H~98
4.410 kJ
ftOLlB VOLUIIE
H~
.000
.000
.ooo
.ooo
.ooa
.ooo
.000
.000
.000
.000
.000
.000
.ooo
.ooo
.ooo
.ooo
716.9
K
kJ
1.5511 J/bar
15.511 c 3
TRAtiSITIOtiS IN BEFEREICE STATE ELEI!EITS
HEAT CAPACITY EQOATIOR

23.535 -
1. 7230x10-ll T
3.4702x10-7 TZ
-1.1320x10 T-z

REFBBEICE
247
247
716.9 - 1800 K)
COIIPILED
5-24-76
94
THEBIIODYillliC PROPERTIES OF IHIEBlLS
Dll TOll IC SULFUR
S2
FOBIIU LA II EIGHT
64.120
Ideal diatoaic gas 298.15 to 1800 K.
-------------------------------------------------------------------------------I!'OBIIATIOII FBOII THE ELEIIEIITS

TEIIP.
so
H;-H~ 98 )/T
J/aolK
-(~-H~ 98 )/T
J/llolK
J/aolK
0.05
0.05
cop
EIITHALPY
J;aolK
GIBBS
FREE EIIEBGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
-13.920
o.ooo
228. 17
228. 17
128.490
79.453
32.46
UNCERTAINTY
0.500
400
500
600
700
8.492
13.720
17.340
20.004
237.96
245.68
252.14
257.69
229.47
231.96
234.80
237.69
34. 10
35.09
35.75
36.21
800
900
1000
22.051
23.677
24.998
262.55
266.87
270.75
240. 50
243. 19
245.75
36.55
36.79
36.98
1100
1200
1300
1400
1500
1600
1700
1800
26.095
27.019
27.809
28.492
29.089
29.616
30.084
30.503
274.29
277.52
280.51
283.28
2 85.86
288.28
290.56
292.71
248.20
250.50
252. 70
254.79
256.77
258.66
260.48
262.21
37.13
37.24
37.34
37.41
37.48
37.54
37.60
37.66
!!ELTING POINT
kJ
0.117
-------------------------------63.477
-8.289
122.591
118.204
114.552
111.489
49.306
35.780
22.938
-5.151
-3.115
-1.712
000
000
.ooo
.ooo
.ooo
.ooo
.ooo
.()()()
-------------------------------.ooo
.ooo
.ooo
.000
.ooo
.ooo
000
.ooo
.ooo
.000
.000
.000
.000
.000
.000
.000
.ooo
.ooo
000
000
.000
.000
.ooo
.ooo
.000
BOIL IMG PO lilT
kJ
IIOLAB VOLUIIE
9. 131 kJ
0.669
2478.9200 J/bar
24789.200 c11 3

SULFUR ORTHO-IIONO 368.54,
B. P. 7 16. 9 K.
II.
P. IIONO 388.36 1
47.069 -
3.4459x10-3 T
-2 .2639x10" T-z
REFERENCE
247
247
298 -
1800 K)
COIIPILED
8-12-76
PROPERTIES AT HIGH TE!IPERATURES
OCTA-ATOftlC SULFUR
S1
95
FORftULA iiEIGHT
256.480
Ideal octatomic gas 298.15 to 1800 IC.
-------------------------------------------------------------------------------FROll THE .ELEftEHTS

FORftATIO~
TEftP.
H~-H;9 8
so
}/T
J/molK
-(G;-H~ 98 }/T
J/molK
J/molK
1.67
1. 67
cop
ENTHALPY
J/molK
GIBBS
FREE E!IEIGY
kJ/mol
Log Kf
kJ/mol
-------------------------------------------------------------------------------298.15
48.836
-8.556
o.ooo
4 30. 32
156.04
430. 32
101.253
UNCERTAINTY
0.628
400
500
600
700
41.290
66.984
84.788
97.859
417.90
515.75
,547.44
574.61
436. 61
448.77
462.65
476. 75
166.86
172. 15
175. 23
111. 18
800
900
1000
107.861
115.763
122.164
598.36
6 19. 44
6 38.38
490. 50
50 3. 68
516.22
178.50
179. 42
180.09
1100
1200
1300
1400
1500
1600
1700
1800
127.454
131.897
135.682
138.943
141.783
144.279
146.489
148.459
655.56
6 7 1. 29
685.79
699.23
711.75
723.48
734.51
744.91
528.11
539.39
550. 11
560.29
569.97
579.20
588.02
596.45
180.513
180.95
181.23
181.46
181.64
181.78
181.91
182.02
!!ELTING POINT
0.920
0.161
--------------------------------4.402
33.707
80.585
66.161
54.758
45.738
.24.054
16.344
10.837
-2 .513
-1.423
-0.809
-395.952
-392.735
7.3u6
51.957
-0.424
-2.714
-389.532
-386.311
-383.097
-379.923
-376.768
-313. 589
-37(1. 436
-367.3(14
96.228
140.285
184.059
227.557
270.791
313.899
356.746
399.428
-4.570
-6.1(16
-7.396
-8.490
-9.430
-10.248
-10.962
-11.591
--------------------------------38.015
-399.186
2.482
BOILING POINT
kJ
ENTHALPY OF VA PORI ZAT ION
31.33(J kJ
KOLAR VOLUftE
kJ
2478.9200 J/bar
24789.200 cm 3

SULFUR
ORTH0-110110 368.54 1
B. P. 716.9 K.
II.
P. IIONO 388.36 1
2.0004x10Z -
6.4724x1Q-l T
-1.6260x 106 T-Z

REFERENCE
24 7
247
298 -
1.1897x1o- TZ
1800 K}
COIIPILED
8-12-76
96
THERIIODYIIAIUC PROPERTIES OF !liBERALS
AIITIIIOIIY (REFER EIICE STATE)
Sb:
FOBIIOL.A WEIGHT
Rhoabohedral crystals 298. 15 to
~~elting
point 904 K.
121.750
Liquid 904 to
1800 K.
-------------------------------------------------------------------------------FOBII.ATIOI PRO! THE BLBIIEHTS

TEIIP.
so
( a;-H~ 98 )/T
-(G;-a~ 98 )/T
J/aolK
J/olK
J/olK
cop
GIBBS
FREE EIIERGY
ENTHALPY
J/olK
kJ/ol
Log Kf
kJ/ol
-------------------------------------------------------------------------------2 98.15
o.ooo
45.52
45.52
25.26
o.ooo
o. 000
o.ooo
UNCERTAINTY
0.21
0.21
400
500
600
70(1
800
900
904
6.517
10.454
13.178
15.239
16.919
18.381
18.411
51.04
58.88
63.77
68.02
71.85
75.39
75.54
46.52
48.43
so. 59
52.78
54.93
57.01
57. 11
25.91
26.48
27.16
28.09
29.32
](I. 92
]0.99
.000
000
000
000
000
.ooo
.000
.000
.000
.000
.ooo
.000
.000
.ooo
.000
.000
.ooo
.000
.ooo
.000
.(100
1000
39.556
100.68
61. 12
31. 38
.000
.ooo
.ooo
1100
1200
1300
1400
1500
1600
1700
1800
38.813
38.193
37.669
37.220
36.831
16.490
36.189
35.922
101.67
106. 40
108.91
111.24
111.40
115.4]
117.33
119.12
64.86
68.21
71.24
74.02
76.57
78.94
81.14
81.20
11.38
11.38
31.38
11. 38
11. ]8
31. ]8
11.18
31.38
.0(10
.ooo
.ooo
.000
000
.000
000
.000
.ooo
.ooo
.000
.000
000
.000
.ooo
.000
000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
-------------------------------------------------------------------------------904
40.424
97.53
.000
.ooo
.ooo
57. 11
31.38
!!ELTING POINT
904
19.874 kJ
1860
BOILING POINT
EIITHALPY OF VlPORIZ.ATIOII
5.870 kJ
IIOLAR VOLUIIE
86.525 kJ
1. 8178 J/bar
18.178 c 3
TRAIISITIOIIS IN REFEREIICE STATE ELEIIBIITS
52.624-
3.2992x1o-z T
1.2617x1os r-z
REFERENCE
107
107
2. 4691x 10-5 TZ
298-
l. 6512x10Z T- os
904 K)
CO!PILED
4-13-76
97
PROPERTIES lT HIGH TEl!PEBlTORBS

FORMULA lf!IGHT
SCANDIUM (REFERENCE STATE)
SC:
44.956
Beta crystals
(body-centered cubic) 1608 to 1812 K.
-------------------------------------------------------------------------------FOBl!lTIOI FBOII THE EL.BIIEITS

TEIIP.
so
-(G;-u~ 98 )/T
cop
J/olK
J/ol K
J/ol K
o. 21
0.21
( H;- H~ 98 )IT
JjmolK
EITHlLPY
kJ/ol
GIBBS
FB.BE ENERGY
Log Kf
kJ/ol
-------------------------------------------------------------------------------o.ooo
298.15
311.611
311.611
25.115
O.CIOO
0.000
o.ooo
ONCEBTAIHTY
400
500
600
700
800
900
1000
6.592
10.588
13.353
15.1129
17.086
18.1178
19.695
112.211
48.17
53.12
57.112
61.25
611.711
67.96
35.65
37.58
39.77
111.99
1111.16
116.26
118.27
26.26
26.86
27.51
28.27
29.13
30. 11
31. 20
.ooo
.ooo
.ooo
.ooo
.ooo
.000
000
.000
000
.ooo
.ooo
.ooo
.000
.ooo
.000
.000
.ooo
.ooo
.ooo
.ooo
.ooo
1100
1200
1300
11100
1500
1600
1608
20.795
21.816
22.785
23. 71 9
211.633
25.536
25.6011
70.99
73.87
76.62
79.28
81.86
811.38
811.58
50.20
52.05
53.811
55.56
57.23
58.811
58.98
32.111
33.71
35.12
36.63
38.211
39.95
110.09
.000
.000
.ooo
.ooo
000
.000
.000
.ooo
.ooo
.CIOO
.OOCI
.000
.ooo
.000
.000
.000
.ooo
.ooo
.000
.ooo
.ooo
1700
1800
28.974
29.81 8
89.54
92.06
60.57
62.211
1111.22
44.22
.000
.000
.ooo
.000
.ooo
.ooo
-------------------------------------------------------------------------------.(100
.ooo
1608
28.105
87.08
58.98
1111.22
.000
ME LTI
1812
NG POI lilT
111.096 kJ
ENTHALPY OF MELTING
0
5.217kJ
H298 - Ho
BOlLING POINT
3104
ENTHALPY OP VAPOBIZATIOI
3111.190kJ
IIOLAR VOLUl!E
1. 5038 J/tla r
15.038 ca3
TRAHSITIOHS IN REFERENCE STATE ELEMENTS

17.1175
11.7392x10-3 T
-2.11760x105 T-z
( }XlUATIOII VALID FROM
REFERENCE
107
107
11.31118x1o-
rz
298 - 1608 K)
COII.PILBD
4-12-76
98
THERIIODYliAIHC PROPERTIES OF IIINERALS
FORIIU LA II EIGHT
SELEIIIUII ( REPEREHCE STATE)
Se:
Crystals 298.15 to elting point ij94 K.
78.960
Liquid 494 to boiling point
Ideal diatomic gas 957 to 1800 K.
957 K.
-------------------------------------------------------------------------------FORUTION FRO II THE ELEIIEIIITS

TEIIP.
(H;-H;98 )/T
J/aol K
so
cop
-( ~-H~98)/T
J/ol K
J/molK
EIITHJ.LPY
J/olK
GIBBS
FUE EIIERGY
lr.J/1101
Log Kf
ltJ/1101
-------------------------------------------------------------------------------0.000
0.000
298.15
o.ooo
42.27
0.000
42.27
25.06
UNCERTliHTY
0.05
0.05
400
494
6.556
10.446
49.826
55.51
43.27
45.06
2&.44
27.30
.ooo
500
600
700
2 3. 056
25.070
2&.339
27.214
27.917
28.305
68.38
74.79
80.03
84.48
88.43
90.50
45.32
49.72
53.&9
57.27
60.51
62.19
35. 85
34.37
33.54
33.2 9
33.93
311.78
000
000
000
000
.000
1000
81.481
147.29
65.81
19. 31
.ooo
000
.ooo
1100
1200
1300
1400
1500
1600
1700
1800
75.834
71.136
67.169
&3. 77&
60.843
58.283
56.028
54.031
19.41
19. 52
19.62
19.73
19.83
19.94
20.04
20.15
.ooo
.000
.uou
.uuo
.uuo
.000
000
.ooo
.000
000
.000
.000
.ooo
-------------------------------------------------------------------------------494
.000
22.906
67.97
000
000
45.06
35.95
BOO
900
957
.ooo
000
.000
.000
.000
.000
000
.ouo
. oou
.ooo
.ooo
.000
.ooo
-------------------------------------------------------------------------------957
146.44
000
.ooo
84.275
62. 19
19.27
000
149.13
150.82
162.39
153.84
155.21
156.49
157.70
158.85
I'IELTING POINT
73.30
79.68
85.22
90.06
94.37
98.21
101.67
104.82
.000
.ooo
.000
.ooo
.1100
.oou
.000
.000
.ooo
BOILING PODIT
957
6.159 lr.J
53.563 kJ
5. 519 kJ
!lOLl R VOLUIIE
494
.000
000
.000
000
.000
.000
000
1.6420
1&.420
Jjba~
c 3
TRAMSITIONS IN REFERENCE STATE ELEIIENTS
-4.5189x1oz +
0.67669 T
-2. 3u24x 1 u T- z
(EQUATION VALID FRO/I
l98 -
494 K)
2. 9520x 10- T2
2.6879x105 r-z
(EQUATION VALID FRO/I
REFERENCE
75
30
957 - 180(1 K)
COli PILED
4-30-76
PROPERTIES
SILICOB ( REFEii!IICI! ST lT E)
Si:
99
lT HIGH TEKPERlTURI!S
POBilULl
Crystals 298.15 to melting point 1685 K.
WEIGHT
28.086
-------------------------------------------------------------------------------FORIUTION FROK THE E.LEUNTS

TEKP.
so
<u;-u~98 )IT
JfolK
-( G;-H~ 98 )/T
JfolK
JjaolK
0.08
o. 08
cop
EHTHlLPY
J/aol K
GIBBS
FREE EHI!BGY
kJjmol
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
0.000
18.81
18.81
19.94
0.000
O.OCJO
o.ooo
UHCERTAIHTY
400
500
600
700
800
900
1000
5.385
8.880
11.393
13.303
14.815
16.047
17.075
25.01
30.10
34.47
38.29
41.68
44.73
4 7.50
19.62
21.22
23.08
24.99
26.87
28.68
30.43
22. 15
23.47
24.40
25.1(1
25.66
26. 13
26.52
1100
1200
1300
1400
1500
160(1
1685
17.950
18.705
19.367
19.952
20.475
20.946
21.312
50.04
52.40
54.58
56.62
58.54
60.35
61.81
32.09
33.70
35.21
36.67
38.06
39.40
40.5(1
26.86
27. 17
27.44
27.68
27.91
28.12
28.28
17(10
1800
51.085
49.664
92.03
93.49
40.95
43.83
25. 52
25.52
.000
OOCJ
.OOCJ
.OOCJ
OCJCJ
.000
.000
.OCJO
000
.000
.000
000
OOt.
.000
.ooo
000
000
000
.ooo
.000
.000
.000
.ooo
.OCJO
.CJOO
.OOCJ
.ooo
.ooo
.CJOO
000
.ooo
.000
000
.000
.ooo
.000
.ooo
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.ooo
.000
-------------------------------------------------------------------------------1685
51.312
91.81
40.50
.000
.ooo
.000
25.52
1685
KELTING POINT
ENTHALPY OF KELTING
50.551 kJ
3. 217 kJ
000
cOOO
BOILING POINT
3553
392.840 kJ
l'IOLAR VOLUl'IE
1. 2056 J/bar
12.056 cm 3
TRANSITIONS IN REFERENCE STATE ELEKENTS
31.778 +
5.3B78x10- T
(EQUATION VALID FROK
REFERENCE
107
107
1.7B64x102 T-o5
298 - 1685 K)
COl'IPILED
4-10-76
100
THERftODYIAftiC PROPERTIES OF ftiiEBALS
SAIIABIOI'I ( REFEREIICE STATE)
sa:
FOBftDLl WEIGHT
Alpha crystals (rhombohedral) 298.15 to 1190 K.

centered cubic) 1190 to aeltinq point 13~5 K.
150.~00
Beta crystals (bodyLiquid 13~5 to 1800 1(.
-------------------------------------------------------------------------------FOB.I'IATION FBOI'I THE ELEftEIITS

TEIIP.
(a;-a~ 98
J/mol K
-(co;-a~ 98 )/T
so
T
)/T
J/aolK
J;aolK
co
p
EITHALPY
JjaolK
GIBBS
FREE EIEBGY
kJ/aol
.Loq Kf
kJjaol
-------------------------------------------------------------------------------298.15
o.ooo
0.000
o.ooo
69.50
29.63
0.000
69.50
UNCERTAINTY
2.09
2.09
400
500
600
700
800
900
1000
7.900
13.426
17.745
21. 176
23.924
26.163
28.038
78.59
86.50
93.66
100.10
105. 86
111.05
115.78
10.69
13.01
75.91
78.92
81.94
8~. 89
87.74
33.20
37.68
40.75
42.58
43.66
44.47
45.36
.000
000
.000
000
.ooo
.ooo
.ooo
000
.000
.ooo
.uoo
1100
1190
29.667
30.899
120.16
123.79
90.49
92.89
46.63
48.27
.000
.000
.ooo
.ooo
.ooo
.ooo
1200
1300
1345
33.172
34.785
35.195
126.93
130.69
132.39
93.16
95.90
97.20
46.94
46.94
46.94
.000
.000
.000
.ooo
000
.ooo
000
.ooo
1400
1500
1600
1700
1800
41.941
42.493
42.975
43.1101
43.778
140.71
14~. 18
147.42
150.46
153.33
98.77
101.69
104.44
107. 06
109.55
50.21
50.21
50.21
50.21
50.21
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.000
.00(1
-------------------------------------------------------------------------------1190
.(100
33.662
126.55
.ooo
92.89
46.94
.ooo
.0(10
-------------------------------------------------------------------------------1345
41.603
138. 80
.ooo
.ooo
97.20
50.21
.000
.000
000
000
000
.000
.000
BOILING POINT
2064
8.619 kJ
166.405 kJ
1. 573 kJ
IIOLAR VOLDI!E
1.9980 Jft.?ar
19.980 ca 3
1345
!'!ELTING POINT
.ooo
TRANSITIONS IN REFERENCE STATE ELEI'IENTS
HEAT CAPACITY
EQUATIONS.
4.0750x102 -
0.23954 T
5.9178x10 T-z
(EQUATION VALID FBOI'I
REFERENCE
107
107
298 -
1190 K)
COftPI.LED
4-27-76
101
PROPERTIES AT HIGH TEI!PEBATORES
FOBIIULl WEIGHT
TIV ( BEFEREICE STATE)
Sn:
Crystals 298.15 to eltiDCJ point 505.1 K.
118.690
-------------------------------------------------------------------------------FOBI!lTION FBOI! THE ELE!IEIITS

TEI!P.
so
( H;-a; 98 )/T
-(G;-H~ 98 )/T
cop
EIITHALPY
GIBBS
FREE EIIERGY
J/olK
J/aolK
0.42
0.42
7.102
11.612
11.897
59.39
66.02
67.13
52.29
54.39
55.23
28.83
30.64
30.73
.ooo
600
700
800
900
1000
26.260
26.599
26.831
27.008
27.152
85.24
89.66
93.46
96.80
99.80
58.98
63.06
66.63
69.79
72.65
28.82
28.50
28.45
28.45
28.45
.000
.000
.000
.ooo
.ooo
.000
.000
.000
1100
1200
1300
11100
1500
1600
1100
1800
27.272
27.372
27.458
27.530
27.592
27.645
27.691
27.732
102.51
104.99
107.27
109. 38
111.35
113.18
114.90
116.53
75.24
77.62
79.81
81.85
83.76
85.53
87.21
88.80
28.45
28.45
28.115
28.45
28.115
28.45
28.45
28.115
.000
.000
000
.ooo
J/olK
J/olK
kJ/aol
Log Kf
kJ/ol
-------------------------------------------------------------------------------298.15
o.ooo
o.ooo
51.20
51. 20
26.99
o.ooo
o.ooo
0 ICEBT lliiTY
400
500
505.1
.000
.000
.000
.000
.000
.ooo
.000
.ooo
.ooo
.ooo
.ooo
ooo--
.000
.000
-------------------------------------------------------------------------------505.1
25.814
000
.000
81.04
55.23
.000
29.69
505.1 K
llELTliiG POIIIT
EIITHlLPY OF IIELTIIIG
.ooo
000
000
.ooo
.000
.ooo
.000
000
000
000
.ooo
.ooo
.000
.000
BOlLI IIG POI liT
.000
.000
2876
.000
.000
.000
.000
.000
7.029 kJ
EIITHlLPY OF VAPORIZlTIOII
295.770 kJ
6.322 kJ
IIOLlR VOLUIIE
1.6289 J/tlar
3
16.289
TRAIISITIONS Ill REFERENCE STATE ELEIIEHrS
5.0767x10- z T
6.0419 J: 104 T-Z
( EQOATIOII VALID FBOII
REFBBEIICE
107
107
298 -
505. 1 K)
COI!PILED
4-10-76
102
THERIIODY HAIUC PROPERTIES OF MIN EBALS
STBOIITIUII ( REl'EB EIICE STATE)
Sr:
FORIIULA WEIGHT
87.620
Alpha crystals (face-centered cubic) 298.15 to 828 K. Gamaa crystals

(body-centered cubic) 828 to melting point 1041 K. Liquid 1041 to
( H;-H~ 98 )/T
TEIIP.
J/aol K
-(G;-H~ 98 )/T
so
T
J/aol K
J/aolK
co
FORIIATIOII FRO!! THE ELEIIENTS

GIBBS
FREE ENERGY
Log Kf
ENTHALPY
J;aolK
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
55.40
55.40
0.000
0.000
29. 18
o. 000
UIICEBT Alii TY
(1.17
o. 17
400
500
600
700
800
828
7.020
11.468
14.730
17.353
19.620
19.970
63.49
70.01
75.67
80.76
85.50
86.83
56.47
58.54
60.94
63.41
65.88
66.86
28.41
30.12
32.02
34.22
36.82
37.63
900
1000
1041
22.444
23.966
24.503
90.83
94.79
96.44
68.39
70.82
71.93
37.66
37.66
37.66
1100
1200
1300
1400
1500
1600
1652
32.529
32.747
32.932
33.089
33.227
JJ.346
33.403
106.12
109.18
111.99
114.59
117.02
119.29
120.41
73.59
76.43
79.06
81.50
83.79
85.94
87 .oo
35. 15
35.15
35.15
35.15
35.15
35.15
35.15
1700
1800
113.621
108.468
203.81
205.01
90.19
96.54
20.82
20.82
.000
.000
.ooo
.000
000
. uoo
.ooo
.ooo
.ooo
.000
000
.000
.000
.000
.000
.ooo
.ouo
.(100
.000
000
.000
000
.ooo
.000
000
.000
.000
.000
.000
.ooo
.ooo
.ooo
.oou
-------------------------------------------------------------------------------828
21.121
87.98
66.86
37.66
.uoo
.000
.oou
.ooo
000
.000
.ooo
-------------------------------------------------------------------------------1041
32.381
104.31
71.93
.ouo
.uoo
35.15
.000
000
000
.ooo
000
.ooo
.ooo
.000
.ooo
.00(1
.0(10
.000
.000
.ooo
.ooo
.0(10
.0(10
-------------------------------------------------------------------------------1652
116.317
203.31
000
.ooo
87.00
20.82
.000
.ooo
-------------------------------------------------------------------------------LTI IIG POINT

1bS2
1041
K
K
BOILING POINT
liE
ENTHALPY OF II ELTING
H~98
Ho
0
8. 201 kJ
136.973 kJ
6.360 kJ
MOL.lli VOLUME
3. 39 21 J/bar
33.921 cm 3
63.451 -
3.4824x1o-z T
3. 1230x1os T-z
(EQUATION VALID FBOK
REFERENCE
107
124
298-
828 K)
COftPILED
5-11-76
PROPEBTIES AT HIGH TEliPERATDRES
FOR!IUL.l IIEIGHT
TANTALD! (REFERENCE STATE)
Ta:
1 OJ
180.948
Body-centered cubic crystals 298.15 to 1800 K.
-------------------------------------------------------------------------------lOR!IATION FRO II THE ELEilEIIITS

TEI'IP.
(u;-11; 98 )/T
J/aolK
-(G;-H~gg)/T
ST
J;aolK
J;aolK
0.17
0.17
Cp
EIITHALPY
J/mol K
GIBBS
FREE ENERGY
kJ;aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298. 15
0.000
41.51
41.51
0.0(10
0.000
o.ooo
25.36
UNCERTAIIITY
400
500
600
700
800
900
1000
6.547
10.464
13.120
15.051
16.529
17.7 OJ
18.667
49.06
511.89
59.7()
63.81
67.40
70.59
73.47
42.51
44.43
46.58
48.76
50.87
52.89
54.80
25.96
26.28
26.53
26.75
26.98
27.22
27.47
1100
1200
1300
1400
1500
1600
1700
1800
19.479
20.180
20.795
21.346
21. 84 7
22.307
22.737
23.142
76.10
78.53
80.78
82.90
84.89
86.77
88.57
90.28
56.&2
58.35
59.98
61.55
63.04
64.4&
65.83
67. 14
21.74
28.03
28.34
28.68
29.03
29.41
29.82
30.24
MELTING POI!IT
ENTHALPY OF !IELTING
3287
31.631 kJ
5.636 kJ
000
.000
.000
000
.ooo
.ooo
.0(10
.000
.000
000
000
.000
.ooo
.ooo
.uuo
.000
.000
.ooo
.ooo
.000
.000
.000
.ooo
.ooo
.ooo
.000
.000
.000
.000
.ooo
.ooo
.ooo
.uoo
.uoo
.{)00
.000
.000
.000
.000
.000
.ooo
.000
.oou
.000
.ooo
BOILING POINT
57]1
74 3. 130
j(J
!lOLA R VOLU!IE
1.0851 J/bar
10.851 CIIJ
TRANSITIONS IN REFERENCE STATE ELE!IEIITS
9.425..!x10" T-Z
26.354 +
1.2092x10-" TZ
(EQUATION VALID FROM 29tl - 1800 K)
REFERENCE
107
107
COl!PILED
4-17-76
1114
THERitOD!IAftiC PROPERTIES OF ltiiBBALS

FORMULA lEIGHT
TEBBIU!t (REFER BIICE STATE)

Tb:
158.925
Alpha crystals (aexagonal close packed) 298.15 to 1560 K. Beta crystals

(body-centered cubic) 1560 to melting poiat 1630 K. Liquid 1630 to
1800 K.
-------------------------------------------------------------------------------FORMATION FRO II THE ELEIIEHTS

so
T
( H;-a~ 98 )/T
TEIIP.
K
JtmolK
-(G;-a~ 98 )/T
J/olK
J/olK
cop
EIIITHALPY
Jtol K
kJtaol
GIBBS
FREE ENERGY
Log Kf
kJ/ol
-------------------------------------------------------------------------------11.000
o.ooo
298. 15
0.000
73.30
73.30
28.91
0.000
o. 84
0.84
400
500
600
700
800
900
1000
7.225
11.452
14.428
16.736
18.650
20.311
21.803
81.63
87.97
93.31
98.02
102.30
106.25
1 09.96
74.40
76.52
78.88
81.28
83.65
85.94
88. 16
28. 15
28.76
29.90
31.29
32.81
34. 41
36.06
1100
1200
1300
140(J
1500
1560
23.175
24.458
25.675
26.843
27.967
28.676
113.48
116.83
120.06
123.17
126.19
128.03
90.31
92.37
94.38
96.33
98.22
99.36
37.73
39.43
41. 14
42.86
44.60
45.64
.000
.000
000
.000
000
.000
1600
16 30
31.791
31.727
131.96
112 .sa
100. 17
100.86
27.74
27.74
1700
1HOO
38.682
39.113
141.08
143.76
102.40
104.65
46.48
46.48
UNCERTAINTY
.ooo
.OOCJ
.000
.OliO
.ooo
000
000
000
.000
.000
.ooo
.000
.ooo
.000
.000
.000
.000
.OCJO
.000
000
.ooo
.000
.ooo
.000
.1100
.OCJO
.000
.000
.000
.000
.000
.000
000
.000
.ooo
000
.000
.000
.ooo
.ooo
.ooo
-------------------------------------------------------------------------------.000
.000
1560
.000
31.895
131.26
99.36
27.74
.000
-------------------------------------------------------------------------------163(1
.000
.1100
.ooo
38.349
139.21
46.48
10CJ.86
IIELT UG POINT
ENTHALPY OF ltELTING
11~98
H~
.ooo
.000
.1100
BOILING POINT
3496
10.795kJ
ENTHALPY OF
330.1190 kJ
9. 426 kJ
!tOLAR VOLUitE
1630
VAPORIZAT~ON
1.9290 J/bar
19.290 ca 3
TRANSITIONS IN REFERENCE STlTE ELEIIENTS
HEAT CAPACITY EYUATION

17.894 + 1.7650x1o-z T
(EQUATION VALID FRO!t
RIP'ERBNCE
107
107
5.1149x105 T-z
298 - 1560 K)
COftPILED
7-29-76
105
PROPERTIES AT HIGH TE!!PEBATUR!S
T ELLU BIUII (REFERENCE STATE)
Te:
FOR!!ULA WEIGHT
1261 K.
127.600
Ideal diatomic gas 1261 to 1800 K.
----------------------------------------------------------~---------------------
TE!!P.
(H;-H~ 98
)/T
J/molK
-(G;-H~ 98 )/T
ST
J/mol K
J/molK
0.42
0.42
Cp
FOBIIATION FRO!! THE ELE!!EIIITS

GIBBS
Log Kf
EHTHALP I
FREE EMEBGY
J/110 1 K
kJ/1101
kJ/11101
-------------------------------------------------------------------------------2 98.15
0.000
49.50
49.50
0.000
0.000
0.000
25.70
UNCERTAINTY
400
500
600
700
723
6.830
11.272
14.602
17.297
17.866
57.37
63.85
69.54
74.69
76.22
50.54
52.58
54.94
57. 39
56.36
27.95
30. 15
32.36
34. 57
35.(17
.OCIO
.000
.000
000
.000
000
.CIOO
000
000
.ooo
800
900
1000
41.631
41.189
40.835
10 3. 83
108.27
112.23
62.20
67.08
71.39
37.66
31.66
37.66
000
.OCIO
000
000
.CIOO
000
.(100
.CIOiJ
.000
1100
1200
1261
40.546
40.305
40.117
115.82
119. 10
120.97
75.27
78.80
80.79
37.66
37.66
37.66
(J(J(J
.OCIO
000
.CIOO
.ooo
.CIOO
.000
.OCIO
.ooo
1300
78.256
161.46
83.20
18.66
.000
.000
.ooo
.ooo
.OOCI
.000
.000
.ooo
-------------------------------------------------------------------------------723
42.055
100.41
58.36
31.66
CIOO
.ooo
.OCIO
-------------------------------------------------------------------------------1261
80.099
160.89
80.79
18.66
.000
.000
.000
I'IELTIMG POINT
723
BOIL UIG POIHT
17.489 kJ
6. 121 kJ
IIOLA R VOLUME
1261
SCI. 341 kJ
..!.0476 J/bar
20.476 c111 3
c~
19.124 +
2.2061x1o-z T
REFERENCE
107
107
298-
723 K)
COIIPIL ED
8-06-76
106
THERIIODYNAIHC PROPERTIES OF IIIIIERALS
THORIUI! ( REFEREIICE STATE)
Th:
FORI'IULA WEIGHT
Alpha crystals (face-centered cubic) 298.15 to 1636 K.
232.038
Beta crystals
-------------------------------------------------------------------------------PORIIATION FRO II THE ELEIIE NTS

TEIIP.
so
( HT-H298 )/T
J/molK
-( G;-H~ 98 )/T
JfaolK
J;molK
Cp
ENTHALPY
J/mol K
GIBBS
FREE ENERGY
kJ/mol
Log Kf
kJ/1101
-------------------------------------------------------------------------------298. 15
o.ooo
53.39
53.39
o.ooo
o.uoo
o.uou
27.32
UNCERTAINTY
0.84
0.84
400
500
f>(J(J
700
1:100
900
1000
7.130
11.560
14.727
17.169
19.160
20.849
22.328
61.61
68.14
73.71
711.61
83.03
87.07
90.83
54.48
56.58
58.98
61.44
63.87
66.22
68. so
28.65
29.92
31.19
32.46
1100
1200
1300
14(/(J
150()
1600
1636
23.654
24.864
25.987
27.U4U
28.()37
28.99()
29.3()4
94.34
97.66
100.1:1.2
1 (13 .B4
1 ()6. 74
109.53
110.53
70.69
7.2.110
74.83
76.80
78.7()
8U.54
81.27
37.55
38.112
40.09
41.37
42.64
1636
1700
18UO
3 o. 997
31.562
32.366
112.27
113.95
116.58
81.27
82.39
114. 21
.000
.(J(J(J
.(J(J(J
.O(J(J
. 0()0
.000
.000
.000
000
.UO(J
.(J(J(J
.(JO(J
.ooo
000
.000
.000
.uuu
.(/(J(J
.ouo
.000
.ooo
44.38
.ouo
.000
.000
.000
000
.(J(J(J
.(J()(J
.(J(J(J
.uoo
.000
000
.000
.ooo
.oou
.ouo
.OO(J
.000
.000
.ooo
.ooo
.O(JO
46. 02
46.02
46.02
.00()
000
.000
.uou
.000
.000
.uuo
.000
.000
33.13
35. 00
36.27
ljj
.92
--------------------------------------------------------------------------------
!!ELTING POINT
20 28
16.120 kJ
6. 510 kJ
BOILING POINT
5061
51tt.460 kJ
IIOLAR VOLUIIE
1.9788 J/bar
19.7dll cm 3
23.317 1.2793x1o-z T
REFERENCE
107
107
5.i.i662 T-os
298- 1636 K)
COli FILED
4-15-76
107
PROPERTIES AT HIGH TE!IPEBATOBES
TITANIU!I (iEPBBENCE STATE)
Ti:
POB!IU LA II EIGHT
47.900
Beta crystals
(body-centered cubic) 1155 to aeltin<J point 19113 K.
-------------------------------------------------------------------------------POB!IATION FRO!! THE ELE!IENTS

TEIIP.
(H~-H; 98 )/T
J/aolK
-(G;-H~ 98 )/T
sT
J/aolK
J/aolK
0.08
0.08
Cp
ENTHALPY
J/aolK
GIBBS
P'BBE EMERGY
kJ/1101
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
30.63
30.63
25.02
0.000
o.ooo
0.000
UNCERTAINTY
400
500
600
700
800
900
1000
6.5115
10.6111
11.492
15.686
17. 454
18.938
20.226
38. 18
44. 17
49.25
53.70
57.68
61.31
611.66
31. 63
3J. 56
35.76
18.01
40. 21
42.37
44.43
26.35
27.39
28. 37
29.34
30.32
31.31
32.32
.000
.000
.000
.000
000
.OliO
.000
000
.000
.000
000
.liOll
000
.ooo
.ooo
.000
.000
.000
.liOO
.000
1100
1155
21.373
21.919
67.79
69.45
46.42
47.53
33. J5
33.92
.000
.OliO
000
.000
.000
.000
25.790
26.132
26.499
26.887
27.290
27.707
28.136
74.24
76.66
78.98
81.21
83.36
85.114
87.47
48.45
50. 53
52.48
54. 32
56.07
57.73
59. J3
29.72
30.75
31.79
32. 83
33.86
311. 90
35.94
.000
.000
.000
.000
.liOO
000
000
000
.uoo
.000
000
.000
000
.000
.ooo
-------------------------------------------------------------------------------1155
25.617
73.15
47.53
29.25
.000
.000
.000
1200
1300
1400
1500
1600
17ll0
1800
/IE LTI NG
POI NT
194]
15.447 kJ
ENTHALPY OF /!ELTING
0
4. 807 kJ
H298 - Ho
.ooo
.000
.000
.000
.000
.ouo
.ooo
BOI LIIIG POI NT
3562
ENTHALPY OF VAPORIZATIOII
421.031 kJ
MOLAR VOLU!IE
1.0631 Jf1lar
1(1.631 ca 3
TRANSITIONS IN REFERENCE STATE ELE!IENTS
11.208 +
1.1603x1o-z T
c~
1.18261:10Z T-OS
298 - 1155 K)
17.2711 + 1.0368x1o-z T
(EQUATION VALID FROM 1155- 1800 K)
REFERENCE
107
107
COMPILED
4-1ll-76
108
THERIIODYNAIUC PROPERTIES OF MINERALS
THALLIUM (REFERENCE STATE)
Tl:
TEMP.
FOR!ULl WEIGHT
204.370
Alpha crystals (he~agonal close packed} 298.15 to 507 K. Beta crystals

(body-centered cubic} 507 to melting point 577 K. Liquid 577 K to
1744 K.
so
u;-H~ 98 }/T
J/molK
-(G;-H~ 98 }/T
JjmolK
J/molK
0.21
0. 21
cop
FORftATIOii FROM THE ELEMENTS

GIBBS
Log Kf
ENTHALPY
FREE ENERGY
J/110 lK
kJ/1101
kJ/aol
-------------------------------------------------------------------------------2 98.15
64. 18
o.ooo
o.ooo
0.000
64. 18
0.000
26.33
UNCERTAINTY
400
500
507
6.827
11. 134
11.388
72.05
78.37
78.78
65.22
67.24
67.40
27.44
29.45
29.66
.ooo
.000
000
.ooo
.ooo
.ooo
.ooo
.uoo
.000
577
14.582
83.72
69.12
32.68
.ooo
.ooo
.ooo
600
700
800
900
1000
22.063
23.156
23.975
24.611
25.1.21
92.04
96.62
100.59
104.09
107.22
69. 98
7 3. 46
76.61
79. 48
82.10
29.71
29.71
29.71
29.71
29.71
.ooo
.ooo
.ooo
.ooo
000
.ooo
.ouo
.000
.ooo
000
.ooo
.ooo
.ooo
.ooo
.000
1100
12 00
1400
150U
1600
1700
1744
.15.538
25.885
26.119
26.431
26.649
26.841
27.009
27.077
110.05
112.64
115.01
117.22
119.26
121. 18
122.98
12 3. 77
84.51
86.76
88.83
90.79
92.61
94.34
95.97
96.70
29.71
29. 71
29 .,.1
29.71
29.71
29.71
29.71
29.71
000
000
000
000
.uou
000
.000
000
.ooo
.ooo
.ooo
000
.ooo
.ooo
.ooo
.ooo
.000
.000
.000
.000
.ooo
.ooo
.ooo
.000
1800
118.115
218.56
10().44
22.05
.oou
.ooo
.ooo
-------------------------------------------------------------------------------507
12.131
79.54
.ooo
.000
67.40
32.01
000
-------------------------------------------------------------------------------571
21.761
90.88
29.71
000
.ooo
69.12
.000
13UO
-------------------------------------------------------------------------------1744
121.200
217.90
96. 7(J
.ooo
000
.000
22.05
BOILING POINT
1744
4. 142 kJ
164.151 kJ
6.828 kJ
KOLAR VOLUitE
1. 7210 JA!ar
17.210 c 3
577
MELTING POINT
ENTHALPY OF KELTING
TRANSITIONS IN REFERENCE STATE ELEIIEMTS
HEAT CAPACITY
EQUATION
30.850 2.8925x1o-z T
( EQUATION VALID FRO II
REFERENCE
107
107
5.J134x1o-s TZ
298 507 K}
COlt PILED
4-30-76
PROPERTIES
AT
PORIIULA WEIGHT
THULIUII (REFERENCE STATE)
Tm:
He~:agonal
109
HIGH TEIIPEBATURES
168.934
close packed crystals 298.15 to Elting point 1816 K.
-------------------------------------------------------------------------------fORI! AT ION FROII THE ELEIIENTS

TEIIP.
K
so
<u;-H~ 96 )/T
J/molK
-(G;-H~ 98
J/IIOlK
J;molK
cop
)/T
J/mol K
ENTHALPY
Gl.BBS
FREE ENERGY
kJ/1101
Log Kf
kJ;mol
-------------------------------------------------------------------------------0.00(1
0.000
0.000
298.15
711.01
711.01
27. OJ
0.000
o.oo
o.oo
1100
500
600
700
600
900
1000
6.750
10.730
1 J. 506
15.627
17.3311
16.767
19.996
81.81
87.75
92.711
97. 11
101.02
104.58
107.85
75.06
77.02
79.23
81.118
83.69
85.81
87.85
26.39
26.97
27.86
28.81
29.75
30.65
31.51
.ooo
.ooo
.ooo
1100
1200
1300
11100
1500
1600
1700
1800
21.080
22.050
22.929
23.736
211.1180
25.1711
25.825
26.439
110.89
113.711
116.112
118.95
121.36
123.66
125.85
127.96
89.81
91.69
93.119
95.21
96.88
98.119
100.02
101.52
32.33
33.10
33.85
311.56
35.25
35.92
36.56
37.19
.000
UNCERTAINTY
1818
liE LTI NG POI liT

16.8111 kJ
7. 397 kJ
.000
.ooo
000
000
.000
000
.0(10
000
.uoo
.00(1
.ooo
.ooo
.ooo
.000
.000
000
.ooo
.ooo
.ooo
.000
000
.(100
.000
.000
.000
.ooo
.uoo
.000
.000
000
.ooo
.000
.000
.ooo
.ooo
.ooo
.ooo
.000
.ouo
.ooo
.ooo
BOILING POI NT
22211
190.670 kJ
IIOL AB VOL Ull E
1.8126 J;llar
18. 126 c11 3
TBAMSITIOMS IM REFEREIICE STATE ELEIIENTS
38.178 +
3.9669x1Q-:S T
( EQUATIOII VALID FROII
REFEilEIICE
107
107
3.8099xl02 T-os
298 - 1800 K)
COIIPILED
6- 9-76
110
THERIIODYUIUC PROPERTIES OF IUNERALS
URANIUII (REFERENCE STATE)
U:
FORIIULA WEIGHT
2JB.029
Alpha crystals ( orthorhoabic) 298.15 to 941 K.

Beta crystals (tetragonal)
941 to 1048 K.
Gaaaa crystals (body-centered cubic) 10411 to melting point
1405 K.
( H;-u~ 98 )/T
TEIIP.
J/aolK
so
J/mol K
-(G;-H~ 98 )/T
J/aolK
CD
FORIUTIOtl FRO!! THE ELEIIENTS

GIBBS
FREE ENERGY
Log Kf
ENTHALPY
J/aolK
kJ/aol
kJ/aol
-------------------------------------------------------------------------------2 98.15
0.000
0.000
0.000
50.29
50.29
0.000
27.68
UNCERTAINTY
o.
(1.13
13
400
500
600
70(1
800
900
941
7.297
12.000
15.557
18.527
21. 192
23.716
24.735
58.70
65.56
71.63
77.23
82.55
87.71
B9. 79
51. 40
53.56
56.07
5B.70
61.36
63.99
65.06
29.69
32.00
34.76
38.01
41.78
4&.09
48.01
1000
1048
28.59b
30.b08
95.38
98.88
66.78
b8.27
42.93
42.93
.000
000
1100
1200
1300
1400
1405
34.005
34.361
34.662
34.921
34.933
103.79
107.12
110.19
113.02
113. 36
69.79
72.76
75.53
78.10
78.43
38.28
38.28
38.28
38.28
38.28
.ooo
.oov
.(J()(J
.(J(I(J
.uoo
.ooo
1500
1600
1700
1800
41.434
41.839
42.195
42.513
122.36
125.45
128.35
131.09
80.93
83.61
86.15
88.58
47.91
47.91
47.91
47.91
.000
000
.000
.000
.uou
.uuo
()()()
.000
.000
.000
.vOO
.oou
.ooo
.ooo
.voo
.000
.000
.000
.000
.oou
.000
.000
.000
()()(I
.()()()
.ooo
.(100
.ooo
.ooo
.000
.000
.ooo
.ooo
.ooo
.ooo
.CJ(JO
000
.000
.000
.000
-------------------------------------------------------------------------------941
27.701
.000
92.76
.000
000
65.06
45.67
-------------------------------------------------------------------------------.(J(I()
1048
33.792
.ouu
102.06
68 .l7
.Ouv
38.28
-------------------------------------------------------------------------------.000
1405
.000
40.996
119.42
78.43
.000
47.91
000
.000
000
.()(J(J
.()(J(I
000
-------------------------------------------------------------------------------41HJ7
K
IIELTI NG POINT
1405
BOILING POINT
K
0
H298
Ho
8.519 kJ
ENTHALPY OF VAPORIZAT I Oil
464.070 kJ
6.364 kJ
IIOLAR VOLUIIE
1 ..!497 J/bar
12.497 c11 3
TRANSITIONS IN REFEBEIICE STATE ELEIIENTS

32. 935 1. 7u8Jx1 o- J T
REFERENCE
107
107
2.8721x10-5 TZ
298 '141 K)
COIIPILED
4-30-76
PROPERTIES AT HIGH
VANADIUI'I (REFERENCE STATE)
V:
111
TEI!PERATURES
50.941
FORI'IU LA II E.IGHT
Body-centered cubic crystals 298.15 to aelting point 2175
-------------------------------------------------------------------------------( H;-H ~
TEIIP.
98
-(G;-H~ 98 )/T
)/T
ST
Cp
FORI'IATIDN FROI'I THE ELEI!ENTS

GIBBS
ENTHALPY
FREE ENERGY
Log Kf
J/molK
J/aol K
JjmolK
0.000
28.91
0.42
24.89
o.ooo
o.ooo
o.ooo
UNCERTAINTY
28.91
0.42
JjmolK
400
500
600
700
800
900
1000
6.515
10.504
13.272
15.340
16.979
18.340
19.515
36.42
42.32
47.26
51.54
55.34
58.78
61.95
29.90
31.82
33.99
36.20
38.36
40.44
42.43
26.09
26.79
27.42
28.09
2S.83
29.64
30.55
.000
000
.000
.000
000
uuo
.ooo
.000
000
.000
.000
(10()
.000
.000
.000
110()
1200
1300
1400
1500
1600
1700
1800
20.563
21.522
22.422
23.279
24.109
24.922
25.7 27
26.529
64.91
67.70
7().36
7 2.91
75.37
71.77
80.11
82.4()
44.35
46. 18
47.94
49.63
51. 26
52.85
54.38
55.87
31. 55
32.63
33.8()
35.06
36.41
37. 84
39.36
4U.97
kJ/mol
kJ/11101
-------------------------------------------------------------------------------298.15
2175
liE LT I NG POI NT
BOlLING
20. 9 28 kJ
ENTHALPY OF MELTING
.ouu
.oou
.000
.uoo
.00()
.000
000
.ooo
000
.uoo
POINT
4. 640 kJ
IIOLAR VOLUME
.uuu
.uuo
. uoo
.()()()
000
.000
.UUU
.000
.000
.000
.00()
uuo
.uuo
.uuo
.000
000
.000
.000
.000
.000
3682
451.893 kJ
0.8350 Jjbat:
3
cm
tl. 350
TRANSITION.S IN REFERENCE STATE ELEIIENTS
HEAT CAPACITY
EVUATIDN
20.403 +
2.8000x10-
-2.9947x10S T
(EQUATION
REFERENCE
107
VALID FROII
107
298-
1800 K)
COI'IPILED
4-10-76
112
THERftODYNAftiC PROPERTIES OF ftiNERALS
TUNGSTEN (REFERENCE STATE)
FORftULl WEIGHT
183.850
Body-centered cubic crystals 298.15 to 1800 K.
W:
-------------------------------------------------------------------------------l'ORftlTION FROft THE ELEftEHTS

TEftP.
so
( H;-H; 98 )/T
J/aolK
-(G;-H~ 98 )/T
J/IIOlK
J/molK
Cp
ENTHALPY
J/aol K
GIBBS
FREE EHEBGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------u.uou
298.15
o.ooo
32.64
32. &4
0.000
o.ouu
24.2&
o. 4.2
0.42
400
500
600
700
800
900
1000
&.295
10.108
12.723
14.646
16.129
11.318
18.301
39.90
45.56
50.26
54.29
57.83
60.99
63.85
33.60
35.45
37.54
39.64
41.70
43.67
45.55
25.09
25.&0
25.99
2&.34
26.67
26.99
27.31
1100
1200
1300
140(1
1500
1600
1700
1800
19.134
19.854
20.488
21.056
21.569
22.039
22.474
22.879
66.47
68.89
71.14
73.24
75.23
77.10
78.89
80.59
47.34
49.04
50.65
52. 18
53.66
55.06
56.42
57.71
27.62
27.94
28.26
28.59
28.92
29.26
29.60
29.95
UNCERTAINTY
!'!ELTING POIHT
3680
ENTHALPY OF !'!ELTING
35.397 kJ
4.979 kJ
000
.0(1(1
.0(1(1
.ooo
.CIOO
.00(1
000
.000
.000
000
000
000
.000
.000
.ooo
.000
.0(1(1
0(10
.ooo
.ooo
.ooo
.ooo
.uoo
.000
.ooo
.0(10
.000
.ooo
.ooo
.ooo
.ooo
.00(1
.000
.000
000
.(1(1(1
.000
.000
.000
.uOO
.ooo
.ouu
.ooo
.(10(1
.ooo
BOILIHG POINT
5828
823.913 kJ
ftOLAR VOLUI'IE
0.9545 J/bar
9.545 cm 3
TRANSITIONS IN REFERENCE STATE ELEftEHTS
24.843 +
2.2255x10-~
(EQUATION VALID FROI'I
REFERENCE
1(17
107
3.5044x10-7 TZ
298 - 1800 K)
COftPILED
4-11-76
113
PROPERTIES AT HIGH TEIIPBUTURES
PORIIULA lEIGHT
XEIIOII ( REPEREIICE STATE)
Xe:
Ideal gas 298.15 to
131.300
1800 K.
-------------------------------------------------------------------------------FORJIATIOII FROB THE ILBBEIITS

TEBP.
H;-H~ 98
)/T
J/IIOlK
cop
-(G;-H~ 98 )/T
ST
J/llol K
J/IIOlK
ENTHALPY
J/IIOlK
GIBBS
PBBB BNEBGI
kJ/1101
Log Kf
kJ/aol
-------------------------------------------------------------------------------169.68
298.15
o.ooo
o.ooo
o.ooo
169.68
20.79
o.ooo
U IICERT AIIITY
0.02
0.02
400
500
600
700
800
900
1000
5.292
8.392
10.457
11.933
13.040
13.900
14.589
175.79
180.43
184.22
187.42
190.20
192.64
194.83
170.50
172.04
17 3. 76
175.49
177.16
178.74
180.211
20.79
20.79
20.79
20.79
20.79
20.79
20.79
1100
1200
1300
1400
1500
1600
1700
1800
15.152
15.622
16.(119
16.359
16.655
16.912
17. 141
17. 343
196.82
198.62
200.29
201.83
203.26
204.60
205.86
207.05
181.67
183.00
184.27
185.47
186. 61
187.69
188.72
189.71
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
1m LTI NG POI NT
ENTHALPY OP IIELTIRG
161.36 K
.ooo
.ooo
.000
.000
.000
.000
.000
.000
.000
.000
.0(10
.ooo
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.000
.000
.ooo
.ooo
.000
000
.ooo
.ooo
.000
.ooo
.00(1
.ooo
.ooo
.ooo
.ooo
.ooo
.000
.000
.000
.000
.000
.000
.000
.000
.000
.ooo
.000
BOlLI IIG POINT
165.03 K
2. 297 kJ
12.636 kJ
6. 197 kJ
I!OLAB VOLOBE
2478.9200 J/tlar
24789.200 cal
TRAIISITIONS IN REPEREIICE STATE ELEIIENTS
REFERENCE
107
35
COIIPILED
3-11-76
114
THERftODYNAftiC
PROPERTIES OF ftiNEBALS
YTTRIUI! (REFERENCE STATE)
Y:
FORftULA WEIGHT
88.9(16

Beta crystals
(body-centered cubic) 1752 to melting point 1799 K.
Liqu1.d 1799 to
-------------------------------------------------------------------------------PORIUTION FRO I! THE ELEIIENTS

TEftP.
(H;-H~ 98 );T
JjmolK
ST
JjmolK
-(G;-H~ 98 )/T
J;molK
cop
ENTHALPY
Jjaol K
GIBBS
FREE ENERGY
kJjaol
Log Kf
kJ;mol
-------------------------------------------------------------------------------298. 15
o.ooo
44.43
44.43
u.ooo
o.ooo
26.53
0.000
0.25
0.25
1 o. 968
13.845
15.999
17.704
19.110
20.309
52.30
58.44
63.59
68.05
72.00
75.58
78.85
45.47
47.47
49.74
52.05
54. 30
56.47
58.54
27. 19
27.88
28.57
29.28
30.00
30.73
31.48
.000
.ooo
.000
.ooo
.000
.000
.ooo
.ooo
000
000
.000
.000
00.0
000
.000
.000
.000
.000
.000
.000
.000
1100
1200
1300
1400
1500
1600
1700
1752
21.359
22.297
23.151
23.938
24.672
25.364
26.021
26.343
81.89
84.73
87.40
89.93
92.34
94.65
96.86
97.99
60.53
62.43
64.25
65.99
67.67
69.29
70.84
71.63
32.24
33.00
33. 78
34.56
35.34
36.13
36.93
37. 45
.000
.ooo
.000
000
.000
.ooo
.000
.000
.ooo
.ooo
.ooo
000
.000
000
.000
.000
.000
.ooo
.ooo
.ooo
.uoo
.000
.000
1799
29.344
100.83
101.76
71.63
72.42
35.02
35.02
000
.000
.000
.000
.000
.ooo
1799
1800
35.679
35.681
108.07
108. 11
72.42
72.43
43.10
43.09
.ouo
.ooo
000
.ooo
.ooo
UNCERTAINTY
4uo
500
600
700
800
900
100(1
b. 825
.(JIJ(I
-------------------------------------------------------------------------------1752
29.192
--------------------------------------------------------------------------------
1799
ftELTING POINT
ENTHALPY OF I!ELTING
11.397 kJ
5. 966 k.J
TRANSITIONS IN
(1(1(1
BOILING POINT
3611
363.340 kJ
I!OL& B VOLUIIE
1. 50 38 Jjbar
15.038 cm 3
REFERENCE STATE E.LEftENTS
20.985 +
8.4202x10-l T
(EQUATION VALID Hl015
REFERENCE
107
107
68.561 T-05
1 752 K)
2 98 -
COI!PILED
4-26-76
115
PBOPEBTIES AT HIGH TEII.PEBATUBES
YTTERBIUII ( BEFEBENCE STATE)
FORIIJU WEIGHT
173.0110
Alpha crystals (face-centered cubic) 298.15 to 1033 K.

Beta crystals
(body-centered cubic) 1033 to aeltiog point 1097 K.
Liquid 1097 to
Yb:
TEIIP.
a;-H~ 98 )/T
JjaolK
so
-( G;-a; 98 )/T
J/aolK
J/aolK
0.17
0.17
cop
POBIUTIOII FRO II THE ELEIIENTS

GIBBS
EIITHAL.PY
FREE EIIEBGY
Log
J/aol K
ltJ/aol
Kf
ltJ/aol
-------------------------------------------------------------------------------298. 15
0.000
59.83
59.83
26.72
0.000
o.ooo
u.oou
UIICERTUIITY
400
500
553
6.900
11.312
1 l. 220
67.79
74.211
77.66
60.89
62.93
64.44
27.61
31.02
34.90
000
.ooo
.000
.000
.000
.000
.000
.000
.000
600
70()
suo
900
1000
1033
14.658
16.859
18.574
19.968
21.138
21.487
79.97
84.60
88.68
92.35
95.68
96.73
65.31
67.74
70.11
72.38
74.54
75.25
29.811
30.31
30.85
31.40
31.92
32.05
.000
.ooo
.000
.ouu
.000
.uoo
000
.000
.ooo
.oou
.uoo
.000
.000
.ooo
.ooo
.uuo
.oou
.ooo
1097
23.937
100. 62
76.69
3b.11
.ooo
000
.oou
30.928
31.1116
31.828
32.182
107.67
110.87
113.81
116.54
76.74
79. 45
81.98
84.36
36.78
36.78
36.78
36.78
.000
000
000
.uoo
.ooo
.000
.000
.ouo
.000
.ooo
.ooo
.uou
-------------------------------------------------------------------------------553
13.349
77.79
64.44
29.68
.000
.000
.uuo
-------------------------------------------------------------------------------1033
23.180
98.115
75.25
36. 11
000
.000
.000
-------------------------------------------------------------------------------1097
30.917
107.61
76.69
36.78
000
.000
.ooo
1100
1200
1300
1400
IIELTING POINT
1097
BOILING POINT
1465
7. 657 kJ
128.935 kJ
H~98
6. 711 kJ
IIOLAR VOLUIIE
2.483u J/bar
24.83 0 ca 3
H~
s.12u2x1oz-
u.73984 r
5.6939x1o-~
TZ
2. 1 191x 106 T- z
c:
2.7211x10-2 T
298 -
553 K)
7.9838x10-6 TZ
4.0139x102 T-os
553 - 1033 K)
REFERENCE
107
107
COIIPILED
11-30-76
116
THEBIIODYNAIIIC PBOPEBTIES 01' IIINEBALS
Zn:
65.380
FORIIULl WEIGHT
ZINC ( BEFEREIICE STATE)
Hexagonal close packed crystals
~98.15
Ideal monatoaic gas 1178 to 1800 K.
to elting point 692.7 K.
Liquid
-------------------------------------------------------------------------------fOBIIATIOIII FBOII THE ELEIIEIITS

TEitP.
H;-H~98 )/T
J/IIOlK
-(G;-H~ 98 )/T
so
T
J/IIOlK
J/olK
co
EIITHALPY
J/mol K
GIBBS
FBBB EIIEBGY
kJ/aol
Log Kf
kJ/1101
-------------------------------------------------------------------------------o.ooo
o.ooo
298.15
o.ooo
41.63
41.63
o.ooo
25.40
o. 13
0.13
49.21
55.19
60.27
64.47
42.63
44.57
46.78
48.89
26.29
27.31
28.46
29.59
.ooo
UNCEBTAI NTY
4CJO
500
600
692.66
6.575
10.620
13.495
15.584
000
.000
.000
000
000
.000
.000
.ooo
.ooo
.ooo
.ooo
-------------------------------------------------------------------------------.000
692.66
26.155
75.04
.000
.000
48.89
31. 38
700
80(1
90(1
1000
26.210
26.856
27. 3 59
27.761
75.35
79.511
8 3. 23
86.511
49. 111
52.68
55.87
58.78
31.38
31.38
31.38
31.38
.000
.000
.CJOO
.O(JO
.000
.ooo
.ooo
.ooo
.ooo
1100
1178
28.090
28.306
89.53
91.68
61.114
63.35
31.38
31. 38
.000
000
000
.000
.ooo
1200
1300
11100
15UCJ
1600
1700
1800
124.296
116.3]11
109.509
103.5911
98.1118
93.852
89.793
189.93
191.59
193.13
194.57
195.91
197.17
198. 36
65.63
75.26
83.62
90.98
97.49
103.32
108.57
20.79
20.79
20.79
20.79
20.79
20.79
20.79
.CJOO
.000
.000
.000
000
.OCJO
.ouo
.ooo
.ooo
.000
.uoo
.000
-------------------------------------------------------------------------------.000
1118
126.229
189.55
.ooo
.000
63.35
20.79
IIELTING POINT
ENTHALPY OF !fELTING
.ouo
.ooo
.000
.ooo
.000
.000
.000
.000
.000
.000
.ooo
.ooo
.ooo
BOILIIIG POINT
1178
7.322 kJ
115.353 kJ
5. 657 kJ
llOLA B VOLUIIE
692.66 K
0.9162 J/bar
9.162 c 3
5.11094x10-6 TZ
2. 4584x 105 T- z
(EQUATION VALID FRO It
REFE BENCE
107
35
2 98 -
J.4981x102 T-os
692.66 K)
COIIPILED
11-10-76
PROPERTIES AT HIGH T!l:tPERATUBES

FORIIULA WEIGHT
ZIRCONIUII (REFERENCE STATE)

Zr:
117
HeKagonal close packed crystals 298.15 to 1136 K.

crystals 1136
91.220
Body-centered cubic
to aelting point 2125 K.
-------------------------------------------------------------------------------FORIIATION FRO II THE ELEIIENTS

TlftP.
so
-(G;-a~ 98 )/T
J/aolK
J/aol K
c H;-a~ 98 ).1T
J/olK
cop
EITHALPY
J/aolK
GIBBS
FREE EIEBGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
u.ooo
o.ooo
0.000
38.99
38.99
o.ooo
25.37
o. 11
0.17
400
500
600
700
800
900
1000
6.1112
10.974
1 J. 960
16.223
18.034
19.546
20.850
46.76
52.98
58.24
62.84
66.94
70.66
74.09
40.02
42.01
44.28
46.62
48.91
51. 11
53.24
27.33
28.42
29.34
30.25
31.18
32. 11
33.06
1100
1136
22.003
22.368
11.29
78.48
55.29
56.12
26. 150
26.552
26.897
27.196
27.1157
27.688
27.893
83.58
86.09
88.41
90.58
92.60
911.51
96.30
57.43
59.54
61.51
63.38
65. 14
66.82
68.tH
UNCERTAINTY
.000
.ooo
000
000
.ooo
.000
.ouu
.ooo
.ooo
.ooo
.000
.000
.ooo
.ooo
.ooo
.ooo
.000
000
000
.000
34.00
34. lJ
.ooo
.ooo
.000
.ooo
.ooo
.ooo
31.38
31.38
31.38
31.38
31.38
31.38
31.38
.000
.000
.000
.000
.000
.000
.000
-------------------------------------------------------------------------------.ooo
1136
.ooo
25.855
81.97
56.12
.ooo
31.38
1200
1300
1400
1500
1600
1700
1800
ft!LTIMG POINT
2125
16.895 kJ
5. 531 kJ
.000
.ooo
.ooo
.oou
.uoo
.000
.000
.000
.000
.ooo
.ooo
.ooo
.ooo
.ooo
.000
BOILING POINT
4682
EIITHALPY OF VAPOBIZAT ION
582.045 kJ
IIOLA B VOLUftE
1. 4016 J/bar
14.016 ca 3
7.2106K105 T-2
REFERENCE
107
107
298 - 1136 K)
COIIPILED
4-13-76
118
THER!ODYIIAIIIC PROPEITIES OF ftUERALS
IIETHANE (IDEAL GAS)
CH 4
FORIIULA IIEIGHT
16.043
Ideal gas 298. 15 to 1800 K.
-------------------------------------------------------------------------------roRIIATION rROII THE ELEIIENTS

TUP.
so
(H;-a~ 98 )/T
J/olK
- ( G;-H ~
98 )/T
J/olK
JfaolK
0. 21
0.21
CD
p
J/ol
EIITHALPY
GIBBS
FREE ENERGY
kJ/1101
Log
Kf
kJ/1101
-------------------------------------------------------------------------------298.15
-50.708
8.884
o.ooo
18&.26
-74.810
186.26
35.&4
UHCEBTAI IITY
o. 335
u. 377
o.u6&
400
500
&00
700
81)0
900
1000
9.600
16.346
21.862
26.627
30.865
34.689
38.192
197.30
2u6. 95
215.95
224.45
232.52
240.21
247.55
187.70
19u.6o
194. (.19
197.82
201.66
205. 52
209.36
40.32
46.41
52.41
57.96
63.01
67.58
71.70
-77.940
-au. 792
-83.285
-85.404
-87.174
-88.&30
-89.792
-41.984
-32.667
-21. 799
-12.548
-2.014
8.123
19.598
5.483
3.413
1.985
0.936
0.131
-0.506
-1.024
1100
1200
1300
1400
1500
1600
170(.1
1800
4 1. 410
44.384
47.143
49.707
52.095
54.32(.1
56.393
sa. 323
254.56
26 1. 27
267.69
273.84
279.74
285.40
29(1.83
296.04
213.15
216.89
220. 55
224. 13
227.64
231.08
234.44
237.72
75.41
78.74
81.71
84.34
86.66
88.67
90.40
91.84
-90.704
-91.398
-91.902
-92.246
-92.455
-9 2. 559
-92.581
-92.549
30. 59 2
41.645
52.750
b].895
75.051
86.240
97.393
108. 5&6
-1.453
-1.813
-2. 12u
-.2.384
-2.614
-2.815
-2.993
-3.151
IIELTING POINT
ENTHALPY or IIELTING
111.70 K
90.60 K
BOILING POINT
0. 937 kJ
ENTHALPY or VAPORIZATION
10.025 kJ
8.318 1W
2478.9200 J/bar
24789.200 cm 3
ftOLAR VOLUIIE
TRAiiSITIOiiS IN REFERENCE STATE ELEI!ENTS
78.976 +
4.3186x1o-z T
1. 8836x 1 o T- 2
(EQUATION VALID FBOft
REFERENCE
247
262
298 - 1800 K)
2&2
COIIPILED
7-26-7&
PROPERTIES
119
AT HIGH TEIIPEBATOBES
COHENITE
FOBI!ULl
IIEIGHT
179.552
crystals 298.15 to 1800 K.
-------------------------------------------------------------------------------FORftlTION FRO II THE EL.EIIENTS

TEftP.
K
a;-H~ 98 )/T
JjmolK
so
-(G;-a~ 98 )/T
J;moll
J;molK
3.35
3.35
31.025
137.24
106.22
600
700
800
900
1000
58.543
66.671
12.924
71.922
82.054
185.47
203.26
218.84
232.73
245.30
1100
85.545
1200
1300
1400
1500
1600
1700
1800
co
ENTHALPY
J;mol K
kJ/mol
GIBBS
FREE ENERGY
Log Kf
kJ/mol
-------------------------------------------------------------------------------298.15
o.ooo
1011.43
104.43
111.03
:.!4.937
19.912
-3.489
1. 339
1. 715
0.30(1
112. 31
28.332
18.852
-2.462
126.93
136.59
145.92
154.81
163.24
114.82
116.07
117.32
118.58
119.83
30.494
30.347
29.177
26.634
21.874
12.234
9. 134
6.165
3.501
1.163
-1.(165
-0.682
-0.403
-0.203
-0.061
256.77
171. 22
121.08
88.559
91.205
93.564
95.&89
97.629
267.36
277.20
286.41
295.06
30 3. 24
178.80
185.99
192.85
199.37
205.61
122.33
123.59
124.84
12&. (19
127.34
99.414
101.070
311.00
318.38
211.59
217. 31
1213.60
1.l9. 85
BOILING POINT
ONCERT&I IITY
400
-------------------------------------------------------------------------------500
47.414
164.65
117.24
15.228
-1.591
113.56
29.820
I'IELTIIfG POIIIT
kJ
18. 112 kJ
-------------------------------0.(123
-0.477
14.408
--------------------------------1.750
0.076
9.643
9. 353
8.906
8.421
7.792
-2.781
-3.739
-4.566
-5. 438
0.112
0.140
0.159
0.178
1. 579
-6.523
-0.11:19
-------------------------------0.188
3.502
-6.130
kJ
2. 3 23() J/bar
.23.230 cm 3
!toLl R VOLUIIE
TRANSITIOifS IN REFERENCE STATE ELEIIENTS

IRON CURIE P. 1042, lLPHA-GAI'IIIA 1184,
1'1. P. DELTA 1809 K.
GAIIIIA-DELTA 1665,
c:
1.0730x102 +
REFERENCE
1. 2528xlo-z T
4&3- 1800 K)
(EQUATION VALID PRO!!
115
108
108
COftPILED
7-24-76
120
THEIIIODYIUIIC PROPERTIES OF IIIIEBlLS
AIIIIOIIl ( IDBlL GlS)
HH~:
FOBIIULl WEIGHT
17.030
-------------------------------------------------------------------------------FOIIIATIOI FIOII THB ELEIIE IITS

TBIIP.
H;-H~ 98 )/T
JjaolK
ST
-(G;-a~ 98 )/T
JjaolK
JjaolK
cop
GIBBS
EITHlLPY
J/aol K
FREE EIIEBGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298. 15
0.000
192.78
-ll5. 940
-1&.410
2.875
35.&3
192.78
o.o8
o.o8
800
900
1000
9.1l50
15.628
20.290
24.067
27.272
30.078
32.581
203.67
212.65
220.59
227.79
234.42
240.60
21l6.1l1
194.22
197.02
200.30
203.72
207. 15
210.52
213. 83
1100
1200
1300
1400
1500
1&00
1700
1800
34.852
36.932
38.852
40.636
42.293
43.841
45.288
46.641
251.89
257. 10
262.05
266.78
271.30
275.62
279.17
283.75
217.04
220. 17
223. 20
226. 14
229.01
231.78
234.48
237.,
OMCBBTliiTY
llOO
500
&00
100
ftE LTI MG
195.36
POI NT
o. 350
0.350
0.061
38.70
41.98
45.19
48.25
51.14
53.85
56.37
-48.086
-49.905
-51.430
-52.684
-53.698
-54.497
-55.113
-5.984
4.760
15.841
27. 155
38.630
50.236
61.887
0.781
-0.497
-1.379
-2.026
-2.522
-2.916
-3.233
58.72
60.88
62.87
64.68
66.32
67.78
&9. 07
70.19
-55.561
-55.868
-56.052
-56.126
-56. 116
-56.031
-55.884
-55.695
73.&22
85.317
97.147
106.933
120.719
132.535
144. 3(17
156.066
-3.1l96
-3.716
-3.9(13
-4.064
-4.204
-ll.327
-4.434
-4.529
239.&8 K
BOILIIIG POINT
5. &57 kJ
10.046 kJ
23. 351 ltJ

2478.92
24789.2
IIOLAR VOLOIIE
J/bar
ca 3
TRANSITIONS IN REFEREIICE STATE ELEIIEIITS
29.735 +
3.9119x1o-z T
8.2274.11:10-6
TZ
2.9243x10S T-2
REFERENCE
247
35
215
298 - 1800 K)
215
COIIPILED
7-26-76
121
PROPERTIES lT HIGH TEIIPEBlTURES
FORIIULl WEIGHT
AClNTHITE (ARGENTITE)
llonoclinic crystals 298.15 to 452 K.
247.796
Cubic crystals (argentite) 452 to
1000 K.
so
( H;- H~98 )/T
TEIIP.
JjaolK
-(G;-H~98 )/T
JjaolK
J/aol K
o. 42
0.42
cop
FORIIATION FRO II THE ELEIIENTS

GIBBS
Log Kf
FREE ENERGY
ENTHALPY
J/aolK
kJ/aol
kJ/1101
--------------------------------------------------------------------------------40.080
7.022
298.15
-32.346
O.CJCJO
142.84
142.84
75.32
UNCERTAI NTI
0.879
400
452
20. b05
27.544
166.52
177.6&
145.92
150.12
86.57
92.31
500
600
700
43.012
50.905
56.544
196.02
212.50
226.44
153.01
161.60
169.89
90.54
90. 54
90.511
BOO
60.825
611.108
66.777
238.57
2119.20
257.90
17 7. 74
185.09
191. 12
90.54
90.54
90.54
o. 837
0.147
--------------------------------112.1185
5.5118
-33.976
-34.633
-44.140
-29.857
-29.736
-29.469
-44.995
-48.082
-51.142
4.701
4.11:16
3.816
-82.327
-80.980
-56.838
-53.216
3. 299
2.780
5.101
--------------------------------------------------------------------------------44.140
5.101
452
-29.915
37.983
188.11
150. 12
90.54
900
1000
--------------------------------59.823
3.906
-83.805
BOIL I IIG POINT
EIITHALPI OP' IIELTING
kJ
EIITH ALPY 0 l
kJ
H~ 98
kJ
IIOLA R VOL Ull E
liE Lri NG POI NT
1061
H~
Y&POR IZATIOII
3.4190 J/bar
34. 190 ca 3
TBliiSITIOIIS Ul REPEREIICE STATE ELE!IENTS

SILVER. II P.
12 34 K.
SULFUR ORTHQ-110110 368.54,

B. P. 716.9 K.
REPEREIICE
115
80
II.
P. IIONO 388.36,
73
CO!IPILBD
7-211-76
122
THERI'IODYNAIUC PBOPERTIES OF IIINERALS
CHALCOCITE
FORI'IULA
O~tho~hombic
TEI'IP.
c~ystals
298.15 to 376 K.
H~-H~ 98 )/T
JjmolK
ST
-(G;-H~ 9 s)/T
J/mol K
J/mol K
2.09
2.09
159.152
Hexagonal c~ystals 376 to
cubic c~ystals 623 to melting point
623 K.
W~IGHT
1403 K.
FOBI'IATION FROM THE ELEI'IENTS

GIBBS
FREE ENEBGY
Log Kf
cop
ENTHALPY
kJjmol
J/mol K
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
120.75
15.219
76.32
-so. 115
-86.tlb8
120.75
UNCERTAINTY
1. 423
1. 255
0.249
-------------------------------376
16.914
139.70
12.317
122.80
81.69
-8 2. :.!16
-88.660
-------------------------------------------------------------------------------376
27.151
149.96
-1:18.6&0
12.317
122.80
97.28
-78. 3bb
400
500
bOO
623
31.380
44.51tl
53.347
54.976
155.98
177.61
195.39
199.05
124.60
133. 09
142.05
144.08
97.28
97.28
97.28
97.28
-17.297
-7b.b75
-75.816
-75.618
-89.269
-92. 2&9
-95. 524
-96.294
11.&57
9.639
8.316
8.073
-74.926
-98.904
7.380
-128.693
-127.713
-105.138
-102.631
6.102
5.361
-12&.775
-125.959
-125.221
-100.148
-97.782
-95.43 0
4.756
4. 25b
3.834
-------------------------------------------------------------------------------623
56.316
200.40
-96.294
8.073
144.08
-74.784
85.02
700
59.473
210.29
150.82
85.02
800
900
1000
62.655
65. 131
67.111
221.67
231.63
240.62
159.01
166.49
173.51
85.02
85.02
85.02
1100
1200
1300
68.770
70.117
71.2 57
248.74
256. 14
262.92
179.97
1B&.u3
191.67
85.02
85.02
85.02
1400
72.234
2&9.20
196.96
85.02
1403
I'IELTl NG POI NT
ENTHALPY OF I'IELTING
0
"298 -
"o
--------------------------------107.896
7.045
-129.768
-------------------------------3.454
-151.146
-92.571
BOIL IIIG POINT
kJ
kJ
kJ
IIOLAR VOLUI'IE
2. 7475 J/ba~
27.475 c11 3

COPPER 1'1. P.
SULFUR
REFERENCE
115
1357 K.
ORTHO-I'IONO 368.54,
B. P. 716.9 K.
120
266
II.
P. IIONO
388.36,
26
219
COI'IPI.LED
7-24-76
123
PROPEBT IES AT HIGH TEMPEBlTOR ES
CHALCOPYRITE
CuFeS 2
FORMULA
Alpha crystals 298.15 to 830 K.
WEIGHT
Beta crystals 830 to 930 K.
183.511
Gaaaa
PORISATIOII FRO!! THE .li:LEISEIITS

GIBBS
Log
EITHALPY
FBEE EIIERGY
TEMP.
J/aol K
J/aol K
o.ooo
o.oo
95.77
400
500
600
700
26.150
42.442
53.952
63.221
30. 10
54.11
74.42
92.72
106.26
109. 15
114.53
123.84
800
830
71.574
72.769
110.07
115.27
136.83
141. 37
830
900
930
83.089
91.478
95.757
125.59
139.80
148.27
108.73
203.75
244.48
93 0
1000
96.076
101.425
148.59
160.10
172.49
17 2. 49
1100
107.885
176.54
172. 49
1200
113.269
191.55
172.49
298.15
kJ/aol
kJ/aol
UIICERTAIIITY
IIELTI NG POI NT
--------------------------------
---------------------------------------------------------------
BOlLI IIG POINT
--------------------------------
kJ
kJ
kJ
I!OLAR VOLUME
Jjbar
TRAIISI TIOIIS Ill REFERENCE STATE ELEIIEIITS

COPPER II. P.
1357 K.
CURIE P. 1042, ALPHA-GAIIIIA 1184, GAIIISA-DELTA 1665,

11. P. DELTA 1809 K.
SULFUR ORTHO-I!ONO 368.54, 11. P. IIONO 388.36,
IRON
B. P. 716.9 K.
HEAT CAPACITY QUATIONS
0
Cp
-5.8753x10Z +
cop
-1.0180x10l +
0.37073 T
REFERENCE
1.3575 T
( EQUAT lOll VALID FROM
209
1.2750x 10 T-05
298 830 K)
830 -
930 K)
COI!PIL.Ii:D
8- 4-76
124
THERIIODYNAIIIC PROPERTIES OF IIINEBALS
FOBIIULA WEIGHT
BORNITE
Cu 5 FeS 4 :
501.817
Gaaaa
FORIIATION FROII THE LEIIENTS

GIBBS
FREE EIIEBGY
Log
EliTHALPI
TEIIP.
J;aol K
J;aolK
0.000
0.00
0.00
400
485
64.850
100.84 7
74.68
126.59
263. 38
277.11
485
500
540
113.330
120.7 34
140.912
139.07
150. 20
180.65
357.74
372.91
653.3b
540
600
700
140.912
160.403
184.346
180.65
215.97
266.55
342. 53
lJ2. 53
324.97
800
900
1000
201.822
215.567
226.999
309.84
348.17
382.'H
324.17
327. 30
332. 87
1100
236.940
414.98
340.04
1200
245.870
444.91
348.30
298.15
UNCERT AllfTY
IIELTING POI NT
ENT HAL PI OF II ELT Ill G
kJ;aol
J;aolK
kJ/aol
--------------------------------
---------------------------------------------------------------
BO ILUIG POIIIT
kJ
EIITHALPI OF VAPORIZATIOll
kJ
kJ
IIOLAR VOLDIIE
J/bar
TRAIISITIOliS Ill REI'EREIICE STATE ELEIIEIITS

COPPER II. P.
1357 K.
IRON CURIE P. 1042, ALPHA-GAUl 1184, GAIIIIA-DEL'U 1665 9

II. P. DELTA 1809 K.
SULFUR ORTH0-110110 368. 54, II. P. 11010 388.36,
B. P. 716.9 K.
HEAT CAPACITY EQUATIOIIS
CD
p
CD
p
-1.3274x10Z + 1.0113 T
( EQUATIOII VALID FBOII
1.8971I10Z + 0. 11703 T
REFERENCE
209
485 -
540
540 K)
2. 613511:10 7 T-Z
1200 K)
COli PILED
8- 4-76
125
PROPERTIES AT HIGH TEIIPEBlTURES
TROILITE
Fes:
87.907
FORI!U LA II EIGHT
Alpha crystals 298. 15 to 411 K.
Beta crystals 411 to Curie point 598 K.
Gaaaa crystals 598 to aelting point 1468 K.
FORftATION FRO!! THE ELEMENTS

GIBBS
FREE ENERGY
EITHALPY.
TEftP.
Jtaol K
kJ/aol
kJ/aol
-100.960
1. 4611
-101.333
1. 506
o.ooo
60.33
0.11
60.33
o. 17
50.50
400
411
15.375
16.580
77.94
79.85
62.57
63.27
65.90
67.56
-102.279
-101.340
12.879
411
500
598
21.517
31.464
37.440
84.79
99.78
112.011
63.27
68.32
74.60
76.94
76.94
76.94
-100. 250
-99.282
-98.680
-101.340
-1111. 57b
-102. 140
12.879
10.612
8.922
598
600
100
39.058
39.120
41.960
113.66
113.84
122.92
74.60
74.72
80.96
57.00
57.02
58.02
-98.178
-98.194
-98.931
-1112. 140
-102.152
-102.744
8.922
8.893
7.667
800
900
1000
44.089
45.746
47.070
130.79
137.73
143.97
86.70
91.99
96.90
59.01
60.01
61.00
-154.544
-155.344
-1112.980
-97.235
5.917
5.079
1100
48.230
149.66
101.43
62.00
1200
1300
1400
1468
49.337
50.465
51.583
52.289
155.01
160. 16
165.06
168.30
105.68
109.69
113.47
116.01
62.99
63.99
64.99
65.66
1500
1600
74.2 52
74.057
19 1. 79
196.35
117.511
122.30
71.13
71. 13
1700
1800
73.885
73.731
200.66
204.72
126.78
130.99
71.13
71 .13
298.15
UNCERT AINTI
17.753
0.2 64
--------------------------------102.115
-101.283
13.226
--------------------------------154.511
-108.772
7.102
--------------------------------156.988
-91.315
4.336
--------------------------------85.358
3.716
-157.590
-156.482
-155.255
-154.379
-79.444
-73.573
-69.562
3.192
2.745
2.475
-121.525
-119.926
-68.1177
-64.950
2. 385
2.120
-118.5110
-58.088
1.686
-------------------------------------------------------------------------------14&8
74.320
190.33
71.13
-69.562
11&.01
-122.037
2. 475
--------------------------------61.515
-119.587
1.890
-------------------------------------------------------------------------------1468
ftELTI RG POI NT
K
BOILING POINT
K
ENTHALPY OF ftELTIRG
32. 342 k.J
kJ
kJ
1.8200 J/l;)ar
18.200 ca 3
110118 VOLOIIE
TRANSITIONS IN REFEREIICE STATE ELE!IEIITS

IRON CURIE P. 1042 9 ALPHA-GAftiiA 1184 9 GAftiiA-DELTA 1665,
SULFUR ORTHD-IIONO 368.54 9 1!. P. 11010 388.36 9
B. P. 7 16. 9 K.
HEAT CAPACITY
c~
~DATION
51.045 +
REFBIERCB
9.9579x10-:. T
( BQOATIOII VALID FROII
)9
82
598 - 1468 K)
220
2
COl PILED
7-211-76
126
THEB!IODUIAIIIC PROPERTIES OF IIIIIERALS
FOBIIULA
PYRITE
FeS 2 :
TEI!P.
W~IGHl
119.967
H;-H~ 98
so
-(G;-u~ 98 )/T
cop
J/IIOlK
J/llol K
J/aol K
o. 13
0.13
)/T
J/IIOlK
FOBJIATIOI FRO!! THE ELEIIIUITS

GIBBS
Log Kf
EIITHALP!
FREE EMERGY
lr.J/aol
lr.J/1101
-------------------------------------------------------------------------------28.072
298.15
o.ooo
-171.544
-160.229
52.93
52.93
62.17
UNCERTAINTY
1.6H
400
500
600
700
16.875
27.644
35.197
40.869
72.37
88.13
101.42
112.97
55.49
b0.49
66.22
72. 10
b9.15
71.95
73.92
75.90
800
900
1000
45.381
49.156
52.427
123.24
132.58
141.21
77.86
83.42
88.78
78. 10
80.57
83.29
1. 715
-------------------------------20.326
-176.747
-155.650
-180.349
-183.303
-185.781
-149.8"4
-143.551
-136.711
15.654
12.497
10.202
-297. 233
-297.590
-120.936
-10 1. 339
7.019
5 ..293
--------------------------------297.402
-140.641
9.183
IIELTI!IG POIIIT
BOILING POIIIT
kJ
9. 632 kJ
0.300
kJ
2. 3940 J/bar
23.940 ca 3
!lOLA R VOLUIIE
TRANSITIOifS IN REFERENCE STATE ELEIIEIITS

CURIE P. 1042, ALPHA-GA!I!IA 1184, GAIIIIA-DKLTA 1665,
SULFUR ORTHO-!IONO 368. 54, II. P. !IONO 388.36,
IRON
B. P. 716.9 K.
-20.319 +
5.0299x1o-z T
BEFEREifCE
39
39
80
1.7tJ70x10.1
298 - 1000 K)
r-os
255
CO!! PILED
7-24-76
PROPERTIES AT HIGH TEftPERATUBES
127
lllRCAHTE
FeS 2
TEftP.
K
FORftULl WEIGHT
119.967
Crystals 298.15 to 700 K.
so
-(G;-H~ 98 )/T
J/olK
J/olK
0.11
o. 11
73.29
89.12
1 02.52
114.19
56.44
61.44
67.20
73.10
<a;-H~98 )/T
J/olK
cop
FORftlTIOIII FROft THE ELEIIEIIITS

GIBBS
FREE EIIIERGY
Log Kf
ENTHALPY
kJ/1101
J/olK
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
53.89
-169.450
-158.421
27.755
53.89
62.43
UNCEBT lilT I
400
500
600
700
16.850
27.680
35.323
41.093
2.090
69.18
72.46
74.58
77.04
ftELTING POIIIIT
2.090
--------------------------------153.934
-174. 663
20.102
-178.237
-181.133
-183.530
- 148.227
-142.041
-135.314
BOILING POINT
ENTHALPY OF f!ELTIIIG
0.366
15.485
12.366
1 0.097
kJ
kJ
!lOLl R VOLU liE
2.4580 Jjbar
24.580 c 3
TRANSITIOIIIS IN REFERENCE STATE ELEliEIIITS

IRON
CURIE P. 1042 1 lLPHA-GAftiU 1184 1 GAlllll-DELTl 1665 1

ft. P. DELTA 1809 K.
SUL PUR..... OBTH0-110 NO 368. 54 1 II. P. 1101110 388.36,
B. P. 716.9 K.
HEAT CAPACITY EQUATIOIII
-3.346h102 +
39.069
ros
8. 9245x 10 l T-1
BEPBREIIICE
81
81
1.1236 T
298 -
700 K)
81
COIIPILED
7-24-76
128
THERilODINli!IC PROPERTIES OF lliiiEBlLS
HYDROGEN SULFIDE (IDEAL GAS)
FORMULA WEIGHT
34.076
H2 S:
-------------------------------------------------------------------------------FOBIIATIOB FRO II THE BLEIIEHTS

so
cu;-u~ 98 }/T
TEIIP.
K
J/aolK
-( G;-u ; 98 )/T
J/aol K
JjaolK
cop
EIIITHALPY
J/ol K
GIBBS
FBEE EHEBGI
kJ/ol
Log Kf
kJ/ol
-------------------------------------------------------------------------------298.15
o.ooo
205.80
205.80
-33.543
5.877
34.19
-20.627
UNCERTAI IIITY
0.21
0.21
0.628
400
500
600
700
8.850
14.346
18.310
21.401
216.01
2 24.10
231.05
237.21
207. 16
209.75
212.74
215. 81
35.48
37.21
39.05
40.85
800
900
1000
23.941
26.100
27.989
242 011
247.88
252.62
218.83
221.78
224.63
42.57
44.2(1
45.72
1100
1200
1300
1400
1500
1600
1700
1800
29.665
31.174
32.545
33.800
34.952
36.014
36.996
37.903
257.04
261 .20
265.12
268.83
27 2. 36
275.71
278.91
281.95
227.37
230.03
232. 57
:l35.Cil
237.41
239.70
241.91
21l4.05
47.12
48.40
49.57
50.&2
51.54
52.34
53.03
53.59
I!ELTI BG POI liT
~~98
H~
kJ
-27.914
-30.626
-32.896
-40.118
-42.346
-ll4.100
4.191
3.687
3. 291
--------------------------------89.515
-51.108
3.337
-89.98b
-90.338
-46.230
-41.354
2.683
2.160
-90.588
-90.746
-90.826
-90.845
-90.814
-90.739
-90.636
-90.518
-36.441
-31.508
-2 6. 569
-21.625
-16.695
-11.740
-6.821
-1.888
1.730
1.372
1.068
0.807
0.581
0.383
0.210
0.055
EIITHALPI OF VlPORIZlTIOIII
9.962 kJ
0.117
-------------------------------4.881
-24.698
-37. 375
BOlLI IIG POIIIT
ENTHALPY OF llELTUIG
0.669
kJ
2478.9200 J/l)ar
24789. 200 cl
llOLlR YOLUIIE
TRAHSITIOHS Ill REFEREIIICE STATE ELEIIEIIITS

SULFUR OBTHO-IIONO 3&8.54, II. P. MOHO 388.36,
B. P. 716.9 K.
26.35& +
2.&497x1o-z T
2.6599x105 T-Z
( EQUlTIOII Y ALID FROM
REFEREIICE
247
262
298 - 1800 K}
262
COl PILED
7-29-76
PBOPBBTI!S lT HIGH TEIIPEBATUBES
129
lLlBAHDITE
!InS:
FOR!ULA WEIGHT
86.998
Crystals 298.15 to aelting point 1803 K.
-------------------------------------------------------------------------------FOBIIATIOII PBOII THE !LBIIBITS

TEIIP.
so
( a;-H~ 98 )/T
J/aolK
J/aolK
-(G;-H~ 98 )/T
J/aoll
cop
EHTHALPY
J/aol K
GIBBS
PIIEE EIEBGI
Log Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
78.20
-218-.155
38.220
78.20
49.96
-213.865
UHC!BTliiiTY
1.67
1.67
o. 837
400
500
600
700
12.850
20.608
25.922
29.796
93.02
104. 54
114. 11
122.29
80. 17
83.93
88.19
92.49
51.07
52.12
52.81
53.23
800
900
32.745
35.067
129.41
135.74
96.66
100.67
53.53
53.82
1000
36.963
141.42
104.46
54.19
1100
1200
1300
38.552
39.927
41.153
146.61
151.40
155.87
108.06
111.47
114.72
54.71
55.42
56.36
1400
42.279
160.09
111.81
57.58
1500
43.350
164.12
120.77
59.08
1600
1700
1800
44.387
45.419
46.464
167.98
171.74
175.41
123.59
126. 32
128.95
60.88
63.01
65.48
!!ELTING POUT
1803
ENTBlLPI OF IIELTIIIG
26. 108 kJ
H~ 98 - H~
1. 004
--------------------------------219. J20
28.640
-216.151
-217.836
-219.289
-220. 586
-219.870
-220.191
-220.219
22.970
19.169
16.433
--------------------------------225.623
14.732
-276. 509
-276.535
-219.225
12.724
--------------------------------212.797
11. 11 s
-278.881
-279.081
-279. 265
-279.415
-206.189
-199.543
-192.890
9.791
8.686
7.750
--------------------------------186.168
6.946
-281.792
--------------------------------179.218
6.241
-284.251
--------------------------------171.519
5.600
-296.791
-291.019
-297.143
-163.692
-155.845
5.030
4.523
BOILIIIG POIIIT
K-
kJ
2.1460 J/bar
21.460 ca 3
11011 B VOLUIIE
kJ
0.176
TBUSITIOIIS Ill BEFBII!HCE STlTB BLE!EIITS

!ANGAIIESE ALPHA-BETA 980, B!TA-Glii!A 1360, Gl!SA-D!LTA 1410,
SULFUR OBTBQ-!0110 368.54, a. P. !OliO 388.36,
B. P. 716.9 K.
1.3529z10Z-
5.7749zto-z
1.1688110 T-Z
(.BQUlTIOII VALID FBOII
R!l!REIIC!
39
120
2.0865z1o-s TZ
298 - 1800 K)
49
COSPI.LID
7-26-76
IBBBIODJilaiC PIOPBIIIBS
130
or
BIIBBILS
POIIULl IBIGB'l
IIOI.JBDBII'IB
160.~60
======a==~=-===--za=================-=============-====z====-==---======
BoS 2 :
crystals 298.15 to 1200 1.
-------------------------------------------------------------------------------POIIIl'liOI PIO!I 'lBB II.I!IIftS

'l'BIP.
cs;-a;,8 ~
01/aoll
1:
sr
-cc;;-a; 98 )/'1'
.l/8olJ:
J/8o11
CDp
Bl'fBlLPI
f;:(BBS
PJlBB BIBIGI
kJ/801
J/8oll
Log If
k.l/801
-------------------------------------------------------------------------------275.300
298.15
-266.454
o.ooo
62.57
62.57
63.55
46.681
OICBJl'l'lll'll
0.21
0.21
5.000
1100
500
600
700
16.850
27.520
35.062
ll0.714
81.99
CJ1.61t
110.90
122.40
65.14
70.12
75.84
81.69
68.48
71.&1
73.80
75.38
800
900
1000
lt5.1l6
48.678
51.588
132.55
1111.62
1119.82
87.42
92.9Jt
98.23
76.57
77.47
78.15
1100
1200
54.029
56.101
157.29
161l.16
103.26
108.06
78.68
79.07
IBI.'IIJG :PO.II'l
BI1BlLPJ OP IBLtlJG
8 ~98 -
5.000
0.880
--------------------------------280.360
-262.734
34.310
-283.735
-286.262
-288.122
-257.838
-252.504
-246.683
26.937
21.983
18.408
--------------------------------398.910
-251.761
16.438
-397.628
-396.351
-233.346
-215.163
13.543
11.239
-395.080
-393.828
-197.113
-179.172
9.360
7.799
BOILIIG POll!
Bl'fBlLPI 0!' flPOIIZltlOI
a:
IIOI.lB
l. 2020 J/bar
32.020 ca 3
YOLUIIB
'l'RliSitiOIS I I IBPIIBICB S'll!Z BI.BIBitS

IOI.JBDBIUI. B. P. 2890 I.
SUI.PUI 01'180-!010 368.511, B. P. BOlO 388.36,
B. P. 716.9 I.
BBU ClPlCIU IQUltlOI
c;
4.8122&10-~ 'f
6.8169z10 ,-
( IQo&UOI TILID PIOII 298 - 1200 I)
1.0453&102 -
IIPBIBIICI
61
COBPII.BD
165
286
03-15-79
131
PBOPEHIES AT HIGH TEI!PEBATUBES
IIILLEBITI
lliS:
TIIIP.
POBIIULA lEIGHT
90.760
so
-(G;-8~ 98 )/T
cop
Jtaol K
Jtaol K
J/aol K
4. 18
4.18
80.21
91.51
10 1. 26
67.97
71.59
75.73
( H;-8; 98 )/T
J/aolK
POBIIATIOII FRO II THE ELBIIEIITS

GIBBS
PBEE EIIIEBGY
Log Kf
EIITHlLPY
kJ/mol
kJ/aol
-------------------------------------------------------------------------------298. 15
66.11
-86.192
u.OOCI
66.11
46.69
-84.868
15. 101
UIICIITAIIITY
400
500
600
12.237
19.916
25.522
4.184
49.41
52.09
5Jf. 77
IIELT ING POIIIT
8;98 -
H~
0.710
--------------------------------IJ6.299
-87. 406
11.270
-89.225
-9(1. 739
BOlLI 11G POIIIT
ENTHALPY OF KELTING
4.393
-85.767
-84.978
8.9bu
7.398
.kJ
ltJ
IIOL AB VOL Ul! E
.kJ
1.6890 J/bar
16.890 CIIJ
TUNSITIONS I I REFERENCE STATE ELEIIENTS

NICKEL CURIE P. 631, II. P.
SULFUR ORTH0-110110 368. 54,
1726 K.
11.
P. 1!0110 388.36,
B. P. 716.9 K.
c;
38.702 +
2.6778x1o-z T
( .EQUAT lOll VALID FRO II
REFIRE liCE
115
80
274
298 -
600 K)
231
COli PILED
7-24-7b
132
THEB!IODYIUIIC PBOPBBTIES OF II II BBALS
GALEIA
FOBI!IULA WEIGHT
239.260
=================:=====================~======================a=================
PbS:
TBIIP.
Crystals 298.15 to aeltioq point 1385 K.
H;-H~ 98 )/T
J/aolK
50
-(G;-H~ 98
cop
)/T
JtaolK
JtaolK
1. 25
1.25
bOO
12.970
20.502
25.872
10&.3&
117.&&
127. 24
93.39
97.15
101.37
51.1&
52.80
54.44
700
30.124
135.81
105.69
56.08
800
900
33.629
36.633
143.60
150.71
109.97
114.08
57.72
59.36
FOBIIATIOif FBOII THE ELEIIEIITS

GIBBS
Loq Kf
FREE EBEBGY
EIITHlLPY
J/aol K
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298. 15
1&.832
o.ooo
91.38
-97.709
-9&.075
91.38
49.50
UIICERTAI BTY
400
500
0.962
1385
IIELTI NG POI NT
o. 837
0.147
--------------------------------99.918
-95.230
12.436
-1(11.566
-102.777
-93. 8l3
-92.187
9.802
8.02&
-1& 2. 182
-83. 505
4.847
--------------------------------108. 387
-89.543
&.682
--------------------------------163.431
-92.389
6.032
BOILING POIIIT
kJ
kJ
kJ
IWLAB VOLUIIE
3.1490 J/l:lar
31.490 ca 3
TRANSITIONS IN REFERENCE STATE ELEIIEIITS

LEAD II. P.
SULFUR
600.&, B. P. 2u21 K.
ORTHO-IIONO 368.54,
B.
II.
P. IIONO 388.3&,
P. 716.9 K.
c~
44.601 +
1.6401x1o-z T
REFB RE NCE
115
120
298 -
900 K)
245
144
COIIPILED
7-24-76
133
PROPERTIES IT HIGH TEIIPEBlTURES
HERZENBERGITE
sns:
FORIIULl WEIGHT

1153 K.
150.750
Beta crystals 875 to eltinq point
-------------------------------------------------------------------------------FORIIJ.TION FRO II THE ELBIIEIITS

TEIIP.
<n;-H;98 )/T
J/olK
-(G~-H~ 98 }/T
co
J/ol K
J/ol K
J/ol K
0.84
0. 84
so
T
ENTHALPY
GIBBS
FREE ENERGY
kJ/ol
Loq Kf
kJ/ol
-------------------------------------------------------------------------------298.15
-104.698
0.000
76.82
76.82
49.25
-106.541
18.343
UNCERTAI IITY
1.464
400
500
12.800
20.524
91.59
103.05
78.79
82.53
50.87
52.02
6.00
700
25.962
30.303
112.74
121.42
86.78
91. 12
54. 51
58.40
BOO
B75
34.124
36.416
129.54
135.12
95.42
98.70
63.50
67.97
900
1000
37.B11
39.5BB
137.47
143.32
99.66
10 3. 7 3
1100
1153
41.315
42.004
148.90
151.74
69.644
70.103
1B1.9B
188.03
1. 506
0.264
--------------------------------103.755
13.549
-108.910
-110.668
-102.212
10.678
-119.450
-95.766
7.146
--------------------------------99.135
-118.891
8.630
--------------------------------174.048
-97.930
6.394
-172.985
-90.640
5.411
54.04
57.07
-171.992
-111.124
-B8.501
-79. 260
5.136
4.140
107.58
109.74
60.11
61.72
-169.966
-169.474
-70.135
-65. 172
3.330
2.953
112. 34
111.93
75.61
75.61
-136.545
-133.694
-f\7.415
-56.347
2.111
2.264
-------------------------------------------------------------------------------B75
37.303
5. 411
136.01
9B.70
53.28
-112.209
-90.640
-------------------------------------------------------------------------------1153
69.401
179. 14
-65. 172
109.74
75.61
-137.885
2. 953
1200
1300
IIBLTI NG POI NT
1153
EIIT HlLPY OF IIELT lNG
31.589 kJ
kJ
BOILING POINT
kJ
2.9010 J~ar
29.010 ca 3
IIOLAB VOLUIIE
TRANSITIONS IN REFEREIICE STATE ELEIIEIITS

TIN 11. P. 505 K.
SULFUR ORTH0-110110 36B. 54,
B. P. 716.9 K.
II.
P. MONO 3B8. 36,
-1.5593x10Z + 0.12193 T
( EQUlT ION VALID FROII
c;
26.722 + 3.0352x1o-z T
(!)JUATIOII VALID PRO!!
REFI!!REBCE
192
120
3.6041x103 T-os
298 B75 K)
875-1153 K)
22(1
COilPILED
7-24-76
134
THERftODYKA!IC PROPERTIES OF ftiWERlLS
STUIIIC SULFIDE
SnS 2 :
FORftULA WEIGHT
182.810
FOR!ATIOH FRO! THE ELE!EWTS

GIBIIS
EWTHALPY
FREE ENERGY
TEftP.
J/aol K
298.15
o.ooo
UWCERTliRTY
J/aol K
kJ/aol
87.45
0.18
87.45
o. 18
70.12
400
500
18.125
29.058
108.36
124.59
90.23
95.53
72.05
73.53
600
700
36.603
42.253
138. 14
149.87
101. 54
107.62
75.19
77. 14
800
900
1000
46.747
50.500
53.752
160.31
169.79
178.54
113.56
119.29
124.79
79. ]J
81.74
84.33
!!ELTING POINT
----------------------------------------------------------------------------------------------
BOlLI IIG POINT
kJ
kJ
IIOLAR VOLU!E
EIIT HlLPY OF !IELTIIIG
kJ/aol
kJ
4.0960 J/l)ar
40.960 ca 3
TRAIIISITIONS Ili REFERENCE STATE ELEftE!iTS

TIN II. P. 505 K.
SULFUR ORTHO-!IONO 368.54,
B. P. 716.9 K.
!1.
P.
!10110
388.36,

20.042 + 3.8228x1o-z T
(EQUATION VALID PROM
BEPEBEIIICE
192
120
8.5441x102 T-os
298 - 1000 K)
COl! PILED
7-24-76
PROPERTIES .lT HIGH TEIIPERATURES
SPHll. ElUTE
zns:
135
FORI!U L.l II EIGHT
Cubic crystals 298.15 to 1200 K.
llurtzite is the stable phase of
97.440
zns
above 1293 K.
-------------------------------------------------------------------------------FORIIATIOII FROB THE ILEBENTS

TEI'IP.
K
so
(H;-H;98 )/T
J/aolK
cop
-(~-H~ 98 )/T
J/aolK
JtaolK
0.13
0. 13
JtaolK
ENTHALPY
GIBBS
FREE EIIEilGY
kJtaol
Log Kt
kJ/aol
-------------------------------------------------------------------------------35.477
45.76
-206.900
-202.496
298.15
o.ooo
58.66
58.66
UIICERTAIIITY
1.700
400
500
600
12.000
19.432
24.618
72.49
83.46
92.67
60.49
64.03
68.05
48.30
49.93
51. 11
700
28.471
100.62
72.15
52.04
800
900
1000
31.466
33.867
35.853
107.62
113.87
119.53
76.15
80.00
83.68
52.79
53.42
53.96
1100
37.521
124.70
87. 18
54.43
1200
1300
38.948
40.186
129.45
133.86
90.50
93.67
54.85
55.23
1.780
-------------------------------26.203
-209.378
-200 .o55
-211.067
-212.397
-198.231
-195.581
20.709
17.027
-276.217
-275.827
-183.699
-173.43)
10.662
9.059
-275.399
-163.226
7.751
-388.484
-131.100
5.268
-------------------------------14.371
-192.592
-220.819
--------------------------------194.035
12.669
-276.553
-------------------------------6.571
-390.047
-150.953
!!ELTING POIIIT
BOILING POINT
ENTHALPY OF IIELTI NG
kJ
I!OLAR VOLUIIE
kJ
0.312
K
kJ
2. 38 JO J/bar
23.830 ca 3
TRAIISITIONS IM REFERENCE STATE ELEBENTS

ZIIfC II.
P. 692.7, B. P.
1178 K.
SULFUR ORTH0-110110 368.54, 11. P. MONO 388.36,

B. P. 716.9 K.
61.506 + 7.6314x1o- T
(gQUATIOII VALID FROB
REFERENCE
208
120
2. 6035x 1 oz T- o s
1300 K)
2 98 -
COMPILED
7-24-76
THEBftODYRlftiC PROPERTIES OF ftiiERlLS
136
FORftO L1 WEIGHT
WU RTZITE
97.440
============================================s==================================
zns:
-------------------------------------------------------------------------------FOBftlTIOII FBOII THE ELEIIEIITS

TEftP.
(a;-a~ 98 )/T
J/aol K
so
J/aol K
-(~-H~ 98 )/T
J/aolK
Cp
EliTHlLPY
GIBBS
FlEE EliEBGY
kJ/aol
J/aolK
Log Kf
kJ/aol
--------------------------------------------------------------------------------194.570
-190.220
298.15
o.ooo
58.811
58.811
45.88
33.326
UNCERTAINTY
0.12
o. 12
1. 500
1100
500
600
12.100
19.570
211.7115
72.78
83.81
93.011
60.68
611.211
68.30
118.71
50. 13
51.08
700
28.563
100.97
72.111
51.85
800
900
1000
31.519
33.889
35.855
107.911
1111. 17
119.81
76.112
80.28
83.95
52.54
53.20
53.85
1100
37.520
124.97
87.115
511.50
1200
1300
38.962
110.232
129.74
134.18
90.78
93.95
!!ELTING POINT
55.14
55.79
1. 5.20
0.266
--------------------------------197.008
-188.1101
24.603
-198.668
-199.991
-186.007
-183.397
19.1132
15.966
--------------------------------208.425
-180.4113
13.465
--------------------------------181.919
11.878
-2611.181
-263.861
-263. 495
-111.619
-161.381
9.961
8.430
-263.070
-151.194
7. 18(1
--------------------------------138.955
-371.701
6.049
-376.095
-119.127
4.787
BOILI RG POINT
ENTHALPY OF I!ELTING
kJ
EliTHALPY OF VAPORIZATION
kJ
llOLlB VOLUftE
kJ
2.3846 J/bar
23.846 c11 3

ZINC 1!. P. 692.7, B. P. 1178 K.
SULFUR ORTHO-I!ONO 368.54, 1!. P. IIONO 388.36,
B. P. 716.9 K.
41.906 + 7.6193x1o-:s T
( i:XlOATION VALID FRO!!
REFERENCE
208
2118
1. 5767x 11.12 T-o s

298 - 1300 K)
215
2
COIIPU.ED
7-211-76
137
PBOPEBTIBS lT HIGH TEI!PEBlTOBBS
COBOIIDOI!
FOifiULl IIBIGHT
101.962
( Corundua), crystals 298. 1S to aelting point 234S !C.
-------------------------------------------------------------------------------POBI!ATIOII PBOII THE ELBI!BIITS

TEI!P.
so
T
<H;-u; 98 )/T
I(
J/aollt
J/aolK
-(G;-8~ 98 )/T
J;aolIC
Co
EIITHALPY
J/aollt
GIBBS
PBBB EIIEBGI
kJ/aol
Log ltf
kJ/aol
-------------------------------------------------------------------------------298.1S
-1S82.228
277.201
0.000
so. 92
so. 92
79.01
-1675.700
UIICBB Tli IITY
0.10
0.10
1.300
1. 320
0.231
-1676.304
-167S.984
-167S. 264
-1674.1f01t
-1673.S65
-1672.865
-1SS0.162
-1S18.6S4
-1487.2S7
-11t55. 990
-1421f.841
-1393.793
202.1131
1S8.6S3
129.1t78
108.648
93.033
80.894
400
500
600
700
800
900
22.575
38.372
50.187
59.371
66.7S6
72.833
76.85
99.47
119.38
137.02
1S2.83
167.13
54.27
61.10
69.19
77.64
86.07
94.30
96.39
1 OS. 95
112.19
116. 6S
120.04
122.73
1000
17.935
180.18
102.25
124.94
1100
1200
1300
1400
1500
1600
1700
1800
82.291f
86.070
89.378
92.307
94.921f
97.217
99.409
101.352
192. 17
203. 28
213.61
223.27
232.34
240.90
249.00
256.68
109.88
117. 21
124.23
130.96
137.42
143.62
149.59
1S5.33
126.79
128. 38
129.77
130.99
132.08
133.07
133.96
134.78
BOlLI BG POIIIT
2345
!IBLTI BG POI BT
BBTHALPI OP !ELTING
a;98 -
-------------------------------71 .1 07
-1691.698
-1361.288
-1692.719
-1691.635
-1690.457
-1689.203
-1687.872
-1686.481
-1685.029
-1683.527
-1328.080
-1294.993
-1261.96"
-1229.065
-1196.232
-1163.513
-1130.906
-1098.329
63.066
S6.370
so. 707
45.857
111.657
37.985
34.749
31.873
It
BITBALPI OF YAPOBIZlTIOII
H~
10.016 kJ
2 .SS75 J/llar
25.575 ca 3
!OL 11 VOL 011 I
TBliSITIOIIS IB REFBBEBCE STlTB ELEIIEBTS

ALOI!IJO! 1!. P. 933 lt.
HEAT CAPACITY EQOlTIDII
1.5736x102 +
7.1899x10- T
9.8804x102
298 - 1800 !C)
r-os
( EQOlTIOI VALID PRO!
BBFEREIICB
28S
50
50
66
35
159
COIIPILBD
7-21-76
138
ALUMINUM OXIDE (GAMMA)
Al 2 0 3
FORMULA
WEIGHT
101.962
-------------------------------------------------------------------------------FORMATION FROM THE ELEMENTS

TEIIP.
(H~-H~ 98 )/T
J/IIIOlK
sr
-(G;-H~ 98 )/T
J/lllolK
J/mol K
b. 28
&.28
cop
ENTHALPY
GIBBS
FREE ENERGY
kJ/11101
J/molK
Log Kf
itJ/11101
-------------------------------------------------------------------------------:.!98.15
-1653.517
-15&2. 702
273.780
0.000
59.83
59.83
79.02
UNCERTAINTY
400
5(J(J
60(1
700
800
900
22.600
38.406
50.222
59.407
66.777
72.844
85.79
1(18.43
128.34
145.98
161.78
176.08
63.19
70.02
78.12
86.57
95 .oo
10 3. 24
96.49
1u&. 01
112.20
116.62
119.99
122.67
1000
77.940
189.12
111.18
124.89
1100
1200
1300
1400
15()0
1600
1700
1800
82.295
86.070
89.380
92.314
94.937
97.300
99.445
101.402
201.11
212.21
222.54
2 32.21
241.29
249.86
257.97
2&5.67
118.81
126. 14
133. 16
139.90
14&. 35
152.56
158.53
164.27
12&.76
128.38
129.81
131.08
1J 2. 23
133.27
134.23
135.12
BOlLING
2291
MELTING POI NT
94. 140 kJ
ENTHALPY OP !!ELTING
kJ
1.2&0
1. 300
0.228
-1654.111
-1653.784
-1&53.0&0
-1652.20()
-1651.365
-1650.672
-1531. 545
-1500.934
-147(1.429
-144u.u51l
-1409.801
-1379. 655
200.000
156.802
128.1.113
1u7.459
92.051
80.073
-1670.534
-1669.452
-1668.272
-1667.010
-1665. 670
-1&&4. 262
-1662.786
-1&&1.254
- 1315.729
-12t!J.526
-1251.388
-1219.388
-1187.455
-1155. b]O
-1123.912
-1092.238
62.479
55.871
50.282
4 5.496
41.351
37.728
3 ... 534
31.696
--------------------------------1348.040
70.415
-1671.510
POINT
kJ
IIOLAR VOLUME
J/bar

ALUIIINUM K. P.
HEAT CAPACITY
933 K.
EQUATION
1.5343x10Z +
1.9681x10-:J T
298 -
REFERENCE
32
32
9.u063x10Z T-05
1800 K)
32
COMPILED
7-27-76
139
PROPERTIES AT HIGH TEMPERATURES
BOEHI!I TE
FOii!ULA WEIGHT
AlO(OH):
TEIIP.
59.989
so
H;-H~98 )/T
J;aolK
-(G~-H~ 98 )/T
J/aolK
J/IIIOlK
FOBllATIOIII FBOI! THE ELEI!EHTS

GIBBS
FBEE EIIEBGY
Log Kf
cop
EIITHALPY
kJ;aol
J/llol K
kJ/mol
2. 110
2.090
0.366
67.43
69.18
-993.589
-992.924
-892.723
-867.565
116.583
90.640
-------------------------------------------------------------------------------298.15
o.ooo
48.45
48.45
65.63
-993.054
-918.400
160.900
UNCERTAINTY
400
500
16.297
28.660
0.21
0.21
67.19
84.54
50.90
55.88
IU:LTING POI NT
BOILING POINT
E liTH ALPY 0 f' I!EL TIIIG
kJ
8.828 kJ
!lOLA i
VOLU 1!E
kJ
1.9535 J/bar
19.535 ca 3
TRANSITIONS Ill iEFERENCE STATE ELEI!EIIITS

ALUI!IIIIUII II.
P.
933 K.
c~
60.396 +
1.7573x1o-z T
REFERENCE
115
120
298-
500 K)
94
216
COI!PlLED
7-14-77
140
THERitODYiilli!IC PROPERTIES OP IUNER&LS
FORitllLA !lEIGHT
GIBBSITE
Al( OH
TEIIP.
Crystals
h:
u;-H~ 98 )/T
J/IIOlK
298.15
so
to
480
K.
Gibbsite deco11poses above
-(G;-H~ 98 )/T
J/IIOlK
J/1101 K
cop
480
78.004
K.
FORit&TION FRO It THE ELEIIENTS

GIBBS
Log
PBEE ENERGY
ENTHALPY
kJ/1101
J/aol K
Kf
kJ/1101
--------------------------------------------------------------------------------1154.889
202.333
298.15
68.44
68.44
-1293.128
o.ooo
91.70
o.
UIK:ERTAI NTY
400
26.467
14
0.14
98.83
72.36
115.10
1. 192
1. 213
0.213
-1294.070
-1106.856
144.543
IIELTING POINT
BOI LI VG PO Ill T
ENTHALPY OF MELTING
kJ
ENTHALPY OF VAPORIZ&TIO'll
kJ
12.719 kJ
3.1956 J/bar
31 .956 CIIJ
ISOLA R VOLUME
TRANSITIOIIS IN REFERENCE STATE ELEIIEIITS

ALUIII NUll
REFERENCE
95
II.
P. 933 K.
95
93
COI!PILED
7-24-76
141
PROPERTIES AT HIGH TEIIPEBATORES
BORIC OXIDE
FORIIULA WEIGHT
69.618
-------------------------------------------------------------------------------FORIUTION FRO II THE ELEIIENTS

TEIIP.
J;aolK
so
-(G;-H~ 98 )/T
cop
J;aolK
J/1101 K
J/1101 K
H;-a~ 98 );T
GIBBS
FREE ENERGY
EtrrHALPY
Log Kt
ltJ/1101
kJ/aol
--------------------------------------------------------------------------------1194.325
298.15
53.97
62.68
-1273.500
209.242
0.000
53.97
0.03
0.03
1.400
1. 715
(1.300
40(1
500
600
700
723
17.475
30.358
40.960
50.006
51.877
74.06
92.27
1(19.37
125. 43
130.48
57.28
61.91
68.41
75.42
78.61
75.28
88.20
99.43
108.88
110. 83
-1273.766
-1273.595
-1272.874
-1271.622
-1271.081
-1167.236
-1140.605
-1114. (169
-1087.697
-1082.695
152.426
119.159
96.989
81.165
78.24(1
800
900
100(1
87.200
92.294
96.257
173 .oo
188.69
202.59
85.80
9&.40
106.33
127.61
127.61
127.&1
-1246.430
-1242.998
-1239.930
-1064.070
-1041.492
-1019.266
69.4 77
60.447
53.242
1100
1200
1300
1400
1500
1600
1700
1800
99.381
101.870
103.905
105.616
107.093
108.386
109.529
110.525
215.05
226.31
236.56
246.06
254.84
263.(19
270.83
278.15
115.67
124.44
132. 66
140.44
147.75
154.70
161.30
167.62
127.61
127.61
127.61
127.61
127.61
127.61
127.61
127.61
-1237.209
-1234.815
-1232.681
-1230.752
-1228.986
-1227.369
-1225.899
-1224.623
-997.358
-975.680
-954.143
-932.828
-911.562
-890.459
-869.430
-848.466
47.361
42.470
38.338
34.804
31.743
29.071
26.715
24.625
BO ILl NG POINT
U.:ERTAI NTY
--------------------------------------------------------------------------------1082.695
723
82.317
160.92
78.240
78.61
127.61
-1249.073
IIELTI NG POI liT
723
ENTHALPY OF IIELTIIIIG
22.008 kJ
H~98
H~
9.301 kJ
kJ
2. 7220 J/bar
27.220 ca 3
IIOLAB VOLUIIE
TRANSITIONS Ill REFERENCE STATE &LE.IIEIIITS

BORON., II. p BETA 2300 K.
HEAT CAPACITY EQOATIOH
2.7845x10Z1.0123x1o-z T
(EQUATION VALID FROB 298 -
REFEREICB
247
35
262
4.5398x10~
T-o
723 K)
35
COMPILED
6- 2-76
142
THERilODYHA!!IC PROPERTIES OF IIINERAI.S
BARIU!l OX! DE
Bao:
FORI!U LA II EIGHT
153.339
-------------------------------------------------------------------------------PORIUTIOH FRO!! THE ELEMENTS

TEI!P.
H;-H~98
so
)/T
J/ol K
-(
G;-H~ 9 a)/T
J/aolK
J/molK
0.38
0.38
cop
GIBBS
FREE ENERGY
ENTHALPY
J/IIOlK
Log Kf
kJ/mol
kJ/aol
-------------------------------------------------------------------------------298.15
0.000
72.07
-520.394
91.171
72.07
47.28
-548.100
UNCERTAINTY
400
500
12.400
20.114
86.37
97.73
73.97
77.62
49.98
51.78
600
700
25.510
29.546
107.30
115.58
81.79
86.03
53. 17
54.33
800
900
1000
32.710
35.278
37.422
122.91
129.48
135.45
90.20
94.20
98.03
55.36
56.28
57. 15
1100
1200
1300
1400
1500
1600
1700
1800
39.253
40.843
42.248
43.507
44.641
45.677
46.632
47.518
140.94
146.02
150.75
155. 18
159.36
163.31
167.06
170.64
101.69
105. 18
108.50
111.67
114. 7 2
117.63
120.43
123.12
57.96
58.73
59.47
60.19
60.89
61.58
62.24
62.90
I!E LTI IIG
POI NT
ENTHALPY OF KELTING
2286
2. 090
2.100
0.368
-547.723
-547.974
-511.001
-501.805
66.730
52.423
-548.997
-483.070
- 549.525
-549.489
-464.114
-454.626
--------------------------------492.475
42.874
-548.930
36.047
--------------------------------473.613
30.924
-549.503
26.937
23.747
--------------------------------444.327
-557.762
21.099
-557.845
-557.761:1
-557.580
-557.241
-556. 830
-556.347
-555.812
-434.017
-423.694
-413.407
-403.102
-392.843
-382.606
-372.401
18.892
17.024
15.424
14.037
12.825
11.756
10.807
BOILING POI NT
58. 600 kJ
kJ
IIOLAR VOLUIIE
9. 983 kJ
2.55':10 J/bar
25. 590 Clll]

BARIUM ALPHA-BETA 582, BETA-GAI!IIA 768, II. P. GAIIIIA 1002,
B. P. 2169 K.
57.218 +
5.3703x10-J T
REFERENCE
33
155
33
1.668h102 T-05
298 - 1 8CIO K)
1. 6694x 105 T- 2
33
58
COMPILED
5-18-76
PROPERTIES AT HIGH TBBPEBlTURES

BBOI'IBLLITI
BeO:
POR!ULA lEIGHT
25.012
Crystals 298.15 to 1800 1.
-------------------------------------------------------------------------------l'O&IIATIOI FBO!I THE BLBBIITS

TEIIP.
sT
<H;-H;98 )/'f
.l/aollt
J/aolK
-c;;-s;98 >1T
.l/aolK
cop
BUHlLPI
J/aoll
GIBBS
FBEB EJBBGY
k.l/aol
Log Kt
k.l/aol
-------------------------------------------------------------------------------298.15
o.ooo
13.77
13.77
25.74
-609.1100
-580.078
101.628
UICDTAIITY
o.oq
0.04
2.500
2.500
O.ll38
111.89
17.26
20.14
23. 19
26.28
29.33
32.3i
33.99
38.89
42.21
114.65
46.55
48.07
119.34
-609.693
-609.658
-609.4411
-609.121
-608.729
-608.2911
-607.836
-570.003
-560.083
-550.179
-5110.332
-530.525
-520.769
-511.076
711.1135
58.512
117.898
40.320
311.640
30.225
26.696
so. 41
-607.371
-606.912
-606.471
-606.066
-605.694
-501.419
-1191.814
-482.243
-472.702
-463.194
23.811
21.408
19.377
17.637
16.130
1100
500
600
700
800
900
1000
13.'178
18.005
21.6116
24.645
27.167
29.322
22.59
30.71l
38.11l
U.81l
50.93
56.50
61.64
1100
1200
1300
1400
1500
31.192
32.832
34.288
35.586
36.761
66.39
70.82
111.96
78.85
82.52
35.20
37.99
ll0.67
43.26
45.76
51.33
52.14
52.86
53.49
1600
1700
1800
37.826
38.797
39.688
85.99
89.28
92.42
118.16
so. ll8
52.73
54.07
54.59
55.07
liE LTI
1.100
IG POI If
ENTHALPY OP !BLTIRG
2681
--------------------------------453.266
111.798
-620.0112
-619.1104
-618.727
-442.851
-432.499
13.607
12.551
BOILIIG POUT
65.610 kJ
BBTHALPY OP VAPORIZATIOI
2.883 kJ
IIOLAB VOLO!B
0.8309 J/bar
8.309 em 3
TRliSITIOHS II BIFBBEICE STATE ELBI'IEITS

BEBYLLIO!t ALPHl-BBTl 1527, B. P. 1560
lt.
HEAT CAPACITY BQUlTIOI

69.936 + 1.8288x10- T
( BQOlTIOI ULID PRO!
BBPEUICB
32
261
215
6.3574x 102 l'-os

298 - 1800 K)
215
CO! PILED
6- 8-76
144
THERIIODYNAIUC PROPERTIES OF IUNERALS
BERYLLIUII OXIDE (BETA)
BeO:
C~ystals
FORIIULA
IIEIGHT
2 5. 012
298.15 to 1800 K.
-------------------------------------------------------------------------------FORIIATION FRO II THE ELEIIE NTS

TEIIP.
(H;-H~ 98 )/T
Jjllo1K
ST
-( G;-H ~ 98 )/T
Jjao1K
Jjmo1K
0.03
o. 03
cop
ENTHALPY
J/aol K
GIBBS
FREE EIIERGY
kJ/1101
Log
Kf
kJ/1101
-------------------------------------------------------------------------------298. 15
u.OlJO
-6()1.785
-573.289
100.438
16.54
16.54
25.56
UNCERTAINTY
3.500
3.
suo
().613
400
':}0()
60()
700
800
900
1000
7.65()
13.432
11. 968
21.626
24.639
27.167
29.328
25.3.2
33.45
4().85
47.56
53.67
59.25
64.38
11.67
2(). 02
22.88
25.93
29. OJ
32.08
35.05
33.84
31:1.85
42.26
44.75
46.64
48. 13
49.35
-602.098
-602.066
-6()1. 851
-601.52()
-601.119
-600.679
-600.215
-563.500
-553.846
-544.212
-534.635
-525.107
'-515.629
-506.195
73.586
57.860
47.371:1
39.895
34.286
29.926
26.441
1100
1200
1300
1400
150()
31. 196
32.833
]4. 282
35.579
36.749
69.14
73.56
11.10
81.58
115.25
37.94
40.73
43.42
46.00
48.50
50.38
51 .0
52.06
52.79
53.47
-599.751
-599.296
- 598. 863
-598.461
-598.097
-496.824
-487.486
-478.197
-468.919
-459.692
23.592
21.220
19.214
17.496
16.008
1600
1700
1800
37.815
38.79]
39.698
88.72
92.02
95.17
so. 91
53.23
55.47
54. 12
54.76
55.39
-611.796
-611.094
-439.901
-429.816
13.511
1.2.473
2720
IIELTIHG POI NT
--------------------------------45().()36
-612.444
14.692
BOIL I IIG POIIIT
59. 120 kJ
kJ
kJ
IIOLAR VOLUIIE
J/bar

BERYLLIUII
ALPHA-BETA 1527, II.
P.
1560 K.
!:19. 212 -
1.1200x1o-z T
-:l.6822x105 r-z
REFERENCE
32
32
298- 18()0 K)
32
COIIPIL ED
7-29-76
PROPERTIES AT HIGH TEftPERATURES

BISftiTE
145
FORftULA WEIGHT
465.959
crystals 298.15 to eltioq point 1098 K.
-------------------------------------------------------------------------------FORftATION FROft THE ELEftENTS

TEftP.
so
-(G;-a~ 98 )/T
cop
J/IIOlK
J/olK
J/olK
2.(19
2.09
< H;-H~ 98 )/T

J/olK
ENTHALPY
GIBBS
FREE EIIERGY
kJ/1101
Loq Kf
kJ/ol
-------------------------------------------------------------------------------298.15
151.46
-493.453
o.ooo
151.46
113.51
-573.877
86.451
UIICERTAI IITY
1.255
1. 464
0.256
-571.969
-570.217
-466.275
-440.062
6(1.89(1
45.973
-589.459
-587.257
-382.105
-352.637
28.513
23.025
400
500
29.325
47.184
185.29
211.74
155.9&
164.56
116.90
120.24
600
700
800
59.638
69.011
76.457
233.96
253.26
270.42
174.32
184.25
193.96
123.58
12&.91
130. 25
BOlLING POI NT
kJ
kJ
kJ
ftOLAR VOLUIIE
IIELTI liG POINT
1u98
--------------------------------591.288
-411.873
35.857
4.9730 J/bar
49.7 30 ca 3
TRANSITIONS IN REFERENCE STATE ELE8ENTS

BISIIUTH ft. P. 544.5, B. P. 1835 K.
c;
1.0356x10Z +
3.J360x1o-z

REFERENCE
115
262
r
298 -
800 K)
262
161
COftPILED
5-26-76
THERMODYMAMIC PROPERTIES Of MIHERALS
146
CARBON IIOHOXIDE
CO:
FOBI!ULA WEIGHT
28.11111
-------------------------------------------------------------------------------FOBI!ATIOII FROM THE E.LEUIITS

so
( H~-H~ 98 )/T
TEI!P.
J/molK
J/molK
-(G;-H~g 8 )/T
J/llo1K
cop
ENTHALPY
GIBBS
FREE E!IIERGY
kJ/1101
kJ/1101
J/ao1K
.Log Kf
------------------------------------------------------------------------------~-
0.1100
197.67
0.113
29.14
UIIICEBTAINTY
197.&7
11.03
-110.5311
11.170
-137.171
0.170
24.1132
11.030
400
500
6110
700
800
900
1000
7.375
11.792
14.857
17.15<)
18.975
20.456
21.705
.20&.19
212.75
218.26
223.03
227.26
231.07
234.53
198.81
200.96
203.411
205.87
208.28
210.61
212.82
29.10
29.79
30.58
31.34
32.03
32.64
JJ.18
-11U.13b
-110.059
-110.20&
-110.509
-110.925
-111.429
-111.984
-146.346
-155.409
-1&4.473
-173.496
-182.465
-191.385
-.200.224
19. 111
16.236
14.319
1.2.946
11.914
11.108
10.459
1100
1200
1300
1400
1500
1600
17110
11100
22.771
23.697
24.513
25.236
25.891
26.480
27.U16
27.501l
2J7. 72
240.67
24 3. 41
245. 98
248.40
250.68
252.84
254. !l9
214.95
216.97
218.90
220.74
222.51
224.20
225.82
.227.38
33.67
34.10
34.49
34.1:l5
35.17
35.47
35.74
35.99
-112.587
-113.221
-11]. 871
-114.553
-115.23()
-115.917
-11&.609
-117.303
-2119.024
-217.771
-.22&.444
-235.079
-243.&75
-252.213
-.2&0. 12b
-269.169
9.'JLb
298. 15
MELTING POINT
ENTHALPY OF MELTING
&8.05 K
BOILING POINT
0. 837 kJ
8.673 kJ
MOLAR VOLUME
'1.479
9.1199
8. 771
8.486
1:1.234
8.011
7.811
81.61 K
&.042 kJ
2478.9200 Jjbar
24789.200 cm 3
9.7115x1o-s T
45.730-
REFERENCE
247
35
4.1469x102 T-os
298 - 1800 K)
35
COMPILED
5-24-76
PROPERTIES AT HIGH TE!PERATUBES
147
CARBOM DIOXIDE
C0 2
PORilULA WEIGHT
44.010
-------------------------------------------------------------------------------POR!ATION FRO! THE ELEilENTS

TEilP.
so
-(G;-a~ 98 )/T
cop
J/II01K
J/1101 K
JjaolK
0.04
0.04
(H~-H; 98 )/T
J/ao1K
ENTHALPY
GIBBS
FREE EIIERGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
&9.093
0.000
213.79
213.79
37.13
-393.510
-394.375
UNCERT AIIITY
0.130
0.167
0.029
400
500
600
700
800
900
1000
9.975
16.588
21.505
25.371
28. 526
31.167
33.416
225.28
234.87
24 3. 26
250.74
257. 50
2&3.&5
269.31
215.31
218.28
221.75
225.37
228.97
232.48
235.89
41.23
44.65
47.42
49.&6
51.49
53.02
54.30
-393.588
-393.685
-393.823
-393.994
-394.184
-394.388
-394.600
-394.660
-394.920
-395.149
-395.359
-395.544
-395.694
-395.830
51.538
41.257
34.401
29.502
25.826
22.966
20.676
1100
1200
1300
1400
1500
1600
1700
1800
35.365
31.072
38.582
39.929
41.140
42.234
43.228
44. 134
274.53
279.39
283.93
288.19
292.20
295.98
299.57
302.97
239.17
242.32
245.35
248.26
251.06
253.75
256.34
258.84
55.38
5&.30
57.10
57.78
58.38
58.89
59.34
59.74
-394.814
-395.027
-395.236
-395.442
-395.640
-395.834
-396.023
-396.211
-395.936
-396.035
-396.107
-396. 111
-396.225
-396.250
-396.293
-396.282
18.802
17.239
15.916
14.781
13.798
12.936
12.177
11.500
MELTING POINT
ENTHALPY OF !ELTING
kJ
BOILING POINT
kJ
!OLAR VOLUME
9.3&4 kJ
2478.9200 J/bac
24789.200 ca 3
TRANSITIONS IN REFERENCE STATE ELEilENTS

87.820 -
2.6~42x10-3

REFERENCE
247
35
96
9.9886x10Z T-os
298- 1800 K)
35
COilPILED
5-24-76
148
THERMODIBABIC PROPERTIES OP ftiMERALS
PO Rft ULA WEIGHT
CALCIUM OXIDE
56.079
====:===========================================================================
cao:
crystals 298.15 to 1800K.
-------------------------------------------------------------------------------FORMATION PROM THE ELEnE lilTS

TEI'IP.
so
-( G;- H~ 9 8 )/T
cop
J/molK
J/molK
J/mol K
0.13
0.13
H~-H; 9 8 )/T
J/olK
ENTHALPY
GIBBS
FREE EURGY
Log Kf
ltJ/ol
kJ/ol
-------------------------------------------------------------------------------105.729
-603.487
-635.089
298.15
38.21
0.000
38.21
42.12
UNCERTAIBTY
400
500
600
700
11.375
18.684
23.863
27.743
51.31
61.99
71.06
78.92
39.93
43.31
47.20
51.18
46.65
48.98
50.46
51.53
suo
900
1000
30.771
33.211
35.235
85.86
92.07
97.70
55.09
58.86
62.47
52.39
53. 10
53.73
11ov
36.943
102.85
65.91
54.30
1200
1300
1400
1500
1600
1700
38.412
39.695
40.829
41.845
42.761
43.596
107.60
112.01
116.12
119.99
123.64
127.09
69.19
7 2.31
75.29
78.15
80.88
83.49
54.84
55.34
55.82
56.28
56.73
57.17
1800
44.362
13 0. 37
86.01
57.60
I'IELTING POINT
3200
0.879
0.900
0.158
-634.672
-634.105
-633.569
-633.161
-592.746
-582.330
-572.024
-561.803
77.405
60.836
49.799
41.922
-633.570
-633.837
-541.275
-531.007
31.415
27.737
-634.485
-520.701
24.726
-641.671
-640.855
-640.001
-639.117
-638.201
-498.671
-487.695
-476.786
-465. 941
-455.137
20.037
18.196
16.603
15.211
13.985
--------------------------------551.540
36.01:l
-633.672
-------------------------------22.187
-509.696
-6112.458
--------------------------------441.040
12.799
-790.750
BOILING POINT
79.496 kJ
6.749 ltJ
ltJ
1.6764 J/bar
16.764 c 3
I'IOLAR VOLUBE

CALCIUI'I ALPHA-BETA 720, 1'1. P. BETA 1112, B. P. 1755 K.
52.422 +
3.6734x10-3 T
REFERENCE
33
33
50.988 T-os
1800 K)
298 -
33
COMPILED
5-18-76
PROPERTIES AT HIGH !EI!PERATORES

PORTLUDITE
Ca(OH) 2
FORIIULl WEIGHT
711.095
-------------------------------------------------------------------------------FORIIATIOM FRO II THE ELEI!IEIITS

so
GIBBS
FREE EIIERGY
-(G;-u; 98 )/T
cop
J/aolK
J/aolK
J/aolK
0.112
0.112
110.&9
133.27
152.&11
169.511
8&.9&
911.011
102.22
110.66
97.92
1011.11
108.21
110.87
I!IELTIHG POUT
BOILUG POUT
kJ
BITHALPY Ol VAPORIZATION
kJ
TEI!P.
( H~-H; 98 )/T
J/aolK
EI!ITHALPY
Log Kf
kJ/aol
kJ;aol
-------------------------------------------------------------------------------298.15
0.000
83.39
83.39
-98&. (185
-898.1108
157.398
87.119
UIICERTAI IITY
1100
500
&00
700
23.725
39.2311
50.1118
58.817
111.159 kJ
1.255
1.300
0.228
-985.203
-983.757
-982.072
-980.365
-8&8.11711
-839.1183
-810.791
-782.1107
113.1112
87.701
70.586
58.3811
IIOLAR VOLOIIE
3.3056 J/bar
33.056 ca 3
TRANSITIOIIS IN REFERENCE STATE ELEIIEIITS

CALCIUII ALPHA-BETA 720, B. P. BETA 1112 9 B. P. 1755 K.

1.8667x102 - 2.1911x1o-z T
(EQUATION VALID FROI!I 298 -
REFEREICE
32
32
86
1.5998x10ll
100 K)
,-os
32
86
COI!IPILED
1- 1-76
THEB!ODJNABIC PROPERTIES OF !INEBALS
150
CEBIUIITE
FORMULA WEIGHT
Crystals 298.15 to
18~~
172.119
K.
-------------------------------------------------------------------------------FOB!ATION FRO! THE ELEMENTS

TEMP.
so
-cG;-H~ 98 )/T
cop
J/aolK
J/IIIOlK
J/aolK
( H;-H~ 98 )/T
J/IIOlK
ENTHALPY
GIBBS
FREE ENERGY
Loy Kf
kJ/1101
kJ/aol
-------------------------------------------------------------------------------62.
298.15
-1u25.38o
179.643
o.ooo
-1088.68u
62.30
61.63
](J
UNCEBTAI IITY
400
500
~.08
1.464
2.929
0.513
64.8~
-1u87.9o6
-1086.939
-1085.943
-1084.994
-1084.125
-1083.352
-1~~3.866
131.u92
102.690
8 3. 773
70.273
60.157
52.294
0.08
900
16.525
27.080
34.573
40.209
44.631
48.222
81.33
96.78
109.91
121.31
131.41
140.47
69.70
75.34
81.10
86.78
92.25
67.52
70.84
73.12
74.86
76.29
77.52
1000
51.206
148.69
97.48
78.62
1100
1200
53.745
55.942
57.870
59.586
61.125
62.523
63.802
64.980
156.23
16 3. 20
169.69
175.75
181.46
186.85
191.95
196.81
102.49
107.26
111.82
116.16
120.33
124.33
128.15
131.83
79.63
80.57
81.45
82.29
83.1u
83.88
84.64
85.38
6~0
700
80~
13~0
1400
1500
1600
170~
1800
-982.964
-962.265
-941.725
-921.325
-901.012
--------------------------------d80.787
46.008
-1085.610
-------------------------------40.846
-1090.5~1
-86~.172
-1089.810
-1089.066
-1088.267
-839.262
-!118.432
-797.627
-176.904
-756.245
-735.616
-715.065
-1~87.419
-1086.517
-1085.561
-1084.551
!!ELTING POINT
BOILING POINT
ENTHALPY OF !ELTING
kJ
IIOLAB VOLUME
10.368 kJ
36.532
32.885
29.760
27. ~54
24.6!19
.a.6~3
20.751
kJ
..1.3853 J/bar
23.853 CIIJ
TRANSITIONS Ill REFERENCE STATE ELEKENTS

CERIUM BETA-GA!!A
HEAT CAPACITY
999, !. P.
K.
E~UATIOII
80.292 +
5.6994x10-3 T
(EQUATION VALID FBO!

REFERENCE
1~71
13~
279
2.0990x10Z T-os
298 - 1800 K)
235
8
COI!PILED
6- 2-76
CERIUM SESQUIOIIDE (HEIAGONAL, )
Cez0 1 :
151
FORMULA WEIGHT
328.238

TEMP.
so
-(G;-H~ 98 )/T
cop
J/olK
J/olK
J;aolK
4.1tl
4.18
(H;-a~ 98 )/T
J/IIOlK
EWTHALPY
GIBBS
FREE EIIERGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
150.62
o.oou
150.&2
124.37
-179&.200
-1707.94(1
299.225
UNCERTAINTY
8.400
8.400
1.472
-1793.790
-1791.054
-1788.273
-1785.571
-1783.000
-1780.585
-1678.148
-1649.544
-1621.506
-1593.932
-1566.732
-1539.826
219.145
172.327
141.165
118.941
102.298
89.370
400
500
600
700
800
900
31.425
51.400
65.525
76. 136
84.475
91.267
186.82
21&. 09
240.90
262.45
281. 52
298.66
155.39
164.69
175.38
186.31
197.05
207.39
128.13
134.00
138. 11
141.40
144.25
146.84
1000
96.942
314.25
217.31
149.27
MELTING POINT
BOILING POINT
ENTHALPY OF MELTING
ltJ
kJ
21.4&4 kJ
--------------------------------1784.337
-1513.197
79.042
4.775() J/bar
47.750 c11 3
IIOLAR VOLUME

CERIUM BETA-GAMMA
999, M. P. 1071 K.
HEAT CAPACITY EUUATION
c:
1.3066x102 + 2.0315x1o-z T
1.7053x10 T-z
(EQUATION VALID FROM 298- 1000 K)
REFERENCE
202
113
235
105
CO!lPILED
5-18-76
152
THER!ODYWA!IC PROPERTIES OF MINERALS
CERIU! SESQUIOXIDE (HEXAGONAL,
Ce
2 0~:
FORMULA WEIGHT
~)
328.238
FORMATION FRO! THE ELEMENTS

GIBBS
FREE ENERGY
ENTHALPY
Log f
TEI!P.
J/olK
2 98. 15
o.ooo
UNCERTAINTY
kJ/ol
o.oo
131.01
400
500
600
700
800
900
33.3 50
54.036
68.578
79.539
88.227
95.389
38.45
68.94
94.69
117.08
136.98
154.96
134. 21
139.15
143.35
147.21
150.88
154.45
1001J
101.469
171.41
157.95
1100
1200
1300
1400
1500
106.761
111.458
115.695
119.571
1 2 3. 1 53
186.63
200.82
214.15
226.74
238.70
161.41
164.84
168.24
171.63
175.02
kJ/ol
---------------------------------------------------------------
!!ELTING POINT
BOILING POINT
kJ
kJ
kJ
!IOLAR VOLUliE
J/bar
TRANSITIONS IN REFERENCE STATE ELEIENTS

CERIU!! BETA-GAIII!A
999, ft. P. 1071 K.

c~
1.2532x1oz + 3.3341x1o-z T
7.1123x1os T-z
(EQUATION VALID FRO!! 298 - 1500 K)
REFERENCE
202
CO!PILEO
6- 8-76

COBALTOUS 01 IDE
CoO:
153
FORftULA WEIGHT
74.933
-------------------------------------------------------------------------------FORIIATIOII FRO!! THE ELE!IEIIITS

TEftP.
so
-(G~-H~ 98 )/T
cop
J/aolK
J/aolK
J/aolK
0.34
u.34
(a;- H~ 98 )/T
J/aolK
EIITHALPY
GIBBS
FREE EIIERGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.oou
52.97
52.97
43.32
-237.940
-214.194
37.526
UIICERTUIITY
400
500
60(J
13.525
21.456
26.930
67.18
79.03
tl8.93
53.&5
57.57
62.00
51.86
53.99
54.50
7uo
800
9(J(J
1000
3u.88u
33.865
36.222
38.158
97.34
104.66
111. 14
117.00
&b.4&
70.80
74.92
78.84
54.66
54.89
55.29
55.91
1100
12(J(J
1300
39.807
41.259
42.572
122.36
127.34
132.01
82.55
86.08
89.44
56.74
57.75
58.94
1400
15(J(J
1600
nov
43.786
44.936
46.035
47. 102
13&.43
140.b3
144.67
148.5()
92.64
95.&9
98.63
101.4&
60.28
&1. 75
63.33
&S.u2
11luo
48.14&
152.32
104.17
66.80
!IEL TI IIG POI liT
2078
EIITHALPY OF !!ELTIIIG
1.255
1.297
O .l27
-23&.659
-235.611
-234.b59
-205.725
-198.111
-190.70(J
26.865
20.697
1b.602
-233.667
-233.214
-232.949
-17&.223
-169.u62
-161.959
11.506
9.812
8.460
-232.896
-233.105
-233.644
-154.862
-147.755
-140.629
7.354
().432
5.651
-23&.u75
-238.172
-241.004
-12b.155
-118.772
-111.235
4.393
3.878
3.418
--------------------------------233.8&1
-183.439
13.&88
--------------------------------234.606
-133.456
4.<J79
--------------------------------248.550
-104.424
3.03u
BOILIIIG POIIIT
kJ
EIITHALPY OF VAPORIZATIOII
kJ
kJ
BOLAR VOLUME
1.1b4u J/bar
11.640 ca 3
TRAIISITIOIIS Ill REFEREIICE STATE ELE!EIITS

COBALT ALPHA-BETA 700, CURIE P. 1394,
ft.
P. BETA 17b8 K.

30.468 +
2.9459x1o-z T
(EQUATIOII VALID FROB

BEPERBIICE
129
120
298 -
1.9317x103
1800 K)
r-os
263
COBPILED
&- 8-76
154
ESKOLAITE
FORIIULA WEIGHT
151.99u
Beta crystals Z98.15 to melting point Z603 K.

TEMP.
( H~-H~ 98 )/T
J/molK
s~
-{G;-H~ 98 )/T
cop
J;molK
J/IIOlK
J/IIIOlK
ENTHALPY
GIBBS
FREE ENERGY
kJ/1101
Log Kf
kJ/11101
--------------------------------------------------------------------------------1(153.(!56
Z98.15
-1134.700
184.492
o.uoo
1:!1.17
il1.17
101.34
UNCERTAINTY
1.25
1.25
8.370
8.400
1.47Z
900
1000
28.125
45.686
57. 9 53
67.049
74.097
79.756
84.408
113.45
139.30
161.05
179.79
19b.27
210.99
2.24.30
85.32
93.61
1CJ3.1u
112.74
122.17
131.23
139.89
113.64
117.85
120.57
12.2.60
1.24 .24
125.67
126.97
-1132.992
-1131.195
-11.29.398
-1127.690
-1126.126
-1124.741
-11.<!3.581
-10.25.37()
-991:1.61:!0
-97.2.345
-946 .299
-920. 506
-894.863
-869.391
133.9(!0
104. 132
84.650
70.b14
6(). l(J]
51.937
45.413
1100
1.200
1300
1400
1500
1600
1700
1800
1:18.332
91.700
94.635
97.229
99.549
101.64.2
1CJ3. 55(!
105.302
.236.45
.247.66
258.()5
267.76
276.86
.285.45
.293.58
301.30
148.12
155.96
163.41
170. 53
177.31
183.81
190.03
196.00
128.17
-1122. b61
-1122.011
-1121.647
-1121.597
-1121.869
-1122.491
-1123.476
-1124.843
-844.020
-818.729
-793.464
-768 .239
-742.968
-717.717
-692.397
-667.01.2
40.079
35.639
J1.882
28.663
.25.873
23.431
.:!1 .275
19.356
400
500
600
700
suo
!!ELTING POINT
13().42
131.49
13.2.54
133.57
134.58
135.59
BOILING POI NT
2603
129.32
kJ
kJ
KOLAR VOLUME
k.J
2. 9090 J/bar
29.090 c11 3

CHROIIIUII M. P .2130 K.
HEAT CAPACITY
E~UATION
1.1902x102
9.4964x10-3 T
3.4045 T-os
.298- 1800 K}
{EQUATION VALID FBOII
REFERENCE
33
33
33
158
COftPILED
6- 8-76
155
CESIUM HYDROXIDE
CsOH:
FORMULA WEIGHT
149.913
Crystals 298.15 to 1000 K. CsOH melts at 588 K. The heat capacities

over the range 298.15 to 1000 K have been estimated.
TEMP.
( H;- H~ 98 }/T
JjaolK
soT
-(G;-H~ 98 )/T
cop
J/aolK
J/molK
J/aolK
4.18
4.18
FOBIUTION FRO! THE ELEI!IEHTS

GIBBS
Log Kf
ENTHALPY
FREE EIERGY
kJ/1101
kJ/1101
-------------------------------------------------------------------------------298.15
98.74
67.86
-416.726
-370.690
64.944
o.ooo
98.74
UNCERTAINTY
0.837
400
500
18. 127
44.936
119.61
152.58
101.49
107.64
74.39
82.42
700
800
900
55.970
59.434
62.128
180.68
191.85
201.71
124.71
132.42
139.59
81.59
81.59
81.59
1000
64.282
210.53
146.25
81.59
0.850
0.149
--------------------------------418.538
-354 .!92
46.266
-409.61il
-338.759
35.390
-404.549
-401.965
-399.639
-311.2il8
-298.137
-285.297
23.229
19.466
16.558
-------------------------------------------------------------------------------600
51.352
167.78
-407.182
-324.805
28.277
116.43
H1. 59
IIEL TI NG POI NT
588
ENTHALPY OF !ELTING
4. 561 kJ
kJ
--------------------------------268.617
14.031
-463.737
BOILING POHIT
kJ
MOLAR VOLUI!E
J/bar

CESIUM
REFERENCE
32
1!.
P. 301.55, B. P. 942 K.
32
32
COIIPILED
10-11-74
THERftODYNAMIC PROPERTIES OF MINERALS
156
TENORITE
cuo:
FORMULA WEIGHT
79.545
-------------------------------------------------------------------------------FORMATIOII FROM THE ELEMENTS

TEMP.
so
(H;-a~ 98 )/T
J/IIO.lK
-(G;-H~ 9 s)/T
J/IIOlK
J/molK
0.21
0.21
cop
ENTHALPY
GIBBS
FREE ENERGY
kJ/1101
J/olK
Log Kf
ltJ/1101
-------------------------------------------------------------------------------298.15
22-.699
o.ooo
42.63
42.6 3
-157.320
-129.564
42.30
UNCERTAINTY
1. 255
1.297
0.227
400
500
600
700
BOO
900
1000
11.475
18.832
24.043
27.951
31.021
33. 522
35.635
55.83
66.60
75.73
il3.65
90.66
96.97
102.72
44.36
47.77
51.69
55.7 0
59.64
63.45
67.09
47.07
49.32
50.79
51.98
53.05
54.09
55. 13
-156.785
-156.071
-155.289
-154.477
-153.640
-152.780
-151.877
-120.151
-111.076
-102.150
-93.360
-84.684
-76.118
-67.647
15.690
11.604
8.893
6.967
5. 529
4.418
3.534
1100
1200
1300
37.455
39.059
40.500
108.02
112.96
117.58
70.56
73.90
77.08
56.18
57.24
58.33
-150.936
-149.951
-148.912
-59.262
-50.981
-42.767
2.814
2.219
1.718
1400
41.814
121.94
80.13
59.43
--------------------------------161.107
-34.355
1.282
MELTING POINT
BOlLING POI NT
ENTHALPY OF MELTING
kJ
7.100 kJ
MOLAR VOLUME
kJ
1.2220 J/bar
12.220 Cll 3

COPPER M. P. 1357 K.

30.967 +
1.3742x1o-z T

REFERENCE
164
120
3.6926z10Z T-05
298 - 1400 K)
263
164
COMPILED
5-28-76
157
CUPRITE
C11 2 0:
FORIIULA WEIGHT
1113.091
crystals 298.15 to melting point 1509 K.
-------------------------------------------------------------------------------FORUTION FRO II THE ELEIIENTS

TE!IP.
H~-H; 98 )/T
J;molK
so
T
-( G;-e~ 98 )/T
J/molK
J/molK
1. 67
1.67
Co
ENTHALPY
J/molK
GIBBS
FREE ENERGY
Log Kf
kJ/mol
kJ/mol
-------------------------------------------------------------------------------25.584
298.15
9]. 111
-168.610
-1116.030
o.ooo
93.111
62.59
UNCERTAINTY
6.276
6.318
1.107
1100
500
600
700
800
900
1000
16.475
27.088
311.748
40.536
45.060
118.722
51.796
112.13
1.27.62
1110.93
152.53
162.77
171.96
180.33
95.65
100.53
106.18
111.99
117.71
123.24
128.53
67.23
71.511
74.32
76.06
77.35
78.67
80.111
-168.618
-168.356
-167.925
-167.428
-166.917
-166.401
-165.851
-138.312
-130.751
-123.270
-115.873
-108.538
-101.268
-94.071
1d.062
13.660
10.732
8.6117
7.087
5.877
11.9111
1100
1200
1300
54.502
56.996
59.4011
188.10
195.45
202.51
133.60
138.115
143.11
82.811
86.18
90.59
-165.192
-1611.344
-163.201
-86.916
-79.8115
-72.839
11.1.27
3.1176
.2.927
11100
1500
61.821
64.341
209.42
216.29
1117.60
151.95
96.21
103.13
-186.375
-56.631
IIELTING POINT
1509
-------------------------------.2.1139
-188.235
-65.380
1. 9 7 2
BOILING POINT
kJ
kJ
IIOLAR VOLUIIE
kJ
2. 3437 Jjbar
23.437 cm 3

COPPER 11. P.
1357 K.
4.2602x102 -
0.25076 T
4.8982x10 T-2
REFERENCE
164
26]
298- 1500 K)
263
1611
COMPILED
6-15-76
THERMODYNAMIC PROPEBTIES OF MINEBALS
158
DYSPROSIUM SESQUIOXIDE (CUBIC)
Dy 2 0 3
FORMULA WEIGHT
Alpha crystals 298.15 to 1590
~.
Beta crystals
15~0
372.998
to 1800 K.
-------------------------------------------------------------------------------FOBI!ATION FROM THE ELEMENTS

TEftP.
so
( H~-H~ 98 )/T
JtmolK
J/aolK
-(G;-H~ 98 )/T
cop
JtaolK
J/molK
ENTHALPY
GIBBS
FREE EIIEBGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
149.79
-1771. J85
31u.J41
149.79
111.74
-1863.130
UNCERTAINTY
u.85
0.85
3.930
4.000
o.7u1
400
500
60(J
700
800
900
1000
30.275
49.402
62.595
72.219
79.576
85.422
90.240
184.64
21L. 72
236.1&
256.19
.!73.69
289.27
303.34
154.36
163.32
173.56
183.97
194.11
203.85
213.10
123.67
127. 59
129.36
130. 53
131. b4
132.87
134.28
-1861.284
-1858.919
-1856.459
-1854.051
-1851.763
-1849.641
-1847.705
-1740 .!98
-1710.314
-1680.836
-1651.758
-1b23.oo7
-1594.545
-156b.315
227. L61
178.676
14o. 330
123.256
105.972
92.545
81.816
1100
1200
1300
1400
1500
1590
94.315
97.851
100.985
103.8111
106.412
108.592
316.21
328.10
339.20
349.62
359.47
367.91
221.90
230.25
238.21
245.81
253.06
259.32
135.87
137.65
139.58
141.66
143.88
145.97
-1846.014
-1844.606
-1843.528
-1842.843
-1842.596
-1842.373
-153tl.245
-1510.316
-1482.518
-1454.791
-1427.081
-1402.142
73.045
65.743
59.569
54.279
49.b96
46.064
1590
1bOu
109.051
109.271
36!!.37
369.28
259.32
260.01
144.23
144.23
-1841.644
-1842.141
-1399.397
45.332
1700
1800
111.328
11J. 156
378.03
386.27
266.70
273.11
144.23
144.23
-1872.523
-1873.665
-1371.321
-1341.693
41.782
38.581
KELTING POINT
BOILING POINT
ENTHALPY OF MELTING
kJ
--------------------------------------------------------------------------------1402.142
4b.Ob4
21.087 kJ
--------------------------------
kJ
4.5683 J/bar
45.btl3 c11 3
MOLAR VOLUftE
TRANSITIONS Ill DEFERENCE STATE ELEftENTS

DYSP&OSIUft. ALPHA-BETA 1657, M. P. 1682 K.
38.243 + 3.7210x1o-z T
(EQUATION VALID FROI!
BEFEI!EIICE
202
235
2.u124x1uJI
298- 1590 K)
r-os
235
103
COMPILED
5-18-76
159
FORMULA WEIGHT
ERBIUM SESQUIOXIDE {CUBIC)
Er 2 0 3
382.518

TEMP.
so
( H;-H~ 98 )/T
-(G;-a~ 98 )/T
co
J/IIOlK
ENTHALPY
GIBBS
FREE ENERGY
Log Kf
k.J/mol
J/IIOlK
J/molK
J/olK
kJ/1101
.298.15
0.000
UNCER TAl NTY
155. b4
0.85
155.64
0.85
118.09
-1897.860
1.920
-1808.879
2.000
0.350
400
500
600
700
800
900
1000
28.250
46.564
59. 158
68.476
75.716
81.544
86.376
190.36
217.09
239.35
258.52
275.39
290.49
3(14.17
162.11
170.53
180.19
190.04
199.67
208.95
217.79
118.77
120.96
123.28
125.43
127.35
129.04
130.55
-1896.1148
-1895. 178
-1893.505
-1891.841
-1890.211
-1888.6119
-1887.171
-1779.486
-1750.348
-1721.536
-1693.013
-1664.703
-1636.613
-1608.691
232.318
182.851:l
149.874
126.335
108.694
94.987
84.030
1100
1200
13(10
1400
1500
1600
1700
90.455
93.958
97.u12
99.700
102.096
104.244
106. 186
31~.68
328 .21
338.90
348.88
358.24
367.05
375.37
226.23
234.25
241.89
249.18
256.14
26.2.81
269.18
131.89
133.09
134.18
135.16
136.05
136.87
137.63
-1885.822
-1884.627
-1883.606
-1882.797
-1882.214
-1881.888
-1881.844
-1580.902
-1553.253
-1525.664
-1498. 161
-1470.734
-1443.320
-1415.900
75.(171
67.612
61.302
55.897
51.216
47.120
43.505
18(10
107.953
383.25
275.30
138.32
BOILING POINT
kJ
-------------------------------------------------------------------------------316.909
MELTUG POINT
ENTHALPY OF MELTING
20.000 kJ
-------------------------------40.290
-1388.377
-1921.8&1
kJ
4.4171 J/bar
44.171 cm 3
MOLAR VOLUME

ERBIUM M. P. 1795 K.
1.6353x1(JZ + 6.9435x1o-s T
1.0957x10l r-os
(EQUATION VALID FROM 298- 180(1 K)
REFERENCE
207
235
235
COMPILED
5-19-76
160
EUROPIUM OXIDE
EuO:
C~ystals
FORMULA WEIGHT
167.959
298.15 to 1800 K.
-------------------------------------------------------------------------------FORKATION FROM THE ELEMENTS

TEMP.
{H~-H~ 9 s)/T
J;molK
ST
cop
-( G;-H~ 98 )/T
J/molK
J/molK
0.85
0.85
ENTHALPY
J/mol K
GIBBS
FREE ENERGY
Log Kf
kJ/mol
kJ/mol
-------------------------------------------------------------------------------298.15
97.424
0.000
62.76
-556.082
48.74
-592.040
62.76
UNCERTAINTY
400
500
12.525
20.030
77.21
88.37
64.68
68.34
49.64
50.42
600
700
800
900
1000
25. 157
28.921
31.835
34.178
36. 126
97.63
105.57
112.55
118.78
124.43
72.47
76.65
80.72
84.60
88.30
51.16
51.87
52.58
53. 29
53.99
1100
1.200
1300
1400
1500
1600
1700
1800
31.781
39.218
40.488
41.6.29
42.659
43.605
44.481
45.298
129.61
134.40
138.86
143.04
146.98
150.71
154.25
15 7. 64
91.83
95.18
98.37
101.41
104.32
107.10
109.77
112.34
54.68
55.38
56.07
56.77
57.46
58.15
58.84
59.53
MELTING POINT
2247
ENTHALPY OF MELTING
8.370
8.370
1. 466
-591. ])8
-590.736
-543.908
-532.121
71.027
55.591
-589.808
-589.468
-589.285
-589.309
-508.846
-497.304
-485.794
-474.299
37.971
32.471
l8.195
24.775
-------------------------------45.J(J8
-520.439
-590.:.!46
--------------------------------598.764
-462.705
21.972
-598.848
-598.880
-598.857
-598. 786
-598.656
-598.467
-59!1.2.21
-450.330
-437.953
-425.565
-413.191
-400.824
-388.458
-376.119
19.602
17.597
15.878
14.389
1J.U86
11.9 36
10.915
BOlLING POI NT
kJ
kJ
kJ
MOLAR VOLUME
2.0475 J/bar
20.475 c11 3

EUROPIUII H. P. 1090, B. P. 1868 K.

c~
47.124 +
6.9013x10-l T
(EQUATION VALID FRO II

I:IEFERENCE
166
235
3.9277x1o T-z
298 - 1800 K)
235
COI\PILED
5-19-76
161
PBOPEBTIES AT HIGH TEftPEBATOBES

EUROPIUft SESQUIOXIDE (ftONOCLINIC)
Eu 2 0~:
FOBftULA WEIGHT
Beta crystals 895 to
18~~
351.918
K.
-------------------------------------------------------------------------------FOBftATIOII FROft THE ELEftENTS

TEftP.
( u;-u~ 98 )/T
J/molK
so
-(G;-H~ 98 )/T
cop
J/molK
J/aolK
JjaolK
8. so
8.50
EliTHl.LPY
GIBBS
FBEE EIIIEBGY
Loq Kf
kJ/1801
kJ/1101
-------------------------------------------------------------------------------298.15
1116.411
146.114
-1651.1120
-1555.158
272.458
115.69
~.1100
UliCEBTU NTY
1100
500
31.500
51.810
182.68
212.36
151.18
160.55
129.62
135.88
600
700
800
895
66.132
76.7110
811.902
90.967
237.116
259.10
278.06
2911.00
171.33
182.36
193.16
203.03
139.28
141.311
142.67
1113.93
895
900
1000
91.685
91.956
97.1182
2911.72
295.119
311.00
203.03
203.53
213.52
146.33
1116.41
147.98
1100
1200
1300
1400
1500
1600
1700
1800
1112.1411
106.161
109.681
112.807
115.627
118.191
120.5115
122.726
3.25.18
338.26
350.112
361.79
372.119
382.60
392.19
401.32
223.011
232.10
240.74
248.98
256.86
264.111
271.64
278.59
1119.56
151. 13
152.71
154.28
155.86
157.113
159.01
160.58
!ELTING POINT
EIITHALPY Of !!ELTING
8.110~
8.400
1. 472
-16118.9118
-1645.981
-1522.618
-11191.386
198.8311
155.805
-1639.982
-1637.210
-1635.0113
-1430.612
-1400.878
-1372.9211
1~6.7511
-16311.1100
-16H.289
-1632.075
-1372.9211
-1371.471
-1342.405
80. 128
79.598
70.120
--------------------------------1460.732
-16112.967
127.169
91.468
80.128
--------------------------------1648.728
-1313.360
62.367
-16116.642
-1644.4511
-1642.163
-1639.751
-1637.226
-1634.576
-1631.803
-1282.952
-1252.738
-1222.681
-1192.796
-1163.090
-1133.51111
-11011.133
55.8116
50.336
45.619
111.537
37.971
311.830
)2.0111
BOILING POINT
kJ
kJ
kJ
I!OLAR VOLUI!E
11.11020 J/bar
44.020 cm 3

EUROPIUI! ft. P. 1090 1 B. P. 1868 K.
cop
cop
1.11102x1oz - 2.78116x10 T-Z

{EQUATION VALID FRO!! 298 1. 3223x 102 + 1.5752x1o-z T
(EQUATION VALID FRO!! 895
REFERENCE
210
281
895 K)
1800
K)
235
57
COI!PILED
5-18-76
162
THERftODYHAftiC PROPERTIES OF ftiNERALS
FORftULA WEIGHT
EUROPIUft SESQUIOIIDE (CUBIC)
Eu 2 0 3
351.918
FORMATION FROM THE ELEMENTS

GIBBS
ENTHALPY
FREE ENERGY
Log
TEMP.
kJ/mol
298.15
o.ooo
UNCERTAINTY
o.oo
120.49
400
500
33.000
53.302
J7 .13
67.13
131.40
137.18
600
700
80(1
900
1000
67.622
78.330
86.700
93.467
99.(194
92.50
114.47
133.87
151.25
167.03
141.05
144.01
146.49
148.70
150.73
1100
1200
1300
103.tl76
108.017
111.661
181.48
194.85
207.28
152.64
154.48
156. 27
!ELTING POINT
kJ/mol
--------------------------------
--------------------------------
BOILING POINT
ENTHALPY OF MELTING
kJ
IIOLAR VOLUIIE
kJ
kJ
4.8290 J/bar
48.290 cm 3

EUROPIUII II. P.
1090 0 B. P.
1868 K.

C~
1.J665x102 +
1.5936x10-2 T
(EQUATION VALID FROII 298 -
REFERENCE
210
1.1l595x106 T-z
1350 K~
COli PILED
5-18-76
PJOPEBTIIS AT HIGH TEBPERATUBES
IIUSTITE
163
FOBIIULA II E.IGHT
Crystals 298.15 to 11elting point 1652 K.
68.887
-------------------------------------------------------------------------------FOBIIATIOIII FBOII THE ELEIIENTS

TEIIP.
so
( a;-H~ 98 )/T
J/IIOlK
J/llolK
GIBBS
FREE EIIIEBG!
-(G;-H~g 8 )/T
cop
J/IIOlK
J/IIOlK
kJ/mol
0.837
0.879
0.1511
-265.1118
-264.109
-263.293
-262.732
-261.481
-262.632
-263.113(1
-238.1011
-231.1160
-225.011
-218.700
-212.1130
-206.11111
-199.832
31. (19 3
24.181
19.589
16.320
13.870
11.9611
1(1.1138
EIIITHALPY
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
57.59
.. 8.12
-2115.155
.. 2.950
57.59
-266.270
UNCEBTliiiiTY
0.112
0.112
1100
500
600
700
8(10
900
1(100
12.875
20.790
26. 1113
30.007
32.961
35.333
37.327
72.41
84.12
93.17
101.97
1(19.13
115.53
121.35
59.53
63.33
67.63
71.96
76.17
80.20
811.02
51.98
52.78
53.04
53.38
53.94
511.75
55.80
1100
39.062
126.72
87.66
57.05
1200
1300
1400
15(10
1600
1652
110.618
42.(152
43.1100
1111.681
115.921
.. 6.2011
131.74
136.49
1111.00
1ij5.32
149.48
151.35
91.12
94.114
97.60
100.64
103.56
1(15.14
58.47
60.(15
61.76
63.58
65.50
66.511
1800
65.398
176.06
110.66
67.90
--------------------------------193.367
9.182
-265.009
--------------------------------265.6116
-186.860
8.134
-264.7611
-263.809
-262.7ij2
-261.5711
-261.521
-180.373
-173.925
-167.522
-161.216
-158.097
7.247
6.1189
5.83ij
5.263
11.999
-229.600
-151.478
11.396
-------------------------------------------------------------------------------1652
65.1711
170.32
67.9()
105.14
-23().182
-158.097
4.999
-------------------------------1700
65.251
172.18
106.93
67.90
-155.879
11.790
-230.607
IIELTIIIIG POIIIIT
1652
ENTHALP! OF !!ELTING
31.338 kJ
9.11611 kJ
BOILING POINT
kJ
1. 20ij0 J/bar
12.0110 cm 3
IIOLAB VOLUIIE
TBAIIISITIONS IN REFERENCE STATE ELEIIENTS

IROIII CURIE P. 1042, ALPHl-GliiiiA 1184, GAIIIIA-DELTA 1665,

19.296 + 3.u165x10-2 T
1.50Q9x103 T-os
(EQUATION VALID FBOII 298 - 1652 K)
IIEFERENCE
44
120
2ij7
2.5333x10 T-2
109
2117
COIIPILED
6-11-76
THERftODYMAftiC PROPERTIES OF ftiMERALS
164
FORMULA IIEIGHT
FERROUS OXIDE (STOICHIOMETRIC)
FeO:
71.846
FORMATION FROM THE ELEftHTS

GIBBS
FREE ENERGY
ENTHALPY
TEMP.
o.ooo
59.80
1.67
59.8(1
1.67
49.92
-272.043
2.092
-251. 156
2. 176
44.002
0.381
400
500
MH1
700
800
900
1000
12.950
20.874
26.425
30.589
33.864
36.533
38.768
74.72
86.45
96.33
104.89
112.47
119.29
125.49
61.77
65.58
69.90
74.30
78.61
82.76
86.72
51.74
53.42
54.90
56.20
57.36
58.40
59.36
-271.032
-270. 131
-269.349
-268.725
-268.352
-268.363
-269.057
-244. 171
-237.553
-231.115
-224.813
-218.568
-212.321
-206.064
31.886
24.817
20.120
16.776
14.271
12.323
10.764
1100
40.680
131.19
90.51
60.24
1200
1300
1400
1500
1600
1652
42.345
43.815
45. 129
46.315
IJ7.396
47.922
136.47
141.39
146.00
150. 31J
154.1J4
157.80
94.12
97.58
100.87
101J.02
107.04
109.88
61.06
61.84
62.57
63.27
63.95
6CJ.29
1652
61.351
171.23
109.88
68.20
1700
11100
61.51J4
61.911J
173.10
17&.99
111.56
115.08
68.20
68.20
298.15
UNCERTAINTY
I'IELTING POINT
-270.287
-269.391
-268.1J80
-267.597
-267.168
-245.551
-244.734
-186.812
-180.441
-171J.094
-167.835
-166.727
7.506
6. 732
6.(163
5.479
5.272
-166.727
5.272
-161J.321
-159.516
5.049
4.&29
BOILING POINT
1652
-------------------------------9.482
-199.668
-.270.603
--------------------------------271.208
-193.235
8.411
22.185 kJ
kJ
1.2000 J/bar
12.000 c 3
MOLAR VOLUME
kJ

IRON CURIE P. 1042, ALPHA-GAMMA 118CJ, GAftftA-DELTA 1665 9
M. P. DELTA 1809 K.

67.352 +
3.7580x10-l T

REFERENCE
21J7
21J7
3.8167x10Z f-05
298- 1652 K)
247
COMPILED
5-24-76
165
PROPERTIES AT HIGH TE!PEBATOBES

HB!ATITE
Fe 2 0~:
FOBKULA WEIGHT
159.692
Beta crystals 950 to aeltiog point
1B95 K.
-------------------------------------------------------------------------------FOB!ATION FRO II THE ELEIIEHTS

TE!P.
cu;-H~ 98 )/T
J;aolK
so
J/aolK
-( G;-H~ 98 )/T
cop
J/aolK
J/aolK
EJITHALPY
GIBBS
FREE EIIEBGY
kJ/aol
Loq Kf
kJ/aol
-------------------------------------------------------------------------------298.15
-742.683
0.000
87.40
87.40
103.85
-824.640
130.116
1.255
1.297
0.227
120.91
131.39
139.01
146.53
156.06
169.20
117.51
-822.970
-82(1.565
-817.888
-815.113
-812.285
-809.359
-807.736
-714.899
-688. 1JO
-661.886
-&36.156
-610.777
-585.703
-573.71l9
93.357
71.889
57.623
47.471
39.880
33.993
31.54 7
152.16
148.49
-807.000
-560.954
29.301
2&6.61
1&1.91l
143.55
107.712
110.267
112.429
111l.459
116.1l89
278.96
290.18
300.60
310.45
319.93
171.19
179.91
188.17
195.99
203.144
lllO. 74
140.07
141.42
144.64
149.58
118.618
120.909
329.19
338.32
210.57
217.141
156.0&
163.95
BOILIHG POI NT
kJ
kJ
UNCBBTAIITY
0.21
0.21
900
950
28.800
48.338
62.833
14.241
83.844
92.55&
96.221l
120.50
148.69
113.34
195. 33
215.1l8
231l.58
243.81
91.70
100.35
110.51
121.09
1J1.61l
142.02
147.59
1000
1 oo. 551
252.71
1100
104.6&6
1200
1300
1400
1500
1600
1700
1800
400
5(10
600
700
5oo
-------------------------------------------------------------------------------950
98.168
21l5. 76
147.59
-805.888
-573.749
31.54 7
151.69
IIELTI IIG POI liT
Hl95
ENTHALPY OF KELTING
15.560 kJ
--------------------------------809.223
-536.201
.25.1l62
--------------------------------511.419
-810.146
22.262
-808.368
-806.715
-805.076
-803.176
-486.665
-462.023
-437.399
-1412.971
19.555
17.238
15.232
13.1482
-801.129
-364.167
10.568
--------------------------------803.2149
-388. 584
11.9140
3.02714 J/bac
30.2714 ca 3
KOLAR VOLUME
TRANSITIONS IN REFEBEVCE STATE ELEKEMTS

IRON CURIE P. 1042, ALPHA-GAMMA 1184, Gl!IIA-DELTA 1665,
K. P. DELTA 18(19 K.

838.61
2.34314 T
2. 7821x10 T-,
298-
+ 0.27267 T
3.3960x10
950 - 1800 K)
-1.0957x10~
REFERENCE
414
78
78
247
6.0519x to- T2
950 K)
r-os
84
COMPILED
6-11-76
166
THERI!OD!KA!IC PHOPEBTIES OP ftiKEBALS
ftAGIETITE
FOB!ULA WEIGHT
Alp~a
231.539
Beta crystals 848 to melting point
1870 K.
-------------------------------------------------------------------------------FORftATIOK PRO! THE ELEIIEIITS

TEIIP.
soT
<a;-H~ 98 )/T
J;aolK
JjaolK
-(G;-H~ 98 )/T
cop
J/aolK
J/aolK
ENTHALPY
GIBBS
FREE EHEBGY
kJ;aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------296.15
o.ooo
146.14
146.14
150.79
-1115.726
-1012.566
177.398
UNCERTAIIITY
0.42
0.42
2.092
2.134
0.374
400
500
600
700
800
848
41.825
70.428
92.007
109.994
127.047
134.099
194.24
235.41
271.81
305.36
338.21
353.81
152.41
164.98
179.80
195.37
211. 16
219.71
176.03
192.45
207.63
229.74
26 5. 64
289.43
-1113.015
-1109.131
-1104.631
-1099.267
-1092.209
-1088.391
-977.691
-944.253
-911.679
-879.995
-1:149.125
-835.281
127.674
98.&46
79.369
65.666
55.442
51.451
900
1000
141.144
147.986
368.15
390.24
227.01
242.25
213.93
205.97
-1085.915
-1086.433
-819.068
-789.434
47.531:1
41.236
1100
153.031
409.63
256.60
201.45
12ou
1300
1400
1500
1600
156.962
160.188
162.964
165.440
167.729
427.06
442.98
457.72
471.53
484.57
270.10
282.79
294.76
306.09
316.84
199.28
198.76
199.43
200.99
203.23
1700
1800
169.896
171.988
496.97
508.84
327.07
336.85
205.99
209. 1 s
BOlLING POI NT
-------------------------------------------------------------------------------848
136.949
35&. 66
-1085.646
-835.281
51.451
219.71
219.99
I!ELTI NG PO lilT
1870
EKTHALPY OF !ELTING
138.072 kJ
--------------------------------759.472
36.064
-1090.416
--------------------------------1092.184
-729.441
31.752
-1089.761
-1087.&39
-1085.600
-1083.668
-699.415
-&69.504
-639.647
-610.018
21:1.103
24.981.1
22.275
19.915
-1084.411
-550.587
15.978
--------------------------------580.354
-1085.295
17.832
ENTHALPY OF VAPORIZATIOK
24.573 kJ
IIOLAR VOLUI!E
kJ
4.4524 J/bar
44.524 cal
TRANSITIONS Ill REFERENCE STATE ELEMENTS

IROII CURIE P. 1042, ALPHA-GAI!IIA 1184, GAI!I!A-DELTA 1665,
!. P. DELTA 1809 K.
HEAT CAPACITY EQUATIOKS

3.558ux103 +
3.3473x102 TDs
9.3090 T
1.4273x1os r-1

96.823 +
5.2733x1o-z T

REFERENCE
44
79
79
298-
848 K)
s. 6413x107
848 -
T- z
1 ~00 K)
84
COMPILED
247
6-11-76
167
PROPERTIES AT HIGH TE!PEBATUBES

GALLIU! SESQUIOIIDE
Ga 2 0 3 :
FOR!ULA WEIGHT
187.~38
Crystals L98.15 to 1800 K.
-------------------------------------------------------------------------------FOBUTIOII .FBO!l THE ELEllEIITS

TE!IP.
(a;- s~ 98 )/T
J/aolK
so
-(G;-s~ 98 )/T
cop
J/aolK
J/aolK
J/aolK
0.~2
0.~2
113.82
137.75
158.38
103.63
110. &6
115.56
119.21
122.04
124.30
126.16
BIIITHALPY
GIBBS
FREE EIIERGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------174.906
298.15
-1089.100
o.ooo
84.98
84.98
92.13
-998.3~2
UIIICEBTAI liT Y
0.850
0.850
-------------------------------125.
-963.710
8~8
~00
25.050
500
600
700
800
900
1000
~1.520
53.475
62.616
69.872
75.800
80.745
192.59
207.10
220.29
88.77
96.23
104.90
113.8&
122.12
131.30
139.55
1100
1200
1300
1400
1500
1600
1700
1800
84.945
88.565
91.721
94.500
96.969
99.178
101.168
102.969
232.39
243.5(1
253.93
263.62
272.69
281.23
289.29
296.93
147.44
155.00
162.21
169.12
175.7 2
182.05
188.12
193.96
127.71
129.02
130. 14
131.10
131.94
132.67
133.32
133.88
!!ELTING POHIT
BOlLI IIIG POI NT
ENTHALPY OF llELTING
kJ
kJ
!OLAR YOLUl!E
176.~8
0.149
-1100.~16
-1099.664
-929.60~
-1098.~25
-895.69~
-1096.879
-1095.124
-1093.217
-1091.192
-862.029
-828.592
-795.380
-762.392
-1089.074
-1 08b.879
-1084.620
-1082.307
-1079.942
-1077.538
-1075.094
-1072.&19
-729.627
-b97. 029
-664.629
-632.~31
-600.377
-568.506
-536.764
-505.151
97.115
77.977
64.326
54.102
46.163
39.823
34.647
30.341
26.705
23.596
20.907
18.560
16.493
14.659
ltJ
2.8941 J/bar
28.941 ca 3
TRANSITIONS IN REFERENCE STATE ELE!IEHTS

GALLIUII
!1.
P. 302.9 K.

1.&578x10Z -
2.4571x10-3 T
1.1589x10~ T-os
298 - 1800 K)
(EQUATION VALID FRO II

REFERENCE
203
120
262
145
COIIPILED
6- 2-76
1&8
THEB!ODYIAftiC PROPERTIES OP ftiNERALS
FOBIULA WEIGHT
GADOLINIDK SESQUIOIIDE (KOIOCLINIC)
Gd 2 0 1 :
362.498
-------------------------------------------------------------------------------PORUTION PBOft THE ELEMENTS

<H;-H~ 98 )/T
TEMP.
J/IDOlK
ST
-(G;-H~ 98 )/T
J/olK
J/IDolK
0.85
0.85
co
ENTHALPY
GIBBS
fREE E IIEBG Y
kJ/IDOl
kJ/IDOl
J/ol K
Log Kf
-------------------------------------------------------------------------------298.15
o.ooo
151.88
-1819.620
-1732.138
303.500
151.88
109.54
UNCERTAINTY
3.600
3.600
0.631
400
500
600
700
800
900
1000
28.025
45.&44
57.867
6&. 927
73.977
79.667
84.399
184.82
210. 7J
232.42
251.11
267.58
282.32
295.70
156.79
165.09
174.55
184.18
193.60
202.65
211.30
114.48
117.&9
120.20
122.35
124.29
126.09
127.81
-1819.248
-1817.862
-1816.452
-1815.113
-1813.860
-1812.693
-1811.596
-1702.831
-1&73.897
-1645.138
-1616.&84
-1588.428
-1560.306
-1532.392
222.368
174.872
143.223
120.639
103.714
90.558
80.0411
1100
1200
1300
1400
1500
88.421
91.909
94.982
97.729
100.209
307.96
319.29
329.85
339. 7J
349.04
219.54
227.38
234.87
242.00
248.83
129.47
131.07
132.64
134.19
135.71
-1810.577
-11109.668
-1808.874
-11108.219
-1807.706
-1504.432
-1476.696
-1448.998
-1421.248
-1393.607
71.440
64.279
58.222
53.028
48.530
1600
1700
1800
102.475
104.5&2
106.499
357.85
36&.21
374.18
255.38
261.65
267.68
137.21
138.70
140. 17
-18JJ.328
-1832.399
-1336.356
-1307.105
41.061
37.931
llELTING POINT
BOILING POINT
ENTHALPY OP ftELTIHG
kJ
kJ
H~98
kJ
llOLlll VOLUIIE
H~
--------------------------------1365.633
44.584
-1834.143
4.3400 J/bar
43.400 CID3
TRANSITIONS IN BEFEREHCE STATE ELEBEHTS

GADOLINIUM. ALPHA-BETA 1533, ft. P. 1585 K.
1.1925x10Z ~ 1.3585x1o-z T
(EQUATION VALID FROB 298 -
REFERENCE
210
281
1.4J51x10Z T-05
1800 K)
235
COMPILED
5-18-76

GADOLINIUM SESQUIOXIDE (CUBIC)
Gd 2 0J:
1&9
FORMULA WEIGHT
3&2.498
FORMATION FROft THE ELEilENTS

GIBBS
ENTHALPY
FREE ENERGY
Log
TEilP.
K
298.15
0.000
UNCERTAINTY
0.00
116.87
400
500
&00
700
800
900
1000
28.100
46.010
58.455
67.767
75.079
81.011
85.941
34.12
60.37
82.36
101.42
118.27
133.40
147.13
116.41
119. 13
122.21
125.02
127.43
129.44
131.11
1100
1200
1300
1400
1500
90.112
93.691
9&.796
99.514
101.913
159. &9
171.27
182.00
192.00
201. 14
132.48
133.59
134.49
135. 19
135.74
ftELTIIIG POIIIT
ENTHALPY OF !ELTING
BOILING POIIIT
kJ
kJ
!tOLAR VOLO!E
kJ
4.7585 J/bar
47.585 cal

GADOLIIIIOil. ALPHA-BETA 1533, ll. P. 1585 K.

c;
2.0401xtoz - 1.1112x1o-z T
2.0523x10J T-os
(EQOATIOII VALID FRO! 298 - 1500 K)
R!FEBEIICB
210
3.1138x10 T-z
COilPILBD
5-18-76
170
GERftANIUM DIOXIDE (QUARTZ TYPE)
PORftULA WEIGHT
104.589
-------------------------------------------------------------------------------FOBIIATION FROII THE ELEIIEHTS

TEMP.
soT
-(G;-H~ 98 )/T
cop
JjmolK
J/molK
J/molK
o. :0
0.27
( H;-H~ 98 )/T
Jjmol K
ENTHALPY
GIBBS
FREE ENERGY
kJ/mol
Log Kf
kJ/mol
-------------------------------------------------------------------------------298.15
0.000
55.27
-497.074
55.27
-551.030
87.086
52.09
UNCERTAINTY
0.800
(1.900
0.158
400
500
600
700
800
900
1000
14.125
23.524
30.463
35.854
40.184
43.744
46.730
71.54
85.15
97.0.2
107.52
116.93
1.25.44
133.19
57.41
61.63
66.56
71.67
76.75
81.70
86.46
58.61
63.33
66.83
69.46
71.45
72.98
74.14
-550.844
-550.261
-549.417
-548.395
-547.258
-546.058
-544.833
-478.664
-460.676
-442.833
-425.146
-407.610
-390.223
-37 2. 973
62.507
48.1.27
38.552
31.725
26.614
.22.648
19.482
1100
1200
49.263
51.437
140.30
146.86
91.04
95.4.2
75.01
75.66
-543.6.27
-542.469
-355.846
-338. 829
16.898
14.749
1300
53.318
152.93
99.61
76.12
--------------------------------578.190
-319.178
1.2.825
MELTING POINT
BOILING POINT
ENTHALPY OF MELTING
kJ
kJ
kJ
IIOL.l R VOLU liE
.2.41440 J/bal:
L4. 440 cm 3
TRANSITIONS IN REFEREMCE STATE ELEIEHTS

GERllAIIIUM ll. P. 1210.4 K.
1.L667x1(1Z 1.015bx1o-z T
1.360itx103 T-os
(EQUATION VALID Fi!Oft 298- 1350 K)
REFERENCE
119
120
262
83
COMPILED
6- 8-76
------------------------------------------------------------------'-------------
PROPERTIES AT HIGH TEBPEBATUiES

GEBftlMIUft DIOXIDE GLASS
171
FOiftULA WEIGHT
104.589
Glass 298.15 to 1800 K.
-------------------------------------------------------------------------------FOill.lTIOK FiOft THE ELEIIBKTS

TEI!P.
-(G;-u~ 98 )/T
cop
J/aolK
J/aolK
J/aolK
0.30
0.30
so
(a;-u~ 98 )/T
JtaolK
ENTHlLPY
GIBBS
FREE BIIBiGY
Loy Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------:.!98. 15
o.ooo
64.511
416.38
-475. 180
614.50
-526.350
83.250
UIICEBTAIIITY
0.630
0.710
0.124
400
500
600
700
800
900
1000
14.250
23.646
30.738
36.253
40.664
44.278
47.310
79.t.7
93.31
105.37
116.05
125.60
134.22
142.08
65.42
69.i6
74.63
79.80
84.94
89.94
94.77
57.70
64.14
67.98
70.55
72.45
73.94
75.17
-526.114
-525.520
-524.572
-523.436
-522.194
-520.898
-519.573
-457.186
-440.015
-422.998
-406.158
-389.482
-372.965
-356.603
59.703
45.966
36.825
30.308
25.431
21.646
18.627
1100
1200
49.893
52.127
149.29
155.97
99.160
103.84
76.23
77.17
-516.254
-516.960
-340.362
-324.252
16.163
14.114
1300
1400
1500
1600
1700
1800
54.088
55.829
57.384
58.792
60.075
61.252
162.18
167.99
173.45
178.61
183.50
188.14
108.09
112.16
116.07
119.82
123.43
126.89
78.03
78.82
79.56
80.26
80.94
81.59
-551.0166
-549.542
-547.989
-546.391
-544.748
-286.572
-267.722
-248.997
-230.378
-211.620
10.692
9.323
8.129
7. 079
6.147
--------------------------------305.523
12.276
-552.510
BELTING POINT
BOILIKG POINT
EIITHlLPY OF ftELTIHG
kJ
EIITH.lLPY OF VAPORIZATION
ltJ
B~ 98 - H~
kJ
I!OLlB VOL UI!E
TBliiSITIOIS Ill BBIBBENCE STATE ELE!EITS
J/bar
GEBI!AIIIU! II. P. 1.210.4 K.
SEAT CAPACITY EQUATION

76.125 +
4.8606x10-~
(EQUATION VALID FlO!!

REFERENCE
119
1.Q814J:102 T-05
298 - 1800 K)
163
COIIPILED
5-28-76
THERftODYUAftiC PROPERTIES OF ftiNERALS
172
WATER
HzO:
FORIIULA WEIGHT
Liquid 298.15 to 372.8 K.
18.015
-------------------------------------------------------------------------------FOR!IATION FRO!l THE ELEIIENTS

TEftP.
sa
( u;-u~ 98 )/T
J/IIOlK
-(G;-u; 98 )/T
JfaolK
J/aolK
o.o8
0.08
15.216
86.76
71.63
400
500
600
700
800
900
1000
118.672
101.882
90.853
83.139
77.506
73.266
69.999
198.78
206.53
213.04
218.71
223.80
228.43
232.71
1100
1200
1300
1400
1500
1600
1700
1800
67.442
65.412
63.786
62.473
61.406
60.535
59.822
59.236
236.69
240.44
243.99
247.35
250.56
253.62
256.55
259.37
CDp
EUTHALPY
J/aolK
GIBBS
FREE EBERGY
kJtaol
Log ltf
kJ/aol
-------------------------------------------------------------------------------298.15
0.000
69.95
-285.830
-237.141
41.546
75.19
69.95
UNCERTAINTY
372.8
0.042
0.084
0.015
75.89
-283.703
-225. 106
31.541
80.11
104.65
122.19
135.57
146.29
155.16
162.71
34.28
35. 18
36.26
37.45
38.70
39.97
41.24
-242.836
-243.820
-244.758
-245.634
-246.444
-247.185
-247.859
-223.882.
-219.035
-.l13. 987
-208.786
-203.473
-198.045
-192.559
29.236
22.883
18.629
15.580
13.285
11.494
10.058
169.25
115.03
180.20
184.88
189.15
193.08
196.73
200. 13
42.48
43.69
44.85
45.95
46.98
47.96
48.85
49.68
-248.464
-249.008
-249.492
-249.923
-250.303
-250.640
-250.937
-251.201
-186.985
-181.311
-175.730
-170.040
-164.322
-158.569
-152.805
-147.035
8.879
7.895
7. 061
6.344
5.722
5.177
4.695
4.267
-------------------------------------------------------------------------------312.8
124.836
196.38
31. 541
71.63
34.09
-242.437
-225.106
!!ELTING FOINT
273.15 K
0
6.008 kJ
13.293 kJ
H298 - 8 o
BOILIIIG POIIIT
372.8 K
40.866 kJ
IIOLAR VOLUIIE
1. 8069 .J/bar
18.069 ca 3

7.3680 +
2.7468xlo-z T
2.2316x1os T- z

REFERENCE
247
196
35
372.8- 1800 K)
35
COIIPILED
8-0J-76
173
PROPERTIES AT HIGH TE!PERATORES
FOR!ULA WEIGHT
STEA!
HzO:
18.015
-------------------------------------------------------------------------------FO.RUTIOif FRO! THE ELE!EIITS

TE!P.
so
-(G;-u~ 98 )/T
cop
J/olK
J/olK
J/ol K
0.04
0.04
( u;-u~ 98 )/T
J/olK
ElfTBALPY
GIBBS
FREE EIJERGY
Loq Kf
kJ/ol
kJ/ol
--------------------------------------------------------------------------------228.569
1&0.01&4
298.15
0.000
188.83
188.83
-241.814
33.58
UNCERTAINTY
0.042
0.084
0.015
4CHI
500
600
700
800
900
1000
8.630
13.840
17.497
20.263
22.489
24.360
25.978
198.78
206.52
213.03
218. 72
223.80
228.43
232.70
190.15
192.68
195.51&
198.45
201.31
204.07
206.72
34.28
35.18
36.26
37.45
38.70
39.97
41.24
-242.837
-243.825
-244.756
-245.631
-21&6.41&2
-21&7.184
-247.864
-223.883
-219.035
-213.981
-208.788
-203.1&71
-198.042
-192.557
29.236
22.883
18.629
15.580
13.285
11.491&
10.058
1100
1200
1300
1400
1500
16CJO
1700
1800
27.1&25
28.730
29.925
31.034
32.063
13.027
33.932
34.783
236.69
240.44
243.98
247.35
250.56
253.62
256.56
259.37
209.27
211.71
214.06
216.31
218.49
22CJ.59
222.62
224.59
42.48
43.69
44.85
45.95
46.98
47.96
48.85
49.68
-21&8.467
-21&9.011
-249.495
-249.922
-250.301
-250.636
-250.933
-251.201
-186.989
-181. 371&
-175.724
-170.034
-164.316
-158.564
-152.812
-147.032
8.879
7.895
7.061
6.344
5.722
5.177
4.695
4.267
!ELTIIfG POUlT
BOILING POINT
ElfTHALPY OF !ELTING
kJ
kJ
9.908 ltJ
2478.9200 J/bar
21&789.200 c 3
!OLU VOLUI!IE
TRAHSITIOifS Ill REFEREifCE STATE ELE!EHTS
HEAT CAPACITY EQUATIOif
7.3680 +
2.7468x1o-z T
-2.2316z10S T-Z
(EQUATIOIJ VALID PRO!
BEFBBEICE
21&7
196
35
1&.8117x1o- TZ
298- 1800 K)
35
196
CO!PILID
8-17-76
174
THERMODYJAAIC PBOPEBTIES OF MINERALS
HAFNIA
FORMULA WEIGHT
210.489
================================================================================
Hf0 2

so
( H~-H~9 8 )/T
TEMP.
K
J/aolK
J/aolK
-( G;-H; 98 }/T
CDp
J/aol K
J/ao1 K
EIITHALPY
GIBBS
FREE ENERGY
k.J/1101
Log Kf
kJ/mo1
-------------------------------------------------~------------------------------
o.ooo
59.33
0.42
59.33
0.42
60.25
-1144.740
1.255
-101:11:1.276
1.297
190.6b2
0.227
600
70(J
800
900
1000
16.275
26.828
34.427
40.209
44.785
48.522
51.639
78.06
93.45
106.65
118.19
128.45
137.68
146.08
61.78
66.62
72.22
77.98
83.66
89.16
94.44
66.91
70.94
73.77
75.93
77.65
79.09
80.12
-1143.912
-1142.763
-1141.453
-1140.061
-1138.630
-1137.180
-1135.736
-1069.100
-1050.528
-1032.199
-1CJ14.10J
-996.206
-978.483
-960.936
139.611
109.748
89.861
75.b74
65.046
56.790
50.194
1100
1200
1300
1400
1500
160CJ
1700
1800
54.296
56.595
58.609
60.393
61.993
63.434
64.744
65.943
153.78
160.91
167.53
173.73
179.55
185.04
190.23
195.17
99.48
104.]2
108.92
113.34
117.56
121.61
125.49
129.21
81.39
82.35
83.21
83.99
64.72
85.39
66.02
86.61
-1134.300
-1132.882
-1131.488
-1130.124
-1128.785
-1127.483
-1126.216
-1124.987
-943.516
-926.242
-909.071
-892.CJ26
-875.060
-858.187
-841.398
-824.693
44.804
4u.318
36.527
33.282
30.472
21:1.017
25.853
23.932
298.15
UNCEBTAIITY
4(J0
suo
MELTING POINT
BOILUIG POINT
kJ
EHTHALPY OF VAPORIZATION
kJ
MOLAR VOLUME
3173
ENTHALPY OF MELTING
kJ
2.0823 J/bar
20.823 cm 3
TRANSITIOIIS IN REFEREIICE STATE ELEAENTS

HAFNIUM ALPHA-BETA 2013 K.

2.0947x10-3 T
95.584 +
BEFEREIICE
188
120
5. 3496x 1 OZ T-D 5
298 - 1800 K)
264
COMPILED
5-26-76
PROPERTIES AT HIGH TEIIPERATURES

IIONTROYDITE
Hgo:
175
FORIIULA WEIGHT
216.589
-------------------------------------------------------------------------------FORIIATION FRO II THE ELEIIENTS

TEIIP.
J/IIOlK
GIBBS
FREE ENERGY
ST
-(G;-H~ 9 a)/T
cop
J;ao1K
J/aolK
J;ao1K
ltJ/1101
0.050
0.060
0.011
-90.388
-89.633
-88.647
-47.558
-36.928
-i6. 478
6.210
3.858
2.305
-144.338
-142.301
-140.170
9.853
29.009
47.926
-0.643
-1.683
-2.503
( H~-H~ 98 )/T
ENTHALPY
Log Kf
ltJ/1101
-------------------------------------------------------------------------------10.254
298.15
-90.789
-58.528
o.ooo
70.27
70.27
44.06
UNCERTAINTY
0.34
0.34
400
500
600
11.825
19.488
25.043
83.89
95.06
104.69
72.06
75.57
79.65
48.53
51.60
53.95
700
800
900
1000
29.313
32.731
35.556
37.938
113.15
120.71
127.56
133.82
83.84
87.98
92.00
95.88
55.84
57.43
58.79
60.00
IIELT.ING POINT
-------------------------------0.713
-9.550
-146.260
BOILING POINT
ltJ
EJTHALPY OF VAPORIZATION
kJ
1. 9320 J/bar
IIOLAR VOLUIIE
9.113 .kJ
19.320
cm 3

IIERCURY B. P. 629 K.

3.0351x10-J T
73.566 +
R!FEIUNCE
24 7
247
5.~510x10Z
T-05
298 - 1000 K)
258
247
COli PILED
6- 'J-76
THERKODYilftiC PROPERTIES OF ftiiERlLS
176
HOLftiUft SESQOIOXIDE (CUBIC)
Ho 2 0 1 :
FORKULl WEIGHT
377.859
Crystals 298.15 to 1800 1.
-------------------------------------------------------------------------------FORftlTIOI FRO! THE ELEKEITS

TEMP.
so
-(G;-a~ 98 ~/T
cop
Jtaoll
JjaolK
J/aoll
0.12
0.32
( a;-a~ 98 )/T
JjaolK
EITHALPY
GIBBS
FREE EIBRGY
kJjaol
Log If
kJ/aol
-------------------------------------------------------------------------------298.15
0.000
158.16
158.16
-1880.700
-1791.373
313.842
106.86
UNCBBTliiiTY
4.850
5.000
0.876
400
500
600
700
800
900
1000
29.400
47.762
60.532
69.916
11. 120
82.856
87.557
191.51
218.53
241.20
260.65
217.68
292.84
306.53
162. 11
170.17
180.67
190.73
200.56
209.98
218.97
118.61
123. 13
125.43
126.93
128.15
129.30
110.47
-1879.106
-1817.175
-1875.093
-1871.011
-1871.040
-1869.229
-1867.648
-1760.876
-1731.535
-1702.602
-16711.014
..;.1645.732
-1617.652
-1589.808
229.948
180.893
148.225
124.917
107.456
91.886
83.043
1100
1200
1300
1400
1500
1600
1700
91.513
911.913
97.892
100.543
102.941
105.131
107. 155
319.02
lJO. 53
341.21
351.23
360.65
369.55
378.01
227.51
235.62
243.34
250.69
257.71
264.112
270.86
131.69
132.97
1311.32
135.74
137.22
1J8. 76
1110.34
-1866.352
-1865.401
-1864.847
-18611.75]
-1865.169
-1866.162
-1867.792
-1562.092
-15311.1159
-1506.918
-11179.403
-11151.844
-11124.266
-1396.612
711.178
66.794
60.549
55.197
50.558
46.498
112.913
1800
109.0114
386.08
211.04
141.98
IIELTING POINT
It
BOIL! NG POI NT
It
ENTHALPY OF KELTING
kJ
kJ
a;9a - H~
21.004 kJ
--------------------------------1900.495
-1367.605
39.687
llOLlR VOLOKE
11.11900 J/bar
44.900 cal
TBAISITIONS IN REFEREMCE STATE ELBKEITS

HOLKIUII ALPHA-BETA 1701, II. P. 1743 K.

74.141 +
2.2966%10-2 T

BEFBREIICE
207
235
1.1132x10J T-05
298 - 1800 K)
235
COKPILED
5-19-76
PBOPBRTIBS AT HIGH TEftPERATURES

DIPOTASSIUft ftOIOXIDE
K2 0:
111
PORftUJ.A IIEIGRT
94.195
Decoaposes above 1154 K. Tabulated data
are a aetastable extrapolation for teaperatures greater than 1154 K.
-------------------------------------------------------------------------------PORI!lTIOI FROft THB ELEIIEITS

TEIIP.
so
-(G;-a~ 98 )/T
cop
J/aollt
J/aollt
J/aolK
6.28
6.28
119.72
140.32
157.89
173.32
187.19
199.86
211.61
97.52
104.08
111.62
119.35
126.98
134.38
141.53
(H;-H~g 8 )/T
J;aolK
ENTHALPY
GIBBS
FREE EIERGY
Log Kf
kJ/aol
kJ/aol
--------------------------------------------------------------------------------322.087
56.429
298.15
94.14
94.14
83.68
-363.171
0.000
UIIICERTAIITY
400
500
600
100
800
900
1000
22.200
36.240
46.268
53.969
60.209
65.478
70.083
2.845
2.092
90.13
94.47
98.31
102.03
105.17
109.56
113.43
0.498
--------------------------------307.317
40.132
-366.867
-365.379
-363.394
-360.992
-358.227
-355.142
-351.751
-292.584
-278.215
-264.196
-250.551
-2J1.269
-224.351
30.566
24.221
19.715
16.359
13.771
11.719
--------------------------------203.151
9.647
-506.535
--------------------------------------------------------------------------------175.835
7.654
77.964
121.35
1200
232.98
155.02
-500.535
1100
74.202
222.60
148.40
117.36
1300
1400
1500
1600
1700
1800
81.457
84.743
87.863
90.854
93.739
96.538
242.86
252.30
261.37
270.13
278.61
286.85
161.40
167.56
113.51
179.2&
184.87
190.31
125.40
129.49
133.63
137.80
142.01
146.25
-494.149
-487.371
-480.200
-1172.625
-464.641
-456.250
-149.042
-122.730
-96.926
-71.635
-46.800
-22.439
!ELTING POIIIIT
BOILIIG POIIT
ENTHALPY OF !ELTING
kJ
kJ
ftOLAB VOLUftE
5.989
4.579
3.375
2.339
1.438
0.651
kJ
11.0380 J/bar
110.380 cal
TRANSITIONS IN REFERENCE STATE ELBBEITS

PO TASSI Oft.. ft. P. 336. 4, B. P. 1030
lt..

49.265 +
11.6059z1o-z T

REFEREIICE
247
2117
6. 1447z102 T-os
298 - 1800 K)
2117
COBPILID
5-24-76
THER!ODYJ&!IC PIOPEBTIES OF !IIERALS
178
POTASSIU! SUPEBOIIDE
K0 2 :
FORI!ULA WEIGHT
Crystals 298.15 to elting point 782 K.
71.097
Aboye 782 K the data
tabalated are a aetastable extrapolation.
-------------------------------------------------------------------------------FOIUlATION FRO II THE ELE!EITS

-( G;-H~'lB )/T
cop
J/olK
JjaolK
J;aolK
11.18
11.18
20.600
33.656
112.870
119.7 59
1116.4!11
165.38
181.59
195.63
125.611
131.72
138.72
1115.87
83.80
87.59
90.13
91.93
900
1000
59.411
62.923
219.03
229.00
159.62
166.08
9 ... 19
94.89
1100
1200
1JuO
1400
150(1
65.854
68.332
70.451
72.279
73.871
238.06
246.38
254.(16
261.17
267.81
172.21
178.05
183.61
188.89
193.94
95.40
95.75
95.98
96.12
96.17
TEIIP.
( H~- H~ 98 )/T
JjaolK
ST
EIITHlLPY
GIBBS
FREE ENERGY
kJjaol
Log Kf
kJ/ol
-------------------------------------------------------------------------------298.15
o.ooo
122.50
-2811.512
-2W. 586
112.150
122.50
77.53
UNCERTAINTY
1100
500
600
700
2.092
2.800
0.1191
--------------------------------2811.828
-225.111111
29.1140
-282.4111
-279.721
-276.861
-210.864
-196.807
-183.215
22.029
17.1311
13.672
-270.921
-267.941
-157.215
-144.751
9.125
7.561
-------------------------------------------------------------------------------BOO
55.116
207.99
152.87
-273.910
-170.030
11. 102
91.211
--------------------------------3114.216
-128.251
6.09(1
-340.287
-336.365
-332.461
-328.573
-108.796
-89.672
-70.831
-52.283
4.736
3. 6(13
2.6113
1.821
IIELT.IIG POIIIT
BO.ILING PO.IIIT
kJ
kJ
kJ
IIOLAR VOLUIIE
3.284(; J/bar
32.8110 cm 3
TRAIISITIOIIS IN BEFEIENCE STATE ELEIIEITS

POTASSIUII II. P. 336.4, B. P. 1030 K.

125.95

BEFERENCE
32
2011
32
769.25 T-os- 1.7033x105 T-z

298 - 1500 K)
32
COIIPILED
6- 8-76
PBOPEBTIBS AT HIGH TBftPEBATUBES
POTASSIUft HtDROIIDE
KOH:
179
FOBftULA II.BlGHT
56.105
1596 K.
-------------------------------------------------------------------------------FORftATIOIII l"ROft THE ELEftEIITS

TEIIP.
H;-H~ 98 )/T
J/aolK
so
-(G;-H~ 98 )/T
cop
J/aolK
J/aolK
J/aolK
0.84
0.84
BHTHALPY
GIBBS
FREE EIERGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
0.0(10
78.91
78.91
64.89
-424.676
-378.932
66.388
UHCEBTAIIITI
o. 500
0.418
400
500
600
679
17.362
28.996
48.053
51.614
98.90
115.72
142.59
183.30
81.53
86.72
94.54
131.68
71.67
79.58
78.66
78.66
700
800
900
1000
64.871
67.150
68.924
70.342
198.33
209.47
219.25
228.00
133.46
142.32
150.33
157.66
83.11
83.11
83.11
83.11
1100
1200
1300
1400
1500
71.503
72.470
73.288
73.989
74.597
235.91
243.14
249.79
249.79
255.95
164.41
170.67
176.50
175.80
181.35
83.11
83. 11
83.11
83. 11
83.11
0.088
--------------------------------426.256
-362.863
47.385
-424.807
-416.556
-415.145
-347.163
-332.859
-342.931
36.268
2H.978
26.381
-406.066
-403.877
-401.741
-399.679
-340.865
-331.733
-322.829
-314.169
25.436
21.660
18.737
16.411
-------------------------------------------------------------------------------679
64.308
195.99
131.68
83.11
-342.931
26.381
-406.526
ftELTIIIIG POIHT
679
ENTHALPI OF IIELTING
8 ~98 - H~
8.619 kJ
12.163 kJ
--------------------------------301.386
14.312
-476.926
-474.009
-471.130
-468.288
-465.483
-285.556
-269.970
-245.917
-230.833
12.430
10.848
9.178
8.038
BOILING POUT
1596
EIITHALPY Ol" VAPOBIZATIOII
142.700 kJ
IIOLAR VOLUIIE
2. 7450 J/bar
27.450 ca 3
TRAHSITIOIIS IN BEFEBEIICE STATE ELEftENTS

POTASSIUII
BEFEBEHCE
709
"
P. 336.4, B. P. 1030 K.
709
709
COIIPILED
10-11-74
TBERBODIIlaiC PROPERTIES OP IIIIRlLS
180
LlNTHlNDB SESQDIOIIDE
La 2 0 3
FORIULl WEIGHT
325.809
-------------------------------------------------------------------------------FOUlTIOH PRO! THE ELEftE!IITS

TEftP.
so
-(G;-u~ 98 )/T
cop
J/olK
J/IIOlK
JjaolK
0.84
0.84
< u;-u~ 98 )/T

J/aolK
E!IITHlLPI
GIBBS
PBEI EIIERGI
kJ/1101
Log Kf
kJ/ol
-------------------------------------------------------------------------------298.15
o.ooo
127.32
-1793.-680
-1705.963
298.879
127.32
107.95
U!IICEBTll NTI
400
500
28.700
46.776
160.38
186.93
131.68
140.15
116.51
121. 33
600
700
800
900
1000
59.495
68.999
76.42:l
82.422
87.400
209.37
228.79
245.93
261.29
275.21
149.87
159.79
169.51
178.87
187.8 1
124.68
127.28
129.44
131.34
133.07
1100
91.625
287.97
196.35
134.66
1200
1300
1400
1500
1600
1700
1800
95.274
98.475
101.321
103.877
106.196
108.319
110.277
2 99.75
310.71
320.96
330.59
339.69
348.32
356.52
204.48
212.23
219.64
226.71
233.49
240.00
246.24
136. 17
137.61
138.99
140.34
141.65
142.93
144.19
1.590
1.600
0.280
-1792.296
-1790.480
-1676.190
-1647.370
218.889
172.100
-1787.113
-1785.198
-1783.437
-1781.875
-1590.658
-1562.730
-1535.901
-1507.495
118.697
102.036
89.142
78.744
-1780.503
-1480.126
70.286
-1796.987
-1795.449
-1793.821
-1792.099
-1790.282
-1788.371
-1423.640
-1394.993
-1366.426
-1338.011
-1309.701
-1281.473
57.203
52.048
47.583
43.682
40.242
37.188
-------------------------------140.936
-1789.155
-1618.878
--------------------------------1798.434
-1452.420
63.222
MELTING POINT
BOILING POINT
ENTHALPY OF !ELTING
kJ
19.841 kJ
kJ
4.9560 J/bar
49.560 ca 3
IIOLAB VOLUftE
TRANSITIONS IN REFERENCE STATE ELEIIEHTS

LANTHANUII ALPHA-BETA 550, BETA-GAftftl 1134, 1. P. 1193 K.

1.3102x102 +
1.0576x1o-z T
298 -

REFERENCE
142
235
2.3418x102
1800 K)
r-o5
235
COIPILED
5-18-76
181
PBOPERTIES AT HIGH TEBP!RATURES

FOSSULA lEIGHT
DILITHIU! BOIOIIDE
29.879
-------------------------------------------------------------------------------FOB!ATIOII FROil THE ELBBEIITS

TEBP.
J/aolK
It
so
-(G;-H~ 98 }/'I'
cop
J/IIOlK
J/IIOlK
J/aolK
0.08
0.08
( H;-H~ 98 }/T
EIITHALPY
GIBBS
FREE EIIERGY
Log 't
kJ/1101
kJ/aol
-------------------------------------------------------------------------------98.458
-561.985
298.15
37.57
37.57
54.09
-598.730
o.ooo
UICERTllliTY
400
14.975
511.79
39.82
62.99
500
600
700
800
900
1000
25.236
32.992
39.150
44.216
48.1189
52.178
69.55
82.62
94.35
104.98
114.72
123.71
44.31
49.63
55.20
60.76
66.23
71.53
69.26
711.09
78.00
81.27
84.08
86.55
1100
1200
1300
1400
1500
1600
55.405
58.268
60.837
63.164
65.289
67.243
132.07
139.87
147.21
1511.13
160.69
166.92
76.67
81.60
86.37
90.97
95.40
99.68
88.75
90.74
92.56
94.24
95.81
97.28
1700
69.051
172.86
103.81
98.67
BELT IHG POINT
1700
ENTHALPY OF BELTING
2.092
2.134
0.374
-599.576
-5119.2911
71.731
-606.667
-606.5114
-606.04!
-605.25
-604.209
-521.926
-507.809
-493.724
-479.736
-465.8119
45.438
37.893
32.237
27.843
24.334
-602.949
-601.1197
-599.872
-598.089
-596.154
-594.075
-452.062
-438.399
-4211.879
-411.483
-398.229
-385. 107
21.467
19.083
17.072
15.353
13.868
12.573
--------------------------------536.024
55.998
-606.314
--------------------------------357.636
10.989
-881.909
It
BOILING POIIIT
kJ
ENTHALPY OF VAPOBIZATIOli
kJ
11.401 kJ
llOLlB VOLUIIE
1.4760 J/bar
14.760 cm 3
TRANSITIONS II REFERENCE STATE ELEBEliTS

LITHIUB ft. P. 453.69, B. P. 1618 K.

1.1748K10Z +
5.3302K10-~
(EQUATION VALID PIOil

REFERENCE
247
247
T
298 -
1.1515K10~
,-os
1800 K)
COIIPILED
5-24-76
182
THEB!ODIHASIC PROPERTIES OF SIJEBALS
LITHIUS HYDROXIDE
LiOH:
FORftULA IIEIGHT
crystals 298.15 to melting point 744.3 K.
23.947
Liquid 744.3 to 1000 K.
-------------------------------------------------------------------------------FOBSATIOII FRO!! THE ELE.IIENTS

TE.IIP.
so
( u;-u~ 98 )/T
J/aolK
-(G;-u~ 98 )/T
co
J/aolK
J/aolK
JjaolK
0.21
0.21
EITHALPY
GIBBS
FREE EIIEBGY
kJjaol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298. 15
-438.94 1
76.901
o.ooo
42.80
-484.926
42.80
49.59
UJCEBTAI NTY
400
13.800
58.66
44.86
58.04
500
600
700
7114. 30
23.230
30.355
36.056
38.231
72.24
84.26
95.08
100.13
49.01
53.91
59.02
61.90
63.64
68.20
72.28
73.99
BOO
67.729
69.878
71.546
133.89
144.14
153.26
66.16
74.26
81.71
86.78
86.78
86.78
o. 159
0.159
0.028
-485.061
-423.193
55.264
-487.299
-486.297
-485.742
-391.401
-375.491
-368.832
34.075
28.020
25.885
-463.398
-460.767
-458.222
-361.350
-348.744
-336.442
23.594
20.241
17.574
--------------------------------407.440
42.565
-487.877
-------------------------------------------------------------------------------744.30
66.281
128.18
-368.832
25.885
-464.864
61.90
86.78
900
1000
I!ELTI NG POINT
744.30 K
BOILING POINT
ENTHALPY OF !ELTING
20.878 kJ
kJ
7.414 kJ
1.6440 Jjbar
16.440 Cllj
ftOLAB VOLUIIE

LITHIUII .II. P. 453.69, B. P. 1618 K.

51.051 +
3.3271x1o-z T
(EQUATIOH VALID FROft

BEFEREHCE
32
215
1.0116x106 T-Z
298- 744.30K)
215
COftPILED
5-19-76
PROPERTIES AT HIGH TE!PBBATUBBS

LUTETIU! SBSQUIOIIDB (CUBIC)
Lu 2 0 3
183
POB!ULA WEIGHT
397.938
-------------------------------------------------------------------------------FO.B!lTIOI FROB THE BLBIBITS

TBIIP.
so
-(G;-H~98 )/T
cop
J/aolK
J/aolK
J/aolK
0.85
0.85
( H;-u; 98 )/T
J;aolK
BBTHALPY
GIBBS
FREE BIBRGY
Loq Kf
kJ/aol
kJ/801
-------------------------------------------------------------------------------298.15
o.ooo
109.96
-1788.849
313.400
109.96
96.39
-1878.200
UICBBTUITY
7.530
6.280
1.100
400
500
600
700
800
900
1000
26.725
43.996
56.398
65.759
73.090
79.000
83.879
140.34
165.54
187.12
205.91
222.51
237.39
250.85
113.61
121.54
130.7 2
140.15
149.42
158.39
166.97
109.39
116.15
120.38
123.29
125.43
127.09
128.41
-1817.510
-1876.178
-1874.499
-1872.679
-1870.842
-1869.073
-1867.428
-1758.252
-1728.583
-1699.212
-1670.148
-1641.334
-1612.753
-1584.348
229.605
180.585
147.930
124.629
107.169
93.602
82.758
1100
1200
1300
1400
1500
1600
1700
1800
87.978
91.478
94.505
97.150
99.487
101.567
103.431
105. 113
263.14
274.45
284.92
294.67
303.79
312.36
320.44
3:.!8. 08
175.16
182.97
190.42
197.52
204.30
210.79
217.01
222.97
129.50
130.42
131.20
131.88
132.48
133.02
133.49
133.92
-1865.966
-18011.731
-18U. 761
-1863.097
-1862.769
-1862.816
-1863.270
-1864.162
-1556.118
-1528.005
-1499.995
-1472.035
-1444.104
-1416.200
-1388.299
-1360.324
73.894
66.513
60.271
54.923
50.288
46.234
42.657
39.476
!liLTING POINT
BOILING POIIIT
ENTHALPY OF BELTING
kJ
ENTHALPY OF YAPORIZATIOI
kJ
17.539 kJ
4.2220 J/bar
42.220 cm 3
I!OLAR VOLUI!E
TRAISITIOIIS Ill RBFERBICB STATE ELBI!ENTS

LUTETIUI! 11. P. 1936 K.
HEAT CAPACITY EQUAtiON

c~
1.4705x10Z-
5.339Jx10Z T-os
1.7548x10 T-z
298 - 1800 K)

REFERENCE
202
281
235
COI!PILEO
6- 8-76
THERIODIIA!IC PROPIBTIIS OP !IIEBALS
184
FORIIDLl !lEIGHT
PEBICLASE
llgO:
40.304
-------------------------------------------------------------------------------FOBUriOI FBOft THE ELEftEHTS

TEitP.
-(G;-a~ 98 )/T
cop
J/aolK
J/ao1K
J/ao1K
0.17
0.17
ca;-a~ 98 )/T
J/aolK
30
EITHALPY
GIBBS
FREE ENERGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------99.721
-569.196
-601.490
298.15
o.ooo
26.94
26.94
37.78
UIICEBTli NTI
400
500
600
100
800
900
10.250
17.010
21.908
25.634
28.580
30.978
38.72
48.55
57.00
64.40
70.96
76.87
28.47
31.54
35.09
38.11
42.38
45.89
42.45
45.41
47.36
48.74
49.78
50.59
1000
32.974
82.24
49.27
51.23
1100
120(1
1300
34.665
36.116
37.375
87.15
91.68
95.88
52.49
55.56
58.50
51.76
52.19
52.55
1400
1500
1600
5000
1800
38.479
39.446
40.302
41.059
41.729
99.80
103.45
106.88
110.11
113.14
61.32
64.00
66.58
69.05
71.41
52.85
53.09
53.32
53.50
53.66
!ELTING POINT
3125
0.290
0.300
0.053
-601.501
-601.302
-601.031
-600.762
-600.528
-600.351
-558.147
-547.337
-536.564
-525.848
-515.157
-504.492
72.887
57.180
46.712
39.239
33.636
29.280
-609.051
-608.882
-608.689
-481.484
-469.892
-458.319
22.864
20.454
18.416
-734.047
-732.649
-731.261
-729.887
-422. H 1
-401.586
-380.951
-360.383
14.707
13.110
11.705
10.458
-------------------------------25.757
-493.092
-609.192
-------------------------------16.535
-735.442
-443.164
BOILIIIG POINT
kJ
5.166 kJ
kJ
1.1248 J/bar
11.248 c;a 3
BOLli VOLUitE
TRANSITIONS IN REFERENCE STATE ELE!ENTS

IIAGNESIUII II. P. 922 1 B. P. 1361 K.

65.211
1.2699x10-J T

REFERENCE
261
204
215
387.24 T-05
298 - 1800 K)
215
247
CO!PILED
7-15-76
185
PBOPEBTIES AT HIGH TEftPEBATDBES

BRUCITE
FOBftULl IIEIGHT
ftg( OK )z:
58.320
At approxiaately 540 K the partial
pressure of steaa in equilibriua vith brucite reaches one ataosphere.
-------------------------------------------------------------------------------POBftATION FRO! THE ELEIIE111TS

TEftP.
K
ca;-a~ 98 )/T
J;aolK
so
T
J;aollt
GIBBS
FREE EHEBGY
-( G;-H; 98 );T
cop
J/aolK
J/aolK
kJ;aol
0.440
0.440
.0.071
-924.416
-923.482
-922.180
-920.691
-919.108
-911.475
-802.310
-171.901
-741.712
-711.766
-682.042
-652.494
104.171
80.640
64.572
53.113
44.533
37.870
EIITHlLPY
Log Kf
kJ/aol
-------------------------------------------------------------------------------146.027
298.15
-833.506
o.ooo
63.18
63.18
77.28
-924.540
UNCERTliiiTY
400
500
600
700
800
900
21.775
36.612
47.477
55.810
62.442
67.889
0.13
0.13
88.21
109.59
128.14
144.44
158.98
172.10
66.43
72.98
80.66
88.63
96.54
104.21
91.91
99.30
104.01
107.45
110.22
112.59
BOILIJG POIHT
!ELTING POUT
ENTHALPY OF ftELTIIG
kJ
11.401 ltJ
EBTHlLPY OP VAPOBIZlTIOI
kJ
2.4630 J/bar
24.630 ca 3
!lOLli VOLD!IE
TBlBSITIOJS Ill BEFEBEICE STATE ELE!IEBTS

!AGBESIU!I !1. P. 922, B. P. 1361 K.
HEAT CAPACITY EQDATIOJ

1.0222x1oz + 1.5107x1o-z T
(EQDlTIOI VALID PBO!I 298 BBFEBEBCE
131
214
2.6172x1o T-z
900 K)
214
102
CO!IPILED
5-26-76
186
THERMODYNAMIC PIOPERTIES OF MINERALS
MA NGA NOS IT E
MnO:
P'OBMULA WEIGHT
Crystals 298.15 to eltinq point
2~54
70.937
K.
-------------------------------------------------------------------------------FOBIIATION FBOM THE ELEIIEJTS

TEIIP.
<a;- H~98 )/T

J/aolK
so
T
-(G;-a~ 98 )/T
J/olK
J/olK
0.42
0.42
co
p
ENTHALPY
J/IIOlK
GIBBS
FREE ENERGY
Log Kf
kJ/1101
kJ/ol
--------------------------------------------------------------------------------362.896
63.578
298.15
59.71
-385.220
0.000
44.10
59.71
UNCEilTAI NTY
400
500
600
700
800
900
11.600
18.856
23.973
27.823
30.854
33.322
73.08
83.76
92.79
100.63
107.59
113.83
61.48
64.90
68.82
72.81
76.74
80.51
46.86
48.78
50.28
51.52
52.59
53.53
1000
35.386
119.52
84.13
54.38
1100
1200
1300
37.148
38.68(1
40.030
124.74
129.57
134.07
87.59
90.89
94.04
55.16
55.89
56.57
1400
41.236
138.29
97.05
57.22
1500
42.321
142.26
99.94
57.84
1600
1700
1800
43.309
44.216
45.053
146.01
149.57
152.96
102.70
105.35
107.91
58.43
59.00
59.56
!!ELTING POINT
o. 502
0.088
-384.870
-384.538
-384.268
-384.073
-383.955
-383.905
-355.324
-347.978
-3110.693
-H3.442
-326.223
-318.997
46.401
36.353
29.660
.24.882
21.300
18.514
-386.207
-386 .261
-386.306
-304.312
-296.855
-289.404
14.451
12.922
11.628
-404.382
-404.918
-257.001
-248.318
7.897
7.206
--------------------------------311.751
16.284
-386.141
-------------------------------10.511
-388.624
-281.888
--------------------------------274. 131
9.546
-391.116
-------------------------------1:1.673
-265.650
-403.802
BOILUIG POINT
ENTHALPY OF MELTING
H~98 -
0.460
kJ
ug
IIOLAR VOLUIIE
.kJ
kJ
1.3221 J/bar
13.221 ca 3
TRANSITIONS IN REFERENCE STATE ELEIINTS

IIANGANESE ALPHA-BETA 980, BETA-GAII!A 1360, GA!IIA-DELTA 1410,
59.749 + 3.&000x1o-~ T
IIFEiENCE
242
120
2.8265x10Z T-os
298 - 1800 K)
263
COIIPILED
6- tl-76
PBOPEBTIES AT HIGH TE!PEBATUBES
PYROLUSITE
187
FOR!ULA WEIGHT
86.937
-------------------------------------------------------------------------------FOi!ATION P'BO! THE ELE!EIIITS

TEl'IP.
( H~-H;98 )/T
J/aolK
so
T
-(G;-H;g 8 )/T
J/aolK
J/aolK
0.42
0.42
70.45
85.17
97.84
108.93
118.78
55.32
59.86
65.15
70.63
76.05
co
ENTHALPY
J/aolK
GIBBS
FREE ENERGY
Log Kf
ltJ/aol
ltJ/aol
-------------------------------------------------------------------------------298.15
0.000
53.05
54.02
-465.138
81.491
53.05
-520.030
UNCEITllNTY
400
500
600
700
800
15.125
25.314
32.692
38.JOO
42.735
IIELTIIIIG POI!IT
ENTHALPY OF !ELTING
63.53
68.08
70.89
72.93
74.60
0.837
0.879
-519.782
-519.163
-518.473
-517.803
-517.180
-446.410
-428. 133
-409.987
-391.964
-314.028
58.295
44.727
35.693
29.249
24.422
BOlLING POINT
ltJ
ltJ
ltJ
!OLAR VOLUl'IE
1.6610 J/bar
16.610 ca 3
TRANSITIONS IN BEPEBEICE STATE ELE!ENTS

MANGANESE ALPHA-BETA 980, BETA-GAftl'IA 1360, GAft!A-DELTA 1410,
1'1. P. DELTA 1517 K.
57.665 + 1.3J83x1o-z T
REFERENCE
168
120
2.6688x102 T-os
298 800 K)
263
COl'IPILED
6-14-7&
THERBODYIABIC PROPERTIES OF ftliEBALS
188
BIIBYITE
FOR!OLA WEIGHT
157.874
-------------------------------------------------------------------------------FOBBATIOH FBOft THE ELEftEITS

TEMP.
so
-(G;-a~ 98 )/T
CDp
Jjaol K
JjaolK
JjaolK
( H;-a~ 98 )/T
JjaolK
GIBBS
ENTHALPY
FBEE EHERGY
Loq Kf
kJjaol
kJ/ol
-------------------------------------------------------------------------------298.15
0.000
110.46
110.46
-958.970
-881.068
154.360
107.65
ONCERTli HTY
.2.09
2.09
400
500
600
700
800
900
27.475
44.204
56.203
65.547
7 3. 211
79.711
14.2.15
166.93
188.10
206.84
223. 77
239.28
114.67
122.73
131.90
141.29
150.56
159.57
109e02
113.55
118.90
124.29
129.37
133.99
1000
85.349
253.62
168.27
138.08
1100
120(1
1300
90.306
94.703
98.622
266.94
279.39
291.05
176.63
184.69
192.43
141.58
144.46
146.71
!!ELTING POINT
ENTHALPY OF MELTIIG
2.092
2. 218
0.389
-958.072
-957.404
-956.738
-955.999
-955.157
-954. 199
-854.602
-828.814
-803.159
-717.625
-752.194
-726.868
111.600
86.586
69.922
58.027
49.113
42.186
-956.433
-955.115
-953.681
-676.042
-650.598
-625.289
32.103
28.320
25.125
-------------------------------36.648
-957.582
-701.592
BOlLI HG POI NT
kJ
EITHALPY OF VAPORIZATIOI
kJ
kJ
IIOLAR VOLOI!E
J. 1370 Jjbar
31.370 cal
TRAISITIONS II REFEBENCE STATE ELEIIEITS

MANGANESE ALPHA-BETA 980 9 BETA-GAIIBA 1360 9 GAIIBl-DELTA 1410,

0.10847 T J.l189z1o- rz
(EQUATIOI VALID FROB 298 - 1300 K)
61.943 +
REFEBEHCE
115
191
120
1. 4552x10 T- 2
263
197
COBPILED
6-14-76
PROPERTIES AT HIGH TERPERATUBES

HAUSIIAUITE
FOR!ULA WEIGHT
Tetragonal crystals 298.15 to
Rn:~O,.:
189
1~~5
K.
Cubic crystals
1~~5
228.812
to 1800 K.
-------------------------------------------------------------------------------FOBIUTIOH FRO! THE ELEREHTS

TEIIP.
so
( u;-H~ 98 )/T
J/IIOlK
J/IIOlK
-(G;-H~ 98 )/T
cop
J/molK
J/mol K
ENTHALPY
GIBBS
FREE ENERGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
153.97
153.97
139.29
-1282.774
224.738
-1387.830
UNCERTAINTY
4.18
4.18
500
600
700
800
900
39.175
64.484
81.855
94.527
104.367
112.467
199.01
235.98
266.73
293.02
316.15
337.02
159.83
171.50
184.88
198.49
211.78
224.55
162.60
167.73
169.57
171.69
175.03
179.74
1000
119.486
356.26
236.77
1100
1200
1300
125.825
131.743
137.411
374.29
391.41
407.85
2~8.47
142.9 36
423.67
1500
160.917
451.79
290.87
210.04
1600
1700
1800
163.986
166.695
169.103
465.34
478.06
490.11
301.36
311.37
321.01
210.04
210.04
210.04
BOILING POIMT
~00
1.674
2.092
0.367
-1386.542
-138~. 870
-1383.639
-1382.903
-1382.511
-1382.254
-12~7.038
-1212.365
-1177.989
-1143.783
-1109.647
-1075.534
162.847
126.655
102.553
85.351
72.453
62.423
185.73
-1388.612
-1041.352
54.395
259.67
270.44
192.86
200.99
209.97
-1388.073
-1386.984
-1385.241
-1006.659
-972.000
-937.495
47.802
42.310
37.669
280.73
219.70
-1374.893
-867.888
30.223
-1411.~29
-795.898
-759.758
24.455
22.048
------------- --- ----------------
--------------------------------1389.601
-902.821
33.685
-------------------------------1445
145.172
430.45
-887.166
32.070
285.28
224.30
-1394.952
-------------------------------------------------------------------------------159.047
444.33
285.28
210.04
-887. 166
32.070
-1374.903
1400
1~45
RELTIIIIG POINT
ENTHALPY OF !ELTING
--------------------------------1411.227
-832.112
27.166
-1411.678
kJ
kJ
IIOLAB VOLUIIE
kJ
4.6950 J/bar
46.950 c11 3
TIANSITIONS IN REFERENCE STATE ELEKEHTS

!ANGANESE ALPHA-BETA 980, BETA-GlftiiA 1360, GAftiiA-D&LTA 1q1o,

-2.4065z10Z +
0.17137 T

BEFEBEIICE
241
197
8.5280x10ll T-OS
298- 1445 K)
263
197
COIIPILED
6- 8-76
190
FORMULA WEIGHT
MOLYBDENUM DIOXIDE
127.939

TEMP.
K
so
-(G~-H~ 98 )/T
cop
Jjaol K
J/aolK
J/molK
( H~-H~ 98 )/T
JjmolK
ENTHALPY
GIBBS
FREE ENERGY
Log Kf
.k.J/1101
kJ/1101
-------------------------------------------------------------------------------93.389
5(1.02
-587.850
-533.053
298.15
o.ooo
50.(12
55.90
UNCERTAINTY
0.30
0.3(1
2.09(1
2.510
0.440
400
500
600
700
800
900
1000
15.400
25.530
32. 87 3
38.517
43.072
46.900
50.212
67.72
82.46
95.13
106.29
116.29
125.42
133.85
52.32
56.93
62.26
67.77
73.22
78.52
83.64
63.88
68.02
71.04
73.69
76.23
78.76
81.33
-587.218
-586.222
-585.035
-583.713
-582.260
-580.668
-578.933
-514.406
-496.327
-478.445
-460.793
-443.324
-426.048
-408.963
67.175
51.851
41.653
34.385
1100
1200
1300
1400
1500
1600
1700
1800
53.159
55.835
58.306
60.621
62.811
64.903
66.918
68.870
141.72
149.14
156.18
162.90
169.35
175.56
181.57
187.40
88.56
93.31
97.87
102.28
106.54
110.66
114.65
118.53
126.95
126.95
126.95
126.95
126.95
126.95
126.95
126.95
-577.041
-574.987
-572.764
-570.368
-567.8(10
-565.055
-562.133
-559.035
-392.054
-375. JJ1
-358.784
-342.406
-326. 225
-310.207
-294.366
-278.703
18.617
16.338
14.416
1.2.775
11.360
10.127
9.045
8.088
MELTING POINT
BOILING POI NT
ENTHALPY OF MELTING
kJ
kJ
MOLAR VOLUI!E
2d.~46
.24.727
.21. 362
kJ
1.9580 J/bar
19.58(1 cm 3

MOLYBDENUM.
ft.
P. 2890 K.

27.146
3.3248x1o-z T

REFERENCE
247
140
247
7.2748x10Z
298 - 1074 K)
T-05
247
159
COMPILED
5-24-76
PROPERTIES AT HIGH TEKPEBATURES

KOLYBOITE
Koo,:
191
FOBKULA WEIGHT
143.938
-------------------------------------------------------------------------------FOB!IATION FRO!! THE ELE!IENTS

TE!IP.
K
so
(H;-H; 98 )/T
J/aOlK
-(G~-H~ 98 )/T
cop
J/aol K
J/aol K
k.J/11101
J/molK
EIITHALPY
GIBBS
FREE ENERGY
Log Kf
kJ/aol
--------------------------------------------------------------------------------668.055
298.15
o.ooo
77.74
77.74
74.88
-745.110
117.041
UNCERTAINTY
0.42
0.42
0.418
0. 460
0.081
4UO
sou
600
700
800
900
1000
1074
20.225
33.286
42.707
so. 010
56.001
61.133
65.694
23. 183
101.03
120.09
136.46
150.91
163.98
176.02
187.26
149.70
80.80
86.8(1
93.75
100.90
107.98
114.89
121.57
126.52
83.01
87.76
91.82
95.86
100.05
104.43
109.01
112.50
-744.120
-742.708
-741.081
-739.241
-737.156
-734.797
-732.118
-718.892
-641.858
-616.453
-591.348
-566.537
-542.000
-517.744
-493.768
-4 76.333
83.818
64.401
51.482
42.276
35.389
30.049
25.792
23.167
1100
1200
1300
1400
1500
69.846
73.708
77.358
80.850
84.225
197.87
207.97
217.67
227.02
236.09
128.02
134.26
140.31
146.11
151.87
126.95
126.95
126.95
126.95
126.95
-729.105
-725.734
-721.984
-717.847
-713.303
-470.071
-446.668
-423.569
-400.761
-378.278
22.322
19.443
17.019
14.953
13.173
-------------------------------------------------------------------------------1074
-476.333
68.724
195.24
126.95
-729.981
23.167
126.52
!!ELTING POIIIT
BOILING POINT
1()74
48.911 kJ
!IOLAR VOLU!IE
kJ
kJ
3.0560 J/bar
30. 560 c111 3
TRANSITIONS IN BEFEREHCE STATE ELE!IENTS

!IOLYBOENU!I.
!1.
P. 2890 K.
5.33u2 +
6.3165x1o-z T
REFERENCE
247
140
247
1.3599x10:t T-os
298- 1074 K)
247
159
COIIPILEO
6- 8-76
THER!ODYNA!IC PROPERTIES OF !IHERALS
19 2
FORIIULA IIEIGHT
NITROGEN DIOXIDE
N0 2
46.005
-------------------------------------------------------------------------------FORUTIOH FROII THE ELEIIEHTS

TEIIP.
so
-(G;-H~g 8 )/T
cop
J/olK
J/molK
J/llol K
o.o8
0.08
( u;-u~ 98 )/T
J/olK
EHTHALPY
GIBBS
FREE EHBBGY
kJ/ol
Log Kf
kJ/ol
-------------------------------------------------------------------------------240.06
51.251
-a. 979
298.15
o.ooo
240.06
36.97
33.095
UNCERTHHTY
0.418
o.q6o
0.081
qoo
500
600
700
800
900
1000
9.825
16.214
20.948
24.661
27.680
30.200
32.334
251.37
26CI.68
268.81
276.04
282.56
288.48
293.92
2"1.54
2"4-"7
247.86
251.38
254.88
258.28
261.59
qo.23
q3.30
q5.86
"7.94
169.63
51.00
52.12
32.520
32.165
31.969
31.882
31.874
31.923
32.003
57.551
63.853
70.209
76.591
82.973
89.378
95.743
-7.515
-6.671
-6.112
-5.715
-5.418
-5.187
-5.001
1100
1200
1300
1400
1500
1600
1700
1800
34.175
35.779
37.188
38.436
39.544
40.537
41.429
42.234
298.93
303.57
307.90
311.95
315.75
319.33
322.71
325.90
264.75
267.79
270.71
273.51
276.21
278.79
281.28
283.67
53.03
53.78
54.39
54.88
55.27
55.58
55.82
56.00
32.110
32.230
32.356
32.485
32.605
32.719
32.824
32.916
102.114
108.483
114.828
121. 167
127.495
133.815
140.120
146.442
-4.849
-4.722
-4.614
-4.521
-4.440
-4.369
-4.305
-4.250
IIELTI HG POINT
261.90 K
10.196 kJ
BOILIHG POIHT
294.25 K
38.116 kJ
IIOLAB VOLUME
2478.9200 Jjbar
24789.200 c 3

91.607-
5.4423:r1u-:~
( EQUlTIOH VALID FRO II

BEFEBEHCE
247
1.108h10:t
298 - 180(1 K)
r-os
247
COMPILED
5-24-76
PROPERTIES AT HIGH TEKPERATORES

DISODIOft KOMOXIDE
193
FORKDLA IIEIGHT
61.979
-------------------------------------------------------------------------------FORUTION FROft THE ELEKEMTS

TEftP.
so
-(G;-H~ 98 )/T
cop
J/aolK
J;aolK
J/aolJI:
0.84
0.84
96.65
114.25
129.44
142.83
154.82
165.71
175.68
78.08
83.61
90.01
96.61
103.15
109.51
115.63
( H;-H; 98 )/T
JjaolK
ENTHALPY
GIBBS
FREE EMEBGY
kJ/aol
Loq Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
75.27
75.27
69. 10
-414.820
-376.089
65.889
UWCEBT llMTY
400
500
600
700
800
900
1000
18.575
30.644
39.433
46.216
51.672
56.200
60.0119
KELTING POUlT
1193
ENTHALPY OF KELTIWG
0.290
0.280
76.30
81.34
85.26
88.47
91.20
93.60
95.711
0.051
--------------------------------362.418
47.327
-420.252
-420.096
-419.372
-418.210
-416.707
-414.941
-412.974
-347.976
-333.611
-319.391
-305.375
-291.569
-271.964
BOILUG POI MT
kJ
EWTHALPY OF VAPORIZATION
kJ
IIOLAR VOLUIIE
36.353
29.0114
23.833
19.939
16.922
14.519
kJ
2.5880 J/bar
25.880 ca 3
TRAWSITIONS IW BEFEBEICE STATE ELEKENTS

SODIUft a. P. 370.98, B. P. 1175 K.
HEAT CAPACITY EQDATIOW
c;
7.11857x1o-~ T 8.1335x10Z T-os

(EQUATIOH VALID FBOS 298- 1000 K)
1.1397x1oz +
RBlBBENCE
247
63
247
183
265
COIIPILBD
6- 9-76
THEIBODYBA!IC PROPERTIES OF BIJEBALS
194
SODIUB HYDROXIDE
HaOH:
FORilULl WEIGHT
Crystals 298.15 to aeltinq point 596 K.
39.997
___________________________________________________________________________ ____
,..
TEIIP.
so
(H;-H; 98 )/T
J/llolK
cop
-( G;-a~ 98 )/T
J/IIOlK
J/llolK
0.81f
0.84
FO.IUIATIOH FROB THE ELEIIEHTS

GIBBS
FREE EIIERGY
Loq Kf
EJTHlLPY
kJ/1101
J/llolK
kJ/1101
-------------------------------------------------------------------------------298.15
64.4]
-379.651
o.ooo
64.43
-425.800
66.514
59.53
UNCEllTAIBTY
0.085
400
500
596
15.877
26.576
45.686
82. 7:J.
98.16
123.36
66.85
71.58
77.67
64.94
75.16
84.97
600
700
800
900
1000
56.972
61.086
64.099
66.378
68. 141
134.98
148.21
159.58
169.54
178.40
78.01
87.12
95.48
103.16
110.26
86.08
85.48
84.88
84.29
83.71
1100
69.531
186.]5
116.82
83.12
1200
1300
1400
1500
1600
1700
1800
70.640
71.534
72.257
72.846
73.324
7J.712
74.027
193.56
200.14
206.20
211.79
216.99
221.83
226.37
122.92
128.61
131.94
138.94
143.67
148.12
152.34
82.54
81.97
81.39
80.82
80.25
79.68
79.11
0.125
0.022
--------------------------------363.727
-428.117
47.498
-lf27.276
-419.155
-347.707
-332.978
36.325
.29.183
-412.443
-409.911
-407.443
-405.057
-402.774
-332.421
-319.286
-30&.507
-294.024
-281.824
.26.940
.23.826
.20.013
17.065
14.721
-400.613
-.269.823
1.2.813
-493.187
-490.491
-487.887
-485.117
-482.958
-480.628
-236.090
-216.430
-196.934
-177.62&
-158.462
-139.454
9.486
6.075
6.858
5. 799
4.869
4.047
-------------------------------------------------------------------------------596
56.178
134.45
-412.541f
-332.978
29.183
77.67
86.10
BELTING POINT
596
ENTHALPY OF !ELTING
6.611 ltJ
10.489 kJ
--------------------------------495. 98]
-.255.972
11. 142
BOILING POI NT
kJ
1.8780 Jjbar
18.780 CIIJ
llOLAR VOLUIIE
TRANSITIOMS IB REFERENCE STATE ELE!EHTS

SODIUI!
1!.
P. 370.98, B. P. 1175 K.

88.445-
5.5178x10-3 T

REFER !ICE
32
32
25.993 T-os
5 96 - 1800 K)
215
32
CO !PILED
5-24-76
PBOP&RTIES AT HIGH TEBPEBATUBES
195
HIOBIUB BOKOIIDE
lbO:
FOBSULA WEIGHT
108.906
-------------------------------------------------------------------------------FOBIIATIOIII FiOft THE ELEBEJTS

TE!P.
so
( a;-H; 98 )/T
J/aolK
-(G;-H~ 98 )/T
cop
J/aolK
J/aol K
lr.J/aol
J/aolK
EIITHALPY
GIBBS
FREE EIIEIGY
Log Kf
kJ/aol
-------------------------------------------------------------------------------&8.&67
298.15
-419.660
-391.945
o.ooo
46.02
46.02
41.11
8.40
8.40
12.550
1.2. 550
2.199
400
500
600
700
800
900
1000
10.875
17.694
22.500
26. 114
28.966
31.300
H.268
58.55
68.58
77.06
84.42
90.96
96.84
102.21
47.67
50.89
54.56
58.31
61.99
65.54
68.94
44.02
45.82
47.20
48.38
49.46
50.48
51.46
-419.377
-418.979
-418.520
-418.021
-417.488
-41&.925
-416.330
-382.515
-373.349
-364.259
-355.259
-346.332
-337.4&4
-328.670
49.952
39.004
31.712
2&.510
22.613
19.586
17.168
1100
1200
1300
14uu
1500
1&00
1700
1800
34.966
3&.460
37.795
39.007
40.117
41.145
42. 105
43.009
107.16
111.7&
116.07
120.13
123.97
127.&2
131.10
134.44
72.19
75.30
78.27
81.12
83.85
8&.48
88.99
91.113
52.42
53.3&
54.29
55.21
56.12
57 .. 02
57.93
58.83
-415.704
-415.048
-414.359
-413.636
-412.881
-41.2.090
-411.264
-410.401
-319.927
-311.254
-302.624
-294.062
-285.561
-277.090
-268.677
-260.317
15.192
13.549
12.160
10.972
9.944
9.u4&
8.255
7.554
UICEBTAIITI
liELTIIIG POIJT
BOI.LIIIG POUT
2210
ENTHALPY OF !ELTING
kJ
lr.J
SOLAR VOLUBE
kJ
1. 4970 J/bar
14.970
cm 3
TRANSITIOJS IN REFERENCE STATE ELEBENTS

IIIIOBIUS 1!. P. 2740 K.
c~ =
43.088
S.8405x10-3 T

REUBENCJ!
33
33
2. 0913 T-o
298 -
1800 K)
33
COIIPILED
5-19-76
THEBftODYNlBIC PROPERTIES OP ftiNEBALS
196
FOBBULA WEIGHT
NIOBIUft DIOXIDE
Nb0 2
llpha crystals 298.15 to 1150 K.
124.905
-------------------------------------------------------------------------------FOBftATIOtl PRO! THE ELEBENTS

TEBP.
( H;-H~ 98 )/T
J/olK
so
-(G;-a~ 98 )/T
cop
J/olK
J/olK
kJ/ol
J/olK
ENTHALPY
GIBBS
FREE ENERGY
Log Kf
kJ/ol
--------------------------------------------------------------------------------7 39. 194

129.5014
298.15
o.ooo
54.51
-794.960
54.51
57.145
URCEBTllRTY
0.30
0.30
8.370
8.370
1. 466
1400
500
600
700
800
900
1000
15.375
25.410
12.835
18.717
41.600
147.800
51.507
7 2.22
86.82
99.57
1 1 o. 97
121.35
130.93
139.87
56.85
61.41
66.73
72.25
77.75
83.13
88.36
63.114
67.83
72.03
75.93
79.62
83.15
86.58
-794.389
-793.465
-792.245
-790.753
-789.001
-786.994
-784.738
-720.221
-701.780
-683.5149
-665.558
-6147.785
-630.241
-612.948
914.052
73.315
59.508
49.665
142.296
36.578
32.017
1100
1150
54.848
56.401
148.28
152.55
93.43
96.15
89.92
91.57
-782.234
-780.870
-595.883
-587.655
28.296
26.692
1200
1300
1400
1500
1600
1700
180(1
61.017
62.712
64.164
65.424
66.526
67.498
68.362
159.53
166.18
172.33
178.06
183.42
188.46
193.21
98.51
103.47
1u8.17
112.64
116.89
120.96
1214.85
83.05
83.05
83.05
83.05
83.05
83.05
83.05
-775.755
-773.937
-772.195
-770. 524
-768.924
-767.390
-765.921
-579.279
-562.973
-546.809
-530.779
-5114.844
-499.028
-483.285
25.215
22.621
20.402
18.1483
16.808
15.333
14.025
-------------------------------------------------------------------------------1150
60.059
26.692
156.20
96.15
-776.664
-587.655
83.05
IIELTING POINT
BOUIRG POINT
kJ
ENTHALPY OF VlPORIZlTION
kJ
kJ
BOLAR VOLUIIE
2175
14.5020 Jjbar
45.020 c 3
TRAHSITIONS IN REFEREHCE STATE ELEBENTS

NIOBIUft 11. P. 2740 K.
HEAT CAPACITY EyUATIONS
c;
69.650 +
2.8178x1o-z T
(EQUATION VlLID FROft

BEFEREMCE
1JO
189
33
3.5572x10Z T-os
298- 1150 K)
33
CO!PILED
8-11-76

197
PBOPERTIBS AT HIGH TE!PBBltORBS
DINIOBIOft PENTOIIDE
Nb 2 0 5
FOR!OLA WEIGHT
crystals 298.15 to .elting point 1785 K.
265.810
-------------------------------------------------------------------------------PORKATION PRO! THE ELE!EIITS

TE!SP.
-(G;-H~ 98 )/T
cop
JjaolK
J/aolK
J/aolK
1. 26
1.26
soT
( H;-H~ 98 )/T
J;molK
ENTHALPY
GIBBS
.P'BEE EBEBGY
Log Kf
kJ/aol
ltJ/ao,l
--------------------------------------------------------------------------------1765.859
309.372
298.15
137.32
137.32
131.99
-1899.536
o.ooo
4.184
4. 200
0.736
142.72
153.32
165.56
178. 13
190.49
202.46
213.91
146.63
154.63
160.10
164.32
167.82
170.90
173.70
-1897.926
-1895.626
-1893.009
-1890.225
-1887.332
-1884.363
-1881.316
-1720.408
-1676.296
-1632.654
-1589.505
-1546.728
-1504.320
-1462.256
224.663
175.122
142.136
118.611
100.991
87.309
76.381
342.73
358.18
372. 58
386.09
398.82
410.87
422.32
485.63
224.88
235.15
245.36
254.93
264.11
272.91
281.36
312.44
176.30
178.76
181.13
183.41
185.63
187.80
189.94
191.73
-1878.212
-1875.048
-1871.820
-1868.525
-1865.172
-1861.747
-1858.252
-1836.357
-1420.491
-1379.034
-1337.80&
-1296.863
-1256.172
-1215.675
-1175.422
-991.481
67.454
60.028
53.754
48.387
43.744
39.688
36.116
29.014
490.99
289.81
242.25
-1751.288
-1135.904
32.963
BOILING POI NT
ONCERTli NTY
400
500
600
700
800
900
1000
35.700
58.748
75.208
87.649
97.456
105.444
112. 137
178.42
212.07
240.71
265.78
287.95
307.90
326.05
1100
1200
1300
1400
1500
1600
1700
1785
117.853
122.827
127.222
131.157
134.712
137.963
140.958
173.186
1800
201.181
--------------------------------------------------------------------------------991.481
29.014
1785
231.598
544.04
242.25
-1732.092
312.44
!SELTUG POINT
1785
ENTHALPY OF MELTING
104.265 kJ
22.288 ltJ
kJ
9.3420 J/bar
93.420 ca 3
BOLAR VOLO!E

NIOBIUM !. P. 2740 K.
1.6605x102 + 1.8368x1o-z T 2.7253x102 T-os

(EQUATION VALID PRO! 298- 1785 K)
BEFEREHCE
189
JJ
J3
CO!PILBD
6- 2-76
THEiftOOYNAftiC PROPERTIES OP ftiiiBALS
198
NEODYftiUft S!SQUIOIIDE (HEXAGONAL)
Nd 2 0~:
FOBftULA WEIGHT
336.478
-------------------------------------------------------------------------------PO illATION FBOll THE ELEIUUITS

TEftP.
ca;-a; 98 )/T
J;molK
so
-( G;-H; 98 )/T
cop
J/molK
J/aol K
J/aol K
4.20
4.20
192.64
220.11
243.47
263.85
282.00
298.41
313.44
163.06
171.81
181.86
192.14
202.26
212.04
221.44
ENTHALPY
GIBBS
FREE ENERGY
Log Kf
ltJ/aol
ltJ/mol
-------------------------------------------------------------------------------298.15
-1721.048
301.522
o.ooo
158.57
-1807.910
158.57
111.25
UICERTAINTY
400
500
600
700
800
900
1000
29.575
48.304
61.612
71.70&
79.736
8&.367
92.000
120.22
125.88
130.31
134.16
137.71
141.07
144. 33
1.000
1.020
0.179
-1806.JJ'l
-1804.506
-1802.667
-1800.93&
-1799.393
-1798.097
-1797.103
-1691.604
-16&3. 136
-1635.030
-1607.239
-1579.669
-1552.271
-1525.013
220.902
173.747
142.343
119.934
103.142
90.092
79.&59
-1796.467
-1497.850
71.127
-1815.2133
-1415.402
52.999
-1814.3J1
-1813.995
-1813.702
-1813.445
-1813.220
-1413.973
-1385.400
-1356.830
-1328.291
-1299.734
52.756
48.244
44.296
40.814
37.717
1100
96.903
327.35
230.45
147.51
1200
101.251
340.32
239.07
150.65
1300
1395
105.170
108.373
352.50
363.26
247.33
254.89
153.75
156.70
1400
1500
1600
1700
1800
109.200
112.299
115.008
117.399
119.523
364.47
375.21
385.25
394.69
403.58
255.27
262.91
270.24
277.29
284.06
155.64
155.64
155.64
155.64
155.64
BOILING POINT
--------------------------------1470.322
-1 tl01. 924
64.002
--------------------------------1455.616
5t1.488
-1815.300
-------------------------------------------------------------------------------1395
109.043
-1415.402
52.999
363.93
254.89
155.64
-1814.348
!!ELTING POINT
EITHALPY OP !ELTING
k.J
21.004 ltJ
ENTHALPY OF YAPOBIZATION
ltJ
4.5920 J/bar
45.920 cm3
liOLAB VOLU!!E

NEODYMIUM ALPHA-BETA 1128, M. P. 1289 K.
c~
1.1574xtoz + 2.9779x1o-z T
1.188Jx10 T-z
(EQUATIOH VALID FBOft 298- 1395 K)
REFERENCE
210
235
235
COftPILID
tl-1 1-76
PBOPEBTIES AT HIGH TEftPERATUBES

BUIISBUTE
lliO:
199
FOBIIULA !lEIGHT
711.699
Crystals 298.15 to aeltinq point 2257 K. a-p transition at 525 K and

p-y transition at 565 K.
TEMP.
K
soT
cH;-a; 98 )/T
J;aolK
FORftlTIOII PBOft THE ELEftEITS

GIBBS
FREE EIIEBGY
Loq Kf
-( G;-a~ 98 )/T
cop
J/aolK
J/aolK
ltJ/aol
J;aolK
EIITH.U.Pl
ltJ/aol
-------------------------------------------------------------------------------298.15
0.000
37.99
168.04
-239.7113
-211. 581
37.99
37.068
UICEBTUIITY
0.17
0.17
0.418
0.460
0.081
1100
500
12. 175
21.212
52.01
64.73
39.83
43.52
52.74
53.22
-239.170
-237.923
-202.044
-192.873
26.384
20.149
800
900
1000
33.786
35.956
17.795
90.71
96.99
102.71
56.92
61.03
64.91
52.87
53.83
54.79
-23b.052
-235.562
-235.099
-166.504
-157.838
-149.219
10.872
9.161
7.794
1100
1200
1300
1400
15(10
1600
1700
39.384
110.787
112.050
43.200
411.261
115.250
116.179
107.98
112.87
117.115
121.76
125.811
129.71
1J3.41
68.60
72.08
75.1.0
78.56
81.58
84.46
87.23
55.75
56.71
57.67
58.64
59.60
60.56
61.52
-234.68(1
-2311.2811
-233.886
-233.466
-232.995
-232.11511
-231.826
-140.663
-132.122
-123.633
-115. 166
-106.7110
-98.334
-89.970
6.680
5.751
11.968
11.297
3.717
3.210
2.764
1800
47.058
136.96
89.90
62.48
-------------------------------------------------------------------------------600
27.747
75.79
50.94
-236.734
-184.009
48.04
16.019
-------------------------------700
31.130
83.71
51.91
-236.535
-175.222
13.075
52.58
I!ELTI IIG POIIIT
2257
EIITHlLPY OF !ELTING
--------------------------------811.885
2. 347
-249.017
BOILING POINT
ltJ
ltJ
6.&911 ltJ
1.0970 J/bar
10.970 ca 3
I!OLAI:! VOLUI!E
TRANSITIONS Ill BEFEBEICE STATE ELEBEIITS

NICKEL CURIE P. 631
1!.
P. 1726
K.

c~
9.6149x1o-~ T
115.175 +
REFERENCE
129
120
565 -
1800 K)
23
263
CO!! PILED
621-76
THER!ODYilftLC PROPERTIES OP !IIEBlLS
200
POB!ULl !lEIGHT
PHOSPHORUS !OIOIIDE
PO:
46.973
-------------------------------------------------------------------------------POB!lTIOII PBOft THE ELE!EITS

TE!P.
so
T
-( G;-H~ 98 )/T
cop
J/olK
J/olK
J/olK
0.02
0.02
{ H;-u~ 98 )/T
J/olK
EITHlLPI
GIBBS
FREE EIIEBGY
kJ/ol
Loq Kf
kJ/ol
-------------------------------------------------------------------------------298.15
0.000
222.77
222.77
-12.134
-41.157
7.211
31.76
UIICEBTll IITY
4.184
4.200
0.736
400
500
600
700
800
900
1000
8.150
13.086
16.507
19.051
21.032
22.622
23.942
232.18
239.49
245.62
250.91
255.57
259.74
263.51
224.03
226.40
229.11
231.86
234.54
237.12
239.57
32.39
33.23
33.99
34.63
35.16
35.59
35.95
-12.654
-13.292
-14.027
-14.871
-101.258
-101.248
-101.231
-51.000
-60.510
-69.890
-79.139
-110.430
-111.578
-112.726
6.660
6.322
6.084
5.905
7.210
6.476
5.888
1100
1200
1300
1400
1500
1600
17(10
1800
25.048
25.992
26.807
27.521
28.144
28.699
29.194
29.637
266.95
270.11
273.04
275.76
278.31
280.70
282.95
285.07
241.90
244.12
246.23
248.24
250.17
252.00
253.76
255.43
36.25
36.49
36.68
36.84
36.97
37.07
37.14
-101.218
-101.210
-101.201
-101.193
-101.198
-101.205
-101.218
-101.236
-113.877
-115.025
-116.174
-117.317
-118.475
-119.633
-120.785
-121.925
5.408
5.007
4.668
4.377
4.126
3.906
3.711
3. 538
IIELTIIIG POIIIT
31.20
BOILING POINT
EIITHlLPY OP !ELTIIG
kJ
9.393 kJ
EHTHlLPI OF VlPOBIZATIOH
kJ
IIOLAB VOLUME
J/bar
TBAIISITIOIS IM BEFEREICE STATE ELE!EITS

PHOSPHORUS. SUBLIMES 704 K.
KElT CAPACITY EOUlTIOI

49.471 -
1.9035I10-;~
(EQUlTIOI VALID FROII

BEPBBEICE
32
32
3. 81 15I10Z T-05
298 - 1800 K)
32
CO!PILEO
5-216-76
201
PBOPBITIBS AT HXGB TB!PIBATUIBS

PHOSPHORUS PBI!OIIDB
P2 0:
POIIIULA IBIGBT

( PaO ) 2
141.945
Tbe free energy change for tbe reaction
c ) P Ou (g) approaches zero at 631 1.
-------------------------------------------------------------------------------l'OB!lTIOI PBOII 1'HB BLB8BITS

TE8P.
(s;-a;98 )/1'
J/aolK
soT
J/aolK
-<~-H~g8)/1'
J/aolK
cop
BIITBALPI
J/aoll
GIBBS
PBBB BIBBGI
Log Kf
kJ/aol
kJ/aol
--------------------------------------------------------------------------------1337.897
234.396
298.15
o.ooo
115.50
105.86
-1470.000
115.50
UICBITUITI
4. 200
4. 200
o. 736
-1469.571
-1467.072
-1462.646
-1456.387
-1619.194
-1607.236
-1593.367
-1292.781
-1248.837
-1205. 572
-1163.209
-1166.197
-1110. 251
-1055. 763
168.820
130.466
104.955
86.800
76. 146
64.438
55.147
0.40
0.40
151.46
18 69
216.28
246.59
275.86
304.23
331.80
120.13
129.75
141.56
1511. 41
167.77
181.37
195.04
125.42
148.01
170.60
153. 97
153.97
153.97
153.97
BIL'flliG POII'l'
BOILIIIG POll!
BITBALPI OP BBLTIIG
kJ
BITBlLPI OP YAPOBIZITIOI
B~ga - B~
ltJ
IIOLAB YOLOBB
400
500
600
700
800
900
1000
31.327
54.936
74.720
92.. 180
108.089
122.861
136.758
5. 9400 J/bar
59.400 ca 3
TRAISITIOIS I I RBPIRIICB STATE BLE!BHTS

PBOSPBOBUS. SOBLX!BS 704
I.
HBl'f CAPACITI IQDATIOI
c; =
35.041 + 0.22594 T
( liQOATIOI UJ.D PBOII
IIPBUICB
21&7
215
298 -
631 lt)
215
CO!PILID
03-15-79
202
THIBIODJIA!XC PIOPIRTIIS o !lJKilLS
FOBIOLl IBIGBT
PHOSPHOBOS PBITOXIDB (DI!IBIC)
283.889
===========================================-=========================-ac=-=
(P 2 0 5
Crystals 289.15
)2:
(Pz0s) 2
(c)~
to 1000 K.
The free energy change for the reaction
P0 10 (g) approaches zero at 631 K.
-------------------------------------------------------------------------------.alUilTIOI FBOI TBB BLBBBITS

TMP.
(a;- B~ 98 )/T
J/olK
so
-(G;-a~ 98 )/T
cop
JjaolK
J/aol K
JjaolK
BITHALPY
GIBBS
Pill BIBBGI
Log 't
kJjaol
kJ/aol
-------------------------------------------------------------------------------468.791
-2940.000
298.15
-2675. 794
o.ooo
231.00
231.00
211.71
o. 80
0.80
302.92
369.37
1132.56
1193. 19
551.72
608.116
663.59
2110.26
259.49
283.11
308.83
335.54
362.73
390.08
U IICBBT.li liT I
1100
500
600
700
800
900
1000
62.665
109.880
1ft9.11115
181t.3611
216.176
2115.721
273.516
I!ELTX IG POI liT

EBTBlLPJ OF !BLTIIIG
kJ
311.551 kJ
250.611
296. OJ
341.22
307.94
307.911
307.94
307. 94
8. 400
8.400
1. 472
-2939. 138
-2934. 140
-2925. 289
-2912. 772
-3238.390
-3214. 473
-3186. 734
-2585.558
-2497.670
-2411. 141
-2326.417
-2332. 395
-2220.501
-2111.526
337.641
260.931
209.909
173.600
152.290
128.876
110.296
BOlLI IG POI IT
BNTBALPJ Ol YAPORIZATIOI
kJ
11.8800 .l~ar
118.800 cal
lOLli YOLO!B
TRlNSITIO!IS I I BEFEBE!ICE STATE BLBftiNTS
BEAT CAPACITY BQOATION
c; =
70.082 + 0.45190 T
( BQDATIOI YAI.ID FBOB
BEFEBBIICB
2117
215
298 -
631 K)
215
CO!PILBD
03-15-79
PROPERTIES AT HIGH TEI!PERATURES
203
ORTHOPHOSPHORIC ACID (CRYSTAL)

H3 Po.:
FORilULA IIEIGHT
Crystals 298.15 to aeltinq point 315.5 K.
97.995
AboYe 315.5 K the data
tabalated are a metastable extrapolation.
-------------------------------------------------------------------------------FORMATION FRO I! THE ELEIIEIITS

so
-(G;-a~ 98 )/T
cop
J/aolK
J/aolK
JjaolK
0.42
0.42
146.02
179.82
212.98
245.70
278.09
310.24
342.18
115.09
124.66
136.63
149.88
163.88
178.3&
193.14
(H;-H~ 98 );T
TEilP.
J;aolK
ENTHALPY
GIBBS
FREE ENERGY
Loq
Kf
kJ/aol
ltJ/aol
-------------------------------------------------------------------------------298. 15
-1112.290
194.869
0.000
110.54
110.54
106.06
-1266.920
UNCERTAINTY
400
500
600
700
800
900
1000
30.925
55. 156
76.3 53
95.821
114.209
131.678
149.037
!!ELTING POINT
315.50 K
ENTHALPY OF llELTI IIIG
13.400 ltJ
H~98
H~
2.510
2. 090
136.91
167.20
197.48
227.77
258.06
288.35
318.64
--------------------------------1059.332
138.335
-1267.310
-1265.005
-1260.004
-1252.301
-1327.312
-1313.073
-1295.984
-1007.551
-956.478
-906.476
-879.923
-824.804
-771.449
BOILING POUT
105.259
83.269
67.&42
57.453
47.871
40.297
kJ
4.8520 J/bar
48.520 c11 3
llOLAR VOLUilE
ltJ
0.440
TRANSITIONS IN REFERENCE STATE ELEilENTS

PHOSPHORUS. SUBLII!ES 704 K.
c;
0.30288 T
(EQUATION VALID FRO!l
15.756 +
BEFEBEIICE
32
32
298- 1000 K)
32
COI!PILED
5-19-76
204
THERMODYHAMIC PROPERTIES OF MIIEBALS

FORMULA IIEIGHT
ORTHOPHOSPHOIIC ACID (LIQUID)
H~PO:
97.995
Liquid 298.15 to 1000 K.
-------------------------------------------------------------------------------FORIUTIOII FRO! THE ELEMENTS

TEitP.
( H~-H~ 98 )/T
J;aolK
-(G;-H~ 98 );T
CDp
J/molK
J/aol K
J/aol K
4.20
4.20
197.69
240.14
280.34
318.97
356.47
393.10
429.04
15&.84
169.31
184.50
200.96
218.06
215.49
253.04
So
T
EIITHlLPY
GIBBS
FREE EIERGY
kJ;aol
Log J(f
kJ/aol
-------------------------------------------------------------------------------194.766
298.15
0.000
-1254.200
-1111.700
150.78
150.78
145.05
UHCERTliiiTY
400
500
600
700
800
900
1000
40.850
70.8)0
95.843
118.014
138.407
157.611
175.995
ltELTING POINT
175.73
205.85
235.98
266. 10
296.22
326.35
35&.47
0.440
-------------------------------138.855
-1063.310
-1250.&20
-1244.448
-1235.590
-1224.046
-1295.233
-1277.193
-1256.306
-1017.154
-972.480
-929.510
-910.548
-863.498
-818.631
106.262
84.&62
69.361
59.453
50.116
42.761
BOILING POI HT
kJ
kJ
kJ
!tOLAR VOLUME
J/bar
315.50 K
ENTHALPY OF !ELTING
2.510
2.090
TRAHSITIOHS IH REFERENCE STATE ELE!EHTS

PHOSPHORUS. SUBLIMES 704 K.
c:
0.30123 T
55.239 +
REFERENCE
32
32
298 - 1000 K)
32
COMPILED
5-19-76
205
LITHARGE (RED)
PbO:
FOB!OLA WEIGHT
223.199
Tetragonal crystals 298.15 to 1400 K. !assicot (orthorhombic) is the

stable phase above 762 K.
See table for lead aoooxide (reference state).
-------------------------------------------------------------------------------FORMATION FRO! THE ELEMENTS

TE!!P.
K
so
-(G;-a~ 98 )/T
cop
J/aolK
J/aollt
J;aolK
0.84
0.84
( u;-H~ 98 )/T
J;molK
ENTHALPY
GIBBS
FREE ENERGY
Log Kf
kJ/aol
kJ/mol
-------------------------------------------------------------------------------33.148
298.15
().000
-219.409
-189.202
66.32
66.32
45.77
UHCERT AIIITY
400
500
600
12.325
20.250
25.910
80.51
92.09
101.97
68.18
71.84
76.06
50.51
53.20
55.13
700
800
900
1000
30.199
33.599
36.389
38.747
11 o. 59
118.25
125.17
131.48
80.39
84.65
88.78
92.73
56.70
58.08
59.35
60.55
1100
1200
1300
1400
40.782
42.572
44. 174
45.621
137.31
142.73
147.80
152.58
96.53
100.16
103.63
106.96
61.71
62.83
63.93
65.02
0.830
0.900
0.158
-218.740
-217.863
-216.909
-178.974
-169.133
-159.474
23.J72
17.669
13.883
-219.733
-218.547
-217.229
-139.025
-129.006
-119.119
9.071
7.487
6. 222
-215.791
-214.236
-212.568
-210.800
-109.388
-99.786
-90.303
-80.978
5.194
4.344
3.628
3.021
-------------------------------11.132
-149.183
-220.786
!ELTIIIG POIIIT
BOILIIIG POINT
EITHALPY OF !ELTIIIG
kJ
kJ
kJ
SOLAR VOLOIIE
2.3910 J/bar
23.910 cm 3
TBAIISITIOIIS Ill REPEBEBCE STATE ELBIIEIITS

LEAD B. P. 600.6, B. P. 2021 K.
51.011 + 1.0272x1o-z T
(EQOlTIOII VALID PRO!
BEPIREIICB
32
32
7. 3872x1 os T-2
298 - 1400 K)
32
COIIPILED
6- 7-76
206
THEBftODYNAftiC PROPERTIES OF ftiNEBALS
ftASSICOT (YELLOW)
PbO:
FORftDLA WEIGHT
Orthorhoabic crystals 298.15 to 1170 K.
223. 199
See table for lead monoxide
(reference state). Liquid 1170 to 1789 K.
-------------------------------------------------------------------------------FOR RATION FRO!! THE ELEftENTS

so
( H;-H~ 98 )/T
-(G;-H~ 98 )/T
Cp
J/aolK
J/aolK
J/aolK
o. 21
0.21
bOO
12.025
19.532
24.827
82.57
93.61
102.96
70.54
74.08
78.13
48.53
50.46
52.10
700
800
900
1000
28.631
32.017
34. &5&
36.894
111. 10
118. 36
124.92
130.93
82.27
86.34
90.2&
94.04
53.&0
55.03
56.41
57.76
1100
1170
38.85.2
18.255
136.50
118.42
97.65
100.16
1200
1300
1400
1500
1600
1700
40.679
42.510
44.099
45.490
46.725
47.831
141.78
146.94
151.74
156 .22
1&0.43
164.40
101.10
104.43
107.&4
110.73
113.70
116.57
TEftP.
K
J;aolK
ENTHALPY
GIBBS
FREE ENERGY
Log Kf
kJ;m~l
kJ/aol
-------------------------------------------------------------------------------29B. 15
0.000
&8. 70
ij5.77
-188.573
33.037
68.70
-218.070
U!ICERTAINTY
400
500
0.630
0.700
0.123
-217.521
-216.883
-21&.220
-178.579
-168.913
-159.379
23.320
17.646
11. B75
-219.659
-218.768
-217.743
-139.039
-129.002
-119.083
9.078
7.487
6.220
59.10
60.03
-216.575
-241.224
-109.281
-102.532
5.189
4.578
&5.00
65.00
&5.00
65.00
65.00
65.00
-215.271
-213.434
-211.&10
-209.794
-208.003
-206.229
-99.582
-90.007
-80.590
-71.303
-&2.126
-53.068
4. 335
3.617
3.007
2.483
2.028
1.631
--------------------------------149.158
-220.404
11.130
-------------------------------------------------------------------------------1170
40.069
-102.532
140.23
4. 578
100.16
65.00
-215.702
!!ELTING POINT
1170
25.522 kJ
kJ
BOILING POINT
1789
207.233 kJ
KOLAR VOLUIIE
2.3150 J/bar
23. 15v cm 3

LEAD II. P. 600.6, B. P. 2021 K.
ij5.188 + 1. 286Jx10- 2 T
REFERENCE
32
2.8918x105 T-2
298- 1170 K)
32
COIIPILED
6- 7-76
PROPERTIES AT HIGH
TE~PERATURES
207
LEAD 80HOXIDE (REFERENCE)
PbO:
FOR8ULA WEIGHT
Litharge (red) 298.15 to 762 K.
223.199
eassicot (yellow) 762 to 1170 K.
Liguid 1170 to 1789 K.
-------------------------------------------------------------------------------FOR!IATION FRO! THE ELEIIENTS

TEIIP.
(H;-H~ 98 )/T
JjmolK
-( G;-H~ 98 )/T
co
J/molK
J/mol K
J/mol K
0.84
0.84
so
T
ENTHALPY
GIBBS
FREE ENERGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
66.32
66.32
45.77
-219.409
-189.202
33.148
UNCERTAINTY
0.830
0.900
0.158
-218.740
-217.863
-216.909
-178.974
-169.133
-159.474
23.372
17.669
13.884
-220.066
-1il1. 863
9.725
4(10
500
600
12.325
20.250
25.910
80.51
92.09
101.97
68.18
71.84
76.06
50.51
53.20
55.13
700
762
30.199
32.385
110.59
114.64
80.39
82.24
56.70
57.57
800
900
1000
33.859
36.257
38.305
118.37
124.90
130.88
84.51
88.64
92.57
55.03
56.41
57.76
-219.525
-218.666
-217.671
-138.913
-128.878
-118.956
9.070
7.480
6.214
1100
1170
40.090
41.214
136.40
139.86
96.31
98.64
59. 10
60.04
-216.552
-215.702
-109.146
-102.093
5. 1tl3
4.558
1200
1300
1400
1500
1600
1700
63.027
63.063
63.172
63.286
63.398
63.514
63.632
161.67
163.22
168.38
173.18
177.66
181.87
185.84
98.64
100. 16
105.21
109.89
114 .26
118.36
122.21
65.00
65.00
65.00
65.00
65.00
65.00
65.00
-190.180
-189.647
-187.871
-186.070
-184.255
-182.4.20
-180.571
-102.093
-99.785
-92.360
-85.088
-77.935
-70.908
-63.':194
4.558
4.344
J. 711
3.175
2.714
2.315
1.966
--------------------------------220.786
-149.183
11.132
-------------------------------------------------------------------------------762
32.824
-141.863
1 15.06
82.24
54.50
-219.731
9. 725
-------------------------------------------------------------------------------1170
~ELTING
POINT
ENTHALPY OF
1170
!~ELTING
25.522 kJ
kJ
TRANSITIONS IN REFERENCE STATE

LEAD
~.
BOlLING POINT
1789
207.233 kJ
~OLAR
.2.3910 Jjbar
23.910 cm 3
VOLU!IE
ELE~ENTS
P. 600.6, B. P. 2021 K.
c~
51.017 + 1.0272x1o-z T
(EQUATION VALID PBO~
REFERENCE
32
115
32
7.3872x1os T-z
298- 762 K)
32
CO~PILED
b-.29-76
THERI!ODYMAftiC PROPERTIES OF ftiMEBALS
208
FORRULA WEIGHT
PLATTNERITE
Pb0 2 :
219.199
-------------------------------------------------------------------------------FOB RATION FBOft THE ELERENTS

TERP.
( H;-H~ 98 )/T
J/IIOlK
ST
J/IIOlK
GIBBS
FBEE EBEBGY
-(G;-a~ 98 )/T
cop
J/aolK
J;aolK
kJ/aol
2.929
3.000
0.526
-273.603
-272.438
-271.184
-195.219
-175.758
-156.536
25.493
18.361
13.628
-273.488
-272.097
-270.624
-117.104
-97.623
-78.324
7.646
5.666
4.091
-269.068
-267.438
-59.177
-40.158
2.810
1. 748
EIITHALPY
Lo<j Kf
kJ/1101
-------------------------------------------------------------------------------37.722
-274.47(1
-215.314
298.15
0.000
71.80
71.80
61.17
UNCERTAINTY
0.42
u.42
400
500
600
16.600
27.310
34.930
90.90
106.54
119.85
74.30
79.23
84.92
68.23
71.82
74.11
700
800
90(1
1000
40.653
45.131
48.756
51.760
131.41
141.62
150.77
159.08
90.76
96.49
102.01
107.32
75.79
77.14
78.30
79.34
1100
12(1()
54.313
56.517
166.69
17 3. 71
112.38
117.19
80.31
81.22
-------------------------------1u.2o1
-274.783
-136.736
I!ELTIIIG POINT
BOILIIIG POINT
kJ
kJ
H~98 - H~
2.5010 J/bar
25.010 ca 3
ftOLlB VOLURE
10.966 kJ
I
TR lHS ITIONS IN B.E.FEBEIICE STATE ELEft!NTS

LEAD ft. P. 600.6, B. P. 2021 K.

73.119 +
7.4840x1o-:. T
(EQUATION VALID FBOB

BE FERENCE
32
32
1. 2605x1o
298 - 1200 K)
r-z
32
COftPILED
6- 7-76
PROPERTIES AT HIGH TEBPERATURES

BIIIIUB
209
FORBULA WEIGHT
crystals 298.15 to 1800
685.598
~.
-------------------------------------------------------------------------------FOIBATION FRO! THE ELEBEITS

TEBP.
so
cu;-u; 98 )/T
J/aolK
cop
-(G;-H; 98 )/T
J/aolK
J/aollt
6.69
6.69
EIITHALPY
GIBBS
FREE ENERGY
kJ/aol
kJ/aol
J/aol~
Log Kt
-------------------------------------------------------------------------------298.15
-601.358
0.000
211.96
1511.93
105.356
211.96
-718.686
UIICERTli NTY
400
500
600
42.025
69.264
88.798
260.32
300.06
334.04
218.29
230.80
245.24
172.95
182.86
189.76
700
800
900
1000
103.624
115.377
125.022
133.143
363.71
390.10
413.90
435.63
260.09
274.72
288.88
302.49
195.24
199.97
204.25
208.26
1100
1200
1100
1400
1500
1600
1700
1800
140.147
146.298
151.785
156.743
161.280
165.466
169.364
173.020
455.66
474.28
491.69
508.09
523.59
538.32
552.36
565.80
315.51
327.98
339.90
351.35
362.31
372.85
383.00
392.78
212.10
215.81
219.44
223.00
226.52
230.00
233.46
236.89
IIELTIIIG POliiT
ENTHALPY OF ftELTIIIG
kJ
30.188 kJ
6.276
6.3110
1. 1011
-716.171
-712.835
-709.171
-561.615
-523.365
-485.803
73.340
54.676
42.293
-715.914
-711.11119
-706.591
-407.698
-369.404
-331.661
26.620
21.440
17.324
-701.350
-695.745
-689.790
-683.508
-676.899
-669.986
-662.772
-655.270
-294.438
-257.697
-221.400
-185.640
-150.294
-115.426
-80.981
-116.924
13.982
11.217
8.896
6.926
5.234
3.768
2.488
1.362
--------------------------------11116.483
-719.952
33.317
BOILIIG POIIIT
It
EIITHALPY OF VAPORIZlTIOII
kJ
7.6810 J/bar
76.810 cal
BOLAR VOLUIIE
TBliiSITIONS Ill REFERENCE STATE ELEIIEIITS

LEAD ft. P. 600.6, B. P. 2021 K.
c;
1.7793x10Z +
3.3260x1o-z T 2.9259x10
298- 1800 K)
r-z
(EQUATION VALID FROB

REFEBEIICE
32
32
32
COBPILED
6- 7-76
210
THER!ODIIA!IC PROPERTIES Of
!INERA~S
PRASEODY!IU! SESQUIOIIDE (HEX)
Pr 2 0 3 :
FORftULA WEIGHT
329.814
-------------------------------------------------------------------------------FORKATIOI FRO! THE ELEMENTS

TEMP.
so
cu;-u~ 98 )/T
JjaolK
-(G;-u~ 98 )/T
J/molK
J/aolK
4.20
4.20
Co
ENTHALPY
GIBBS
FREE EKERGY
lr.Jjaol
lr.J/1101
J/aolK
Log Kf
-------------------------------------------------------------------------------298.15
o.ooo
158.57
-1121.025
158.57
-1809.580
301.518
120.40
UNCERTAiliTY
6.690
6.700
1.174
-1807.380
-1804.946
-1802.579
-1800.364
-1798.355
-1796.589
-1795.082
-1691.286
-1662.541
-1634.282
-1606.415
-1578.839
-1551.510
-1524.352
220.860
173.685
142.278
119.873
103.088
90.048
79.624
40(1
500
600
700
800
900
1000
31.025
50.492
64.138
74.391
82.484
89.111
94.703
194.79
223.40
..!47.53
268.47
287.04
303.78
319.06
163ft 76
172.91
183.39
194.08
204.56
214.67
224.36
126.08
130.46
134.20
137.57
140.68
143.61
146.40
1100
1200
99.526
103.767
333.14
346.23
2J3.61
242.46
149.10
151.72
1300
1400
1500
1600
1700
1800
107.553
110.979
114.114
117.009
119.425
122.235
358.47
370.00
380.89
391.25
401.12
410.56
250.92
259.02
266.78
214.24
281.69
288.32
154.27
156.77
159.23
161ft65
164.05
166.41
!ELTING POINT
BOIL! NG POI NT
EHTHALPY OP KELTING
k.J
ENTHALPY OF VAPOBIZATIOH
k.J
--------------------------------1497.163
-1799.927
71.095
-1797.91 1
-1469.729
63.976
-1808.803
-1807.071
-1805.136
-1803.472
-1800.b49
-1413.023
-1384.806
-1356.712
-1329.249
-1300.915
52.721
48.223
44.292
40.843
37.752
--------------------------------1441.323
-1810.328
57.913
lr.J
4.6530 Jjbar
46.530 ca 3
ftOLAR VOLUME
TRANSITIONS IN REFERENCE STATE ELE!EWTS

PRASEODYMIUM ALPHA-BETA 1068, ft. P. 1204 K.

1.3845x10Z +
2.0864x1o-z T
4.0b16x102
298- 1800 K)
r-os

REFERENCE
200
281
235
COIPILED
6-14-76
PIOPEITIBS AT HIGH TB!PBIATUBES
PBASEODI!IU! OliDE
Pro 1 .~:
211
POB!ULA WEIGHT
Alpha crystals
298.15
to 760 K.
170.235
-------------------------------------------------------------------------------FOil!lTIOI PBO! THE BLBIIEITS

TEIIP.
(H;-8; 98 )/T
J/aolK
so
-( G;-8~9 8 )/T
cop
J/aoll
J/aolK
J/aolK
4.20
4.20
EIITHALPY
GIBBS
PBEE EIBBGY
Loq
Kf
kJ/aol
kJ/ol
-------------------------------------------------------------------------------298.15
79.91
79.91
0.000
65.86
-1904.560
-1196.610
314.760
UICEBT.UITY
6.690
6.700
1.114
400
500
600
700
760
17.400
28.542
36.713
43.337
46.446
99.95
116.25
130.44
143.19
150.72
82.55
87.71
93.67
99.85
104.28
70.74
75.54
80.33
85.12
87.99
-1903.208
-1901.609
-1899.717
-1897.736
-1896.563
-1831.9160
-1814.308
-1797.010
-1780.051
-1170.536
239.228
189.540
156.444
132.830
121.689
800
900
1000
so. 707
55.256
59.393
157.15
167.94
178.11
106.44
112.68
118.72
89.16
94.13
99.10
-1894.012
-1891.638
-1889.048
-1763.732
-1747.588
-1731.707
115.160
101.428
90.455
1100
63.229
187.79
124.56
104.07
llELTIIIG POUlT
BOILING POIIIT
ENTHALPY OF !ELTIJG
kJ
EITHALPY OF VAPOBIZATIOI
kJ
kJ
IIOLAB VOLUIIE
-------------------------------------------------------------------------------760
48.553
152.83
104.28
87.18
-1894.962
-1770.536
121.689
-------------------------------81.487
-1889.283
-1716.020
2.4600 J/bar
24.600 c 3
TRAISITIOIS II BXFEBEICI STATE ELEIEITS

PBASEODJ!IUB ALPHA-BETA 1068, !. P. 1204 K.
c;
c;
51.577 + 4.7918x1o-z T
( EQUATIOI V lLID FBO!
298 -
49.403 + 4.9701x1o-z T
760- 1100 K)
BEFEBEIICE
200
281
76 0 K)
281
COIIPILED
5-18-76
212
THEBBODYIABIC PBOPIBTIES OP BIIEilLS
SULFUR DIOXIDE
S0 2 :
FOUULA lEIGHT
"' 059
-------------------------------------------------------------------------------FOBBA'!IOI FROB THE ELBBEITS

TEBP.
so
(H;-u~ 98 )/T
JjaolK
J/IIOlK
-( G;-u; 98 }/T
J/aolK
cop
GIBBS
FREE EIEBGY
EITHlLPY
Jjaoll!l:
Log Kf
kJ/IIO.l
ltJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
52.589
248.22
248.22
39.87
-296.810
-300.110
UICERT AI NTY
0.06
0.06
400
500
6(10
700
10.650
17.562
22.613
26.519
260.48
270.56
279.28
286.98
249.83
253.00
256.67
260.46
43.66
46.65
48.99
50.84
800
90(1
1000
29.654
32.233
34.412
293.86
3 00. 10
305.78
264.21
267.87
271.31
52.30
53.48
54.44
1100
1200
1300
1400
1500
1600
1700
1800
36.268
37.875
39.278
40.514
41.610
42.587
43.464
44.253
J 11.01
315.84
320.33
324.52
328.45
332.15
335.63
338.93
274.74
271.96
281.05
284.01
286.84
289.56
292.11
294.68
55.21
55.85
56.36
56.78
57.12
57.38
57.59
57.74
KELTING POUT
ENTHALPY OF BELTING
197. 64 K
0.251
0.200
--------------------------------300.831
39.285
-300.222
-302.690
-304.665
-306.256
-300.649
-300.095
-299.190
7.401 kJ
31.409
26.126
22.326
--------------------------------362.267
-303.629
19.825
-362.212
-362. 111
-296.262
-288.927
17.195
15.092
-361.988
-361.840
-361.678
-361.510
-361.340
-361.166
-360.996
-360.834
-281.628
-274.318
-267.027
-259.754
-252.497
-245.254
-238.012
-230.785
13.373
11.941
10.729
9.692
8.793
8.007
7.313
6.697
BOILING POINT
263.08 K
10.548 kJ
0.044
BOLAR VOLUIIE
24.937 ltJ
2478.9200 Jjbar
24789.200 c11 3

SULFUR ORTHO-ftONO 368.54, ft. P. 8010 388.36,
B. P. 716.9 K.
86.219 4.3073x10-J T
REFERENCE
247
35
8.8646x102 T-05
298 - 1800 K)
5.5769x105 T-2
35
COBPILED
5-24-76
PIOPBITI!S lT BIGB TB8PBRlTURBS
SO LPUR TRIOIIDB
213
POR!OLl IIEIGHT
80.058
================================================================================
S0 3
-------------------------------------------------------------------------------POR!lTIOI PRO !I THE ELB!BITS

TE!P.
<a;-a~ 98 )/T
J/aolK
so
T
J/aolK
-( G;-8~98 )/T
J/8olK
cop
EITBll.PI
J/aolK
GIBBS
FREE EIERGY
Log Kf
kJ/801
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
256.76
50.66
-371.046
-395.722
65.006
256.76
UICERTliiiTY
0.84
0.84
0.795
0.711
400
500
600
700
13.875
23.240
30.245
35.746
272.72
286.24
298.13
308.72
258.84
263.00
267.88
272.97
57.94
63.21
67.16
70.19
800
900
1000
40.205
43.911
47.034
318.26
326.91
334.83
278.05
283.00
287.80
72.55
74.42
75.90
1100
1200
1300
1400
1500
16(10
1100
1800
49.715
52.036
54.065
55.850
57.435
58.845
60.106
61.238
342.13
348.88
355.15
361.01
366.50
371.67
376.51
381.13
292.42
296.84
301.09
305.16
309.06
312.82
316.42
319.89
17.08
78.03
78.78
79.36
79.82
80.16
80.40
80.56
0.139
--------------------------------362.087
47.284
-399.356
-401.807
-403.624
-404.962
-352.431
-342.423
-332.097
16.818
29.811
24.781
--------------------------------327.167
-460.657
.21.362
-460.233
-459.748
-310.440
-293.824
18.018
15.348
-459.209
-458.634
-458.035
-457.431
-456.818
-456.208
-455.608
-455.026
-277.274
-260.755
-244.279
-227.870
-211.490
-195.168
-118.867
-162.600
13.167
11.350
9.815
8.502
7.365
6.372
5.496
4.719
!ELTIIIG POIIT
BOlLI IG POI IT
EITBlLPY OP !ELTIIG
kJ
EITHlLPY OF YlPORIZlTIOI
kJ
kJ
!OLlR YOLU!E
2478.9200 J/bar
24789.2(10 cal
TRliSITIOIS II REPEREICE STlTE ELE!EITS

SULFUR ORTHQ-!010 368.$4, ll. P. !1010 388.36 9
B. P. 716.9 K.
BElT ClPlCITY EQOlTIOR
1.2760x10Z- 7.8140x10-3 T + 6.1238x105 TZ

(EQUlTIOI YlLID PRO! 298 - 1800 K)
RBPERERCI
247
247
247
CO!IPILED
5-24-76
214
THBI!ODIIA!IC PROPERTIES OP !IIBRALS
SCAIDIU! SESQUIOXIDE
Sc 2 o.:
FOR!ULA WEIGHT
137.910
-------------------------------------------------------------------------------FOBftlTIOI FRO! THE BLE!EIITS

TE!P.
so
-(G;-H~ 98 )/T
cop
JjaolK
JjaolK
JjaolK
0.42
O.ll2
(H;-u~ 98 )/T
J;aolK
BITHALPY
GIBBS
FREE EIIEHGY
Log Kf
ltJjaol
kJjaol
-------------------------------------------------------------------------------298.15
o.ooo
-1819.371
318.748
76.99
76.99
96.98
-1908.820
UIIICEBTAIIITY
2.510
2.520
0.441
400
500
600
700
800
900
1000
25.400
42.016
54.087
63.336
70.682
76.678
81.661
106.24
130.41
151.26
169.57
185.87
200.55
213.88
80.84
88.39
97.17
106.23
115.19
123.87
132.22
104.70
111.77
11&.85
120.63
123.48
125.66
127.34
-1908.470
-1907.5.32
-1906.270
-1904.845
-1903.370
-1901.927
-1900.590
-1788.852
-1759.042
-1729.459
-1700.103
-1670.950
-1641.972
-1613.160
233. &01
183.767
150.563
126.864
109.102
95.298
84.264
1100
1200
1300
1400
1500
1600
85.874
89.478
92.593
95.307
97.687
99.786
226.08
237.31
247.71
257.39
266.43
274.90
141.1.21
147.83
155.12
162.08
168. 7ll
175. 11
128.62
129.60
130.32
130.83
131.17
131.36
-1899.407
-1898.429
-1897.694
-1897.241
-1897.102
-1897.305
-1584.500
-1555.896
-1527.391
-1498.927
-1470.486
-1442.048
75.242
67.727
b 1. 372
55.926
51.207
47.078
1700
1800
101.646
103.299
282.87
290.38
181.22
187.08
131.43
131.39
-1907.787
-1384.040
40.1611
BOILIIG POIIl'
!ELTING POIIIT
EITHALPY OP !ELTIIG
--------------------------------1413.093
43.419
-1906.511
EIITHALPY Of VAPOBIZATIOII
13.975 kJ
kJ
3.5910 J/bar
35.910 c11 3
!lOLli VOLU!E
TBAIISITIOIIS II REFEBEIICE STATE ELE!EITS

SCANDIU! ALPHA-BETA 1608, ft. P. 1812 K.

1.9455x102
1.2212x1o-z T
1.7527x10 T-os
298- 1800 K)
(EQUATIOI VALID FRO!

REF EBB !ICE
203
281
264
162
CO!PlLED
6- 9-76

SI~ICOB
SiO:
BOIOIIDE
215
FORBULA WEIGHT
44.085
-------------------------------------------------------------------------------FORUTIOB FROB THE ELEBEITS

TBBP.
K
(a;-a; 98 )/T
J/olK
-( G;-a;98 )/T
so
J/olK
J/oll
0.84
0.84
cop
EBTHU.PY
J/olK
GIBBS
!'BEE EIERGI
kJ/aol
Log Kf
kJ/ol
-------------------------------------------------------------------------------298.15
o.ooo
211.57
29.90
-127.305
22.304
211.57
-100.416
UBCERTAIITY
8. 368
8.500
1.489
400
500
600
700
800
900
1000
7.775
12.590
15.975
18.519
20.514
22. 122
23.464
220.54
227.64
233.63
238.84
243.44
247.57
251.31
212.76
215.05
217.65
220.32
222.93
225.45
227.85
31.22
32.40
33.37
34.15
34.78
35.28
35.70
-100.972
-101.605
-102.293
-103.018
-103.776
-104.5&7
-105.374
-136.410
-145.200
-153.848
-162.385
-110.813
-179.150
-187.394
11.813
15.169
13.394
12.117
11.153
10.398
9.788
1100
1200
1300
1400
1500
1600
24.592
25.557
26.392
27.121
27.765
28.336
254.73
257.87
260.79
263.50
266.04
268.42
230.14
232.31
234.40
236.38
238.27
240.08
36.03
3&.10
36.52
36.70
36.84
36.95
-106.210
-107.0&9
-107.951
-108.858
-109.785
-110.734
-195.563
-203.627
-211.653
-219.598
-227.474
-235.286
9.287
8.864
8.504
8.193
7.921
7.681
1700
1800
28.845
29.301
270.66
272.78
241.81
243.48
37.03
37.09
-162.923
-247.306
7.177
IIEl.TI BG POI IT
EBTHALPY OF IIELT.IBG
kJ
--------------------------------242.600
7.454
-162.215
BOIL.ltiG POIBT
EBTHALPY OF VAPORIZATIOB
!lOLli VOLUBE
8.711 kJ
kJ
2478.9200 J/bar
24789.200 cal
TRANSITIOBS IN REFERENCE STATE ELEIIENTS

SILICON
ft.
P. 1&85 K.

2.0840x10-~ T
50.373 -
REFEREICE
247
247
4.0900x102 T-os
298 - 1800 K)
247
CO!!PILED
5-24-76
THER!ODINA!IC PROPBITIBS OP BINBIALS
216
FORBULl IIBIGHT
QUARTZ
Alpha quartz 298.15 to 844 K.
60.085
Beta quartz 844 to 1800 K.
Beta quartz is etastable above 1140 K.
-------------------------------------------------------------------------------POIII.lTIOI PRO! THE ELE!EITS
-(G;-u; 98 )/T
cop
J/olK
J/olK
J/olK
(1.20
0.20
12.575
21.376
28. 152
33.667
38.350
40.059
55.91
68.51
79.81
90.09
99.58
103.76
43.34
47.13
51.66
56.162
61.2J
63.69
900
1000
42.356
44.967
108.35
115.56
1100
1200
1300
1400
1500
1600
47. 194
49.132
50.851
52.393
53.800
55.092
1700
1800
56.291
57.413
TE!IP.
<u;-a~ 98 );T
J;olK
soT
GIBBS
BITHlLPlC
PaEE BIERGI
ltJ/ol
Loq Kf
ltJ/ol
-------------------------------------------------------------------------------150.(119
-910.700
-856.288
298.15
o.ooo
41.46
41.46
44.59
UNCERTlliiTY
400
500
600
700
800
844
1.000
1. 100
0.193
53.44
59.47
64.47
68.99
73.24
75.06
-910.848
-910.540
-909.897
-908.952
-907.711
-907.160
-837.660
-819.395
-801.219
-783.176
-765.287
-757.697
109,;388
85.602
69.753
58.442
49.968
46.894
65.99
70.59
67.96
68.96
-906.260
-905.502
-7167.512
-729.982
43.388
38.131
122.18
128. 31
134.03
139.40
144.47
149.28
74.99
79.18
83.18
87 .o 1
90.67
94.19
69.96
70.97
71.97
12.97
13.91
74.98
-904.732
-903.937
-903.108
-902.241
-901.321
-900.352
-712.474
-695.017
-617.649
-660.349
-643.096
-625.920
33.833
30.253
27.228
24.638
22.395
20.434
153.85
158.22
97.56
100.81
75.98
76.98
-948.460
-588.298
17.072
-------------------------------------------------------------------------------46.894
844
40.623
-757.697
104.31
-906.684
67.39
63.69
--------------------------------949.834
18.693
-608.355
I!ELTIIIG POIIIT
BOILING POINT
ENTHALPY OP ftELTIIIG
kJ
EIITHALPY OP VAPORIZATION
kJ
2.2688 J/bar
22.688 c 3
!lOLli VOLU!E
6.916 kJ
TRANSITIOIIS IN REFERENCE STATE BLE!EIITS

SILICOII.... ft. P. 1685 K.

3.7754x1o-z T
(EQUATION VALID FlO!
1.0018x10 ,-z
298 844 K)
1.0031x1o-z T
(EQUATION VALID PRO!
844 -
44.603 +
c;
58.928 +
R.EFEREIICE
247
35
278
1800 K)
35
284
COIIPILED
7-16-76
PROPERTIES AT HIGH TEKPERATUBES

FORK ULl WEIGHT
CBISTOBALITE
Si0 2
211
Alpha cristobalite 298.15 to 523 K.
60.085
Beta cristobalite 523 to 1800 K.
---- ----------- ----------------------------------------------FRO! THE
---------~-
POBUTION
TEI!P.
-(G;-H~ 98 )/T
cop
J/aolK
J/aolK
J/aolK
o.u
0.13
57.93
70.56
73.77
45.30
49.08
50.84
soT
(H;-H; 98 )/T
J/aolK
ENTHALPY
GIBBS
FREE ENERGY
kJ/aol
------
ELE!EHTS
Loq 't
kJ/aol
-------------------------------------------------------------------------------298.15
-854.512
149.708
o.ooo
43.40
43.40
44.18
-908.346
UIICEBTAINTY
4(10
500
523
12.625
21.482
22.936
50.73
68.59
77.54
2.090
2.110
0.313
-908.474
-908.133
-908.055
-836.094
-818.(113
-813.854
109.183
85.458
81.284
-------------------------------------------------------------------------------523
25.504
76.34
-906.712
-813.854
81.284
50.84
58.33
600
700
800
900
1000
29.955
34.784
38.730
41.989
44.735
84.60
94.42
103.28
111. 30
118.61
54.64
59.64
64.55
69.31
73.88
62.06
65.23
67.34
68.82
69.92
-906.461
-905.816
-905.053
-904.236
-903.380
-800.657
-783.071
-765.589
-748.203
-730.910
69.704
58.434
49.988
43.425
38.179
1100
1200
1300
1400
1500
1600
47.065
49.069
50.812
52.343
53.698
54.907
125.32
131.50
137.24
142.60
147.61
152.32
78.26
82.43
86.43
90.26
93.91
97.41
70.77
71.44
72.00
72.47
72.87
73.22
-902.520
-901.659
-900.804
-899.957
-899.120
-898.293
-713.716
-696.567
-679.518
-662.545
-645.605
-628.725
33.892
30.321
27.303
24.720
22.482
20.526
1700
1800
55.994
56.976
156.77
160.98
100.78
104.00
73.53
73.82
-946.892
-591.698
17.171
KELTING POUlT
BOILING POUT
8.159 kJ
kJ
7. 040 kJ
!OLlli VOLU!IE
1996
EITHlLPY OP KELTIIG
--------------------------------947.986
-611.471
18.788
2.5739 J/bar
25.739 ca 3
TBANSITIONS IN BBFEBEICB STATE ELB!ENTS

SILICON B. P. 1685 K.
HBAT CAPACITY EQUATIONS

+ 2.5480 T + 7.1680x10 r-os
(EQUATION VALID PBOK 298 - 523 K)
-4.1596x10~
c;
1.3004x10-~ T
( EQOlTIOR YlLID FBOII
72.753 +
RBPEIENCB
24 7
172
2117
278
4.1320x10 T-z
5 23 - 1800 I)
COIIPILBD
6- 8-76
218
THEiftODYMAIIIC PROPERTIES OF IIIWERALS
TRIDYftiTE
FORIIULA WEIGHT
Alpha tridyite 298.15 to 390 K.
60.085
Beta tridymite 390 to 1800 K.
-------------------------------------------------------------------------------FOBUTIOIII FRO II THE ELEIIEIIITS

TEIIP.
{ H;- H~ 98 )/T
J/molK
ST
-(G;-u~ 98 )/T
J/molK
J/olK
O.ij2
O.ij2
cop
ENTHALPY
J/aolK
GIBBS
FREE ENERGY
kJ/ol
Log Kf
kJ/ol
-------------------------------------------------------------------------------298.15
ijJ.93
ijij.60
0.000
ij3.9J
-907.ij88
1ij9.585
-853.812
UIIICERTAIIITY
2.385
2.ij27
(J.ij25
390
11.6ij0
57.15
ij5.52
54.15
-907.593
-837.302
112.1ij5
ijOO
500
600
700
800
900
1000
13.275
22.468
29.155
34.253
38.281
"1.556
44.290
59.01
72.21
83.61
93.60
102.48
110.46
117.72
ij5.73
49.74
54.45
59.35
64.20
68.90
73.ij3
56.97
61.17
63.84
65.73
67.18
68.35
69.35
-907.356
-906.782
-906.083
-905.330
-904.554
-903.768
-902.967
-835.ij08
-817.487
-799.685
-782.011
-764.450
-746.979
-729.607
109.09"
85.403
69.619
58.355
ij9.914
43.354
38. 111
1100
1200
1300
1400
1500
1600
46.607
ij8.607
50.355
51.900
53.283
54.527
124.37
130.51
136.22
141.56
146.57
151.29
77.76
81.90
85.87
89.66
93.29
96.76
70.21
70.98
71.67
72.32
72.92
73.49
-902.165
-901.356
-901J.5ij1
-899.719
-898.885
-898.043
-712.316
-695.076
-677. 929
-660.851
-643.810
-626.827
33.825
30.256
27.J.40
24.657
22.420
20.464
1700
1800
55.659
56.694
155.76
160.111
100.10
103.32
74.03
74.54
-946.542
-589.602
17.110
-------------------------------------------------------------------------------390
12.069
112.1ij5
57.57
-907.426
-837.302
56.41
"5.52
--------------------------------947.697
-609.465
18.727
!ELTIIIG POINT
BOlLI WG POI NT
ENTHALPY OF !ELTING
ltJ
ltJ
IIOLAR VOLUIIE
ltJ
2.6530 J/bar
26.530 c 3
TBAIISITIONS IN REFERENCE STATE ELEIIENTS

SILICON II. P. 1685 K.

74.904 +
3.0999xto-~
{EQUATION VALID FRO!!

REFERENCE
172
285
2.3669xtoz
390 - 1800 K)
r-os
148
COIIPILED
6-28-76
PROPERTIES AT HIGH TEftPEBATUBES

COESITE
219
FORMULA WEIGHT
60.085
-------------------------------------------------------------------------------FORftATIOII F.BOft THE ELEftEIITS

TEI!P.
K
so
T
( H;-a; 98 )/T
J/aolK
-( G;-a~ 98 )/T
CD
J/aollt
J/aolK
kJ/aol
J/aolK
ETHALPY
GIBBS
FREE EIERGY
Loq Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
40.38
40.38
149.066
45.40
-905. 584
-850.850
UIICERTAIIITY
0.42
0.42
2.092
2.134
0.374
400
500
600
700
800
900
1000
12.475
21. 102
27.708
32.946
37.190
40.689
43.611
54.72
67.11
78.17
88.09
97.02
105.10
112.47
42.24
46.01
50.46
55.14
59.83
64.41
68.86
52.54
58.45
62.76
65.79
67.89
69.36
70.40
-905.772
-905.561
-905.047
-904.341
-903.523
-902.644
-901.742
-832.108
-au. 716
-795.385
-777.165
-759.051
-7111.031
-723.132
108.663
85.009
69.245
57.993
49.561
43.009
37.773
1100
1200
1300
1400
1500
1600
46.083
48.202
50.041
51.657
53.106
54.419
119.22
125.44
131.21
136.60
141.66
146.44
73.14
77.24
81.17
84.94
88.55
92.02
71.18
71.81
72.40
73.01
73.70
74.52
-900.838
-899.938
-899.045
-898.155
-897.246
-896.313
-705.324
-687.574
-669.920
-652.343
-634.806
-617.337
33.493
29.929
26.918
24.339
22.106
20.154
1700
1800
55.629
56.764
150.99
155.34
95.36
98.58
75.49
76.66
-944.512
-579.166
16.807
-------------------------------18. 421
-945.844
-599.503
IIELTIIIG POIIIT
BOILIIIG PO.IIIT
EIITHALPY OF ftELTIIIG
kJ
EITHALPY OP VAPORIZATIOII
kJ
kJ
IIOLAR VOLUIIE
2.0641 J/bar
.t0.641 ca 3
TRANSITIOIIS Ill REFERENCE STATE ELEIIEIITS

SILICOII II. P. 1685 K.

2.3306x102 -
7.7765x1o-z T
2.6036x10 r-z

REF.BREIICE
285
101
298 -
1800 K)
101
COftPil.BD
7-16-76
THERMODYNAMIC PROPERTIES OF !IIEIALS
220
STISHOVITE
FOB!ULA IIBIGHT
60.085
-------------------------------------------------------------------------------FOBDTIOI FRO! THE ELE!EITS

TEMP.
so
cs;-H; 98 )/T
J/IIOlK
-(G;-a; 98 }/T
cop
J/olK
J/olK
J/olK
EHTH&LPY
GIBBS
FREE EIBBGY
kJ/ol
Log Kf
kJ/ol
-------------------------------------------------------------------------------140.653
298.15
o.ooo
-861.318
-802.827
27.78
27.78
42.97
UNCEBT&I NTY
0.42
0.42
2.092
2.134
0.374
400
500
600
700
800
900
1000
12.425
21.270
27.958
33.170
37.335
40.744
43.574
42.03
54.66
65.84
75.77
84.65
92.65
99.93
29.60
33.39
37.88
42.60
47.32
51.91
56.36
53.47
59.40
63.12
65.58
67.30
68.57
69.56
-861.526
-861.211
-860.631
-859.918
-859.1111
-858. 328
-857.513
-782.786
-763.141
-743.571
-7211.118
-7011.773
-685.510
-666.363
102.222
79.725
64.734
54.035
46.011
39.786
34.8(17
1100
1200
1300
1400
1500
1600
45.976
48.045
49.855
51.464
52.913
54.240
106.60
112.76
118.119
123.85
128.90
133.69
60.62
64.72
68.64
12.39
75.99
79.45
70.110
71. 18
71.95
72.77
73.66
74.66
-856.689
-855.860
-855.021
-854.159
-853.270
-852.333
-647.293
-628.280
-609.360
-590.497
-571.690
-552.957
30.7 38
27.3118
211.484
22.032
19.908
18.052
1700
1800
55.474
56.636
138.25
142.61
82.78
85.97
75.78
77.03
-900.476
-512.216
14.864
MELTIIIG POINT
ENTHALPY OF MELTING
--------------------------------901.842
16.403
-533.8113
BOILING POIIIT
kJ
kJ
kJ
!OUR VOLUME
1.4014 J/bar
14.0111 c 3
TRANSITIONS IN REFERENCE STATE ELE!EITS

SILICON !. P. 1685 K.

1.4740z1oz -2.8339z105
4.027h1o-z T

RE.PEBEICE
285
1.2026z1o-s TZ
r-z
101
298- 1800 K)
101
CO.IIPILED
7-16-76
PROPERTIES AT HIGH TBRPEBATUiES

SILICA GLASS
221
PORRULl IIBIGHT
60.085
Glass 298.15 to 1800 K.
-------------------------------------------------------------------------------FOiliATIOIIl PRO! THE ELE!EHTS

TBRP.
K
so
(H;-a; 98 )/T
J/aolK
-( G;-a; 98 )/T
cop
J/aolK
J/aolK
J/aolK
EMTB&LPI
GIBBS
FREE EIIERGY
Loq Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
47.40
47.40
37.94
-850.559
149.015
-903.200
UICBBTUITI
0.21
0.21
2.092
2.134
0.374
400
500
600
100
800
900
1000
11.875
20.896
27.738
3J.Oil1
37.259
40.689
43.555
61.01
73.69
84.97
94.96
103.88
111.91
119.21
49.13
52.79
57.21
61.92
66.62
71.22
75.66
53.16
59.95
63.64
65.93
67.53
68.77
69.84
-903.628
-903.280
-902.6165
-901.890
-901.084
-900.260
-899.414
-832.480
-814.725
-797.063
-179.523
-762.100
-744.776
-727.544
108.711
85.114
69.391
sa. 169
49.760
43.226
38.003
1100
1200
1300
1400
1500
45.989
48.099
49.958
51.621
53.139
125.91
132. 11
137.90
143.33
148.46
79.92
84.01
87.94
91.71
95.32
70.82
71.79
72.71
73.81
74.90
-898.557
-897.677
-896.768
-895.821
-894.812
-710.402
-693.317
-676.340
-659.431
-642.572
33.734
30.179
27.176
24.604
22.376
IIELTI IG POIIT
BOILIIG POIIT
BITHALPI OF ftELTIIG
kJ
EITHALPI OF YAPOBIZlTIOI
kJ
ROLli YOLURE
kJ
2. 7270 J/bar
27.270 cal
TiliSITIOIS II BEPEBEICE STATE ELEIIEJTS

SILICOI ll. P. 1685 K.
HEAT
C~PlCITY
EQUATION
74.639 -
7.2594z10-~ T
(EQUATIOI llLID FBOB

BElBBEJCE
52
21f0
285
278
5.5704z10- TZ
298 - 1500 K)
11f8
COIIPILED
281f
6- 8-76
THERl!ODIIAl!IC PIOPERTIES OP l!IIEIALS
222
SAl!ARIUl! SESQUIOIIDE (l!OIOCLIIIC)
Sa 2 o~:
FOil!ULA WEIGHT
348.798
Beta crrstals 1195 to 1800 K.
-----------------~--------------------------------------------------------------
so
-(G;-a~ 9 a)/T
cop
J/aolK
J/aolK
J/aolK
4.20
4.20
( H~-H~ 98 )/T
TEIIP.
K
J/aolK
FOUATIOI FIOII THE ELEIIEITS

GIBBS
Log Kf
EITHALPI
FREE BURGI
kJ/aol
kJ/ao1
-------------------------------------------------------------------------------314.774
-1796.690
298.15
o.ooo
151.04
151.04
-1822.970
113.36
UICEITliNTI
2.010
2.020
0.354
400
500
600
700
800
900
1000
]0.500
50.050
63.947
74.423
82.677
89.411
95.051
186.16
214.75
239.07
260.22
278.97
295.84
311.21
155.66
164.70
175.12
185.80
196.29
206.43
216.16
124.86
131.15
135. 51
138.95
141.90
144.58
147.07
-1821.626
-1820.503
-1819.774
-1819.280
-1818.861t
-1818.451
-1818.0Jb
-1704.896
-1675.853
-1647.001
-1618.240
-1589.548
-1560.898
-1532.316
222.638
175.076
143.385
120.755
103.787
90.593
80.040
1100
99.889
325.34
225.45
149.45
-1817.660
-1503.764
71.408
1200
1300
104.&95
1 08.519
333.3&
345.72
228.&7
237.20
154.41
154.41
-1823.015
-1822.342
-1468.397
-1438.868
&3.918
57.815
1400
1500
1600
1700
1800
111.800
114.637
117.123
119.316
121.266
357.16
367.81
377.78
387.14
395.97
245.36
253.17
260.66
267.82
274.70
154.41
1511.41
154.111
154.41
1511.41
-1839.1104
-1839.520
-1839.672
-1839.854
-1377.899
-1347.11111
-1316.387
-1285.598
47.983
43.980
40.11118
37.307
BOILIIG POI 11'
EITHALPI Ol YlPOIIZlTlOI
ltJ
------------------------------1469.873
&4.250
1195
1 OJ. 735
331.96
-1823.947
228.23
151.&4
--------------------------------------------------------------------------------1469.873
64.250
1195
104.487
332.72
-1823.049
228.23
154.41
IIELTJ: IG POIIT
EITHlLPI OP IIELTIIG
H~ 98
H~
21.004 kJ
--------------------------------1408.683
-1839.323
5~.559
11.5040 J/bar
45.040 cal
IIOL11 YOLUIII
TBliSITl:OIS II BEPEIEICE STATE ELEIIEITS

SliiABIUII ALPHA-BETA 1190 a. P. 13115 K.
HilT CAPACITY EQUATJ:OIS

c;
1.28111x10Z +
2.0545x1o-z T
1.8827x10 ,-z
298- 1195 K)
(EQUATIOI VALID FIOII

BEFEIEICI
210
235
235
COl!PILED
5-18-76
223
SAIIABIUB SBSQOIOIIDE (CUBIC)
S 2 0~:
348.798
so
TEI!P.
FOBBULA WEIGHT
( u;-u; 98 )/T
JjmolK
s298
J/olK
-(G;-u~ 98 )/T
J/llOlK
co
p
FOBBlriOII FRO II THE ELEBEIITS

GIBBS
EIITHALPY
PllEE EII!BGY
Loq
J/olK
kJ/ol
kJ/IlOl
-------------------------------------------------------------------------------298.15
0.000
0.00
112.37
UIICEBTAUTY
400
500
600
700
800
900
1000
30.600
50.486
64.643
75.274
83.589
90.300
95.871
35.23
64.21
88.89
110.32
129.25
146.21
1 & 1. 59
126.22
133. 13
137.44
140.53
142.98
14 5. 04
146.87
1100
100.585
175.66
148.54
IIELTIIIG POUlT
BOILIIIG POIIIT
EIITHALPY OF BE1TIIIG
kJ
ENTHALPY OF VAPORIZATIOI
kJ
kJ
IIOLAB YOLUIIE
4.9100 J/bar
49.100 c 3
TRAIISITIOIS Ill BEFEREICE STATE ELEBEITS

SAIIARIUI! ALPHA-BETA 1190, 1!. P. 1345 K.

c;
1.3702x1oz +
1.2365x1o-z T 2.5189x10 T-z

298- 1100 K)

REFBREIICE
193
COB PILED
9-28-76
224
THERKODYJl!~C
PROPERTIES OF !IIERlLS
FOR!ULA iEIGHT
CASSITB&ITE
150.689
crystals 298.15 to elting point 1903 K.
-------------------------------------------------------------------------------FOB!ATION FRO! THE ELEI'IENTS

TEMP.
<a;-a~ 98 )/T
J/molK
-(G;-H~ga)/T
co
J/oll(
J/mol K
J/olK
1.25
1.25
so
T
ENTHALPY
GIBBS
FREE EBERGY
kJ/ol
Log Kf
kJ/ol
-------------------------------------------------------------------------------91.085
298.15
o.ooo
-sao. 740
-519.902
52.30
52.30
52.59
UNCEBTUNTY
.. oo
500
15.050
25.468
69.57
84.54
511.52
59.07
64.03
69.82
600
700
800
900
1000
33.185
39.144
43.912
47.844
51.160
97.62
109.16
119. 48
128.81
137.35
64.43
70.02
75.57
80.97
86.19
73.50
76.18
78.34
80.18
81.83
1100
1200
1300
1400
1500
54.018
56.524
58.753
60.764
62.589
145.22
152.53
159.38
165.81
171.90
91.20
96.01
100.63
105.05
109.31
83.36
84.81
86.19
87.53
88.84
KELTIIG POUT
1903
0.628
0.753
0.132
-sao.s8s
-579.910
-1199.109
-478.820
65.171
50.022
--------------------------------457.383
39.819
-585.837
-584.465
-582.914
-581.225
-579.426
-436.079
-1114.986
-394.088
-373.396
32.5111
27.096
22.812
19.504
-577.519
-575.508
-573.393
-571.170
-568.852
-352.888
-332.544
-312.392
-292.388
-272.557
16.757
14.475
12.552
10.909
9.491
BOILIIIG POIIT
kJ
ENTHALPY OF VAPORIZATIOB
kJ
!OLlR VOLU!.E
kJ
2.1550 J/bar
21.550 c 3
TBABSITIONS IN REFERENCE STATE ELE!EITS

Til ll. P. 505 K.
HEAT CAPACITY EQUlTIOI
72.158 + 1.1726x1o- z T
(BQUlTIOI VALID PRO!
B!l'EB.ENCE
115
120
2.0502x10 T-Z
298 - 1500 K)
262
CO!PILBD
5-24-76
PIOPBI~IBS
l~
HIGH TBIIPBilfUiBS
225
STIOVTIDII OIIDB
sro:
FOIIIULl lEIGHT
103.619
Crystals 298.15 to 1800 1.
JGIIIlTIOI 11011 THB BLBIIBITS

GIBBS
BITHlLPt
Fill IlliG!
Log I t
TEIIP.
K
o.ooo
55.52
0.42
55.52
0.42
lf5.41
-590.490
0.920
-560.353
0.930
98.172
0.163
400
500
600
700
800
12.000
19.518
24.813
28.786
31.905
69.35
80.41
89.75
97.86
105.0if
57.35
60.89
64.94
69.07
73.11l
48.55
50.52
52.00
53.21
54.26
-590.010
-589.509
-589.066
-588.740
-588.581
-su.580
-539.531f
-529.573
-519.692
-509.l41
71.768
56.365
lf6.101f
38.780
33.289
900
1000
3ll.lllllf
36.562
111.48
117.llf
77.04
80.78
55.20
56.07
1100
1200
1300
1400
1500
1600
38.373
39.948
41.339
42.586
43.711
44.740
122.73
127.71
132.35
136.71
140.81
144.70
84.36
87.76
91.01
94.12
97.10
99.96
56.89
57.66
58.41
59.13
59.83
60.52
1700
1800
45.688
46.568
148.39
151.90
102.70
105.33
61.19
61.85
298.15
OICBITll ITt
IIELTIIG POIIT
IITHlLPI OF ftELTIIG
u;98 - H~
2938
--------------------------------499.921
-589.309
29.015
-589.241
-1190.001
--------------------------------597.162
-479.627
22.776
-596.723
-596.228
-595.674
-595.067
-594.402
-468.953
-458.324
-447.750
-437.192
-426.698
-727.763
-393.827
BOLli VOLDIII
8.673 tJ
11.429
EITHlLPI OF YlPOIIZlTIOI
75.300 tJ
20.413
18.416
16.706
15.224
13.930
--------------------------------412.468
12.674
-729.968
BOILIIG POIIT
25.595
kJ
2.0686 J/bar
20.686 ca 3
TBliSITIOIS II BEPIIBICB STlfB ELB!IITS

STIOITIUII &LPHl-Gllllll 828, II. P. Gllllll 1041, B. P. 1652 I.
HilT ClPlCITY EQOlTIOI
c; =
5.4617x1o- T
(IQOlTIOI YlLID FIOII
55.667 +
B!FBUICI
33
155
33
1.5122x10
298 - 1800 I)
,-o
24
COIIPILID
6- 8-76
THEB!ODYBA!IC PROPERTIES OF !IIIBALS
226
DITABTlLU! PBBTOIIDI (BETA)
Ta 2 0 5
POB!ULA WEIGHT
441.893
-------------------------------------------------------------------------------POB!lTIOII PRO! THE ELE!EJTS

TE!P.
so
( u;-a~ 98 )/T
J/olK
J/olK
-(G;-u~ 98 )/T
cop
J/olK
J/olK
EIITHALPI
GIBBS
FREE EBERGY
ltJ/ol
Log Kf
kJ/01
-------------------------------------------------------------------------------298.15
334.798
o.ooo
143.13
-2045.976
-1910.984
143.13
135.03
UNCEBTllliTY
1.26
1.26
4.18lt
4.200
0.736
400
500
600
700
800
900
1000
36.425
59.960
76.878
89.760
99.987
108.378
115.435
185.06
219.41
248.84
274.58
297.48
318.15
337.00
148.63
159.45
171.96
184.82
197.49
209.77
221.57
149.51
158.20
164.48
169.45
173.63
177.29
180.58
-2044.204
-2041.680
-2038.723
-2035.483
-2032.029
-2028. 397
-2024.610
-18&5. 110
-1820.620
-1776.682
-17 JJ. 265
-1690.313
-1647.805
-1605.720
243.559
190.200
154.675
129.338
110.367
95.637
83.875
1100
1200
1300
1400
1500
1600
1700
1800
121.496
126.792
131.483
135.693
119.505
142.992
146.207
149.191
354.36
370.45
385.48
399.59
412.90
425.50
437.48
448.90
232.86
243.66
254.00
263.90
273.39
282.51
291.27
299.71
183.61
186.44
189.12
191.67
194.12
196.49
198.79
201.03
-2020.684
-2016.633
-2012.458
-2008.171
-2003.778
-1999.284
-1994.692
-1990.012
-1564.030
-1522.671
-1481.694
-1441.017
-1400.658
-1360.620
-1320.838
-1.281.334
74.270
66.280
59.535
53.765
48.175
44.420
40.585
37.184
!ELTIIIIG PO.IliT
2058
ENTHALPY OF !ELTING
120.100 ltJ
BO.IL.IIIG POIIIT
kJ
ltOLAB VOLU!E
23.041 kJ
5.3170 J/bar
3
53. 17(1
TBAIISITIONS Ill REFERENCE STATE BLE!ENTS

1.8972x10Z +
1.66J9x1o-z T
298 -
(EQUATIOM VALID FRO!

REPEREMCE
33
189
33
7.7377x10Z
1800 K)
r-os
33
CO!PILED
&- 2-76
PIOP!BTIES lT
TBRBIOft
SESQO~OIIDB
TbzO:
CCJ&tals 298.15 to 1800 I.
B~GH
T&IPEBlTORES
(CUBIC)
227
POR!OLl lEIGHT
365.849
-------------------------------------------------------------------------------POBftlTIOI PBOft THE ELEftEITS

soT
Ca;-a~98 )/T
TB!P.
I
J/aoll
J/aoll
-(G;-a~ 98 )/T
cop
J/aollt
J/aoll
UTBlLPI
GIBBS
FREE EIERGI
Log If
ltJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
156.90
127.27
-1716.553
311.246
-1865.230
156.90
UICBBTlliTI
4.20
4.20
8.370
8.400
1.472
400
500
600
700
800
900
1000
30.725
119.850
63.168
13.013
80.819
87.122
92.1105
192.31
220.118
244.13
2611.55
282.58
298.71
313.52
161.58
170.63
180.96
191.118
201.76
211.65
221.12
124.12
128.21
131.19
133.79
136.27
138.75
1111.25
-1863.256
-1860.889
-1858.521
-1856.269
-18511.173
-1852.237
-1850.472
-1746.5511
-1717.6311
-1689.2011
-1661.172
-1633.4111
-1605.961
-1578.702
228.078
179.4111
147.059
123.959
1116.653
93.208
82.1163
1100
1200
1300
1400
1500
96.961
100.972
104.567
107.836
110.855
327.10
339.73
351.55
362.69
373.25
230.14
238.76
246.98
254.85
262.39
1113.80
1116.39
149.04
151.72
154.45
-18118.857
-18117.389
-1846.0511
-18114.857
-1843.761
-1551.593
-15211.655
-1497.797
-1471.071
-1444.386
73.679
66.367
60.183
511.887
50.298
1600
113.666
383.31
269.64
157.21
1700
1800
116.310
118.816
392.92
"02. 15
276.61
28J.]J
160.01
162.811
-1869.729
-1361.053
39 ... 97
--------------------------------11117 ... 65
46.276
-1851.521
--------------------------------1389.430
.. 2.692
-1871.000
ftBLTUG POIHT
BOILIIG POIIT
IITHALPI OP ftBLTIIG
kJ
BITHALPI OF YlPORIZlTIOI
.ltJ
H~ 98
ltJ
!OUR YOLU!I
H~
4.6,.80 J~ar
46.480 cal
TlliSITIOIS II RBPIIBICB STATE BLB!IITS

TERBIUft lLPHl-BBTA 1560, ft. P. 1630 K.
HilT CAPACITY EQUlTIOI

3.2J26x1o-z T
(EQOlTIOI VALID PRO!
88.639 +
IEPERE!ICE
2110
281
+
7.0601x102 T-os
298 - 1800 K)
235
COftPILED
8-18-76
228
TBIBBODIIlBIC PBOPIRTIIS OP BliBRlLS

FOBBULl IBIGBT
TEBBIUB OXIDE
186.348
crystals 298.15 to 1000 1.
-------------------------------------------------------------------------------FOIBlTIOI PBOB THE ILBBBITS

TIIIP.
soT
( a;- a; 98 )/T
J/olK
-( G;-u; 98 )IT
JtolK
J/oll
4.2(1
4.20
99.12
113.67
126.04
136.92
146.69
155.63
163.90
83.19
87.88
93.23
98.71
104.10
109.n
114.38
cop
BIITHl.LPI
J/olK
GIBBS
PBBB BIIBGI
kJtol
Loq ltf
kJtol
-------------------------------------------------------------------------------298.15
-938.980
164.506
o.ooo
80.75
-953.950
80.75
57.37
URCIBTliiTI
400
500
600
700
800
900
1000
15.925
25.794
32.815
38.210
42.589
46.289
49.518
IIEUIIG POUT
63.92
66.58
69.25
71.91
74.57
77.24
79.90
4.180
4.200
0.736
-953.(161
-951.996
-950.847
-949.636
-948.373
-947.057
-945.684
-886.743
-870.276
-854.034
-838.002
-822.131
-806.4JJ
-790.876
115.797
90.918
74.351
62.533
53.680
46.804
41.311
BOlLI IIG POI IT
IITHALPY OF IIILTIIG
kJ
ENTHALPY OP VAPOBIZATIOI
kJ
8~98 - 8~
kJ
IIOLAB VOLDIII
J/bar
TBAISITIOIS II BEPEBBICE STATB ELEIIIITS

TBR8IUII ALPHA-BETA 1560 B. P. 1630 I.
HEAT CAPACITY BQDATIOI

c;
53.269 + 2.6629z1o-z T
BBFIRBICE
200
281
298- 1000 I)
235
COIIPILBD
8-18-76
PIOPDTIBS lT HIGH TIIPB81TUIBS
229
rOBIULl IIIGHT
TBIIBI Ul OIIDI
Crystals 298.15 to
187.916
900 K.
-------------------------------------------------------------------------------rOIIlTIOI r101 TBI BLBIBITS

TBIP.
ca;-a; 98 )IT
J/aolK
so
J/aoll
-( a;-s;98 )/T
cop
J/aoll
J/aoll
BITBlLPI
GIBBS
raBB IlliG!
Log 'f
ltJ/aol
ltJ/aol
--------------------------------------------------------------------------------942.180
165.067
81.17
-960.230
298.15
o.ooo
81.17
61.96
UICBIITIIITI
400
500
600
700
800
900
15.825
26.090
33.448
39.0116
43.1l97
47.167
11.20
4.20
99.110
1111.36
127.16
138.35
148.32
157.32
83.57
88.27
93.71
99.30
1011.82
110.15
ULTIIG POIIT
BITBlLPI or IBLTIIG
65.11
68.81t
71.51
73.69
75.60
77.35
11.180
4. 200
0.736
-959.530
-958.427
-957.200
-955.941t
-9511.702
-953.1190
-889.131
-871.645
-8511.1t01
-837.371
-820.516
-803.805
116.109
91.060
711.383
62.486
53.574
116.652
BOILIIG POUT
ltJ
BITBlLPY or VlPOIIZlTIOI
ltJ
ltJ
IIOLlll VOLUIII
J/bar
TBIISITIOIS II BIPBBIICI STlTI BLIIIIITS

TIBBIUII lLPBl-BITI 1560, II. P. 1630 1.
HilT ClPICITI IQUlTIOI

c;
65.863 +
1.11175x1o-z T
(IQOlTIOI VlLID rBOII

IIPBIIICI
200
281
1.0273x10 ,-z
298 - 900 K)
235
COIIPILID
8-18-76
230
THEIBODYNASlC
PROPEBTl~S
OP SliEIALS
THORIAIHTE
Th0 2
POISULl WEIGHT
264.037
-------------------------------------------------------------------------------POBBATIOII PROS THE ELESBITS

TEBP.
K
so
-< G;-a~ 98 )/T
cop
J/olK
J/olK
J/olK
<a;-a~98 )IT
J/olK
fiTHALPY
GIBBS
PRE! EBEBGY
ltJ/ol
Log Kf
kJ/ol
-------------------------------------------------------------------------------298.15
204.765
o.ooo
65.23
65.23
-1226.410
-1168.175
61.76
OIICE.IlTliiiTJ
0.21
0.21
3.510
3.510
0.615
400
500
600
700
80!1
900
1000
16.600
27.180
34.655
40.244
44.609
48.133
51.060
84.34
99.84
112.96
124.33
134.37
143.36
151.51
67.74
72.66
78.30
84.09
89.76
95.23
100.45
67.82
70.95
72.99
74.52
75.78
76.88
71.88
-1225.646
-1224.688
-1223.705
-1222.764
-1221.890
-1221.092
-1220.372
-1149.190
-1130.188
-1111. 37 3
-1092.732
-1074.218
-1055.807
-1037.472
150.069
118.070
96.754
81.541
70.140
61.278
54.192
1100
1200
53.541
55.685
163.98
165.88
110.44
110.19
78.82
79.72
-1219.734
-1219.175
-1024.726
-1001.027
48.660
43.574
KELTING POUT
3493
EIITHALPY OF ftELTliG
BOILIIIG POIIIT
kJ
EITHALPY OF YAPO.IliZATIOI
kJ
10.562 kJ
2. 63 73 J/bar
26.373 ca 3
IIOLAR YOLUSE
TRAISITIOIIS II BEFEREICE STATE ELEBEITS

THOBIUS ALPHA-BETA 1636, B. P. BETA 2028 K.

71.379 + 7.5563x10-~ T
(EQDATIOI VALID PROS
BEPEBEIICE
260
240
215
1.0529x1o
298 - 1200 K)
r-z
215
COIIPILED
6-11-76
231
PIOPBBTIBS AT HIGH TBftPBIATUIBS
POIIIULA IIEIGHT
TIT111IUII OIIDB
TiO:
llpha crystals 298.15 to 1265 1.
63.899
Beta crystals 1265 to 1800 1.
-------------------------------------------------------------------------------POBBATIOI PIOft THE BLEftBITS

TBIJP.
(a;-a; 98 )/T
p;
J/aolK
so
-< G;-a~ 98 )/T
cop
J/aoll
.J/aolK
J/aolK
EITHALPI
GIBBS
FlEE BIBIGI
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------89.931
298.15
-513.312
o.ooo
34.77
34.77
39.96
-5112.&60
UHCEBTUITI
2.10
2.10
400
500
600
100
800
900
1000
11.225
18.614
21.828
27.760
30.910
33.578
35.929
47.68
58.112
67.51
75.42
82.119
88.96
94.97
36.45
19.81
43.68
47.66
51.58
55.38
59.04
46.811
49.16
50.62
52.11
53.87
55.95
58.33
1100
38.084
100.65
62.57
60.98
1200
1265
40.110
111.330
106.08
109.34
65.97
68.01
61.86
65.84
1300
1400
1500
1600
1700
1800
41.983
43.664
45.246
46.739
48.162
49. 52&
1 1 1. 20
11&.06
120.71
125.17
129.47
133.62
69.22
72.40
75.4&
78.43
81.31
84.09
64.67
6&.46
68.24
70.03
71. 82
12.550
12.550
2.199
-542.300
-541.704
-541.0811
-540.461
-539.814
-539.103
-538.304
-503.326
-493.654
-484.099
-1174.647
-lf65.290
-456.015
-446.824
65.728
51.572
lf2. 145
35.419
30.380
26.467
23.340
-537.378
-lf37.718
20.786
-539.348
-1122.719
17.455
-538.722
-537.108
-535.425
-533.683
-531.879
-530.011
-419.252
-410.128
-401.115
-392.219
-383.444
-374.743
16.846
15.302
13.968
12.805
11.782
10.875
-------------------------------18.655
-428.553
-5lf0.351
--------------------------------------------------------------------------------422.719
1265
17.455
64.04
41.340
-539.335
109.35
68.01
ft.BLTI IG POIHT
2023
EITHALPY OF ftELTIJG
13.b(J
BOlLI IIG POI NT
41.800 kJ
EITHALPY OF VAPOIIZATIOI
kJ
kJ
1.3000 J/bar
13.0CJO ca 3
!lOLli YOLOftE
TRAHSITIOBS II BEFEIEICE STATE ELEIIEITS

TITANIUft ALPHA-BETA 1155, ft. P.
1943 K.
52.&6] + 5.0219x1o-z
(EQUATIOB VALID FBOII
c;
2.0349x10~
41.441 + 1.78&7xto-z T
(EQUATIOII VALID FROB 1265 -
REFERENCE
176
33
T-05
298- 1265 K}
1800 K)
33
COl!PILED
8-11-76
232
THIBBODYIAIIC PIOPIITIIS OF IIIBIALS

FOBBOLA WEIGHT
RUTILE
79.899
Crystals 298.15 to aeltiag poiat 2103 K.
-------------------------------------------------------------------------------FOBUTIOI FlO! THE BLEftEITS

TIIIP.
so
T
( H;-H; 98 )/T
JtaolK
JtaolK
-( G;-a~ 98 )/T
J/aolK
cop
GIBBS
EIITHALPJ
rBE! BIIIGJ
kJ/ROl
J/aolK
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
155.828
o.ooo
50.29
-944.750
-889.446
50.29
55.10
OICEB'l' liiTJ
0.17
0.11
400
500
600
700
800
900
1000
14.875
24.502
11.380
36.591
40.716
114.100
46.9110
6 7.42
81.46
91.45
103.90
113.19
121.57
129.21
52.55
56.96
62.07
67.31
72.47
77.47
82.27
61.16
64.54
66.89
68.17
70.39
71.85
73.22
1100
119.389
136.25
86.86
711.53
1200
1300
1400
1500
1600
1700
1800
51.537
53.452
55.179
56.759
58.214
59.568
60.837
142.79
1118.91
1511.66
160.10
165.27
170.19
174.90
IIELTIIIG POIIIT
2103
BITHALPY OF IIILTIIG
8~98 - H~
91.25
95.46
99.48
103.14
107.06
110.62
114.06
75.80
17.04
78.26
79.46
80.64
81.82
82.99
1.260
1.030
0.180
-944.442
-943.894
-943.269
-942.623
-941.979
-941.342
-940.730
-870.590
-852.189
-833.907
-815.727
-797.6U
-779.610
-761.700
113.688
89.028
72.598
60.871
52.081
45.249
39.787
-940.132
-743.826
35.321
-------------------------------31.596
-9113.603
-725.851
-942.572
-9111.557
-940.550
-939.556
-938.571
-917.594
-707.753
-689.725
-671.765
-653.892
-636.073
-618.292
28.438
25.734
23.393
21.347
19.544
17.9112
80ILIIG POUT
kJ
ENTHALPY OP VAPOIIZATIOH
kJ
8.669 kJ
1. 8820 J/bar
18.820 ca 3
!lOLli VOLOIE
TRAIISITIOIS II IBFEREIICE STATE ELB!IITS

TITliiUB ALPHA-BETA 1155 1 II. P. 1943 K.

63.079 + 1.1307&10-2 T
(EQUATION VALID PBOII
BEPEREICB
33
176
33
5.6160 T-os
298 - 1800 K)
J)
215
COIIPILED
6-21-76
PROPERTIES AT HIGH TBftPEBlTOBES
233
ANATASE
PORftULA IIEIGHT
79.899
-------------------------------------------------------------------------------FOBftlTIO.N PBOI! THE ELE!IBIITS

TE!IP.
K
J;olK
GIBBS
PBEE EHERGI
sa
-(G;-H~ 98 )/T
cap
J/olK
J/ol K
J/olK
kJ/ol
2.090
2.090
0.366
-938.172
-937.237
-936.216
-935.215
-934.267
-933.382
-932.567
-864.432
-846.107
-827.976
-810.013
-792.195
-774.479
-756.867
112.884
88.393
72.082
60.444
51.725
44.950
39.535
-931.812
-739.345
35.109
( H;-H~ 98 )/T
EHTHALPI
Log Kf
kJ/ol
-------------------------------------------------------------------------------298.15
o.ooo
49.91
49.91
55.27
-938.720
-883.303
154.752
UHCEBTlltfTI
0.29
0.29
400
500
600
700
800
900
1000
15.475
25.756
33.085
38.560
42.819
46.244
49.073
67.70
82.61
95.32
106.32
116.02
124.69
132.54
52.22
56.85
62.24
67.76
73.20
78.45
83.47
64.70
68.60
70.69
72.07
73.15
74.10
75.01
1100
51.471
139.74
88.27
75.90
1200
1300
53.545
55.371
146.38
152.56
92.84
97.19
ftELTI NG POIIIT
76.81
77.74
--------------------------------935.164
-721.720
31.416
-934.047
-103.913
28.286
BOILIHG POIIT
EHTHALPI OP !IELTIHG
kJ
BHTHALPI OF YlPOBIZATIOH
kJ
I'IOLlR YOLUI'IE
kJ
2.0520 J/bar
20.520 c 3
TBANSITIOBS IH REFERENCE STATE ELEI'IB.NTS

TITAIIUft ALPHA-BETA 1155, ft. P. 1943 K.
HEAT CAPACITY EQUATIOB

43.961
1.3738x1o-z T
(EQUATIOB VALID PIOft

IEPBIBIC!
176
]3
6.29l7x10Z
298 - 1300 K)
r-as
33
COftPILID
6-14-76
234
THERMODYNAMIC PROPERTIES OF MIKIRALS
DITITANIUM TRIOXIDE
Ti 2 0:s:
FORMULA WEIGHT
143.798
-------------------------------------------------------------------------------FOBUTIO!f FROM THE ELEI!EIITS

TEMP.
soT
< u;-H~ 98 )/T

J;aolK
-(G;-u~ 98 )/T
J/aolK
J/aolK
0.21
0.21
cop
ElfTHALPY
GIBBS
FREE ENERGY
kJjaol
kJ;aol
Jtaol K
Log Kf
-------------------------------------------------------------------------------298.15
-1433.903
251.215
0.000
71.25
77.25
95.81
-1520.884
UIICEBTAI NTY
8.368
a. no
1.466
400
470
27 .o 17
38.797
108.27
129.60
81.26
87.80
117.53
132.47
-1519.il49
-1519.299
-1404.293
-1384.751
183.383
153.899
500
600
700
800
900
1000
49.622
63.625
74.326
82.749
89.556
95.161
139.36
163.71
185.05
203.97
220.93
236.27
89.74
100.08
110.72
121.22
131.37
141. 11
130.29
136.46
140.32
142.96
144.88
146.35
-1515.819
-1512.777
-1509.576
-1506.369
-1503.229
-1500.216
-1375.804
-1348.080
-1320.877
-1294.141
-1267.789
-1241.796
143.730
117.361
98.566
84.499
73.581
64.865
1100
99.871
250.28
150.41
147.54
-1497.346
-1216.098
57.748
1200
1300
1400
1500
1600
1700
1800
1 OJ. 885
107. ]52
110.379
113.050
115.426
117.556
119.481
263.16
275.08
286.18
296.56
306.30
315.50
3.24.20
159.28
167.73
175.80
183.51
190.87
197.94
204.72
148.52
149.36
150.10
150.76
151.36
151.92
152.44
-1499.276
-1495.989
-1492.881
-1489.958
-1487 .219
-1484.667
-1164.448
-1138.821
-1113.411
-1088 .206
-1063 .214
-1038.321
46.788
42.490
]8.773
35.526
12.669
10.131
BOILING POINT
ElfTHALPY OF VAPORIZATION
kJ
-------------------------------------------------------------------------------470
44.259
153.899
-1384.751
132.05
87.80
-1516.732
127.69
MELTING POINT
.2115
ENTHALPY OF MELTIIfG
104.600 kJ
14.088 kJ
--------------------------------1190.141
51.814
-1502.743
3.1430 J/bar
31.430 ca 3
MOLlB VOLUME
TRANSITIONS IN B&PEBEHCE STATE ELIM!IfTS

TITANIUM ALPHA-BETA 1155, 8. P. 1943 K.

1.4861x10Z +
J.2861x10-3 T .27.026 T-os

470- 1800 K)
(EQUATIOV VALID FROM

REFEREHCE
J3
176
JJ
JJ
COMPILED
8- 2-76
PROPERTIES AT HIGH TEKPERATORES
235
FOR!OLA VEIGHX
TRITITAilU!I PEITOIIDE (ALPHA)
Ti 3 0s:
223.697
-------------------------------------------------------------------------------FOU&TIOI FRO! THE ELB!IBITS

TEBP.
K
so
(H;-a; 98 )/T
JjaolK
J/aolK
-( G;-8; 98 )/T
CDp
J/aolK
J/aolK
IIITBALPY
GIBBS
FREI BURGY
kJjaol
Log 't
ltJ/aol
-------------------------------------------------------------------------------406.003
-2459.150
-2317.411
129.37
129.37
154.81
298.15
0.000
OICBBTAIITY
1.67
1.67
400
450
43.377
59.739
179.23
203.71
135.85
143.97
500
600
700
800
900
1000
97.272
111.947
123.857
133.571
141.589
148.298
248.33
282.08
312.17
339.08
3&3.31
385.29
1100
153.979
1200
1300
1400
1500
1600
1100
1800
158.846
163.058
166.736
1&9.977
172.851
175.416
177.722
182.84
196.52
4.180
4.600
0.806
-2457.213
-2456.285
-2269.219
-221J6.952
296.331
260.821
--------------------------------------------------------------------------------2442.784
-2246.952
260.821
450
87.489
231.45
143.97
168.1J5
-2441.655
-2439.397
-243&.657
-2433.179
-2430.91J7
-2428.265
-2223.690
-2180.290
-2137. 31&
-2094.751
-2052.524
-2010.625
232.308
189.812
159.489
136.774
119.126
105.025
-2425.803
-1968.984
93.500
151.06
170.13
188.31
205.51
221.72
236.99
178.31
191.15
198.90
203.92
207.37
209.83
405.38
251.40
211.66
423.86
440.96
456.86
471.71
1185.65
498.77
511.17
265.01
277.90
290.12
301.73
312.80
323.35
333.45
213.01J
214.12
214.98
215.&7
216.24
216.70
217.10
BOILliG POIIT
!IBLTI IG POUT
2050
BITHALPI OF !IBLTIIG
172.000 kJ
-------------------------------83.884
-2435.754
-1927.092
-2U2.433
-2429.412
-242&.695
-21124.293
-21J22.210
-2420.450
-1884.847
-1842.840
-1801.015
-1759.405
-1711.943
-1676.528
EITHALPI OF VAPOBIZATIOI
ltJ
5.2690 Jjbar
52.690 ca 3
IIOLAR VOLOIIE
kJ
75.734
68.758
62.717
57.439
52.786
48.652
TRAISITIOIS II REPEBBICB STATE ELEIIBNTS

TITAIIO!I ALPHA-BETA 1155, !1. P. 1943 K.
HEAT CAPACITY EQOATIOI
c;
2.2034z1oz -
BEPBIBICE
1.0507z107 r-z
450 -
( EQOAT.IOI VlLID FlO!

176
33
1800 K)
33
COIIPILBD
8-17-76
236
TBEBftODYHlftlC PROPERTIES OP ftiNEBlLS
TETBlTITlHIUft HEPTOIIDE
Ti.o 7 :
FOBftULl lEIGHT
303.596
-------------------------------------------------------------------------------1'0BftlTIOH 1'BOft THE ELBftEHTS

TEftP.
so
-(G;-a~ 98 )/T
cop
J/olK
J/mol K
J/aolK
(H;-a~ 98 )/T
J/IIOlK
EHTHlLPY
GIBBS
FREE EHBilGY
Log Kf
lr.J;aol
kJ/1101
-------------------------------------------------------------------------------298.15
562.936
o.ooo
198.74
198.74
-3404.520
-3213.166
208.49
UNCEBTliBTY
12.00
12.00
400
500
600
7(J0
800
9(J0
1000
57.650
96. 214
124.34:;
145.864
162.929
176.844
188.435
265.05
320.86
369. 14
411.52
449.21
483.14
513.99
207.40
224.65
244.80
265.66
286.28
306.30
325.56
240.78
258.73
270.54
279.(12
285.48
290.61
294.82
1100
198.272
542.26
343.99
298.36
568.35
592.58
615.20
636.40
656.37
675.22
693.10
361.61
378.46
394.57
409.99
424.78
438.95
452.58
301.38
304.01
306.33
308.39
310.24
311.91
313.44
BOILIIG POUT
1200
206.742
214.125
220.629
226.413
231.594
236.271
240.516
1JOO
1400
1500
1600
1700
1800
ftELTIBG POUlT
1950
ENTHALPY OF ftELTIBG
226.000 kJ
kJ
6.280
6.280
1.100
-3402.516
-3398.949
-3394.675
-3390.109
-3385.465
-3380.869
-3376.418
-3148.030
-3084.814
-3022.372
-2960.687
-2899.653
-2839. 168
-2779.238
411.092
322.270
263.122
220.930
i 89 .129
164.782
145.173
-3372.161
-2719.729
129.1 so
-3378.725
-3373.389
-3368.349
-3363.622
-3359.215
-3355.142
-2599.843
-2540.137
-2480.769
-2421.790
-2363.092
-2304.572
104.463
94.774
86.388
79.064
72.609
66.877
-------------------------------115.786
-3384.347
-2659.973
EJTHlLPY OP YlPORIZlTIOH
kJ
I!OLlR YOLUftE
J/bar
TRlBSITIOIS II REFERENCE STATE ELEftEITS

TITlHIUft lLPHl-BETl 1155, ft. P. 1943 K.
BElT CAPACITY EQOlTIOB

3.6004z1oz +
5.2682x1o- T 1.97J9x10.J
298- 1800 K)
r-.a
(IQOlTIOB YlLID PRO!

REFEB.BJCB
33
33
33
COI!PILED
5-19-76
PROPERTIES lT HIGH TEBPERlTURIS

THULIUS SBSQUIOXIDE
Ta 2 0~:
237
POIBULA WEIGHT
Alpha crystals 298.15 to 1680 x.
385.867
Beta crystals 1680 to 1800 x.
-------------------------------------------------------------M-----------------I'ORUTIOII I'IOB THE BLBBEHTS

TEIIP.
X
soT
-(G;-H~ 98 )/T
cop
J/aolX
J/aolX
J/aolX
0.85
o.85
( a;-H~ 98 )/T
J/aolX
EHTHlLPY
GIBBS
PREB EVBBGY
Log xf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
-1794.446
3114.381
0.000
139.75
139.75
-1888.660
112.88
UIICERTliUY
0.850
0.850
0.1149
400
500
600
700
800
900
1000
30.125
148.830
61.803
71.336
78.642
84.433
89.135
1714.29
201.87
2214.95
2144.76
262.09
277.49
291.34
11414.16
153.014
163.15
17 3. 42
183.45
193.06
202.20
121.143
125.143
127.73
129.23
130.30
131.13
131.80
-1886.5146
-18814.107
-1881.666
-1879.363
-1877.238
-1875.307
-1873.558
-1762.492
-1731.767
-1701.525
-1671.687
-16142.162
-1612.885
-1583.828
230.159
180.917
1148.132
124.743
107.223
93.610
82.731
1100
1200
1300
1400
1500
1600
93.039
96.337
99.165
101.621
1 OJ. 7714
105.682
303.93
315.47
326.12
336.02
345.26
353.93
210.89
219.13
226.95
2314.140
241.49
248.25
132.37
132.87
133.32
133.73
134.12
134.49
-1871.993
-1870.600
-1869.366
-1868.287
-1867.351
-1866.553
-1554.940
-1526.170
-1497.514
-11468.979
-1440.481
-1412.049
73.838
66.433
60.171
514.809
50.162
46.099
kJ
EIITHlLPY OP VlPORIZlTIOII
IIBLTIJG POIIIT
BOILIIIG POIIIT
EIITHlLPY OP BBLTIIIG
H~ 98 - H~
20.878 kJ
kJ
4.3420 J/bar
43.420 ca 3
BOLAR VOLUBE
TBliiSITIOHS Ill RIPEBEIICI STATE ELBBBIITS

THULIUS II. P. 1818 X.
BElT ClPlCIT! BQUlTIOI
c;
-=
1.J06JJ:10Z + 2.8191J:1o-:s T
1.6528:~10
(EQUlTIOI VALID FROB 298 - 1600 X)
BBPIBBICB
207
235
r-z
235
COIPIJ.BD
5-19-76
238
THEB!ODYHA!IC PROPEBTIES OF !INEBALS
U:UUUTE
U0 2
FOB!ULA WEIGHT
270.028
-------------------------------------------------------------------------------FORUTION FRO II THE ELEIIENTS

TERP.
K
so
-( G~-H~ 98 )/T
cop
J/aolK
J/aolK
J/aolK
0.24
( H~-u~ 98 )/T
J/aolK
ENTHALPY
GIBBS
FREE ENEBGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------180.763
-1031.770
-1084.910
298.15
o.ooo
77.03
77.03
63.60
0.24
1.000
1.000
o. 175
17.375
28.644
36.672
42.707
47.449
51.311
97.01
113.46
127.45
139.62
150.38
160.06
79.63
84.82
90.78
96.91
102.93
108.75
71.65
75.51
77.96
79.83
81.42
82.90
-1083.903
-1082.676
-1081.493
-1080.491
-1079.744
-1079.312
-1013.679
-996.276
-979.103
-962.128
-945.264
-928.481
132.313
104.081
85.239
71.795
61.720
53.888
1000
54.536
168.87
114.33
84.31
1100
1200
1300
1400
57.306
59.729
61.885
63.836
176.97
184.48
191.51
198.11
119.66
124.75
129.62
134.27
85.70
87.07
88.45
89.84
1500
1600
1700
1800
65.613
67.258
68.792
70.236
204.36
210.29
215.95
221.36
138.75
143.03
147.16
151.12
91.23
92.64
94.05
95.48
UNCERTAINTY
400
500
600
700
800
900
!!ELTING POINT
3151
ENTHALPY OF !ELTING
--------------------------------911.574
47.616
-1081.664
--------------------------------894.J64
42.470
-1085.478
-1084.218
-1082.857
-1081.388
-877.038
-859.829
-842.730
38.177
34.549
31.443
-1088.524
-1087.680
-1086.716
-807.548
-790.027
-77 2. 526
26.364
24.275
22.418
-------------------------------28.734
-825.129
-1089.249
BOILHIG POINT
kJ
kJ
IIOLAR VOLOIIE
kJ
2.4618 J/bar
24.618 ca 3
TRANSITIONS IN REFEBENCE STATE ELEIIEITS

ORANIOII lLPHA-BETA 941, BETA-GAIII!l 1048, !. P. 1405 K.
HElT CAPACITY EQUATION

1.6057z1o-z T
(EQOlTION VlLID FROII
58.454 +
REFIRE ICE
77
60
110
215
3.6889x10Z
298 - 1800 K)
r-os
41
215
COMPILED
7-21-76
PBOPERTIES AT HIGH TEKPERATURES

URANIUK TRIOXIDE (GAftftA}
239
FORKULA WEIGHT
Crystals 298.15 to
286.027
900 K.
-------------------------------------------------------------------------------FORftATION FROK THE BLEftEJTS

TEftP.
ST
-< G;-H~ 98 };r
cop
J/aolK
JjaolK
JjaolK
0.25
0.25
124.00
144.21
161. 36
176.25
189.35
201.01
101.98
108.47
115.89
123.48
130.90
138.07
( a;-H~ 98 );T
J/aolK
EJTHALPY
GIBBS
FREE EJERGY
Log Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
-1146.461
o.ooo
98.62
98.62
84.72
-1223.800
200.856
UNCERTll IITY
400
500
600
700
800
900
22.025
35.736
45.467
52.773
58.447
62.944
88.55
92.53
95.54
97.53
98.68
99.14
0.800
1.000
0.175
-1222.445
-1221.064
-1219.732
-1218.588
-1217.754
-1217.351
-1120.243
-1094.864
-10MI. 747
-1044 .. 848
-1020.078
-995.402
146.289
114.380
93. 130
77.968
66.605
57.772
!ELTING POUlT
BOILING POINT
ENTHALPY OF MELTING
kJ
kJ
KOLAR VOLUftE
kJ
3.5560 Jjbar
35.560 ca 3
TRANSITIONS IN REFERENCE STATE ELEKENTS

URANIUK ALPHA-BETA 941, BETA-GAKKA 1048, ft. P. 1405 K.

2.1500x1oz-
J.8496x1o-z T
298-

REFERENCE
170
112
215
2.5272x1(J:J T-os
90(1 K)
215
COMPILED
6- 8-76
240
THERftODYIASIC PROPERTIES OP ftiiERALS
VAHADIU! ftOHOXIDE
YO:
POBftULA WEIGHT
66.941
Ccystals 298.15 to 1800 K.
-------------------------------------------------------------------------------FOR!ATION l"ROft THE ELEftEHTS

TEftP.
so
-(G;-a~ 98 )/T
cop
J/olK
J/molK
J/aol K
0.85
0.85
ca;-a; 98 )/T
J;molK
ENTHALPY
GIBBS
FREE ENERGY
Log 't
kJ/mol
kJ/1101
-------------------------------------------------------------------------------298.15
0.000
39.01
-404.219
70.818
45.50
-431.790
39.01
UIICERTAIHTY
6 .280
6.280
1.100
400
500
600
700
800
900
1000
12.075
19.746
25.257
29.4 79
32.867
35.689
38.097
5 2.91
64.16
73.78
82.23
89.78
96.64
102.914
40.84
44.41
48.52
52.75
56.91
60.95
64.84
49.10
51.71
53.85
55.73
57.44
59.03
60.55
-431.078
-43(1.213
-429.225
-428.146
-426.998
-1425.795
-424.555
-394.900
-385.958
-377.196
-368.611
-360.178
-351.896
-3143.755
51.569
40.321
32.838
27.506
23.517
20.424
17.956
1100
1200
1300
1400
1500
1600
1700
1800
40.205
42.081
10.775
45.321
46.755
48.089
49.343
50.528
108.78
1114.23
119.36
124 .21
128.82
133.22
137.42
141.46
68.58
72.15
75.59
78.89
82.07
85.13
88.08
90.93
62.00
63.41
64.79
66.13
67.45
68.76
70.04
71. 31
-423.284
-421.995
-420.699
-419.410
-H8.126
-416.865
-415.635
-414.445
-335.735
-127.825
-320.027
-312.338
-3014.741
-297.225
-289.776
-282.415
15.943
14.270
12.859
11.654
10.612
9.703
8.904
8.196
fiELTIMG POIIIT
BOILING POINT
2063
ENTHALPY OP !ELTING
54.400 kJ
fiOLAB VOLUfiE
kJ
kJ
1.0260 J/bac
10.260 ca 3
TRANSITIONS IN REFEBEHCE STATE ELEftENTS

VlNlDIUft II. P. 2175 K.

55.912 +
1.1245x10-2 T

REFERENCE
115
191
33
2.0393x102 T-os
298 - 1800 K)
33
COSPILED
6- 2-76
PBOPIITIBS lT HIGH T!ftPBilTUIBS

UIBLiliiTI
241
FOiftULl VIIGHT
149.881
-------------------------------------------------------------------------------lORI!IlTIOI FROI!I THE ELE!EITS

TE!P.
(a;-a; 98 )/T
JtaolK
so
-(G;-a~ 98 )/T
cop
J/aolK
J/aolK
J/aolK
1.25
1.25
EITHALPY
GIBBS
FREE BIBBGY
Log Kf
ltJ/aol
ltJ/aol
--------------------------
----------------------------------------------------298.15
-1139.052
o.ooo
98.07
98.07
104.96
-1218.800
199.558
OIC!BTli HTY
6.280
6.500
1.139
400
500
600
700
800
900
1000
28.625
47.090
60.143
69.920
17.596
83.867
89.144
131.01
157.98
180.83
200.65
218.18
233.96
248.36
102.38
110.89
120.69
130.73
140.58
150.09
159.22
117.82
123.52
127.11
129o99
132.66
135.32
138.04
-1217.098
-1214.891
-1212.518
-1210.092
-1207.647
-1205.189
-1202.727
-1112.044
-1086.036
-1060.481
-1035.337
-1010.531
-986.030
-961.817
145.219
113.458
92.323
17.258
65.981
57.228
50.240
1100
1200
1300
1400
1500
1600
1700
1800
93.715
97.763
101.415
104.757
1G7.867
110.786
113.552
116.194
261.65
274.03
285.65
296.63
307.08
317.05
326.62
335.82
167.93
176.27
184.211
191.87
199.2 1
206.26
213.07
219.63
140.84
143.74
146. 7J
149.80
152.95
156.17
159.46
162.80
-1200.251
-1197.763
-1195.262
-1192. 759
-1190.239
-1187.722
-1185.211
-1182.714
-937.846
-914.101
-890.555
-867.211
-844.069
-821.058
-798.232
-775.536
114.535
39.790
35.783
32.356
29.393
26.805
211.527
22.506
IIBLTIHG POllfT
BOlLI IG POI IT
BRTBlLPI OF I!IBLTIIG
ltJ
EITHlLPY OF VlPOBIZlTION
ltJ
ltJ
!OLlR VOLOII!
2.9850 J/bar
29.850 cal
TBliSITIOMS II BBFEBEICB STlTI BLBIIBITS

VlNADIO! ft. P. 2175 K.
HilT ClPlCITI BQOlTIOI

57,989 +
11.1200z1o-z T
( BQUlTIOI
IBFBBBICB
38
V lLID
33
FIOI!I
1.3510z10
298 - 1800 K)
r-os
33
COI!IPILBD
6-21-76
242
THEB!ODYIA!IC PBOPIBTIES OF !IIEIALS
DIVABADIU! TETBOIIDE
FOB!DLA WEIGHT
Crystals 298.15 to 1600
165.880
~.
-------------------------------------------------------------------------------FOB!ATIOI FRO! THE ELE!EIITS

TE!P.
a;-a; 98 )/T
so
<
J/olK
-( G;-8~98 )/'l
J/olK
J/olK
2.09
2.09
cop
EIITHALPY
GIBBS
FREE EIIIEBGY
.kJ/ol
J/olK
Log 't
kJ/801
--------------------------------------------------------------------------------1318.457
298.15
o.ooo
103.52
103.52
-1427.162
230.989
115.40
OIICIBTUNTY
6.276
6.500
1.139
400
500
600
700
800
90(1
1000
54.700
71.516
83.905
93.471
101.120
107.400
112.670
1160.96
111.89
198.47
221.72
242.37
260.93
271.80
86.26
100.37
114.57
128.25
141.25
153.53
165.13
134.214
142.77
148.61
152.93
156. 27
158.95
161.16
-1416.54l
-14116.084
-1411.2169
-1408.222
-1405.110
-11601.990
-1398.910
-1272.694
-1217.009
-1201.855
-1167.198
-1132.974
-1099.131
-1065.650
166.198
129.230
104.631
87.098
73.976
63.792
55.664
1100
1200
1300
1400
1500
1600
117.165
121.054
124.458
127.471
130.153
132.564
293.25
307.50
320.73
333.08
344.65
355.54
176.08
186.45
196.27
205.61
214.50
222.98
163.02
164.b1
165.99
167.19
168.2 5
169.19
-1395.918
-1393.051
-1390.336
-1387.800
-1385.471
-1383.382
-1032.467
-999.547
-966.861
-934.396
-902.102
-869.9162
169.028
143.509
38.849
34.863
31.414
28.401
IIELTING POUlT
1818
BOILING POIBT
ENTHALPY OP IIELTIIG
112.068 kJ
EIITHALPY OF VAPORIZATIOI
kJ
IIOLlB VOLUIIE
Jjbar
18.100 kJ
TRAISITIONS IN BEFEBEICE STATE ELE!ENTS

VUADIUII. ft. 1?. 2175 K.
2.0206x10Z 1.1l4Jx10-3 T
1.2270x103 T-us
(EQUATION VALID PRO! 298 - 1600 K)
REFERENCE
38
33
33
CO!PILED
5-19-76
PiOPiiTIIS AT HIGH TIBPiiATUiiS

DIVAIADIOB PIITOIIDE
V2 0 5 :
243
POiBOLA WEIGHT
Crystals 298.15 to aelting point 943 1.
181.880
Liquid 943 to 1800 1.
-------------------------------------------------------------------------------l'OBII&TIOI l'BOB THE ELIBEITS

TEBP.
J/aolK
so
T
-(G;-a~ 98 )/T
cop
J/aolK
J/aolK
J/aol K
2.09
2.09
(H;-a; 98 )/T
GIBBS
EUH&LPI
FlEE EBBRGI
ltJ/aol
Log Kf
ltJ/aol
-------------------------------------------------------------------------------248.&80
298.15
130.54
-1550.590
-1419.435
0.000
130.60
130.54
OICEBT&IITY
&.276
6.300
1.104
400
500
600
700
800
900
943
38.650
62. 27&
78.852
91.401
101.431
109.178
113.445
175. 11
210.07
239.55
265.23
288.15
308.94
317.32
136.46
147.79
160.70
173.83
186.72
199.16
203.87
154.30
159.26
164. ,l1
169.16
174.12
179.07
181.20
-1547.902
-1545.176
-1542.335
-1539.352
-1536.208
-1532.897
-1530.841
-1374.940
-1332.01&
-1289.648
-1247.767
-1206.125
-11&5.275
-1147.106
179.550
139.155
112.274
93.110
78.765
67.631
63.541
1000
182.305
396.04
213.74
189.05
-1464.050
-1127.240
58.881
1100
1200
1300
1400
1500
182.966
183.590
184.170
184.707
185.197
414.11
430.68
445.98
460.18
473.43
231.14
247.09
261.81
275.47
288.23
190.06
190.82
191.41
191.89
192.27
-1460.065
-1456.311
-1452.807
-1449.577
-1446.6163
-1093.754
-1060.&11
-1027.785
-995.221
-962.878
51.938
46.168
41.297
37.132
33.531
-------------------------------------------------------------------------------943
63.541
181.865
385.74
-1466.321
-1147.106
203.87
188.33
BELr:I IG POUT
943
BOILIIIG POIIT
EITHALPY OP BELTING
64.520 ltJ
EITHALPY OP YAPOBIZATIOI
21.506 ltJ
BOLAR VOLUBE
ltJ
5.3940 J/bar
53.940 ca 3
TBAISITIOIS II BIPEBEICE STATE ELE!IITS

YAIADIUL B. P. 2175 K.
HEAT CAPACITY EQUATIOIS
c:
c:
1.3449z10Z
+ 4.9532z1o-z r
298 -
(EQUATIOI VALID PBOB

1.9484x1oz -
BEPEBENCE
9163 K)
5.7891z10 r-z
943- 1500 K)
(EQUATIOI VALID PBO!

837
710
710
COilPILED
6- 7-76
244
THBRIODtlliiC PIOPEITIES OP IIIEilLS
POBIOLl IBIGHT
TUIGST!I DIOXIDE
10 2 :
215.849
-------------------------------------------------------------------------------POBilTIOI PIOI THE BLBIEITS

TBIIP.
saT
( H;-H~ 98 )/T
J/aolK
-(G;-a~ 98 )/T
cap
J/aolK
J/aolK
J/aolK
EITHlLPI
kJ/aol
GIBBS
PBBE EIBIGI
Log l(f
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
-533.858
93.530
50.53
50.53
55.74
-589.690
UICBBTliiiT!
0.29
0.29
0.880
0.960
0.168
400
500
600
700
800
900
1000
15.150
25.282
32.762
38.506
43.045
46.722
49.761
67.96
82.62
95.41
106.65
116.64
125.60
133.73
52.81
57.311
62.65
68.14
73.60
78.88
83.97
63.02
68.29
71.77
74.02
75.53
76.64
77.63
-589.172
-588.191
-586.919
-585.495
-583.996
-582.464
-580.924
-514.848
-496.371
-478.127
-460.111
-442.300
-424.667
-407.221l
67.233
51.856
41.625
34.334
28.879
24.647
21.271
1100
1200
1300
1400
1500
1600
1700
1800
52.342
54.587
56.593
58.436
60.181
61.870
63.547
65.245
141.18
148.07
154.53
160.64
166.47
172.10
177.58
182.96
88.84
93.48
97.94
102.20
106.29
110.23
114.03
117.72
78.68
79.92
81.48
83.42
85.81
88.70
92.14
96.16
-579.361
-577.761
-576.091
-574.316
-572.380
-570.245
-567.850
-565.138
-389.930
-.372.765
-355.754
-338.892
-322.120
-305.525
-289.050
-272.728
18.516
16.226
14.294
12.644
11.217
9.974
8.881
7.914
IIELTIIIG POUT
kJ
BOILIIIG POIIT
1997
1.9920 J/bar
!IOLAB VOLOIE
TBlNSITIOIS IN BEPEBEIICE STATE ELEIBIITS

TONGSTEI I. P. 3680 K.
HEAT ClPlCITY EQDlTIOI
2.7572x10Z-
0.12311 T
2.4616x10 T-Z
(EQOlTIOII VALID FBOII
ll.!FEBENCE
140
247
3.9685x1o-s TZ
298- 1800 K)
247
COIPILBD
7- 2-76
245
PIOPIBTIIS I f BIGB TBBPIIATUBBS

TUIGSTBI TBIOIIDI
FOBBULA IBIGBT
Crystals (aonoclinic) 298.15 to 593 K.
10~:
1050 K.
231.848
Orthorhoabic crystals 593 to
Tetragonal crystals 1050 to aeltinq point 1745 K.
-------------------------------------------------------------------------------FOBBATIOII PBOB THB ILBBIITS

( a;-a~ 98 )/T
TBBP.
K
J/aolK
soT
-(G;-a; 98 )/T
cop
J/aolK
J/aolK
J/aolK
1.26
1.26
98.79
111 .as
134.112
149.01
161.99
173.63
184.12
189.36
78.91
84.84
91.75
98.91
106.00
112.89
119.48
122.98
GIBBS
Fill IlliG I
BITHALPt
Log Kf
kJ/aol
kJ;aol
--------------------------------------------------------------------------------764.062
133.861
298.15
75.91
-842.909
o.ooo
73.14
75.91
UICBI'UIITt
400
500
600
700
800
900
1000
1050
19.875
13.010
42.667
50.100
55.991
60.71l4
611.635
66.374
82.19
88.56
93.07
96.15
98.15
99.32
99.85
99.91
0.837
0.879
0.154
-842.013
-8110.590
-838.821
-816.851
-737.247
-711.210
-685.494
-660.101
-634.989
-610.139
-585.516
-573.510
96.275
711.300
59.678
119.258
111.461
35.412
30.5811
28.531
-an. 111
-832.682
-830.616
-829.509
-------------------------------------------------------------------------------28.531
1050
67.894
-573.510
190.88
122.98
99.23
-827.916
1100
1200
1300
1400
1500
1600
1700
69.368
71.9118
74.216
76.236
78.066
79.713
81.269
BBLTIIG POIIT
IITHALPI
8~98
195.24
203.97
212.09
219.68
226.83
2ll.S9
2110.01
125.87
132.02
137.87
143.44
1118.76
.153. 86
158.74
1745
0, BBLTIIG
B~
99.78
100.88
101.98
103.09
104.19
105.29
106.40
-826.951
-825.021
-823.068
-821.094
-819.075
-817.025
-811l.933
26.6118
23.379
20.620
18.261
16.220
111.441
12.874
-561.180
-537.099
-513.187
-489.434
-465.795
-442.329
-1118.978
BOILIIG POIIT
73.429 kJ
BITHALPt OF YAPOBIZATIOI
kJ
12.339 kJ
IIOLAI YOLUBB
3.1610 J/bar
31.610 ca3
TI&ISITIOIS II IIPBBBJCB ST&TB BLBBBITS

TUIGSTBI B. P. 3680 I.
BlAT C&P&CITI IQUATIOIS
c; =
c;
2.1388z102 - 3.46811z1o-z T - 2.5610x10~

(BQUATIOI VALID FBOB 298 - 1050 K)
r-os
1.6l74z10 r-z
87.642 + 1.1033z1o-z
( BQUA!IOI ULID PIOB 1050 - 171l5 I)
IBFBIBICB
140
247
COBPILBD
8-12-16
THBBBODIIABIC PBOPBBTIIS OP !IIBBALS
246
FOB!ULA MIIGHT
ITTBID! SBSQDIOIIDE (CUBIC)
Alpaa crystals 298.15 to 1130 1.
225.81~
-------------------------------------------------------------------------------POB!.lTIOI PRO! THE ELEBBITS

c a;-a~ 98 )/T
TBBP.
K
J/olK
-cG;-a; 98 )/T
cop
J/olK
J/olK
J/olK
4.20
4.20
sT
BITBALPY
GIBBS
PBEE BURGY
Log If
kJ/ol
kJ/ol
--------------------------------------------------------------------------------1816.609
318.264
298.15
o.ooo
99.08
99.08
-1905.310
102.84
UICBJITUITI
2.260
2.400
0.420
500
600
700
800
900
1000
27.650
45.256
57.652
66.881
74.047
79.800
84.537
130.91
156.71
178.51
197.35
213.94
228.75
242.15
103.26
111.45
120.86
130.47
139.89
148.95
157.61
112.95
117.97
121.09
123.31
125.05
126.52
127. 81
-1904.246
-1902.782
-1901.211
-1899.651
-1898.156
-1896.745
-1895.432
-1786.448
-1151.112
-1728.186
-1699.472
-1670.992
-1642.657
-1614.512
233.287
183.571
150.453
126.817
109.105
95.318
84.334
1100
1200
1300
1330
88.526
91.946
94.922
95.742
254.39
265.66
276.12
279.12
165.86
171.71
181.20
183.38
128.99
130.10
131.15
131.46
-1894. 221
-1893.114
-1892.109
-1891.675
-1586.474
-1558.536
-1530.709
-1521.247
75.]]6
67.842
61.505
59.825
1400
1500
1600
1700
98.143
100.378
102.313
104.058
286.51
295.59
304.09
312.07
188.37
195.21
201.76
208.01
131.66
131.66
131.66
131.66
-1890.373
-1889.671
-1B89. 168
-1888.858
-1503.007
-1475.356
-1447.752
-1420.194
56.078
51.377
47.264
43.637
1800
105.591
319.59
214.00
131.66
BOILIIG POIIT
kJ
EITH.lLPY 01 VAPOBIZ.lTIOI
40~
-------------------------------------------------------------------------------59.825
1330
96.178
279.76
-1521.247
181.38
-1890.864
131.66
!ILTIIG POUT
EITH.lLPI OP ULTIIG
H~ 98
H~
16.665 kJ
-------------------------------40.404
-1392.308
-1921.256
kJ
4.4880 J/bar
44.880 c 3
I!OLAB VOL Dill
TB.liSITIOIS II BEPIBEICB STATE ELEBBITS

ITTRIUB .lLPH.l-BBTA 1752, 11. P. 1799 K.
BEAT CAPACITY EQUATIOIS
c;
1.2106z102 +
REPBBEICE
8.6019z10-3 T 1.8480z10 T-z

298- 1330 K)
(BQUATIOI VALID PRO!

210
264
264
CO! PILED
5-18-76
PBOPBBTIES AT P.IGH TESPEBATUBES

YTTEBBIOS SBSQOIOllDB (CUBIC)
Yb 2 0:
POBBOLA WEIGHT
394.078
-------------------------------------------------------------------------------FOBBATIOB PROS THE BLEIIEBTS

TEI!P.
K
ca;-a~ 98 )/T
J;aolK
so
J/aolK
-(G;-H~ 98 )/T
cop
J/aolK
J/aolK
EBTHALPY
GIBBS
FREE EIERGY
Log Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
133.05
-1814.600
-1726.844
302.537
133.05
109.84
OBCEBTUITY
0.85
0.85
90(1
1000
30.225
49.238
62.428
72.094
79.465
85.267
89.939
167.87
195.80
219.21
239.26
256.76
272.26
286. 17
137.64
146.56
156.78
167.17
177.29
186.99
196.23
122.88
127.16
129.39
130.66
131.41
131.86
132. 13
11(10
1200
1300
1365
93.781
96.992
99.711
101.249
298.17
310.28
320.88
327.39
204.99
213.29
221.17
226.14
132.27
132.34
132.34
132.34
400
500
600
700
BOO
0.850
0.850
0.149
-1812.566
-1810.425
-1808.611
-1806.496
-1804.504
-1802.659
-1800.978
-1697.160
-1668.560
-1640.350
-1612.485
-1584.909
-1557.545
-1530.418
221.627
174.314
142.806
120.326
103.484
90.398
79.941
-------------------------------71.378
-1818.783
-1503.137
-1818.233
-1817.735
-1851.564
-1474.464
-1445.857
-1344.489
64.182
58.095
51.450
-1816.717
-1417.143
52.874
-------------------------------------------------------------------------------51.450
1365
101.623
-1344.489
327.76
226.14
134.64
-1851.053
1400
102.450
331.01
228.56
134.64
1500
1600
1700
1800
104.599
1'06.476
108.133
109.606
340.30
348.99
357.15
364.84
235.70
242.51
249.02
255.23
134.64
134.64
134.64
134.64
IIELTIIIG POIIIT
BOILHIG POINT
kJ
kJ
19.623 kJ
--------------------------------
IIOLAB VOLO!E
4.276(1 J/bar
42.760 ca 3
TRAIISITIONS Ill BEFEREIICE STATE ELEBEIITS

YTTEBBIUII ALPHA-BETA 1033, 1!. P. 1097, B. P. 1465 K.
c;
1.3614x102
BEFEREIICE
2.0174x10-3 T
1.9928x10 T-z
298- 1365 K)
(EQUUIOII VALID FROII

207
235
235
COI!PILED
8-11-76
248
THBIIOD!IlllC PIOPIITIES OP IIIBilLS
ZIHCITE
zno:
POBIULl &BIGHT
81.379
-------------------------------------------------------------------------------POBilTIOI PRO! THE BLEIBITS

TBIP.
(H;-H~ 98 )/T
J/aolK
SD
T
J/aolK
-(c;;-H;98)/T
CDp
J/aolK
J/aol K
GIBBS
EITHlLPI
Pill BlDG!
Log 't
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
-320.477
56.146
o.ooo
43.611
-350.460
40.62
43.61t
UICEBTlliTY
0.40
11. 12 5
18.298
23.ll5
56.115
66.92
75.76
45.32
48.62
52.42
45.84
47.88
49.10
700
800
900
1000
27.089
30.026
32.1111
34.419
83.111
90.16
96.23
101.76
56.32
60.13
63.82
67.34
50.11
51.06
51.99
52.91
1100
36.141
106.84
70.70
53.81
1200
1300
1400
1500
1600
1700
1800
111. 56
115.97
120.10
124.00
127.68
131.16
134.47
37.648
38.987
40.186
41.273
42.257
43.154
43.971
IELTIIG POUT
2242
EITHlLPY OP IELTIIG
u;98 - H~
0.270
0.300
0.053
-350.152
-349.665
-349. 182
-310.2711
-300.355
-290.535
40.518
31.378
25.293
0.40
400
500
600
73.91
76.98
79.91
82.73
85.42
88.01
90.50
54.65
55.44
56.15
56.77
57.29
57.70
57.99
--------------------------------280.722
20.948
-356.098
-355.843
-355.532
-355.149
-269.967
-259.259
-248.579
17.627
15.047
12.984
-354.704
-237.939
11.299
--------------------------------225.262
9.805
-469.312
-1167.679
-465.991
-464.246
-462.459
-460.638
-458.792
-205.001
-184.857
-164.831
-144.931
-125.135
-105.452
80ILIIG POIIT
kJ
EITHlLPI OF VlPORIZlTIOI
6.933 kJ
8.237
6.897
s. 740
4.732
3.845
3.060
kJ
1.4JJ8 J/bar
14.338 ca3
IIOLlJI YOLUIIE
TRliSITIOIS II BEPEREICE STATE ELE!EITS

ZINC II. P. 692.7, B. P. 1178 K.
HilT ClPlCITI EQUlTIOI
,-z
-2.1882x10
(EQUATION YlLID PROII
BIPBIEICE
115
120
215
298 - 1800 K)
41
215
CO!PILED
7-29-76
PROP!ITIBS AT HIGH
249
~BftPERATUBBS
BADDELBYITB
POR!OLA WEIGHT
ftonocliaic crystals 298.15 to 1478 K.
123.219
Tetragonal crystals 1478 to
1800 K.
-------------------------------------------------------------------------------FORftATIOB PRO! THE BLB!BBTS

TEBP.
so
T
( u;-H~ 98 )/T
JjaolK
JjaolK
-(G;-u~ 98 )/T
cop
J/aol K
J/IIOlK
GIBBS
BITBALPY
FREE BIIBBGY
ltJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
-1042.790
182.693
o.ooo
50.38
50.38
56.14
-1100.560
UIICERTAilll'Y
0.34
0.34
400
500
600
700
800
900
1000
15.350
25.474
32.772
38.310
42.674
46.211
49.146
68.06
82.75
95.37
106.39
116.17
124.94
132.90
52.71
57.28
62.60
68.08
73.50
83.75
63.68
67.82
70.53
72.46
73.92
75.07
76.01
1100
51.625
140.19
88.57
76.80
1200
1300
1400
1478
53.752
55.598
57.221
58.335
18.13
146.90
153.12
158.92
163.18
93.15
97.52
101.70
104.84
17.47
78.05
78.56
78.91
1.674
1.715
0.300
-1100.141
-1099.398
-1098.525
-1097.606
-1096.687
-1095.799
-1094.958
-102 l. 11]
-1003.933
-984.921
-966.055
-947.327
-928.705
-910.188
133.605
104.881
85.745
72.088
61.854
53.901
47.544
-1094.176
-891.754
42.346
--------------------------------1097.188
-873.160
38.008
-1096.137
-1095.064
-1094.244
-854.532
-835.994
-821.546
34.336
31.191
29.035
-------------------------------------------------------------------------------1478
62.387
167.23
104.84
74.48
-821.546
29.035
-1088.254
1500
1600
1700
1800
62.565
63.309
63.966
64.550
105.72
109.79
113.65
117. 33
168.28
173.10
177.61
181.88
IIBLTIIIG POIBT
3123
EBTBALPI OP ftBLTIIG
H~ 98 - B~
74.48
74.48
74.48
74.48
-1088.115
-1087.482
-1086.873
-1086.285
-817.552
-799.557
-781.578
-763.658
BOILING POIIIT
I{
87.027 kJ
BITHALPY OP VAPOBIZATIOB
8. 749 ltJ
28.4 70
26.103
24.015
22.161
ltJ
2. 1150 J/bar
21.150 cal
IIOLAR VOLUIIE
TBliSITIOIS II BBPEBEICE STATE ELEK!ITS

ZIBCOIIOB ALPHl-BBTA 1136, K. P. 2125 K.
BElT CAPACITY EQUlTIOI
c;
90.700-
R!PIB!ICI
4.3877&102
,-o
(EQUlTZOI VALID P&Oft

43
264
8.1334&10' ~-z
298- 1478 K)
264
104
COBPILBD
6- 8-76
THEIBODYBA!IC PROPERTIES OF ftiNERALS
250
FOBKULA WEIGHT
Tll.LITE
Al 2 Ti0 5 :
181.861
-------------------------------------------------------------------------------FOR!lTIOJ FRO II THE ELEMENTS

TEIIP.
( H;-H~ 98 )/T
JjaolK
so
T
-(G;-H~ 98 )/T
J/aolK
J/aolK
o. 84
0.84
cop
EJITHALPY
J/aolK
GIBBS
FREE EBBBGY
kJ/aol
.Log Kf
kJ;aol
-------------------------------------------------------------------------------298.15
o.ooo
109.62
109.62
136.40
UBCEBTliBTY
400
500
600
700
800
900
38.275
64.292
83.383
98.046
109.720
119.2119
153.62
191.13
223. 71
252.38
277.93
300.99
115.34
126.84
140.33
154.33
168.21
181.70
161.24
174.34
182.81
188.94
193.75
197.74
1000
127.306
322.01
194.70
201. 18
1100
134.164
341.33
207.17
204.24
1200
1300
1400
1500
1600
1700
1800
140.122
145.370
150.043
154.256
158.081
161.582
164.809
359.22
375.90
391.52
406.23
420.13
433.32
445.88
219.10
230.53
241.48
251.97
262.05
271.74
281.07
207.03
209.61
212.04
214.34
216.53
218.65
220.70
!ELTING POUT
BOILING POINT
EBTHALPY OF IIELTIBG
kJ
EBTHALPY OF VAPORIZATION
ltJ
KOLAR VOLUIIE
---------------------------------------------------------------
kJ
4.8750 J/bar
48.750 ca3
TRABSITIOBS IN REFEREBCE STATE E.LE!EliTS

ALU!IBU! ft. P. 933 K.
TITABIUI! ALPHA-BETA 1155 II. P. 1943 K.
2.1110x1oz +
1.4609x1o-z T 6.6101x10Z
298- 1800 K)
r-os
(EQUATIOB VALID FROII

BEFE.REBCE
21
120
COIIPILED
8- 2-76
251
FORBULA WEIGHT
CALCIDB FERRITE
215.772
-------------------------------------------------------------------------------FORBlTIOif FROB THE ELEBEiiTS

TEBP.
( u;-u~ 98 )/T
JjaolK
((
so
T
-( G;-a; 98 )/T
J/aoll
J/molK
0.84
0.84
cop
E.IITHALPY
J/aoll
GIBBS
FREE EIIERGY
Log Kf
kJ/mol
kJ/aol
--------------------------------------------------------------------------------1412.666
247.494
298.15
153.64
-1520.340
o.ooo
11l5. 35
145.35
UlfC ERT lllfTY
0.021
0.120
0.120
-1518.063
-1515.867
-1514.109
-1512.943
-1376.217
-1340.997
-1306.186
-1271.685
179.716
140.u94'
.113. 714
94.895
-1513.830
-1516.115
-1202.549
-1167.869
69.794
61.003
400
500
600
7uo
40.650
65.850
83.295
96.189
192.19
229.36
260.44
287.19
151.54
163.51
177. 14
191.00
164.03
168.82
172.10
174.97
800
900
1000
106.212
114.333
121.119
J 10.73
331.84
351.04
204.52
217.51
229.92
177.81
180.72
183.77
1100
126.958
368.71
241. 75
186.94
1200
1300
1400
1500
132.093
136.697
U0.893
1lllt.763
385.11
400.47
414.95
428.68
253.02
263.77
274.06
283.92
190.24
193.66
197.18
200.78
BOILIHG POINT
EITHALPY OF YAPOBIZATIOI
kJ
BELTIHG POIIIT
1510
IITHALPY OF BELTIIG
108.240 ltJ
a;98 -
H~
-------------------------------80.779
-1513.291
-1237.163
--------------------------------1132.804
53.793
-1520.1tJ5
-------------------------------47.747
-1096.896
-1530.125
-1527.896
-1525.551
-1522.999
-1060.957
-1025.160
-989.467
4.4980 J/bar
44.980 ca 3
BOLAR YOLUU
25.422 kJ
42.630
38.249
34.456
TBAHSITIOIS Ilf BBPBRBICE STATE ELB!EITS

CALCIUB ALPHA-BETA 720, B. P. BETA 1112, B. P. 1755 I.
IROI CUBIB P. 1042, lLPHA-GABBl 1184, GABBA-DELTA 1665,
B. P. DELTA 1809 I.
HBAT CAPACITY EQUATIO!f
4.6664x1o-z T
95.884 +
BEF!R!IfCE
183
214
1.4097xi0~
298 -
T-os
1510 I)
214
COBPILED
8- 2-7&
THERftODYNAftlC PROPERTIES OF ftiNERALS
252
FORftOLA WEIGHT
DICALCIOft FERRITE
CazFe 2 0 5
271.851
-------------------------------------------------------------------------------FORftlTION FRO!I THE ELEI!IENTS

TEI!IP.
so
( H;-a; 98 )/T
JfaolK
J/aolK
-(G;-H~ 98 )/T
J/aoll
cop
BBTHALPY
GIBBS
FREE ENERGY
kJ/aol
kJ/aol
Jfaoll
Log 't
-------------------------------------------------------------------------------350.667
188.78
-2139.280
-2001.560
298.15
o.ooo
188.78
192.88
UNCERTAINTY
0.850
0.850
0.1119
-2136.286
-2132.584
-2129.129
-2126.373
-1954.922
-1909.9811
-1865.787
-1822.179
255.288
199.536
162.1132
135.973
1.26
1.26
1100
500
600
700
52.775
87.012
111.158
129.0119
2149.52
299.411
341.71
378.111
196.75
212.113
230.55
2119.09
217.89
228.711
234.52
238.02
800
900
1000
1112.826
153.767
162.670
1110.08
1138.50
11611.08
267.25
284.73
301.111
240.38
242. 11
243.119
1100
170.071
1187.34
311.27
2114.64
1200
1300
11100
1500
1600
176.328
181.698
186.364
190.Q70
1911.113
508.68
528.38
546.69
563.79
579.811
332.35
346.68
360.33
373.32
385.73
245.67
246.61
247.50
248.35
249.18
1700
197.376
594.98
397.60
250.00
BOILIIG POUT
!ELTING POINT
1750
ENTHALPY OF I!IELTING
151.080 kJ
31.648 kJ
-------------------------------116.136
-2126.1110
-1718.672
-2125.651
-2127.487
-1735.206
-1691.751
100.709
88.368
--------------------------------16117.927
78.2511
-2131.984
--------------------------------2149.447
-1602.620
69.761
-2146.520
-21113.757
-2141.057
-2138.511
-1557.251
-1512.074
-1466.990
-11122.161
62.571
56.416
51.085
46.429
-------------------------------42.322
-2138.450
-1377.393
kJ
6.7180 J/bar
67.180 ca 3
I!IOLlR VOLOI!IE
TRANSITIONS IN REFERENCE STATE ELEBENTS

CALCIUI!I ALPHA-BETA 720, ft. P. BETA 1112, B. P. 1755 I.
IRON CURIE P. 1042, ALPBA-GAI!Iftl 1184, GAI!IBA-DELTA 1665 9
1!1. P. DELTA 1809 I.
2.2228x10Z +
9.7281x10-3 T + 5.419Sx10Z T-os

298- 1750 K)
(EQUATIOI VALID FRO!I

REFEREICE
183
214
214
COIIPILID
8- 2-76
PROPERTIES AT HIGH TEftl'EBATUBES

PEBOYSIUTE
CaTi0 3 :
253
FOBftULA WEIGHT
Alpha crystals (orthorhobic} 296.15 to 1530 1.

1530 to 1800 1.
135.978
Beta crystals (cubic}
-------------------------------------------------------------------------------FOBftATIOI FBOft THE ELEftEIITS

TEftP.
I
so
( H;-H~ga )/T
J/IIOlK
-( G;-H; 98 }/T
J/lloll
J/1101 I
0.42
0.42
cop
EIITHALPY
GIBBS
FREE EIIEBGY
kJ/1101
J/ol K
Log Kf
.kJ/1101
-------------------------------------------------------------------------------298.15
275.979
o.ooo
93.64
93.64
97.65
-1575.256
-1660. 630
UIICEBTAIHTY
1. 715
1. 757
0.308
-1659.455
-1657.675
-1655.926
-1654.412
-1546.237
-1518. 135
-1490.389
-1462.927
201.919
158.599
129.750
109.165
-1652.923
-1652.339
-1408.330
-1381.189
81.738
72.146
-1652.161
-1354.083
&4.300
-1661.232
-1659.023
-1656.689
-1655.935
-1298.207
-1270.369
-1242.674
-1234.767
52.163
47.398
43.274
42.155
-1652.602
-1651.130
-1215.442
-1188.178
39.680
36.508
400
500
600
700
27.375
45.416
58.082
67.424
12 5.13
151.33
173.46
192.49
97.76
105.91
115.38
125.07
114.27
119.97
122.60
124.30
800
900
1000
74.629
80.400
85.194
209.19
224.10
231.&2
134.56
143.70
152.43
125.82
127.42
129.21
1100
89.284
250.02
1&0.74
131.19
1200
1300
1400
1500
1530
92.865
96.072
98.993
101.705
102.450
261.53
272.30
282.45
292.08
295.28
168.66
176.23
183.46
190.37
192.82
133.38
135.75
138.30
141.00
141.83
1600
1700
105.264
106.948
302.46
310.58
197.20
203.63
134.01
134.01
1800
108.468
318. 28
209.81
134.01
BOILIIIG POIRT
kJ
EIITHALPY OF VAPOBIZATIOII
kJ
kJ
ftOLA.I VOLUftE
--------------------------------1435.573
93.734
-1653.929
--------------------------------1326.208
57.729
-16&3.354
-------------------------------------------------------------------------------1530
-1234.767
42.155
103.955
134.01
296.78
192.82
-1653.633
ftELTIIIIG POIHT
2188
EHTHALPY OF ftELTIHG
--------------------------------1157.665
33.595
-1803.252
3.3626 J/bar
13.626 c 3
TBAISITIOIS Ill B&PEBEICE STAT! BLBftEIITS

CALCIUB ALPHA-BETA 720, ft. P. BETA 1112, B. P. 1755 K.
TITUIUft ALPHA-BETA 1155 1 ft. P. 1943 I.
HEAT CAPACITY EQUATIOJ
4.5156x1o-z T
(BQUAXIOII YALID F.IOB
12.496 +
BBFBBEICB
177
120
+
2.4620x103
298 - 1530 I)
r-os
214
COftPILI:D
7-17-76
254
THERMOOYHAMIC PROPERTIES OF MIVEBALS
PEROVSKITE
CaTi0 3 :
FORMULA WEIGHT
Alpha crystals (orthorhoabic) 298.15 to 1530 K.
135.978
Beta crystals (cubic)
1530 to 1800 K.
-------------------------------------------------------------------------------FOR.IUTIOH FROM THE OXIDES

TE.I'IP.
D
ST
(H;-H~ 98 )/T
J/IIOlK
-( G;-H~98 )/T
CD
J/molK
J/molK
J/aol K
0.42
0.42
GIBBS
FREE ENERGY
ENTHALPY
k.J/1101
Log Kf
kJ/mol
--------------------------------------------------------------------------------82.323
14.423
298.15
0.000
93.64
-80.791
93.64
97.65
UHCERTAINTY
o. 760
400
500
600
700
800
900
1000
27.375
45.416
58.082
67.424
74.629
80.400
85.194
125.13
151.33
173.46
192.49
209.19
224.10
237.62
97.76
105.91
115.38
125.07
134.56
143.70
152.43
114.27
119.97
122.60
124.30
125.82
127.42
129.21
-80.341
-79.676
-79.088
-78.628
-78.278
-78.011
-77.772
1100
1200
1300
1400
1500
1530
89 .284
92.865
96.072
98.993
101.705
102.450
250.02
261.53
272.30
282.45
292.08
295.28
160.74
168.66
176.23
183.46
190.37
192.82
131.19
133.38
135.75
138.30
141.00
141.83
-77.544
-77.293
-76.989
-7o.611
-76.138
-75.931
0.810
-82.901
-83.616
-84.458
-85.397
-86.390
-87.425
-88.482
10.826
8.735
7.353
6.372
5.641
5.074
4.622
-89.556
-90.661
-91.783
-92.949
-94.123
-94.888
4.253
3.946
3.688
3.468
3.278
3.240
-------------------------------------------------------------------------------3.240
1530
103.955
-94.888
296.78
134.01
-73.629
192.82
3.121
-95.609
1600
105.264
302.46
-73.929
197.20
134.01
2.979
106.948
-96.968
1700
310.58
-74.358
203.63
134.01
2.853
-98.326
1800
108.468
318.28
-74.908
209.81
134.01
BELTING POINT
2188
ENTHALPY OF MELTING
BOILING POINT
kJ
kJ
kJ
MOLAR VOLU.IIE
3.362o J/bar
33.626 cm 3
TBAVSITIONS IN REFERENCE STATE OXIDES
12.496 + 4.5156x1o-z T
{EQUATION VALID FROM
REFERENCE
177
120
2.4620x103 T-os
298- 1530 K)
6. 3 o18x 1 o T- z
214
COMPILED
7-17-76

COBALT SPINEL
Co 3 o.:
255
FOBftULA WEIGHT
240.797
-------------------------------------------------------------------------------FOBIUTION FBOft THE ELEftE!ITS

TEftP.
K
so
-(G;-a~ 98 )/T
cop
J/IIOlK
J/1101 K
J/1101 K
(a;-a~ 98 )/T
J/olK
ENTHALPY
kJ/ao1
GIBBS
FREE ENERGY
Log Kf
kJ/ao1
-------------------------------------------------------------------------------135.349
-772.553
298.15
102.51
-891.190
o.ooo
102.51
123.05
UNCERTAINTY
0.84
0.84
8.500
8.500
1.489
-891.199
-890.632
-889.991
-731.979
-692.247
-652.613
95.587
72.319
56.815
-888.845
-886.561
-883.346
-573.621
-534.328
-495.366
37.454
31.012
25.875
400
500
600
34.725
57.598
74.093
142.43
175.67
204.19
107-71
118.07
130.10
144.84
152.84
160.63
700
800
900
1000
87.153
98.404
1 08.744
118.692
229.69
253.33
275.86
297.78
142.54
154.93
167.12
179.09
170.88
183.92
199.49
217.25
MELTING POINT
BOILING POINT
ENTHALPY OF MELTING
kJ
kJ
kJ
llOLAR VOLUME
-------------------------------45.753
-613.134
-889.067
3.9770 J/bar
39.770 ca 3
TRANSITIONS IN REFEREHCE STATE ELEMENTS

COBALT ALPHA-BETA 700, CURIE P. 1394
ft.
P. BETA 1768 K.

0.34236 T
-4.8355x102 +
REFEBE NCE
129
263
1.1845x10 T-os
298 - 1000 K)
263
COftPILED
8- 4-76
256
THEBSODIIABIC PROPERTIES OF !IHEBALS
CHBOIIITE
FOBBULA WEIGHT
223.837
FOB!ATIONFBO! THE ELE!EHTS

GIBBS
FBEE EIEBGY
EIITHALPY
TE!P.
K
J/llol K
Jjaol K
ltJjaol
ltJjaol
298.15
o.ooo
UNCEBTAIITY
146.02
1.67
146.02
1.67
133.64
400
500
600
700
800
900
1000
36.275
60.126
77.515
90.844
101.439
110.089
117.311
187.75
222.43
252.39
278.71
302.15
323.21
342.47
151.48
162.30
174.88
187.87
200.71
213.18
225.16
149.96
160.53
167.96
173.42
177.60
180.90
183.60
1100
123.445
360.08
236.64
185.89
1200
1300
1400
1500
1600
128.734
133.357
137.450
141.104
144.409
376.35
391.46
405.59
418.85
431.37
247.62
258.10
268.14
277.75
286.96
187.90
189.74
191.47
193.14
194.81
1700
1800
147.424
150.199
443.23
454.51
295.81
304.31
196.51
198.27
!!ELTING POIIIT
BOILING POUlT
EIITHALPY OF !!ELTING
ltJ
ltJ
ltJ
!OLAB VOLU!E
4.4010 Jjbar
44.010 ca 3
TRANSITIONS IN REFEBEHCE STATE ELE!EIITS

IRON CURIE P. 1042, ALPHA-GAII!A 1184, GA!!A-DELTA 1665,
a. P. DELTA 1809 K.
CHBOI!IUII 11. P. 2130 K.
3.0184x10Z+
REFERENCE
4.1571x1o-z T
4.8769x105 T-z
120
298- 1800 K)
CO!PILED
7-17-76
PROPERTIES AT HIGH TB!IPBBATOBES
ILftEUT!
257
FOB!IULA WEIGHT
Crystals 298.15 to 8eltinq point
16~0
K.
151.7~5
Liquid 1640 to 1800 1.
-------------------------------------------------------------------------------FOBUTIOI PBO!I THE BLB!IEITS

TE!IP.
so
-( G;-H~ 98 )/T
cop
J/8olK
J/8olK
J/8ol K
1.25
1.25
cH;-a~ 98 )/T
J/80lK
EITHALPI
GIBBS
FREE BIEBGI
kJ/801
Log
't
kJ/801
-------------------------------------------------------------------------------298.15
o.ooo
105.86
105.86
-1159.170
203.083
99.50
-1236.622
UICBBTUITI
400
500
600
700
800
900
1000
27.275
44.886
57.297
66.594
73.938
80.000
85.187
137.25
162.96
1811.71
203.57
220.30
235.43
249.33
109.97
118.07
127.41
136.98
146.36
155.43
164.14
112.115
117.63
120.92
123.84
126.87
130.14
133.69
1100
89.767
262.24
172.47
137.51
1200
1300
1400
1500
1600
1640
93.913
97.743
101.336
104.758
105.541
106.523
2111.38
285.88
296.85
307.38
314.68
318.57
180.47
188.14
195.51
202.62
209.14
212.05
141.57
145.85
150.33
154.97
159.76
161.71
1. 590
1.632
0.286
-1235.523
-1234.099
-1232.752
-1231.587
-1230.674
-1230.104
-1230.137
-1132.854
-1107.341
147.936
115.684
94.207
78.884
67.400
58.1172
51.333
-1082.11~
-1057.125
-1032.266
-1007.463
-982.744
--------------------------------957.935
-1230.896
45.489
--------------------------------933.023
-1234.603
~0.614
-1232.068
-1229.337
-1226.133
-1227.093
-1226.352
-908.028
-883.221
-858.572
-833.623
-824.285
36.485
32.954
29.898
27.215
26.254
-------------------------------------------------------------------------------1640
161.808
-824.285
26.254
373.85
212.05
199.16
-1135.684
--------------------------------812.407
1700
163.126
380.71
217.58
-1132.527
24.962
199.16
1800
165.128
392.13
ftELl'IIG POUT
16110
BITHALPI OP !IBLTIIG
-1125.878
-793.789
23.035
227.00
199.16
BOILUG POI IT
BITHALPI OF YAPOBIZATIOI
kJ
90.667 kJ
kJ
3.1690 J/bar
31.690 c8 3
!IO.UB YOLO!IB
TIAISITIOIS II BBPEBBICE STATE BLEBBITS

IBOI COli! P. 1042, ALPHA-GA!I!IA 1184, GA!I!IA-DBLTA 1665,
TITAIIO!I ALPHA-BETA 1155, ft. P. 1943 K.
-2.9895 +
6.5049x1o-z T
(EQUATIOI VALID FlO!

l!liBEIC!
177
120
2.4266x10 T-o
298 - 1640 K)
122
COIIPILBD
7-17-76
258
THER!ODYHA!IC PROPERTIES OF !IRERALS
POBIIULA WEIGHT
ILIIEHITE
Crystals 298.15 to melting point 1&40 K.
151.745
Liquid 1&40 to 1800 K.
-------------------------------------------------------------------------------FOR!ATIOR FRO II THE OXIDES

TEIIP.
so
-(G;-a~ 98 );T
cop
J/aolK
J/aolK
J/aolK
1. 25
1.25
( H;-a~ 98 )/T
J/IIOlK
GIBBS
FREE ENERGY
ENTHALPY
kJ/1101
Log Kf
kJ/1101
--------------------------------------------------------------------------------18.5&8
3.253
298.15
o.ooo
105.86
105.86
-19.829
99.50
UNCERTAINTY
2.300
2.340
2.3&3
1.839
1. 488
1.238
1.048
0.900
0.782
1100
89. 7&7
-20.161
-14.441
0.&86
262.24
172.47
137.51
0.607
1200
93.913
-19.792
-13.936
.274. 38
180.47
141.57
97.743
-19.209
-13.463
0.541
1300
285.88
188.14
145.85
1400
101.336
0.487
296.85
195.51
-18.389
-13.055
150. 33
1500
104.758
-12.713
0.443
307.38
202.62
-17.303
154.97
-11.897
O.J88
1600
105.541
314.68
209.14
-19.940
159.76
1640
106.523
o. J36
318.57
-19.921
-10.548
212.05
1& 1. 71
-------------------------------------------------------------------------------v. 336
1640
161.808
37 3. 85
70.747
-10.548
212.05
199.16
-------------------------------1700
163.126
-12.014
0.369
380.71
217.58
51.595
199.16
0.464
1800
165.128
-15.980
392.13
56.450
227.00
199.1&
400
500
&00
700
sou
900
100u
27.275
44.88&
57.297
66.594
73.938
80.000
85.187
137.25
1&2.96
184.71
203.57
220. 30
2J5.1U
249.33
109.97
118.07
127.41
13&.98
14&.36
155.43
1&4.14
112.45
117.63
120.92
123.84
126.87
130.14
133.69
-20.049
-20.074
-20.134
-20.239
-20.343
-20.399
-2u.35o
-18.093
-17.599
-17.u92
-16.585
-16.055
-15.512
-14.980
!!ELTING POINT
1640
BOlLING POI NT
90.6&7 kJ
3.1690 Jjbar
J1.690 CIIJ
IIOLAB VOLUIIE
kJ
kJ
TRANSITIONS IN BEFEBEVCE STATE OXIDES

FEO ft. P. 1650 K.
HEAT CAPAClTY EQUATION
-2.9895 + b.5049x1o-z T
(EQUATION VALID PBOII
REFERENCE
177
120
2.426bx10.J T-os
298- 1640 K)
5.1057x1o T-z
122
COMPILED
7-17-76
PIOPEBX1ES AX HIGH TE!PERATUBES
259
FOR!ULA WEIGHT
TITliO!AGNETITE
223.592
-------------------------------------------------------------------------------FOR!ATIOI FRO! THE ELE!ENTS

TE!P.
so
-(G;-a~ 98 )/T
cop
J/molK
J/olK
J/ol K
( u;-H~ 98 )/T
J/olK
ENTHALPY
GIBBS
FREE EIERGY
ltJ/sol
Log Kf
kJ/mol
-------------------------------------------------------------------------------298.15
168.87
0.000
168.87
142.30
0 NCEB7liBTY
2.51
2.51
400
500
600
700
800
900
1000
39.050
64.178
81.868
95.199
105.81'19
114.856
122.741
213.81
250.53
281.57
308.56
JJ2.66
354.65
375.05
174.76
186.35
199.70
213.36
226.79
239.79
252.31
160.82
167.82
172.72
177.75
183.51
190.10
197.48
1100
129.897
394.25
264.35
205.56
1200
1300
1400
1500
1600
136.561
142.889
1118.986
154.933
160.716
412.51
1130.02
446.93
4b3.3b
479.39
275.95
287.13
297.94
308.43
318.61
214.26
223.118
233.16
243.23
253.61'1
1700
1800
166.554
172.293
495.08
510.50
328.53
338.21
264.38
275.38
!!ELTING POIIIT
BOILING POINT
ENTHALPY OF !ELTING
kJ
kJ
!OLAR VOLUI!E
8 ~98 -
Ho
---------------------------------------------------------------
--------------------------------
kJ
4.6820 J/bar
46.820 cm 3

IRON CURIE P. 1042, ALPHA-GAI!I!A 1184, GA!!A-DELTA 1665,
1!. P. DELTA 1809 K.
TITANIUII ALPHA-BETA 1155, 1!. P. 1943 K.
1.0257x1oz +
REFERENCE
21
5.2707x1v~
0.14252 T
(EQUATION V!LID FROM

120
298 -
T-o5
1800 K)
COMPILED
8- 2-76
THBBKODIJl!IC PBOPBRTIBS OP BIIBilLS
260
PORBOLl iBIGHT
PSBODOBROOIUTE
239.591
POR!lTIOJ PRO! THI BLIBBITS

GIBBS
PBBB BIIBBGY
BITHlLPI
TEKP.
K
298.15
o.ooo
UICEBTlliTY
156.48
1.25
156.48
1.25
164.26
400
500
600
7(10
800
900
1000
44.275
72.714
92.963
108.214
120.192
129.911
138.002
207.44
249.02
284.41
315.19
342.43
366.89
389.10
163.16
176.31
191.45
206.98
222.24
236.98
251.10
181.43
190.86
197.22
202.02
205.94
209.30
212.30
1100
144.883
409.46
264.58
215.04
1200
1300
1400
1500
1600
150.836
156.064
160.714
164.893
168.686
428.28
445.79
462.18
477.59
492.15
277.44
301.47
312.70
323.46
217.58
219.99
222.29
.224. 51
226.65
1700
1800
172.157
11-5.351
505.96
519.09
333.80
343.7 j
228.74
230.78
llELTIIIG POIIIT
BOlLI IIG POI IT
EIITHlLPY OF llELTIIIG
kJ
BIITHlLPY OF VlPOBIZlTIOJ
kJ
kJ
KOLlR VOLUftE
289.13
5.4530 J/bar
54.530 cJ
TBliiSITIOJS II BBPERBIICE STlTE ELEBEMTS

IROJ CURIE P. 1042, lLPHl-Gllllll 1184, Glllftl-DELTl 1665,
ft. P. DELTl 1809 K.
TITlMIUil lLPHl-BETl 1155, 8. P. 1943 K.
2.1356x10Z + 1.6245x1o-z T 4.7946x102
(EOOlTIOM VlLID FIOil 298- 1800 K)
REPEBEMCE
21
120
,-os
COBPILBD
8- 2-76
PIOPJ.TIJS lT HIGH TIBPBilTUBIS

LITBIUB ALUBIIlTI
261
(lLPHl)
POBBULA IIBIGHT
65.921
Lill0 2 : crystals 298.15 to aelting poiat 1883 K.
-------------------------------------------------------------------------------FOBBlriOII FROII THE ELIIIEIITS

TIBP.
SD
-(G;-a; 98 )/T
CDp
J/aolK
J/aolX
J/aolK
( a;-a; 98 )/T
J/aolX
'l
EITHlLPI
GIBBS
PRIB EIIBGI
kJ/aol
Log xf
kJ/aol
-------------------------------------------------------------------------------298. 15
o.ooo
53.35
-1188.670
-1126.276
197.320
53.35
67.81
UICBR'!U:ITI
400
19.225
2.10
2.10
75.44
56.21
81.39
500
600
700
800
900
32.400
42.092
49.534
55.461
60.322
94.40
110.90
125.41
138.35
150.03
62.00
68.81
75.88
82.89
89.71
88.25
92.57
95.68
98.13
100.20
1000
611.400
160.69
96.29
102.02
1100
1200
1300
1400
1500
1600
67.897
70.944
73.638
76.050
78.233
80.226
170.49
179.58
188.06
196.02
203.52
210.63
102.59
108.64
114.42
119.97
125.29
130.40
103.68
105.23
106.69
108.10
109.46
110.79
1700
1800
82.063
83.767
217.39
223.83
135.33
140.06
112.09
113.37
BJLTIIIG POIIIT
1883
BIITHALPI OF BILTIIG
87.900 kJ
4.180
4.180
0.732
-1189.215
-1104.851
144.279
--------------------------------1083.441
-1192.306
11J. 187
-1192.119
-1191.740
-1191.282
-1190.822
92.428
17.604
66.489
57.848
--------------------------------974.425
-1201.065
50.899
-1200.336
-1199.491
-1198.530
-1197.461
-1196.279
-1194.988
-951.780
-929.227
-906.732
-884.JJ7
-862.004
-839.772
45. 196
40.448
36.433
32.995
30.018
27.416
--------------------------------1338.844
-809.787
24.882
-1336.550
-778.712
22.598
BOILIIG POIIIT
EITHlLPI OP YAPOBIZATIOII
kJ
IIOLAI YOLUBE
kJ
-1061.685
-1039.973
-1018.314
-996.719
2.5210 J/tlar
25.210 ca 3
TRAISITIOIS Ill BEP!B!IICE STATE ELEBEITS

LITHIUB B. P. 453.69, B. P. 1618 K.
lLUIIIIDB !. P. 933 X.
95.382 +
1.1387z1o-z T
(EQUATIOI VALID PBOII

BBPIRBIIJCI
32
32
75.392 r-us
298 - 1800 X)
32
COBPILID
5-19-76
THERitODYHAftlC PROPERTIES OF !IHEBALS
262
FOB!ULA WEIGHT
SPINEL
142.267
-------------------------------------------------------------------------------FOB!ATIOH FRO! THE ELEKEIIITS

TE!P.
so
cH;-H~ 98 );T
J/IIOlK
'1'
J/molK
-( G;- H~98 )/T
cop
J/aolK
JjaolK
EIIITHALPY
GIBBS
FREE ENERGY
kJjaol
Log Kf
kJ;aol
-------------------------------------------------------------------------------298.15
0.000
-2174.860
381.0 28
80.63
80.63
115.94
-2299.320
UNCERTAINTY
0.750
o. 760
0.133
-2300.065
-2299.704
-.2298.833
-2297.757
-.2296.663
-2295.686
-2131.541
-2089.439
-2047.457
-2005.654
-1963.991
-1922.456
278.352
218.283
178.248
149.664
128 .236
111.577
-2323.824
-23.22.247
-2320.474
-1834.159
-1789.7.23
-1745.393
87.097
17.905
70.131
-.2442.192
-2438.746
-.2435.154
-2431.428
-1644.342
-1591.258
-1538.421
-1485.780
57 .261
51.949
47.270
43.116
0.42
0.42
118.00
150.08
178.21
203.17
225.57
245.~9
85.50
95.27
106.80
118.82
130.78
142.46
137.27
149.86
158.58
165.13
170.33
174.64
264.49
153.75
178.30
117.027
122.519
127.372
281.63
297.55
312.40
164.60
175.03
185.03
181.49
184.31
186.85
131.707
1].5. 608
139.151
142.390
145.368
326.34
339.46
351.87
363.64
374.85
194.63
203.85
212.72
221.25
2.29.48
189.17
191.30
193 .27
195.12
196.86
BOILING POINT
kJ
kJ
400
500
600
700
800
900
32.500
54. 806
71.415
84.354
94.787
103.433
1000
110.737
1100
1200
1300
1400
1500
1600
1700
1800
IIELTING POINT
2408
ENTHALPY OF KELTING
15. 410 kJ
--------------------------------1878.752
98.136
-2325.192
-------------------------------63.340
-2445.485
-1697.647
3.9710 J/bar
39.710 cm 3
I!OLAR VOLUIIE

!IAGNESIUII 1!. P. 922, B. P. 1361 K.
ALUI!INU!I 1!. P. 933 K.
2.2291x10Z +
6.1267x10-3 T 1.5512x10~ T-o5

298- 1800 K)

REFERENCE
22
214
237
31
COftPILED
a-
2-76
263
PROPERTIES lT HIGH TE!PEBATUBBS
PICBOCBBO!ITB
-------------------------------------------------------------------------------FO.II.IU.TIOII FBOll THE BLBliEIITS

(H;-a~ 9 a)/T
TEMP.
J;aolK
ST
-( G;-a; 98 );T
J/aolK
J/llolK
0.84
0.84
co
p
ENTHALPY
J/aolK
GIBBS
FREE EIIEBGY
Loq
Kf
kJ/1101
kJ/aol
-------------------------------------------------------------------------------292.417
-1783.640
-1669.079
298.15
0.000
106.02
106.02
126.78
UIICBBTlliiTY
8. 370
8.400
1.472
-1783.163
-1781.786
-1780.051
-1778.236
-1776.495
-1771l.932
-1629.971
-1591.836
-1553.995
-1516.464
-1479.199
-1442.112
212.853
166.299
135.288
113.160
96.582
83.698
-1781.414
-1780.499
-1179.835
-1366.692
-1329.035
-1291.438
64.899
57.852
51.891
-1905.172
-1904.263
-1903.71..2
-1903.544
-1203.472
-1156.727
-1110.033
-1u63.J76
41.909
37.763
34.107
30.859
4uo
500
600
7ou
800
900
35.325
59.u18
76.242
89.350
99.690
108.078
146.63
180.91
210.49
236.38
259.35
279.99
111.30
121.89
134.25
147.03
159.66
171.91
147.92
158.75
165.51
170.22
17J.76
176.58
1000
115.051
298.72
183.67
178.90
1100
1200
1300
120.949
126.019
Hu. 435
315.86
331.68
346.36
194.91
205.66
215.92
180.89
182. 64
184.20
14uo
1500
160u
1700
1auu
134.329
137.791
140.899
143.712
146.274
360.06
372.92
385.02
396.46
407.31
225.73
235. 13
244.12
252.75
261.04
185.62
186.92
188.13
189.27
190.35
!l!LTI NG POINT
BOILING PO.iNT
ENTHALPY OF !lELTING
kJ
8~98
H~
kJ
TRAIISITIONS Ill REFERENCE STATE

!AGIIESlU! ft. P. 9..22, B. P.
-------------------------------73.361
-1782.554
-1404.444
-------------------------------46.649
-1906.419
-1250.281
kJ
4.3560 J/bar
43.560 ca 3
BOLAR VOLU!E
ELE~ENTS
1361 K.
CHROMIU!l ft. P. 2130 K.
1.9614x102 + 5.3977x10-3 T
(EQUATION VALID FROM 298 -
REFERENCE
174
214
6.16A8x102 T-os
1800 K)
214
3.1260x10 T-2
CO!lPILED
7-17-76
THIIBODIIlaiC PIOPIRrliS OF BIIIBALS
264
POBBDLl WEIGHT
PICBOCHIOBITE
192.295
-------------------------------------------------------------------------------FOB!lTIOI FBOII TBB OIIDES

TEI!P.
K
so
( a;-a~ 98 )/T
J/aolK
J/aolK
-( G;-a; 98 )/T
cop
J/aoltt
J/aollt
GIBBS
PREB BIEBGI
BIITHlLPI
ltJ/aol
Log If
ltJ/aol
--------------------------------------------------------------------------------116.827
8.2011
-47.1150
298.15
0.000
106.02
126.78
106.02
DICBBTAIITJ
8.1100
8.370
0.811
0.811
1100
500
600
700
800
900
1000
35.325
59.018
76.242
89.350
99.690
108.078
115.051
146.63
180.91
210.49
236.38
259.35
279.99
298.72
111.30
121.89
134.25
147.03
159.66
171.91
183.67
147.92
158.75
165.51
170.22
17 3. 76
17&.58
178.90
-48.620
-49.312
-49.666
-49.812
-49.841
-49.810
-119.744
-116.492
-45.872
-115.142
-44.373
-43.601
-112.826
-42.054
1100
1200
1300
1400
1500
1600
1700
1800
120.949
126.019
130.435
134.329
137.791
140.899
143.712
146.274
315.86
331.68
346.36
360.06
372.92
385.02
396.46
407.31
194.91
205.66
215.92
225.73
235. 13
244.12
252.75
261.04
180.89
182.64
184.20
185.62
186.92
188.13
189.27
190.35
-49.664
-49.571
-49.487
-119.390
-49.283
-49.162
-49.016
-48.842
-41.282
-40.529
-39.776
-39.016
-38.303
-37.578
-36.844
-36.152
!!ELTING POINT
BOU.ING POIIT
ENTHALPY OP !ELTING
ltJ
EITHlLPY OF VAPORIZATION
ltJ
IIOLlB VOLUIIE
6.071
4.792
3.930
3.311
2.847
2.1186
2.197
1. 960
1. 764
1.598
1.456
1.H4
1.227
1.132
1.049
ltJ
4. 3560 J/bar
43.560 ca 3
TRANSITIONS II REPEREICE STATE OXIDES

1.9614x102 + 5.3977x10-3 T
6.1688x102
(EQUATIOI VALID PROII 298- 1800 It)
BEPBREICE
174
214
r-os
214
COIIPILBD
7-17-76
PROPERTIES AT
H~GH
TESPERATURES
265
PORSULI lEIGHT
SlGIIESIOPBIRITE
Alpha
crys~als
298.15 to 665 1.
Gaaaa
crys~als
1230 to 1800 1.
Be~a
199.997
crystals 665 to 1230 1.
-------------------------------------------------------------------------------FORUTIOII FROS THE ELBitEIITS

TE.IlP.
(a;-a; 98 )/T
J;aoll
so
-( G;-a;98 )/T
cop
J/aoll
J;aoll
J/aoll
BIITHlLPY
GIBBS
FREE BURGY
Log If
kJ/aol
kJ/aol
-------------------------------------------------------------------------------230.735
-1311.0011
1113.72
298.15
0.000
123.85
123.85
-11128.420
UIICERT lilT I
1100
500
600
665
39.350
66.022
86.428
97.601
o. 811
0.84
169.11
207.59
2111.91
262.55
129.76
141.57
155.48
164.95
164.30
180.83
196.01
205.88
1.841
1.883
0.330
-1426.6111
-1423.820
-1420.197
-1418.140
-1279.171
-1242.595
-1206.670
-1185.187
167.043
129.814
105.050
93.095
--------------------------------------------------------------------------------1185.187
93.095
665
97.601
262.55
186.68
-1418.1110
164.59
700
800
900
102.857
113.470
121.867
272.03
297.10
319.36
169.17
183.63
197.49
187.13
188.110
189.68
1000
128.711
339.41
210.70
190.95
1100
1311.426
357.67
223.24
192.23
1200
1230
139.296
140.623
374.45
235.15
238.61
193.50
193.88
319.23
-1416.079
-1414.267
-1413.500
-1170.817
-1135.915
-1101.103
87.368
74.168
63.907
--------------------------------1065.610
55.662
-11123.296
--------------------------------1029.671
118.895
-11125.959
--------------------------------993.684
43.254
-1426.829
-1426.207
-982.951
41.743
--------------------------------------------------------------------------------982.951
111.743
1230
141.592
380.20
176.92
238.61
-1425.015
-1424.600
-957.768
-1548.260
-1545.451
-873.195
-828.308
1300
143.602
390.10
246.50
180.93
1400
1500
1600
146.1171
149.3110
152.207
403.72
416.79
1129.39
257.25
267.45
277.18
186.64
192.36
198.07
1700
11100
155.073
157.938
1141.57
453.38
286.50
295.1t4
203.79
209.50
kJ
EITBALPY OF YlPOBIZATIOI
kJ
I!OLAB YOLUI!E
I!ELTIIG POIIT
38.484
--------------------------------918.3114
311.264
-1550.717
30.407
27.042
-------------------------------24.075
-783.525
-1544.627
-1541.769
-738.786
21.1139
80XLIIG POJ:IT
BITHALPY OF ft!LTIIG
kJ
4.4570 J/bar
44.570 ca 3
TBAISITIOIS II RBFEBBICB STlTB BLBI!EITS

.lllGIBSIDit
1!.
P. 922, B. P. 1361 I.
IBOII COilE P. 1042, ALPHA-GABBA 1184, GAI!I!A-DBLTI 1665,

S. P. DBLTA 1809 I.
BBAT CAPACITY EQDATIOIS
c;
c;
1.7820z1oz +
1.2752z1o-z T
665 -
(BQDlTIOI VALID 1108
1230 K)
5.7158z1o-z T
(IQUITIOI YlLID FIOI 1230 - 1800 l)
1.0662z1oz +
RBl!JliWCI
183
120
214
146
COl PILED
8- 2-76
2&6
THERKODYNAKIC PROPERTIES OF
MINERAL~
GEIKELITE
FORMULA WEIGHT
1.20.203
-------------------------------------------------------------------------------FORMAriOll FROM THE ELE.KEHTS

TEKP.
soT
( H;-H~ 98 )/T
J;molK
J/aolK
-( G;-H~ 9 a)/T
JjmolK
cop
ENTHALPY
JjaolK
GIBBS
FREE ENERGY
Log Kf
kJ/mol
k.J/1101
-------------------------------------------------------------------------------298.15
o.uuo
-1572.765
-1484.371
260.057
74.56
74.56
91.76
UNCERTAINTY
0.42
0.42
900
25.725
42.910
55.255
64.564
71.877
77.822
104.13
129.0.2
150.34
16tl.89
185.33
200.09
78.40
86.11
95.09
104.33
113.45
122.27
107.77
114.78
118.89
121.83
124.26
126.47
1000
82.793
213.52
130.7 3
128.56
110(1
87.046
225.tl7
138.82
130. 60
1200
90.759
94.055
237.32
248.02
146.56
153.97
132.60
134.59
97.021
99.7.21
1o2.2u&
104.510
106.6&3
258.06
267.55
27&.55
285.12
293.31
161.04
167.tl3
174.34
180.61
186.65
136.56
138.50
140.43
142.33
144.20
400
500
&00
700
sou
1J(j(j
140(1
1500
160(1
1700
1800
KELTING POINT
1903
ENTHALPY OF KELTING
1.590
1.630
0.285
-1572.228
-1571.02.2
-1569.645
-1568.273
-15&6.9&7
-1565.748
-1454.218
-1424.857
-1395.75(1
-1366.876
-1338.203
-1309.662
189.902
14!1.854
121.511
101.998
87.376
76.011
-1572.416
-1251.260
59.418
-1573.590
-1192.599
47.919
-1695.847
-1&92.8.27
-1689.756
-1686.633
-1121.347
-1083.139
-1045.142
-1007.313
39.049
35.3&1
3.2.113
29.232
--------------------------------1280.508
66.887
-1573.568
--------------------------------1221.961
53.191
-1575.283
--------------------------------1159.744
-1698.814
43.271
BOILING POINT
k.J
13.55& kJ
k.J
3.08&0 J/bar
30.860 cm 3
t!OLAR VOLUME

.MAGNESIUM K. P. 922, B. P. 1361 K.
TITANIUK
ALPHA-BETA 1155, K. P. 1943 K.
&1.&35 +
3.767lx1u-2 T
-4.3444x10 T-2
REFERENCE
177
120
3. 5882x 1 o- T2
298- 1800 K)
214
COMPILED
7-17-76
267
PBOPEBTIES AT HIGH TEI!PEUTUBES

GEIKELITE
FOBI!ULA WEIGHT
120.203
-------------------------------------------------------------------------------FOBI!ATION FBO.Il THE OXIDES

TEIIP.
-( G;-H~ 98 )/T
cop
J/aolK
J/molK
J/mol K
0.42
0.42
so
T
(H~-H; 98 )/T
JjaolK
GIBBS
FREE EliiERGY
ENTHALPY
Log Kf
ltJ/1101
ltJ/1101
-------------------------------------------------------------------------------4.508
298.15
74.56
-25.729
o.ooo
74.56
91.76
-26.525
UNCERTAINTY
0.920
0.960
3.327
2.646
2.201
1.888
1.659
1.482
1.343
400
500
600
700
800
900
1000
25.725
42.910
55.255
64. 564
71.877
77.822
82.793
104.13
129.02
15 0. 34
168.89
185.33
200.09
213.52
78.40
86.11
95.09
104.33
113.45
122.27
130.73
107.77
114.78
118.89
121.83
124.26
126.47
128.56
-26.285
-25.826
-25.345
-24.888
*
-24.460
-24.055
-23.646
-25.481
-25.331
1100
1200
1300
1400
1500
1600
1700
1800
87.046
90.759
94.055
97.021
99.721
102.206
104.510
106.663
225.87
231.32
248.02
258.06
267.55
276.55
285.12
293.31
138.82
146.56
153.97
161.04
167.83
174.34
180.61
186.65
130.60
132.60
134.59
136.56
138.50
140.43
142. J3
144.20
-23.233
-22.798
-22.329
-21.815
-21.250
-20.622
-19.924
-19.152
-25.950
-26.218
-26.528
-26.855
-27.250
-21.662
-28.118
-28.638
BOILING POINT
ltJ
kJ
!!ELTING POINT
1903
ENTHALPY OF .llELTING
-25.301
-25.404
-25.540
-25.716
*
*
*
*
*
*
*
1.232
1.141
1.066
1.002
0.949
0.903
0.864
0.831
3.0860 J/bar
30.860 c11 3
IIOLAB VOLUME
13.556 kJ
*
**
*
-25.27~
TRANSITIONS IN REFERENCE STATE OXIDES

61.635 +
J. 767Jx1o-z T
3.5882x1o- T2
-4.3444x10 T-2

REFEREIICE
177
120
298- 1800 K)
214
COI!P.ILED
7-17-76
268
THER!ODYNA!IC PROPERTIES OF !INEBALS
ZINC TITANIU! SPINEL
FOR!OLl WEIGHT
242.658
Zn 2 Ti0 4 :
-------------------------------------------------------------------------------PORKATIOII PRO! THE ELE!ENTS

TE!P.
so
( u:~-u; 98 )/T
J,f11olK
J/llolK
-( G;-a~ 98 )/T
cop
J/IIOlK
J/IIOlK
EIITHlLPY
GIBBS
FREE EIEBGY
Loq ltf
kJ/1101
kJ/1101
--------------------------------------------------------------------------298.15
o.ooo
268.758
143.09
-1647.660
-1534.035
143.09
133.58
UNCERTUNU
2. 510
2.510
0.440
-1646.976
-1645.361
-1643.290
-1495.288
-1457.541
-1420.156
195.265
152.269
123.636
0.28
0.28
400
500
600
36.525
1&0. 804
78.605
185.12
220.31
250.84
148.59
159.51
172.24
151.79
163.31
171.48
700
8{){)
900
1000
~2. 333
103. 307
112.322
119.884
217.76
301.80
323.52
343.32
185. 43
198.49
211.20
223.44
177.63
182.44
186.30
189.47
1100
126.334
361.51
235.18
192.12
1200
1300
14{){)
1500
16{){)
1700
1800
131.912
136.790
11l1. 100
11l4.93.l
148.369
151.470
154.281
378.32
393.96
ll08. 56
422.27
435.11
447.36
458.91
246.41
257.11
267.46
217.34
286.80
295.89
304.63
194.35
196.25
197.89
199.30
200.53
201.60
202.53
!ELTING POIIIT
BOILIIG POI'IIT
ENTHALPY OF !ELTIBG
kJ
EBTHALPY OF VAPOBIZlTIOB
kJ
!lOLli VOLO!E
-------------------------------1 03.201
-1655.715
-1382.995
-1653.625
-1651.J36
-1648.912
-1344. 169
-1305.619
-1267.332
87.766
75.776
66.199
-1646.401
-1229.303
58.375
-1872.947
-1867.759
-1862.590
-1857.441
-1852.329
-1847.266
-1129.815
-1{)72.839
-1016.230
-959.985
-904.069
-848.410
45.397
40.028
35.388
31.340
27.719
24.620
--------------------------------1878.124
-1187.164
51.676
kJ
4.5580 J;tar
45.580 CIIJ
TBANSITIONS IN BKFERENCE STATE ELEIIEBTS

ZIBC ft. P. 692.7, B. P. 1178 K.
TITABIUft ALPHA-BETA 1155, !. P. 1943 K.
2.6129x1oz - 5.1374x1o-~ T - 2.0949x10
(EQUATION VALID FRO! 298 - 1800 lt)
REF.EBIBC!
21
264
,-os
264
COIIPILBD
a- 2-76
PBOPEITIES AT HIGH TEBPERATDRES

BIOBUGIIITE
AgBr:
FOBBDLA WEIGHT
Crystals 298.15 to eltiag point 703 K.
TEIIP.
so
-( G;-H~ 98 )/T
CDp
J/olK
J/olK
J/olK
0.42
O.ij2
123.42
1J7. 26
1ij9.76
161.31
162.63
109.2ij
113. ij9
118.52
123.81
124.93
( a;-H; 98 )/T
269
J/olK
187.772
FOBBATIOI l"BOB THE BLEilE ITS

GIBBS
PBEE BURGY
Log Kf
EITHALPY
kJ/ol
kJ/ol
--------------------------------------------------------------------------------97.121
17.015
298.15
107. 11
-100.580
0.000
107.11
52.38
DICEBTAIITJ
ij(JO
500
600
700
703
1ij.175
23.172
31.243
37.501
37.700
0.180
0.180
58.94
65.39
71.83
78.27
78.47
0.032
--------------------------------114.82 9
-92.932
12.136
-113.070
-110.727
-107.810
-107.621
-87.650
-82.780
-78.342
-78.387
9.157
7.207
5.8ij6
5.82ij
-------------------------------------------------------------------------------so. 7Jij
12ij.93
-78.387
5.824
703
175.66
62.34
-98.458
800
900
1000
52.142
53.277
54. 183
182.76
190.08
196.65
BELTIIG POIIT
BITBALPY
H;98 -
01"
BELTIIG
703
130.62
136.80
1ij2.46
9.163 kJ
HZ
kJ
62.34
62.3ij
62.34
-97.009
-95.516
-9ij.109
-75.515
-72.888
-70.450
ij.931
4.230
3.680
BOlLI IG POI IT
EITHALPY
lr.J
01"
YAPOIIZATIOI
2.8991 J/bar
28.991 c 3
llOUB YOLUBI
TBAISITIOIS II I&FEBEJCB STATE BLBilBITS

SILVBB B. P. 1234 K.
BBOiliiB B. P. 332 K.
c;
33.169 + 6.44l4x1o-z T
( BQUATIOI YALID PBOil
BBPIIBICB
115
120
215
298 -
703 K)
215
COilP.ILED
6- 2-76
THER!ODYHA!IC PROPERTIES OF MINERALS
27()
POTASSIU! BROIUDE
KBr:
FORMULA WEIGHT
119.002
-------------------------------------------------------------------------------FORMATION FRO! THE ELEIIENTS

TEI!P.
(H;-H~ 98 )/T
J;molK
so
T
J/llolK
-(G;-H~ 98 )/T
Cop
J/mol K
J/mol K
ENTHALPY
GIBBS
FREE ENERGY
Log Kf
kJ/1101
kJ/1101
--------------------------------------------------------------------------------380.061
66.585
298.15
0.000
95.90
-393.460
95.90
52.30
UNCERTAINTY
400
500
600
700
BOO
900
1000
13.550
21.710
27.333
31.594
35.()75
38.089
40.821
0.20
0.20
111.54
123.65
133.76
142.57
150.50
157.83
164.71
97.99
101.94
106.43
110.98
115.42
119.74
123.89
MELTING POINT
53.87
54.79
56.20
58.21
60.75
63.74
67.09
1007
ENTHALPY OF !ELTING
0.180
0.180
25.500 kJ
kJ
0.032
--------------------------------410.879
-410.401
-409.751
-408.897
-407.806
-406.454
-404.813
-371.93()
-362.236
-352.668
-343.218
-333.904
-324.750
-315.746
48.569
37.843
30.703
25.b11
21.802
18.848
16.493
BOILING POINT
1671
149.200 kJ
IIOLAi VOL UI!E
4.3280 J/bar
43.280 CIIJ

POTASSIUII 11. P. 336.4,
BROfliNE
B.
B.
P. 103() K.
P. 332 K.

43.924 +
5.8546x1o-z T

R.EFKBEMCE
247
173
215
298 -
1.7173x103
1000 K)
r-o5
215
COI!PILED
6-29-76
271
STRONTIUM BROMIDE
SrBr 2
TEll P.
fORMULA WEIGHT
Crystals 298.15 to
( H;-H; 98 )/T
JjaolK
ST
247.428
900 K.
-(G;-H~98)/'l
J/molK
J/IIOlK
0.20
0.20
FORMATION FRO II THE ELEMENTS

GIBBS
ENTHALPY
FREE ENEBGY
Log Kf
cop
J/aol K
kJ/mol
kJ/aol
-------------------------------------------------------------------------------298.15
0.000
135.10
135.10
-717.560
-695.908
121.921
75.35
UIIICERTUNTY
o. 850
400
500
600
700
800
19.875
32.016
40.433
46.853
52.157
158.01
175.98
191.02
204.17
.216.09
138.14
143.96
150.59
157.32
163.93
79.69
81.44
83.76
87.15
91.58
900
56.822
227.18
170.36
96.89
0.850
--------------------------------747.032
-745.595
-744.162
-74.2.670
-741.039
-682.375
-666.379
-650.667
-635.204
-619.962
89.109
69.616
56.646
47.400
4u.4t:lO
--------------------------------604.873
-739.886
35.106
MELTING POINT
BOILING POI NT
ENTHALPY OF MELTING
kJ
17.828 kJ
0.149
kJ
5.8310 J/bar
58.310 cm 3
I'!OLAR VOLUME

STROHTIU!!
ALPHA-GABMA 828, !!. P. GAIII'!l 1041, B. P.
1652 K.
BROMINE B. P. 332 K.
-1.2317x10Z + 0.11349 T
REFERENCE
250
.250
3.7012x10~
298 -
r-o5
900 K)
214
COMPILED
7- 1-76
272
TBBR!ODIHlftiC PROPERTIES OP BIIEBALS

PORRULl WEIGHT
TITliiOB TBIBRO!IDB
TiBr 3 :
287.612
crystals 298.15 to 1200 1.
-------------------------------------------------------------------------------POBIIATIOII FRO! THE BLEB EilTS

<u;-u~98 )/T
-(G;-u~ 98 )/T
co
J/oll
J/olK
J/olK
3.35
3.35
600
70(1
800
900
1000
25.750
42.452
55.590
66.63(1
76.189
84.60(1
92.072
206.15
230.48
252.55
273.02
292.11
309.99
326.77
180.40
188.03
196.96
206.39
215.92
225.39
234.70
103.80
115.17
127.27
138.23
147.71
155.81
162.68
1100
98.764
342.56
243.80
168.51
TB!P.
J/olK
so
T
GIBBS
PBBB BURGI
EIITHlLPY
kJ/ol
Loq Kf
kJ/ol
-------------------------------------------------------------------------------298.15
0.000
176.44
-595.380
-570.732
99.990
176.44
101.71
UICEBTliiiTY
400
suo
1200
104.788
357.44
8. 370
8.450
1.480
--------------------------------639.619
-553.109
72.229
-636.924
-633.157
-628.359
-622.655
-616.183
-609.082
-531.779
-511.080
-491.104
-471.876
-453.404
-435.692
55.555
44.494
36.647
30.810
26.315
22.758
-601.459
-418.726
19.884
--------------------------------597.458
-402.309
17.512
252.65
173.46
!BLTIIIG POIIIT
BOlLI IIG POI IT
EITHlLPI OP !BLTIIG
kJ
EITHALPI OP VlPORIZlTIOH
kJ
BOLli YOLO!E
kJ
6. 7800 J/bar
67.800 c 3
TRliiSITIOIIS Ill REPBREIICE STlTB BLBBBIITS

TITliiiU! ALPHl-B!Tl 1155, l!. P. 1943 I.
BBO!IIIE B. P. 332 K.
BElT ClPlCITY EQUlTIOI
c;
3.9749x10Z - 2.6092x10-Z T - 6.9169x103 T-05

(BQUlTIOI VALID PRO! 298 - 1200 K)
IBPIBBICE
141
247
247
1.0014x107 T-Z
COBPILED
6- 2-76
213
PIOPIITIIS lT BIGB TIBPIIlTUIIS

CBLOiliGJBIT.I
lqCl:
POBBULl 81IGBT
crystals 298.15 to aeltiaq poiat 728 1.
11f3.321
-------------------------------------------------------------------------------POIUTIOI PBOB TBI ILl! BITS

TIBP.
soT
( H;-a;98 )/T
J;aolK
-cG;-a; 98 ),rr
cop
JjaolK
JjaolK
J/aolK
GIBBS
IITHlLPY
Pill IlliG I
kJ;aol
Loq 't
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
-109.819
19.240
96.23
96.23
50.79
-127.070
OICIITll IT!
400
500
600
700
728
13.775
22.678
29.1125
33.806
311.932
0.20
0.20
112.08
125.08
136. 15
145.78
148.97
98.30
102.40
107.13
111.97
111f.Oif
56.65
59.70
61.70
63.21
63.81
0.085
0.085
0.015
-125.938
-124.502
-122.900
-121.208
-120.678
-104.086
-98.787
-93.789
-89.071
-88.257
13.592
10.320
8.165
6.647
6.333
-------------------------------------------------------------------------------728
52.634
166.67
111f.04
-88.257
6.333
66.94
-107.791
800
900
1000
53.921
55.368
52.3112
172.34
180.20
187.27
118.1f2
124.81f
131f.93
66.94
66.94
66.94
-106.373
-1011.1f04
-106.706
IILTIIG POIIT
728
IITBlLPY OP IILTIIG
12.887 kJ
IITBlLPY OP YlPORIZlTIOI
12.033 kJ
BOLli YOLOBI
8;98 -
H~
-85.939
-83.482
-85.1f60
5.611
11.81f5
4.461f
BOILIIG POIIT
kJ
2.5727 J/bar
25.727 ca 3
TlliSITIOIS II REPIRIICB STlTI ILIIIITS

S.lLYIB !. P. 12311 K.
HilT CAPACITY IQUATIOI
c;
59.955 + 7.6201z1o- T
(IQDlTIOI YlLID PRO!
IEPUIICI
115
120
215
- 1.0167z10
298 - 728 K)
r-z
215
CO!l'ILID
7- 1-76
214
THER!ODYHA!IC PROPERTIES OF !IHEBALS
HY DBOPHILJ:TE
FORMULA WEIGHT
110.986
crystals 298.15 to aelting point 1055 K.
-------------------------------------------------------------------------------FOBitlTIOH FRO! THE ELE!EJJTS

TEMP.
so
-(G;-u; 98 )/T
cop
J/IIOlK
J/aolK
J/aolK
1.25
1.25
( u;-u; 98 )/T
J/aolK
EHTHlLPY
GIBBS
FREE BURGY
kJ/1101
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
-748.06 3
104.60
104.60
-795.800
131.058
12.59
UHCERTAI NTY
400
500
600
700
18.975
30.528
38.453
41l.273
126.47
143.59
157.!12
170.03
107.49
113.06
119.37
125.76
75.90
77.48
78.64
79.73
800
9(10
1000
48.714
52.40(1
55.434
180.75
190.34
199.05
131.98
137.94
143.62
80.85
82.06
83.37
!ELTING POINT
1055
ENTHALPY OF MELTING
28.368 kJ
k.J
0.650
0.750
0.131
-794.363
-792.949
-791.629
-790.450
-731.971
-716.539
-701.317
-686.437
95.586
74.!157
&1.uo1
51.22J
-789.218
-788.567
-65b.tl01
-64.2.117
38.120
33.541
--------------------------------671.565
43.849
-790.165
BOll. I NG POl HT
ENTHALPY OF VAPORIZAriON
MOLAR VOLUME
kJ
5.0750 J/bar
50. 750 Cll3

CALCIUM ALPHA-BETA 720, M. P" BETA 1112, B. P. 1755 K.
HEAT CAPACITY
E~UATION
6.6490x10- TZ
1.2847x1o T-3
(EQUATION VALID FROM 298 - 1055 K)
76.846 +
REFERENCE
115
169
214
214
COMPILED
6-14-76
275
PBOPEBTIBS AT HIGH TEKPBiATUBES

FORMULA IIBIGHT
LAIIB.EICITE
crystals 298.15 to aelting poiat 950 K.
126.753
1347 K.
-------------------------------------------------------------------------------FOB!lTION FRO! THE ELEl!EITS

TEMP.
K
ca;- a~ 98 )/T
J;aolK
so
-(G;-a~ 98 )/T
cop
J/aolK
J/aolK
J/aolK
0.42
0.42
ENTHALPY
GIBBS
FREE EIEBGI
Log Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------52.939
-302.112
298.15
-341.650
0.000
117.95
117.95
76.32
UNCERTAINTY
0.420
0.420
0.074
37.736
21:1.1:183
23.010
18.833
15.712
13.289
12.290
11.474
400
500
600
700
800
900
950
20.225
32.446
40.643
166.616
51.307
55.244
56.902
141.26
159.41
174.29
186.99
198.23
208.44
213.51
121.03
126.96
133.65
140.37
146.92
153.20
156.61
81.01
81.47
81.90
83.15
85.29
88.26
90.01
-339.749
-338.007
-336.528
-135.262
-334.188
-333.337
-332.832
-288.974
-276.474
-264.307
-252.388
-240.632
-228.965
-223.522
1000
102.173
263.64
161.47
102.17
-289.477
-219.664
1100
102.165
273.34
171.17
102. 17
1200
1300
102.159
102.154
282.21
290.41
180.05
188.26
102. 17
102.17
BOILING POINT
1347
--------------------------------------------------------------------------------223.522
12.290
-289.820
950
102.177
102.17
258.79
156.61
-------------------------------10.098
-212.654
-288.791
-------------------------------8.959
-205.828
-287.239
-284.230
-199.233
8.005
!ELTING POINT
950
ENTHALPY Of !ELTING
43.012 kJ
124.809 ltJ
16.272 ltJ
IIOLAR VOLUME
3.9460 J/bar
39.460 ca 3

liON CUBIE P. 1042, ALPHA-GA!IIA 1184, GA!IIA-DELTA 1665,

-1.1231x1oz +
8.9510x1o-z T
298 -

REFERENCE
169
215
3.7897x103 T-os
950 K)
215
147
COMPILED
7- 1-76
THEBIOD!IA!IC PBOPBBTIIS OP IIIIBlLS
276
IOLYSITI
POBIDLl WEIGHT
605 K.
TIIP.
Ideal gas (diaer) 605 to 700 K.
soT
( H;-a;98 )/T
162.206
JtaolK
J/aolK
POB!lTIOI FlO I THE ILl !BITS

GIBBS
PB!I !IEBGY
Log If
!ITBlLP!
-(G;-a~ 98 )/T
cop
JtaolK
JtaolK
ltJtaol
0.1120
1.420
0.249
123.68
123.68
123.68
-396.840
-393.159
-395.087
-311.729
-290.713
-275.554
40.708
30.377
24.945
ltJtaol
-------------------------------------------------------------------------------298.15
-333.7511
o.ooo
-399.2110
58.473
1112.26
1162.26
911.93
UNCEBTliiTY
400
500
577
25.887
43.220
46.367
0.42
0.42
172.05
197.11
207.97
146.16
153.89
161.60
-------------------------------------------------------------------------------577
121.055
282.66
211.945
-275.554
161.60
133.89
-351.992
600
605
128.352
128.397
294.22
295.23
165.87
166.82
133.89
133.89
-346. 857
-346.647
-272.244
-271.885
23.701
23.474
-------------------------------------------------------------------------------605
164.566
23.474
-324.764
-271.885
331.38
166.82
71.13
700
154.503
3114.51
190.01
71.13
-324.532
-263.199
ll!LTIIIG POINT
577
ENTHALPY OF !ELTIIG
43.095 kJ
EITHlLPY OP VAPORIZATION
8~ 98
19.707 kJ
ftOLlB VOLU!E
H~
BOILIIG POIIT
605
19.640
21.882 kJ
5.7860 J/bar
57.860 cal
TRAISITIONS II REFERENCE STATE ELEftENTS

IRON CURIE P. 1042 1 lLPHl-Gl!ftl 1184 1 GAftftl-DBLTl 1665 1
KElT CAPACITY EQUATION
c;
1.2368x10Z -
2.5564x10Z

BEP!BEIICE
169
215
,-z
298-
577 K}
215
147
COIIPILED
7-24-76
PIOPBB~IBS
lf HIGH
277
~BBPBRl~UBBS
POB!ULl lEIGHT
HJDBOGBI CRLOIIDI
Bel:
36.461
-------------------------------------------------------------------------------POIUTIOI FBOB TBI BLBBBITS

<a;-H~98 )/'l
TB!P.
K
J/aoll
-<~-a~98)/f
SD
'1'
J/aoll
J/aolK
CD
p
GIBBS
FlEE IIBBGJ
Bl'l'HlLPI
J/aoll
Log 'f
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
186.90
-92.312
-95.299
16.&96
o.ooo
29.14
186.90
UICBB'l'liiT!
0.03
0.03
0.130
o.uo
0.023
400
500
600
700
800
900
1000
7.375
11.706
14.663
16.844
18.5411
19.922
21.073
195.41
201.89
207.26
211.87
215.93
219.58
222.89
188.03
190.18
192.60
195.03
197.39
199.66
201.82
28.91
29.22
29.68
30.19
30.69
31.19
31.68
-92.609
-92.952
-93.285
93.596
-93.878
-94.132
-94.362
-96.276
-97.154
-97.963
-98.716
-99.1127
-100.108
-100.762
12.572
10.150
8.528
7.366
6.492
5.810
5.263
1100
1200
1300
1400
1500
1600
1700
1800
22.060
22.921
.23. 684
24.371
24.995
25.568
26.099
26.593
2:.!5.93
228.75
231.38
233.85
236.17
238.38
240.47
242.48
203.87
205.83
207.70
.l09.48
211.18
212.81
214.37
215.89
32.16
32.62
33.07
33.52
33.95
316.38
34.80
35.21
-94.563
-94.744
-94.903
-95.041
-95.161
-95.263
-95.347
-95.416
-101.384
-101.998
-102.599
-103.196
-103.763
-104.336
-104.893
-105.469
4.814
4.440
4.122
3.850
3.613
3.406
3.223
3.061
DLTIIG POIIT
BITBlLPJ OP BBLTIIG
8~ 98
H~
ltJ
8.640 kJ
BOILIIG POIIT
BITBALPY OP VlPOBIZATIOI
kJ
BOLla VOLUBE
2478.9200 J/t)ar
24789.200 ca 3
TlliSITIOIS II BBFBBBICI STlfl BLIBBITS
HilT ClPlCITJ IQUlTIOI
c; =
32.325 + 3.3258z10-~ '1'

(BQUATIOI VlLID FBOB
BBFBBIICB
247
215
1.J590z10Z T-DS
298- 1800 I)
J.28J5z10S '1'-Z
215
CO BPI LID
6- 2-76
278
THEBftODIIAft~C
PIOPBB7IBS 0' ftiiBRlLS
SII.UTE
FORftULA WEIGHT
KCl:
74.551
Liquid 1043 to fictiYe boiling
point 1750 K.
-------------------------------------------------------------------------------FORUTIOI FIOft THE BLBftEWTS

so
<H;-u~98 }/T
TEBP.
K
J;aolK
J/aolK
cop
-(G;-H~ 98 )/T
J/aolK
GIBBS
FREE .BIERGY
EITHlLPY
ltJ/aol
J;aolK
Loq Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
82.59
-436.470
-408.554
71.577
82.59
51.29
UIICEaTAIBTY
o. 20
0.20
0.140
0.140
400
500
600
700
800
900
1000
13.375
21.506
27.145
31.411
34.872
37.833
40.482
98.01
110.06
120.15
128.93
136.82
144.07
150.84
84.63
88.55
93.00
97.52
101.95
106.24
110.36
53.41
54.611
56.11
57.99
60.27
62.87
65.7&
1043
41.6110
153.95
112.31
b7.Q7
1100
1200
1300
1400
1500
1600
1700
67.191
67.725
68.177
&8.564
68.899
69.193
69.452
182.80
189.20
195.10
200.54
205.&0
210.37
214.80
115.61
121.117
126.92
131.97
136.70
141.18
1115.35
66.94
66.94
66.94
66.94
66.94
66.94
66.94
0.025
--------------------------------398.638
-438.418
52.057
-1137.908
-1137.221'1
-436.356
-1135.275
-433.9711
-432.428
-388.7113
-378.979
-369.331
-359.828
-350.480
-341.278
40.612
32.993
:.!7.560
23.494
20.341
17.827
-483.160
-479.761
-476.364
-1172.973
-469.583
-466.198
-462.816
-329.331
-315.497
-301.955
-288.646
-275.576
-262.786
-250.1211
15.639
13.733
12.133
10.770
9.596
8.579
7.685
--------------------------------511.382
-336.959
16.875
-------------------------------------------------------------------------------10113
66.841
179.15
-336.959
16.875
112.31
66.94
-1185.098
I'IELTIIIG POIIIT
1043
BOILIHG POIIT
1750
26.284 kJ
EHTHALPY OF VAPORIZATIOH
155.394 kJ
H~98
11.368 kJ
I!OLAR VOLUME
3.7524 Jjbar
37.524 cm 3
H~
TBliSITIOHS Ill BEFEBEIICE STATE ELEIIEHTS

POTASSIUM ft. P. JJo.ll, B. P. 1030 K.
24.516 + 4.8522x1o-z T
1.3710x103
(EQUATION VALID FROM 298 - 1043 K)
REFERENCE
247
173
215
1. &054x 1 o T- z
r-os
215
COI!PILED
5-28-76
PBOP!ITI!S lT HIGH T!BP!BlTUB!S
CHLOBOBlGI!SU'!
279
POiBOLl IIBIGHT
95.211
1710 K.
-------------------------------------------------------------------------------POBBlTIOI PBOJI TB! !L!JIEIJTS

TEIIP.
( a;-a~ 98 )/T
J;aolK
so
T
J/aolK
-< G;-a~ 98 )/T
co
JjaolK
Jjaol K
!IJTBlLPY
GIBBS
PBEB EIIIEBGY
Log Kf
ltJjaol
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
89.62
71.04
-641.320
-591.785
89.62
103.679
UICEBTliHTY
0.84
0.84
400
500
600
700
800
900
18.750
30.394
38.508
44.529
49.205
52.967
111.22
128.39
142.80
155.23
166.17
175.96
92.47
98.00
104.29
110.70
116.97
122.99
75.64
78.17
79.93
81.33
82.53
83.63
987
55.798
184.01
128.21
84.52
0.460
o. 544
0.095
-639.951
-638.495
-637.004
-b35.515
-634.042
-632.5911
-575.067
-559.015
-543.254
-5.27.749
-512.458
-497.354
75.096
58.400
47.295
39.381
13.460
28.866
--------------------------------483.881
-640.229
25.608
-------------------------------------------------------------------------------987
99.461
227.67
128.21
92.47
-597.134
-483.881
25.608
1000
99.370
228.82
129.45
92.47
-596.844
-48.2.356
25.196
1100
1200
1300
98.743
98.219
97.771
237.65
245.68
253.09
138.91
147.46
155.31
92.47
92.47
92.47
-594.610
-592.389
-590.174
-471.025
-459.876
-448.928
22.367
20.018
18.038
1400
1500
1600
1700
97.398
97.069
96.781
96.527
259.91
266.31
272.29
277.90
162.51
169.24
175.51
181.37
92.47
92.47
92.47
92.47
-711.544
-708.167
-704.798
-414.633
-394.956
-375.491
14.439
12.894
11.537
!ELTIIG POIRT
987
ENTHALPY OP BELTING
--------------------------------434.507
-714.928
16.212
BOILIIIG POIRT
1110
43.095 kJ
156.230 kJ
13.770 kJ
BOLl.li. VOLUB!
4.0810 J/bar
40.810 cal
TBlHSITIOHS IH BEFEB!HC! STATE ELEBEHTS

ftlGH!SIUB II.. P. 922, B. P. 1361 K.
8.4955x10- J T
76.903
.li.EPEBEHCE
169
120
247
298-
987 K)
214
247
COitPILED
6- 9-76
THIIIODIIlllC PIOPIITIIS OF llllllLS
280
POIBULl IIIGBT
SClCCBI1'1
CrJstals 298.15 to aeltiag poiat 923 l.
125.844
Liqaid 923 to 1400 1.
-------------------------------------------------------------------------------POUUIOI PIOI TBI ILIIIIITS

TIIIP.
soT
<a;-a;98 )/T
J;aoll
J/aoll
-(G;-a; 98 )/T
cop
J/aolK
J/aoll
IITHlLPI
GIBBS
PBII IlliG!
kJ/aol
Log 't
kJ/aol
-------------------------------------------------------------------------------298.15
118.24
o.ooo
118.24
-481.290
-440.488
11.112
73.01
OICIITli ITI
400
500
600
700
800
900
923
19.175
31.068
39.357
45.529
50.352
51f.267
55.167
0.21
o. 21
140.35
157.88
172.61
185.33
196.56
206.616
209.60
121.17
1.26.81
133.25
139.80
146.21
152.37
154.114
77.25
79.80
81.73
83.37
84.85
86.24
88.56
0.837
0.879
0.15lt
-lt79.930
-478.557
-477.211
-475.898
-474.610
-1673.332
-472.767
-426.762
-413.622
-400.765
-388.124
-375.674
-363.388
-361.187
55.730
43.211
34.890
28.962
24.529
21.091
20.4160
-------------------------------------------------------------------------------923
95.828
250.26
-361.187
20.1640
154.416
916.56
-1657.696
-------------------------------1000
95.730
257.19
161.166
-1636.085
-354.396
18.512
94.56
1100
1200
1300
95.624
95.535
95.459
266.19
274.43
282.00
170.56
178.89
186.54
94.56
94.56
94.56
1400
95.395
288.99
193.59
94.56
-4lll. 169
-432.306
-430.1195
-346.296
-338.405
-330.657
16.41616
14.730
13.286
-------------------------------12.050
-1631.014
-322.961
IIILTIIG POUT
923
BOILIIG POIIT
EITBlLPI OP BELTIIG
31.530 kJ
BITHlLPI OP YlPOIIZlTIOI
kJ
15.071 kJ
!lOLli YOLOIIE
a;98 -
R~
4. 2110 J/bar
112.110 ca 3
TBliSITIOIS II BBPBRBICE STATE ILBIEITS

lliGliBSB 1LP81-BET1 980, BETl-Glllll 1360 1 G1Ba&-DBLT1 1410,
!. P. DILTl 1517 1.
HilT ClPlCITI EQUlTIOI
c; = 76.261
(EQUlTIOI YlLID PIO!l
IBPEIBICB
169
34
298-
923 I)
2111
147
COBPILBD
6- 9-76
281
PIOPEBTIBS Ar HIGH TBIJPEilTOIBS

POR!U.Ll lEIGHT
Sl.Lliii!IOIIlC
NH 4 Cl:
TB!P.
I
53.1691
llpha crystals 298.15 to 1657.7 1. Beta crystals 1657.7 to eltiaq poiat

793.2 1. Decopositioa teperature (fro differeatial theral analysis)
is 611.4 K.
(a;-a~ 98 )/T
J;oll
-(G;-H~g 8 )/T
cop
J/oll
J/oll
J/oll
0.160
0.40
SD
T
POR!lTIOI PBO! THE ELB!EITS

GIBBS
BIUl.LPI
PBBB EIBBGI
Log If
kJ/ol
ltJ/ol
-------------------------------------------------------------------------------35.701
298.15
95.02
-315.190
-203.716
o.ooo
95.02
86.65
UIC!BTliNTI
1600
1657.7
24.172
316.470
122.80
1.37.06
98.63
102.59
102.97
110.65
0.290
0.290
0.051
-3111.694
-313.810
-165.7118
-145.435
21.6115
16.598
----------------------------------------------~---------------------------------
457.7
500
600
163.099
166.920
55.117
1165.69
153.169
170.98
102.59
106.57
115.86
86.03
90.50
101.67
-309.860
-310.002
-309.556
-145.435
-129.015
-92.837
16.598
13.1178
8.082
700
62.563
187.49
1211.92
112.80
-308.062
-56.822
16.240
BELT:UG POIIfT
793.20 l
!ITHlLPI OF !B.LTIIG
kJ
22.698 ltJ
BOILIIG POI IT
!ITHl.LPI OP YlPOBIZlTIOI
kJ
3.5060 J/bar
35.060 c 3
I!IOLll YOLO!B
TBliSITIOIS II BBPBBBICB STlTB BLB!EITS
B!PBBBICB
2117
215
215
COIIPILBD
7-21&-76
282
THERMODYNA8IC PROPERTIES OF 8INERALS
HALITE
NaCl:
FORIIOLA WEIGHT
Crystals 298.15 to melting point 1073.8 K.
58.443
Liquid 1073.8 to fictive
-------------------------------------------------------------------------------FORIIATION FRO II THE ELEMENTS

TEMP.
so
-(G;-H~g 8 }/T
cop
J/11olK
J/11olK
J/llol K
0.21
0.21
{H;-H~ 98 )/T
J;aolK
ENTHALPY
GIBBS
FREE ENERGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
72.12
7 2.12
-411.260
-384.212
67.313
50.51
ONCERTAIIITY
o. 110
400
500
600
700
800
900
1000
1073.80
13. 100
21.124
26.775
31.070
34.515
J7 .3 89
39.877
41.702
87.22
99.09
109.12
117.88
125.71
132.82
139.37
144.11
74.12
77.97
82.34
86.81
91.20
95.43
99.49
102.41
1100
67 .. 934
171.89
103.96
68.46
1200
1300
1400
1500
1600
1700
67.964
67.965
67.943
67.903
67.847
67.779
177.83
183.27
188.29
192.93
197.26
201.30
109.87
115.30
120.35
125.03
129.41
133.52
68.14
67.82
67.50
67.17
6o.as
66.53
52.34
54. 14
55.94
57.73
59.53
61.33
63.12
64.45
0.110
0.019
--------------------------------413.461
-374.837
48.949
-413.024
-412.352
-411.456
-410.352
-409.0b4
-407.593
-380. 693
-365.229
-355. ho
-346.356
-337.136
-328.064
-319.133
-313.098
38.155
30.969
25.846
22.013
19.040
16.670
15.231
-377.51.7
-310.967
14.767
-472.918
-470.082
-467.285
-464.521
-4o1.794
-459.103
-302.951
-288.905
-275.089
-261.445
-248.002
-234.720
13.187
11.608
10.264
9.104
8.096
7 .212
-------------------------------------------------------------------------------1073.80
67.925
170.33
102.41
-352.535
-313.098
15.231
68.55
IIELTIIiG POINT
BOILING POIIIT
1791
28.158 kJ
164.787 kJ
10.611 kJ
IIOLAR VOLU8E
2.7015 Jjbar
27.015 c11 3
1073. 8
--------------------------------

SODIUII II. P.
370.98, B. P.
1175 K.
c~
c~
45.151+ 1.7974x1o-zT
298- 1073.8 K)
72.008 3.2228x10-;J T
{EQUATION VALID FROft 1073.8
REFERENCE
247
215
1791 K)
215
COI!PILED
6- 2-76
PBOPEBTIES AT HIGH TEliPEBlTUBES
NICKEL CHLOIIDE
NiC1 2 :
283
FOBliULA WEIGHT
129.606
-------------------------------------------------------------------------------FOBliATION FRO!! THE ELEI!ENTS

TEI!P.
K
so
(H;-9~9 8 }/T
J/aolK
-(G~-H~ 98 )/T
J/aolK
J/IIOlK
0.21
o. 21
Cp
ENTHALPY
J/mol K
GIBBS
FREE ENERGY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
97.66
71.67
45.381
o.ooo
97.66
-305.330
-259.030
UIICEBTlllfTY
400
500
600
19.150
30.888
38.840
119.71
137.09
151.41
100.56
106.20
11.2.57
77.20
78.33
78.88
700
800
900
1000
44.616
49.082
52.733
55.853
163.63
174.36
184.01
192.85
119.01
125.28
131.28
137.00
79.73
81.05
82.86
85.10
1100
1200
1300
58.628
61.172
63.562
201.08
208.84
216.22
142.45
147.67
152.66
87.72
90.65
93.87
I!ELTIIIG POINT
o.o8o
0.014
-303.987
-302.727
-301.768
-243.411
-228.422
-213.65.2
31.786
23.863
18.600
-.299.586
-.298.256
-296.846
-184.578
-170.285
-156.136
12.052
9.883
8.156
-.295.313
-293.610
-291.684
-142.138
-128.286
-114.584
6.750
5.584
4.604
--------------------------------199.030
14.852
-300.831
BOILING POINT
77.280 kJ
kJ
14.385 kJ
I!OLAB VOLUl!E
1303
0.080
3.6700 J/bar
36.700 ca 3
TRANSITIONS IN BEFEBEHCE STATE ELEI!EHTS

HICKEL CURIE P. 631, 1!. P. 1726 K.
50.781 + 5.7481x10-2 T
2.6078x103
{EQUATION VALID FROl! 298 - 1303 K)
BEPEBEHCE
40
263
,-os
263
CO.IIPil.ED
6- 2-76
2811
THER!ODYIA!IC PROPERTIES OP aiNERALS

FOR!ULA WEIGHT
COTUINITE
278.106
================================================================================
-------------------------------------------------------------------------------PORftlTION FRO! THE !LEft BITS

TE!P.
so
-< G;-a~98 ).IT
J/aolK
J/aollt
2.09
2.09
( a;-a~ 98 ).1T
J/aolK
cop
BITBlLPY
GIBBS
FREE BURGY
Jfaollt
Log ltf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
55.017
o.ooo
135.98
-359.400
-314.033
135.98
73.15
UNCERTAINTY
400
500
600
19.550
32.110
111.130
158.50
176.85
192.56
138.95
11111.711
151.113
79.95
84.118
87.82
700
768
117.993
51.698
206.30
215.07
158.31
163.38
90.42
91.89
0.293
0.711
0.125
-357.861
-355.979
-353.871
-298.761
-284.1911
-270.027
39.014
29.690
23.508
--------------------------------255.432
19.061
-356.470
-354. 936
-2115.970
16.729
-------------------------------------------------------------------------------768
82.752
-331.087
-245.970
16.7 29
246.13
163.38
113.80
800
900
1000
83.9911
87.306
89.956
250.41
163.80
275.77
166.42
176.50
185.81
113.80
113.80
113.80
BOILIIG POINT
KELTING POINT
768
ENTHALPY OF !tELTIIG
23.849 kJ
16. 941 kJ
-329.592
-324.920
-320.229
-242.234
-231.581
-221.436
EHTHALPI OP YAPOBIZATIOH
15.816
13.441
11.567
kJ
4.7090 J/bar
117.090 cal
ftOLlB YOL UIIE
TBAHSITIOIS II BEPEBEICB STATE ELB!EJTS

LEAD ft. P. 600.6 9 B. P. 2021 K.
c;
1.2287x10Z - 8.5847x10Z r-os

(EQUATIOJ YALID PIOII 298 -
BIPEBEICE
115
120
215
768 lt)
247
215
CO!PI.LBD
6- 9-76
285
PBOPBKTIES lT HIGH TEftPBRlTOBBS

FOR!ULA lEIGHT
TI!liiU! TRICHLORIDE
TiC1 3 :
= TiC1 3
154.259
The free energy for the reaction TiC1 3 (c)
(q) approaches zero at 1104.1 K.
-------------------------------------------------------------------------------FOBUTIOII FRO! THE ELB!EIITS

TB!P.
K
JfaolK
GIBBS
FREE BIJEBGI
so
-(G;-a~ 98 )/T
cop
JtaolK
J/aolK
JtaolK
kJ;aol
4.180
5.020
0.879
-719.646
-717.680
-715.757
-713.870
-712.009
-710.173
-708.371
-631.862
-610.145
-588.822
-567.801J
-5117.071f
-526.573
-SU6. 271
82.513
63.742
51.262
142.371
35.720
30.562
26.445
-706.592
-486.142
23.085
<a;-a~ 98 )/T
EIIITHlLPI
Loq Kf
kJ/aol
-------------------------------------------------------------------------------114.667
298.15
97.16
-654.507
o.ooo
139.75
139.75
-721.740
UICEBTll HTI
1.26
1.26
400
500
600
700
800
900
1000
25.025
40.030
50.285
57.790
63.560
68.167
71.942
168.61
190.93
209.1f5
225.29
239.17
251.54
262.70
143.58
150.90
159.16
167.50
175.61
183.37
190.76
99.26
100.87
102.22
103.41
104.49
105.49
106.43
1100
75.118
272.89
197.77
107.33
1200
77.838
282.26
204.42
108.19
It
BOILIIG POIIT
EITBALPI OP !&LTIIG
kJ
EITHALPI OP VlPOBIZlTIOI
&~ 98 - H~
tJ
!OLlR VOLUU
!BLTIIG POUT
-------------------------------20.285
-466.021
-708.896
kJ
s. 7300
57.300
J/bar
ca 3
TBliSITIOIS II BBPIBEIICE STlTE ELE!BITS

TITliiOB lLPHl-BETl 1155, !. P. 1943 K.
BElT ClPlCITI EQOlTIOI
c;
1.0609z10~ + 6.2428&10-3 T 1.8660z1o

(EQOlTIOI VlLID PROB 298- 1200 K)
IIPBBBICB
141
247
r-o
247
COIIPIJ.BD
6- 2-76
THE&!ODYHABIC PROPERTIES OF BIHERALS
286
URAHIU! TRICHLORIDE
ucl,:
FOR!DLA WEIGHT
344.3ij8
-------------------------------------------------------------------------------FOR!ATIOII FROB THE ELE!IEIITS

TE!P.
so
-(G;-a~ 98 );T
cop
J/molK
J/aolK
J/aolK
o. 40
0.40
( H~-H~ 98 )/T
J;molK
BITHALPY
GIBBS
ENERGY
FREE
lr.J/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------144.330
298.15
o.ooo
158.95
-891.190
-823.820
158.95
101. 7J
UNCEBTAI!fTY
4.000
5.000
0.876
-888.957
-886.81:12
-885.031
-883.364
-881.785
-880.223
-800.997
-779.257
-757.910
-736.854
-716.025
-695.417
104.600
81.409
65.982
54.985
46.752
40.361
400
500
600
700
800
900
26.125
41.912.
52.643
&0.569
66.891
72.;.78
188.69
212.14
.231. 52
248.18
263.01
276.60
162.57
170.23
178.88
187.61
196.12
204.32
104. 2 3
105.71
107.02
109.43
113.09
117. 92
1000
77.130
289.32
212.19
123.75
IIELTING POINT
BOILIJG POI!fT
lr.J
ENTHALPY OF VAPOBIZATIO!i
kJ
kJ
IIOJ.AB VOI.UftE
--------------------------------674.803
35.248
-881.003
6.2040 Jjbar
62.040 c11 3
TBAHSITlOHS II REPEBEHCB STATE ELE!ENTS

UBAHIU! ALPHA-BETA 941, BETA-GA!ftA 1048, !. P. 1405 K.
HEAT CAPACITY EQDATIOH

0.13399 T
(EQDATIOH VALID FRO!
-1.7529x102 +
BEPBREJCE
70
70
5.4565x10' T-os
298 - 1000 K)
89
233
CO!.PILBD
7- 1-76
287
PROPERTIES AT HIGH TE!PEBATUBES

URAHIU! TETRACHLORIDE
ucl.:
FORMULA lEIGHT
Crystals 298.15 to
379.841
700 K.
-------------------------------------------------------------------------------POBBATIOII FROB THE ELEI!EUS

GIBBS
lBEB BURGY
-(G;-a~ 98 }/T
co
J/IIOlK
J/aolK
J/aolK
0.50
0.50
233.05
2b1.90
286 .21
307.50
201.42
210.73
221.33
232.15
127.29
131.32
135.62
140.87
IIELT l!IG POIIIT
BOILIIIG POIIIT
lr.J
EHTBALPY OF VAPOBIZATIOII
kJ
BOLAR YOLO!E
TEI!P.
ca;-a; 98 )/T
JfaolK
ST
EIITHALPY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
162.731
o.ooo
196.60
196.6 0
119.89
-1018.390
-928.850
UHCERTAIHTY
4{)0
500
600
700
31.62 5
51.174
64.878
75.347
3.000
3.000
0.526
-1015.723
-1013.001
-1010.255
-1007.420
-898.855
-869.951
-841.596
-813.708
117.379
90.884
73.268
.60.720
lr.J
1. 7600 J/bar
17.600 ca 3
TBAIISITIOIIS IH BEPEBEHCE STATE ELE!EBTS

UBAIIIUB ALPHA-BETA 941, BETA-GA!!A 1048, ft. P. 1405 K.

80.231 + 0.12983 T
(EQOATIOIIVU.IDFIO!
BEPEBBIICE
10
10
3.6987x103 T-os
298- 700K}
89
233
COMPILED
8-17-76
THEB!ODYHl!IC PROPERTIES OF BIHERlLS
288
VANADIUB DICHLORIDE
POB!OLA WEIGHT
121.847
-------------------------------------------------------------------------------POBIIlTIOIII !'BOB THE ELE!EHTS

(H;-H~ 98 )/T
TE!P.
J/molK
so
T
-(G;-H~ 9 a)/T
cop
J/aolK
J/aolP.:
J/aol K
1.26
1.26
EliTHALPI
GIBBS
PBEB EIIERGY
k.J/aol
Log Kf
kJ/11101
-------------------------------------------------------------------------------298.15
0.000
97.07
97.07
-451.870
-405.681
71.074
72.20
UNCERTAINTY
8. 500
1.489
-450.498
-449.107
-447.691
-446.246
-444.713
-443.272
-441.761
-390.118
-375. 177
-360.523
-346.104
-331.901
-317.884
-304.031
50.944
39.195
31.386
:l5.827
21.671
18.450
15.881
-440.231
-438.695
-437.158
-290.323
-276.766
-.263.335
13.786
12.047
10.581
8.500
4(10
500
600
700
800
'.:100
1000
18.775
30.228
38.118
43.949
48.479
52.144
55.189
118.73
135.68
149.82
161.98
172.69
182.28
190.98
99.95
105.45
111.70
118.03
124.21
130.14
135.79
75.06
76.84
78.27
79.57
80.81
82.03
83.24
1100
1200
1300
57.794
60.(165
62.081
198.97
206. 37
.213. 28
141.18
146.3(1
151.20
84.45
85.66
86.87
BELTING POIHT
BOILING POINT
ENTHALPY OF BELTING
kJ
kJ
H~98
k.J
!lOLA R VOL Ull E
Jjbar
H~
TRANSITIONS IN REFERENCE STATE ELEftEHTS

VlHADIUII !. P. 2175 K.
HEAT CAPACITY EQUlTIOH
c~ ..
66.755 +
1.3045z1o-z T
( BQUAUOH Y ALID FROB

BEPBBBHCE
125
120
1.2465z10Z T-OS
298 - 1300 K)
264
COIIPILED
5-28-76
289
PIOPEBTIBS AT HIGH TBBP!IlTUIBS

VAIADIUB TBICBLOBIDB
YC1 3 :
FOBBULA i!IGBT
crystals 298.15 to
157.300
900 K.
-------------------------------------------------------------------------------FOBIIlTIOI PRO II 'lBB EJ.BKBI'l'S

TBIIP.
K
sa
<u;-a~ 98 )/T
J/aolK
-(G;-u; 98 )!'l
J/aolK
J/aolK
cap
Bl'lBlLPI
J/aolK
GIBBS
FIB! BIBBGY
Log Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
-511.399
89.595
o.ooo
130.96
130.96
93.16
-580.740
UICBRTUITY
0.850
0.850
0.149
-578.834
-516.764
-574.579
-572.3119
-570.120
-567.935
-487.994
-465.524
-443.480
-421.800
-400.449
-379.376
63.726
48.633
38.609
31.1675
26.147
22.018
1.70
1. 70
159.21
181.67
200.52
216.72
230.91
243.5(1
134.68
141.92
150.16
158.53
166.71
174.56
98.88
102.26
104.41
105.79
106. 64
107.11
IIELTIMG POIRT
BOILIIG POIIT
EITHALPY OF IIELTIIG
kJ
ENTHALPY OP VlPOBIZATIOI
kJ
kJ
IIOLlB VOLOBB
4(10
5(10
600
7(10
800
900
24.525
39.752
50.362
58.189
64.196
68.944
5. 448(1 J/bar
54.480 ca 3
TlliSITIOIS II BEPEREICE STATE ELEftBITS

fliADIOB ft. P. 2175 K.
HBlT CAPACITY EQOATIOI

148.86
1.J301z10-Z T
8.9326I102 T-os
(EQUATION VALID PIOB 298 - 900 K)
B!P!BEICE
125
120
264
COBPILED
6-29-76
290
THEBIIODYiliiiC PROPEBTIES OF ftiJER.lLS
ALUIIIHUII TRIFLUORIDE
AlF~:
PORIIULA liElGHT
83.977
The
dissociation temperature is 1549 K.
-------------------------------------------------------------------------------FORIIATIOH FRO II THE ELEIIEHTS

TEIIP.
H~-8~ 98 )/T
J/aolK
so
J/aolK
-(G;-a~ 98 )/T
cop
J/molK
J/aolK
UTHALPY
GIBBS
FREE ENERGY
Log Kf
kJ/mol
kJ/aol
-------------------------------------------------------------------------------298.15
-1431.076
0.000
66.48
-1510.400
250.720
66.48
75.13
UNCEBTAIBTY
0.42
0.42
1.300
1. 300
0.228
400
500
600
700
728
20.750
34.422
44.495
52.577
54. 442
90.34
110.21
127.49
143.06
147.97
69.59
75.79
82.99
90.48
93.52
86.07
92.00
97.8.2
104.48
106.52
-1509.575
-1508.342
-1506.806
-1504.895
-1504.252
-1404.081
-1377.849
-1351.895
-132b. 220
-1319.660
183.355
143.944
117.&93
98.9&4
94.687
800
900
5';1.237
63.700
157.22
168.93
97.98
105.23
98.88
99.87
-1502.743
-1501.479
-1300.856
-1275.706
84.938
74.040
1000
67.364
179.50
112.14
100.87
1100
1200
1300
1400
1500
70.455
73.113
75.439
77.507
79.359
189.16
198.07
206.34
214.07
221.34
118.71
124.96
130.90
136.56
141.98
101.86
102.85
103.85
104.84
105.83
-1509.672
-1508.259
-1506. 7tH
-1505.233
-1503.621
-1223.864
-1197.965
-117 .l. 136
-114b.454
-1120.895
58.117
52.14b
47.097
42.775
39.033
1700
82.591
84.(120
234.70
240.90
152.11
156.88
107.82
1 Oll.ll1
-1500.174
-1498.339
-1070.092
-1044.848
32.880
J0.321
-------------------------------------------------------------------------------728
55.265
-1319.660
148.79
98.16
-1503.653
94.687
93.52
--------------------------------1249.924
-1511.024
65.290
--------------------------------------------------------------------------------1095.438
1600
81.045
-1501.935
35.763
228.20
147.15
106.83
1800
IIELTI!IG POINT
BOILIIIG POI NT
ENTHALPY OP MELTING
k.J
kJ
MOLAR VOLUIIE
kJ
2.6150 Jjbac
2&.150 CIIJ

ALUIIINUM II. P. 933 K.

-1.461Sxtoz +
c~
o.15u39 T
4.153bx10~
298-
728 K)
9.9J37x1o-~ T
(EQUATION VALID PROII
728 -
1800 K)
T-os
90.932 +
REFERENCE
51
1!:i1
247
215
247
215
COli PILED
8-11-76
PROPERTIES AT HIGH T.B!PERATUR.ES
291
l"LUOIUTE
l"OBI'IULl lEIGHT
crystals I 298.15 to transition point 1424 K.
elting point 1691 K.
78.077
crystals II 1424 to
-------------------------------------------------------------------------------POiii'IATIOB PROI'I THE ELEI'IEBTS

TEIIP.
so
-(G;-H~ 98 )/T
cop
J/olK
J/olK
J/olK
o. 34
0.34
(H;-H~ 98 )/T
J/olK
EIIITHlLPJ
GIBBS
.P'REE ENERGY
Log Kf
ltJ/aol
lr.J/ol
--------------------------------------------------------------------------------1176.920
298.15
206.192
0.000
68.87
68.87
68.59
-1229.260
UBCE.BTli BTI
0.420
0.420
0.074
-1227.845
-1226.375
-1224.961
-1223.625
-1159.245
-1142.270
-1125.583
-1109.126
151.383
119 .H3
97.991
82.764
-1221.729
-1220.523
-1076.550
-1060.493
62.482
55.395
-1219.416
-1044.549
49.602
-1011.765
-995.722
-992.219
40.653
37.151
3b.396
400
500
600
700
18.300
29.710
37.678
113.673
89.94
106.75
120.88
133.15
71.64
77.04
83.20
89.118
74.09
76.50
78.54
80.80
800
900
1000
48.474
52.522
56.068
144.11
154.10
163.37
95.64
101.58
107.30
83.42
86.39
89.68
1100
59.283
172.09
112. 8 1
93.24
1200
1300
11100
1424
62.268
65.0911
67.807
68.402
180.36
188.28
195.92
198.05
118.09
123.19
128. 11
129.65
97.02
101.01
105. 17
10~.19
-1222.11111
-1218.574
-1217.706
1500
1600
1&91
74.363
77.1156
80.057
207.44
215.43
222.42
133.08
137.98
142.36
123.68
124.73
125.68
-1208.715
-1203.106
-11811.042
-980.240
-965.194
-952.223
311.135
31.510
..!9.414
-1167.850
-950.673
29.211
-------------------------------71.351
-1223.080
-1092.768
--------------------------------1028.083
44.751
-1225.326
-------------------------------------------------------------------------------1424
71.722
-1212.978
-992.219
36.396
201.37
129.65
122.88
-------------------------------------------------------------------------------1691
29.414
97.624
239.99
-1154.336
-952.223
142.36
1 oo.oo
1700
97.635
240. so
142.86
1 oo.oo
1800
97.743
2116.19
148.115
100.00
BOILING POIIIT
ENTHALPY OF VAPO.BIZATIOII
kJ
!IELTIIIG POIIIT
EIITUA~PY
1691
OP I'IELTIIIG
29.706 kJ
kJ
--------------------------------934.620
27.122
-1318.202
2.45112 J/bar
24.5112 CIIIJ
!IOLlR VOLUIIE
TRAHSITIOIIS Ill BEPBBEICE STATE ELEI'IEBTS

CALCIUI'I ALPHA-BETA 720, 1'1. P. BETA 1112, B. P. 1755 K.

24.692 +
5.8095x10-2 T

REFERENCE
175
215
1.8706x10~
T-os
298- 1424 K)
215
COMPILED
b-15-76
THEI!ODIJlKIC PBOPEITIES OP !IIIIlLS
292
SELLllTE
FOB!ULl lEIGHT
Crystals 298.15 to elting point 1536 K.
62.302
-------------------------------------------------------------------------------FOIUTIOI FlO! THE ELE!ERTS

TEftP.
soT
( a;-a~ 98 )/T
J/olK
J/olK
-(G;-a~ 98 )/T
cop
J/olK
JtolK
EJTHALPI
GIBBS
FlEE EIEIGI
Log Kf
ltJ/ol
ltJ/ol
--------------------------------------------------------------------------------1071.064
187.6117
298.15
o.ooo
57.25
-11211.200
57.25
61.59
UMCERTliiCTI
(1.42
0.42
900
16.7(1(1
27.520
35.225
41.029
45.587
49.289
76.118
92.26
105.70
117.39
127.73
137 .OJ
59.78
64.74
70.118
76.36
82.14
87.74
68.75
72.46
74.90
76.73
78.24
79.56
1000
52.378
145.47
93.09
80.76
1100
1200
1300
55.010
57.295
59.310
153.22
1b0.39
167.08
98.21
103.10
107.71
81.89
82.97
84.01
11100
1500
1536
61.107
b2. 737
61.233
173.34
179.24
181.66
112.23
116.50
118.42
85.02
86.01
87.02
1600
1700
1800
100.8311
100.1165
100.137
223.19
228.92
234.36
122.35
1.28.45
134.22
94.56
94.56
94.56
1100
500
600
700
BOO
1.200
1. 200
0.210
-1123.403
-1122.369
-1121.261
-1120.140
-1119.031
-1117.949
-1053.027
-1035.549
-1018.289
-1001.217
-984.296
-967.523
137.512
108.184
88.650
74.712
64.268
56.154
--------------------------------950.106
49.629
-1125.846
-1124.715
-1123.501
-1122.204
-932.578
-915. 170
-897.863
411.285
39.836
36.017
--------------------------------1247.790
-817.055
32.723
-1245.141
-121111.243
-850.670
-841.187
29.623
28.606
-1183.837
-1180.324
-1176.827
-827.257
-805.082
-781.182
21.001
24.717
22.727
-------------------------------------------------------------------------------1516
101.096
219.52
-1186.085
-841.187
28.606
118.42
911.56
llELTIMG POINT
EMTHALPI OF llELTIMG
1536
58.158 kJ
9.983 ltJ
BOIL.IIG POI!IIT
2630
EITHALPY OF YlPOBIZATIOB
240.162 kJ
KOLlll YOLO!!
1.9610 J/bar
19.610 c 3
TIIAMSITIOMS IM REFEIIEMCE STATE ELE!EITS

ftAGBESIOil ft. P. 922, B. P. 1361 K.
c;
9.1200z1Q-3 T
(EQUATION YlLID FRO It
72.887 +
REFERERC!
175
247
1.2460z10 T-z
298 - 1536 K)
215
CO!PILBD
6- 9-76
PBOPIBTIBS lT HIGH TI&P.BBlTUBIS

POBIIUU IIBIGBT
fiLLilUIIITI
HaP:
293
Crystals 298.15 to eltiaq point 1269 K.
41.988
-------------------------------------------------------------------------------POBIIUIOI PBOII THE BLBIIIITS

TBIIP.
(a;-a~ 98 )/T
J/aolK
J/olK
soT
-(G;-a~ 98 )/T
cop
J/oll
J/oll
DTBALPI
GIBBS
PBEE EIBBGI
Loq Kf
ltJ/ol
ltJ/ol
--------------------------------------------------------------------------------546.319
95.713
-576.550
298.15
o.ooo
51.30
51.30
46.85
UICBBTliiTI
0.08
0.08
400
500
6(10
700
800
900
1000
12.350
19.980
25.292
29.287
32.481
35.167
37.507
65.54
76.80
86.25
94.45
101.77
108.44
114.61
53.19
56.82
60.96
65.16
69.29
73.27
71.10
49.72
1100
39.616
120.40
80.78
61.81
51.18
52.53
54.02
55.71
57.58
59.63
1200
1269
41.562
43.067
125.87
129.83
84.31
86.76
64.12
65.77
1269
1300
1400
1500
1600
1700
1800
69.179
69.165
69.121
69.017
69.042
69.011
68.983
155.94
157.51
162.58
167.31
171.73
175.88
179.80
86.76
88.35
93.46
98.23
102.69
106.87
110.82
68.51
68.51
68.51
68.51
68.51
68.51
68.51
IIELTIIG POIIT
1269
BITHlLPJ OP IIELTIIG
33.137 ltJ
8.485 ltJ
0.670
0.670
0.117
--------------------------------535.833
69.973
-578.927
-578.665
-578.236
-577.641
-576.877
-575.934
-574.818
-525.087
-514.411
-SOl. 805
-493.3(19
-482.919
-472.648
54.856
44.784
37.595
32.210
28.028
24.689
-573.526
-462.487
21.962
--------------------------------669.452
-450.400
19.605
-667.412
-437.699
18.017
-634.275
-633.385
-630.513
-627.660
-624.810
-621.970
-619.139
-437.699
-433.078
-417.764
-402.676
-387.710
-373.039
-358.488
18.017
17.401
15.587
14.022
12.659
11.462
10.403
BOIL I IIG POI IT
EHTHALPI OF YAPOBIZlTIOH
kJ
1.4984 J/bar
14.984 c 3
IIOLAB YOLDIIB
TBAISITIOHS II RBPEBBICE STATE ELBIIEITS

SODIDII II. P. 370.98 9 B. P. 1175 K.
HEAT CAPACITY BQOATIOIS

-2.6123 +
J.3468z1o-z T
(EQUATIOI VALID PBOII

BEPEBBICI
181
215
9.S415z10Z
298 - 1269 I)
,-os
215
COIIPILBD
6- 9-76
294
THEB!ODYIA!IC PROPERTIES Ol !IIBBALS
CRYOLITE
FORMULA WEIGHT
209.942
Cryolite dissociates above 1279 K
presuaably by the reaction la.lll 6 = laAll + 21al.
TE!P.
( a;-H~ 98 )/T
J;aolK
so
cop
-(G;-H~ 98 )/T
J/aoll
JjaolK
1.67
1.67
57.350
94.176
121. 155
142.429
160.109
165.721
304.50
358.33
404.97
446.58
484.46
499.38
247.15
264.15
283.82
304.15
324.35
333.66
FOB!AUOI FRO! THE ELE!ENTS

GIBBS
FREE ENERGY
Log [(f
EITHALPY
kJ/aol
J/aolK
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
238.45
-3309.544
-3144.915
550.978
238.45
215.72
UNCERTUNTY
400
500
600
700
800
838
4.180
233.86
248.90
263.11
276.99
290.72
295.92
4.]00
0.753
--------------------------------3316.03(1
-3088.271
403.289
-3313.924
-3310.537
-3305.921
-3300.126
-3291.226
-3031.559
-2975.388
-2919.857
-2865.079
-2845.884
316.706
259.032
217.883
187.071
177.392
-3285.947
-2811.727
163.189
-3285.264
-2705.476
128.473
-3561.380
-2583.536
105.020
-3446.797
-3427.946
-3409. 151
-3390.413
-3371. 72fl
-3353.093
-2573.571
-2507.12J
-2442.0111
-2378.156
-2315.501
-2253.891
103.408
93.542
85.039
71.639
71.147
65.407
-------------------------------------------------------------------------------176.292
-2845.884
177.392
838
509.95
333.66
-3282.367
262.96
900
183.456
528.25
344.79
272.55
1000
193.138
557.77
364.63
288.02
1100
202.467
585.94
383.47
303.49
1200
1285
211.531
217.696
613.01
635.45
401.48
417.75
318.96
332.11
1300
1400
1500
1600
1700
1800
305.729
312.243
317.887
322.826
327.184
331.058
726.83
756.24
783.63
809.24
833.31
855.99
421.10
444.00
465.74
486.41
506. 13
524.93
396.91
396.91
396.91
396.91
396.91
396.91
[(
BOILING POIIIT
kJ
--------------------------------3291.721
-2758.551
144.093
--------------------------------2646.975
115.220
-3569.632
-------------------------------------------------------------------------------105.020
1285
304.665
417.75
-3449.625
-2583.536
722.42
396.91
!!ELTING POINT
1285
111.755 kJ
38.100 kJ
7.0810 J/bar
70.810 ca 3
!OLAB VOLUIIE
TBAISITIOIIS IN REFERENCE STATE ELEBENTS

SODIUII 1!. P. 370.98, B. P.
1175
I(.
ALU!INUI! 1!. P. 933 K.
cop
1.8277x102 + 13.542 T
1.96931:1011 T-2
298 838 K)
cop
1.3331x102 + 0.15471 T
838- 1285 K)
REl'ERENCE
181
247
247
COI!PILED
8-11-76
PBOPEBTIES 17 HIGH TEMPE&ATOBES
UBAHIUK TETBAPLUOBIDE
UF 4
295
FORMULA WEIGHT
314.023
crystals 298.15 to aeltinq point 1330 K.
-------------------------------------------------------------------------------FOBUTIOII Pi Oil THE ELEIIENTS

TEilP.
(H;-a~ 98 )/T
J/aolK
so
JjaolK
-( G;-H~ 98 )/T
cop
Jjaol K
Jjaol K
EIITHALPI
GIBBS
FREE EBEBGI
kJ/aol
Loq Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
151.67
151.67
116. 02
-1851.500
-1762.800
308.837
UIIICEBTAIIITI
0.17
0.17
900
30.300
48.598
61.072
70.249
77.432
83.3411
186.60
213.17
236.27
255.59
272.64
288.02
156.30
165.17
175.20
185.34
195.21
204.68
120.86
122.64
124. 29
126.42
129.11
132.30
1000
88.422
302.15
213.73
135.95
1100
1200
1300
92.923
97.022
100.835
315.29
327.66
339.39
222.37
230.64
238.55
139.97
144.31
148.92
400
500
600
700
BOO
ltELU NG POINT
1330
ENTHALPY OF llELTIIIIG
5.000
5.100
0.894
-1850.867
-1848.513
-1846.463
-1844.689
-1843.144
-18111.808
-1732.227
-1702.848
-1673.915
-1645.301
-1616.912
-1588.720
226.207
177.896
145.728
122.774
105.574
92.207
--------------------------------1843.064
-1560.514
81.513
-------------------------------72.7511
-1845.558
-1532.102
-18112.705
-1839.451
-1503.754
-1475.606
65.457
59.291
BOILING POUlT
42.803 kJ
kJ
22.552 kJ
llOLAB YOLUilE
4.688u J/bar
46.880 ca 3
TRANSITIONS IN BEFEBENCE STATE ELEMENTS

URANIUM ALPHA-BETA 9111, BEl'A-GAitiiA 10118, ll. P. 1405 K.
-8.5443 + 7.036Jx1o-z T
REFERENCE
70
70
2.4522x10~
298 -
t-os
1300 K)
2H
COil.I?ILED
6- 8-76
296
THERBODIIA!IC PROPERTIES OP !IIBBlLS
IODUGUITE
Aqi:
TE!P.
l
POR!ULA lEIGHT
Heaqoaal ccystals 298.15 to 423 1.
so
( a;-a~ 98 )/T
J/aolK
Cubic crystals 423 to 831 1.
-( G;-a~98 )/!
cop
J/aoll
J/aolK
J/olK
23 ... 772
POB!ATIOI PRO! TBE ELE!BITS

GIBBS
Loq Kf
PBEE BlDG I
BITHALPI
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
115.48
115.1l8
56.82
-61.840
-66.254
11.607
UIICEBTli liT I
IJOO
423
15.167
17.903
1.67
1.67
132.93
136.56
117.76
118.68
1.671J
28.38
28.62
1.757
0.308
--------------------------------69.113
-67.538
8.820
-69.350
-67.1J47
8.329
-------------------------------------------------------------------------------423
32.449
151.13
118.68
-67.1JIJ7
8.329
56.118
-63.188
-------------------------------500
36.150
160.54
-66.270
6.924
124.39
56.1J8
-83.929
600
700
80(1
39.538
41.960
43.775
170.88
179.54
187.07
!ELTIIG POIHT
831
ENTHALPY or !ELTING
1J1.JII
137.58
143.29
56.118
56.48
56.48
-82.827
-81.770
-811.798
-62.869
-59.593
-56.484
5.1173
4.447
3.688
BOILIIG POUT
It
kJ
EITHALPY or VAPOBlZATIOI
kJ
kJ
BOLAR fOLUIIE
IJ.1301 J/bar
111.301 ca 3
TBAISITIONS IN BEPEBEICE STATE ELE!EITS

SILYEB ft. P. 1231J K.
IODIIE II. P. 386.75 1 B. P. 458 K.
HEAT CAPACITI EQUATIOI
c:
21J.351 + 1.008310-z T
(EQUATION V &LID rBOI!
BEPEBEICE
115
120
263
298 -
IJ23 K)
263
CO!PILED
7-24-76
PROPERTIES AT HIGH TEBPEBATURES
297
POB!ULA WEIGHT
COCCI !liTE
Crystals I 298.15 to 403 K.
454.399
crystals II 403 to elting point 523 K.

POR!lTION PRO! THE ELE!ENTS
GIBBS
FREE EIERGI
TE!P.
EITHALPI
J/olK
J/olK
o.ooo
181.33
6.28
181.33
6.28
400
20.334
204.77
184.44
500
38.108
229.71
600
79.775
298.15
UNCEBTli liT!
kJ/ol
kJ/ol
-105.437
1.674
-102.203
2.552
17.906
0.447
82.01
-121.977
-100.475
13.121
191.66
84.12
-161.813
-91.682
9.578
202.64
102.09
-139.467
-79.817
6. 949
BOILING POINT
627
59.166 kJ
BELTING POINT
52]
ENTHALPY OF !ELTING
18.828 kJ
kJ
BOLAR YOLUBE
7.1840 J/bar
71.840 c 3
!RlNSITIONS IN REFERENCE STATE ELE!ENTS

!ERCORI B. P. 629 K.
IODINE
BEFERENCE
115
32
ft.
P. 386.75, B. P. 458 K.
263
32
263
247
COBPILED
7-24-76
298
THER!ODYNAftiC PROPERTIES OF !lNERALS
WITHERITE
FORMULA WEIGHT
orthorboabic crystals 298.15 to 1079 K.

1241 K.
197.349
Cubic crystals 1241 to 1600 K.
-------------------------------------------------------------------------------.FORMATION FBOft THE ELEMENTS

TE!P.
( H~-H~ 98 )/T
JjaolK
ST
JjaolK
-(G;-H~9a)/T
cop
Jjaol K
Jjaol K
ENTHALPY
GlBBS
FREE ENERGY
kJjaol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298. 15
o.ooo
112.13
112.13
-1210.850
-1132.210
198.359
85.35
UIICERTAlNTY
2.09
2.09
400
500
23.575
39.400
139.25
1b2.13
115.68
122.7 3
98.42
106.59
2.230
2.:.!40
0.392
-1210.071
-1209.550
-1105.461
-1079.381
1411.359
112.763
600
700
51. 173
60.506
182.17
200.12
131.00
139.61
113.36
119.57
800
900
1000
68.264
74.956
80.885
216.48
231.60
245.74
148.22
156.64
164.85
125.54
131.38
137.15
-1208.319
-1027.417
76.667
-1205.493
-1203.:.!82
-976.011
-950.629
56.646
49.656
1079
85.640
256.91
171.27
141.68
1100
1.200
1241
102.926
107.250
108.734
276.02
289.49
295.01
173.09
18.2.24
18b .28
154.81
154.81
154.81
-1190.676
-1186.910
-1185.454
-924.964
-900.986
-891.519
43.923
39.219
37.525
1300
1400
1500
1600
113.422
116.679
119.495
121.963
304.49
J 16.28
327.24
3J7 .so
191.07
199.60
207.74
215.54
158.98
15tl.98
158.98
158.98
-1179.876
-1175.722
-1171.549
-1167. 421
-877. 4:.!7
-854.351
-831.516
-808.986
35.256
31.tl76
.28.956
26.411
BOILING POINT
kJ
kJ
kJ
~OLAB
--------------------------------1053.335
-1209.498
91.701
--------------------------------1001.631
65.400
-1207.305
--------------------------------1209.054
-930.172
45.030
-------------------------------------------------------------------------------1079
101.917
273.19
-1191.491
-930.172
45.030
171.27
154.81
-------------------------------------------------------------------------------1241
111.254
297.5J
-1182.328
-891.519
H. 525
186.4!8
158.98
~ELTING
POINT
ENTHALPY OF !ELTING
VOLU~E
4.5810 Jjbar
45.810 Cllj

BARIU~
ALPHA-BETA 582, BETA-GA!!!A 768, !!. P. GAK!A 1002,

P. 2169 It.
a.
81.001 + 5.64tl4x1o-z T
(EQUATIOII VALID FBOft
REFERENCE
155
120
3.J107x10 T-l
298 - 1079 K)
COMPILED
6-28-76
.299
PROPERTIES AT HIGH TE!PERATORES

WITHERITE
FOB!ULA WEIGHT
orthorhombic crystals .298.15 to 1079 K.
1241 K.
197.349
-------------------------------------------------------------------------------FOR!ATIOII .FRO! THE OIIDES

TE!P.
(a;-u; 98 )/T
Jjaollt
So
T
-(G;-H~g 8 )/T
J/aolK
J/aollt
2.09
2.09
CD
GIBBS
.FREE .EIEBGY
ENTHALPY
J/aolK
Loq Kf
ltJ/aol
ltJ/aol
--------------------------------------------------------------------------------217.446
38.096
298.15
-269.240
o.ooo
112. 13
112.13
85.35
UIICEIT liiiTY
o. 770
0.780
26.091
-199.799
-182.656 19.082
14.426
-165.711
-148.987 11. 117
-132.473
8.649
* -116.201 6.744
-100.172
5.232
-87 .76() 4.249
-------------------------------------------------------------------------------4. 249
1079
-87.766
101.917
273.19
171.27
154.81
-238.953
1100
4.022
102.926
154.81
-84.701
276.0.2
173.09
-238.100
3.087
1200
-70.933
1 07 .2 50
289.49
182.24
154.81
-234.038
2.767
1241
108.734
-232.460
-65.740
295.01
186.28
154.81
400
500
600
700
800
900
1000
1079
23.575
39.400
51.173
60.506
68.264
74.956
80.885
85.640
139.25
162.13
182.17
200.1.2
216.41:1
231.60
245.74
256.91
115.68
122.73
131.00
139.61
148.22
156.64
164.85
171.27
98.42
106.59
113.36
119.57
12 5. 54
131.38
137.15
141.6B
-268.760
-267.891
-266.745
-265.328
-263.618
-.261.580
-259.193
-.256.515
-------------------------------------------------------------------------------1241
2.767
111 .254
-65.740
297.53
186.28
158.98
-229.333
-57.623
2.315
1300
113.422
304.49
191.07
158.98
-226.872
1400
1500
1()00
116.67':1
119.1l95
121.963
316.28
327.24
337.50
199.()0
207.74
215.54
158.98
158.98
158.98
-222.700
-211:1.668
-214.757
-44.77.2
-3.2.188
-19.893
1.670
1.121
o.o49
I!ELTIIIG POINT
BOILIIiG POINT
ENTHALPY OF !ELTIIIG
ltJ
EIITHALPI OF VAPORIZATlOII
ltJ
ltJ
BOLAR VOLUI!E
4.51:110 J/bar
45.810 ca 3
TRANSITIOIIS Ill RE.FEREIICE STATE OXIDES

81.001 + 5.6484x1o-z T
(EQUATION VALID .FRO!
BEFEBEIICE
155
120
J.3107x10 T-:t
298 - 1079 It)
4
CO!PILED
6-28-76
300
THER!ODYJAKIC PROPERTIES OP KIJERALS
ARAGONITE
CaC0 3
FOi!ULA WEIGHT
100.089
-------------------------------------------------------------------------------FORKATIOII PRO! THE ELEUJTS

TEIIP.
so
T
ca;-a~ 98 )/T
J;aolK
J/aolK
-(G;-a~ 98 )/T
J/aol K
cop
EIIITHlLPY
J/aolK
GIBBS
FREE EIERGY
kJ/aol
LOCJ Kf
kJ/aol
-------------------------------------------------------------------------------298.15
0.000
87.99
-1207.430
-1127.793
197.585
87.99
82.32
UIICERTliNTY
o. 20
0.20
1. 423
1. 464
0.256
-1206.681
-1205.665
-1204.567
-1203.438
-1100.691
-1074.310
-1048.132
-1022.16()
143.736
112.2JJ
91.248
76.}.75
400
500
600
700
22.375
37.184
48.128
56.754
113.75
135.23
153.96
170.68
91.37
98.05
105.83
113.9J
92.67
99.81
105.71
111.18
800
900
1000
63.879
69.971.!
75.346
18 5. 86
199.84
212.87
121.98
1}.9.86
137.52
116.29
121.23
126.07
I!ELTIIIG POIIIT
BOILIIIG POIIIT
EIITHALPY OF KELTIIIG
kJ
BJTHALPY OF VAPORIZATIOII
kJ
kJ
KOLAR VOLUU
-------------------------------65.049
-1203.022
-996.251
-1201.749
-1200.573
-970.468
-944.833
56.325
49.353
3.4150 J/bar
34.150 ca 3
TRAIISITIOHS IN REFEREIICB STATE ELE!BMTS

ClLCIU! ALPHA-BETA 720 9 K. P. BETA 1112, B. P. 1755 K.
c;
81.533 +
4.5673x1o-z T
(EQUATIOJ VALID FIOI!

REPBREIIICE
115
243
1.1405x1Q6 r-z
298 - 1000 K)
214
COIIPILBD
8- 2-76
PBOPBBTIES lT BIGS TEBPEBlTURBS

lRlGOliiTE
301
FOB!ULl WEIGHT
100.089
-------------------------------------------------------------------------------FOB!ATIOI PB.O! THE OIIDES

so
-(G;-a~ 98 )/T
cop
JtaolK
JjaolK
J/aolK
( a;-a~ 98 )tT
TEBP.
K
J/aolK
GIBBS
PiEE EIIBRGY
EBTHlLPY
Log Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
87.99
87.99
-129.936
22.763
o.ooo
82.32
-178.831
OJCEllTliiTI
400
500
22.375
37.184
48.128
56.754
&3.879
69.978
75.346
bOO
700
800
900
1000
0.20
0.20
113.75
135.23
153.96
170.68
185.86
199.84
212.87
91.37
98.05
105.83
113.93
121.98
129.86
137.52
1.110
92.67
99.81
105.77
111.18
116.29
121.23
126.07
-178.421
-177.875
-171.175
-176.283
-175.166
-173.791
-172.136
1. 150
BELTIIIG POUT
BOILIJG POIBT
kJ
EITHlLPI OF YlPORIZlTIOI
8~98
kJ
!OLlB VOLUBE
H~
-113.284
-97.060
-80.959
-64.996
-49. 165
-33.497
-17.995
!IITHlLPY OF !ELTIIG
-
14.793
10.140
7.048
4.850
3.210
1.944
0.940
kJ
3.4150 J/bar
34.150 cal
TBliiSITIOIS II REFEBEICE STlTE OIIDBS
BElT CAPACITY EQOATIOI
c;
4.5673z1o-z T
(BQUlTIOI YlLID FROB
81.533 +
BBFBBIICE
115
243
1.1405z10 r-z
298 - 1000 I)
214
COIIPILBD
8- 2-76
THER!ODYNA!IC PROPERTIES OF !liBERALS
302
CALCITE
FOR!ULA WEIGHT
10Q.089
-------------------------------------------------------------------------------FOR!ATIOB FRO! THE ELE!ENTS

TEIIP.
so
( a;-s; 98 );T
J;aolK
J;molK
-( G;-a; 98 )/T
J/aolK
cop
ENTHALPY
GIBBS
FREE ENERGY
kJ/aol
J/aolK
J.oq Kt
kJ/aol
-------------------------------------------------------------------------------197.769
298. 15
o.ooo
91.71
-1207.370
-1128.842
91.71
83.47
o. 2<.1
0.20
400
500
600
700
23.175
38.750
50.180
59.021
118.36
140.88
160.43
177.70
95.18
102.13
110.25
118.68
97.00
104.54
109.87
114. 16
800
900
1000
66.150
72.089
77.170
193.19
207.27
.l20. 22
127.04
135.18
143.05
117.88
121.28
124. 48
1100
81.610
232.23
150.62
127.54
1200
85.563
243.45
157.89
130.52
UNCERTAINTY
!ELTING POINT
EBTHALPY OF !ELTING
1.339
1. 381
Q.242
-1206.301
-1204.822
-1203.276
-1201.791
-1102.155
-1076.292
-1050.723
-1025.427
143.927
112.440
91.474
76.519
-1199.789
-1198.689
-975.195
-950.299
56.599
49.639
-1197.837
-925.510
43.949
--------------------------------1201.145
-1000.238
65.309
--------------------------------900. 161
39.183
-1204.162
BOlLI BG POI Br
kJ
3.6934 J/bar
36.934 ca 3
!IOLAB VOLU!E
kJ
TRANSITIOBS IN REFERENCE STATE ELE!IENTS
CALCIU!I ALPHA-BETA 720,
!1.
P. BETA 1112, B. P. 1755 K.
HEAT CAPACITY EQUATIOB

2.6920xto-z T
99.715 +
iiEPEREBCE
115
243
2. 15 76x 1 o T- z
298 - 1200 K)
214
CO!! PILED
7-27-76
PROPERTIES AT HIGH
TE~PEBATURES
CALCITE
303
FOR~ULA
WEIGHT
100.089
Crystals 298. 15 to 140v K.
-------------------------------------------------------------------------------FORIUTIOH FROII THE OIIDES

so
GIBBS
FREE ENERGY
-( G~-H~ 98 }/T
cop
J/olK
J/aolK
J/IIOlK
0.20
0.20
700
BOO
900
1000
23. 175
38.750
50. 180
59.021
66.150
72.01!9
17.170
118.36
1140.88
160.43
177.70
193. 19
207.27
220. 22
95.18
102. 13
110.25
111!.68
127.04
135.18
143.05
97.00
104. 54
109.87
114. 16
117.88
121.28
124.48
-178.041
-177.032
-175.884
-174.636
-173. 21l9
-171.831
-170.252
-114.781
-99.042
-83.550
-6t1.26J
1100
1200
81.610
85.563
232.23
243.45
150.62
157.!;9
127.54
130.52
-168.538
-166.677
-8.t173
5.572
TEI'IP.
( u;-H; 98 )/T
J/olK
ENTHALPY
kJ/1101
Log Kf
kJ/1101
-------------------------------------------------------------------------------298. 15
91.71
o.ooo
91.71
83.47
-178.771
-130.985
2.2.947
UIICEIIT.U IITY
400
500
bOO
!!ELTING POINT
1.000
1.040
-~3.152
-3t1.224
-23.461
14.984
10.347
7. 27 j
5.094
3.470
2.218
1.225
0.421
-0.243
BOILING POINT
ENTHALPY OF KELTING
kJ
kJ
IIOLAR VOLUIIE
kJ
3.6934 J/bar
36.934 c11 3
HEAT CAPACITY
c;
E~UATION
99.715 +
2.6920x1o-z T

BEFERENC!i
115
243
2.1576x10 T-z
298- 1200 K)
214
COIIPILED
7-27-76
THERBOD!HAftlC PROPERTIES OF BIHERlLS
104
DOLOftiTE
FORBULA WEIGHT
Ca!q( CO:~ ) 2 :
184.403
-------------------------------------------------------------------------------FORUTIOH PRO! THE BLEB! US

TEBP.
so
-(G;-a~ 98 )/T
cop
J/olK
J/olK
J/olK
0.29
0.29
( H;-a; 98 )/T
J/olK
'l
EHTBlLPY
GIBBS
FREE ENERGY
kJ/ol
Loq Kf
kJ/ol
-------------------------------------------------------------------------------298.15
o.ooo
155.18
-2161.672
378.718
155.18
157.53
-2324.480
UHCEBTliHTY
1. 460
1.670
0.293
-2323.420
-2321.333
-2318. 7JO
-2315.875
-2106.176
-2052.098
-1998.480
-1945.344
275.040
214.382
173.984
145.164
-2310.455
-1840.054
106.794
-2312.986
-17311.4111
82.362
400
500
600
700
43.600
73.520
96.110
114.003
205.32
248.35
286.43
320.53
161.7 2
174.83
190.32
206.53
181.53
201.88
215.65
226.64
800
900
128.685
141.103
351.42
379.73
222.74
238.63
236.07
244.72
1000
151.888
405.96
254.07
253.14
1100
161.481
430.118
269.00
261.33
IIELT:IHG POUlT
BOILUG POIIIT
EITHlLP! OP ftELTIIIG
kJ
EHTHlLP! OF VAPORIZATIOJ
kJ
8~98
H~
25.983 kJ
--------------------------------1892.522
123.570
-2313.625
--------------------------------1787.193
93.354
-2316.263
6.113110 J/bar
64.340 cJ
IIOLAR YOLOIIE
TBAISITIOHS IH REPEREHCE STATE ELIBEHTS

CALCIOII ALPHA-BETA 720, ft. P. BETA 1112, B. P. 1755 K.
IIAGHESIOB II. P. 922, B. P. 1361 K.
5.4788x102+ 2.8400x10
0.16759 T
r-z

BIPBBEICB
151
244
298- 1100 K)
225
COIIPILBD
8- 2-76
lOS
PBOPBITIIS lT HIGH TI!PIIlTUBBS

POB!ULl VBIGBT
DOLO!ITI
184.403
Crystals 298.15 to 1000 1.
-------------------------------------------------------------------------------FOBIIlTIOI 11011 THE OIIDBS

TEBP.
soT
-(G;-s; 98 )/T
cop
J/aoll
J;aoll
J/aoll
( H;-8; 98 }/1'
J;aoll
GIBBS
PBBE BIBBGI
BITHlLPI
Log If
ltJ/aol
ltJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
155.18
155.18
157.51
-100.881 -200.249 35.081
1.13(1
1.120
UICBBTliiTI
0.29
0.29
400
500
600
700
8(1(1
900
1000
U.600
73.520
96. 110
114.003
128.685
141.1 OJ
151.888
205.32
248.35
286.113
120.53
351.42
379.73
405.96
1100
161.481
lf30.48
190.32
206.53
222.74
238.63
251f.07
-300.071
-298.556
-296.484
-293.963
-291.056
-287.758.
-281f.034
-165.963
-132.591
-99.594
-66.97 3
-llt.735
-2.900
28.566
269.00
261.33
-279.822
59.614
ltJ
BITBlLPI 07 VlPOBIZlTIOI
171f.8l
!BLTUIG POIHT
21.673
13.852
8.670
4.998
2.2&8
0.168
-1.492
-2.831
BOIJ.IIG POIIT
BITHlLPI 07 IIILTIIG
a; 98 -
183.53
201.88
215.&5
226.64
236.07
241f.72
253.11f
161.72
B~
25.983 k.J
ltJ
6.4340 .J/bar
64.340 ca 3
BOLli VOLU.IIB
TRliSITIOIS II BIPBBIICI STlTI OXIDES
BElT ClPlCITI BQUlTIOI

5.4788x10Z-
0.16759 T
1. 7076x1o- rz
+ 2.8400x10 ,-z
(EQUlTIOI YlLZD PBO!

BBPBBBICB
151
298- 1100 I}
225
COIIPILID
8- 2-76
306
THEB!ODYVA!IC PROPERTlES Of !INERALS
l!lGNESITE
FOO!ULA iiEIGBT
84.314
!gCO~:
-------------------------------------------------------------------------------FOB!ATION FBOll THE ELEli.ENTS

TE.IIP.
so
H~-H; 98 )/T
J/IIOlK
-( G~-u; 98 )/T
J/IIOlK
J/IIOlK
0.14
0.14
cop
ENTHALPY
GIBBS
fREE EH.EBGY
kJ/1101
J/IIOlK
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
-1029.41W
o.ooo
65.09
-1113.280
180.361
65.09
76.09
UIICEBTAI N'l'Y
400
500
bOO
700
800
900
21.4 00
36.206
47.463
56.500
64.067
70.611
89.67
110.94
129.1H
146.89
162.51
176.99
68.1.7
74.73
82.37
90.39
98.44
106.38
90.57
99. 'n
107.38
113.96
120.06
12 5. 89
1000
76.426
190.54
1 14. 11
1 J1. 54
!!ELTING POINT
1.]81
0.242
-1112.899
-1111.9bJ
-1110.704
-1109.190
-1107.423
-1105.399
-1000.885
-97J..9<J3
-945.305
-917.866
-890.b52
-863.668
1J(J. 703
101.648
82.29b
68.492
58.154
50.126
--------------------------------836.156
43.676
-1112.036
BOILING POINT
ENTHALPY Of IIELTING
1.3]9
kJ
11.b31 kJ
kJ
2.8018 J/bar
28.018 cm 3
I!OLA B VOL Ull E
TRANSITIONS IN REFERENCE STATE ELEBENTS

I!AGNESIUII II. P. 922 1 B. P.
1361 K.
c~
81.119 + 5.2254x1o-z T
(EQUATION VALID FBO.II
REFERENCE
115
95
1.8320x106 T-z
298- 1000 K)
220
COI!PILED
7-29-76
307
PROPERTIES AT HIGH TESPEBATUBES
ftAGI!IBSITE
FO.RftULA WEIGHT
84.314
-------------------------------------------------------------------------------FOIUUTIOJ Pi Oil THE OXIDES

TEIIP.
so
(H;-a; 98 )/T
J/IIOlK
J/aolK
-< G;-u~98 )/T
cop
J/aolK
J/aolK
GIBBS
FREE EIIERGY
ENTHALPY
Log Kf
kJ/aol
kJ/1101
--------------------------------------------------------------------------------65.914 11.547
298.15
o.ooo
65.09
65.09
76.09
-118.280
UIICBRTUIITY
1.300
1.340
0.14
0.14
89.67110.94
129.83
146.89
162.51
176.99
190.. 54
68.27
74.73
82.37
90.39
98.44
106.38
114.11
90.57
99.92
107.38
113.96
120.06
125.89
131.54
IIELTIIIG POIIIT
BOILING POII!IT
ENTHALPY OF ftELTII!IG
ltJ
EI!ITHALPY OF VAPO.RIZATIOI!I
kJ
400
500
600
700
800
900
1000
21.400
36.206
47.463
56.500
64.067
70.611
76.426
11.631 kJ
-117.810
-116.976
-115.850
-114.'U4
-112.711
-110.660
-108.244
-48.077
-30.736
-13. 59.l
3.343
20.050
36.529
52.767
6.278
3.211
1.183
-0.250
-1.309
-2. 120
-2.756
2.8018 J/bar
28.018 c11 3
IIOLAR VOLUIIE
TRANSITIONS Ill BEFEBEIICE STATE OIIDBS
c:
81.119 + 5.2254x10-2 T
BEFBBEIICE
115
95
1.1U20x10 T-2
298- 1000 K)
220
COIIPILED
7-29-76
THBBSODIIlftiC PIOPEITIBS OP SIIBBlLS
308
POBftOLl VEIGBT
IHODOCHBOSITE
ftoCO~:
114.947
Crrstals 298.15 to 700 I.
FOBSlTIOI PROS THE BLBSEITS

GIBBS
PBBB BIEIGI
BITHlLPY
TUP.
JtJ/ol
o.ooo
100.00
2.10
100.00
2.10
75.52
-889.270
1.213
-816.047
1. 381
142.969
0.242
22.2 5(1
38.026
49.663
58.503
125.52
148.06
167.71
184.90
103.27
110.03
118.05
126.40
96.10
105.21
110.02
112.81
-888.728
-887.472
-886.120
-884.891
-791.118
-766.862
-742.867
-719.096
103.310
80.114
64.673
53.660
298.15
ONCEBT&IITI
400
500
600
700
.kJ/ol
!!ELTING POIIT
BOlLIIIG POINT
ENTHALPY OF I!EL.TING
kJ
ENTHALPY OF YAPORIZlTIOII
kJ
SOLAR VOLOSE
kJ
3.1073 J/bar
3
31.073
TRANSITIONS IN REFEBEIICE STATE ELEIIENTS

IIANGANESE lLPHA-BETl 980 1 BETA-GAIIIIA 1360 1 Gl!Sl-DBLTA 1410 1
1!. P. DELTA 1517 K.

1.2l39x10Z -
2.9399x10-3 T 298-
(EQUlTIOI VALID FRO!

BEFEIEIICE
168
2114
220
4.1777x10
70(1 K)
r-z
220
&8
CO !PILED
6- 2-76
309
PIOPBITIBS IT BIGB TBIPIIITDIIS

POIIULI lEIGHT
STBOITIIIITB
orthorhoa~ic
crystals 298.15 to 1197 1.
147.629
Hexagonal crystals 1197 to
1500 I.
-------------------------------------------------------------------------------POIIIITIOI PROI THB BLBliBITS

TEKP.
<a;-a~ 98 )/T
J;aoll
-(G;-a~ 98 );r
CDp
J/aoll
J/aoll
J/aoll
1.67
1.61
So
T
BITBILPY
GIBBS
PREB BIBIGY
Log
't
kJ/aol
kJ;aol
--------------------------------------------------------------------------------1137.640
199.311
298.15
97.07
97.07
81.42
-1218.680
0.000
UICBBTIIITI
400
500
600
700
800
23.375
38.838
49.71t2
57.996
64.680
123.93
146.38
165.38
181.95
196.83
100. 55
107.54
115.611
123.95
132.15
98.06
102.71
105.81
109.35
113.71
900
1(100
70.411
75.541
210.51
223.33
140.10
147.79
118.87
124.72
1100
1197
80.301
84.980
235.52
155.22
162.36
131.16
137.88
~47.34
1.450
1.460
0.256
-1217.718
-1216.508
-1215.515
-1214.727
-1214.046
-1110.080
-1083.318
-1056.770
-1030.390
-1001t.099
144.962
113.174
92.000
76.889
65.561
--------------------------------977.816
56.751
-1214.057
-1212.958
-951.628
49.708
--------------------------------925.109
43.930
-1219.436
-1216.800
-899.446
39.250
--------------------------------------------------------------------------------899.1146
39.250
1197
100.703
-1197.976
263.06
162.36
11t4. 77
1200
1300
14011
1500
100.814
104.211
107.121
109.645
263.41
275.02
.!'85.76
295.76
IBLTIIG POIIT
144.77
144.77
144.77
1411.77
BOII.IIG POIIT
BITBILPI OP liBLTIIG
a; 98 -
-1197.877
-1194.568
-1191.3116
-1188.196
162.60
170.81
178.611
186.11
-898.688
-873.898
-849.3511
-825.031
BITBILPI OP YIPOBIZITIOI
a~
kJ
!lOLII YOLOIIB
39.119
35.114
J1.690
.l8.1JO
kJ
3.9010 J/bar
39.010 ca3
TIIISITIOIS II RBPBBBICB STITB BLBBBITS

STBOITIUB ILPHI-Gilllll 828 9 ll. P. GIBBI 1041, B. P. 1652 I.
BBIT CIPICITI BQDITIOI

81.596 + 0.10754 T + 3.1677z1oa r-os
(BQUlTIOI YILID PBOB 298 - 1197 I)
BBPIRBICB
155
120
COBPILBD
6-29-76
310
THEBIODIIASIC PROPERTIES OF liBERALS
STROIITUHITE
POBSULA WRIGHT
orthorhoabic crystals 298.15 to 1197 K.
147.&29
Hexaqonal crystals 1197 to
1500 K.
-------------------------------------------------------------------------------FORSATIOII PROS THE OUDES

TEIP.
so
( u;- H~ 98 )/T
J;aolK
-(G;-H~ 98 )/T
J/aolK
J/aolK
1.67
1.67
cop
GIBBS
FREE EIIIBBGY
EIITBALPI
kJ;aol
J;aolK
Log Kf
kJ/aol
-------------------------------------------------------------------------------32.(;45
298.15
o.ooo
97.07
-182.917
97.07
81.42
-234.680
URCEBTAIHTY
1.11 (;
1.120
400
500
bOO
700
800
900
1000
23.375
38.838
119.742
57.996
64.6110
70.411
75.541
123.93
146.38
165.38
181.95
196.83
210.51
223.33
1(;0.55
107.54
115.64
123.95
132.15
140.10
147.79
98.0&
102.71
105.81
109.35
113.71
118.87
124.72
-234.120
-233.314
-232.&26
-231.993
- ..U1.2tl1
-:.!30.360
-:.!29.111
-1&5.839
-1411.864
-132.(;48
-115.337
-98.712
-112.200
-&5.79&
1100
1197
80.301
811.9tl0
235.52
247.34
155.22
1&2.36
131.1&
137.88
-227.460
-225.041
"'
-119.546
-34.142
1400
1500
107.121
109.645
285.76
295.76
1111.64
186.11
144.77
144.17
-200.230
-197.489
IIELTIIIG POINT
BOILING POINT
ENTHALPY OF SELTIIIG
kJ
kJ
SOLAR VOLUIIE
21.656
15.552
11.496
11.606
6.445
4. 771
3.437
2.353
"' 1.490
-------------------------------------------------------------------------------1197
100.703
-34.142 "'
1. 490
263.06
162.36
144.77
-206.218
12(10
1u0.814
263.41
1.467
162.60
-206.127
-33.698
144.71
13(;0
104.211
275.(12
-19.464
0.782
170.81
144.17
-203.104
-5.433
8.387
"'
0.203
-0.:.!92
kJ
3.9010 J/!lar
39.010 Cll3
81.59& + O. 10754 T
(EQUATIOH VALID PROS
REFERENCE
155
120
J.1677x103 T-os
298 - 1197 K)
COSPILED
6-29-76
PIOPEI~IBS
IIITIOBlllTE
Ba( 110_. ) 2
311
AT 81GB TE!PBBATUBES
FOI!OLA WEIGHT
261.350
crystals 298.15 to aeltinq point 865 K.
-------------------------------------------------------------------------------l"OB!lTIOII l"BO! THE ELE!EIITS

TE!P.
so
(B;-a~ 98 )/T
J/aolK
J/aolK
-( G;-a~ 98 )/T
cop
J/aolK
J/aolK
EIITHALPY
GIBBS
l"BEE EIIEBGY
ltJ/aol
Log Kf
ltJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
213.80
-796.579
213.80
151.38
-992.070
139.558
UIICEaTlliiTY
0.84
0.84
2.100
2.500
0.43ij
-990.496
-987.983
-7l9.996
-6&5.1"9
95.328
&9.488
400
500
41.700
70.272
261.76
302.8&
220.06
232.59
174.97
193.70
&00
700
92.275
110.357
339.7(1
373.40
247.42
263.04
210.70
22&.90
125.914
404.73
278.82
242.67
BOILIIIG POINT
kJ
kJ
kJ
BOLAR VOLU!E
800
!ELTIIIG POINT
865
EIITHALPY OF !ELTIIIG
--------------------------------984.858
-600.848
52.309
-979.605
-537.259
40.091
--------------------------------474.459
-973.561
30.979
8. 0580 J/bar
80.580 ca 3
TRANSITIONS IN REFEBEICE STATE ELE!EIITS

BARIUB ALPHA-BETA 582, BETA-Gl!!A 768, !. P. GA!!A 1002,
8. P. 2169 K.

1.2554x10Z + 0.149&7 T
REFERENCE
238
214
1.6697xlu
298 800 K)
r-z
214
COMPILED
&-28-76
THEIBODtlllllC PIOPBBTIES OP BliEilLS
312
POI!OLl WEIGHT
ClLCIOB IITllTB
Crystals 298.15 to
Ca(10:~) 2 :
164.090
800 K.
-------------------------------------------------------------------------------l"OUlTIOI 1"1011 THE BLBIIEITS

TEBP.
J/8011
so
( H;-H~ 98 )/T
J/aolK
-(G;-s~gs)/T
J/aoll
cop
EITBlLPI
GIBBS
l"BEE EIEBGt
kJ/aol
kJ/aol
J/aoll
Log 't
-------------------------------------------------------------------------------130.168
298.15
193.30
-938.390
-742.985
o.ooo
193.30
149.37
UHCBBTlllfTt
O.lfO
0.40
1.510
1. 7&0
0.308
-936.506
-932.983
-928.173
-922.205
-676.458
-611.833
-51f8.031
-485.139
88.337
63.918
lf7.711
36.202
lfOO
500
600
700
41.350
69.766
91.720
109.833
21f0.84
281.70
318.39
352.011
199.49
211.93
226.67
21f2.21
173.81
192.72
210.10
226.88
800
125.497
383.41
257.91
2113.38
BOI LI IIG POI IT
EITHlLPY OP YlPOIIZATIOI
kJ
I'IELTIIG POIIT
EITHlLPY OP BELTING
-------------------------------27.625
-915.843
-423.083
6.6090 J/bar
66.090 ca 3
BOLli YOLUI'IE
kJ
TRAISITIOIS IN BBPEIEICE STlTB ELEBBITS

CALCIOB ALPHl-BETl 720 B. P. BETA 1112 B. P. 1755 K.
HEAT CAPACITY EQUlTIOI
c;
1.11f81x1oz + 0.16160 T
(EQUATIOII YlLID PBOB
BEl"ERENCB
238
2111
- 3.6099x1o r-:~
298 - 800 K)
2111
COBPILED
6-28-76
PROPERTIES lT HIGH TEBPEilTURBS

lllTBR
313
FORftULl WEIGHT
Orthorhoabic crystals 298.15 to 401 K.
melting point 610 K.
( H;-H~ 98 )/T
TEIIP.
K
J/aOlK
so
~rystals
1101 to
Liqlli.d 610 to 700 K.
-(G;-u~ 98 )/T
cop
J/aolK
J/aolK
J/aolK
0.67
0.67
Bhoabohedral
101.103
PORillTIOII FROII THE EL!BEITS

GIBBS
FREE EIIERGY
Log Kf
BIITHlLPY
kJ/aol
kJ/aol
--------------------------------------------------------------------------------3911. 5114
298.15
o.ooo
133.09
96.27
-1194.1160
69.123
133.09
UIICERTli HTY
0.1120
0.1120
400
1101
26.0115
l6.293
163.09
163.38
137.04
137.09
108.111
108.53
1101
500
600
610
40.901
56.736
67.362
68.384
177.99
2011.68
226.611
228.73
137.09
1117.911
159.28
160.35
120.50
120.50
120.50
120.50
0.0711
--------------------------------360.141
117.030
-1195.591
-1195.1158
-359.970
116.891
-1189.521
-486.815
-4811.0113
-483.799
-321. 97(1
-328.061
-296.576
-293.450
116.891
311.272
25.819
25.128
-------------------------------------------------------------------------------610
84.935
245.28
-293.450
160.35
123.43
25.128
-1173.703
100
89.734
262.08
172.35
BELTIIIG POUT
610
EIITHlLPY OF BELTIIIG
10.096 kJ
H~98
H~
123.43
-1171.048
-267.000
BOILIIG POIIIT
kJ
19.9211
EITHlLPY OP YlPOBIZlTIOI
BOLlS YOLUIIE
kJ
16.8040 J/bar
168.0110 cal
TRliSITIOIS II RBPBREICE STATE ELE!EITS

POTlSSlUII II. P. 336.16 9 B. P. 1030 I.
BBPBREICE
115
120
215
215
COIIPILBD
7-24-76
314
ftAGNESIUft NITRATE
FORMULA WEIGHT
Crystals 298.15 to
600 K.
FOR !tAT ION FROM THE ELEMENTS

GitiBS
FREE ENERGY
Log Kf
ENTHALPY
so
-(G;-a~ 98 );T
cop
Jjaol K
JjaolK
J/aolK
1.60
1.60
209.45
249.99
281!.05
169.92
181.92
196.47
168.77
195.63
222.70
MELTING POINT
BOILING POINT
ENTHALPY OF MELTING
k.J
k.J
IIOLAR VOLUftE
TEllP.
(H;-u~ 98 )/T
J;aolK
148.315
k.J/aol
k.Jjaol
-------------------------------------------------------------------------------298.15
0.000
-589.181
103. 2..l2
164.01
164.01
-790.650
141.92
UIICERTAI NTY
400
500
600
39.525
68.066
91.580
1.300
1.420
0 .<!49
-789.474
-786.052
-71!0.405
-520.478
-453.577
-387.573
67.968
47.385
33.741
kJ
6.2930 Jjbar
62.930 ca 3

IUGN!SlUlt.. M. P. 922, B. P.
1361 K.
c~
58.417 + 27.292 T
1.8949x1os T z
(EQUATIONVALIOFROft 298- 60UK)
REFERENCE
238
214
214
COli PILED
6-28-76

li!IIOIU-IIITEB
315
FORII ULA II EIGHT
80.043
l88onia-niter undergoes pbase changes at 305.3, 357.4, 398.4 K.
It
8e1ts at 442.8 K.
FORftATIOII FROM THE ELEMENTS

GIBBS
EITHlLPY
FREE EIIERGY
TEI!P.
J/aol K
J/8olK
kJ/801
kJ/801
o.ooo
151.08
0.21
151.08
0.21
139.37
-365.560
0. 837
-183.803
0.879
32 .202
0.154
400
51.255
208.94
157.69
190.79
-358.483
-122.292
15.970
500
86.692
260.24
113.55
161.08
-349.018
-64.508
6. 739
298.15
UIICERTAIIITY
I!ELTIIIG POIIIT
EIITHALPY 0' IIELTIIIG
442.80 K
5.439 ltJ
kJ
BOILIIG POIIIT
kJ
IIOLAR VOLUI!E
4.6490 J/bar
46.490 ca 3
TRAIISITIOIIS IN REFEREMCE STATE ELEftEIITS
REFERENCE
115
262
262
COI!PILED
7-24-76
THBR!ODYNABIC PROPERTIES OP !INERALS
316
PORBDLA WEIGHT
SODA NITER
84.995
Beta crystals 549.2 to 583.2 K.
Alpha crystals 298.15 to 549.2 K.
Liquid 583.2 to 700 K.
TEBP.
so
-(G;-a~ 98 )/T
cop
J/aolK
J/aollt
J/aollt
0.68
0.68
(H;-a~ 98 )/T
J/aollt
PORBATION PRO! THE ELB!ENTS

GIBBS
FREE ENERGY
Log 't
EIITB&LPY
kJ;aol
.kJ/aol
-------------------------------------------------------------------------------64.324
298. 15
-468.020
-367.153
o.ooo
116.52
116.52
93.05
UNCERTAINTY
0.420
0.420
400
500
26.097
46.652
146.48
175.14
120.38
128.49
115.76
138.07
600
700
94.823
103.393
234.63
258.48
139.81
155.09
154.81
1511.81
0.074
-------------------------------43.440
-469.273
-332.651
-465.552
-298.883
31.22 4
-441.240
-435.118
-266.811
-238.210
23.228
17.176
BELTING POINT
583.20 K
BOILING POUT
ENTHALPY OF BELTING
15.447 .kJ
kJ
.kJ
flOUR VOLUliE
3. 7600 J/bar
37.600 ca 3
TRANSITIONS IN REFERENCE STATE ELEliENTS

SODIUll ft. P. 370.98, B. P. 1175 l.
REFERENCE
115
120
215
215
COBPILED
7-24-76
PIOPBBTIBS
1f
HIGH TBBPIBlTOBBS
POBBOLl lEIGHT
STBOITIOB IITilTB
Sr(
RO:~
Crystals 298.15 to
)2 :
311
211.630
900 K.
-------------------------------------------------------------------------------POIUTIOI PIOB THE BL!IIBITS

so
-(G;-a~ 98 )/T
cop
J/aolK
J/aolK
JtaolK
0.50
o.so
(H;-a~ 98 )/T
TEIIP.
K
J/aolK
ERTBlLPJ
GIBBS
PBBB BIBIGJ
kJ/aol
Log Kf
kJtaol
--------------------------------------------------------------------------------719.086
136.493
298.15
o.ooo
194.56
194.56
149.91
-978.220
OICEBTliiTJ
1.000
1. 300
0.2.28
-971.073
-973.755
-968.370
-961.675
-954.431
-711.189
-645.055
-579.786
-515.551
-452.311
92.812
67.389
50.475
38.471
29.533
400
500
600
700
800
39.975
68.722
92.218
111.644
127.569
240.55
281.42
319.59
354.74
386.65
200.57
212.70
227.37
243.10
259.08
169.18
197.80
220.31
234.84
242.19
900
140.422
415.31
274.89
243.52
IIELTIIG POINT
BOILIIG POIIT
EITHlLPJ OP IIBLTIIG
kJ
BITHlLPI OP VlPOiiZlTIOI
kJ
H~ 98
B~
--------------------------------389.893
22.629
-947.983
!lOLli VOLOBB
28.677 ltJ
7.0930 J/llar
70.930 cal
TiliSITIOIS II BBPBIBICI STlTE ELBBEITS

STBOITIOII lLPHl-Gllllll 828, II. P. GliiBl 1041, B. P. 1652 I.
HilT ClPlCITJ IQOlTIOI

0.37901 T
(EQOlTIOI VlLID PBOII
1.3389x1031 -
BEPBIIICI
250
214
2.l582x10
298 900 I}
r-o
2111
COIIPILID
5-28-76
318
THEB!ODXNAKIC PROPERTIES OF !INEBALS
ALUIUNUll SULFATE
FOR!ULA WEIGHT
342.137
Al 2 (S0 4 ) 3 : Crystals 298.15 to 1100 K.
-------------------------------------------------------------------------------FORIUTIOII FROM THE ELEIIENTS

TEMP.
-( G;-H~ 98 )/T
cop
J/aolK
J/aolK
J/aolK
1.2CJ
1.20
so
( H~-H~ 98 )/T
J/aolK
ENTHALPY
GIBBS
FREE ENERGY
Log Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
239.32
-l440.840
-3099.852
543.084
239.32
259.41
UNCERTAINTY
1.8CJ(J
1.88u
0.329
-------------------------------389.442
-3448.086
-2982.237
400
suo
600
700
74.850
127.184
166.443
197.447
325.26
400.24
466.31
525.38
250.41
273.06
299.87
327.93
319.87
351.02
373.64
392.95
800
900
223.(107
244.267
579.03
634.22
356.02
389.95
410.74
401.30
1000
259.972
676.50
416.53
401.30
1100
272.820
714.75
441.93
401.30
KELTING POINT
BOILING POUlT
ENTHALPY OF liELTING
kJ
kJ
kJ
KOLAR VOLUIIE
J/bar
-3449.833
-3448.797
-3445.683
-2865.400
-2748.710
-2632.212
299.348
239.298
196.419
-3595.808
-2405.081
139.51:18
-3602.799
-2138.165
101.533
--------------------------------2532.944
165.385
-3605.0(}3
-------------------------------118.658
-2271.629
-3609.981
TRANSITIONS IN BEFEBENCE STATE ELE!EHTS

ALU!INUII 11. P. 933 K.
SULFUR ORTHQ-KONO 368.54, ft. P. MOllO 388.36,
B. P. 716.9 K.
HEA~-CAPACITY
EQUATION
0.15871 T
2.8769x10Z +
REFERENCE
239
262
2. 0037x10 T-3
298 850 IC)
262
COilPILED
6-29-76

BARITE
319
POR!ULA WEIGHT
233.398
-------------------------------------------------------------------------------POiftATIOI PRO! THE ELEftEIIITS

TEI'IP.
so
-( G;- H; 9 8 )/T
cop
J/aolK
J/ao1 K
J/IIOlK
0.84
0.84
(H;-8~ 98 )/T
J;aolK
EBTBALPY
GIBBS
PREE EBEBGY
Log Kf
kJ/1101
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
132. 21
132.21
101.75
-1473.190
-1362. 186
238.650
UNCERTAIBTY
1. 300
1.000
400
500
28.475
47.506
164.94
192.50
136.46
144.99
119.28
127.17
600
700
61.172
71.411
216.10
236.57
154.93
165.16
131.46
134.04
800
900
1000
79.352
85.678
90.845
254.59
270.65
285.11
175.24
184.97
194.26
135.72
136.87
137.69
1100
1200
1300
95.132
98.750
101.842
298.26
310.12
321.44
203.13
211.57
219.60
138.30
138.76
139.13
0.228
--------------------------------1475.567
-1321.916
172.886
-1471.073
-1285.793
114.326
-1479.044
-1208.840
90.205
-1533.286
-1532.216
-1130.916
-1086.259
65.637
5o.741
--------------------------------1478.672
-1247.418
108.598
--------------------------------1534.379
-1175.734
76.768
--------------------------------1040.897
-1519.558
49.428
-1538.802
-1537.9~5
-995.598
-950.357
43.337
38.186
!ELT IBG POIBT
BOILHG POIBT
EBTHALPY OF MELTIBG
kJ
kJ
kJ
I!OLAR VOLUME
5.2100 J/bar
52.100 ca 3
TRAISITIOHS IN REFERENCE STATE ELE!ENTS

BARIU! ALPHA-BETA 582, BETA-GAI'I!A 768, !. P. GA!!A 1002
B. P. 2169 K.
SULFUR ORTHQ-!010 368.54, M. P. MOHO 388.36,

B. P. 716.9 K.
c;
1.4120z10Z -
BBFEREIICE
3.5066z10 T-z
298 -

115
120
1300 K)
214
CO!PILED
7-29-76
THBR!ODIIABIC PROPERTIES OP !IIERALS
320
FOR!DLA WEIGHT
AIHYDIITB
136.138
caso.:
-------------------------------------------------------------------------------FORBATIOI FROB THE ELEBBITS

TEI!P.
ca;-a; 98 )/T
J/aolK
so
T
-( G;-8~98 )/T
cop
J/olK
J/olK
J/aolK
1.67
1.67
EIITHALPY
GIBBS
FREE EIIEBGY
kJ/aol
Log Kf
kJ/ol
-------------------------------------------------------------------------------1434.110
-1321.696
231.557
298.15
o.ooo
106.69
106.69
99.66
UICERT"AIITY
400
500
600
700
26.750
44.450
57.920
68.949
137.47
163.16
185.97
206.78
110.72
118.71
128.05
137.83
110.26
120.30
130.21
140.04
800
900
1000
78.449
86.922
94.683
226.12
244.33
:.!61.66
147.67
157.41
166.98
149.84
159.62
169.39
1100
101.917
27fJ.26
176.34
179.15
1200
1 08.759
115.299
121.600
1JUO
1400
294.27
309.77
324.85
I!ELTIIIG POIIIT
ENTHALPY OF BELTING
1723
-1437.948
-1438.205
-1437.601
-1244.262
-1205.527
-1166.775
129.988
104.951
87.066
--------------------------------1133.629
74.019
-1491.651
-1488.262
-1484.470
-1089.009
-1044.846
63.205
54.577
-1480.207
-1001.097
47.538
--------------------------------1482.418
-957.125
41.663
188.90
198.65
208.39
BOIL.IIIG POIIT
-1475.005
-1466.695
-913.642
-870.782
36.711
32.489
kJ
4.5940 J/bar
45.940 c 3
BOLAR VOLOI!E
kJ
0.733
--------------------------------1436.727
-1282.908
167.531
185.51
194.47
203.25
28.033 kJ
4.184
4.226
TBAISITIOIS II REPEBEIICB STATE BLB!EHTS

CALCIUI! ALPHA-BETA 720, B. P. BETA 1112, B. P. 1755 K.
SULFUR ORTH0-1!0110 368.54, B. P. BOlO 388.36,
B. P. 716.9 It.
c:
72.182 + 9.734Jx1o-z T
(EQUATIOI VALID PRO!
IEPBREICE
115
120
214
1.3733x105 r-z
298 - 1400 K)
214
COIIPILED
7-27-76
PIOPBI!IIS I! HIGH !B!PIBI!OIBS

PUBIC SOLPU'B
Pe 2 (S0 4
) 3:
321
POI!OLI IIIGB!
Crystals 298.15 to
399.867
800 1.
-------------------------------------------------------------------------------POB!lTIOI PBO! THB BLB!BftS

!B!P.
so1'
<H;-a298 )/1'
J/aollt
It
J/aolK
-< G;-a298)/T
CDp
J/aollt
J/aollt
EITHILPY
GIBBS
PRBB BIBIGY
Log
If
kJ/aol
ltJ/aol
-------------------------------------------------------------------------------298.15
-2249.555
394.114
o.ooo
282.84
282.84
275.01
-2576.930
OICBITIIITY
o.85
0.85
3.010
2.930
--------------------------------2136.699
279.025
-2583.862
1100
500
600
7fJO
76.175
128. 144
167.683
199.790
370.45
1145.29
511.83
572.27
294.27
317.15
344.15
372.48
319.69
351.28
379.15
405.58
800
221. 129
628.11
1100.98
431.35
It
BOILIIG POIIT
EITBlLPY OP !BLTIIG
ltJ
BITHlLPY OP YlPOBIZITIOJ
H~98 -
ltJ
BOLli YOLUIIB
IIEI.TIIG POUT
ag
0.527
-2586.067
-2585.1115
-2582.307
-2024.4114
-1912.270
-1800.298
211.493
166.1179
134.340
--------------------------------1705.547
111.361
-27111.246
ltJ
13.0770 J/bar
130.710 ca 3
TBliSITIOIS I I BBPBBIICI STlTB BLB!BJTS

IBOI CURIE P. 1042, lLPHl-Gl!ftl 1184, Gl!!l-DILTI 1665,
!. P. DILTl 1809 It.
SOLPUB OBTHQ-!010 368.54, !. P. !010 388.36,
B. P. 716.9 It.
HilT CIPlClTY BQUlTIOI
2.3359x10Z + 0.24933 T
(BQUlTIOI YlLID PBO!
BJPEBIICII
212
212
8.72.30x10
298 - 800 K)
r-,
14
CO!PILBD
6-28-76
322
t'B:UIIODIJA.IUC PBOPBBTIBS 01' IU:U&LS
l'OBIIOL& IBIGBT
lBClii'fB
Ortl&oa:llouic crystals (alpha) 298.15 to 856 1.

(beta) 856 to aeltiag poiat 1342 1.
Bezagoaa.~
174.254
crystals
Ligaid 1342 to 1700 1.
-------------------------------------------------------------------------------lOBilTIOI I'BOII t'B.B BLBDITS

TBIIP.
<a;-a~98 )l'f
J/ao~l
J(
so
J/aO~I
cop
-(G;-a~98 )/T
J/ao~l
BITRll.PI
ltJ/aol
J/aoll
GIBBS
PllBB BIIBBGY
Log 't
Jt.J;aol
-------------------------------------------------------------------------------298.15
-1437.700
-1319.662
231.200
175.56
130.04
o.ooo
175.56
OICBBTllftt
0.35
o.35
o.so
o. 540
400
500
600
700
35.667
59.812
77.5113
91.989
216.65
251.50
281.75
309.:Z4
180.98
191.67
2011.21
211.25
149.06
163.03
175.17
186.44
800
856
105.122
111.137
335.56
350.29
230.'11
239.02
197. 25
203.18
0.095
--------------------------------1278.057
166.898
-14115.193
-11145.811
-11&45.207
-14U.170
-1236.116
-1194.265
-1152.5117
129.137
103.970
86.004
--------------------------------1493.925
-1116.8114
72.923
-1490.991
-1090.949
66.572
-------------------------------------------------------------------------------856
-1090.949
121.868
66.572
360.89
-1481.805
239.02
218.98
900
1000
125.422
132.337
369.92
390.44
2114.50
258.10
203.55
189.91
1100
1200
1300
13112
137.791
143.621
150.682
151.000
408.76
426.82
41t5.65
450.81
270.97
283.20
294.97
299.81
197.63
219.88
252. 38
268.37
-1479.752
-1475.086
-1070.920
-1025.762
62.155
53.581
--------------------------------912.403
-1629.289
46.176
-1621.631
-1611.284
-1610.064
-913.004
-854.352
-828.710
39.742
Jlt.328
32.256
-------------------------------------------------------------------------------1342
119.247
479.06
-1572. 157
-828.710
32.256
299.81
197.61
1400
1500
1600
1100
180.007
181.180
182.207
183.114
IBLt'I IG POI IT
486.97
500.61
513.36
525.34
197.61
197.61
197.61
197. 61
1342
IITBlLPI 01' I!BLt'll6

a;98 -
306.96
319.43
331. 15
342.23
-1568.429
-1562.002
-1555.627
-1549.301
-797.351
-1112.510
-688.093
-6311.058
29.750
25.857
22.464
19.482
BOIL.liG POIIT
37.907 ltJ
B~
BITB lLPI 01' UPOB.IZJ.T.IOL
kJ
IIOLlB YOLOII.B
kJ
6.5500 J/ilar
65.500 ca 3
TBliSIUOIS II IBP:UBICI STlTB BLBIIBBTS

POTlSSIUII I. P. 336.4, B. P. 1030 K.
SULPUB OITBG-11010 368.54,
B. P. 716.9 lt.
a.
P. 8010 388.36,
HBlT ClPJ.CITI JQUJ.TIOIS
c; =
r -
120.37
9.9519z1o-
( ~Olt'IOI YlLID PBOII
c; = -8.4452ll10
0.68449 T
(BQUITIOI YILID PBOII
BBPBBBIICB
239
215
1.7824x1o ,-.
298 856 I)
3.4994z1o ,-.
856 - 1342 l)
215
COIIPILBD
6-28-76
PIOPBRTIES 1T HIGH TIIIPIBUUIBS

POT&SSIUII &LOIIIIUII SULP&TI
323
PORIIUL& lEIGHT
258.195
l&l(so.) 2 : Crysta1s 298.15 to 1000 I.
-------------------------------------------------------------------------------FOIUTIOI 11011 TBI ll.BIIEITS

TIIIP.
J;aolK
It
so
-(G;-a;98 )/T
cop
.J;aolK
J;aolK
.J;aolK
1. 26
1.26
<a;-a;98 )IT
GIBBS
BITBU.PJ
I' IBE IlliG I
Log l(f
ltJ/aol
lt.J/aol
--------------------------------------------------------------------------------2239.790
392.404
192.97
-2470.150
298.15
o.ooo
204.60
2011.60
OICBa'UI BTl
400
500
600
700
511.525
92.070
120.073
1112.010
267.25
321.22
368.60
410.76
212.73
229.15
2118.53
268.75
230.89
252.19
267.34
279.58
800
900
159.885
174.922
448.80
483.56
288.92
308.64
290.27
300.06
1000
187.901
515.66
1.380
1.300
327.76
309.30
IIILTIIG POINT
0.2112
--------------------------------2477.813
-2159.839
282.047
-2479.424
-2479.034
-2477.202
-2080.032
-2000.262
-1920.570
211.300
174.139
1113.315
--------------------------------1852.324
120.945
-2583.688
-2517.590
-1761.151
102.215
--------------------------------2581.667
-1670.019
87.233
BOILIHG POIJT
EITBALPY OF IIILTIIG
ltJ
EITHALPY OF V&POBIZATIOI
ltJ
!lOLli VOLUIIE
kJ
9.2330 J/bar
92.330 ca 3
TBAISITIONS II B&PEBEHCE STATE ELBIIIITS

POT&SSIOII 11. P. 336.4, B. P. 1030 K.
lLUaiHUII
1!.
P. 933 K.
SULFUR ORTH0-11010 368.54, II. P. !lOBO 388.36,

B. P. 716.9 K.

c;
2.3700z10Z +
7.8284z1o-z T 298 -

BEFIBENCE
265
265
5.9884z10 r-z
1000 K)
265
CO!PILED
6-28-76
!BBI!ODtllaiC PIOPBITXBS OP !XIBilLS
3211
POI!ULl IBIG&r
lLOIITB
828.1106
CrJsta1s 298.15 to 700 1.
POR!lTIOI PIO! TBB BLB!BITS

GIBBS
BITBILPI
Pill BIBBGt
-(G;-B~g 8 )/T
TB!P.
kJ/aol
o.ooo
656.05
3. 77
656.05
3.17
745.17
216.150
367.720
481.010
569.996
904.24
1121.21
1312.01
1482.08
688.09
753.119
831.00
912.08
925.89
1014.98
1077.37
1129.36
298.15
UICBB!liiTt
400
500
600
700
IIELTIIG POUT
kJ/aol
--------------------------------
BOILIIIG POXIT
EITHlLPI OF !ELTIIG
kJ
EITHlLPI OP VlPOIIZlTIOI
ltJ
BOLli VOLO!E
ltJ
29.3600 J/bar
293.600 cal
TBliSITIOIS II BBPEBBICE STATE BLBKBITS

POTlSSIUB 11. P. 336.4 9 B. P. 1030 K.
ALOKIIOII II. P. 933 K.
SULFUR OITB0-!010 368.54 9 !. P. !OliO 388.36 9
B. P. 716.9 K.
BElT CAPlCITI EQUATIOI

8.5901z102 +
0.41235 !
(BQOITIOI VALID PRO!

B!l'EIBICB
121
120
6.2756x10 T-JI
298 700 It)
COKPILBD
6-29-76
PIOPZRriiS I f 81GB !IIPZRlTUBIS

POBIULl 111GB!
I&IGliiSI SULrl!B
lnso 4 :
325
150.996
crysta1s 298.15 to 1000 1.
-------------------------------------------------------------------------------POBIIl'l'IOI PRO II '1'81 ILBIII'l'S

TIIIP.
Jfaoll
so
a;-a~98 )/T
-( a;-a~98 )/T
CDp
J/aoll
J/aoll
J/aoll
Bl'l'BlLPI
kJ/aol
GIBBS
Pill IIIIGI
Log 't
kJ/aol
--------------------------------------------------------------------------------957.326
167.720
298.15
112. 1l
112.13
100.50
-1065.250
o.ooo
OJCII!UITY
0.85
o.85
400
500
600
700
28.115
47.368
61.620
72.754
1114.5{1
172.17
196.38
211.88
116.32
124.80
134.76
145.13
118.66
129.00
136.45
142. 52
800
900
81.815
89.433
237.27
254.97
155.1l6
165.54
147.87
152.79
1000
96.002
271.31
175.31
157.45
IIILTIIG POIIT
1.300
1.050
-------------------------------120.156
-1061.1l54
-920.119
-1068.017
-1067.759
-1066.914
-883.166
-846.259
-809.388
92.264
73.674
60.398
--------------------------------178.230
50.813
-1120.316
-1117.466
-735.572
42.692
--------------------------------693.261
36.212
-1116.615
BOILIIG POll!
IITHlLPI OP IILTIIIG
kJ
II!BlLPI OP YlPOilZlTIOI
B~ga
kJ
IIOLl.ll YOLUIII
0.228
B~
kJ
4.3620 J/bar
43.620 ca 3
'l'BliSITIOIS Ill BIPIRIICI STlTI ILIBII!S

BliGliiSI lLPBl-BITl 980 1 BITl-GliiBl 1360 1 GlBBl-DBL'l'l 1410,
B. P. DILTl 1517 I.
SULPUB OITB0-8010 368.54 1 II. P. 11010 388.36 1
B. P. 716.9 I.
HilT ClPlCITY IQUlTIOI
c; =
1.2028z1oa +
BIPIBIICI
3.9993z1o-a T
2.8181z1o
298 - 1000 l)
,-z
(IQUl!IOI YlLID PBOB

242
263
263
COBPILID
6- 8-16
326
THBBaODIIA!XC RBOPBBTXBS OP !ZIBBALS

POB!ULA
!lSCAGUrB
~~~GHT
132.134
-------------------------------------------------------------------------------POBU.TIOI PRO! THE BLB!EITS

TB!P.
so
(a;-a; 98 )/T
J/aolK
J/aolK
-(G;-a; 98 )/T
cop
J/aolK
J/aoll
G~BBS
EITHALPI
FREE BIIBBGI
Log '
k.:J/aol
kJ/aol
-------------------------------------------------------------------------------157.971
298.15
-901.677
o.ooo
220.08
187.49
-1180.850
220.08
UICBBUIHTI
400
500
6110
51.350
87.048
115. 488
1.255
1.339
11.235
-1185.821
-1187.521
-1186.375
-805.519
-710.150
-614.781
1115.190
74.189
53.522
1.25
1.25
279.15
330.31
227.80
243.26
261.73
215.88
243.76
271.64
BOILIIIG POUlT
kJ
BITHALPY OP VAPORIZATIOI
kJ
kJ
IIOLAR VOLU!IE
311.22
!BLT:IHG POUT
EITHALPY OP !BLTIIG
7.4680 J/bar
74.680 ca 3
TRAISiriOIS IH REPEREIICB STATE ELE!EIITS
HEAT CAPACITY
c;
EQUAT~OH
1.0438xloz + 0.27876 T
(EQUATION VALID PBOft
REPEBEIICE
121
239
120
262
298-
6011 K)
262
COIIPILED
6-28-76
327
PIOPIITXBS IT HIGH TI!PBilTOIES
PO&BULl lEIGHT
l!!OIIU! BXSOLPlTE
xa.aso.:
'l'E!P.
crrstals 298.15 to aelting point 417 K.
(a;- B~ 98 )/T
.l/aolK
I(
s;5
298
J/aolK
cop
-< G;-a;98 )/T

J/aolK
J/aolK
115.104
FORal'l'XOI FROB THE ILIJIIITS

GIBBS
EITHlLI.'J
Fill EIBIGI
Log f
kJ/aol
kJ/aol
-------------------------------------------------------------------------------142.88
298.15
o.ooo
o.oo
OICEITlUTI
400
417
40.792
46.355
46.86
511.22
177.40
183.16
417
500
6(10
80.670
102.192
125.093
88.53
126.64
170.211
197.12
223.63
255.57
!ILTIIG POUT
417
IITHALPY OF BELTING
14.310 ltJ
BOILHIG POUlT
IITHALPY OP VAPOBXZITIOI
110111 VOLUIIE
ltJ
I(
kJ
6.5070 J/bar
65.070 c 3
TBliSITIOIS II RIPEBEICI S'l'lTI BLBBIITS

SULPOB OBTH0-!010 368.54, Jl. P. !010 388.36,
B. P. 716.9 K.
HilT CAPACITY EQUlTIOI
c~
63.922 + o.J1941 T
(EQUlTIOK VALID FRO!
RIPIBENCE
239
417-
600 K)
CO II PILED
6-28-76
TBBIIODIIlaiC PIOPIITIIS or BIIBRlLS
328
POIIDLl IIIGBT
TBIIliDIT!
142.037
Orthorhoabic crrstals (V) 298.15 to 450 K. Orthorhoabic crrstals

(III) 450 to 514 K. Bezaqoaal crrstals (I) 514 to 1155 K. Liquid
1155 to 1800 K.
TIIIP.
(a;-a~ 98 )/T
JtaolK
so
J/aolK
-(G;-a~ 98 )/T
cop
JtaolK
Jtaollt
POB!lTIOI PBO! THI ILI!BITS

GIBBS
PBBB BJERG I
Log ltf
IITBlLPI
kJ/aol
kJ/aol
--------------------------------------------------------------------------------1269.985
222.497
149.58
149.58
127.28
-1387.790
298.15
o.ooo
DICIBTliiTI
400
450
36.807
49.929
0.08
0.08
191.96
210.10
155. 16
160.17
0.420
0.420
146.82
162.80
0.074
-------------------------------160.498
-1395.113
-1229.048
-1395.1197
-1208.123
140.235
-------------------------------------------------------------------------------140.235
450
216.98
1616.77
-1392.401
-1208.123
56.809
160.17
500
514
68.032
70.981
234.89
239.66
166.86
168.68
173.30
176.40
-1392.071
-1392.002
-1187.782
-1182.022
124.087
120.122
--------------------------------------------------------------------------------1384.976
-1182.022
120.122
514
84.651
253.34
163.78
168.68
600
700
96.290
107.514
279.30
306.23
183.01
198.72
170.78
178.92
800
900
1000
116.949
125.189
132.600
330.66
353.16
374.15
213.71
227.97
241.55
187.06
195.20
203.34
1100
1155
139.402
143.392
393.91
404.12
254.51
260.72
211.48
215.96
-1384.277
-1382.534
-1148.353
-1109.125
99.973
82.764
--------------------------------1434.556
-1075.797
70.243
-1429.852
-1424.453
-1031.172
-987.159
59.848
51.564
-1418.395
-1414.289
-943.707
-919.498
44.813
41.584
-------------------------------------------------------------------------------1155
424.65
-1390.566
-919.498
41.584
163.931
260.72
196.55
-------------------------------39.(117
1200
431.72
-1583.206
-896.335
165.140
266.58
196.37
167.527
169.543
171.267
172.750
174.035
175.155
1JOO
1400
1500
1600
1700
18(10
ISBLTIIG POUT
447.42
461.93
475.41
487.99
499.79
51(1.89
1155
EITBALPI OP !BLTIIG
-1576.781
-1570.476
-1564.269
-1558.155
-1552.133
-1546.200
279.89
292.39
304.14
315.24
325.76
335.74
195.98
195.58
195.19
1911.80
194. 40
194.01
BOILIBG POINT
23.723 tJ
kJ
-819.366
-782.895
-726.849
-671.219
-615.987
-561.093
BITHALPI OP VlPOBIZlTIOI
33.726
:.!9.210
25.311
21.913
18.927
16.283
kJ
5.3330 J/bar
53.330 ca 3
!lOLli VOLDIB
TBliSITIOIS II BBPEB!ICB STlTB ELI!BITS

SODIDII !. P. 37(1.98, B. P. 1175 lt.
SULPDB OBT&o-!010 368.54, I. P. 11010 388.36,
B. P. 716.9 K.
HilT ClPlCifJ BQUlTIOIS
c;
c;
1.219lx102 + 8.141lx1o-a T
(BQDlTlOI VALID PIOI 514- 1155 It)
2.0110x102 - J.9406z1o-~ T
(BQDlriOI VALID PIO! 1155- 1800 K)
BBPBaBICB
42
215
215
COIPILBD
6-28-76
329
PBOPBITIIS AT HIGH TI!PBBATUBBS

FOBBULA lEIGHT
AIGLBSit!
PbS0 4
303.258
-------------------------------------------------------------------------------POB!ATIOI PBOII THE BLBIIBITS

TJUIP.
K
soT
<a;-e~ 98 )/T
J/olK
-ca;-a~ 98 )/T
CDp
J/olK
J/olK
J/olK
0.29
0.29
liTH ALP!
GIBBS
BIBBGY
PBE.B
Log Kf
kJ/ol
kJ/ol
-------------------------------------------------------------------------------1112.439
298.15
o.ooo
148.57
-813.026
148.57
104.31
-919.940
OICIU'liiTI
400
500
600
26.950
44.154
57.267
1,79. 65
204.82
227.18
152.70
160.67
169.91
108.70
117.60
128.27
700
68.224
247.81
179.59
139.77
800
900
1000
77.911
86.789
95.119
267.25
285.82
303.73
189.34
199.03
208.61
151.72
163.93
176.30
1100
103.065
321.12
218.05
188.78
!BLTIIG POIIT
1.046
1.088
--------------------------------776.138
101.3511
-922.605
-924.147
-924.675
-739.286
-702.287
IITBA~t
20.062 kJ
17.233
61.140
-977.749
-972.4118
-588.781
-545. 8J4
34.172
:.!8.512
-965.983
-503.4911
23.909
--------------------------------664.443
119.582
-928.962
--------------------------------632.308
41.286
-981.9111
BOILIIG POII1'
BITHALPY OP BELTIIG
0.183
OP YAPOBIZATIOI
BOLli YOLUBI
kJ
11.7950 J~u
117.950 cl
TRAISITIOIS II RBPIIIICI STATI ILBBBITS

LIAD
a. P. 600.6, B. P. 2021 I.
SULPUB OITBQ-8010 368.511, B. P. BOlO 388.36,

B. P. 716.9 I.
BlAT CAPACITY EQUATIOI
c~
46.827 + 0.12775 t + 1.72111&10 ,-.

(IQUATIOI YALID PIOI 298 - 1100 I)
IUBBIICB
115
262
262
COBPILID
7-27-76
330
THIR!ODYHA!IC PROPERTIES OP BIHERlLS
ZIHKOSirE
znso.:
TE!P.
FORBULA WEIGHT
161.438
sa
-( G;-s~ 98 )/T
cop
J/aolK
J;aolK
J;aolK
( a;- H~ 98 )/T
J;aolK
PORBUIOIII PRO !I THE ILEIIEIITS

GIBBS
FREE EHIRGY
Log Kf
EHTHlLPY
kJ/aol
.kJ/aol
-------------------------------------------------------------------------------298.15
152.689
o.uoo
110.46
-982.820
-871.530
110.46
104. 13
ONCEI!TliNTY
1.25
1.25
400
500
600
26.375
42.7 J.2
55.022
140.90
164.99
186.21
114.52
122.27
131.19
104.85
111.90
121.1U
700
65.259
205.71
140.45
132.09
800
900
1000
74.312
82.633
90.461
224.08
241.&4
258.59
149.77
159.01
168.13
143.38
155.02
166.90
IIELTI NG POINT
ENTHALPY OF BELTIIIG
0.962
0.837
0.1&9
--------------------------------83l.141
108.797
-985.596
-987.518
-988.579
-794.74 7
-756.123
83.027
65.827
-104&.723
-1042.527
-637.307
-592.033
36.988
30.925
--------------------------------717.266
53.523
-996.002
--------------------------------683.036
44.598
-1049.874
BOlLI IIG POI liT
lr.J
ENTHALPY OF VlPORIZATIOH
lr.J
kJ
!OUR VOLUIIE
4.1570 J/bar
41.570 ca 3
TRANSITIONS Ill REFERENCE STATE ELBaBNTS

ZINC
a.
P. 692.7 B. P. 1178 K.
SULFUR OBTHO-ftOHO 368.54 1 a. P. 8010 388.36,

B. P. 716.9 K.
HilT CAPACITY EQUATION
c;
o.124J2 T
2.3892x1o T-z
(EQIJUION VALID FROB 298 - 1000 K)
40.186 +
BEPERIIICE
115
271
2b2
3
CO!PILED
7-29-7&
331
PROPBllUBS A'f HIGB TBIPIIA'fORBS
.POJliULA II&IGHT
BBILIII'll
AlPo.:
Crystals 298.15 to
121.953
800 1.
-------------------------------------------------------------------------------.POJliA%IOI .PIOI TBB ILIIIBI'l'S

'fliP.
(s;-a; 98 )~
J/aoll
It
SD
'f
.1/aoll
-<a;-a~98)/'f
J/aollt
c;.
BIUUPI
.J/aoll
GIBBS
OBI IIBJlGI
Log
Kt
lt.l/aol
lt.J/ol
-------------------------------------------------------------------------------298.15
-1716.400
281.344
-1605.875
o.ooo
90.79
90.79
93.18
0.21
0.21
120.71
146.87
170.02
190.88
210.61
94.69
102.55
111. 90
121.72
131.60
UICIR'fUIU
ltOO
500
600
700
800
26.025
41f.321t
58.120
69.161
79.005
110.97
122.97
131.01
11t0. 52
156.82
2.092
2.134
0.374
-1716.857
-1716.242
-1715.104
-1713.577
-1796.663
-1568.013
-1530.855
-1493.878
-1457.132
-1442.815
204.763
159.928
130.054
108.733
94.207
BILri IG POI IT
80 ILl IG POIIT
Bl! BALPY O.P IBLTIIG
IITBJLPI OP lAPORIZATlOB
a~ 98 - a~
11t.761 lr.J
.tJ
4.6580 .JAar
lt6.580 ca3
IOLU YOL081
'fRliSIUOIS II RBPDBICB St'lTI BLBIIRTS
ALUIIID! B. P. 933 I.
PBOSPBOBDS. SOBLIIIS 704 I.
BBlT ClPlCITI BQUATIOI
c; = -3.5888&10
3.1323&102 T0.5
8.2315 1'
1.9776&10-. 1'2
1.61t54x10 ~
(BQOATIOB ULID .PiOI
RBPBIIBCB
151
262
298 -
830 I )
262
COIIPILJID
03-15-79
TB BIIIODI IAIIIC PROPB.i'l'IIS OP II II :U&I.S
332
iBITLOCKU'I
PORBU~
Rhoabohedral crystals 298.15 to 1373 1.
IBIGBT
310.183
llooclinic crystals 1373
to 1600 1.
-------------------------------------------------------------------------------!OBIIUIOI PRO! TBB BLEilE ITS

TBBP.
(a;-a;98
Jjaoll
It
so'l
>~
J/aoll
-<c;;-a;98>rr
J/aoll
cop
BITHlLPI
GIBBS
PBBI BIBBGI
'
tJjaol
tJ/aol
J/aolK
Log
-------------------------------------------------------------------------------298.15
-3860.760
o.ooo
-4085.925
676. 394
235.98
235.98
227.82
UtfC:UT.UWTJ
0.84
o. 84
400
500
600
700
62.075
102.738
133.072
157.386
307.46
366.59
418.1J5
465.17
245.38
263.85
285.38
307.78
255.19
275.25
291J.10
312.39
800
900
1000
177.887
195.822
211.9.0
508.06
51J8.00
585.60
330.17
352. 18
313.66
330.37
348.17
365.87
1100
226.735
621.29
394.56
383.49
1200
1300
1373
240.529
253.553
262.681
655 2
688.21
711.67
411J. 89
4JIJ. 66
448.99
401.06
418.60
ll31.39
2.100
2. 200
0.385
-4085.591
-4084. 165
-4081. 949
-4079. 141
-3783.851
-3708.572
-3633. 634
-3559. 161
494. 122
387.434
316. 337
265. 589
--------------------------------4248.877
-3529.180
230.433
-4242.604
-4236.054
-3439.542
-3350.664
199.627
175.021
-4229.191
-3262. 464
154. 922
--------------------------------4242.840
-3173.049
138. 120
-4228. 705
-4217.337
-3084.466
-3020.356
123.936
114.907
-------------------------------------------------------------------------------1373
273.956
7 22.95
448.99
330.54
-4201. 857
-3020.356
114. 907
11400
1500
1600
274.9149
278.654
281.897
729.27
752.08
713.41
454.32
1473.42
491.52
I!ELTIIG POIIT
-2997.637
-2911.910
-2826. 637
BOlLI IG POIWT
BITBlLPJ or BBLTIWG
a~ 98
-4200.391
-4194.454
-4188. 637
330.54
330.54
330.54
a:
!BAISITIOIS II BBrJBBICB STlTB
111.844
101. 402
92. 281
tJ
!ITBlLPI or YlPOBIZlTXOI
kJ
!OLlB YOLUBB
9.7620 Jj!)ar
97.620 ca 3
ELE!BI~S
ClLCIUB lLPBl-BITl 720, a. P. BEtl 1112, B. P. 1755 l.

PHOSPBOBUS. SOBJ.IBBS 7011 I.
HilT ClPlCitl BQUlTIOI
c; =
1.9285z10Z
BEPIBIICI
0.17419 'l
(IQOlTIOW YlLID PBOB

115
2111
1.17l6x10
298 - 1373 K)
,-z
21.
CO! PILED
03-15-79
333
PBOPIRTIJS lT BIGB TB!PBBlTOBJS
IIBITLOCKIT!
ca
< P0 4 ) 2 :
FOB!DLl WEIGHT
Bhoabohedral crystals 298.15 to 1373 1.
310.183
!onoclinic crystals 1373
to 1600 1.
-------------------------------------------------------------------------------FOB!lTIOI FRO! THB OXIDES

so
( B;-a~ 98 )/T
TB!P.
-(G;-a~98)/T
cop
JfaolK
Jfaoll
JfaolK
J/aollt
400
500
600
700
800
900
1000
62.075
102.738
133.072
157.386
177.887
195.822
211.940
307.116
366.59
418.115
465.17
508.06
548.00
585.60
245.38
263.85
285.38
307.78
330.17
352.18
373.66
255.19
27 5. 25
294.10
312.39
330.31
348.17
365.87
1100
1200
1300
1373
226.735
240.529
253.553
262.681
621.29
655.42
688.21
711.67
394.56
414.89
434.66
448.99
383.49
1101.06
418.60
431.]9
GIBBS
FB!B BIEBGI
BITHlLPI
Log
't
kJ/aol
kJ/aol
--------------------------------------------------------------------------------7H.1.653 -712.396 124.809

298.15
o.ooo
235.98
235.98
227.82
UICBBTUBTI
0.84
0.84
-712.0011
-714.778
-718.596
-723.271
-728.667
-734.658
-741.176
-712.832
-712.7115
-711.990
-710.543
-708.363
-705.466
-701.880
93.086
74.460
61.984
53.021
46.251
40.944
36.662
-------------------------------------------------------------------------------1373
722.95
448.95
273.956
330.54
1400
1500
1600
274.949
278.654
281.897
729.27
752.08
713.41
454.32
473.42
491.52
330.54
330.54
330.54
It
BOILIIG POIIT
I(
JITBlLPI OF YlPOIIZlTIOI
kJ
!BLTI BG POIIT
BITHlLPI OP !ILTIIG
a~ 98
a~
kJ
!OLl.l YOLU!I
9.7620 J/bar
97.620 cal
TlliSITIOIS II BJFIIBICI STlTB OIIDBS

PzO !. P. 842 1.
HilT ClPlCITI BQDlTIOI
c;
1.9285x10Z + 0.17419 T
(BQDlTIOI flLID PIOI
IIPIIBICB
115
1.1736z10 r-z
298 - 1373 I)
COIPUID
7-27-76
TBBiliiODJIAIIIC PllOPBil'liBS OP IIIIBillLS
BJDBO.IJAPATITB
POIIIULl iBI&BT
502.321
-------------------------------------------------------------------------------POBIIlTIOI PBOII TBB BLBIIBITS

TEIIP.
( a;-u;98
p;
J/aolK
so
>l'l
J/aolK
-(G;-a~ 98 )/T
J/aol II:
cop
Bl'lBlLPJ
J/aol II:
GIBBS
PBBI IIBBGJ
kJ/aol
Log
J[f
k.J/aol
-------------------------------------------------------------------------------298.15
390.37
-6669.259
o.ooo
385.10
390.37
-6286.093
1101. 302
UliCBBTU ITJ
1. 67
1.&7
400
500
600
700
106.900
118.142
229.773
269.189
513.31
616.52
705.113
783.35
406.41
438.38
475.66
514.16
U6.35
477.23
1197.55
513.28
800
900
1000
300.561
326.389
348.259
852.78
915.55
972.97
552. 22
589.16
621f. 71
526.80
539.15
550.89
1100
367.201
1026.01
658.81
562.29
1200
1300
1400
1500
383.926
398.936
412.593
425.167
1075. lf2
1121.76
1165.49
1206.91
691.49
722.82
752.90
781.80
IIELTI IIG POIIIT
5.000
0.876
-6667.545
-6663.244
-6658. 313
-6653. 651
-6155. 325
-6027. 762
-5901.106
-5775. 324
803.807
629.719
513.739
430.962
-------------------------------373.231
-6909. 611
-5716.202
-6902.718
-6897. 107
-5567.379
-5419. 322
323. 123
283.078
-6892.774
-5271.788
250.338
--------------------------------6924.440
-5121. 478
222.933
-6911.624
-6897. 959
-6883.402
-4971. 763
-4823.090
-4675.360
H~
199. 769
179.952
162.811
BOILiliG POUT
ENTHALPY OP IIBLTING
H;98 -
573.50
584.61
595.67
606.72
5.000
BHTH&LPJ OP V&POBIZlTIOB
ltJ
64. 21f5 ltJ
15.9600 J/bar
159.600 ca 3
IIOLlll VOL 0 liB
TRlBSITIOIS IM REPBaEICB STATE ELBIIEHTS

ClLCIOII
ALPHA-BETA 720, ft.
P. BBTl 1112, B. P. 1755 K.
PHOSPHORUS. SOBLIItBS 70if K.
HEAT CAPACITY BQO&TIOB
3.8776x102 + 0.11856 T
( BQU&TIOI VALID FBOll
REFEBEICE
52
120
+ 1.8112x10
298 - 1500 K)
r-
1.2703x10l'
214
150
.,-z
COIIPILBD
03-15-79
335
PROPBRTIBS lT HIGB TBIPBBlTUBBS

PLUOilPl'lUB
POIBOLl IBIGBT
504.313
-------------------------------------------------------------------------------POiill!llTIOI PRO! 'fBI BLII!lBI'fS

<a;-a; 98 )/T
TBI!lP.
J/aoll
so'l
J/8011
-(G;-a~ 98 )/T
cop
J/oll
J/aol.l
BITHlLPI
GIBBS
PIIBB BBBBGI
kJ/aol
Log If
kJ/ol
-------------------------------------------------------------------------------298.15
-6819.860
o.ooo
387.86
387.86
315.93
1131.033
-6455. 778
1.. 67
1.67
SOi.Oil
UICBBTll ITt
400
500
600
700
102.725
170.858
220.715
259.059
604.86
690.119
765.85
403.31
4311.00
1169.17
506.79
426.53
ll58.27
1180.52
IJ96. 94
800
900
1000
289.611
3111.611
335.1182
833.07
891.67
948.80
543.46
579.06
613.32
509.49
519.30
527.09
1100
353.196
999.34
646. 14
533.35
1200
1300
1400
1500
1600
368.427
381.665
393.271
403.535
1112.661
1045.97
1089.23
1129.56
1167.31
1202.78
677.54
707.57
736.29
763.78
790.12
I!IBLTIIC POIIT
H~
5. 000
0.876
-6818.464
-6814.827
-6810. 383
-6806.063
-6331.506
-6210. 185
-6089.647
-5969.908
826.813
648.776
530. 153
445.482
--------------------------------5916.800
386. 329
-7062. 361
-7055. 955
-7051. 144
-5773. 932
-5631. 760
335. 112
294.174
-7048.036
-5490.009
260.700
--------------------------------7081. 464
232. 678
-5345.348
-7071. 045
-7060.490
-7049.820
-7039. 109
-5201. 104
-5057.699
-4914.979
-4773.056
BOILIIG POIIT
IRTHlLPl OP aJTIIG
B~g 8
538.40
542.49
545.79
548.45
550.55
5. 000
kJ
63.471 kJ
208.984
188. 706
171. 155
155. 825
BNTHlLPI OP YlPOIIZlTIOI
I!IOLlB YOLU!IB
15.7560 J/bar
157.560 c 3
TlliSITIOIS II RBPBRBICB S'flTB BLBI!IEITS

ClLCIDII lPBl-Bftl 720, 1!. P. BETA 1112, II. P. 1755 lt.
PHOSPHORUS. SOBLIBBS 704 I.
BElT ClPACZTI IQUlTlDI
c; =
7.54llx102- 3.0255K10-z T
6.200Sx103 T-os
( IQUATIOI YlZD PROII 298 - 1600 It)
UPIBBICB
52
120
COIIPILBD
03-15-79
THBBBODIIABIC
336
PBOPIB~IBS
OP BIIBBALS
DICISIOB OBAilTE
POB!ULl WEIGHT
567.837
Cs 2 U0 4 : Crystals 298.15 to 1100 K.
-------------------------------------------------------------------------------PORBlTIOI PBOB THE ELBIIEITS

TE!P.
so
T
<s;-s; 98 )/T
J/aolK
J/aolK
-(G;-a~ 98 )/T
cop
J/aolK
J/aolK
EITHlLPI
GIBBS
PBEE EIEBGI
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
219.66
314.881
-1797.300
219.66
152. 76
-1920.000
UliCE.BTliiTT
0.42
0.42
3.500
3.800
0.666
--------------------------------1925.011
-1153.901
229.037
400
500
600
100
800
900
40.225
65.142
82.482
95.326
105.284
113.278
266.01
302.11
333.61
360.17
383.54
404.41
225.78
237.63
251.13
264.84
l78.26
291.13
162.06
167.28
170.92
173.17
116.17
178.31
1000
119.883
423.30
303.42
180.27
-------------------------------77.964
-2053.313
-1492.575
1100
125. 457
440.57
315.11
182. 11
--------------------------------1436.400
-2055.172
68.209
BOILIIG POIIT
IIELTIIG POIIT
EITHALPI OP IIELTIJG
kJ
s;98 - H~
30.815 kJ
-1924.351
-1922.817
-1921.005
-1919.439
-1918.614
-1711.186
-1668.681
-1626.473
-1584.503
-1542.686
178.767
145.272
121.369
103.458
89.536
EITBALPT OP VAPOBIZlTIOJ
BOLli VOLU!B
kJ
8.5400 J/bar
85.400 ca 3
TBAJSITIOJS II BEPBBEJCB STATE BLBBBITS

CESIOR II. P. 301.55 1 B. P. 942 K.
OBAJIOII ALPHA-BETA 941, BETl-GlB!A 1048 1 II. P. 1405 K.
1.738JJ:10Z +
1.3456x1o-z T 1.8078J:10Z T-os

298- 1100 K)
(BOUlTIOJ VALID PRO!

BEPBBBIICB
64
193
185
89
COIIPILBD
5-19-76
PBOPBI~IIS
AT HIGH TB!PIBlTUBBS
331
D.ISODIO! UBUUB ( lJ.PBl)
POB!OLl IIIGBT
348.006
crystals 298.15 to 1100 1.
Ja 1 00 4 :
-------------------------------------------------------------------------------POB!lTIOI PBO! TBE BLE!BITS

TBBP.
so
(H;-a~ 9 a)/T
J;aolK
J/aoll
cop
-(G;-&~ 98 )/T
J/aoll
GIBBS
PRBB EIUGY
EITBlLPY
J/aoll
Loq If
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
166.02
166.02
146.67
-1887.000
-1768.600
309.853
OICBBTUITY
0.33
0.33
3.000
:3.600
0.631
--------------------------------1727.808
225.629
-1891.627
400
500
&00
700
800
900
39.225
64.124
81.733
94.961
105.362
113.833
211.19
247.70
278.64
305.50
329.29
350.67
171.97
1&3. sa
196.91
210.511
223.93
236.84
159.811
167.11
172.22
116.311
179.93
183.23
1000
120.929
370. 111
2119.21
186.35
--------------------------------1485.611
77.601
-1886.911
1100
127.0111
388.011
261.03
189.35
-------------------------------68.632
-111115.310
-1889.7611
!ELTI liG POUT
BOILIIG POIIT
EliTHlLPI OP !ELTIIG
kJ
BITBALPI OP YlPOBIZlTIOI
kJ
8~ 98 - B~
26.227 kJ
-1890.668
-1889.384
-1887.998
-1886.6118
-1885.1152
-1686.968
-1646.3112
-1605.933
-15&5. 736
-1525.687
176.237
143.327
119.837
102.232
88.5119
5. 8500 J/bar
58.500 cal
IIOLlB YOLO!B
TRAISITIOIS II BBPBBEICB STATI BLB!BITS

SODIO! 5. Po 370.98, 8. P. 1175 I.
OBliiOB lLPHl-BBTl 9111, BBTl-GlB!l 10118, B. P. 11105 I.
KElT ClPlCITI BQOlTIOI
c;
1.5846x10' + 2.74311x1o-z T + 84.123

(BQOATIOI YALID PBOB 298- 1165 I)
BBPBBBICE
195
r-os
2.2082x1o ,-,
89
1811
CO!PILID
5-19-76
338
THBRKODIIA!IC PBOPBBrlBS OF !IIBBALS
TBISODIU! UBliiU! OXIDE
POB!ULA WEIGHT
370.996
-------------------------------------------------------------------------------POB!ATIOII FBO! THE BLBIIBITS

TBI!IP.
so
(H;-u~ 98 )/T
J;aolK
J;aolK
-(G;-u~ 98 )/T
cop
J/aolK
JjaolK
BITHALPY
GIBBS
PBBB EJBBGY
.kJ/aol
Log Kf
.kJ;aol
-------------------------------------------------------------------------------298.15
o.ooo
-1897.400
332.418
198.20
198.20
173.01
-2021.500
UIICBBTliBTY
0.40
0.40
900
46.1(10
74.996
95.115
110.046
121.686
131.133
251.32
293.81
329.48
360.24
387.37
411.71
.205.22
.218.81
234.36
250.19
265.68
280.58
187.01
19 l. 46
197.78
201.42
204.92
208.44
1000
139.042
4JJ.86
294.82
212.08
1100
145.851
454.24
308.39
215.83
1200
151.844
473.19
321.35
.219.72
400
500
600
700
suo
BILTIIIG POIHT
.kJ
EITHALPY OF !BLTiliG
4. 200
4.000
31.109 kJ
0.736
-------------------------------242.164
-1854.425
-2029.052
-2028.509
-20l7.648
-2026.683
-2025.742
-2024.923
-1810.829
-1767.368
-1724.045
-1680.&85
-1637.824
189.177
153.864
128.650
109.751
95.057
--------------------------------2026.726
-1594.696
83.299
--------------------------------1551.293
73.665
-2029.880
--------------------------------15(1 1.720
65.368
-2320.051
BOILING POlliT
EITHALPY OF YAPOBIZATlOll
.kJ
!OI.AB VOLUIIE
J/bar
TBAISITIOIS II BBFBBBICB STATE BLBBBITS

SODIUI!I 1!1. P. 370.98 1 B. P. 1175 K.
UBAliiU! ALPHA-BETA 941 1 BBTA-GAI!I!A 1048 1 !. P. 1405 K.
1.1152x102 + 5.3894x1o-z T
( EQUlTIOI VALID lRO!I 298 -
BBPEBBICE
62
194
1.6100x103
1212.70 K)
r-os
89
186
CO!PILED
6- 8-76
PBOPBBTIBS IT BIGB TBBPBBl!OBIS
339
KUIIT!
POBBOLl lEIGHT
162.047
-------------------------------------------------------------------------------POBBlTIOI PBOB THE BLIIIEITS

TIIIP.
(u;-a; 98 )IT
JfolK
so
T
-(G;-a~ 9 a)/T
J/olK
J/olK
cop
BITHlLPY
GIBBS
Pill BIBRGY
Log 't
kJ/801
kJ/801
J/olK
-------------------------------------------------------------------------------298.15
o.ooo
83.76
83.76
121.70
-2591.730
-2441.276
427.703
0.34
o. 34
34.825
59.438
77.995
92.1176
104.096
113.656
123.76
158.92
190.03
217.66
2112.42
264.80
88.94
99.48
112. 04
125. 18
138.32
151.14
149.24
165. 27
175.60
182. 71
187.911
192.11
1000
121.680
285.23
163.55
195.72
1100
1200
1300
1400
1500
128.566
134.589
139.959
144.836
149.345
304.05
321.52
337.88
353. 31
367.97
175.48
186.93
197.92
208.47
218.63
199. 13
202.59
206.26
210.28
214.76
OWCBBTAIITI
400
500
600
700
800
900
I!BLTIIIG POUT
1.900
1. 920
0.336
-2592.612
-2592.009
-2590.697
-2589.084
-2587.1114
-2585. 835
-2389.682
-2339.004
-2288.516
-2238.279
-2188.275
-2138.464
312.062
244.355
199.234
167.023
142.880
124.1111
--------------------------------26115.752
-2087.312
109.030
-2603.794
-2601.638
-2599.246
-2596.584
-2593.592
-2035.566
-1983.993
-1932.6(16
-1881.451
-183(1. 465
96.661
86.361
77.653
7(1.198
63.743
BOIL:UG POUT
!ITHlLPY OP !ELTIIG
kJ
EITHlLPY OP VlPOBIZATIOI
16.041 kJ
kJ
4.40911 J/bar
44.090 ca 3
IIOLlB VOLUBB
TBliSITIOIS II RBP!BBICB STATE !L!IIEITS

lLUI!IIUII. B. P. 933 K.
HE AT ClP lCITY EQ Ul TIO I
4.3612x10Z- 0.13576 T
( EQUlTIOI VALID FRO!
UP!ll!ICE
20S
120
4. 7 236x 1 o-s TZ
298- 1500 K)
99
98
CO!PILBD
1- ij-76
3110
T!!RBOD!IlBIC PBOPIITIIS OP llllllLS

POIBOLl 111GB!
KUIITI
162.0117
-------------------------------------------------------------------------------l'OBBATIOI PBOB THE OUDIS

TIIIP.
(a;-a; 98 )IT
J/aolK
It
so
J/aolK
-(G;-a; 98 )/T
J/aolK
cop
GIBBS
l'IBB IlliG!
BITHlLPY
J/aolK
Loq Kf
kJtaol
kJtaol
--------------------------------------------------------------------------------2.760
0.1184
298.15
o.ooo
-5.330
83.76
83.76
121.70
UICEBTliiTI
o. ]4
0.]11
]II. 825
0.970
0.960
-5.460
-5.485
-5.536
-5.728
-6.138.
1100
500
600
700
800
59.11]8
77.995
92.476
1011.096
121.76
158.92
190.0]
217.66
242.42
88.911
99.48
112.04
125. 18
138. 32
149.24
165.27
175.60
182.71
187.94
900
1000
113.656
121.680
264.80
285.23
151.14
16 ]. 55
192.11
195.72
1100
1200
1300
11100
1500
128.566
134.589
139.959
144.8]6
149.345
]04.05
]21. 52
ll7. 88
353.31
367.97
175.48
186. 9]
197.92
208.47
218.63
199.13
202.59
206.26
210.28
214.76
!liLTING POINT
BOILIIG PODT
kJ
EITHALP! OP VAPOBIZlTIOI
a;ga - ~~~
-1.860
-0.955
-0.040
0.887
1.854
0.24]
0.100
0.0011
-0.066
-0.121
-------------------------------2. 902 -0.168

-6.710
]. 958 -0.207
-6.552
4.986 -0.237
-6. ]43
6.017 -0.262
-6.066
7.007 -0.282
-5.681
7. 964 -0.297
-5.140
8.861 -0.309
-4.399
4. 4090 J/bar
44.090 cal
ROLli VOLUBE
TRANSITIOIS II BBPEREICE STATE OXIDES

SiOz ALPHA- BETA TBAISITIOI 844 lt.

4.]612x10Z- 0.13576 T
( IQUATIOI VALID PROII
BBPBBBIICE
205
120
4.7236x1o-s TZ
298 - 1500 It)
99
98
COIIPILBD
1- 8-76
PIOPIBTIIS IT HIGH
341
~EBPIIlTOIIS
FOIIIULl WEIGHT
IIDALOSITB
162.047
-------------------------------------------------------------------------------POBIUTIOII PIOII Till BLIUIEITS

TB!P.
K
( H;-s~ 98 )/T
J/olK
so
T
-(G;-H~ 98 )/T
JfolK
JtolK
o. ll2
0.42
cop
ElfTHlLPY
kJ/ol
J/ol K
GIBBS
FREE EIIEBGY
l.oq
't
kJ/aol
--------------------------------------------------------------------------------2439.892
427.458
122.70
-2587.525
298.15
93.22
93.22
o.ooo
OICBBTli ITY
400
500
600
700
800
900
34.900
59.381l
77.800
92.157
103.675
113.133
133.31
168.35
199.29
226.77
251.37
273.60
98.1l1
108.97
121.1l9
1311.61
147.69
160. IJ7
11l8.98
161l .u
174.61
181.61
186.74
190.73
1006
121.063
293.87
172.81
194.06
1100
1200
1300
1400
1500
1600
127.835
133.723
138.928
11J3.607
147.871
151.826
312.51
329.78
31J5.90
361.04
375.36
388.99
181l. 67
196.06
206.97
217.43
227.49
237.16
197. OS
199.93
202.86
205.96
209.33
213.03
!ILTIIG POIIT
2.100
0.368
-2588.377
-2587.831
-2586.609
-2585.102
-2583.546
-2582.100
-2389.267
-2339.541
-2289.984
-2240.674
-2191.5&7
-2142.649
312.005
244.409
199. 360
167.201
143.094
124.356
-2600.393
-2598.472
-2596.362
-2591l.099
-2591. 597
-2588.828
-2041.471
-1990.739
-1940.168
-1889.788
-1839.555
-1789.522
--------------------------------2092.364
109.294
-2602.164
96.941
8&.654
77.957
70.509
64.059
58.422
BOILIIG PODT
IITHlLPY OF !ELTIIG
H~ 98 - H~
2.100
IITHlLPY OF VlPOIIZlTIOI
kJ
17.096 kJ
kJ
5.1530 J/bar
51.530 ca 3
IIOLll VOLOIIB
TlliSITIOIS I I IIPEBEICI STl'll BLIIIBBTS

lLO!IIOII II. P. 933 K.
SILICOI II. P. 1685 K.
HilT ClPlCITI BQOlTIOI
cop
4.08Ux10Z - 0.11050 T
( IQOlTIOI VlLID PBOII
BIFIIIICI
205
120
3.5897x1o-s TZ
298 - 1600 K)
285
267
COIIPILID
1o-12-77
342
THBR!ODlllaiC PIOPBRTIBS OP !IIBIALS
.lJDlLUSIT!
POI!ULA WEIGHT
162.047
-------------------------------------------------------------------------------POBIIATIOII PRO! THE OJIDES

TBIIP.
soT
<B;-a;98 )/'1'
J/olK
J/olK
-(G;-s; 98 )/T
JtolK
cop
GIBBS
FBBB BIIBBGI
BITBALPI
kJ/ol
J/olK
Log Kf
kJ/ol
--------------------------------------------------------------------------------1.376
298.15
o.ooo
-1.125.
0.241
93.22
122.70
93.22
DICEBTlliTY
0.42
0.42
1.260
1.260
400
500
600
700
800
34.900
59.3811
77.800
92.157
103.675
133.31
168.35
199.29
226.77
251.37
98.41
108.97
121.49
1311.61
147.69
148.98
164.49
174.61
181.61
186.74
900
1000
113.133
121.063
273.60
293.87
160.47
172.81
190.73
194.06
1100
1200
1300
1400
1500
1600
127.835
133.723
138.928
143.607
147.871
151.826
312.51
329.78
3115 90
361.04
375.36
388.99
184.67
196.06
206.97
217.43
227.119
237. 16
197.05
199.93
2(.12.86
205.96
209.33
213.03
IIELTIIG POI IT
BOILIIG PODT
!ITHlLPY OP !BLTIIG
kJ
BITHALPY OP VAPORIZATION
kJ
-1.225
-1.307
-1.1148
-1.746.
-2.267
0.189
0.156
0.131
0.113
0.094
--------------------------------1.283
0.074
-2.975
-1.0911
o.p57
-2.964
-2.942
-2.900
-2.817
-2.655
-2.4011
-1.995
-0.919
-0.729
-0.555
-0.313
-0.229
-0.090
0.044
0.032
0.(.122
0.014
0.008
0.003
5.1530 J/bar
51.530 c3
IIOL lB VOL Oft!
17.096 kJ
-1.445
-1.492
-1.508
-1.508
-1.438
0.221
TBAISITIOIS II RBFBBBICB STATE OIID!S

SiOz ALPHA- BETA TBAISITIOI 844 K.
HEAT CAPACITY BQOATIOI

4.084lx102- 0.11050 T
(EQOATIOI VALID FRO!
R!F!REIC!
205
120
3.5897x1o-s TZ
298- 1600 K)
285
267
COIIPILBD
10-12-77
PBOPEBTIBS AT HIGH TEftPEBirORBS
SILLiftAIITI
343
PORBOLl WEIGHT
162.047
Crystals 298.15 to 1800 1.
-------------------------------------------------------------------------------POBII&TIOI PRO! TBB BLUBUS
(a;-a2 98 )IT
TBBP.
K
J/aoll
soT
-(G;-s298>1T
J/aolK
J/oll
cop
EITHll.PI
GIBBS
FB!B EIBBGI
ltJ/aol
J/olK
Log Kf
ltJ/aol
-----------~-------------------------------------------------------------------298.15
o.ooo
96.11
96. 11
122.60
-2585.760
-2438.988
427.302
OICBRT liiTI
0.42
0.42
1.750
1.740
0.307
400
500
600
700
300
900
35.025
59.310
77.Jil8
91.339
102.595
111.922
136.33
171.20
201.72
228.12
252.94
274.91
101.30
111. 89
124. 37
137. 38
150.3Q
162.99
149.06
162.79
171.78
178.53
184.10
188.97
1000
119.855
295.05
175.19
191.41
1100
1200
1300
1400
1500
126.732
132.801
138.236
141.164
147.683
313.68
331.014
347.32
362.68
377.23
186.95
198.24
209.08
219.52
229.55
197. 57
201.53
205.37
209.10
212.76
!BLTIIIG POIHT
I{
BOILING POIIT
EBTHALPI OF BELTIBG
ltJ
EHTHALPY OP VAPOBIZATIOH
ltJ
ftOLAB VOLUftE
H~98
H~
17.414
-2586.562
-2586.103
-2585.115
-2583.910
-2582. 645
-2581.425
-2388.660
-2339.238
-2289.948
-2240.847
-2191.922
-21143.153
311.928
244.380
199.359
167.215
143.118
124.386
--------------------------------2601.607
-2092.987
109.327
-2599.842
-2597.814
-2595.516
-2592.954
-2590.115
-2042.207
-1991.593
-1941.148
-1890.939
-1840.878
96.977
86.692
71.997
70.552
616.105
4.9900 Jfbar
49.900 c 3
TRlHSITIOIS II BEPEIEICE STATE ELE!EHTS

lLUIUNOB II. P. 933 K.
SILICOI ft. P.
1685 K.
c;
1.6442x1oz + 3.3594x1o-z T
4.&078x1o T-z
(EQOATIOH VALID FRO! 298- 1500 K)
REFERENCE
205
120
31
267
CO! PILED
7- 8-76
THBBIOD!IliiC PIOPBITIBS OP KIIBBlLS
3411
POIIULl IIIGBT
SILLUliiTI
162.0117
crrstals 298.15 to 1800 l.
-------------------------------------------------------------------------------POBKl'liOI PBOI THE OIIDBS

TBKP.
K
so
(a;- H; 98 )/T
-(G;-a~9B )/T
cop
J/olK
J/oll
J/olK
1100
500
6(10
700
BOO
35.025
59.310
77.3118
91.339
102.595
136.33
171.20
201.72
228.72
252.94
101. 30
111.89
1211.37
137.38
150.311
1119.06
162.79
171.78
178.53
1811.10
900
1(100
111.922
119.855
2711.91
295.05
162.99
175.19
188.97
193.41
1100
1200
1300
11100
1500
126.732
132.801
138.236
143.1611
147.683
313.68
331.011
347.32
362.68
377.23
186.95
198.24
209.08
219.52
229.55
197.57
201. 53
205.37
209.10
212.76
Bl'l'BlLPJ
GIBBS
PI!B BIBBGY
ltJ/ol
J/olK
Loq If
ltJ/ol
--------------------------------------------------------------------------------0.1172
298.15
0.640
0.083
o.ooo
96.11
96.11
122.60
UICBBTliiTJ
0.590
0.600
o. 42
0.112
B3B
0.109
-o.
-1.189
0.1211
-1.472
0.128
-1.681 0.125
-1.793 0.117
--------------------------------2.300
-1.787.
0.1011
-1.717
0.090
-2.407
-1.655.
0.079
-2.391
-1.583
0.069
-2.242
-1.951
-1.535
0.062
-1.510
0.057
-1.524
0.054
-0.922
-1.552
0.590
0.1121
0.046
-0.554
-1.369
ftELTIJG POIJT
BOILIIIG POUT
EJTHlLPJ OP KELT IIIG
BITBlLPJ OP VlPOBIZlTIOI
17.414 kJ
ftOLlB VOLUIIE
kJ
4.9900 J/bar
49.900 c3
TRUSITIOIS IK BEPBBBICB STATE OIIDIS

Si0 2 ALPHA - BETA TBliSITIOI 844 K.
BElT CAPACITY EQUATIOJ
c;
1.61142ztoz + 3.3594z10-, T - 4.607Bz1o ,-z

(EQUATIOI VALID PBOft 298 - 1500 K)
REPEREICB
205
120
31
267
COli PILED
7- 8-76
345
PROPERTIES lT HIGH TEBPEBlTUBES
FOIISULA IIBIGHT
f!ULLITE ( 3-2)
426.(156
cr ysta1s 2 98.15 to ae1t ing point 2133 1.
-------------------------------------------------------------------------------FORIIlTIOI FROB THE ELEIIEITS

TEIIP.
Jtao11
so
( H;-n~ 98 }/T
-(G;-H~ 98 )/T
Jtao11
J/11011
4. 18
4. 18
cop
EIITHlLPJ
J/11011
GIBBS
FREE EIIEBGY
Log Kf
ltJ/1101
ltJ/aol
-------------------------------------------------------------------------------298.15
0.000
269.57
326.10
-6431.286 1126.739
269.57
-6810.421
OIICBRTliHTY
2.200
2.220
0.389
-6812.769
-6811.616
-6808.737
-6805.066
-6801.209
-6797.606
-6301 .260
-6173.481
-6046.104
-5919.294
-5792.991
-5667.173
822.864
644.942
526.362
441.705
378.245
328.916
400
500
600
700
800
900
92.275
156.542
204.813
242.569
273.006
298.133
375.60
467.72
549.00
621.27
686.15
744.93
283.32
311.18
344.19
378.70
413.14
446.80
392.41
431.95
458. 85
478.36
493. 13
504.61
1000
319.249
798.58
479.33
513.73
1100
1200
1300
1400
1500
1600
331.275
352.847
366.438
378..400
389.011
398.476
847.90
893.50
935.89
975.45
1012. 54
1047.42
510.63
540.65
569.45
597.05
623.53
648.94
521.06
527.02
531.88
535.85
539.09
541.73
1700
1800
406.968
414.621
1080.33
1111.46
673.36
696.84
543.85
545.53
BOIL I IG POIIIT
EIITHALPY OF flPOBIZlTIOI
ltJ
kJ
!lOLli YOLOIIB
f!EL!I IG POI IT
2133
EIITHlLPI OF IIELTIIG
---------------------------------6858.509
-5537.159
289.233
-6853.935
-6849.053
-6843.927
-6838.642
-6833.221
-6827.734
-5405.233
-5273.739
-5142.630
-5012.022
-4881.711
-4751.816
256.674
229.561
2(16.634
187.002
169.997
155.132
---------------------------------4621.451
-6923.211
142.001
-6911.091
-4486.139
130.185
13.4550 J/bar
134.550 cal
TBliSITIOIS II BEFERBICE STATE EL!BEITS

lLOIIIIUB B. P. 933 I.
SILICOI.... II.
P.
1685 I.
H!lT ClPlCITJ EQOATIOI
7.5455x10Z 2.9426x1o-z T
6.5757x10~ T-os
(BQOATIOII VALID FIOII 298 - 1800 I)
IBl'!IBIC!
213
99
21l
99
267
COIIPILBD
7- 9-76
THEB!ODYNA!IIC PROPERTIES OF ftiNEBALS
346
ftULLITE ( 3-2)
FORMULA WEIGHT
426.056
Crystals 298.15 to aeltinq point 2133 K.
-------------------------------------------------------------------------------FOB!IATION FRO!! THE OXIDES

soT
( H;-H~ 98 )/T
TE!P.
J/aol K
-(G;-H~ 98 )/T
JjaolK
JjaolK
4.18
4. 18
CDp
GIBBS
FREE ENERGY
ENTHALPY
kJ/aol
JjaolK
Loq Kf
kJjaol
-------------------------------------------------------------------------------38.079
298.15
27.974
o.ooo
269.57
326.10
-4.901
269.57
UNCERTAINTY
1. 470
400
500
600
700
800
92.275
156.542
204.813
242.569
273.006
375.60
1Ui7. 72
549.00
621.27
686.15
283.32
311. 18
344. 19
378.70
413.14
392.41
431.95
458.85
478.36
493. 13
900
1000
298.133
319.249
744.93
798.58
446. 80
479.33
504.61
513.73
1100
1200
1300
1400
1500
1600
1700
1800
337.275
352.847
366.438
378.400
389.0.11
398.476
406.968
414.621
847.90
893.50
935.89
975.45
1012.54
1047.42
1080.33
1111.46
51().63
540.65
569.45
597. OS
623.53
648.94
673.36
696.84
521.06
527.02
531.88
535. 85
539.09
541.73
543.85
545.53
BOILING POINT
!!ELTING POI NT
2133
1.490
37.839
37.416
36. 849
36.051
34.909
-3.206
-2.222
-1.576
-1.122
-0.791
33.686
33.726
33.661
33.449
33.037
32.415
31.546.
30. 411
3. 951
1.277
-1.438
-4.127.
-6.833
-9.439
-12.022
-14.555
-0.188
-0.056
0.058
0.154
0.238
0.308
0.369
0.422
kJ
H~ 98
kJ
!!OLAR
H~
24.547
21.271
18.104
15.031
12.110
--------------------------------9. 353
-().543
lJ. 5()9
33.589
6.669
-0.348
ENTHALPY OF KELTING
-
kJ
13.4550 J/bar
134.550 ca 3
VOLUI!E

Si0 2
ALPHA - BETA TRANSITION 844 K.

7.5455x102 -
2.9426x1o-z T
6.5757x103 T-os
298 - 1800 K)

REFERENCE
213
99
213
99
267
COl! PILED
7- 9-76
347
LARNITE
FORBULA iEIGHT
Ca 2 Si0 4 :
172.244
m' crystals (bredigite) 970 to 1710 K.
m crystals 1710 to 1800 K.
-------------------------------------------------------------------------------FORBATION FRO II THE ELEIIENTS

TEIIP.
so
-(G;-H~ 98 }/T
J/aolK
JjaolK
0.84
0.84
( H;-H;98 )/T
JjaolK
cop
ERTHlLPY
JjaolK
GIBBS
FREE ENERGY
kJ/aol
Log Kf
ltJ/aol
-------------------------------------------------------------------------------127.61
127.61
-2305.980
-2191.264
383.902
298.15
o.ooo
128.60
UtiCEBT AINTY
3.220
3.225
0.565
-2305.1114
-2304.116
-2302.520
-2300.900
-2152.126
-2113.956
-2076.056
-2038.456
2li1 .040
220.844
180.7 37
152.112
-2299.472
-2298.787
-1963.450
-1937.335
113.956
104.326
-2298.667
-1926.167
100.613
-2298.502
-1888.940
89.699
-2309.705
-2306.393
-2302.973
-2299.460
-1812.053
-1773.904
-1735.986
-1698.307
72.809
66.185
60.453
55.444
-2345.989
-1656.571
50.603
400
500
600
100
35.025
58.216
75.240
88.406
167.91
201. 56
230.77
256.57
132.89
143.34
155.53
168. 16
145.21
156. 16
164. 18
170. 38
800
900
970
98.975
107.700
112.967
279.65
300.55
314.08
180.67
192.85
201.12
175. 35
179.45
181.92
1000
115.048
319.64
204.59
180.66
1100
121.354
337.21
215.86
185.2B
1200
1300
1400
1500
1600
126.837
131.663
135.950
139.791
143.257
353.50
368.67
382.87
396.23
408.83
226. 66
237.01
246.92
256.44
265.57
189.89
194.50
199.11
203. 12
208.33
1100
1710
146.406
146.700
420.76
421.95
274.35
275.25
212.94
213.40
BOIL IIIG POIBT
ltJ
ENTHALPY OP VAPOBIZATIOtl
kJ
IIOLAB VOLUIIE
-------------------------------130.645
-2000.884
-2300.892
-------------------------------------------------------------------------------104. 326
970
-1937.335
113.040
314.16
201. 12
179.28
-2298.716
-------------------------------80.548
-1850.445
-2312.899
-------------------------------51.018
-1660.403
-2346.370
-------------------------------------------------------------------------------50.603
434.33
275. 25
-2324.826
-1656.571
1110
159.076
205.02
-------------------------------46.896
-2629.040
-1616.0:.22
1800
160.596
444.84
284.24
205.02
!IELTI IIG POI liT
2403
ENTHALPY OP !ELTING
5. 1600 J/bar
51.600 ca 3
TRAtiSITIOIIS Ill REFERENCE STATE ELEI!EIITS

ClLCIUI! ALPHA-BETA 720, ft.
P. BETA 1112, B. P.
1755 K.
BEAT CAPACITY EQUATION
2.4871z102- 8.3145z10- T
2.0521z1oa T-as
(EQUATION VALID FROft 298 - 970 I)
c;
134.557
0.046108 T
(EQUATION VALID FBOII 970 -
REFERENCE
45
120
1710 I)
126
COB PILED
7- 9-76
348
THEBIIODY HliiiC PROPEBTIBS OF !liBERALS

FORIIULA WEIGHT
LlRNITE
Ca 2 Si0 4 :
Crystals 298o15 to 970 Ko
172o244
a' crystals (bredigite} 970 to 1710 Ko
crystals 1710 to 1800 Ko
-------------------------------------------------------------------------------FOBIIlTIOil FBOl'l THE OIIDES

TEll Po
ca;-a; 98 }/T
JjaolK
so
JjaolK
-(G;-a; 98 }/T
J/aolK
cop
GIBBS
FRBB BBEBGY
BBTHALPY
kJ/aol
J/aolK
Log Kf
kJ/aol
-------------------------------------------------------------------------------298o15
22o425
OoOOO
127 61
127o61
128.60
-125.102
-128o002
0
UNCERTAIBTY
Oo 84
Oo960
0.84
16o842
13o571
11o386
9o826
8o652
-------------------------------7o738
900
107o700
-126o 072 -133o326
300o55
192.85
179o 45
970
112o967
7o211
314.08
201o12
-125o769 -133o903
181o92
-------------------------------------------------------------------------------7o211
970
113.040
314o16
-125o698 -133o903
201o12
179o28
1000
115o048
319o64
-125o491
-134o 171
7o008
400
500
600
700
800
35o025
58o216
75.240
88o406
98o975
167o91
201o 56
230o 77
256o 57
279o 65
132o89
143o34
155o53
168o16
180o67
145o 21
156o16
164o18
170o38
175o35
204o 59
180o66
-125o222
-125o366
-125.485
-125o625
-12So836
Oo 970
-128o974
-129o901
-130o789
-1l1o 673
-132o516
-135o 064 6o414

-136o033
5o921
-137.059
5o507
-138. 165 5o155
-139o321 4.852
-140.504 4.587
-141.774
... 356
-141.901 4o335
-------------------------------------------------------------------------------1710
159.076
434.33
-98o452 -141o901
4o33S
275o25
205.02
1800
160.596
4.227
444o84
-99.076 -145.660
284o24
205o02
1100
1200
1300
1400
1500
1600
1700
1710
121o 154
126o 837
131o663
135.950
139o 791
141.257
146.406
146o 700
337o21
353o50
368.67
38 2o 87
396.23
408.83
420.76
421o 95
IIELTIHG POINT
2403
ENTHALPY OF IIELTIBG
H;98 -
H~
215o86
226o66
237.01
246.92
256.44
265. 57
274.35
275o 25
185o28
189o89
194.50
199o11
203.72
208o 33
212.94
213o40
-124o800
-124o046
-123o 254
-122o442
-121.650
-120.873
-120o133
-119.615
BOILIBG POIIT
kJ
BBTRALPY OP VlPOBIZATIOB
kJ
!lOLl B VOLOIIE
kJ
5.1600 JAar
51.600 c 3
TBlRSITIOBS II BEPEBEIICE STATE OXIDES

SiOzoo o o o o ALPHA - BETA TBABSITIOW 844 K.
HEAT CAPACITY EQUlTIOB

2.4871x10Z - 8.l145x1o- T - 2o0521z1o T-os
(EQUATIOB VALID FBOft 298- 970 K)
c;
134.557
o.046108 T
( EQUATIOB VALID FBOII
BEPEIBIICE
45
120
970 - 1710 K)
126
COIIPILBD
7- 9-76
349
PROPERTIES AT HIGH TEIIPEBlrURES
CALCIUII OLIVINE
FORIIULA WEIGHT
172.244
calcium oliYine is tbe stable form of
dicalcium silicate below 1120 K.
-------------------------------------------------------------------------------FORIIATIOH FRO II THE ELEliENTS

TEIIP.
K
so
( H;-u~ 98 )/T
J/mo1K
-(G;-u~ 98 )/T
J/110111:
J/III01K
0.84
0.84
cop
ENTHALPY
GIBBS
FREE ENERGY
kJ/1101
J/II01K
Log Kf
kJ/1101
-------------------------------------------------------------------------------298.15
-2316.621'
385.395
o.ooo
120.50
120.50
126.80
-2199.784
UNCERT .liNTY
3.920
3.950
0.692
-2316.324
-2315.454
-2314.383
-2313.286
-2159.892
-212(1. 884
-2082.051
-2043.429
282.054
221.568
181.259
152.483
-2312.592
-2311.872
-1966.202
-1927.762
114.116
100.696
-2311.550
-1889.382
89.720
400
500
600
700
34.350
56.820
73.202
85.911
160.05
192.74
220.99
245.98
125.70
135.92
147.79
160.07
141.67
151. 21
158.78
165. 44
800
900
1000
96.241
104.944
112.483
268.48
289.03
308. OJ
172.24
184.09
195.55
171.60
177.48
183.18
1100
119.165
325.75
206.59
188.76
1200
125.194
342.41
217.22
194.26
!ELTING POINT
BOILING POIIT
ENTHALPY OF KELTING
kJ
kJ
kJ
IIOLAR VOLU!E
-------------------------------130.899
-2313.719
-2004.775
-------------------------------80.518
-2325.511
-1849.749
5.9110 J/bar
59.110 c11 3
TRUISITIONS IN REFEREIICE STATE ELE!EIITS

CALCIUII
ALPHA-BETA 720,
SILICON II. P.
ll.
P.
BETA 1112, B. P.
1155 K.
1685 K.
c;
1.3257x10Z +
5.2510x1o-z T
298 -
UPEBEHCE
45
120
1.9049x10 T-z
1200 K)
93
229
COI'IPILED
7- 9-76
350
THER!IODYNliUC PROPERTIES OF !IIHERALS
CALCIU!I OLIVINE
FORftULA WEIGHT

dicalci~
172.244
Calcium oliYine is the stable fora of
silicate below 1120 K.
-------------------------------------------------------------------------------FOB!IATION FRO!! THE OXIDES

TMP.
so
( H~- H~ 98 )/T
J;aolK
-cG;-a ; 98 }/T
J;aolK
J/aolK
0.84
o. 84
cop
GIBBS
FREE ENERGY
ENTHALPY
Log Kf
kJ/1101
kJ;aol
J/IIOlK
--------------------------------------------------------------------------------136.522
23.918
298.15
o.ooo
120.50
-135.742
120.50
126.80
OBCERTAINTY
1.000
400
500
600
700
800
34.350
56.820
1 Jo 202
85.911
96.241
160.05
191.74
220.99
245. 98
268. 48
125.70
135.92
147.79
16u.o7
172.24
141.67
151.21
158.78
165.44
171.60
900
1000
104.944
112.483
289.03
308.03
184.09
195.55
171.48
183.18
1100
1200
119.165
125.194
325.75
342.41
206.59
217. 22
188.76
194.26
1.020
-136.740
17.856
-136.829 14.294
-136.784
11.9(18
-136.646 10.197
-1J6.4u7 8.9u6
-------------------------------7.898
-136.078
-139. 192
7.092
-138.696 -135.766
6.435
-137.848 -135.506
5.891
-136.658 -135.337
BOlLI HG POINT
kJ
kJ
kJ
!!OL AB VOL U!IB
!!ELTING POINT
-136. 132
-136.704
-137.348
-138.011
-138.663
5.9110 J/bar
59. 110 ca 3
TRANSITIONS IN REFERENCE STATE OIIDES

SiOz ALPHA- BETA TRANSITIOH 844 K.
c~
1.J257x10Z + 5.2510x1o-z T
1.9049x10 T-z
(EQUATION VALID FRO!! 298 - 1200 K)
REPEBEHCE
45
120
93
229
CO!! PILED
1- 9-76
351
PROPERTIES AT HIGH TE!PERATURES
GEHL ENITE
FORftULA WEIGHT
274.206
Crystals 298.15 to eltinq point 1863 K.
-------------------------------------------------------------------------------FOR!ATION FBOII THE ELEIIEliTS

TEIIP.
H;-H~ 98
so
)/T
J/molK
-(G;-a~ 98 )/T
JtolK
J/olK
1.64
1.64
cop
ENTHALPY
J/8olK
GIBBS
FREE EIIIERGY
Log Kf
kJ/801
kJ/ol
-------------------------------------------------------------------------------298.15
0.000
209.80
-4007.570
-3808.705
66 7.272
209.80
206.40
U NCEBT AINTY
2.820
2.900
0.508
-4007.948
-4006.908
-4005.317
-4003.661
-3740.651
-3673.938
-3607.47 8
-3541.319
488.481
383.815
314.06 0
264.258
-4002.587
-3409.174
197.864
-40:.!3.617
-3273.549
155.449
-40311.968
-4031.696
-4028.312
-4 024.833
-31H. 719
-3065.614
-2996.714
-2928.071
125.955
114.380
104.355
95.592
400
500
600
700
56.750
94.7'>2
122.688
144.259
27'>. 09
330.07
377.87
420.04
218. 34
235. 32
255. 18
275.78
236.74
255.46
268.58
278. 35
800
900
lb1.514
17'l. 689
457.72
491.77
296.21
316.08
285.96
292.06
1000
187.586
522.8..1
335.21
297.06
1100
197. 7H
551.32
353. 59
301.23
1200
1300
11100
1500
1600
206.508
214.183
220.964
226.997
232.409
517. 6il
602. 2()
625.10
646.59
666.83
371.17
388.02
1104.14
419.59
434.42
304.75
307.76
310.35
312.59
314. 55
1700
237.292
685.9S
448.66
316. 26
1800
2111.722
704.07
462.35
317.76
BOILIKG POIIIT
kJ
kJ
!lOLA R VOL UftE
1863
IIELTING POINT
--------------------------------4003.721
-3475. 182
226.907
-------------------------------174.554
-4023.652
-3341.722
-------------------------------139.471
-3204.088
-4038.103
-------------------------------87.853
-4071.779
-2859.212
-------------------------------80.710
-43711.866
-2781.240
9.0240 Jjbar
90.240 cm 3

CALCIUII
ALPHA-BETA 720, 11.
P.
BETA 1112, B. P.
1755 K.
ALUftiNUft ft. P. 933 K.

SILICON ft.
P.
1685 K.
4.0573x10Z(~OAT
REFERENCE
206
7.0986x10-3 T
298 -
ION VALID FROII
27 3
268
3.1744x103 T-os
1800 K)
93
11
COil PILED
7- 9-76
352
THERIIODY NAIUC PROPERTIES OF II IN El!lLS
GEHLENITE
FOI!IIULA
274.206
WEIGHT
crystals 298. 15 to aelting point 1863 K.
-------------------------------------------------------------------------------FORIIlTION FRO II THE OIIDES

GIBBS
FREE ENERGY
so
-(G~-H~ 98 )/T
J/molK
Jjaol K
1. 64
1.64
BOO
56.750
94.752
122.688
144.259
161.514
275.09
330.07
377.87
420.04
457.72
218.34
235.32
255.18
275.78
296.21
236.74
255.46
268.58
278.35
285.96
900
1000
175.689
187.586
491.77
522.80
316.08
335.21
292.06
297.06
1100
1200
1300
1400
1500
1600
1100
1800
197.733
206.508
214.183
220.964
226.997
232.409
237.292
241.722
551. 32
577.68
602.20
625.10
646.59
666.83
685.95
704.07
353. 59
371. 17
388.02
404.14
419.59
434.42
448.66
462.35
301.23
304.75
307.76
310.35
312.59
314.55
316.26
317.76
BOILING POINT
ltJ
kJ
MOLAR VOLUME
TEMP.
H~-H~ 98 )/T
J/IIOlK
Cp
JjaolK
ENTHALPY
Log Kf
kJ/1101
kJ/ol
--------------------------------------------------------------------------------163.215
28.595
298.15
o.ooo
-150.992
209.80
209.80
206.40
UNCERTAINTY
400
500
600
700
1863
MELTING POINT
ENTHALPY OF MELTING
3.090
-151.452
-152. 171~
-153.018
-153.982
-155.100
3. 170
-167.336
-171.229
-174.954
-178.545
-181.971
21.852
17.888
15.231
13.323
11.882
--------------------------------156.322. -185.257 10.752

-188.438
9.843
-156.718
-157.196
-157.615.
-158. 060
-158.542
-159.111
-159.765
-160.513
-161.373
-191.594
-194.682
-197.761
-200.809
-203.818
-206.756
-209.676
-212.547
9.098
8.474
7.946
7.492
7.098
6.750
6.443
6.168
kJ
9.0240 Jjbar
90.240 ca 3

SiOz
BETA TRANSITION 844 K.
ALPHA -
4.0573z1QZ-
7.0986I10-~
( EQUATION VALID FROM
REFERENCE
206
273
268
T
298 -
3.1744z103 T-05
1800 K)
93
11
CO!! PILED
1- 9-76
PROPBBTIBS lT HIGH TBIIPDITUBBS

GROSSULlR
353
PORBULI
iB~GBT
450.455
CrJsta1s 298.15 to 1200 K.
-------------------------------------------------------------------------------PDRIUUOI PRO! TBB ILBUITS

TEBP.
soT
<a;-a~98 )!r
J/aoll
-(G;-a~ 98 )/T
JtaolK
JtaolK
cop
GIBBS
BITHlLPI
J/aolK
UBI BJEIIGY
Log Kf
kJ/aol
kJ/aol
--------------------------------------------------------------------------------6281.359
298. 15
255.50
255.50
330.10
1100.472
o.ooo
-6643. 140
UNCBRTliiiTI
o. 51
o. 51
400
500
600
700
92.225
155.598
202.645
238.817
361.51
452.65
532.42
602.72
269.28
297.05
329.78
363.84
389. 55
425.66
1148.31
463.18
800
900
267.621
291.056
665.31
721.66
397.69
430.60
473.91
482.89
1000
310.680
773.00
462.32
491.71
1100
327.577
820.32
492.74
501.53
1200
342.547
864.44
521.89
513.15
!ELTI'NG POIIIT
6.000
6.100
1. 069
-6643.817
-6641.469
-6637.887
-6634.129
-6157.534
-6036.219
-5915.468
-5795. 383
804.095
630.602
514.989
432.458
--------------------------------6632.988
-5675.525
370.576
-6630.058
-5555.984
-6648.281
-5313.882
252.336
-------------------------------225.947
-6668.283
-5190.716
BOILIIG POIIT
ENTHALPY OP !ELTING
322.462
-------------------------------283.909
-5435.229
-6649.649
BHTHALPI OP YAPORIZlTION
ltJ
47.047 kJ
12.5300 Jjbar
125.300 cal
BOLAR VOJ.UBI
TBAISITIONS II RBPEREIICE STATE ELE!EHTS

ClLCIU! lLPHl-BBTl 720, !. P. BETA 1112, B. P. 1755 K.
ALU!IIU! !. P. 933 K.
SILICON
ft.
P. 1685 K.
H.ElT ClPACI!T BQUl!IOI
c; =
1.5293K103 -
0.69900 T
2.5300xlo- T2
7.4426x10 T-z
( IQUl'liOJ YlL.ID PRO!
IIEPEBBICJ!
152
283
298 -
1200 K)
286
88
COIIPILBD
03-15-79
354
~BBIIODIIliiC
PIOPBITIBS OP IIIBRlts
GBOSSOI.ll
POI!ULl IBIGBr 450.455
a=acc:a=aa.-a:aaaa==-==z=========-========za::==========-================
CrJstals 298.15 to 1200 1.
-------------------------------------------------------------------------------POIIllTZOI :FIOI 'rHB OXIDBS

sT
Ca;-a~g8)~
TEBP.
.Jtollt
.J/aollt
-(G;-8~98 )/T
.J/ollt
cp
GIBBS
l'llBI BJERG!
lftBlLPI
lt.J/aol
.J/ollt
Log I t
lt.J/ol
-------------------------------------------------------------------------------298.15
o.ooo
255.50
255.50
330.10
56.029
-330.073 *
-319.806 *
UICBB~liiU
o. 51
0.51
7. 320
400
500
600
700
800
92.225
155.598
202.645
238.877
267.621
361.51
452.65
532.42
602.72
665.31
269.28
297.05
329.78
363.84
397.69
389.55
425.66
"8.31
463.18
473.91
900
1000
291.056
310 . 680
721.66
773.00
1130.60
462.32
482.89
491.71
1100
1200
327.517
342.547
820.32
864.44
492.74
521.89
501. 53
513. 15
-330.953
-331. 550
-332.225
-333.384
-335.272
7. 560
*
*
*
*
*
-316. 153
-312. 390
-308.483
-304.453
-300. 199
-337.934
-290.974
15. 199
-337.911
-337.463
*
*
-286.279
-281.579
*
*
13.594
12. 257
IIBLUIG POift
BOlLI 1IG POI IT

BITHlLPI OP YlPOIIZlTIOI
a~
47.0117 k.J
~BliSIUOIS
41. 285
32.635
26.856
22.719
19.601
-------------------------------17. 159
-337.703 *
-295.647 *
IITHI.LPI OP IIBLTUG
a;98 -
*
*
*
*
*
lt.J
12.5300 J;1ar
125. 300 cal
IIOLlB YOLUIIB
II IIPBBBICB STlTI OXIDES
SiOz lLPBl- BBTl TlliSITIOI 844 lt.
HilT ClPlCIT! IQUlTIDI
c; =
1.5293z10
BBPBIBICB
0.69900 '
7.4,26:110 r-z
(BQUI!IOI tlLID PIO!
152
4183
2.5300:~1o- rz
298 - 1200 &)

286
88
CO!PILID
03-15-79
355
PIOPII'rl!S lT HIGH t'BIIPBI&rUIES
POIIIULl WEIGHT
I!IEIIIIITB
Ca;~llg{
Si0 4
) 2 :
328.712
crrstals 298.15 to iacongrueat 11eltiag point 1848 ...
-------------------------------------------------------------------------------P'OIIllTIOI PIOII THE ELIIIEITS

TEIIP.
K
a;-s~ 98 )1'1'
J/olK
so
T
-(G;-a~ 98 )/T
J/olK
Co
EITHlLPY
J/ollt
J/olK
GIBBS
PIEE EIEBGI
Log Kf
kJ/ol
kJ/ol
---------------------~----------------------------------------------------------
298. 15
0.000
UICEITli ITI
253.13
2.09
253.13
2.09
252.30
-4566.790
5.310
-4339.403
5.397
760. 21J9
0.91J6
-4566.036
-4563.869
-4561.297
-4558.887
-4261.765
-4185.954
-IJ110.588
-4035.686
556.532
437.306
357.860
301.148
IJOO
500
600
700
69.050
114.736
147.915
173.193
332.56
398.87
456.05
506.11
263.51
284.13
308.14
332.92
286.70
306.81
319. 97
329.27
800
900
193. 167
209.433
550.56
590.51J
357.39
381.11
336.43
342.1J6
1000
223.012
626.91
403.90
348.02
1100
234.625
660.31J
425.71
353.53
1200
1300
244.773
253.822
691.35
720. 35
IJ46. 58
466.53
359.31
365.59
1400
1500
1600
262.050
269.667
276.842
747.70
173.66
798.47
485.65
503.99
521.63
372.52
380.24
388.85
IIELTIIG POIIT
-------------------------------258.616
-3960.814
-4559.142
-4557.514
-3886.081
225.543
--------------------------------3810.761
199.055
-4565.941
-4566.383
-3735.257
177.373
--------------------------------3657.764
159.219
-IJS88.577
-4581J.197
-3580.4(/IJ
143.863
-IJ699.695
-IJ692.423
-31J13.832
-3328.342
118.881
108.660
--------------------------------3499.798
130.580
-IJ706.302
BOILIIIG POIIT
!MTHlLPI OP IIELTIIG
kJ
IITHALPY OP VlPOBIZATIOI
kJ
IIOLlB VOLUIIE
kJ
1u.4400 J/bar
104.400 ca 3
TBlMSITIOIS II BEFEREHCE STlTE ELEIIEIITS

ClLCIUI!I lLPHl-BETl 720 1 II.
P.
BETA 1112 1 B. P.
1755 K.
lllGHESIUII II. P. 922 1 B. P. 1361 K.

SILICON.... II. P.
1685 K.
BElT CAPACITY EQUlTIOB
6.5076x10Z 0. 18169 T
( ~UlT lOll VlLID PBOII
BBPEBBJCE
206
273
7. 0357x1 o-s T2
298- 1600 K}
179
116
COIIPILED
7- 9-76
356
TBIBIIODYJliiiC PBOPIBTIBS or IIIIEBALS
IIIBIIIIITB
328.712
FOBftULA II!IGBT
ca 1 11g( Si0 4
)2 :
Crystals 298.15 to incongruent .altinq point 18118 K.
-------------------------------------------------------------------------------rOBI'IlTIOI FRO II THB OIIDBS

TBIIP.
I(
a;-a~ 98 )/T
J/aOlK
so
J/aolK
-(G;-a~ 98 )/T
J/aolK
cop
GIBBS
FBBB EIIBBGY
EITBALPY
LOCJ Kf
kJ/aol
kJ/aol
J/aolK
--------------------------------------------------------------------------------247.170. 43.303
298.15
o.ooo
253.13
253. 13
-238.633
252.30
UICBBTli ITt
2.09
2.09
1. 590
400
500
600
700
800
69.050
1111.136
147.915
113.193
193.167
332.56
398.87
1156.05
506.11
550.56
263.51
284. 13
308.14
332.92
357.39
286.70
306.81
319.97
329.27
336.43
900
1000
209.433
223.012
590.54
626.91
381.11
403.90
342.46
348.02
1100
1200
1300
1400
1500
1600
234.625
244.773
253.822
262.050
269.667
276.842
660.34
691. 35
720.35
7117.70
773.66
798.47
425.71
446. 58
466.53
485.65
503.99
521.63
353.53
359.31
365.59
372.52
380.24
388.85
I(
SOIL lNG PO lifT
liE LTI NG POINT

ENTHALPY or IIELTIIG
u;98 -
H~
-238.823
-239.112
-239.765
-240.736
-242.111f
1. 600
-250.059
-252.837
-255.514
-258.075
-260.461
32.654
26.414
22.245
19.258
17.006
--------------------------------243.933. -262.618 15.242

-244.234 -264.684 13.826
-244.413
-244.447
-2411.277
-243.913
-243.003
-241.717
-266.723
-268.746.
-270.769.
-212.852
-2711.954
-277.1192
12.666
11.698
10.880
1 0.1 80
9.575
9.046
kJ
kJ
I!OL lB VOL Ull E
kJ
10.4400 J~t~ar
104.400 ca 3
TRA.HSITIONS II REFERENCE STATE OIIDBS

SiOz ALPHA - BETA TRANSITION 844 K.
BElT CAPACITY
~UlTIOB
6.5076K102 0.18169 T
(EQUATION YALID FBOII
REFBIBRCI
206
273
7.0357K10-5 TZ
298 - 1600 K)
179
116
COIIPILBD
1- 9-76
j~
PIOPII'!'IBS U' HIGH !IIIPERlTDR!S
POBIIDLl VElGRf
lltllllliiU
27l.&JJ
cr:rstals 298.15 to aeltiDCJ poiat 1727 Jt.
-------------------------------------------------------------------------------POR!llTIOI PBOII THE KLEIIEIITS

<a;-al98 )/'1'
'l'EIIP.
J;aoll
It
SD
'1'
-< G;-H l98 )/'1'
.J/aoll
JtaolK
CD
UTBAJ.PY
JtaolK
GIBBS
FIJI BIEBGY
Loq J(f
ltJ/aol
kJ/aol
--------------------------------------------------------------------------------3679.069
644.560
298.15
o.ooo
209.33
212.00
-3876.520
209.33
UICII'l' Allt'Y
2.09
2.09
238.34
255.18
267.22
276. "1
283.80
290.04
1100
500
600
700
57.600
95.540
123.200
144.457
275.62
378.38
420.29
218.02
235.19
255.18
275.83
800
900
,61. 427
175.378
457.69
ll91. 119
296.26
316.11
330.13
1000
187.125
522.34
335.21
295.54
1100
197.212
550.75
353.54
300.56
206.023
213.839
577.10
601.72
371.08
387.88
305.31
309.93
1200
1300
2.830
2.850
0.499
-3876.213
-3874.839
-3873.058
-3871.239
-3611.616
-3545.624
-3479.928
-3414.566
471.631
370.410
302.956
254.799
--------------------------------3349.260
-3871.063
218.685
-3869.523
-3877.235
-3887.711
621t.86
U6.72
667.116
1104.00
li19.1i6
lt34.J1
314. 51
319.11i
323.88
1700
238.633
687. 21i
41i8.61
328.78
It
BO.ILIIG PODT
ltJ
IIOLlB VOLDIIB
ll'l'BlLPY
H~9s
0' IIILTIIG
-3152.478
-3018.318
-4005. 352
-3999.609
-2872.279
-2796.913
121.278
100.022
91.310
--------------------------------2721.052
83.608
-4091i.524
IITHlLPY OF VlPOBIZlTIOJ
~~
149.699
--------------------------------291i8.011i
-4010.766
109.992
220.861t
227.263
2ll. 152
1727
190.605
--------------------------------3085.312
-3891.343
134.301
1400
1500
1600
liE L'l'I IG POIII'l'
-32811.102
--------------------------------3218.355
-3871.575
168.110
ltJ
-9.2810 J/t)ar
92.81(1 ca 3
'l'lliSI'!'IOIS II BB,BBBICB STl'l'B BLBIIBI'l'S

ClLCIDII lLPHl-BETl 720, II. P. BBTl 1112, B. P. 1755 1.
lllGIESIDII II. P. 922, B. P.
1361 K.
SILICOI 11. P. 1685 I.

HilT CAPACITY BQUl'l'IOI
4.4511x 102 -
5.11i63x1o-z T + 2.1857s1o- rz
298 - 1700 It)
( BQDlTIOI VALID PBOII
BEFBBBICB
206
273
178
116
COli PILED
7- 9-76
358
THDIOD!IliiiC PIOPIBTIBS OP IIIIDlLS
AUIIIliiT!
272.633
POBIIOLl ii!IGBT
crystals 298.15 to aeltiag poiat 1727 K.
-------------------------------------------------------------------------------PORIIlTIOI PBOI THE OXIDES

TBIIP.
H;-H~ 98 )/T
J;aoltt
It
so
J/aoltt
-(G;-a; 98 }/1'
J/aoltt
cop
GIBBS
PilE BIEIGY
!ITHlLPY
J/aolK
Log Kf
ltJtaol
ltJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
-190.323
209.33
33.31111
209.33
212.00
-183.1152
OICBBTAIBTJ
2.09
2.09
0.920
1100
500
600
700
800
57.600
95.540
123.200
1114.457
161.1127
275.62
330.73
378.38
420. 29
457.69
218.02
235.19
255.18
275.83
296.26
238.311
255.18
267.22
276.111
283.80
900
1000
175.378
187.125
491.49
522.34
316. 11
335.21
290.04
295.54
1100
1200
1300
11100
1500
1600
1700
197.212
206.023
213.839
220.864
227.263
233.152
238.633
550.75
577.10
601.72
624.86
646.72
667.46
687.24
353.511
371.08
387.88
404.00
419.46
4311.31
448.61
300.56
305.31
309.93
314.51
319.111
323.88
328.78
BOILIIG POUT
ltJ
IIOLU VOLDIIE
I!ELTI NG POINT
1727
BliTHlLPY OP IIBLTIIG
-183.672
-1811.2117
-185.095
-186.250
-187.768
0.93(1
-192.656
-1911.837
-196.879
-198.759
-200.4118
25.158
20.355
17.140
14.832
13.088
--------------------------------201.915
-189.512
11.719
-189.705.
-203.285
10.619
-189.750.
-189.671
-189.469
-189. 132
-188.661
-188.021
-187.192.
-204.646
-205.991
-207.356
-208.762
-210.187
-211.605
-213.117
9.718
8.967
8.332
7.789
7.319
6.908
6.548
ENTHALPY OP VlPOBIZATIOI
ltJ
9.2810 J/llar
92.810 ca 3
TRlNSITIONS II BEl"EBEJCE STATE OXIDES

Si0 2 ALPHA -
BETA TBAISITIOI 844 K.
HEAT CAPACITY EQDATIOI
4.4511xloz- 5.1463x1o-z T + 2.1857x1o-s TZ

(EQDATIOI VALID PBOII 298- 1700 K)
BEPEBERCE
206
273
178
116
COli PILED
7- 9-76
359
PROPBITIBS IT HIGH TIBPEIITDBBS

POBBULl WEIGHT
TITliiTB ( SPHEIE)
CaTiSiOs:
196.063
Liquid 1670 to 1aoo K.
-------------------------------------------------------------------------------lOBUTIOI PROS THE ELEIIBIITS

TEIIP.
so
<a;-a; 98 )IT
J/aolK
cop
-(G;-a; 98 )/T
J/aolK
J/aolK
EIITHlLPI
GIBBS
PBBB EIIBGY
ltJ/aol
J/aolK
Log Kf
ltJ/aol
---------------------------------~---------------------------------------------
298.15
o.ooo
UHCIBT .liJTI
129.20
0.84
129.20
0.84
139.00
-2601.400
2.380
-2459.855
2.430
43 0.958
0.426
-2600.913
-2599.490
-2597.787
-2596.079
-2411.527
-2361f.3115
-2317.1f64
-2270.888
314.915
21f7.002
201.754
169.456
400
500
600
100
38.600
64.382
83.077
97.313
173.59
210.92
2113.09
271.25
134.99
146.54
160.01
173.94
161.33
172.69
179.96
185.28
800
900
1000
108.585
117.789
125.510
296.28
318.82
339.36
187.69
201.03
213.85
189.58
193.27
196.59
1100
132.114
358.24
226. 13
199.67
1200
1300
1400
1500
1600
1670
137.865
142.952
147.507
151.635
155.410
157.779
375.74
392.07
407. 39
421.84
435.52
444.98
237.88
249.12
259.88
270.21
280.11
287.20
202.58
205.38
208.09
21 o. 73
213.33
215.13
--------------------------------2224.1154
145.243
-2595.225
-2593.723
-2592.562
-2178.117
-2132.072
126.419
111.368
-2591.763
-2086.071
99.060
-2599.572
-2596.764
-2593.886
-2590.938
-2589.005
-1992.551
-1945.975
-1899.580
-1853.394
-1821.898
--------------------------------2039.336
88.770
-2602.320
80.062
72.606
66.150
60.507
56.986
-------------------------------------------------------------------------------1670
56.986
231.914
519.11
287.20
279.50
-2465. 200
-1821.898
-------------------------------1700
55.6 00
232.754
523.89
291.14
279.50
-2512.860
-1809.510
-------------------------------1800
235.350
-2656.740
-1764.949
51.218
539.82
304.4 7
279.50
BELTING POINT
1670
BOILING POINT
EIITHALPY OP MELTIWG
123.805 ltJ
ENTHALPY OP V.lPOIIZATION
ltJ
ltJ
5. 5650 J/ba r
55.650 CIIJ
IIOL.lR VOLUIIE
TRANSITIONS IN REFERENCE ST.lTE ELEIIENTS

CALCIUB ALPHA-BETA 720 II. P. BETA 1112 B. P. 1755 K.
TITANIUM ALPHA-BETA 1155 II. P. 1943
K.

HE.lT CAPACITY EQUATION
c;
1.7673:r.1oz + 2.3852:r.1o-z T - 3.9905:r.10 T-z

(EQUATION VALID PBOII 298 - 1670 K)
RB!'EBEIIICE
132
120
93
253
COli PILED
7- 9-76
360
THEIIODIIlBIC PROPEITIIS OF RIIEBALS

POBBULl WBIGRt
TITliiTI ( SPREIE)
Crystals 298.15 to aelting polDt 1670 1.
CaTiSiOs:
196.063
Liquid 1670 to 1800 1.
-------------------------------------------------------------------------------FOBII.lTIOI FROB THE OIIDIS

T!ftP.
I
( H;-8~98 )/T
J/aoll
so
T
-(G;-H~g 8 )/T
J/aoll
J/aoll
Cop
GIBBS
Pill IlliG!
EITHALPY
kJ/aol
kJ/aol
J/aoll
Log If
--------------------------------------------------------------------------------110.634
19.383
298.15
o.ooo
129.20
-110.861
129. 20
139.00
U11CBBTlii'l'Y
0.84
0.84
1.520
400
500
600
700
800
38.600
64.382
83.071
97.313
108.585
113.59
210.92
243.09
271.25
296.28
134.99
11f6.54
160.01
113.94
187.69
161.33
172. 69
179.96
185.28
189.58
900
1000
111.789
125.510
318.82
JJ9. 36
201.03
213.85
193.27
196.59
1100
1200
1300
1400
1500
1600
1670
132.114
137.865
142.952
1117.507
151.635
155.410
157.779
358.24
375.74
392.07
407.39
421.84
435.52
4114.98
226.13
237.88
249.12
259.88
270.21
280. 11
287.20
199.67
202.58
2(15.38
208.09
210.73
213.33
215.13
1. SilO
14.11311
11.537
9.601f
8.222
7.181
-------------------------------6.367
-112.551 -109.698
5.714
-112.493 -109.383
5.179
-112.414 -109.071
4.735
-112. 322 -108.711
-112.221 -108.471
4.359
4.037
-112.111 -108.206
3.759
-112.014. -107.935
-110.951
-110.951
-111.052.
-111.3113
-111.863.
-110.531
-110.1f31
-110.314
-110.181
-109.983
-111.913.
-111.955.
-107.640
-107.993
3.514
3.378
-------------------------------------------------------------------------------1670
231.914
3.378
519.11
11.850 -107.993
287.20
279.50
3.378
1700
232.754
279.5(1
13.746 -109.945
523.89
291.14
1800
3.405
235.350
539.82
279.50
20.067 -117.327
JOif. 47
ftELTIRG POIIIT
1670
BOlLIIIG POIIT
ENTHALPY OP BELTING
123.805 kJ
!ITHALPI OP VlPORIZlTIOI
H;98 - H~
kJ
kJ
5.5650 J/bar
55.650 ca 3
ROLl B VOLUftB
TBAISITIORS I I RBFBRIICI STATE OIIDES

SiOz ll.PHA- BETA TRlMSITIOif 844 I .
c;
1.7673x10Z + 2.3852x1o-z T
3.990Sx106 ,-z
( BQOATIOII VALID FIOII 298 - 1670 I)
RlliBENCE
132
120
93
253
COli PILED
1- 9-76
361
PROPERTIES AT HIGH TE!!PEBATUBES
FOB!ULA WEIGHT
FlYAU:TE
Crrstals 298.15 to
~ltinq
point 1490
~.
203.778
-------------------------------------------------------------------------------FOR!UTIOI FRO !I THE ELE!IERTS

TE!!P.
( H~-
a; 98 )/T
J;aolK
so
-(G;-a~ 98 );T
JjaolK
J;aol K
1.67
1.67
cop
JjaolK
EBTBlLPY
kJ/aol
GIBBS
FREE EIERGY
Loq Kf
ltJjaol
--------------------------------------------------------------------------------1379.375
241.662
148.32
148.32
132.90
-1479.360
298.15
0.000
UNCERTAI IITY
400
500
600
700
800
900
1000
36.625
60.836
78.293
91. 593
102.186
110.944
118.426
190.46
225.60
255.77
282.18
305.72
327.04
346.60
153.83
164.76
177.48
190.59
203.53
216.10
228.17
152.JO
162.14
168.70
173.95
178.71
183.37
188.14
1100
124.988
364.76
239.77
193.13
1200
1300
1400
1490
130.885
136.295
141.350
145.163
381.79
397.90
413.24
425.70
250.90
261.61
271.89
280.53
198.42
204.06
210.07
215.81
1500
1600
207.247
209.331
489.11
504.63
281.86
295. 30
240.60
240.60
1700
1800
211.169
212.803
519.23
533.00
308.06
320.20
240.60
240.60
2.410
2. 470
0.432
-1478.226
-1476.520
-1474.794
-1473.253
-1472.103
-1471.590
-1472.267
-1345.361
-1312.315
-1279.627
-1247.269
-1215.071
-1182.918
-1150.821
175.687
137.097
111.402
93.073
79.336
68.655
60.113
-------------------------------53.115
-1118.527
-1474.434
--------------------------------1474.452
-1086.235
47.283
-1471.098
-1467.417
-1464.465
-1054.104
-1022.201
-993.164
42.355
38.139
34.817
--------------------------------------------------------------------------------993.164
34.817
1490
207.024
487.56
280.53
240.60
-1372.292
!!ELTING POI liT

ERTHALPY OF !!ELTING
1490
-1371.UO
-1365.007
-990.572
-965.401
34.495
31.517
--------------------------------940.134
28.887
-1411.469
-1405.691
-912.531
26.481
BOILIIIG POIBT
92.173 kJ
kJ
ltJ
4.6390 J/bar
46.390 ca 3
!!OUR VOLU!IE
TRANSITIORS IH REFEREHCE STATE ELE!!EITS

IRON CURIE P. 1042, ALPBA-GA.I!!A 1184, GU!A-DELTA
ft. P. DELTA 1809 ~.
SILICON ft. P. 1685 K.
1665~
1.7276x102- 3.4055:r10-JI T
2.2411%10-s T2
(EQUATIOI VALID FROB 298- 1490 1)
BEPBRERCE
190
251
120
93
127
CO!IPIL.BD
8-27-76
362
THER!ODYMA!IC PROPERTIES OF !liBERALS
FAYALITE
Ct"ystals 298.15 to aeltinq point 1490 K.
-------------------------------------------------------------------------------FOR!ATIOI FRO! TilE OXIDES

TE!P.
so
o;-0~ 98 )/T
-(G;-a~ 98 )/T
JjaolK
J/aolK
JjaolK
36.625
60.836
78.293
91.593
102.186
190.46
225.60
255.11
282.18
305.72
153.83
164.76
177. 48
190.59
203. 53
cop
GIBBS
FREE EIIERGY
EIIITHALPY
JjaolK
ltJ/aol
152.3 0
162. 14
168. 70
173.95
118.71
-25.314
-25.718
-26.199
-26. 850
-27.687
Log Kf
ltJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
3.640
148.32
148. 32
132.90
-24. 574
-20.775
UIIICEBTUNTY
1.67
1. 67
400
500
600
700
800
-19.358
-17.809
-16.185.
-14.469
-12.641
2.528
1.860
1.409
1.080
0.825
--------------------------------28.604
-10.697
0.621
0.455
1100
124.988
364.76
-6.716
239.77
-28.1196
0.319
193.13
1200
130.885
381.79
-28.099
-11.760
0.207
250.90
198.42
1300
136.295
397.90
0.113
261.61
204.06
-27.415
-2.820
1400
141.350
413. 24
-26.3911
-0.974
0.036
271.89
210.07
11190
145.163
425.70
-25.911
1.084 -0.038
280.53
215.81
-------------------------------------------------------------------------------11190
207.024
487.56
1.084 -0.038
280.53
2110.60
66.262
1500
207.247
489.11
66.651
0.697 -0.024
281.86
240.60
1600
209.331
504.63
-3.8211
0.125
295.30
70.540
240.60
-------------------------------1700
211.169
519.23
29.468
-3.124
0.096
308.06
240.60
-5.188 0.151
1800
212.803
533.00
32.238
320.20
240.60
900
1000
110.944
118.426
327.04
346.60
ftELTI NG POI NT
11190
ENTHALPY 0 F llELT ING
216.10
228.17
18J. 37
188.14
BOILIMG POIIIT
92.173 ltJ
ltJ
-28.651
-8.715
ltJ
II .63 90 J/ba t"
llOLAB VOLU!E
46.390
CID3

FeO !. P. 1650 K.
Si0 2
ALPHA -
BETA TRANSITION 844 K.
1.7276x10Z- 3.4055x10-3 T
2.2411x1o-s TZ
(EQUATION VALID FROB 298 - 11190 K)
REFERENCE
190
251
120
93
127
CO!IPILED
8-27-76
PROPERTIES AT HIGH TBBPER&rORES
POBST BRITE
363
PORBULA WEIGHT
140.694
crystals 298.15 to aelting point 2163 1.
-------------------------------------------------------------------------------POR!ATIOB PBO! THE EL.EBEIITS

TE!P.
so
<a;-H;98 )/T
J/aolK
-(G;-H; 9 a)/T
J/aolK
J/aoll
cop
EBTHALPY
J;aolK
GIBBS
PBEE EBEIGY
ltJ/aol
Log If
ltJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
95.19
359.3 85
95.19
117.90
-2170.370
-2051.325
UBCEITAIBTY
400
500
600
700
800
900
0.84
0.84
1.325
32.600
54.618
70.915
83.583
93.785
102.233
132.68
164.47
192.24
216.83
238.88
258.87
100.08
109.85
121.33
133.25
145.10
156.64
136.53
148.09
156.32
162. 61
167.63
171.80
1000
109.365
277. 16
167.79
175.33
1100
1200
1300
115.505
120.859
125.587
294.01
309.65
324.25
118.51
188.79
198.66
178.39
181.09
183 .so
1400
1500
1600
129.800
133.594
137.031
337.93
350.80
362.97
208.13
217. 21
225.94
185.68
187.66
189.48
1100
1800
140.165
143.042
374.51
385.48
234.34
242.44
191. 16
192.73
!IELTIBG POIHT
2163
EBTHALPY OF BELTIBG
1.345
0.236
-2170.730
-2170.223
-2169.281
-2168.114
-2166.838
-2165.522
-2010.566
-1970.578
-1930.726
-1891.067
-1851.575
-1812.218
262.554
205.866
168.085
141.114
12 0.896
105.179
-2180.644
-2178.997
-2177.196
-1730. S34
-1689.674
-1648.995
82.177
73.550
66.258
-2424.752
-2420.205
-1542.240
-1483.534
53.706
48.433
-2461.018
-1363.610
39.571
-------------------------------92.535
-2182.126
-1711.526
-------------------------------59.743
-1601.239
-2429.185
--------------------------------1424.709
43.776
-2466.061
BOILIBG PODT
ltJ
BITHALFY OP VAPORIZATIOI
17.276 kJ
4.3790 J/bar
43.790 ca 3
BOLAR YOLOBE
TRABSITIOBS I I REPERBBC! STAT! ELB!IItrl'S

ft.AGIIESIU!I B. P. 922, B. P. 1361 I.
SILICOB !1. P.
1685 K.
BEAT CAPACITY EQOATIOB
2.2798x10Z + 3.4139x10-3 T
( EQUAT 1011 VALID FROB 298 -
REFER! ICE
190
120
1.7446x103 T-05
1800 K)
93
128
COB FILED
7-13-76
364
THEBIIODYBAIUC PBOP):BTIES OF !liBERALS
FORSTERITE
FOBIIULA WEIGHT
140.694
crystals 298. 15 to .elting point 2163 K.
-------------------------------------------------------------------------------FORIUTION FRO II THE O:UDES

TEI'IP.
H;-a~98 )/T
J/IIOlK
so
T
-(G;-u~ 98 )/T
J;aolK
J;aol K
0.84
o. 84
co
J/1101 K
GIBBS
FREE ENERGY
EIITHALPY
kJ/1101
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
95.19
-56.690
-56.645
9.924
95.19
117.90
UNCERTAINTY
0.610
400
500
600
700
800
32.600
54.618
70.915
83.583
93.785
132.68
164.47
192.24
216.83
238.88
100.08
109.85
121.33
133.25
145. 10
136.53
148.09
156.32
162.61
167.63
900
1000
102.233
109.365
258.87
271.16
156.64
167.79
171.80
175.33
1100
1200
1300
1400
1500
1600
1700
1800
115.505
120.859
125.587
129.800
133.594
137.031
140.165
143.042
294.01
309.65
324.25
337.93
350.80
362.97
3H.51
385.48
178.51
188.79
198.66
208.13
217.21
225.94
234.34
242.44
178. 39
181. 09
183.50
185.68
187.66
189.48
191.16
192.73
BOIL I BG POINT
II! LTI NG POI liT
2163
kJ
17.276 kJ
-56.880
-57.079
-57.322
-57.637
-58.070
0.660
-56.612
-56.509
-56.380
-56. 194
-55. 974
-55.360
2.892
-57.810
-57.296
-56.709.
-56.060
-55.337
-54.554
-53.704
-52.783
-55.094
-54.873
-54.706
-54.563
-54.482 ..
-54.443
-511.452
-54.546
2.616
2.389
2.198
2.036
1.897
1.777
1.67 3
1.583
7.393
5.903
4.908
4.193
3.655
--------------------------------58.560
-55.663
3.231
-58.240
..
....
ENTHALPY OF YAPOBIZATIOB
kJ
4.3790 Jt1ar
43.790 ca 3
IIOL lR VOL 011 E
TRAHSITIOBS IN REFERENCE STATE OIIDES

Si0 2 ALPHA- BETA TBAHSITION 844 K.
2.2798x10Z + 3.4139x10-3 T
1.7446x103 T-os
(EQUATION VALID FROII 298- 1800 K)
REFERENCE
190
120
93
128
COIIPIL!D
7-13-76
365
PROPERTIES lT HIGH TEI!PBBlTURBS

FOBI!ULl lEIGHT
PIBOPE
-03.130
-------------------------------------------------------------------------------POBlllTXOI noa TBB !LBIIBITS

THIIP.
so
CH;-a~98 )/T
JjaolK
-(G;-H~ 9 a}/T
J/aolK
Jtaoll
cop
EITBALPJ
Jjaol K
GXBBS
Fill EUBGJ
Loq If
lr.J/aol
kJ/aol
-------------------------------------------------------------------------------1039.341
298.15
260.76
o.ooo
325.50
-6284.620
260.76
-5932.412
U!ICE BTU ITI
10.00
10.00
400
500
600
100
800
900
91.250
153.722
199.935
235.469
263.571
286.267
365.63
455.57
534.09
603.22
664.67
719.77
274.38
301.85
334.16
367.75
401.10
433.50
385.20
419.38
IJ41.07
455.29
1164.62
1110.55
1000
304.885
769.54
464.66
1173.99
1100
1200
320.3111
333.287
814.80
856.19
494.46
522.90
1175.54
475.63
I'IBLTING POIHT
6.000
7.000
1.226
-6285.621
-6283.764
-6280.657
-6277.167
-6273.814
-6270.958
-5811.810
-5693.564
-5575.782
-5458.593
-5341.880
-5225.529
758.948
594.806
485.417
407.327
348.791
303.284
--------------------------------5105.693
266.696
-6317.003
-63111.698
-6312.676
-4984.686
-4863.835
236.704
211.719
BOILIHG POliT
ENTHlLPJ OF IIELTIIG
kJ
ENTHALPY OF VAPOBIZlTIOB
)tJ
IIOLlB YOLUIIE
11.3270 J/bar
113.270 cal
TRlBSITIOIIS II REPBBBICB STATB BLBIIBNTS

l'llGIBSIUll ll. P. 922, B. P. 1361 I.
ALUIIIBUll II. P. 933 K.
SILICOI.... 11. P. 1685 K.
HEAT ClPACITJ EQUlTIOH
8.0258x102 - 9.5795x10-2 T
7.2873x10~ T-os
( EOUlTIOI VALID FROM 298 - 1200 I)
REPB.IlEICB
252
285
252
31
COI!PILBD
03-15-79
366
THBRIIODJ UIIIC PiOPBIT IBS OP II II BilLS
POIBOLl WEIGHT
PDOPE
403.130
=============z=====z=======================:aaaz====-=====================-=
CrJstals 298.15 to 1200 1.
-------------------------------------------------------------------------------PORIIAriOI no a TBJ OIIDBS

TBIIP.
<a;-a~ 98 )~
Jtaoll
sT
Jtaoll
-(G;-a~ 98 )/T
JtaolK
cp
GIBBS
Bft'HALPJ
PllBB BIBBGJ
kJ/aol
J/aoll
Log If
kJ/aol
-------------------------------------------------------------------------------12.918
-7 2. 350
298.15
0.000
325.50
260.76
260.76
-73.732 *
10.00
OICBITll lrt
10.00
4.950
400
500
600
700
800
91.250
153.722
199.935
235.469
263.571
365.63
455.57
534.09
603.22
664.67
274.38
301.85
334.16
367.75
401.10
385.20
1119.38
1141.07
455.29
464.62
900
1000
286.267
304.885
719.77
769.54
433.50
464.66
470. 55
473.99
1100
1200
320.341
333.287
814.80
856.19
494.46
522.90
1175.54
1175.63
liE LTI IG POI l r
BM!BlLPt OP BBI.TIIG
-72.270
-72.2511
-72.609
-73.619
-75.530
5.950
-74.226
-74.714
-75.177
-75.529
-75.706
*
*
*
*
*
9.693
7.806
6.545
5.635
4.942
--------------------------------78.260
4.385
-75.543 *
-79.223
-75.183
3.928
-so. 630
-74.737
-74.114
*
*
3.548
3.227
-82.584
BOlLI IG POIIT
BITHALPt OP VAPOIIZITIOI
kJ
11.3270 JAiar
113.270 cal
!lOLli VOL OIIE
TRlliSITIOIS II IBPBBEICB STITE OIIDBS

SiOz lLPBI - BITl TRAISITIOI 844 I.
HBIT CAPACITY IQOITIOI
c:
8.02581:102- 9.579511:10-2 T 7.2873x103

(BQOlTIOI YILID PIOII 298 - 1200 I)
REI'EBBIICI
252
285
252
r-os
31
COBPILED
03-15-79
367
PROPERTH!S AT HIGH TBIIPEBATURES
CORDI!RITE
FOBitULl WEIGHT
584.957
crystals 298.15 to 1700 l.
-------------------------------------------------------------------------------POBIUTIOI PIOII THE !LEIIEITS

TEIIP.
so
a;-a~ 98 )/T
J;aollt
-(G;-a; 98 )/T
J;aolK
JfaolK
co
ENTHALPY
Jfaol K
GIBBS
PBEE EMEBGY
kJ/aol
Log J(f
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
407.20
407.20
452.30
-91&1.524
-8651.112 1515.645
3. 80
3.80
400
500
600
700
800
900
127.125
214.440
279.428
330.036
370.842
404.656
553.31
678.89
788.99
886.62
974.25
1053.76
426.18
4&4.45
509.56
556.58
603.41
649. 10
537. 34
586.54
620.40
645.93
666.39
683. 53
1000
433.303
1126.56
693.26
698.34
1100
1200
1300
458.005
479.627
498.793
1193.74
1256.16
1314.49
735.74
776.53
815.70
711.46
723. JO
734. 14
1400
1500
1600
515.964
531.497
545.658
13&9. 27
1420. 94
1469.86
853.31
889.44
924.20
744. 19
753.59
762.47
1700
558.662
1516.34
957.68
770.90
IIELTIHG POJ:NT
BOILING POIB T
ENTHALPY OF IIELTIIG
kJ
kJ
ltOLAB VOLUIIE
DNCERTliHTY
5.850
5.900
1.034
-9164.054
-9162.518
-9159.031
-9154.564
-911l9.651
-9144.646
-8476.171
-8304.353
-8133.000
-7962.358
-1792.357
-7622.957
1106.879
867.554
708.044
594.161
sua. 791
442.427
-9193.912
-9186.852
-9179.137
-7274.828
-7100.620
-6927.084
345.454
309.083
278.335
-9413.451
-9401.602
-6556.126
-6366.013
228.306
207.830
--------------------------------9200.284
-7449.584
389.128
--------------------------------6747.032
251.736
-9424.739
-------------------------------189.722
-6174.551
-9641.738
kJ
23.3220 J/bar
233.220 ca 3
TRAJSITIONS IN BEPERENCE STATE ELEIIENTS

IIAGNESIUII
II.
P. 922, B.
ALUIIINUII II. P.
SILICON
II.
P.
P.
1361 K.
933 K.
1685 K.
8.2134x10Z +
4.3339x10-Z T
298 -
REFERENCE
206
273
S.0003x103 T-05
1700 K)
31
COl! PILED
7-13-7&
368
THER!ODYHAIIIC PROPERTIES OF lliHERlLS
FORIIULA WEIGHT
CORDIERITE
584.957
-------------------------------------------------------------------------------FORillTIOH FRO II THE OIIDES

TB!P.
H;-H~ 98 )/T
so
T
-(G;-H~ 98 )/T
J/aolK
J/molK
J/molK
400
500
600
700
800
127.125
214.440
279.428
330.036
370.842
553.31
678.89
7 88.99
886.62
974. 25
900
1000
404.656
433.303
1100
1200
1300
1400
1500
1600
1700
458.005
479.627
498.793
515.CJ64
531.497
545.658
558.662
co
GIBBS
FBEE EIIERGY
EtiTHlLPY
J/ol K
kJ/mol
kJ/aol
426.18
464.45
509.56
556.58
603.41
537.34
586.54
620.40
645.93
666.39
-54.204
-ss. 246
-56.956
-59.470
-62.908
-71.252
1053.76
1126.56
649.10
693.26
683.53
698.34
1193.74
1256.16
1314.49
1369.27
1420.94
1469.86
1516.34
735.74
776.53
815.70
853.31
889.44
924.20
957.68
711. 46
723.30
734.14
744. 19
753.59
762.47
770.90
Log Kf
-------------------------------------------------------------------------------298.15
-53.644
-66.824 11.707
o.ooo
407.20
407.20
452.30
OIICEBTll HTY
1.450
1.470
3. 80
3.80
9.305
-75.396 7.877
-79.265 6.901
6.179
-82.800 5.610
-85.924
-------------------------------5.138
-66.914
-88.525
-66.994
-90.914
4. 749
-66.712
-66.133
-65.303
-64. 244
-63.008
-61.580
-59.986
-93.336
-95.764
-98.270
-100.828
-103.523
-106. 220
-109.063
4.432
4.169
3.949
3.762
3.605
3.468
3.351
IIELTI'IIG POIHT
BOILING POIHT
EHTHlLPY OF IIELTIHG
kJ
EHTHlLPY OF VlPORIZATIOH
kJ
H~98
kJ
llOL.lR VOLOIIE
H~
23.3220 J/bar
233.220 c3
TRlHSI'l'IOHS llf BEPEBElfCE STA 'l'E OIIDES

Si0 2 ALPHA - BETA TRAHSITION 844 K.
8.2134z102 + 4.3339z1o-z T
( BQU.l'l'IOI VALID FRO II 298 -
B!l'EBBIICB
206
273
S.0003z103 T-os
1700 K)
31
CO! PILED
7-13-76
369
PBOP!ITIBS At BIG& TBIIPIBlrUBBS
TBPBBOI!B
POBBULA IBIGBT
crJstals 298.15 to eltiDg point 1620 I.
<a;-a~ 98 )/T
TBIIP.
K
J/olK
so
J/ollt
-(G;-H; 98 )/T
J/oll
cop
201.960
Liquid 1620 to 1800 I.
l'OB!lTIOI PRO! TBB !LBBBITS

GIBBS
PBBB BIBBGY
BITHlLPY
Log If
J/ollt
kJ/ol
kJ/ol
-------------------------------------------------------------------------~------
o.ooo
163.20
4. 20
163.20
4.20
129.87
-1728.070
3.180
-1629.695
3.430
285.517
0.601
1100
500
600
100
800
900
34.975
58.052
74.993
88.007
98.307
106.6411
203.46
236.96
266.06
291.65
314.40
334.82
168.49
178. 91
191.07
203.64
216.09
228.18
11l4.50
155.61
163.31
168.53
172.07
1711.57
-1727.838
-1727.064
-1726.026
-1724.943
-1723.952
-1723.120
-1596.114
-1563.264
-1530.600
-1498.114
-1465.777
-1433.545
208.432
163.314
133.251
111.791
95.706
83.201
1000
113.5110
353.32
239.78
176.46
1100
1200
1300
119.335
124.298
128.628
370.21
385.78
400.23
250.88
261.48
271.60
178.10
179.71
181. so
298.15
UICBBTliiTY
11100
132.479
II 13.76
281.28
183.61
1500
135.969
426.51
290.54
186.15
1600
1620
139.197
139.783
438.62
441.54
299.112
301.76
189.21
189.89
--------------------------------1401.333
-1726.913
73.198
-1726.1147
-1726.022
-1725.618
-1368.803
-1336.288
-1303.834
64.999
58.167
52.389
--------------------------------1271.288
-1729.759
117.1133
--------------------------------1734.194
-1238.278
43.121
--------------------------------1758.908
-1203.882
39.303
-1759.059
-1191.982
38.627
-------------------------------------------------------------------------------1620
195.131
496.89
301.76
2113.10
-1197.982
-1669.395
38.627
-------------------------------1700
197.388
508.00
310.61
243.10
36.050
-1173.273
-1715.998
1800
199.928
521.89
1620
IIBLTI IG POUT
321.96
2113.10
BOlLI IG POIIT
89.663 kJ
Blll'BlLPY OP IIBLTIIG
-1710.890
-1141 ... 76
BI!HlLPY OP flPOBIZlTIOI
kJ
33.125
kJ
4.8610 JA!ar
118.610 cl
BOLli YOLOBB
TlliSI'fiOIS II BBPBBBIICB STlTB BLB!BB!S

ftliGIIBSB lLPRl-BBTI 980 1 BBTl-GI!!l 1360 1 Gl!Bl-DBLTl 1410 1
SILICOI.... ft. P. 1685 K.
HilT ClPlCITf BQDlTIOI
S.12S2s10Z4.6026x10
0.18273 T
( BQD&Tl:OI flLID PBOI
BBPBBDCI
160
5.20SSx1o-
rz
r-z
120
298 - 1620 It)

93
111
COIIPILBD
7-15-76
370
TBEBBODYJlB~C
PROPERTIES OF BIJBBlLS
TEPBBOITE
FOBIIULl lEIGHT
201.960
-------------------------------------------------------------------------------FOBUTIOJ FROB THE OXIDES

TEBP.
(a;-a; 98 )/T
J;aolK
so
J;aol K
-cco;-a~ 98 )/T
JfaolK
cop
GIBBS
FREE EIIERGI
EIITHlLPY
JfaolK
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
163.20
163.20
129.87
-46.930
-47.615
8.342
Ull CERT lllll TY
4.20
4.20
2.000
2. 020
6.243
5. 005
4.178
3.586
3.137
-------------------~----------900
106.644
334.82
-49.050
-47.979
2. 785
228. 18
174.57
1000
113.540
353. 32
239.78
176.46
-49.129
-47.849
2.499
1100
119.335
370.21
250.88
178.10
-49.301
-47.706
2.265
1200
124.298
385.78
261.48
179.71
-49.563
-47.560
2.070
1300
128.628
400. 23
271.60
181.50
-49.897
-47.375
1.904
1400
132.479
413.76
18 ). 61
1. 76()
281.28
-50.270
-47.163
1500
135.969
426.51
290.54
-46.920
1.634
186.15
-50.6'"
1600
119.197
438.62
299.42
21
-50.951
-46.662
1.523
1620
139.783
441.54
301.76
189.89
-50.907
-47.211
1.522
-------------------------------------------------------------------------------1620
195.131
496.89
-47.211
1.522
301.76
243.10
38.756
1700
197.388
-5().916
508.00
310.61
243. 10
42.601
1.564
1800
1.641
199.928
521.89
47.407
-56.544
321.96
243. 10
400
500
600
700
800
34.975
58.052
74.993
88.007
98.307
203.46
236.96
266.06
291.65
314.40
168.49
118. 91
191.07
203.64
216.09
144.50
155.t.1
163.31
168.53
172.07
-47.250
-47.448
-47.593
-47.844
-48. 330
-47.806
-47.913
-47.995
-48.054
-48.042
18~.
IIELTIIIG POIIIT
1620
EJTHALPY OF IIELTIRG
BOILING POIIIT
ENTHALPY OF VAPOBIZlTION
89.663 kJ
4.8610 J/bar
48.610 ca 3
!IOLAR VOLUIIE
kJ
kJ
TBliiSITIOIIS Ill BEFEBEHCE STATE OXIDES

SiOz ALPHA- BETA TBARSITIOH 844 K.

5.1252x10 2
0.18273 T
4.6026x10 T-2
( BQUATIOH VALID FRO!!

REFEBEIICE
160
120
298 -
1620 K)
93
1 11
COli PILED
7-15-76
371
PIOPBBTIBS lT HIGH rBIPBilTUIBS
ZIICOI
POBIOLA VBIGHT
Tetragonal crystals 298.15 to 1800 1.
183.304
lote zircoa decoaposes to
Zr01 and Si0 2 at approxiaately 1949 1.
-------------------------------------------------------------------------------FOBI&TIOI PBOI THB BLBIBITS

TBIP.
I
ca;-ai98 )/T
J/aoll
so
T
-(G;-a; 98 )/T
J/aolK
J/aoll
co
p
BITBALPJ
J/aollt
GIBBS
FBBB BIBBGJ
Log If
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
-1918.890
336.183
o.ooo
84.03
84.03
98.60
-2033.400
UIC!IT AliT I
1.25
1. 25
400
500
600
100
800
900
1000
27.425
46.166
60.108
70.943
79.627
86.744
92.694
115.57
142.55
166.20
187.15
205.89
222.81
238.22
88.14
96.38
106.09
116. 21
126.26
136.07
145.53
115.47
125. 99
133.22
138.41
142.23
145.08
147.21
1100
97.725
252.32
154.59
148.78
1200
1300
1400
1500
1600
102.030
105.747
108.979
111.807
114.292
265.32
217.36
288.55
298.99
308.17
1.000
1.040
0.182
-2033.329
-2032.420
-2031.051
-2029.422
-2027.655
-2025.839
-2024.019
-1879.753
-1841.455
-1803.381
-1165.564
-1127.984
-1690.626
-1653.489
245.472
192.376
156.999
131.749
112.826
98.122
86.370
-2022.250
-1616.515
76.762
-------------------------------68.753
-1579.475
-2024. 290
163.29
171.61
179.57
187.18
194. 48
149.93
150.72
151.23
151.51
151.59
IIBLTI IIG POI IT
80ILI IG POINT
J(
BMTHALP! OF IBLTIIG
kJ
BITH&LP! OF YAPOI.IZATIOI
kJ
14.90 3 kJ
-2022.298
-2020.335
-2018.413
-2016.549
-1542.507
-1505.696
-1468.917
-1432.421
61.979
56.178
51.155
46.764
3.9260 J/tlar
39.260 ca3
I!OLAB VOLUI!E
TBAIS.ITIOIS IN IEFBBBICE STATE ELEIBITS

ZIRCOHIOK ALPHA-BETA 1136 1 8. P. 2125 K.
SILICON.... ft.
P. 1685 K.
BEAT CAPACITY EQUATION
2.3695z1oa1.7879z1o-a T 2.2678z10~ T-os

(EQUATION VALID PBOI! 298- 1600 I)
BEPEBBHC!
115
120
264
234
COli PILED
7-13-76
372
THBRBODIIliiC PROPERTIES OP BIIBBALS
ZIRCOI
zrsio 4
PORBULA WEIGHT
Tetragonal crystals 298.15 to 1800 1.
183.304
lote zircon decoaposes to
ZrOz and SiOz at approziately 1949 K.
-------------------------------------------------------------------------------POR81Tl01 PROS THE OIIDBS

TEBP.
so
-cG;-a; 98 >n
J/ollt
J/lloll
cu;-a~ 98 )/T
J/oll
cop
GIBBS
PRBB BIBBG!
BIITHlLPY
't
kJtaol
kJ/ol
J/oll
Loq
-------------------------------------------------------------------------------298.15
3.471
o.ooo
84.03
-22. 140
-19.812
84.03
98.60
UICEBTliiT!
1.25
1.25
2.010
400
500
600
700
800
27.425
46.166
60.108
70.91113
79.627
115.57
142.55
166.20
187.15
205.89
88.14
96.38
106.09
116.21
126. 26
115.47
125.99
133. 22
138.41
142.23
900
1000
86.7ill4
92.6'!if4
222.81
238.22
136.07
145.53
145.08
147.21
1100
1200
1300
1400
97.7.25
102.030
105.747
108.979
252.32
265.32
211. 36
288.55
154.59
163.29
171.61
119.57
148.78
1169.93
150.72
151.23
1500
1600
111.807
114.292
298.99
308.17
187.18
194.48
151.51
151.59
-22.340
-22.482
-22.629
-22.864.
-23.257
-18.980
-18.127
-17.241
-16.333
-15.369
l.479
1.894
1.501
1.219
1.004
--------------------------------14.348
-23.780
0.833
-23.559
-23.3112
-23.165
-23.053
-23.030
-13.319
O.b9f>
-12.288
-11.298
-10.326
-9.352
0.584
0.492
0.415
0.349
0.221
--------------------------------28.977
-8.330
0.290
-28.715.
f!BLTIHG POllfT
BOILIIG POIIT
EITHlLPY OP ftELTIIG
EITHALPY OP VAPORIZATION
14.903 kJ
2.050
IIOLlB VOLUIIE
-6.943
kJ
3.9260 J/tlar
39.260 ca 3
TRANSITIOIS II REFERENCE STATE OIIDBS

Zr0 2 ftOIOCLINIC TO TETRAGOIAL CRYSTAL 1478 lt.
Si02
ALPHA -
BETA TB.UISITION 844 It.
2.3695z10Z1.7879z1o-z T
2.2678z103 T-os
(EQOlTIOI VALID PRO! 298- 1600 K)
REFEREICE
115
120
264
234
CO!PILBD
7-13-76
PIOPEITIIS
l~
BIGB
373
~IBPBIIrUIBS
FOIBULA VJIGHT
IOLLlS'l'OII~I
CrJstals 298.15 to 1400 K.
Pseudovollastoaite is the
s~able
116.164
phase
aboYe 1398 K.
-------------------------------------------------------------------------------FORIIUIOI FIOII TBB BLIIIBITS

TIBP.
(a;-a;98 }/'1'
J/aoll
so
T
-(G;-a~ 98 )/T
Cop
J/aoll
J/aoll
J/aolK
D~BU.PI
GIBBS
PBBB BIBIGI
kJ/aol
Log '
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
82.01
82.01
-1549.903
271.538
85.27
-1635.220
UICIII'l'liiTI
0.811
0.84
1100
500
600
700
23.900
40.052
51.813
60.789
109."
132.81
152.96
170.63
85.59
92.76
101. 15
109.811
100.48
108.08
112.85
116.28
800
900
1000
61.902
n. 111
78.578
186.311
200.50
213.39
118 ....
126.79
1JIJ. 81
119.01
121.32
123.38
1100
82.738
225.24
1112.50
125.28
1200
1300
86.358
89.555
236.21
2116.45
149.85
156.89
127.06
128.76
1.435
1.455
0.255
-1631l.971
-1634.080
-1633.018
-1631.979
-1520.765
-11192.315
-14611.0119
-11135.980
198.592
155.902
127.457
107.155
--------------------------------1407.951J
91.930
-1631.789
-1630.931
-1630.394
-1380.021
-1352.174
80.095
70.631
-1630.186
-1324.375
62.890
--------------------------------1295.929
56.411
-1637.250
-1635.498
-1267.573
50.932
-------------------------------------------------------------------------------11JOO
92.1J111
116.2111
256.06
-1633.657
-1239.362
163.65
130.111
IIILTI IG POI I~
BOILIIG POUT
IITHlLPI OP IILTIIG
IITHlLPI OP VlPOBIZlTIOI
a; 98 - a:
kJ
3.9930 J/.bar
39.930 ca 3
lOLl B YOLUIII
!BliSITIOIS II I&PIIIICB STATE BLBftiiTS

ClLCIUB lLPHl-BBTl 720, B. P. BBTl 1112, 8. P. 1755 K.
SILICOI II. P. 1685 lt.
HilT ClPACITI BQUlTIDI
1.1125z10Z + 1.4373z1o-z T + 16.936
( BQUlTIOI ULID FROII 298 - 11100 I)
IBFBIIICB
2110
120
,-os
254
19
COIPIJ.BD
7-13-76
374
THBB!ODYil!IC PBOPBBTIBS OP IIIBBlLS
116. 164
POl !U L1 IIBIGHT
lOLLI STOll 'lB
crystals 298.15 to 11t00 K.
Pseudowollastonite is the stable phase
aboYe 1398 K.
-------------------------------------------------------------------------------POil!lTIOI PIOII THE OIIDBS

TEIIP.
so
( a;-H; 98 )/T
J/aolK
'
J/aolK
-(~-a; 98 )/T
J/aolK
cop
GIBBS
FREE EIBIGY
EITBALPY
J/aolK
Loq
It
kJtaol
kJtaol
-------------------------------------------------------------------------------15.790
-90.128
298.15
0.000
82.01
82.01
85.27
-89.~t31
0.84
0.8.
109.49
132.81
152.96
170.63
186.34
85.59
92.76
101.15
109. 84
118.44
UICBRT !Ill TY
400
500
600
700
800
23.900
40.052
51.813
60.789
67.902
0.5160
-89.451
-89.435
-89.552
-89.866
-90.406
100.48
108.08
112.85
116.28
119.01
900
1000
73.711
78.578
200.50
213.39
126.79
134.81
121.32
123. 38
1100
1200
1300
82.738
86.358
89.555
225.24
236.21
2166.45
142.50
149.85
156.89
125.28
127.06
128.76
o. 860
-90.359
-90.590
-90.806
-91.000.
-91.126
11.800
9.464
7.905
6.791
5.950
4.331
--------------------------------91.173
5.292
-91.101
-91.185
4.763
-91.055
-90.969
-90.855
-90.719
-91.201
-91.215 3.970
-91.252 3.667
-------------------------------------------------------------------------------3.407
-91.318
1400
-90.561
92.414
256.06
163.65
130.41
BOIL I lfG POIIT
J(
ltJ
ENTHALPY OF VlPOBIZATIOif
kJ
kJ
I!OLlB VOLUI!B
I!ELTIIfG POINT
ENTHALPY OF IIELTIBG
3.9930 J/bar
39.930 ca 3
TRANSITIONS IB BEP'EBEBCE STATE OXIDES

Si0 2
ALPHA- BETA TBAISITIOI 844 I.
1.1125x102 + 1.437Jx1o-z T
16.936 T-os
(EQUATIOI VALID FRO!! 298 - 1400 K)
REFERENCE
240
120
254
19
CO!! PILED
7-13-76
PROPIITIIS lT HIGH TI!PBBlTDIIS

PSIDDOIOLLlSTOIITI
casio 3 :
375
FOR!DLA lEIGHT
116.164
-------------------------------------------------------------------------------FOB!lTIOI PRO! THE !l.I!BITS

TIBP.
(a;-a;98 )/T
J/aoll
so
-(~-8~ 98 )/T
cop
J/aoll
J/aoll
J/aolK
'I'
BITHALP!
GIBBS
PBIB IIIIGI
Log If
kJ/aol
ltJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
87.45
86.48
-1544.955
270.671
87.45
-1628.650
UliCIBTUITY
0.84
0.84
400
500
600
700
.23.925
39.834
51.372
60. 176
114.96
138.03
157.90
175.31
91.03
98.20
106.53
115. 13
99.74
106.65
111. 21
111f. 65
800
900
1000
67.167
72.900
77.728
190.81
204.80
217.56
123.64
131.90
139.83
117 .so
120.00
122.28
1100
81.877
229.32
147.44
124.43
1200
1300
1400
1500
1600
85.509
88.738
91.643
94.293
96.727
240.23
250.44
260.03
269.09
277.69
154.72
161.70
168. 39
174.80
180.96
126.48
128.47
130.40
132.30
134.17
1100
98.985
285.88
186.90
136.02
BOILilfG
!liLTING POlliT
1811
ENTHALPY OF IIBLTIHG
27.405 kJ
2.594
2.636
0.462
-1628.391
-1627.619
-1626.713
-1625.838
-1516.373
-1488.461l
-11f60.708
-1433.115
198.019
155.1f99
127.166
106.91f1
--------------------------------1405.548
91.773
-1625.807
-1625.091
-1621l.674
-1378.051
-1350.624
79.980
70.550
-1624.563
-1323.240
62.836
--------------------------------1295.202
56.379
-1631.699
-1267.253
-1239.430
-1211.715
-1184.156
-1629.991
-1628.167
-1626.211
-1624. 132
--------------------------------1156.285
35.528
-1672.430
--------------------------------
POIIT
!HTHALPY OP YlPORIZlTIOH
kJ
4.0080 J/bar
40.080 ca 3
!lOLl B YOLO Ill
kJ
50.919
46.244
42.196
3 8.659
TlliSITIOIS II B!F!BBICE STATE ELIIIINTS

ClLCIDII lL.PHl-BITl 720, II. P. BETA 1112 B. P. 1755
SILICOII
11.
P. 1685
BElT
CAP lCITY EQ Ul TIO I
c;
1.0110x102 +
K.
1.7481x1o-z T
298 -
( EQUATIOI VALID FRO!!
RBFEBIICB
115
120
K.
2.2965x10 ,-z
1700 K)
116
COli PILED
8-27-76
376
THIRIODIDIIC PIOPIB'l'IIS OP IIIIIRlLS
PSBUDOiOLLlSTOIITI
CaSi0 11 :
POiBULl lEIGHT
116.164
Crystals 298.15 to eltiag poiDt 1817 I.
-------------------------------------------------------------------------------PORilTIOI PiOB THE OIIDIS

TEIIP.
so
<a ;-a~ 98 )/'l
J/oll
J/olK
cop
-ca;-a~98 )/'l
J/Doll
GIBBS
PI!! Bl!iGI
BITHlLPI
Log If
kJ/DOl
kJ/ol
J/oll
-------------------------------------------------------------------------------298.15
o.ooo
87.45
-85.180. U.923
87.45
86.48
-82.861
UNCBBTli ITI
0.84
o. 84
400
500
600
800
23.925
39.834
51.372
60.176
67.167
114.96
138.03
157.90
115.31
190.81
900
1000
72.900
71.728
204.80
211.56
131.90
139.83
120.00
122.28
1100
1200
1300
11100
1500
1600
1100
81.871
85.509
88.738
91.643
94.293
96.727
98.985
229.32
240.23
250.44
260.03
269.09
277.69
285.88
147.114
154.72
161.70
168.39
174.80
180.96
186.90
124.43
126.48
128.47
130.40
132.30
134.17
136.02
100
IIBLTING POIIT
91.03
98.20
106.53
115.13
123.64
1817
EITHlLPY OF IIBLTING
-85.967
-86.739
-87.465
-88.135
-88.720
11.22 6
9.062
7.615
6.577
5.793
--------------------------------85.261
-89.203
5.177
-85.335
4.682
-89.635
-85.346
-85.304
-85.212
-85.071
-84.889
-811.663
-811.395
-90.066
-90.488
-90.932
-91.386
-91.834
-92.295
-92.793.
4.277
3.939
3.654
3.410
3.198
3.013
2. 851
BOILIIG PODT
27.1105 kJ
H~ 98 - H~
-82.871
-82.974
-83.247
-83.725.
-84.424
99.74
106.65
111 .21
114.65
117.50
kJ
EITHlLPI OP VlPOiiZlTIOI
ltJ
4.0080 J/bar
110.080 c 3
!lOLli YOLOIIE
TRlNSITIOIS II B!PBR!ICE STlTB OIIDBS

Si0 2
lLPHl- B!Tl TiAISITIOI 8114
I.
HilT ClPlCITI EQUATION
c;
1.0710x10Z + 1.7481x1o-z T
2.2965x10 T-z
( EQUlTIOI VlLID FBOII 298 - 1700 I)
BBPBBBNCB
115
120
116
COil PI LID
8-27-76
~ROPBRTIBS
317
AT HIGH TEBPBRATURBS
Ca-ll PYROIEIB
FOR!OLl IBZGHr
218.126
crystals 298.15 to 1700 1.
-------------------------------------------------------------------------------FORIIATIOIII FROB TBI ILI!BIITS

TEIIP.
so
< a;-a~ 98 )/T
-<s;-a; 98 )/T
J/aolK
J/aolK
J/molK
cop
ENTHALPY
JtaolK
GIBBS
l"REI BIIBRGY
kJ/ol
Log Kf
kJ/ol
-------------------------------------------------------------------------------298.15
o.ooo
156.00
156.00
157.03
-3275.680
-3103. 770
543. 770
OHCERTUITY
4.00
2. 761
11.00
400
500
600
700
45.575
71.626
101.380
119.650
208.32
254. 18
294.28
329.61
162.74
176. 55
192.90
209.96
195.65
214.21
225.29
232.811
800
900
134.166
146.022
361.09
389.115
226.92
243. 43
238.50
.243.07
-3276.395
-3275.223
-3273.414
-3271.505
2. 971
0.521
-3044.840
-2987.078
-2929.602
-2872. 463
397.617
312. 059
255.045
214. 347
--------------------------------2815. 485
-3270.509
183.833
-3269.026
-2758. 683
160. 111
--------------------------------2700. 510
141.061
-3289.440
1000
155.925
415.27
259.35
246.97
1100
1611.360
438.97
274.61
250.41
1200
1300
1400
1500
1600
171.664
178.078
183.779
188.900
193.545
460.89
481.31
500.42
518.40
535.38
289.23
303.23
316.64
329. so
341.83
253.56
256.49
259.27
261.93
264.51
BOILIIG POIIT
BMTHALPY 01" VlPORIZlTIOM
kJ
IIBLTIIG POIIIT
ER'l'HALPY 01" IIEI.TIIG
JtJ
-3288.404
-2641.670
125.443
-3294.562
-3291.829
-3288.940
-3285.888
-3282.679
-2582.280
-2523.035
-2464.033
-2405.206
-2346.597
112.404
101.377
91. 934
83. 757
76.608
---------------------------
6.3500 JA_)ar
63.500 ca 3
I!IOLAR VOLOIIB
TRAISI TIOHS II RBFIBBBC! STATE ELEIIEHTS

CALCIUM ALPHA-BETA 120 !!. P. BETA 1112 B. P.
ALUIII lOll... ft.
1755 K.
P. 933 K.

c;
2.3240x102 + 2.18qSz1o-z T 7.2788z10 ,-z

(IQUlTIOJ YALID l"BOB 298 - 1600 K)
REPEREICE
285
88
286
88
COBPILID
03-15-79
~BIB
378
IIODJillllC PllOPBB'll IS OP IU JIB lLS

POil!ULA WIIGBT
Ca-ll PIBOIDB
218.126
Crystals 298.15 to 1700 1.
-------------------------------------------------------------------------------FOBBlTIOI FBOII THE OIIDBS

TBBP.
(H;-a;98
J/aolK
so
-( ~- 8 ~98 )f':
.l/aolK
J/aollt
cop
GIBBS
BITBlLPI
Filii BIBBGI
kJ/aol
Jtaoll
Log Kf
kJ/aol
------------------------------------------------------------------------------298.15
o.ooo
156.00
10. 821
156.00
157. OJ
-54. 191 *
-61. 767 *
UIICBITliiTI
400
500
600
700
800
45.575
77.626
101.380
119.650
134. 166
4.00
lt.OO
208.32
2511.18
294.28
329.61
361.09
162.14
176.55
192.90
209.96
226.92
2.040
195.65
214.21
225.29
232.84
238.50
900
1000
146.022
155.925
389.45
lt15. 27
2U.43
259.35
21U.07
246.97
1100
1200
1300
1400
1500
1600
164.360
111.664
178.078
183.779
188.900
193.545
438.97
460.89
481.31
500.42
518.1t0
535.38
274.61
289.23
303.23
316.64
329. so
3111.83
250.41
253.56
256.49
259.21
261.93
264.51
BB Lft IG POI IT
-54.571
-54.594
-54.684
-54.987
-55.560
2.080
*
*
*
*
'fBliSITIOIS II llBPIBBICI
S~lTE
8. 393
6.968
6. 016
5. 335
4. 820
--------------------------------76.041 *
4. 414
-56. 331 *
-56.403
-78.233
4.087
-56.468
-56.532
-56.592
-56.641
-56.694
-56.728
*
*
*
*
-80.416
-82.572
-84.749
-86.924
-89.094
-91. 223
*
*
3. 818
3. 594
3.405
3. 243
3.103
2. 978
BOILIIG PODT
!ITBlLPJ OP BBLTIJG
-64. 271 *
-66.699 it
-69.102 *
-71.493 *
-73.816 *
*
*
*
kJ
IITBlLPJ OF VlPOBIZ&riOI
kJ
IOLlB VOLUIIB
kJ
6 .1500 J~ar
63.500 ca 3
OXIDES
SiOz lLPBl - BBTl TlliSITIOI 841t I.
HilT ClPlCITJ BQDlTIOI
c;
2. 3240%102 + 2.181t5x1o-z T 7.2788x10 r-z

(BQUlTIOI YlLID FROB 298 - 1600 I)
IEPBilBICB
285
88
286
88
COIIPI.LBD
03-15-79
PROPERTIES AT HIGH TIBPERATURES
DIOPSIDE
379
FOBBULA WEIGHT
216.553
Crystals 298.15 to aeltiuq point 1664 K.
~--------------------------------------------------------------------------------
FORBATIOII FRO! THE ELEBEITS

GIBBS
FREE Ell EB GY
TE!P.
ENTHALPY
J/aol K
298.15
o.ooo
UBCIRT AI liT Y
kJ;aol
kJ/aol
143.09
o. 84
143.09
0.84
166.52
-3210.760
9. 120
-3036.554
9.160
531.994
1.605
600
700
46.400
77.808
100.950
118.877
196.45
241.77
281.24
316.13
150.05
163.96
180.29
197.25
194.83
210.81
221.96
230.60
-3210.800
-3209.587
-3207.850
-3205.893
-2976.984
-2918.662
-2860.617
-2802.91(1
388.756
304.912
249.040
209.157
800
900
133.300
145.244
347.40
375.76
214.10
230.52
237.70
243.72
-3204.605
-3202.512
-2745.390
-2688.092
179.256
156.013
1000
155.356
401.71
246.35
248.90
-3209.601
-2630.281
137.392
400
SOu
1100
164.069
425.65
261.58
253.39
-3207.899
-2572.451
122.156
1200
1300
171.678
178.394
447.87
468.59
276.19
290.20
257.27
260.59
-3213.333
-3209.850
-2514.107
-2455.994
109.437
98.683
1400
1500
1600
184.364
189.714
194.521
488.01
506.26
523.47
303.65
316.55
328.95
263.38
265.67
267.48
-3333.180
-3328. 236
-3323.214
-2394.565
-2327.674
-2261.133
89.343
81.057
73.819
IIELT I NG POUT
EIITHALPY OF !ELTIIIG
1664.50 K
77. 404 kJ
kJ
BOILIIIG POIIIT
ENTHALPY OF VAPORIZATIOII
BOLAR VOLUIIE
6.6090 J/bar
66.090 ca 3
TRAIISITIOIIS II REFIREICE STATE ELE!EIITS

CALCIU! ALPHA-BETA 720, !. P. BETA 1112, B. P. 1155 K.
!AGNESUI'I !. P. 922, B. P. 1361 K.
SILICON 8. P. 1685 K.
HEAT CAP &CITY EO UA TIOll
1.9182x102 + 8.3079x1o-z T
2.1718x1o-s T2
( )!1JU1TIOII VALID FRO! 298 - 1600 K)
REFBREICE
115
120
148
178
CO!PILED
10-29-76
380
THEII!ODI llli!IC PROPERTIES OP IUIIEIALS
DIOPSIDE
216.553
FORI!OLA WEIGHT
Cal! 9( S iO 3
crystals 298.15 to aelting point 1664 11:.
)2 :
-------------------------------------------------------------------------------PORI!A!IOII PRO!! THE OIIDES

TEI!P.
so
( H;-H; 98 )/T
J/IIOlK
II:
J/olK
-(G;-a~ 98 }/T
JfaolF.:
cop
GIBBS
FREE EliERGI
EliTHALPY
kJ/1101
JfaolX
Log F.:f
kJ/1101
---------~----------------------------------------------------------------------
0.000
143.09
0.84
143.09
o. 84
166.52
-152.781
8.850
-151.295
8.900
400
500
600
700
800
46.400
77.808
100.950
118.877
133.300
196.45
241.77
281.24
316.13
347.40
150.05
163.96
180.29
197.25
214.10
194.83
210.81
221.96
230.60
237.70
-152.931
-153.100
-153.456
-154.065
-154.982
-150.771
-150.205
-149.592
-148.906
-148.118*
19.6 89
15.692
13.023
11.112
9.671
900
1000
145.244
155.356
375.76
401.71
230.52
246.35
243. 72
248.90
1100
1200
1300
1400
1500
1600
164.069
171.678
178.394
184.364
189.714
194.521
425.65
447.87
468.59
488.01
506.26
523.47
261.58
276. 19
290.20
303.65
316.55
328.95
253. 39
257.27
2M. 59
263.38
265.67
267.48
-145.320
-144.484
-143.705.
-143.009
-142. 366
-141.767
6.901
6.289
5.774
5.336
4.958
4.628
298.15
OIICERTliiiTJ
1664.50 K
!!ELTING POIRT
11.404 kJ
ENTHALPY OP I!IELTI NG
kJ
26.506
-------------------------------8.542
-156.071 -147.180.
-146.218
7.638
-155.568
-154.899
-154.119
-153.273
-152.401
-151.546
-150.743
BOILING POIIT
EITHALPY OP VAPORIZATION
kJ
6.6090 Jfbar
66.090 ca 3
I!IOLA B YOLO I!E
TRANSITIOHS Ill REPEBEMCE STATE OXIDES

Si02
BETA TBliiSITIOI 844 I.
ALPHA -
HEAT CAPACITY EQOATIOM
1.9182z102 +
8.3079x1o-z T
2.1718z1o-s T2
298 - 1600 X)
( BQOATIOII VALID PBO!
BEPEIBICB
115
120
148
178
CO! PILED
10-29-76
381
PROPEBTIES AT HIGH TEIIPERATORES
m-SPODOIIEIIB
POBIIOLA WEIGHT
186.090
-------------------------------------------------------------------------------POBIIATIOII PBOII THE ELEIIEIITS

TEIIP.
so
-(G;-H~ 98 )/T
cop
J/olK
J/ol K
J/olK
o. 80
o. 80
179.80
135.88
<a;-H~ 98 )/T
J/olK
GIBBS
PRBB EHBBGY
BIITBALPY
Log 't
kJ/aol
kJ/ol
-------------------------------------------------------------------------------129.30
-2880.203
504.602
298.15
o.ooo
129.30
158.90
-3053.500
OIICEBTAI liT I
400
43.925
184.70
500
600
700
800
900
74.022
96.763
114.746
129.414
141.644
223.11
261.45
295.75
326.72
354.93
149.09
164.69
181.00
197.31
213.29
203.21
217.09
227.74
236.09
242.72
1000
152.032
380.79
228.76
248.04
1100
1200
160.963
168.727
404.64
426.75
243.68
258.02
252.34
255.82
2.800
0.490
-3054.521
-2820.797
368.360
--------------------------------2762.071
288.553
-3057.381
-3056.322
-3054.560
-3052.332
-3049.822
-2703.090
-2644.353
-2585.884
-2527.725
235. 326
197.325
168.842
146.706
-3054.684
-3051.373
-2410.380
-2351.930
114.460
102.317
--------------------------------2469.101
128.973
-3057.801
BOI LI NG POUT
kJ
EITBALPY OP YAPOBIZATIOI
kJ
kJ
IIOLAB YOLOIIB
IIELTIIIG POIIIT
EIITHALPY OF IIELTIBG
2.790
5.8370 J/bar
58.370 c3
TBAIISITIOIIS Ill BEPEBEICE STATE ELEIIEIITS

LITHIOII II. P.
453.69, B. P. 1618 K.
ALOIIIIIOII II. P. 933 K.

SILICOII ft. P.
1685 K.
BEAT CAPACITY EQOATIOII
c; =
4.2117x10Z-
2.4005x1o-z T 4.7761x10~
2 98 - 1200 It)
,-o
1.9100x10 ,-z
( EQOUIOI YALJ:D FIOII
BEPBRDCB
211
211
93
15
COIIPILBD
9-13-76
382
THERftODIIAftiC PROPERTIES OF !IIEBALS
cr-SPODUftEIE
186.090
FOR!ULJ. IIEIGBT
======================================================================~==~======
-------------------------------------------------------------------------------FOBII.lTIOI FBOft THE OXIDES

TEI!P.
a;-a~ 98 }/T
so
T
-(G;-a~ 98 )/T
CD
p
GIBBS
FBEE EIIERGY
EITH.lLPY
Log Kf
J/molK
JjmolK
JjmolK
J/molK
kJ/1101
kJjmol
o.ooo
129.30
o.8o
129. 30
o. 80
158.90
-94.885
2.300
-95.520
2.31 5
16.735
400
500
600
700
800
43.925
74.022
96.763
114.746
129.414
179.80
223. 11
261. 45
295.75
326.72
135.88
149. 09
164.69
181.00
197. 31
184.70
203.21
217.09
227. 74
236. 09
-94.885
-95.152
-95.562
-96.181
-97.103
*
*
*
-95. 749
-95.942
-96.061
-96.101
-96.027
*
*
12.504
10.023
8.363
7.171
6.270
900
1000
141.644
152.032
354.93
380.79
213.29
228.76
242.72
248.04
1100
1200
160.963
168.727
404.64
426.75
------------------------------------------------------------------------------298.15
UIICEBT.liiiTI
-97.843
*
*
-95.56 8
-97.386
-96.933
-95.363
-95.200
252.34
255.82
!ELTING POINT
BOILIBG PODIT
EliTHALPY OF I!ELTIIIG
kJ
EITHALPY OP VAPORIZATIOII
kJ
-------------------------------5.561
-98.240
-95.815
243.68
258.02
8 ~98 - Ho0
*
*
*
4.992
4.528
4.144
K
kJ
5.8370 Jjbar
58.370 CIIJ
I!OLA B VOLU liE
TBAIISITIOIIS Ill REPEBEHCE STATE OXIDES

Si0 2
BETA TBAIISITIOII 844 ft
.lLPH.l -
HEAT CAPACITY EQO.lTIOii
4.2117x10Z -
2.4005x1o-z T
4.7761z10~ T-os
298 - 1200 K)
( EQU.lT 1011 VALID FRO II
BEPEBEICE
211
211
93
15
CO! PILED
9-13-76
383
j'j-SPODUIIEHE
FORIIULA
186.090
WEIGHT
Crystals 298. 15 to 1700 K.
-------------------------------------------------------------------------------FORIUTIO!i FRO II THE ELEI!EiiTS

TEIIP.
so
T
( a;- a; 98 )/T
J/aolK
-(G;-a~ 98 )/T
Co
J/aol K
J/aolK
J/aolK
EliTHALPY
GIBBS
FREE EliEBGY
ltJ/aol
Log
Kf
kJ/1101
-------------------------------------------------------------------------------298.15
o.ooo
1511.110
1511.110
162.80
-3025.300
-2859.487
500.97 2
2.790
2. 805
0.490
-3025.841
-2802.709
365.998
-3026.815
-3024.757
-3022.282
-30 19. 542
-2690.1185
-2634.591
-2579. 01 0
-2:')23.761
2311.229
196.596
168.393
1116.1176
-3023.9011
-3020.281
-3016.449
-3012.4113
-3008.271
-3003.9611
-2412.303
-2356.850
-2301.722
-2246.925
-2192.374
-2138.121
114.551
102.591
92.1185
83.834
76.3116
69.803
1. 20
1.20
400
45.125
206.28
161. 15
189.61
500
600
700
800
900
75.894
98.9112
117.036
131.726
143.956
250.61
289.62
3211.38
355.69
384.17
1711.72
190. 68
207.34
223.96
240.21
207.37
220. 38
230.42
238.43
245.01
1000
154.3117
410. 27
255.92
250.51
1100
1200
1300
11100
1500
1600
163.308
171.137
178.053
184.214
189.753
194.759
434.37
456.76
417.65
497.24
515.68
533.09
271.06
285.62
299.60
313.03
325.93
338.33
255.20
259.24
262.76
265.86
268.60
271.05
1700
199.312
549.59
350.28
27 3. 25
BOlLING POINT
ltJ
MOLAR VOLUIIE
UliCERTAI NTY
IIELTI NG POINT
-------------------------------286.9115
-3028.245
-27116.685
-------------------------------128.919
-3027.286
-2468.066
-------------------------------63.789
-3245.573
-2076.045
kJ
ENTHALPY OF !IELTING
7 82 50 J /bar
78.250
ca 3

LITHIU!I !1. P.
453.69 1 B. P. 1618 K.
ALUIIIHUII
933 K.
II.
P.
SILICON II. P.
1685 K.
c;
3.6281x10Z
3.6841x10-3 T
3.43116x103 T-05
298 - 1700 K)
REFEREHCE
211
211
93
15
COli PILED
9- 8-76
384
THERBODYIA!IC PROPERTIES OF !IIERALS
j;-S PODUKEN E
186.090
FORBULA VEIGHr
-------------------------------------------------------------------------------FOR!ATIOIII FROII THE OXIDES

TEIIP.
H;-H~ 98
so
)/T
J/aolK
J;aol K
-(G;-H; 98 )/T
J/aolK
cop
GIBBS
FREE EIBRGY
EITBALPY
J;aolK
Loq Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
154.40
-66.685
-74.804
o.ooo
154.40
162.80
13.105
UNCERT AI!fTY
1.20
1. 20
2.320
2.300
-77.661 10.141
8.416
-80.556
-83.456
7.265
-86.339
-89.153 6.443
5.821
--------------------------------67.960
-91.851
5.331
-67.328
-94.533
4.938
400
500
600
700
800
45.125
75.894
98.942
117.036
131.726
206.28
250.61
289.62
324.38
355.69
161. 15
174.72
190.68
207.34
223.96
189.61
207.37
220. 38
230.42
238.43
900
1000
143.956
154.347
384. 17
410.27
240.21
255.92
245.01
250.51
1100
1200
1300
1400
1500
1600
1700
163.308
171.137
178.053
184.214
189.753
194.759
199.312
434.37
456.76
417.65
497.24
515. 68
533.09
549.59
271.06
285.62
299.60
313.03
325. 93
338.33
350.28
255.20
259.24
262.76
265.86
268.60
271.05
273.25
BOIL! NG POI!IT
kJ
kJ
kJ
IIOLAR VOLOIIE
IIELTI NG POUT
-66.205
-66. 016
-66.055
-66.378
-67.053 .
-66.606
-65.841
-65.068
*
-64.315
-63.616
*
-62.981
-6 2. 435
-97.286 *
-100.120
-103.002 *
-105.951
-108. 953
-111.973
-115.066
4.620
4.358
4. 139
3.953
3.794
3.656
3.536
7.8250 Jft!ar
78.250 ca 3
TRANSITIONS IN REFERENCE STATE OIIDES

Si0 2 ALPHA -
HEAT CAPACITY
c;
BETA TRAISITIOIII 844 K.
EQUATIOI
3.6281x102
3.6841x1o-:s T
3.4346x10:S T-os
2 98 - 1700 K)
( EQOATIOII VlLID FBOB
REFER EHCE
211
211
93
15
COil PILED
9- 8-76
PROPERTIES lT HIGH TERPEBlTUBES
385
BUCBYPTITE
LillSi0 4 :
FOB!ULl lEIGHT
a-eucrrptite 298.15 to 1300 l.
126.006
1300 to 1600 l.
~-eucryptite
-------------------------------------------------------------------------------FOIIIlTIOI FiO! THE BLEIIEITS

TB!P.
< a;-a; 98 )/T
J/aoll
It
soT
cop
-<co;-a~ 98 )/T
J/aollt
BITBlLP!
JjaolK
J/aollt
GIBBS
FBEB EIBBG!
Log
It
kJ/aol
ltJ/aol
--------------------------------------------------------------------------------2009.114
298.15
o.ooo
103.80
103.80
113. 30
-2123.300
352.000
UHCERT lilT!
400
32.025
o.8o
o. 80
140.59
108.57
136.03
500
600
100
800
900
54.286
71.047
84.201
94.864
103.722
172.52
200.73
225.86
248.48
269.04
118.23
129.68
141.66
153 62
165.32
149.79
159.38
166.56
172.20
116.79
1000
111.224
287.87
176.65
180.61
1100
1200
117.684
123.319
305.24
321.36
187.56
198.04
183.86
186.67
1.980
1. 990
0.348
-2123.903
-1970.047
257.263
--------------------------------1931.316
201.764
-2126.521
-2125.464
-2123.922
-2122.081
-2120.072
-1892.364
-1853.631
-1815.129
-1176.876
164.746
138.320
118.516
103.128
--------------------------------1138.100
90.789
-2128.640
-2126.146
-2123.467
-1699.158
-1660.448
80.687
72.278
--------------------------------------------------------------------------------1fi21. 438
65.15 0
1300
128.642
336.34
201.70
191.20
-2120.170
1400
1500
1600
133.543
138.295
142.946
350.89
365.01
378.74
-2116.492
-2112. 137
-2107.066
-1583.135
-1545.166
-1507.544
217.35
226.72
235.79
200.83
208.75
216.67
IIELTIJG POIHT
It
BOILIIG POIIT
EHTRlLPY OP !ELTIHG
kJ
BITHlLPY OF VlPOBIZlTIOI
kJ
ROLli VOLU!E
59.068
53.808
49.216
kJ
5.3630 J/bar
53.630 ca 3
TRliSITIOIS II REFERBICE STlTB ELBREWTS

LITBID!. .
ft.
P. 453.69, B. P. 1618 l.
ALD!IIU! II. P. 933 lt.

SILICOI.... II. P. 1685 K.
HEAT CAPACITY EQ UlTIOI S
c;
2.4697z102-
2.0577z10~
( EQUlTIOtl VALID FROII
c;
r-os
298 -
1.2895z10 r-z
1300 K)
7.9203z1o-z T
( IQOlTIOH VALID FRO! 1300 - 1600
89.943 +
REFBREICE
211
211
K)
93
15
COIIPILID
9- 8-76
386
TBEB!OD!Il!IC PROPERTIES OF BIBBBlLS
EOCBYPTITI!
FOB!OLA WEIGHT
Li.AlSiO,.:
cr Eucr:rptite 298.15 to 1300 K.
126.006
Bucr:rptite 1300 to 1600 K.
-------------------------------------------------------------------------------FOR!ATION FRO! THE OXIDES

Till P.
(a;-a~ 98 )/T
J/aolK
-( G;-H~ 98 )/T
co
J/aolK
J/aolK
J/aol K
0.80
0.80
so
T
GIBBS
EBTHALPY
Log
FBEE EIIIEIGY
kJ/aol
J(f
kJ/ol
-------------------------------------------------------------------------------14.152
298. 15
-so. 779
o.ooo
103.80
103.80
113.30
-75.385
OBCI!BTAIBT!
2. 105
1100
500
600
100
800
32.025
54.286
71.047
84.201
94.8611
140.59
112.52
200.73
225.86
248.48
108.57
118.23
129.68
141.66
153.62
136.03
149.79
159.38
166.56
172.20
900
1000
103.722
111.2211
269.04
287.87
165.32
176.65
176.79
180.61
-75.115
-74.832
-74.601
-74.495
-74.563
2. 115
-82.659
-811.582
-86.554
-88.555
-90.559
10.794
8.836
7.535
6.608
5.913
--------------------------------74.750
-92.539
5.371
-94. 549
4.939
-74. 1811
-96.615
4.588
-98.734 11.298
-------------------------------------------------------------------------------1300
128.642
4.033
336.34
-71.897 -100.367
207.70
191.20
1400
133.543
350.89
-70.605 -102.511
3.825
217.35
200.83
1500
138.295
-104.840
3.651
365.01
226.72
-68.803
208.75
1100
1200
117.684
123.319
305.211
321.36
187.56
198.011
183.86
186.67
-73.580
-72.964
1600
1112.946
378.74
235.79
216.67
-66.435
!!ELTING POINT
BOILUIG POIKT
ENTHALPY OP !ELTING
kJ
ENTHALPY OF VlPORIZATIOH
kJ
8 ~98
kJ
I!OLlB VOLUI!E
- Ho0
-107.315
3.503
5.3630 J/bar
53.630 c3
TRANSITIONS IN BEFEREIIICE STATE OIIDES

Si0 2 ALPHA - BETA TRANSITION 81111
J(.
c;
c~
2.4697x102- 2.0577x103 T-os

1.2895x106 T-2
(EQUATION VALID FROII 298 - 1300 K)
89.943 7.9203x1o-z T
( EQUATIOIII VALID FRO!! 1300 - 1600 K)
REFERENCE
211
211
93
15
COli PILED
9- 8-76
PROPERTiES AT HIGH TE!PERTORES

CLIIOEIS'l'ATITE
llqSiOJ:
387
POBftULA lEIGHT
100.389
Crystals 298.15 to aeltioq point 1830 K.
-------------------------------------------------------------------------------POBBATIOI PROII THE ELBIIBITS

TEIIP.
J/aolK
((
so
<a;-a~98 )/'l
-(G;-u~ 98 )/T
J/aolK
J/aolK
cop
J/aolK
EITni.Pf
GIBBS
FREE EIEilGY
kJ/aol
Loq ((f
kJ/aol
-------------------------------------------------------------------------------298.15
67.86
o.ooo
67.86
82.09
-1547.750
-1460.883
255.942
OICII'l' liiiTI
0.42
0.42
400
500
600
700
800
900
22.350
31.336
48.517
57.284
64.391
70.289
93.58
115.25
134.27
151.20
166.44
180.27
71.23
77.111
85.75
93.92
102.05
109.98
93.01
101. 18
107.39
112.19
115.95
118.113
1000
75.278
192.93
117.65
121.30
1100
1200
1300
79.551
81.252
86.488
204.58
215.37
225.40
125.03
132.12
138. 91
121.19
124.70
125.90
1400
1500
1600
89.336
91.1)65
94.114
234.77
243.54
251.79
145.43
151. 68
157.68
126.85
127.57
128. 11
BOlLING POIIT
I!ELTilfG POINT
1830
ENTHALPY OP IIELTIJG
1.215
1.225
0.215
-1548.099
-1547.927
-1547.414
-1546.686
-1545.830
-1544.1111
-1431.137
-1401.912
-1372.745
-1343.693
-1314.755
-1285.909
186.888
146.457
119.509
100.268
85.845
74.633
--------------------------------1552.917
-1256.427
65.629
-1551.881
-1550.774
-1549.616
-1226.831
-1197.321
-1167.924
58.258
52.118
46.928
-1673.000
-1670.609
-1096.489
-1058.122
38.183
34.544
--------------------------------1135.021
-1675.393
42.?48
61.505 kJ
ENTHALPY Ol VAPORIZATION
12. 113 kJ
I!OL AB VOL Oft E
3. 1 4 7 0 J /!)a r
31.470
ca 3
TRAISI HOIS Il!l llEPEREIICB STATE EI.EIIElfTS

!AGNESIOB II. P. 922, B. P. 1361 K.
SILICON.... II. P. 1685 K.
2.0556x10Z -
1.2796x1o-z T 2.2977x10.J T-os

298- 1600 K)
(EQUATIOlf VALID PBOII

BEP!RENCE
115
120
93
254
COIIPILED
8-26-76
388
THBBBODYIA!IC PBOPBBTIBS OP BIIBBALS
CLIIOBISTATITE
llgSi0 3
POBBDLA lEIGHT
100.389
-------------------------------------------------------------------------------FOBBATIOI PBOB THE OIIDBS

TE!IP.
so
T
( a;-H;98 )IT
J/aolK
-(G;-H; 98 )/T
J/aolK
J/aolK
0.42
0.42
co
GIBBS
PBEE EREBGY
EITBALPY
J;aolK
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
-35.399
o.ooo
67.86
-35.560
6.202
67.86
82.09
UNCEBTliiTY
0.630
400
500
600
700
800
22.350
37.336
48.517
57. 284
64.391
93.58
115.25
134. 27
151.20
166.44
71.23
77.91
85.75
93.92
102 .os
93.01
101. 18
107.39
112. 19
115.95
900
1000
70.289
75.278
180.27
192.93
109.98
117.65
118.93
121.30
1100
1200
1300
1400
1500
1600
79.551
83.252
86.488
89.336
91.865
94.111l
204.58
215.37
225.40
231l. 77
243.54
251.79
125.03
132. 12
138. 91
145. 43
151.68
157.68
123.19
124.70
125.90
126.85
127.57
128.11
IIELTI NG POI IT
ENTHALPY OF !ELTiliiG
1830
-35.750
-36.085
-36.Q86
-36.972
-37.591.
0.650
-35.330
-35.180
-34.962
-31l.669
-Jil.J11
ll.614
3.675
3.044
2.587
2.240
-31.509
-31.062
-30.616.
1.176
1.082
1.000
--------------------------------33.846
-38.300
1.964
-33.353
-38.223
1. 742
-32.874
-38.098
1.561
-37.955
-32.412
1. 411
-31.956
-37.819
1.284
-37.710
-37.632
-37.608
BOIL IIG PO liT
61.505 kJ
EITHlLP! OF VAPOBIZATIOlll
12. 113 kJ
!lOLli VOLO!B
kJ
3.1470 J~ar
31.1l70 cal
TBANSITIOIS IN BEPEBEliiCE STATE OXIDES

SiOz ALPHA- BETA TRlliiSITIOlll 844 K.
c;
2.0556x10Z1.2796x1o-z T 2.2977x10:J T-os

(EQUATIOI VALID FRO! 298 - 1600 K)
REFERENCE
115
120
93
254
1.1926x10 T-z
COIIPILED
8-26-76
389
PBOP!BTIBS lT HIGH TBBPBBl:rOBBS
BHO'DOIITE
POBBOLA WEIGHT
131.022
BDSiO:s:
-------------------------------------------------------------------------------POBIIlTIOI PBOB THE ELEII!ITS

TEI!P.
K
so
T
( H;-u;98 )/T
JjaolK
Jjaollt
-(G;-H~ 98 )/T
Jjaollt
co
GIBBS
FlEE ENERGY
EITBlLP!
JjaolK
kJ/aol
Log ltf
.kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
102.50
102. so
86.44
-1319.350
-1243.081
217.784
OJCEBTliiTY
2.10
2.10
1.310
1.440
0.252
-1319.148
-1318.411
-1317.542
-1316.668
-1315.829
-1315o 025
-1216.938
-1191.466
-1166.153
-1140.996
-1115.954
-1091.007
158.916
124.472
101.523
85.143
12.865
63.321
'400
500
600
700
800
900
24.175
40.1126
52.213
61.186
68.287
74o089
130.30
153.79
114.04
191.17
207.52
221o71
106. 12
113. 36
121.83
130.58
139. 23
147o62
101.42
108.73
113.29
116.61
119. 31
121o67
1000
78o957
234o64
155.68
123 83
1100
1200
1300
83o130
86.773
90.005
246.54
257.58
267.89
163o41
170.81
177o88
125o87
127 83
129.74
1400
92.914
277.57
184o66
131.63
1500
95.555
286o 72
191o17
133o so
kJ
ENTHALPY OP VlPOBIZlTIOH
kJ
!OLl B YOLO I!!
I!ELTIIIG POIBT
1564
ENTBlLPJ OP !ELTING
--------------------------------1316o469
-1066.119
55o689
-1315o702
-1314o875
-13 13o 982
-1041o130
-1016o190
-991.349
49.439
44.234
39o833
--------------------------------966o500
-1315.295
36o061
--------------------------------941.491
-1316o717
32o786
BOILIIG PODIT
3.5160 J/bar
35.160 cal
TRAISITIOIS IN BEPEBENCE STATE ELEI!BJTS

BliGlNESEoo lLPHl-BETl 980, BETl-Gll!l!l 1360, Gllll!l-DELTl 1410,
1!. Po DELTA 1517 Ito
SILICOio o 1!. P. 1685 K.
HilT CAPACITY EQUATION
99.043 + 1.9145z1o-z T
(BQUATIOI VALID PBOII
BEPBBBICE
115
241
285
+ 2. 7447.:.:1 oz T-os
298 - 1500 It)
3o 0407z 1 o T- z
93
127
COil PILED
7-13-76
390
THER!ODYIA!IC PROPERTIES OP !IIBBALS
BHODOIIITE
131.022
FOB!ULA WEIGHT
Crystals 298.15 to eltiog poi.Dt 1564 lt.
-------------------------------------------------------------------------------POB!lTIOI FRO! THE OIIDES

TE!P.
so
u;-u~ 98 )/T
JtolK
J/olK
-(G;-H~ 98 )/T
J/olK
cop
GIBBS
FREE EIIEBGY
EJTHALPY
kJ/ol
J/olK
Log
't
kJ/ol
--------------------------------------------------------------------------------23.897
4.187
298.15
o.ooo
-23.430
102.50
102.50
86.44
UIC EBT lilT I
0.710
0.960
2.10
2. 10
400
500
600
700
800
24. 175
40.426
52.213
61.186
68.287
130. 30
153.79
174.04
191.77
207.52
106.12
113.36
121.83
130. 58
139. 23
101.42
108.13
113.29
116.61
119.31
900
1000
74.089
78.957
221.71
234.64
147.62
155.68
121.67
123.83
1100
1200
1300
1400
1500
83.130
86.773
90.005
92.914
95.555
246.54
257.58
267.89
277.57
286.72
163.41
110.81
171.88
184.66
191.17
125.87
127.83
129.74
131.63
133.50
1564
IIELTI NG POI IT
-23.430
-23.333
-23.317
-23.643
-24. 163
-23.954
-24.093
-24.241
-24.378
-24.443
3.128
2.511
2.110
1.819
1.596
--------------------------------24.437
-24.860
1.418
-24.386
-24.826
1.274
-24.763
-24.677
-24.568
-24.430
-24.280
-24.345
-24.318
-24.295
-24.263
-24.264
1.156
1.059
0.976
0.905
0.845
BOIL I IG PO liT
ENTHALPY OF !ELTIIIG
kJ
ltJ
8~98
kJ
llOLlB VOLOIIE
H~
3.5160 J/bar
35.160 c3
TBA NSI TI ONS II REFERENCE STATE OXIDES
Si0 2
ALPHA -
BETA TBANSITIOI 844 K.
99.043 +
1.9145x1o-z T
(EQUATIOI VALID PBO!
REFERENCE
115
241
285
2.7447x10Z T-os
298 - 1500 K)
93
127
CO! PILED
7-13-76
PBOPEBTIBS AT HIGH TE!PEilTUBBS
JADEITE
391
POB!lULl WEIGHT
202.140
llall( SiO:. )z:
-------------------------------------------------------------------------------POB!ATION FBOII THE BLE!lEITS

TE!lP.
K
<H;-H~ 98
so
)/T
J/aolK
cop
-(G;-H; 98 )/T
J/aolK
EITH&LPY
J;aolK
J/aolK
GIBBS
PBEE EIEBGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
133.47
133.47
159.95
-3029.400
-2850.834
499.456
UICBBTUU'Y
1.25
1.25
4.180
4.230
O.H1
--------------------------------3033.114
-2789.270
361t.243
400
500
600
700
800
900
44.725
75.266
97.971
115.656
129.906
141.711
184.87
228.87
267.40
301.56
332.22
360.02
140. 14
153.60
169.42
185.90
202.31
218.31
188.44
205.34
217.10
225.98
233.09
238.99
1000
151.696
385.47
233.71
244.05
1100
160.297
408.94
248.64
248.47
1200
1300
167.813
174.461
430.74
451.09
262.93
276.63
252.42
255.99
I!EL TI NG POitiT
BOILING POINT
ENTHALPY OF I!ELTIHG
kJ
kJ
kJ
BOLAR VOLU!lE
-3032.857
-3031.734
-3030. 084
-3028.105
-3025.928
-2728.337
-2667.516
-2606.934
-2546.617
-2486.541
285.029
232.229
194.533
166.278
144.316
-3031.621
-2365.274
112.]18
-3122.193
-2234.316
89.716
--------------------------------3034.310
-2425.980
126.721
-------------------------------100.237
-312&.141
-2302.757
&.0400 J;bar
60.400 c11 3
TRAHSITIOIS IN REPEREHCE STATE ELEI!ENTS

SOOIU!l 1!.
P. 370.98, B. P. 1175 K.
ALUI!INU!l 1!. P. 933 K.

SILICON 1!. P.
1685 K.
BEAT CAPACITY EQUATIOI
3.0113x102 + 1.0143x1o-z T
( EQUATION V&LID FRO I! 298 -
RBPEREHCE
115
120
2.0551x10~
T-os
1300 K)
97
149
COI!PILED
7-13-7&
TB!BilODlll!IIC PROPERTIES OF !IUEBlLS
392
FOR!IOLl WEIGHT
JADEITE
202.140
II all( SiO 3 }z:
-------------------------------------------------------------------------------FOiftlTIOII FROB THE OllDES

TEIIP.
soT
C a;-a~98 }/T
J/olK
J/olK
-(G;-H ~ 98 }/T
J;ol K
CD
GIBBS
FREE EIIEBGY
EITHlLPY
kJ/ol
J/olK
Loq 't
ltJ/ol
-------------------------------------------------------------------------------133.47
-162.740 -159.000 27.856
298.15
o.ooo
133.47
159.95
UIICERTliiTY
1. 25
2.380
2.400
1.25
400
500
600
700
800
44.725
75.266
97.977
115.656
129.906
184.87
228.87
267.40
301.56
332.22
140.14
153.60
169.42
185.90
202.31
188.44
205.34
217.10
225.98
233.09
900
1000
141.711
151.696
360.02
385.47
218.31
233.77
238.99
244.05
1100
1200
1300
160.297
167.813
174.461
408.94
430.74
451.09
248.64
262.93
276.63
248.47
252.42
255.99
!!ELTING POIIIT
-163.140.
-163.737
-164.622
-165.873
-167.547
-157.660
-156.232
-154.644
-152.891
-150.935.
2 0.588
16.321
13.463
11.409
9.855
--------------------------------8.631
-169.505 -148.716.
7.647
-169.975 -146.390
BOILING POIIIT
EIITHlLPY OF I!ELTIIIG
kJ
!KTHlLPY OF VlPORIZATIOII
6.0400 J/bar
60.400 c 3
IIOLlR VOLUIIE
TRAIISITIOIIS Ill REFEREIICE STATE OXIDES
lla 2 0 II. P. 1193 K.
Si0 2
lLPHl- BETA TRAISITIOII 844 K.
HEAT CAPACITY EQUlTIOli

3.011lx10Z +
1.014lx1o-z T
2.0551x103 T-os
298- 1300 K)
(EQUATIO!i VALID FBOII

RIPER !liCE
115
120
97
149
COIIPILBD
7-13-76
393
PROPERTIES AT HIGH TEIIPERATDRES

FOBIIDLA WEIGHT
TREIIOLITE
812.374
-------------------------------------------------------------------------------FORIIATIOB FRO II THE ELEIIEBTS

TEfiP.
Jjao1K
I(
so
-(G;-a~ 98 )/T
cop
J/11011(
J/11011(
Jjao1K
1. 25
1.25
Ca;-a~98 )/T
GIBBS
EBTHALPI
FREE EBERGI
kJjao1
Loq l(f
kJ/1101
-------------------------------------------------------------------------------298. 15
548.90
-12355.080 -11627.910 2037.170
o.ooo
548.90
655.63
UNCERTAIBTI
400
500
600
700
182.900
309.508
403.765
476.370
759.12
9 40.88
11 oo. 30
1240.82
576.22
631 .37
696.54
7611.45
774.84
850.59
895.89
926.91
800
900
531l. 4 75
583.180
1366.46
1480.95
831.98
897.77
956. 04
992.15
17. 320
17.360
3.041
-12356.640
-12351.782
-12343.991
-12335.242
-11378.298
-11134.232
-10891.365
-10649.984
1485.860
1163.190
948.182
794.715
-12317.399
-10170.383
590.276
-------------------------------679.685
-12327.561 -10409.676
1000
626.419
1587.91
961.49
1041.50
-------------------------------518.624
-9928.687
-12350. 187
1100
667.067
1690.18
1023. 11
1108.67
-12334.212
ftELTI BG POI BT
460.015
-9687.325
BOILIBG POIIT
BBTHALPI OF IIBLTUG
BBTHALPI OF VAPORIZATION
kJ
97.646 kJ
IIOLAB VOLUIIB
kJ
27.2920 J/tlar
272.920
ca 3
TRA BSI TIOBS I B RUIREBCE STATE ELEIIEITS

CALCIUII ALPHA-BETA 720 11. P. BETA 1112 B. P. 1755 K.
RAGBESIUII ft. P. 922. B. P. 1361 1(.
SILICOB. II. P. 1685 K.
BEAT CAPACITY BQUATIOI
6. 1310z10:11
4.1890 T
5.1385z107 T-Z
(EQUATIOI VALID FBOII
RBPBUJCB
151
228
1.7568z10-:ll TZ
298 - 1100 It)

270
COBPILBD
7-13-76
394
THERftODYNlftlC PROPERTIES OF BINEBlLS

FORI'IULA VIIGHT
TREI'IOLITE
812.374
Ca 2 1'1g 5 [Sie0 22 ](OH)2 : Crystals 298.15 to 1100 K.
-------------------------------------------------------------------------------FOBftlTIOB FROft THE OIIDBS

TEI'IP.
(a;-a; 98 )/T
so
-(G;-u~ 98 )/T
cop
J/olK
J/olK
J/olK
400
500
600
700
800
182.900
309.508
403.765
476.370
534.475
759.12
940.88
1100.30
1240.82
1366.46
576. 22
631.37
696. 54
764.45
831.98
714. 84
850.59
895.89
926.91
956.04
900
1000
583.180
626.419
1480.95
1587.91
897.77
961.49
992.15
1041.50
1100
667.067
1690. 18
1023.11
1108.67
GIBBS
FBBE EIIIBIIGY
EITHALPY
J/olK
Log Kf
kJ/ol
kJ/ol
-------------------------------------------------------------------------------298.15
0.000
548.90
-506.022 -487.511 85.410
548.90
655.63
15.200
UIICDTliNTY
15.200
1.25
1.25
--------------------------------550.171 -476.907 62.278
-548.922 -458.692 47.919
-547.764 -1140.760 38.372
-547. 856 -422.940 31.560
-549.441 -405.040 26.447
--------------------------------551.239 -386.750 22.447
-544.678 -368.798 19.264
-53.1.667
-351.733
16.70.1
I!E LTI NG POI NT
BOILIIIG POINT
ENTHALPY OF ftELTIIIG
kJ
kJ
H~ 98 - Hg
97.646 kJ
27.2920 J/bar
272.920 c3
IIOLAR 'IOLUBE
TRANSITIONS IH REFERENCE STATE OXIDES

Si0 2
H 2 0
ALPHA - BETA TRANSITIOII 844 K.

B.
P.
373. 15 K.

6. 1310x 10:1
4.1890 T
5. 1385x 107 T- z

REFERENCE
151
228
298 - 1100 K)
270
COIIPILED
7-13-76
395
PBOPIBTIIS lT HIGH TIBPIRlTOBIS
liOBTBITI
POBIUL& IIIGHT
278.211
crystals 298.15 to aeltiug poiut 1830 1.
-------------------------------------------------------------------------------POBIU.'I'lOB PIOI 'I'BI ILBIBI'I'S

TEBP.
so
<a;-a; 98 )IT
It
J/aoll
-(G;-a~ 98 )/T
J/aollt
.l/aollt
cop
BftBlLP!
J/aolK
GIBBS
lBBI BIBBG!
k.J/aol
Log Kf
ltJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
199.30
199.30
-4229.100
211.40
-4003.326
701.369
UIICBRTU liT!
o. 30
0.30
1100
500
600
700
58.975
99.192
129.013
152.151
267.10
325.04
375.71
420.54
208.12
225.85
246.70
268.39
248.31
270.22
285.18
296.30
800
900
170.7116
186.122
460.71
497.11
289.96
310.99
305.21
312.60
1000
199.138
530.43
331.29
319.18
1100
210.399
561.21
350.81
325.49
1200
1300
1400
1500
1600
220.323
229.220
237.321
21111.810
251.821
589.87
616.76
642.15
666.27
689.31
369.55
387.54
404.83
421.46
437.49
331.86
338.52
345.63
353.34
361.74
1100
258.1166
711.42
452.95
310.92
1800
2611.836
732.74
467.90
380.44
IIBLTIJIG POIU
1830
BVTBlLPY OP BBLTIJG
a;98 -
a~
3. 125
3.145
o. 551
-4229.633
-4228.388
-4226.342
-4223.993
-3926.038
-3850.273
-3774.824
-3699.763
512.691
402.237
328.629
276.081
--------------------------------3624.941
-4222.356
236.686
-4220.036
-3550.385
206.060
--------------------------------3474.566
181.494
-4239.416
-4237.126
-3398.199
161.368
--------------------------------3321.390
144.577
-4241.787
-4237. 278
-4232.291
-4226. 764
-4220.657
-3244.871
-3168.755
-3092.956
-3017.582
130. 381
118.228
107.707
98.514
--------------------------------2941.741
90.389
-4314. 917
----------------------------------4460.376
-2857.785
82.931
BOILI RG POI D
81.000 k.J
BITBlLPI OF YlPOBIZlTIOI
33. 333 kJ
BOLU YOL UBB
10.0790 J/!)ar
100.790 ca3
TRUSITIOIS II RBPIRBICB STATE BLE!.EITS

ClLCIDft lLPHA-BETl 720 a. P. BBTl 1112 B. P. 1755 I.
lLU!I 1011. . B. P. 933 K.
SILICOI B. P. 1685 lt.
HilT CAPACITY IQUITIOI
c; =
5.168lx1oz-
9.2492x1o-z T
1. 4085x 1 o T- z
( IQUlTIOI VlLID lliOft
RBPBREICB
152
56
227
2 98 -
4.188Jx1o- 'fZ
1800 K)
286
93
COIIPILID
03-15-79
396
TBER!ODIIAIUC PBOPEBTIES OF IUIIEBlLS
ABOBTBITI
FOB!ULl lEIGHT
278.211
crystals 298.15 to elting point 1830 K.
-------------------------------------------------------------------------------FOR!ATIOI FBO! TBB OIIDES

TEIIP.
soT
(a;-a~ 98 )/'f
J/olK
.J/oll
-(G;-a~ 9 a)/T
J/oll
cop
GIBBS
FBBE BIEBGI
EITHALPI
J/oll
ltJ/ol
Log Kf
ltJ/ol
-------------------------------------------------------------------------------18.402
298. 15
o.ooo
199.30
199.30
211.40
-105.035 *
-96.911 *
UliCBBTAIITI
0.30
0.30
3. 430
400
500
600
100
800
58.975
99.192
129.013
152.151
170.746
267.10
325.01t
375.71
lt20. 54
460.71
208.12
225.85
246.70
268.39
289.96
248.31
270.22
285.18
296.30
305.21
900
1000
186.122
199.138
497.11
530.43
310.99
331.29
312.60
319.18
1100
1200
1300
1400
1500
1600
1700
1800
210.399
220.323
229.220
237.321
244.810
251.821
258.466
264.836
561.21
589.87
616.76
642.15
666.27
689.31
7 11. "2
732.74
350.81
369.55
387. 54
404.83
421.46
437.49
452.95
467.90
325.49
331.86
338. 52
345.63
353.34
361.74
370.92
380.44
IIBLTIIG PO.IIT
1830
INTHALPI OF IIBLTIIG
-96.961
-97.219
-97.715
-98.523
-99.696
3. 450
*
*
*
*
*
-107.809
-110. 499
-113.105
-115.617
-117.983
*
*
*
*
*
14.079
11.544
9. 846
8. 628
7. 704
--------------------------------101.081 *
-120.170 *
6. 975
-100.877
-122. 307
6. 389
-100.458
-99.820
-98.933
-97.751
-96.249
-94.354
-92.018
-89. 178
*
*
*
*
*
*
*
*
-124.472
-126. 664
-128.936
-131.296
-133.749
-136. 289
-138.988
-141.829
*
*
*
*
*
*
*
5. 911
5. 513
5. 181
4. 899
4. 658
4. 449
4.271
4.115
BOILING POIIT
81.000 ltJ
BNTBALPI OF VAPOBIZATIOII
ltJ
33.333 kJ
IIOLAB VOLU!B
10.0790 J/.bar
100.790 c 3
TBAISITIOliS II BBFBRBICB STATE OIIDBS

Si0 2 lLPBI- BEfl TRAISITIOI 844 K.
HBlT CIPACITI BQUATIOI
5.1683x102-
9.2492x1o-z T
1.4085x10 r-z
(BQUlTIOI VALID FRO!
BBPBBBICB
152
56
227
298-
4.1883x1o-s T2
1800 K)
286
93
COI!PILBD
03-15-79
PROPERTIES AT HIGH TEftPBBArURBS
397
~ORSOLA ii~GHT
CaA1 2 Si2 0 8
278.211
Glass 298.15 to 1500 K.
-------------------------------------------------------------------------------POIUtl'UOI FRO! THE BLBJIBIITS

TEI!P.
K
soT
( H;-s~ 98 )/T
JjaolK
-(G;-a~ 98 )/T
J/aolK
J/aolK
cop
EBTHALPY
J/aolK
GI:BBS
FREE BHERGI
Log Kf
kJ/aol
kJ/aol
--------------------------------------------------------------------------------4157.300
298.15
237.30
690.775
o.ooo
237.30
210.60
-3942.856
U NCERT AIHTY
2.50
400
500
600
700
58.750
98.874
128.792
152.209
304.84
362.62
413.34
458.43
246.09
263.75
284. 55
306.22
247.40
269.91
286.13
298.85
800
900
171.215
187.089
499.04
536.02
327.83
348.93
3(19.40
318.49
1(100
200.635
570.00
369.37
326. 55
1100
212.418
601.47
389.05
333.86
222.822
1200
1300
1400
1500
232.123
240.529
248.201
630.81
658.33
684.25
708.78
!!ELTING POIHT
1830
ENTHALPY OF ftKLTI:NG
3. 300
3. 320
o. 581
-4157. 923
-4156.747
-4154.675
-4152. 153
-3869.424
-3797.422
505.297
396.716
324.356
272. 700
2.50
-3725. 735
-3654.446
--------------------------------4150. 181
-3583.430
233. 975
-4147. 366
-3512.734
-4163. 105
-3368.464
159.956
--------------------------------4166.989
-3295.720
143.459
407.99
426.21
443.72
460.58
340.58
346.85
352.76
358.37
BOlliNG POLHT
kJ
BHTHALPY OF VAPORIZATI:OR
33.154 kJ
203.875
--------------------------------3440.839
179.732
-4166.119
-4161.704
-4156. 001
-4149. 877
-3223.338
-3151.405
-3079.834
129.516
117.580
107.250
kJ
1 o. 3000 J/bai:
103.000 ca 3
JIOLAR VOLUI!B

CALCIOB ALPBA-BITA 720, M. P. BETA 1112, B. P. 1155 K.
lLUftiiiUft II. P. 933 K.
SILICON M. P. 1685 K.
3.7517x102 +
3.1970x1o-z T 2.4594x103 T-os

298 - 1500 K)
(BQUATIOI VALLO lROft

RBPERBJCE
152
56
227
286
148
COIIPZLBD
03-15-79
398
!BER!ODIIAIIC PBOPBBTXBS 0!' IIIBBllS

!'OBIIOLl 11BlGBr
Call 2 Si 2 0 8 :
218.211
Glass 298.15 to 1500 K.
-------------------------------------------------------------------------------!'ORIIATXOI !'BOll TBB OlXDES

TBIIP.
sr
-<c;;-a; 98 )tr
cp
J/aoll:
J/aoll
J/aolK
( a;-a; 98 )It'
J/aolK
GZBBS
r&BB BIB&GI
UTBALPI
kJ/aol
Log Itt
kJ/aol
------------------------------------------------------------------------------298.15
7.808
o.ooo
237.30
237.30
210.60
-25.111 *
-44.565 *
UICBBTliiTI
2.50
2. 50
3.600
400
500
600
700
800
58.750
98.874
128.792
152.209
171.215
3011.84
362.62
413.34
1158.43
lt99.04
246.09
263.75
284.55
306.22
327.83
21J7.40
269.91
286.13
298.85
309.1JO
900
1000
187.089
200.635
536.02
570.00
348.93
369.37
318.49
326.55
1100
1200
1300
11t00
1500
212.418
222.822
232.123
240.529
248.201
601.47
630.81
658.33
684.25
708.78
389.05
407.99
426.21
443.72
460.58
333.86
340.58
346.85
352.76
358.37
I!BLTIIIG POIIT
1830
EBTBALPI OF IIBLTIIG
3. 620
-25.251
-25.578
*
*
-26.048
-26.683
-27.521
*
*
*
-51.195
-57.648
-64.016
-70.300
-76.473
6.685
6.023
s. 573
5.246
4.993
*
*
*
--------------------------------28.411 *
4. 790
-82.519 *
-27.580
-26.437
-25.022
-23.359
-21. 461
-19.362
*
*
*
*
BOIL IHG PODIT
.kJ
EBTBALPY OF VAPOBIZATIOI
33. 154 ltJ
-88.580
4. 627
-94.737
-100.995
-107.403
-113.946
-120. 627
*
*
*
*
4.499
4. 396
4. 315
4. 251
4. 200
10.3000 J/bar
103.000 ca 3
BOLAR VOLU!IB
TRAISI!IOIS II REPIBBICB STATE OXIDES

SiOz ALPHA- BBTA TRAISITIOI 844 I.
BEAT ClPACITI BQDA!IOI

3.7517z10Z 3.1970x1o-z T
2.4594z10~
( BQUATIOI YALID FBO!I 298 - 1500 K)
BEP.UBICE
152
56
227
r-es
286
148
2.8147x10
r-z
CO!IP.ILBD
03-15-79
399
PROPERTIES AT HIGH TE!PEBATURES
IUCBOCLIHE
FOB!ULl IIEIGHT
278.333
-------------------------------------------------------------------------------POR!ATIOII PBOIJ THE ELEliENTS

TE!P.
(a;-a~ 98
JjaolK
)/T
ST
-(G;-H~ 98 )/T
J/aolK
J/aolK
0.41
0.41
co
p
ElfTHALPY
J;aolK
GIBBS
FflEE ElfERGY
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
214.20
214.20
-3967.690
-3742.330
655.644
0.000
202.40
UICEBTUHTJ
3.310
3.400
0.596
-------------------------------IJ78.544
-3971.889
-3&64. 553
IJOO
500
600
700
800
900
56.100
94.674
123.710
146.474
164.841
180.000
278.70
334.16
383.14
IJ26. 75
IJ65.91
501.39
222.60
239. 49
259.43
280.28
301.07
321.39
236.41J
260.08
276.75
288.74
297.66
304.58
1000
192.749
533.78
341.03
310.27
1100
1200
llOO
1400
203.664
213.161
221.555
229.093
56 3. 59
591.23
617.02
641.25
359. 93
378.07
395.47
412.16
315.27
319.95
324.62
329. 50
!ELTI HG POI HT
BOILING POIHT
ENTHALPY OF !ELTING
kJ
EJTHALPY OF VAPORIZATION
kJ
33.989 kJ
-3971.836
-3970.558
-3968.549
-3966. 137
-3963.518
-3587.706
-3510.975
-3434'. 533
-3358.394
-3282.564
374.807
305.659
256.289
219.282
190.516
--------------------------------3206.286
167.480
-3971.546
-------------------------------148.423
-4047.759
-3125.604
-401JJ. 555
-4039. 122
-4034.420
-3041.930
-2958.649
-2875.727
132.412
118.880
107.295
10.8720 J/bar
108.720 cal
!OL AB VOL UftE
TilJSITIOIIS IN REFERENCE STATE ELEIJENTS

POT I.SSIU! ft. P.
ALUIII IIU!
a.
336.4, B. P. 1030 K.
P. 933 K.
SILICOM IJ. P.
1685 K.
HElT CAPACITI EQUATION
co
p
7.5955x10Z -
o. 21711
4. 761J2x10 T- 2
( EQUATIOII VALID FRO!
REFERENCE
90
115
187
123
6.4333x10-5 TZ
9.5268x103 T-os
298 - 11.00 K)
93
269
COPIPILED
10- 5-76
400
THERBOD!Il!IC PROPERTIES OP !IIERlLS
POR!ULl WEIGHT
!ICROCLili E
278.333
-------------------------------------------------------------------------------PORMATIOI FRO! THE OXIDES

TEIIP.
K
so
<H;-a~98 )/T
J/aolK
-(G;-n~ 98 )/T
J/aolK
J/aolK
0.41
0.41
cop
EITHlLPY
GIBBS
FREE UEBGY
kJ/aol
kJ/aol
J/aolK
Log Kf
-------------------------------------------------------------------------------38.772
298.15
o.ooo
214.20
-216. 154
-221.308
214. 20
202.40
URCEBT AIMTY
1.970
400
500
600
700
BOO
56.100
94.674
123.710
146.474
164.841
278.70
334.16
383.14
426.75
465.91
222.60
239. 49
259. 4 3
280.28
301.07
236.44
260.08
276.75
288.74
297.66
900
1000
180.000
192.749
501.39
533.78
321.39
341.03
304.58
310.27
2.000
-222.833 29.099
-223.902 23.391
-224. 584 19.552
16.783
-224.911
-224.835 14.680
--------------------------------230.754 -224.316 13.019
-232.315 -223.520 11.676
-233.936 -222.569 10.569
--------------------------------235.659 -221.465
9.640
8.848
-237.494 -220.199
8.163
-239.409 -218.781
-217.759
-219.534
-221.538
-223.994
-227.107
1100
203.664
563.59
359.93
315.27
1200
1300
1400
213.161
221.555
229.093
591.23
617.02
641.25
378.07
395.47
412.16
319.95
324. 62
329.50
I!ELTI!fG POIBT
BOILIJG PODIT
ElfTHlLPY OF !!ELTING
kJ
kJ
33.989 kJ
TBAISITIOIS IN
BE~EREICE
10.8720 J/bar
108.720 cal
!lOLl B YOLO BE
STATE OXIDES
K2 0 DECOIIPOS!S ABOVE 1154 K.

SiOz ALPHA -
BETA TBAIISITIOII 844 K.
7.5955x1QZ-
0.21711 T
4. 7642x10 r-z
( BQDATIOI ULID FBOII
B.EFEREICE
90
115
187
123
298 -
1400 K)
93
269
CO!PILBD
10- 5-76
401
PBOPERTIES U' HIGH TEI!PEBATOBIS
POUOL.l lEIGHT
HIGH SlllDIIE
278.333
Crystals 298.15 to aeltiag poiat 1473 1.
------------------------------------------------------------------------------POBI!lTIOI!I PBOI! THE ELBI!EI!ITS

TEI!P.
( a;-H;98 )/T
JtaolK
so
cop
-(G;-u~ 98 )/T
J/aolK
JtaolK
0.48
o. 48
EI!ITHlLPY
GIBBS
PBBE BIBBGI
k.J/aol
J/aolK
Log
't
k.J/aol
--------------------------------------------------------------------------------3739.716
-3959.560
655.196
298.15
o.ooo
232.90
232.90
204.50
01 CEB TAll Tt
400
500
600
700
800
900
56.725
95.638
124.845
147.699
166.117
181.311
298.12
354.10
403.44
447.32
486.71
522.36
241. 39
258.46
278.59
299.62
320.59
341. OS
238.93
262.241
278. 61
290.43
299.26
306.11
1000
194.073
554.91
360.84
311.68
1100
1200
1300
1400
204.986
214.458
222.800
230.250
584.85
612.57
638.42
662.65
379.86
398.11
415.62
432.40
316.46
320.81
324.99
l29.19
IIELTIVG POII!IT
1473
BI!ITHALP! OP I!ELTIIG
3.400
3.370
0.596
-------------------------------4178.4641
-3663.9411
-3963.509
-3963.224
-3961.747
-3959.562
-3956.986
-3954.228
-3589.064
-3514.344
-34139.945
-3365.883
-3292.127
374.949
305.952
256.693
219.771
191.071
--------------------------------3217.962
168.090
-3962.092
-------------------------------149.079
-3139.405
-4038.1741
-4033.868
-4029.373
-4024.670
-3057.851
-2976.720
-2895.937
133.105
119.607
108.049
BOILIJG POUT
61.500 kJ
EITHlLPI OP VlPOBIZlTIOI
33.989 k.J
!lOLli VOLOI!E
1 0. 9050 J/llar
109.050 cal
TBAISITIOIS II B!PBBEI!ICE STATE ELBI!EITS

POTASSIOII II. P. 336.4, B. P. 1030 K.
lLDIII IDS 11. P. 933 K.

HilT CAPACITY BQOlTIOI
6.9337:.:102-
0.17170 T
3.4622:.:10 T-Z
(EQDATIOI VALID PBOII
BBPEBEICE
90
115
187
4.9188:.:10-s TZ
298 - 1400 K)
93
COIIPJ:LBD
10- 5-76
402
THBR!lODIIIAIIIC PBOPEITIES OF IIIIIBBALS
HIGH SANIDIRE
POB!lULl WEIGHT
278.333
crystals 298.15 to melting point 1473 K.
-------------------------------------------------------------------------------POB!llTIOII PRO II THE OIIDES

TE!P.
so
<H;-H~98 )/T
-cs;-H; 98 )/T
cop
J/aol K
J/aolK
J/aolK
JjaolK
400
500
600
700
800
56.725
95.638
124.845
147.699
166.117
298.12
354.10
403.44
447.32
486.71
241.39
258.46
278. 59
299.62
320. 59
238.93
262.24
278.61
290.43
299.26
900
1000
181.311
194.073
522.36
554.91
341.05
360.84
306.11
311.68
1100
204.986
584.85
379.86
316. 46
1200
1300
1400
214.458
222.800
230.250
612.57
638.42
662.65
398.11
415.62
432.40
320.81
324.99
329.19
BITBlLP!
GIBBS
PilE EIIIEBG!
kJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
232.90
232.90
-208.024 -218.754 38.325
204.50
URCBBTAI BTl
0.48
1. 970
2.000
0.48
BELTING POINT
1473
-222.221 29.019
-225.260 23.533
-227.953
19.845
-230.323 17.187
-232.324
15.169
--------------------------------221.444 -233.879 13.574
-222.861 -235. 196 12.285
11.224
-224.351 -236.310
--------------------------------225.912 -231.386
1 0.333
-227.745 -238.270
9.574
8.917
-229.659 -238.991
-209.379
-210.922
-212.727
-215.007
-217.956
BOIL IIIG POilf T
ENTHALPY OF IIELTIIG
61.500 kJ
kJ
H~98
33.989 kJ
IIOLAB VOLUIIE
8~
10.9050 J/bar
109.050 cal
TRANSITIONS II REFERENCE STATE OXIDES

K 2 0
DECOMPOSES ABOVE 1154 K.
SiOz ALPHA- BETA TBANSITIOI 844 K.
6.9337xtoz -
0. 17170 T
3.4622x10 T-z
( BQUlTIOI Vll.ID PIOI
REFERENCE
90
115
187
298 -
1400 K)
93
COl! PILED
10- 5-76
PBOP.BTXES lT HIGH TESPEBl!DBES
lllSi 3 0 8
Kl1Si 3 o8
GLASS
1603
POBIIOLA lEIGHT
278.333
Glass 298.15 to 1300 K.
-------------------------------------------------------------------------------POBII.lTIOJ PBOII THE BLEil BITS

TBIIP.
J{aolK
It
so
c H;-a; 98 )/T
cop
-cc;;-H~ 98 )/T
EITHlLPY
J/aolK
GIBBS
PIE! BUlGY
Log
It
kJ/aol
J/aolJt
J{aolK
ltJtaol
1.78
1. 78
900
57.925
97.564
127.262
150.459
169.097
184.400
328.21
385.26
435.169
480.12
520.11
556.24
270. 28
287.70
308. 23
329.66
351.01
371.84
243.67
267.09
283. 48
295. 14
303.57
309.76
1000
197.178
589.12
391. 94
314.39
1100
1200
1300
208.003
217.286
225.339
619.26
647.05
672.82
411.26
429.76
447.48
317. 95
320.77
323. 12
BOILIIIG POIJT
kJ
EITHALPY OP YlPOBIZlTIOI
-------------------------------------------------------------------------------648.810
298.15
-39116.740
-3703. su
261.60
261.60
209.160
o.ooo.
OICEBTliiTY
400
500
600
700
BOO
IIELTUG POIJT
1473
ERTHlLPY OP IIELTIJG
34. 884 kJ
3.370
3.500
0.613
-------------------------------474.120
-3918.209
-3630.671
-3917.441
-3915.477
-3912.810
-3909.782
-3906.628
-3558.861
-3487.304
-3416.153
-3345.399
-3275.{)19
371.793
303.598
254.918
218.433
190.078
--------------------------------3204.247
167.373
-3914.167
--------------------------------3129.118
148.590
-3990.036
-3985.655
-3981.252
-3051.014
-2973.319
132.808
119.470
11.~500
IIOLAB YOLOIIE
116.500
J/bar
cal
TBliSITIOIS II BBPEBEICE STlTB BLEIIEITS

POTASSIDS 11. P. 336.4, B. P. 1030 K.
ALUSUOII 11. P. 933 K.
SILICOJ 11. P.
1685 K.
HEAT ClPACITY EQUlTIOJ
6.8469Jt10Z-
0.14814 T
3.3049x1o-s TZ
,-z
3.5277Jt10
( BQ UlT lOR YlLID FRO II
BBl'BBEICE
152
56
227
29 8 - 1 300 It)
93
269
COli PILED
12- 3-76
404
TBBRBODYilBIC PROPBBTIBS OP BIIBilLS
Kl1Si 3 0e
PORIIOLl IIIGBT
GLASS
KllSi 3 o.:
278.333
Glass 298.15 to 1300 K.
-------------------------------------------------------------------------------FORUTIOI FROB THE OIIDBS

TEIIP.
<H;-a~98 )/T
J/olIC
so
T
J/olIC
-(G;-u~ 98 )/T
J/aolK
cop
GIBBS
FBBE BIBRGY
EITBlLPY
ltJjaol
ltJ/801
J/aolK
Log Kf
-------------------------------------------------------------------------------298. 15
o.ooo
261.60
-163.204 -182.491
261.60
209.40
UIC.ER Tl i liT I
1.78
1.970
2.000
1.78
31.97~
400
500
600
700
800
57.925
97.564
127.262
150.459
169.097
328.21
385.26
435.49
480.12
520. 11
270.28
287.70
308.23
329.66
351.01
243.67
267.09
283.48
295.14
303.57
900
1000
184.400
197.178
556.24
589.12
371.84
391.94
309.76
314.39
1100
208.003
619. 26
411.26
317.95
1200
1300
217.286
225.339
647.05
672.82
429.76
447.48
320.77
323.12
I!ELTIIG POiliT
1473
F.IITHALPY OF IIELTIIG
-188.957
24.675
20.378
-195.057
-200.913 17.491
-206.531 15.412
-211.840 .- 13.832
--------------------------------173.844 -216.771 12.581
-174.936 -221.481 11.569
-164.079
-165. 139
-166.457
-168.255
-170.752
-116.213
-226.083
10.736
--------------------------------177.759 -230.549 1 0.036

9.437
-179.624 -2311.869
BOILIIG PODIT
ltJ
EWTHALPI OF VAPORIZlTIOB
34.884 kJ
!lOLli VOLUIIB
11.6500 J/bar
116.500 c3
TRAISITIOIS II BBPEREBCE STATE OIIDES

K2 0 DECOIIPOSES ABOVE 1154 K.
Si0 2
HEAT CAPACITY
ALPHA - BETA TlllBSITIOB 844 K.

~UATIOII
6.8469z10Z -
0. 14814 T
3.5271z10 r-z
( BQU1TIOI VALID PROf!
BEFEREICE
152
56
227
298 - 1300 K)
93
269
COli PILED
12- 3-76
405
PIOPBITIBS IT 81GB TBIPBI&TUIBS

I&LIOPBILLIU
Kl1Si0 4 :
POIIULl lEIGHT
Lov taliophillite 298.15 to 810
~.
158.164
High taliophillite 810 to 1800
~.
-------------------------------------------------------------------------------l0Bil1'IOI PIOII TBB .BLBIIBITS

TBIP.
<u;-&; 98 )/T
J/aol~
-<co;-a; 98 )/T
soT
J/aolK
J/aolK
cop
GIBBS
Bl'lBlLPJ
l'IBB BIIBIGJ
kJ/aol
J/aol~
Log
It
k.l/aol
-------------------------------------------------------------------------------298.15
o.ooo
133.26
119.79
-2005.915
351.440
-2121.920
133.26
OICEIT lll TJ
400
500
600
700
800
810
32.800
55.016
71.865
85.1116
96.770
97.751
1.25
1.25
170.98
203.04
231.47
257.15
280.67
286.45
138. 18
148.02
159.60
171.73
183.90
188.70
1.450
1.435
137.02
150.34
161. 62
171.62
180.75
181.63
0.254
-------------------------------256.703
-2125.083
-1965.763
-2124.839
-2123.719
-2121. 882
-2119.442
-2109.308
-1925.949
-1886.263
-1846.8216
-1807.682
-18(16.875
201.203
164.214
137.812
118.(130
116.521
-------------------------------------------------------------------------------810
98.327
287.03
188.70
177.65
-2108.842
-1806.875
116.521
900
106.256
303.87
197.61
177.65
-2116.778
1000
113.391
322.58
209.19
177.65
1100
1200
1300
1400
1500
1600
119.233
124.101
128.219
131.750
134.810
137.1187
339.52
354.97
369. 19
382.36
394. 61
406.08
220.29
230.87
240.97
250.61
259.80
268.59
177.65
177.65
177.65
177.65
177.65
177.65
1700
1800
139.850
1111.949
416.85
427.00
277 .oo
285.05
177.65
177.65
801 t i IG POliT
IIBLTIIG POUT
BITBILPJ OF IBLTIIG
-1770.441
102.754
--------------------------------1731.296
90.434
-2125.596
--------------------------------1687.653
80.140
-2202.973
-2200. 265
-2197.660
-2195. 148
-2192.717
-2190.362
-1640.911
-1594.403
-1548.112
-1501.961
-1456.(106
71.427
64.064
57.761
52.303
117.5311
-------------------------------43.317
-1409.749
-2238.580
-2236.068
-1361.029
BITB&LPJ OP YlPOI.IZlTIOI
39.1196
kJ
5.9890 J~ar
59.890 cal
lOLli YOLUIB
TBliSinOIS II Jl'U'UUCB STlTB BLBIIBITS
POTlSS.IOI I. P. 336.11, B. P. 1030 I.
lLOIIIOII... I. P. 933
I.
SILICOI I. P. 1685
~.
BElT ClPlCITI BQUlTIOI

1.88881102 5.5187z1o-z T (BQUlTIO YlLXD PBOI 298 -
RIPDBICB
201
120
1.4787z10JI
810 It)
r-o.
93
15
COIIPILBD
7-15-76
406
TBERBODIIl!IC PROPERTIES 0' !IIIIlLS
Kl LI OPBILLITE
Low kaliophillite 298.15 to 810 K.
KllSi0 4 :
158.164
'OI!ULl WEIGHT
Big~
kaliophillite 810 to 1800 K.
-------------------------------------------------------------------------------FOB!lUOI FlO! THE OXIDES

TEI!P.
(a;-a; 98 >/T
J/aolK
so
J/aolK
-(G;-H~g 8 )/T
J/aolK
cop
GIBBS
PB.EB BURGI
EIITHlLPI
kJ/aol
J/aolK
Log Kf
kJ;aol
-------------------------------------------------------------------------------298.15
o.ooo
133.26
-191.784
-197.529
133.26
119.79
34.606
UICBRT l i IT I
400
500
600
700
800
810
32.800
55.016
71.865
85.416
96.770
97.751
1.25
1.25
170.98
203.04
231.47
257.15
280.67
286.45
138.18
148.02
159.60
171.73
183.90
188.70
1. 605
137.02
150.34
161.62
171.62
180.75
181. 63
-192.649
-193.617
-194.493
-195.231
-195.834
-195.928
1. 620
-199.363
-200.935
-202.308
-203.554
-2<14. 698
-207.618
26.034
2 0.992
17.613
15.189
13.365
13.389
-------------------------------------------------------------------------------810
98.327
287.03
-195.462
-207.618
188.70
177.65
13.389
-------------------------------1{16. 2 56
900
303.87
197.61
12.034
177.65
-196.514 -207.337
1000
111.391
322.58
209.19
-197.369 -2{18.4916 1 {1.891
171.65
1100
119.233
120{1
1300
1400
1500
1600
1700
1800
124.101
128.219
131.750
134.810
137.487
139.850
141.949
339.52
354.97
369.19
382.36
394.61
406.08
416.85
427.00
220.29
230.87
240.97
250.61
259.80
268. 59
277.00
285.05
I!ELTiliG POiliT
EITBlLPI OF !ELTIIG
177.65
177.65
177.65
177.65
171.65
171.65
177. 65
177.65
-198.614
-209.565
-211.251
-211.865
-212.287
-212.512
-212.541
-212.347
9.951
--------------------------------2{10. 243
-210.479
9.162
-202.248
-204.619
-207.359
-210.456
-213.910
-217.719
8.488
7.905
7.393
6.938
6.531
6.162
BOIJ.IIG POUT
kJ
BITBlLPI OF VlPOIIZlTIOI
kJ
kJ
!OLll VOLU!B
5. 9890 J/bar
59.890 ca 3
TRliSITIOIS IN IEFBB!JCE STATE OIIDES

K2 0 DECOBPOSES ABOVE '1154 K.
SiOz lLPHl -
BET& TRliiSITIOI 8411 K.
HEAT CAPACITY EQ UlTION
1.8888x102 + 5.5187x1o-z T
{ EQUlT lOll V&LID FlO! 298 -
BEFEIEICE
201
120
1.4787x10JI T-as
810 K)
93
15
CO!PILED
7-15-76
PBOP!ITIES IT HIGH TBaPBilTURBS
407
LBUCl:T!
POB!ULI WEIGHT
Tetraqoaa~
218.248
-------------------------------------------------------------------------------PO.RalTIOH PRO! THB BLB!BJTS
(s;-a~ 98 )IT
TEaP.
K
J;aolK
so
-(G;-H~ 98 )/T
cop
J;aolK
J;aol K
J/aolK
EIITHlLPY
GIBBS
I'BEB BURGY
ltJ/aol
Log Kf
kJ/aol
-------------------------------------------------------------------------------298.15
o.ooo
200.20
200.20
164.14
-3038.650
-2875.890
503.846
UICBITUITI
400
500
600
700
800
900
54.825
88.056
110.810
127.461
140.242
147.644
1. 70
1.70
263.42
312.71
353.65
388.69
419.37
ltl4.14
208.59
224.65
242.84
261.23
279. 13
286.50
2.755
188.59
206.89
222.96
237.98
252.44
266.57
2.850
0.499
--------------------------------3038. 181
-2820.285
368.293
-3035.577
-3033.170
-3030.999
-3029.085
-3029.938
-2766.122
-2712.458
-2659.180
-2606.198
-2544.641
288.976
236.141
198.431
110.168
147.688
-------------------------------955
154.715
450.14
274.26
-3037.912
-2514.757
137.547
295.42
-------------------------------------------------------------------------------955
156.647
452.07
295.42
236.33
-3036.067
-2514.757
137.547
1000
160.234
462.95
302.72
236.40
1100
1200
1300
1400
1500
1600
165.820
171.800
176.963
181.507
185.567
189.249
484.04
504.71
523.83
541.66
558.39
574.16
318.22
332.91
346.87
360.15
312.82
384.91
237.04
238.18
239.69
241.46
243. 42
245.53
1700
1800
192.624
195.750
589.11
603.34
396.49
407.59
247.74
250.05
aELTIIIG POUT
-3035. 252
-2490.242
130.017
--------------------------------2431.398
115.458
-3114.402
-3111.952
-3109.537
-3107.109
-3104.632
-3102.073
-2369.394
-2307.614
-2246.041
-2184.615
-2123.364
103.138
92.721
83.801
76.075
69.321
-3197.060
-1994.474
57.878
--------------------------------3200.423
-2061.410
63.340
BOIL I BG POl liT
BHTHALPI OP 8BLTIIG
ltJ
BITHlLPY OP YAPOBIZlTION
kJ
a; 98
kJ
IIOLlB YOLO!B
a~
8.8390 J/bar
88.390 c 3
TBUSITIOIIS II BBPBBBICB STATE ELB!BITS

POTlSSl:Ua a. P. 336.4, B. P. 1030 K.
lLU!IHOft !. P. 933 K.
SILICOI a. P. 1685 K.
BElT CAPACITY EQUATIOIS
cop
Co
1.4842x10Z + 0.13425 T
(EQUATION YlLID PBO!
2 .1645x1 o T-z
955 K)
298 -
1.9647x10Z + 2. 7666x1o-z T
( B,lUATIOII YlLID FBO! 955 -
BBPBBB liCE
201
93
120
1.2261x 107 T-Z

1800 K)
93
15
CO! PILED
7-15-76
TBBBBODYIABIC PIOPIITIBS OP IIIBBALS
408
LEU CITE
FOIBULA lEIGHT
Tetraqonal crystals 298.15 to 955 K.
218.248
-------------------------------------------------------------------------------FOBIATIOI FROB THE OXIDES

TEIIP.
<H;-u; 98 )/T
JjaolK
soT
-<ca;-u; 98 )/T
J/aolK
J/aolK
1. 70
1.70
263.42
312.71
353.65
388.69
419.37
208.59
224.65
242.84
261.23
279. 13
cop
GIBBS
FBBE EIIEBG Y
BITHALPY
kJ/aol
J/aolK
Loq 't
kJjaol
-------------------------------------------------------------------------------298.15
o.ooo
200.20
-197.814. -211.156. 36.994
200.20
164. 14
UIICERTAIWTY
400
500
600
700
800
54.825
88.056
110.810
127.1661
140.242
2.255
2.350
188.59
206.89
222.96
237.98
252.44
-194.899
-193.815
-194.047
-195.396
-197.766.
-216.225.
-221.713
-227.284
-232.734
-237.926
28.236
23.162
19.787
17.3 67
15.535
--------------------------------203.4111 -233.966
13.579
-202.325 -235.600
12.886
-------------------------------------------------------------------------------955
156.647
1152.07
-200.480 -235.600
12.886
295.42
236.33
900
955
147.644
154.715
434. 14
450.11l
286. so
295.42
266.57
274. 26
1000
160.234
462.95
302.72
236.40
1100
165.820
484.04
318.22
237.04
1200
1300
1400
1500
1600
1700
1800
171.800
176.963
181.507
185.567
189.249
192.624
195.750
504.71
523.83
541.66
558.39
574.16
589.11
603.34
332.91
346.87
360.,15
372.82
384.91
396.119
407.59
238. 18
239.69
241.46
243.42
245.53
247.74
250. OS
-201.523
-237.458
12.404
-205.311 -240.836
11.436
--------------------------------207.993
-243.946 10.619
-211.017 -246.813
9.917
-214.339 -249.1145
9.307
-217.953 -251.846
8. 770
-221.815 -253.952
8.291
-225.919 -255.847
7.861
-257.495
7.1172
-230.251
IIELTIIIG POIIIT
BOILIIG POUT
EIITHALPY OF BELTIIG
kJ
EIITHlLPY OP VlPOBIZlTIOI
kJ
IIOLAR VOLUIE
8.8390 J/bar
88.390 ca 3
TIAISITIOJS II IEFBIEICE STATE OIIDBS

K2 0 DBCOBPOSIS ABOVE 1154 K.
Si0 2 ALPHA - BETA TBAIISITIOI 844 K.
HEAT CAPACITY EQUATIOIS
0.13425 T
( EQUATIOI VALID FRO!
1.4842x10Z +
c:
1.9647x10Z +
REFBIUCE
2.1645x10
298 955 I)
,-z
2.7666x1o-z T + 1.2261x10? T-z

955 - 1800 K)
(BQUATIOI VALID FIOII

201
93
120
93
15
COB PILED
7-15-76
PROPERTIES AT HIGH TEIIPERATURBS

DEHYDRATED AIALCITE
409
l'ORIIULl WEIGHT
202.140
1'0 Rill T IO I
TEIIP.
( u;-H~98 )/T
JjaolK
so
T
-(G;-u; 98 )/T
CD
J/aollt
J/aolK
J/aolK
1. 70
1.70
IITHALPY
kJ/aol
FRO II THE.ILBIIEHTS
GIBBS
l'BEE EIIBGY
Log '
kJ/aol
-------------------------------------------------------------------------------298.15
0.000
175.40
164.40
175.110
UIICERT AI IT Y
--------------------------------
400
500
600
700
800
900
45.475
76.940
101.078
120.269
136.032
149.344
225.27
270.112
310.81
347.08
379.96
410.09
179.79
193.48
209. 1J
226.81
243.93
260.75
190.13
213.52
229.19
2111. 22
251.30
260.26
1000
160.8511
437.94
217.09
268.51
IIELTIIG POIIT
80ILIIG POUT
EITHALPY Ol' IIBLTIIG
kJ
BITHALPJ OF VAPORIZATIOI
kJ
IIOL.lR VOLOD
J/bar
--------------------------------
TRAISITIOIS II REPEREICE STlTE ILEIIEITS

SODIUII II. P. 370.98, B. P. 1175 K.
lLUIIIIUII II. P. 933 I.
BEAT CAPACITY BQUlTIOI
c:
2.1110z1oz + 6.4921z1o-z T
7.5102z10 r-z
( BQOATIOI YlLID l'BOII 298 - 1000 I)
RBFBREICE
201
136
COIIPILBD
7-15-76
410
TBEBIIODYNAIUC PROPERTIES OF IIINEBALS
LOlf ALBITE
FORIIULA WEIGHT
lllallSi :~Oa:
262.225
crystals 298. 15 to 1400 l .
-------------------------------------------------------------------------------FOBI'IlTIOIII FBOII THE ELEIIEHTS

TEI'IP.
0~-H;9 8 )/T
J/olK
so
T
-(G;-H~ 98 )/T
J;olK
J/olK
0.110
0.40
co
p
EIIITHALPY
J/ol K
GIBBS
PBEE ENERGY
Log Kf
kJ/1101
kJ/o1
-------------------------------------------------------------------------------298. 15
o.ooo
-3935. 120
-3711.722
207.40
205.10
650.281
207."0
UNCEBTli NTY
3. 415
3.435
--------------------------------3939. 122
474.675
-3634. 926
400
500
600
700
800
900
56.950
95.922
125.125
147.969
166.396
181.611
272.87
328.97
378.36
422.27
461.70
497.42
215.92
233.05
253.23
274. 30
295.30
315.81
239. 71
262.61
278.80
290.69
299.69
306.71
1000
194.412
530.04
335.63
312.34
1100
205.350
560.03
354.68
316.99
1200
1300
11100
2111.822
223. 122
210.479
587.79
613.62
637.78
372.97
390.50
407.30
320.95
324.45
327.64
!!ELTING POINT
BOlLI IIIG POINT
EHTHALPJ OF !!ELTING
kJ
8~98
H~
-3938.777
-3937.253
-3935.004
-3932.324
-3929.418
-3558.907
-3483.046
-3407.512
-3332.333
-3257.489
371.798
303.227
254.273
217.580
189.061
-3933.728
-3106.9.23
147.536
-4023. 167
-4018.563
-2946.882
-2864.289
118.408
106.868
--------------------------------3937.083
-3182.243
166.2211
--------------------------------4027.646
-3029.831
131.886
10.0070 J/bar
100.070 ca 3
IIOLAB VOLUIIE
33.452 kJ
0.602
TBANSITIOIIIS IN BEFEBEHCE STATE ELEIIEITS

SODIUI'I 1'1. P. 370.98, B. P. 1175 K.
ALU.!IINUII li. P. 933 l .
SILICON II. P.
1685 K.
5.8394x10Z -
0.092852 T
1. 6 7 80 X 1 O T- 2
( EQUATIOH VALID FBOII
REFERENCE
115
90
187
123
298 - 1500 K)
93
COIIPILED
10- 5-76
411
LOI ALBITE
FOBftUI.l lEIGHT
2b2.225
crystals 298. 15 to 11100 It.
-------------------------------------------------------------------------------FOBIIlTIOI !'BOft THE OIIDES

TEftP.
K
( H;-a~ 98 )/T
J;aollt
ST
-(G;-8; 98 )/T
J/aolK
J/aollt
0.40
(1.40
cop
GIBBS
ENTHALPY
J/aolK
FBEE EIIIEBGY
Log Kf
kJ/aol
kJ/aol
-------------------------------------------------------------------------------298.15
207.40
o.ooo
207.40
205.10
-157.760
-163. b99
28.680
UICERTliiTY
2. 105
40(1
500
600
700
800
56.950
95.922
125.125
147.969
166.396
272.87
328.97
378.36
422.27
461.70
215.92
233. OS
253.23
274.30
295.30
239.71
262.61
278.80
290.69
299.69
900
1000
181.611
194.412
497.42
530.04
315.81
335.63
306.71
312.34
1100
205.350
560.03
354.68
316.99
1200
1300
1400
214.822
223.122
230.1179
587.79
6 13.62
637.78
372.97
390.50
407.30
320.95
324.45
327. 64
ftELTIIG POIIT
-158.300
-159.117
-160.244
-161.840
-164.054
2.125
-165.656
-167.407.
-168. 95b
-170.293
-171.362
kJ
21.633
17.489
14.709
12.707
11.189
--------------------------------166.735 -172.091
9.988
-172.671
9.019
-167.241
--------------------------------
BOILIIIG PODIT
EBTH!LPY OP !ELTING
EITHlLPY OF YlPOBIZlTION
ftOLl B YOLUftE
33.452 kJ
10.007u J;bar
100.070 ca 3
TBliSITIOIS II BEPEBEICI STATE OXIDES

Ha 2 0
ft. P. 1193 K.
Si0 2
lLPHl - BETl TBliSITIOI 844 11:.
BElT CAPACITY BQUATIOI

5.8394z10Z -
0.092852 T
1.6780x10 T-z
(EQUATIOI VALID 110ft
REPDhCE
115
90
187
123
298- 1500 K)
93
COJIPILED
10- 5-76
412
THERIIODYNAIIIC PROPERTIES OF !INERALS
ANALBITE
FORIIUL.l lEIGHT
262.225
Crystals 298.15 to 1400 1.
-------------------------------------------------------------------------------FOR!ATION FRO! THE ELEIIEHTS

TEIIP.
so
( H;-a; 98 )/T
J/11olK
cop
-cc;-a; 98 )/T
J/molK
J/IIOlK
0.40
0.40
ENTHALPY
GIBBS
FREE ENERGY
kJ/1101
J/IIOlK
Loq Kf
kJ/1101
-------------------------------------------------------------------------------298.15
0.000
226.40
-3924.240
-3706.507
649.367
226.40
204.80
UNCERT AIH TY
3.640
400
500
600
700
800
900
56.875
95.932
125.278
148.247
166.754
181.989
291.78
347.96
3 97 .so
441.58
481.13
516.92
234.90
252.03
272. 22
293.33
314.38
334.93
239.70
263.27
279.81
291.70
300.47
307.10
1000
194.773
549.55
354.78
312.27
1100
205.651
579.52
373.87
316.47
215.037
223.236
607.21
632.95
392.17
409. 71
320.03
323.21
1200
1300
3.660
0.641
--------------------------------3928.272
-3631.640
474.246
-3927.892
-3926.281
-3923.929
-3921.158
-3918. 198
-3557.517
-3483.558
-3409.954
-3336.711
-3263.819
371.653
303.272
254.455
217.866
189.428
-3922.517
-3117.151
148.022
-4012.139
-2960.983
118.9711
--------------------------------3925.842
-3190.512
166.656
--------------------------------4016.508
-3041.997
132.615
-------------------------------------------------------------------------------1400
230.486
657.01
-4007.673
-2880.321
107.467
426. 52
326.20
1391
/!ELTING POINT
BOlLING POINT
59. 280 kJ
kJ
Jl. 423 kJ
!OLAB YOLUIIE
10.0430 J/llar
1(10. 430 c3
TRANSITIONS I I BEFEBEICE STATE BLEIIEITS

SODIUft II. P. 370.98, B. P.
ALUIIINUII II.
1175 It.
P. 933 K.
SILICOM II. P.
1685 It.
6.7137x1oz-
0.14671 T
3.17110x10 T- z
(EQUATION flLID FBOII
REFERENCE
90
76
187
3.6586x1o-s TZ
298 - 11100 It)
93
100
COIIPXLID
10- S-76
PROPERTIES AT HIGH TEIIPERATURES

AIIALBITE
413
PORIIULA iBIGHT
262.225
TEftP.
K
-(G;-H;ga )/T
cop
JjaolK
JjaolK
Jjaol K
o. 40
0.40
<H;-a~98 )IT
J;aolK
ST
FORIIATION PRO!! THE O.IIDES

GIBBS
FREE ENERGY
Log Kf
ENTHALPY
kJ/aol
kJ;aol
--------------------------------------------------------------------------------158.484
298. 15
0.000
226.40
226.40
204.80
-146.880
27.76&
UIC!RTAIJTY
2.450
400
500
600
700
800
56.875
95.932
125.278
148.247
166.754
291.78
347.96
3 97. so
441.58
481. 13
234.90
252.03
272.22
293.33
314.38
239.70
263.27
279.81
291.70
300.47
900
1000
181.989
194.173
516.92
549.55
334.93
354.78
307.10
312.27
1100
205.651
579.52
373.87
316.47
1200
1300
215.037
223.236
607.21
632.95
392.17
409.71
320.03
321.21
-147.450
-148. 232
-149 .272
-150.765
-152.888
*
*
*
2.470
-162.370
-166.017
-169. 468
-172.735
-175.740
21.203
* 17.344
14.754
12.890
* 11.475
--------------------------------178.421
10.355
-155.515
-156.000
-180.940
9.451
--------------------------------
-------------------------------------------------------------------------------1400
230.486
657.01
426.52
326.20
1391
ftELTING POINT
EWTHALPY OF !ELTING
BOlLING POUT
59. 280 ltJ
kJ
33.423 kJ
IIOLAR VOLOIIB
10.0430 J/bar
100.430 ca 3
TUJSITIOIS I I !BFBRBNCB STAT! OIIDES

Na 2 o ft. P. 1193 K.
SiOz ALPHA - BETA TBAJSITION 844 K.
3.171101110 '2
(BQOATIOI VALID PBOII
BEF!IENCB
90
76
187
298 - 1400 K)
93
100
COIIPILID
10- 5-76
tHBB.IIOD!IIAII.IC PBOPBBTIES OP ll.IIIBALS
POBIIUL1 WEIGHT
262.225
Glass 298.15 to 1200 K.
-------------------------------------------------------------------------------POBIIATIOI PRO II THE BLEI!IIITS

TEIIP.
so
H;-H~ 98 )/T
JjaolK
cop
-( G;-H; 98 )/T
J/aolK
JjaolK
EITHALPY
J/aol K
GIBBS
PBBB BURGY
Log Kf
kJjaol
kJ/aol
-------------------------------------------------------------------------~------
298.15
o.ooo
UICBRTAIIT!
251.90
1. 50
251.90
1.50
209.90
400
500
600
100
800
900
58.325
98.416
128.448
151.887
170.782
186.456
318.96
376.60
427.35
472.42
512.87
549.60
260.63
278. 18
298.90
320.53
342.09
363. 14
246.01
269.92
286.29
298.18
307.62
315.98
1000
199.821
583.31
383.49
324. 20
1100
211.520
614.62
403. 10
332.94
1200
222.036
643.99
liE LTI IIG POI IT
1391
EJTHALP! OP IIELT IJG
-3875.460
3.7(10
-3665.330
3.720
--------------------------------3593.152
469.220
-3878.912
-3877.870
-3875.599
-3872.601
-3869.155
-3865.398
-3521.815
-3450.786
-3380.214
-3310.100
-3240.431
367.923
300.419
252.236
216.128
188.071
--------------------------------3170.444
165.608
-3872.014
-3867.281
-3100.525
147.232
-------------------------------131.847
-3028.954
-3959.329
421.95
342. 67
BOILIIIG PODT
K
ltJ
BITHALPY OP YAPOBIZATIOI
kJ
642.153
0.652
11.0086 J/t)ar
110.086 cal
IIOLAB YOLU!IB
TRAISITIOJS I I REPBRBJCE STATE ELEIIEJTS
SODIU! II. P. 370.98, B. P. 1175 K.
ALUIII 110.11 11. P. 933 K.
HEAT CAPACITY EQUATIOJ
c;
9.1795x1oz-
0.38242 T
5.2796x1o T- z
( BQUATIOII YlLID PIC II
BBPBBBJCB
152
227
1.4740x1o- rz
1.1511.1:10
r-os
2 98 - 1200 It)
93
269
CO!IPIJ.BD
10-19-76
1115
PROPERTIES IT HIGH TE!PERlTURES

FOB!ULl WEIGHT
262.225
Glass 298.15 to 1200 1.
-------------------------------------------------------------------------------FOBftlTIOll FlO! THE O.IIDES

cu;-&~ 98 )/T
TEI!P.
J/aoll
so
r
J/aolK
-{G;-u~ 98 )/T
J;.olK
cop
BliTHlLPY
J/aolK
GIBBS
FBBE EIIIBBGY
Log 't
kJ/aol
ltJ/aol
-------------------------------------------------------------------------------298.15
209.90
o.ooo
251.90
251.90
-98.100 -117.307 20.552
UICBBTliliTI
2. 530
1.50
1. 50
2.510
1100
500
600
800
58.325
98.1116
12.8.448
151.887
110.782
318.96
376.60
427.35
472.42
512.87
260.63
218. 18
298.90
320.53
342.09
246.01
269.92
286.29
298.18
307.62
900
1000
186.456
199.821
549.60
583.31
363. 14
383.49
315.98
324.20
1100
211.520
614.62
403.10
332.94
1200
222.036
643.99
421.95
342. 67
100
I!ELTIIG POUT
1391
-123.882
-130.315
-136.696
-142.995
-149.129.
-102.112
-160.872
8.403
--------------------------------
80 IL Ill G PO IIIT
ltJ
34.257 ltJ
16.117
13.6111
11.901
10.670
9.737
--------------------------------155.033
8.998
-102.715
ENTHALPY OF I!ELTIIIG
8~98 - H~
-98.090
-98.210
-98.590
-99.437
-100.885
kJ
11 0086 J/tla r
110.086 cal
BOLAR VOLOI!E
TBliSITIOliS Ill BEFEBBHCE STATE OliDES

la 2o !. P. 1193 l.
Si0 2 ALPHA - BBrA TBARSITIOI 844 l.
BEAT CAPACITY EQUATIOll
9.1795x102+
BEPB&EliCE
0.38242 T
5.2796Jt10 T-2
{BQUlTIOI VlLID FlO!
152
227
1.4740x1o- T2
298 - 1200 K)
93
269
COB PILED
10-19-76
416
THERI!ODYNUHC PROPERTIES OF IIINERALS
NEPHELINE
FOB!ULA WEIGHT
142.055
Carnegieite is the stable phase above
cz- ~ transition at 467 K.
1521 K.
-------------------------------------------------------------------------------FORIIATION FBOI! THE ELEI!E NTS

TEIIP.
so
( H;- H~ 98 )/T
J/llolK
-(G;-H~ga
J/IIOlK
Jjaol K
1.25
1.25
cop
)/T
EITHlLPY
GIBBS
FREE EIIEBGY
kJ/aol
J/aol K
Log Kf
kJ/1101
-------------------------------------------------------------------------------296.15
o.ooo
124.35
-2092. 110
-1977.498
346.449
124.35
115.81
UNCERTAINTY
2.420
2.450
0.429
-------------------------------400
32. 372
161.59
-2095.567
-1937.982
253.076
129.22
145.90
------------------------------------------------------------------------------500
52.552
196.36
-1901.019
196.599
143.81
145.64
-2096.396
600
700
800
900
72.662
84.577
94.140
102. 136
223. 80
247.62
269.33
288.91
151 .14
163.24
175. 19
186.77
152.36
159.07
165.78
172.49
-2093.545
-2092.730
-2091.737
-2090.576
- 1859.733
-1820.601
-1762.022
-1743.390
161.905
135.870
116.355
101.184
1000
108.993
306.86
197.86
179.20
1100
115.516
324.09
208.58
165.91
-2097.645
-1664.62 3
79.047
122.207
126.582
130.361
133.665
341. 12
355.47
368.78
381.20
218.92
228.89
238.92
247.54
178.&2
179.18
179. 7J
180.28
-2191.381
-2188.&31
-2185.935
-2183.278
-1623.349
-1576.151
-1529.162
-1482.351
70.663
63.331
57.054
51.620
--------------------------------1704.090
!l9.013
-2099.954
-------------------------------1180
120.471
-1632.754
72.276
337.48
-2192.761
217.01
191.28
-------------------------------------------------------------------------------1180
-1632.754
72.276
121.244
-2191.807
338.25
217.01
178.51
1200
1300
1"00
1500
!\ELTING POIIIT
BOILING POINT
kJ
kJ
kJ
IWLAR VOLU!E
5.4160 Jjbar
54.160 Cll 3
TBANSITIOIS IN REFEBEIICE STATE ELEIIENTS

SODIUI! 1!. P. 370.98, B. P.
1175 K.
ALUIIINUI! II. P. 933 K.

SILICON 1!.
P.
1685 K.
HEAT CAPACITY BQUATIOIIS

0
Cp
cop
cop
27.74
0.2954 T
( !)JUATIOII VALID FRO I! 298 - 467 K)
112.09
0.06711 T
( EQUATIOII VALID FRO I! 467-1180 K)
172.00
0.00552 T
( EQUlTIOI VALID FRO I! 1180 -
REFERENCE
115
120
1525 K)
93
229
COIIPILED
4-15-76
PROPERTIBS AT HIGH TE!PERATORES
NEPHELINE
POR!OLA WEIGHT
142.055
carnegieite is the stable phase aboYe
1521 K.
TE!P.
K
a;-H~98
JjaolK
so
T
)1'1'
-(G;-H~ 98 )/T
JjaolK
Jjaoll
1.25
1.25
co
FOR!lriOII FROB THE Oil DES

GIBBS
Log If
ENTHALPY
FREE EIIERGI
JjaolK
kJ/aol
kJ/aol
--------------------------------------------------------------------------------142.052
24.887
298.15
o.ooo
124.35
124. 35
115.81
-136.150
UNCERTAINTY
400
-136.461 -144.032 18.809
161.59
129. 22
145.90
32.372
-------------------------------------------------------------------------------15.494
500
52.552
143.81
145.64
-137.816
-148.309
196.36
600
700
800
72.662
84.577
94.140
223.80
247.82
269.33
151. 14
163.24
175.19
152.36
159.07
165.78
900
1000
102.136
108.993
288.91
306.86
186.77
197.86
172.49
179.20
1100
1180
115.516
120.471
324.09
337.48
208.58
217.01
185.91
191.28
1300
1400
1500
126.582
130.361
133.665
355.47
368.78
381.20
228.89
238.42
247. 54
179.18
179.73
180.28
12.892
-148.080
-149.934 11.188
-151.&26
9.900
--------------------------------140.413 -153. 13&

8.888
8.069
-141.116 -154.482
-136.330
-137.470
-138.889
-------------------------------------------------------------------------------1180
121.244
338.25
217.01
178.51
-------------------------------1200
122.207
341.12
218.92
118.62
!ELTING POI NT
ENTHlLPY OF !ELTING
BOILiliG POIIIT
kJ
ERTHALPY OF VAPORIZATION
kJ
BOLAR VOLOBE
kJ
5.4160 J/!;lar
54.160 ca 3
TRANSITIONS Ill REFERENCE STATE OXIDES
Ba 2 o !. P. 1193 I.
Si0 2
REFERENCE
ALPHA- BETA TRANSITIOJ 844 K.
115
120
93
229
COB PILED
4-15-76
THIRBODIIl!IC PBOPIITIIS OP BIIEilLS

BOSCOVITE
POB!OLl lEIGHT
398.311
-------------------------------------------------------------------------------PORI!IlTIOI PIO! THE ILE!EITS

TEI'IP.
(a;-a; 98
J/aoll
I{
so
)/'f
J/aollt
cop
-(G;-H; 98 )/T
J/aolK
GIBBS
PIEB BIBBGI
BITR.lLPI
kJ/aol
J/olK
Log 't
kJ/ol
-------------------------------------------------------------------------------298.15
o.ooo
306.40
306.40
326. 10
-5976.740
-5600.671
981.219
OICBITliNTI
0.61
0.61
3.235
0.576
3.290
-------------------------------714.486
-5981.048
-5471.333
400
500
600
700
800
900
91.100
154.242
202.007
239.653
270.176
295.444
411.12
501.73
582.02
653.74
718.32
776.92
320.02
347.49
380.01
414.09
448.14
481.48
385.54
425.67
454.42
475.56
491.35
503.24
1000
316.693
830.42
513. 73
512.16
I!ELTIIIG POIMT
BOILIIG PODT
ENTHALPY OP !ELTIIG
kJ
EITHlLPY OP VAPORIZATION
kJ
49.443 kJ
-5979.503
-5975.746
-5970.644
-5964.809
-5958.697
-5344.043
-5217.261
-5091.248
-4965.994
-4841.485
558.291
454.205
379.915
324.248
280.994
--------------------------------5984.613
-4715.393
246.308
14.0710 J;bar
140.710 c 3
!Ol.AR VOLD!E
TRAISITIOIS II REFERENCE STATE ELEI!EITS

POTASSI 011.. II. P. 336.4, B. P. 1030 K.
ALUIUNDII 11. P. 933 lt.
c;
9.1767x102-
8.1110x1o-z T
1.0348xlO
298 - 1000 K)
r-os
2.8J41x10 r-z
( EQUAT 10111 VALID PBOII

REFERENCE
152
199
226
277
93
12
COli PILED
1Q-22-76
PIOPBR!XBS
~~
BXGB
419
~B!PBIA~UIBS
FOB!OLl
!USCOUTB
Crysta~s
398.311
IBXGH~
298.15 to 1500 K.
-------------------------------------------------------------------------------.FOB!lHOI Fa Oil THE OIIDES

SD
-(G;-a~ 98 )/T
CD
J/aolK
J/aolK
J/aolK
(H;-8~98)/'l
~BKP.
J/aoll
I(
'l
GIBBS
Log I t
FREE EIEBGI
EITBALPY
kJ/aol
kJ/aol
--------------------------------------------------------------------------------263.674
298.15
o.ooo
306.ft0
306.40
326.10
-260.280 * 45.600
UJCEI!ll ITI
0.61
0.61
2. 525
400
500
600
700
800
91.100
154.242
202.007
239.653
270.176
411.12
501.73
582.02
653.74
718.32
320.02
347.49
380.01
414.09
448.14
385.54
425.67
454.42
475.56
491.35
900
1000
295.444
316.693
176.92
830.42
481.48
513.73
503.24
512.16
liE LTI IG
POX IT
BITBlLPI OP IIELTIIG
a;98 - 8
kJ
119. 443 kJ
2. 550
-------------------------------33.374
-255.569
-307.778
* -242.550 * 25.339
*
19.991
* -229.625
-216.849 16.182
* -204.121
*
* 13.329
--------------------------------305.863
-191.398
*
* 11.109
-303.825 -118.780
9.339
-307. 397
-306.704
-306.050
-305.769
BOILIIIG POIIIT
BIITHlLPI OF VlPOBIZlTIOJ
kJ
14.0710 J/l)ar
140.710 cal
!OL lB VOL Ull E
TiliSITIOJS II BBFBBBJCB STATE OXIDES

KzO DBCO!POSBS ABOVE 1154 K.
Si02
. . . .
1LPH1 - BBU TRAIISITIOI 844 K.
H2 0 B. P. 373.15 K.
BElT CAPACITY EQUlTIOH

2. 8341x 1 o T-z
9.1767x1oz- 8.1110x1o-z T
1.0348x10 T-us
(EQOlTIOJ VALID PBO! 298- 1000 K)
REFEREICE
152
199
226
271
93
12
COil PILED
10-22-76
420
THER!ODIBl!IC PROPIRTIBS OF !IIIRALS
FLUORPHLOGOPITE
FOR.I'IDLl IIEIGHT
Crystals 298.15 to .alting point 1670 1.
421.2114
Liqid 1670 to
1800 K.
-------------------------------------------------------------------------------FOBft.lTIOII FRO II THE ELB.I'IBHTS

TE!P.
a;-a;98 )/T
so
<
J/aolK
-(~-8~ 98 )/T
J/aolK
JfaolK
2.10
2. 10
CD
EIITH.lLPI
J/aoll
GIBBS
FREE EBBBGI
kJ/aol
Log
It
kJ/aol
-------------------------------------------------------------------------------298.15
-6053.067 1060.477
0.000
336.30
342.40
-6392.880
336.30
UBCERT AIIITI
3.800
3.660
400
500
600
700
800
900
94.325
157.048
202.693
237.664
265.530
288.433
444.81
535.12
614.23
683.18
744.67
800.21
350.48
378.67
411. 54
445.52
479.14
511.78
392.83
420.87
439.96
454. 48
466.38
476.62
1000
307.712
850.90
543. 19
485.76
1100
1200
1300
324.2 84
338.765
351.602
897. 60
940.93
981.40
573.32
602. 16
629.80
494.13
501.92
509.29
14CJO
1500
1600
363. 114
373.557
383.109
1019.40
1055.26
1089.22
656.29
681.70
706.11
516.32
523.09
529.64
0.666
--------------------------------6395.894
-5936.351
775.211
-6394.402
-6391.926
-6388.999
-6385. 882
-6382.729
-5821.622
-5707.271
-5593.399
-5479.948
-5366.855
608.183
496.864
417.386
357.805
311.486
--------------------------------5251.119
-6417.149
274.292
--------------------------------5130.390
-6492.677
243.623
-6487.537
-6481.933
-5006.741
-4883.581
217.939
196.226
-6846.697
-6836. 183
-4599.943
-4450.468
160.185
145.2 93
--------------------------------4750.073
117.228
-6856.764
IIELTING POINT
1670
BOILING POIIIT
ENTHALPY OF KELTING
308.779 kJ
kJ
kJ
14.6370 J/bar
146.370 ca 3
!lOLA R VOLUIIE
TRANSITIONS IN REFERENCE S'l'ATE ELE.IIENTS

POTASSI Ul! 1!.
P.
336.4, B. P. 1030 K.
I!AGNESIUI'I 1!. P. 922, B. P. 1361 K.

SILICON
1!.
P.
1685 K.
ALU!U Null !!. P. 933 K.

HEAT CAP ACITY EQUATION
4.9287x102 + 4.9103x1o-z T
1.5688x103 T-os
(EQUATIOI VALID FROII 298- 1670 K)
REFERENCE
118
118
257
93
118
CO! PILED
8-26-76
421
PORBOLI WEIGHT
TALC
379.268
crystals 298.15 to 1100 1.
-------------------------------------------------------------------------------PORBATIOI FROI THE ELEIEITS

TEftP.
( a;-H~ 98 )/T
J/aoll
so
cop
-(G;-H; 98 )/T
J/aoll
J/aolK
EITHlLPY
J/aolK
GIBBS
FREE EIERGY
Log If
ltJ/aol
kJ/aol
-------------------------------------------------------------------------------969.897
321. 70
-5915.900
-5536.048
298.15
o.ooo
260.83
260.83
OICEITIIITY
400
500
600
700
800
90.925
153.808
200.257
237.119
270.051
0.63
0.63
365.30
455.61
534.40
604.91
669.80
274.38
301.80
334.14
367.79
399.75
386.59
420.63
444.26
475. 20
525.95
4.330
4.350
0.762
-5917.050
-5914.990
-5911.596
-5906.844
-5898.951
-5405.971
-5278.425
-5151.383
-5024.997
-4898.009
705.950
551.436
448.470
374.972
31 9.809
IIEL'I'IIG POI 11'1'
BOIL! HG POIIIT
EITBlLPY OP ftELTIIG
46.886 kJ
ltJ
13.6250 JJilar
136.250 cal
IIOLAII VOLOIIE
TlliSITIOHS IN BEFDEHC! STATE ELEIIEJTS

IIAGIESIOII B. P. 922, B. P. 1361 K.
SILICOJ B. P. 1685 K.
BElT CAPACITY EQOITIOI
5.6536x10:J+
BEFIBEICE
5.2717 T
4.0211x107 '1'-z
( EQOITIOI VALID PBOB
151
28
228
2.7291x10-ll TZ
2 98 -
800 I)
93
11
COIIP:ILED
8-26-76
'rBIIIODtlliiiC P80PH1'11S OP IDIIlLS
1122
!lLC
roaau&
IBIGB~
379.268
crystals 298.15 to 1100 1.
TBIIP.
(a;-a; 98 )/'r
J/11011
so
'
-ca;-&2 98 )/T
J/aoll
ol/aoll
cop
POIIlUOI PBOI 'rHB OXIDES

GIBBS
Loq It
IITB.li.P!
Pill IIIIGf
lr.J/aol
J/aoll
lr.J/aol
------------------------------------------------------------------------------298.15
o.ooo
260.83
-)66. 167
260.83
321.711
-182.800
29.112
OICIITlll'rl
0.63
0.63
365.30
455.61
534.4(1
604.91
669.80
2711.38
301.80
334.14
367.79
399.75
386.59
420.63
11114.26
475.20
525.95
!IEL'l'IWG POIIT
BOILIIIG PODT
EITBlLPI OF !IBLTIIG
kJ
BITBlLPI OJ' YlPOBIZlTIOI
400
500
600
700
800
90.925
153.808
200.257
237.119
270.051
46.886 kJ
1. 420
-226.319
-225. 1011
-2211. 147
-223. 1,_
-220.(177
1.1150
-157.007
-139.799.
-122.829
-105.961
-87.917
20.503
111.605
10.693
7.9(17
5.740
It
13.6250 ol/bar
136.250 cal
llOLl I YOLO II
TBliSlTIOIS 11 BBPERBICI STlTB OllDIS

Si02
lLPBl - BB'l'l TBlJSl'l'IOI 844 1.
H2 0 B. P. 373.15 lt.
BElT ClPlCITY BQOATIOI

5.6536x1o+
5.2717 T
( BQOUIOI YlLID PBO.II
BEFBBIICB
2.7291x1o- TZ
4.Q211x10' T-z
151
28
228
298 -
800 K)
9l
11
COIPILBD
8-26-76
423
PBOPBiTIBS AT HIGH TBIPI.RUUBBS
PYBOPHILLITE
POI!OLl lEIGHT
ll 2 si.o 10{ OH }2 :
360.311
Crystals 298. 15 to 800 1.
-------------------------------------------------------------------------~----TBIIP.
so
(B;-H~g 8 )~
Jjao1K
I[
-( G;-a~ 98 )/T
J/aolK
JjaolK
cop
IOBillTIOJ PBOII 'fBE Bl.EIIB11'S

GIBBS
Pa B.l BR:BBGI
EITBALPI
Log Kf
JjaolK
lt.Jjaol
kJ/aol
-------------------------------------------------------------------------------298. 15
-5639.800
-5265.884
922.565
o.ooo
239.40
293.70
239."0
3. 950
3. 960
o. 694
-5641.641
-5640.439
-5637.406
-5633. 192
-5628.207
-5137.750
-5011.889
-4886.421
-4761.587
-4637.392
670.924
523.590
425.402
355.316
302.791
o. 40
0.40
334.16
416.33
489.17
251.71
276.58
306.07
336.96
367.86
31&9. 62
386.06
412."1
"32.59
448.71
I'IBLTING POIBT
BOILIIG POIIT
ENTHALPY OF I'IELTIBG
kJ
BITHALPJ OP VAPOBIZlTIOI
UICEBTAIIITY
400
500
600
82.450
139.148
183.103
217.363
245.309
100
800
551&.32
613.17
42.695 kJ
TRAISIT~ONS
!lOLAR VOLU!lE
12.7820 Jjbar
127.820 ca 3
II BEFBBEICE STATE ELEMEBTS
&LOlli HUM
II. P. 933 K.
SILICOI !1. P.
1685 I.
HEAT CAPACITY EQUA'UOI
7.4675x1oz- 5.3543x1o-z T +
( EQUATIOI VALID FRO! 298 -
BEPEBEICE
152
226
139
1.9855x1o-s
800 K)
rz
286
152
CO! PILED
03-15-79
4211
TBBB!QDYIAftiC PBOP!BTIES OF ftli&BALS
PIBOPBILLITB
FOBBOLl iEIGBT
llii!SiOaa(OB)z:
1'!11P.
Crrstals 298.15 to 800 K.
(a;-a; 98 )/T
360.317
JtaolK
so'l
-(s;-a; 98 )/T
JtaolK
Jtaol K
cop
FOR!lTIOtt FROB THE OIIDIS

GIBBS
Pill BURGI
Log
BITHlLPY
Jtaoll
't
k.J/aol
kJ/aol
-------------------------------------------------------------------------------3. 743
298.15
o.ooo
239.40
239.40
293.70
-35.470 *
-21. 363 *
o. 40
0.40
3311.16
416.33
489.17
5511.32
613.17
251.71
276.58
306.07
336.96
367.86
349.62
386.06
1112.41
432.59
448.71
BOILIIG PODT
OIICIB'lli I'll
400
500
600
700
800
82.450
139.748
183.103
217.363
2115.309
IIBL'IIIG POIJT
BITBALPY OF BBLTIJG
8 ~98 -
~~
kJ
42.695 k.J
1. 325
1. 350
-------------------------------1. 706
-13.065 *
-79. 109 *
-78.475
-77. 796
-77.346
-77.354
*
*
*
*
3. 380
19.697
35.894
52.071
*
*
*
*
-o. 366
-1. 715
-2.678
-3.400
BlfHlLPI OP YlPOBlZArlOI
12.5900 Jtbar
125.900 ca 3
IIOLlB YOLUBB
TlliSITIOIS II BIPBBBICI S'll'll OIIDES

Si02
lLPBl- BEU 'l'Jll!BZTIOI 844 K.
BzO B. P. 373.15 I.
Bll'f CAPACITY BQUlTIOI
7.4675x10 5.354lx1o-z T +
( BQUlTIOI ULID PROil 298 -
BBPIBBICB
152
226
139
1. 9855x 1 o-s T2
800 l}
7.5777x1o
286
152
,-os
CO!PILBD
03-15-79
PROPBITIIS lT HIGH
425
TBBPIB~OBIS
CHBYSOTILE
POBBOLl lEIGHT
277.113
-------------------------------------------------------------------------------PORBATIOB PBOB THE BLEB BITS

TEBP.
K
c a;-a;98 }/T
J/aolK
so
-(G;-H; 98 )/T
cop
GIBBS
PBEI EBEllGI
BIIITHlLPI
J;aolK
kJ/aol
Log Kf
kJ/aol
J/aolK
J/aolK
0.80
0.80
309. 13
385.05
452. 1IJ
511.78
565.13
613.14
232.70
255.76
283.01
311. 51
339.93
367.67
323.22
356.33
378.95
394.26
404.32
410.47
I!ELTIIIG POIBT
BOILIIG PODT
IJTHlLPJ OP BELTIBG
kJ
EBTHlLPJ OP VlPOBIZlTIOB
--------------------------------------------------------------------------------4361.660
-4034.024
706.747
298.15
0.000
273.70
221. 30
221--30
UNCEBTliBTI
400
500
600
100
800
900
76.425
129.292
169.133
200.273
225.195
245.467
3.480
3.500
0.613
-4362.729
-4360.883
-4357.294
-4352.759
-4Jif7. 832
-4342. 911
-3921.820
-3811.788
-3702.258
-3593.451f
-31f85.318
-3377.752
512.139
398.216
322.312
268.11f8
227.569
196.041
BOUB VOLOBB
10.8500 J~ar
108.500 cal
TBlJSITIOIS IN BEFEBEBCE STATE BLBBIITS

l!lGBISIDII. B. P. 922, B. P. 1361 K.
SILICOB. 1!. P. 1685 K.
HilT ClPlCITJ BQOlTIOB
c;
8.9960z10Z -
0.14476 T
( BQOlT:tOI VALID 1'108

BBFBBBICB
128
128
1.0932:~:1()4
298 -
,-o
4.4999z10
r-z
900 K)
93
128
COIPIJ.BD
9- 3-76
426
THEBIIODlllftiC PROPERTIES OF I!IIEBALS
POBIIULA WEIGHT
CHBlSOTILE
277.113
TEIIP.
(a;-a~ 98 )/T
J/8ollt
so
-(G;-a~ 98 )/T
co
p
J/80lK
J/8ol K
J/8olK
!'OBI!A TIOII PBOI! THE OXIDES

GIBBS
Log
EITHlLPl
FBEE EUBGY
kJ/801
Kf
kJ/801
-------------------------------------------------------------------------------24.454
298.15
-164. 130 -139.578
o.ooo
221. 30
221.30
273.70
2.710
OIICBBTllliTT
2.750
o. 80
0.80
400
500
600
700
800
900
76.425
129.292
169.133
200.273
225.195
245.467
309.13
385.05
452. 14
511.78
565.13
613.14
232.70
255.76
283.01
311.51
339. 93
367.67
liB L TI IIG P OIIIT
323.22
356.33
378.95
394.26
404.32
410.47
--------------------------------250.858 -124.294 16.231

9.707
-248.257
-92.917
5.1611
-244.891
-62. 154
2.387
-241.301
-31.985
0.152
-237.938
-2.327
-234.968.
-1.565
BOILI.IIG POIIT
EITHALPY OP ftELTIIG
26.957
ltJ
BIITHALPY OF VAPOBIZATIOII
ltJ
IIOLAB VOLDI!B
lrJ
10.8500 J/bar
108.500 c8 3
TRAISITIOIS II BEPBBBIICB STATE OXIDES

Si0 2
.......
ALPHA- BETl TR.lliSITIOII 844 K.
H2 0 B. P. 373.15 K.
BElT CAPACITY EQOATIOI
8.9960x10Z-
0.14476 T
( BQOlTIOII VALID PBOI!
BBPBBEIICE
128
128
1.0932x1~
298 -
T-os
900 K)
93
128
COI!PILBD
9- 3-76
428
THERftODYIA!IC
1.
PROPERTIES
OF
ftiHEBALS
Adaai, L. H., and Kelley, K. K., 1963, Heats

crystalline hydrates of ferrous sulfate:
Inv. 6260, 7 p.
of
foru tion of two

Bur. ftines Kept.
u. s.
2.
ldaai, L. H., and King, E. G., 1964, Heats and free energies
foraation of sulfides of aanganese, iron, zinc, and cadaiua:
s. Bur. Kines Kept. Inv. 6495, 10 p.
3.
Adaai, L. H., and King, ~. G., 1965, Heats ~f foraation of anhydrous

sulfates of cadaiua, cobalt, copper, nickel, and zinc: u. s . Bur.
Kines Rept. Inv. 6617, 10 p.
4.
Adaai, L. H., and Conway, K. c., 1966, Heats and free energies of
foraation of anhydrous carbonates of bariua, strontiua, and lead:
u. s. Bur. Kines Rept. Inv. 6822, 7 p.
s.
Andon, a. J. L., and !ills, K~

tetragonal geraaniua dioxide:
p. 583-588.
6.
Ba in, R.
147 p.
7.
Baker, F. B., Fitzgibbon, G. c., Pavone, D., Holley, c. E., Jr.,

Hansen, L. D., and Levis, E. A., 1972, Enthalpies of foraation of
Sa 2 0 3 (cubic): Jour. Chea. Theraodynaaics, v. 4, p. 621-636.
8.
Baker, F. B., Huber, E. J., Jr., Holley, c. E., Jr., and Krikorian,
N.
H.,
1971, Enthalpies of foraation of ceriua .iioxide, ceriua
sesquicarbide, and ceriua dicarbide: Jour. Chea. Theraodyaaaics,
v. 3, p. 77-84.
9.
Barany, R., 1962a, Heats and free energies of formation of soae

hydrated and anhydrous sodiua- and calciua-aluainua silicates: u.
s. Bur. Kines Rept. Inv. 5900, 17 p.
10.
Barany, R., 1962b, Beats and free energies of foraation of calciua

tungstate, calciua aolybdate, and aagnesiua aolybdate: u. s. Bur.
ftines Kept. Inv. 6143, 11 p.
11.
Barany, R., 1963, Heats of foraation of gehlenite and talc:

Bur. Kines Rept. Inv. 6251, 9 p.
12.
Barany, R., 1964, Heat and free energy of

U. s. Bur. Kines Bept. Inv. 6356, 6 p.
13.
Barany, R., 1965, Heats of foraation of goethite, ferrous vanadate,

and aanganese aolybdate: o. s. Bur. Mines Kept. Inv. 6618, 10 p.
14.
Barany, R., and Adaai, L. H., 1965, Heats of foraation of anhydrous

ferric sulfate and indiua sulfate: u. s. Bur. Kines Rept. Inv.
6687, 8 p.
15.
Barany, a., and ldaai, L. B., 1966, Heats of formation of lithiua

sulfate and five potassiua- and lithiua-aluainua silicates: u. s.
Bur. Kines Bept. Inv. 6873, 18 p.
16.
Barany, a., and Kelley, K. K., 1961, Heats and free energies of
foraation of gibbsite, kaolinite, halloysite, and dickite: 0. s.
Bur. Kines Bept. Inv. 5825, 13 p.
17.
Barton, P. B., Jr., and Bethke, P .!. 1 1960 1

Ther11odynaaic
properties of soae synthetic zinc and copper ainerals: Aa. Jour.
Sci., v. 258-A, (Bradley voluae), p. 21-34.
Barton, written
coaaun., Kay 5 9 1967 1 has also deterained the free energy of
f~raation of bisauthinite and his value has been adopted for these
tables.
v.,
1964, Steaa tables:
of
u.
c.,
1971, The heat capacity of

Jour. Chea. Theraodynaaics, v. 3,
London, H. !. Stationery Office,
formation
of
u.
s.
muscovite:
BEPEREICES
AID
429
IOTES
18.
Barton, P.B., Jr., and Skinner, B. J.,

1977,
Ore
lli.neral
stabilities, in Barnes, H. L., Geocheaistry of hydrotheraal ore
deposits: Hew York, John Wiley, in press
19.
Benz, a., and lagner, c., 1961, Theraodynaaics of the systea

CaO-Si02 fro electromotive force data: Jour. Phys. Cheaistry, v.
65, p. 1308-1311.
20.
Bonnickson, I. B., 1954, High-teaperature heat contents of calciua

and aaqnesiua ferrites: Aa. Chea. Soc. Jour. v. 76 1 p. 1480-1"82.
21.
Bonnickson, K. R., 1955a, High-teaperature

titanates of aluainua, iron, and zinc:
77, p. 2152-2154.
22.
Bonnickson, K. a., 1955b 1 Higb-teaperature heat

aluaina tes of calcium and aagnesiua: Jour. Phys.
59, p. 22Q-221.
23.
Boyle, B. J., King, E. G., and Conway, K. c., 1954 1 Heats of

foraation of nickel aad cobalt oxides (BiO and CoO) by coabustion
calori~~etry:
Aa. Chea. Soc. Jour., v. 76, p. 3835-3837.
24.
Brink, :r. J., and Holley, c. E., Jr., 1976, The enthalpy of
foraation of strontiua aonoxide: (abs.]: Caloriaetry Conference,
31st, Argonne, IL., sept. 1976, progra of aeeting, p. 49.
25.
Brodale, G., and Giauque, w. P., 1958, The heat of hydration of

sodiua sulfate.
Low temperature heat capacity and entropy of
sodiua sulfate decahydrate: Am. Chem. Soc. Jour., v. so, p.
2042-2044.
26.
Brooks, A. A., 1953, A theraodynaaic study of the equilibriua 2Cu(s)

+ H2 S(g) = Cu 2 S(J) + H2 (g):
.la. Chea. Soc. Jour., v. 75, p.
2464-2467.
27.
Burnhaa, c. 1., Holloway, J. B., and Davis, B.

F., 19&9,
Theraodynaaic properties of water to 1000 oc and 10,000 bars:
Geol. Soc. Aaerica, Spec. Paper 132, 96 p.
28.
Cassell, B., 1973, written coamun., August 1973.
29.
Chang, s. s., and Bestul, A. B., 1971, Heat capacities of cnbic,

monoclinic, and vitreous arsenious oxide froa 5 to 360 K: Jour.
Chea. Physics, v. 55, p. 933-946.
30.
Chang, s. s., and Bestul, A. B., 1974, Heat capacities of seleniua

crystal (trigonal), glass, and liquid froa 5 to 360 K: Jour. Chem.
Theraodyna lli.cs, v. 6, p. 325-344.
31.
Charla, T. v., Iewton, B. c., and Kleppa, o. J., 1975 1 Enthalpies of

foraation at 970 K of coapounds in the systea ~gO-ll 2 0~-Si0 2 froa
high teaperature solution caloriaetry:
Geochia. et Cosaochia.
Acta, v. 39, p. 1487-1497.
32.
Chase, !. v., Curnutt, J. L., Hu, A. T., Prophet, H., Syverud, l.

H., and Walker, L. c., 1974, JAlAP theraocheaical tables, 1974
suppleaent: Jour. Phys. Chea. Ref. Data, v. 3 1 p. 311-480.
33.
Chase, 11. W., Curnutt, J. L., Prophet, H., !cDonald, B. 1., and
SJYerud,
A.
N.,
1975 1
JlHAP theraocheaical tables, 1975
suppleaent: Jour. Phys. Chea. Ref. Data, v. 4, p. 1-176.
34.
Chishola, B. c., and Stout, J. w., 1962, Heat capacity and entropy
of CoCl 2 and l!nC1 2 fro no to 3000 K. 'l'beraal aaoaaly associated
with antiferroaagnetic ordering in CoC1 2 : Jour. Chea. Physics, v.
36, p. 972-979.
heat contents of soae

Aa. Chea. Soc. Jour., v.
contents
of
Cheaistry, v.
THERftODYHAftiC
1130
35.
PROPERTIES
OF
!liBERALS
CODATA Task Group, 1976, CODATA recommended key

values
thermodynamics, 1975:
Jour. Chea.
Thermodynamics, v.
for
a,
60 3-605.
36.
Cohen, E. R., and Taylor, B. N., 1973, The 1973 least-squares

adjustment of the fundamental constants: Jour. Pbys. Chem. Ref.
Data, v. 2, p. 663-7311.
37.
Commission on ~tomic weights, Int. Union Pure and

1976, Atomic weights of the eleaents 1975:
Chemistry v. 47, p. 75-95.
38.
Cook,
o. A.,
V2 0 5 :
39.
19117, High-temperature heat contents of V2 o 3 , V2 0 4

Am. Chem. Soc. Jour., v. 69, p. 331-333.
and
Coughlin, J. P., 1950, High-temperature heat contents of man~anous

sulfide, ferrous sulfide, and pyrite: la. Chem. Soc. Jour., v.
12, p.
40.
App 1. Chemistry,
Pure and Appl.
511115-511118.
:oughlin, J.
chlo~ide:
P., 1951, Hi~h-temperature heat contents

of
nickel
41.
Coughlin, J. P., 1954, Contributions to the data on theoretical

metallurgy XII. Heats and free energies of formation of inorganic
oxides: U. s. Bur. Bines Bull. 542, 80 p.
112.
Coughlin, J. P., 1955, High-teaperature heat contents, heats of

transition, and heat of fusion of anhydrous sodium sulfate: Aa.
Chem. Soc. Jour., v. 77, p. 868-870.
43.
:oughlin, J. P., and King, E. G., 1950, High-temperature heat

contents of some zirconiua-containing substances: la. Chea. Soc.
Jour., v. 72, p. 2262-2265.
44.
Coughlin, J. P., King, E. G., and Bonnickson, K. B., 1951,

High-temperature beat contents of ferrous oxide, magnetite and
ferric oxide: Am. Chem. Soc. Jour., v. 73, p. 3891-3893.
45.
Coughlin, J. P., and O'Brien, c. J., 1957, High te11perature heat

content of calcium orthosilicate: Jour. Phys. Chaaistry, v. 61,
p. 767-769.
46.
Darken, L. s., and Gurry, a. w., 1946, The systea iron-oxygen.

II.
Equilibrium and ther aody na mics of liquid oxide and other phases:
liB. Chell. Soc. Jour., v. 68, p. 798-816.
47.
Dellien, I., McCurdy, K. G., and Hepler, L. G., 1976, Enthalpies of

formation of lead chromate, lead molybdate, and lead tungstate,
and the entropy of aqueous
tungstate
ion:
Jour.
Che
The~aodynamics, v. 8, p. 203-207.
48.
Deslattes, a. D., Henins, A., Bovaan, H. A., Schoonover, B. ft. t

Carroll, c. L., Barnes, I. L., !lachlan, L. A., l!oore, L. J., and
Shields, w. B., 19711, Determination of the Avogadro constant:
Phys. Rev. Letters, v. 33, p. 463-466.
49.
Dewing, E. w., and Richardson, F. D., 1960, The theraodyoamics of

the conversion of magnesium cmd manganese oxides to sulfides:
Iron ~nd Steel Inst. Jour., v. 195, p. 56-58.
50.
Ditma~s,
D. A., and Douglas, T. B., 1971, fteasureaent of the

enthalpy of pure o:-Al 2 o 3 ( IIBS heat capacity and enthalpy
standard reference material no. 720) from 273 to 1173 K:
u. s.
Natl. Bur. Standards Jour. Research, v. 75A, p. 401-420.
~elative
REFERENCES
liD
NOTES
431
51.
D:>uglas, r. B., and Ditaars, D. 1., 1967, l'leasured rel:ltive enthalpy

of anhydrous crystalline aluainua trifluoride, llF 3 , fro 273 to
1173 K and derived theraodynaaic properties froa 273 to 600 K: u.
s. Natl. Bur. Standards Jour. Research, v. 71, p. 185-193.
52.
Egan, E. P., Jr.,

Wakefield, z.
1' .. ,
and Blaore,
High-teaperature heat content of hydroxyapatite:
J:>ur., v. 72, p. 2418-2421.
53.
Egan, E. P., Jr., Wakefield, z. T., and Luff,

B. B.,
1961, Lov
teaperature heat capacity, entropy and heat of foraation of
crystalline and colloidal ferric phosphate dihydrate: Jour. Phys.
Cheaistry, v. 65, p. 1265-1270.
54.
Ferrante, 1'1. J., 1972, Enthalpies above 298.15 K for copper sulfate
and copper oxysulfate: u. s. Bur.
l'lines Rept. Inv. 7600, 8 p.
55.
Ferrante, 1'1. J., Stuve, J. 1'1., and Richardson, D.

w., 1976,
Theraodynaaic data for synthetic davsonite:
u. s. Bur. l'lines
Rept. Inv. 8129, 13 p.
56.
Perrier, 1., 1969, Enthalpy of synthetic anorthite between 298 and

1950 K: Coapt. Bend. lead. Sci. [Paris), v. 269C, p. 951-954.
57.
Fitzgibbon, G. c., Huber,

E. J., and Holley, c. E., Jr.,
Enthalpy of foraation of europiua sesquioxide
Jour.
Theraodynaaics, v. 4 1 p. 349-358.
1972,
Chea.
sa.
Fitzgibbon, G, c., Huber, E. J., Jr., and Holley, c. E., Jr.,

enthalpy
of
foraation
of
bariua
aonoxide:
Jour.
Theraodynaaics, v. 5 1 p. 577-582.
1973'
Chea.
59.
Flotow, H. E., an~ Osborne,

D. v.,
1974, The heat capacity of
dicesiua aonoxide ( Cs 2 o) froa 5 to 350 K and the Gibbs energy of
foraation to 763 K: Jour. Chea. Theraodynaaics, v. 6, p. 135-140.
&0.
Fredrickson, D. B., and Chasanov, 1'1. G., 1970, Enthalpy

dioxide and sapphire to 1500 K by drop caloriaetry:
Theraodynaaics, v. 2, p. 623-630.
61.
Fredrickson, D. R., and Chasanov,

M.
G.,
1971, The enthalpy of
aolybdenua disulfide to 1200 K by drop caloriaetry: Jour. Chea.
62.
Fredrickson, D. R., and Chasanov, 1!. G.,

1972, Theraodynaaic
investigation of trisodiua uraniua(V) oxide
(Na 3 uo.).
III.
Enthalpy
to
1200
K
by
drop
caloriaetry:
Jour. Chea.
63.
Fredrickson, D. R., and Chasanov, ft.

G.,
1973, The enthalpy of
sodiua oxide Ha 2 o to 1300 K by drop caloriaetry: Jour. Chea.
Theraodynamics, v. 5, p. 485-490.
64.
Fredrickson, D. R., and O'Hare, P. 1. G., 1976, Enthalpy increaents

for m- and p-Ba 2 uo. and Cs 2 oo. by drop caloriaetry. The enthalpy
of the to ~ transition in la 2 oo.: Jour. Chea. l'heraodynaaics, v.
a, p. 353-360.
65.
Preeaan, R. D., 1962 1 l'heraodynaaic properties of binary

Oklahoaa State Univ. Research Pound. Bept. 60, 41 p.
L., 1950,
Am. Chea. Soc.
K.
of uraniua
Jour. Chea.
sulfides:
1132
TBERMOD!Hl!IC
PROPERTIES
OF
MINERALS
66.
Furukawa, G. T., Douglas, T. B., Mccoskey, a. E., and Ginnings,

D.
c., 1956, Thermal properties of aluainum oxide froa 0 to 12000K:
u. s. Hatl. Bur. Standards Jour. Research, v. 57, p. 67-82.
67.
Furukawa, G. T.,
and Saba,
thermodynamic properties of
BeOll 2 0 3 , from 16 to 3800K:
Research, v. 65, p. 13-18.
68.
Garrels, a. M., Thompson, M. E., and Siever, B., 1960, Stability of

some carbonates at 25DC and one ataosphere total pressure:
Am.
Jour. Sci., v. 258, p. 1102-1118.
69.
Giauque, w. F., Hornung, E. w., Kunzler, J. E., and Rubin,

T.
1960,
The theraodynaaic properties of aqueous sulfuric acid
solutions and hydrates from 15 to 3ooo K:
la. Chem. Soc. Jour.,
v. 82, p. 62-70.
70.
Ginnings, D. c., and Corruccini, B. J., 19117a, Heat capacities at

high temperatures of uranium,
uranium trichloride, and uraniua
tetrachloride: U. s. Natl. Bur. Standards Jour. Research, v. 39,
p. 309-316.
71.
Ginnings, D. c., and Corruccini, B. J., 19117b, Enthalpy, specific

heat, and entropy of aluminua oxide from ()D to 9000C:
u. s. Hatl.
Bur. Standards Jour. Res., v. 38, p. 593-600.
72.
Goates, J. R., Cole, A. G., and Gray, E. L., 1951, Free energy of
formation and solubility product constant of mercuric sulfide:
1111. Chem. Soc. Jour., v. 73, p. 3596-3597.
7 3.
Goates, J. R., Cole, 1. G., Gray, E. L., and

Theraodynamic properties of silver sulfide:
v. 73, p. 707-708.
711.
Good, w. D., Lacina, J. L., and !cCullough, J.

P.,
1960,
sulfuric
acid:
heat of foraation of aqueous solutions by rotating bomb
calorimetry: Am. Chem. Soc. Jour., v. 82, p. 5589-5591.
75.
~ronvold,
76.
Gronvold, F., 1975, Heat capacity and theraodynaaic properties of

bismuth in the range 300 to 950 K.
Fusion characteristics: leta
Chem. scandinavica, v. 291, p. 9115-955.
77.
Gronvold, P., Kveseth, H. J ., sveen, A., and Tichy, J., 1970,

Thermodynamics of the U02+x phase 1. Heat capacities of UOz o17
and U0 2 25 from 300 to
1000 K and electronic contributions:
Jour. Chem. Thermodynamics, v. 2, p. 665-680.
78.
Gron vold, P., and Samuelsen, E.

J.,
1975, Heat capacity and
thermodynamic properties of 11-Fe 2 0 3
in the region 30G-1050 K.
Antiferromagnetic transition: Jour. Physics and Chemistry Solids,
v. 36, p. 2119-256.
79.
Gronvold, P., and sveen, A., 19711, Heat capacity and theraodynamic
properties of synthetic aagnetite (Fe 3 0) froa 300 to 1050 K.
Perriaagnetic transition and zero-point entropy: Jour. Chem.
Thermodynamics, v. 6, p. 859-872.
w.
G., 1965, Heat capacity

and
berylli.ua a lumina te ( chrysoberyl ).
u. s. Hatl. Bur. Standards Jour.
a.,
Faux, N.D.,
1951,
Am. Chera. soc. Jour.,
F., 1973, Heat capacities and thermodynamic properties of

hexagonal and liquid selenium in the range 298 to 1000 K. Enthalpy
and temperature of fusion: Jour. Chem. Thermodynamics, v. 5, p.
525-531.
REFERENCES
AND
NOTES
433
80.
Gronvold, F., and Westrum, E. F., Jr.,

1962,
Heat capacities and
thermodynamic
functions
iron
disulfide (pyrite),
of
iron
diselenide, and nickel diselenide from 5 to 3500 K.
The
estimation
of
standard
entropies
of
transition
metal
chalcogenides:
Inorganic Chemistry, v. 1 t P 36-48.
81.
Gronvold, F., and Westrum, E.

F.,
Jr.,
Heat capacities of iron
disulfides.
Thermodynamics of marcasite from 5 to 700 K, pyrite
from 350 to 770 K, and the transformation of marcasite to pyrite:
Jour. Chem. Thermodynamics, v. 8, p. 1039-1048.1976
82.
Gronvold, F.,
Westrua, E.
F., Jr.,
and Chou,
c., 1959, Heat
capacities and thermodynamic properties of the pyrrhotites FeS and
Fe 0 887 S from 5 to 3500K: Jour. Chem. Physics, v. 30, p. 528-531.
83.
Gross, P., Hayman, c., and Bingham, J. T., 1966, Heats of formation
of germanium tetrafluoride and of the germanium dioxides:
Faraday Soc. Trans., v. 62, p. 2388-2394.
84.
Haas, J. L., Jr., 1976, written communication, August 1976.
85.
Haas, J. L., Jr., and Fisher, J. B., 1976, Simultaneous evaluation

and correlation of thermodynamic data: Aa. Jour. s=i., v. 276, p.
525-545.
86.
Hatton, W. E., Hildenbrand, D. 1., Sinke, G. c., and Stull, D.

R.,
1959,
The chemical thermodynamic properties of calcium hydroxide:
Am. :hem. Soc. Jour., v. 81, p. 5028-5{)30.
87.
Havtin, P., Levis, J. B., Moul, N., and Phillips, R. H.,

1966,
The
heats of combustion of graphite, diamond and some non-graphitic
carbons:
Royal Soc. [London) Philos. Trans., Ser. A, v.
261, p.
67-95.
88.
Hays,
J.
F.,
1966,
Lime
alumina
silica: Carnegie
Washington, Geophys. Lab. Ann. Bept. 1965-66, p. 234-239.
89.
Hemingway, B.
s., 1977,
An evaluation of
the
thermodynamic
properties of selected uranium compounds and ionic species: u. s.
Geol. Survey internal report.
90.
Hemingway, B.s., Krupka, K. 11., and Robie, R. A., [Heat capacities

and thermodynamic functions of the alkali feldspars and of
hematite between 350 and 1000 K by
differential
scanning
calorimetry.] Unpublished data.
91.
Hemingway, B. s., and Robie, R. A., 1972, The heat ca.pacities at low
temperatures and entropies at 298.15 K of huntite, Cal!g 3 (C0 3 ) 4 ,
and artinite, 11g 2 (0H) 2 C0 3 3H 2 0:
Am.
lhneralogist,
v.
57,
p.
1754-1767.
92.
Hemingway,
B.
s.,
and Robie, R.
A.,
1973,
A
caloriaetric
determination of the standard enthalpies of formation of huntite,
Cal1g 3 (C0 3 ) 4 , and artinite, Mg 2 (0H)zC0 3 3H 2 o,
and their standard
gibbs free energies of foraation: u.
s.
Geol.
survey Jour.
Research, v. 1, p. 535-541.
93.
Heaingway, B. s., and Robie, R. A., 1977, ~nthalpies of formation of

low albite (NaAlSilOa)t gibbsite (Al(OH) 3 ) , and
NaAl0 2
revised
values for t.H~ , 298 and t.G~ 298 of alumino-silicates:
U. s. Geol.
Survey Jour. Research, v. ~, p. 413-429.
94.
Hemingvay, B.s., and Robie, R.

A.,
The entropy anj
Gibbs free
energy of formation of the aluminum ion: Geochim. et Cosmochim.
Acta, v. 41, p. 1402-1404.1977
Inst.
434
THERftODYRAfU:C
PROPERTIES
OF
ftUTERALS
B. s., Robie, R. A., Fisher, J. a., and

Wilson,
w.
H., 1977, The heat capacities of gibbsite, Al( OH)n between 13 and
480 K and aagnesite,
ftqC0 39
between 13 and
380
K
and
their stand~rd
entropies
at
298.15
K,
and
the heat
capacities of Caloriaetry Conference benzoic acid between 12 and
316 K:
u. s. Geol. Survey Jour. Research, Y. s, p. 797-806.
95.
Hemingv~y,
96.
Hilsenrath, J., Beckett, c. w., Benedict, w. s., Fano, L., Hodge, H.

J., ftasi, J. F., Nuttall, R. L., Touloukian, Y. s.,
and Woolley,
H. w., 1955, Tables of theraal properties of gases:
u. s. Hatl.
Bur. standards Circ. 564, 488 p.
97.
Hlabse, T., and Kleppa, o. J., 1968, The theraocheaistry of jadeite:

Aa. ftineraloqist, v. 53, p. 1281-1292.
98.
Hola, J. L., and Kleppa, o. J., 1966a, High teaperatura caloriaetry

in liquid oxide systeas.
IV.
The enthalpy of foraation of
kyanite Al 2 Si0 5 :
Inorganic Cheaistry, v. 5, p. 698.
99.
Holm, J. L., and Kleppa, o. J., 1966b, The thermodynamic properties

of
the
aluminum silicates:
Am.
Mineralogist,
v. 51, p.
1608-1622.
100.
Hola, J.
L., and Kleppa, o.
J.,
1968, Theraodynamics of the
disordering process in albite (NallSi 3 0 8 ) :
Aa. ftineralogist, v.
53, p. 123-133.
101.
Hola, J.
L., Kleppa, o. J., and Westrum, E. F.,
Jr., 1967,
rhermod yna mics of polymorphic transformations in silica. Thermal
properties from 5 to 10700K and P-T stability fields for coesite
and stishovite: Geochim. et Cosaochia. Acta, v. 31, p. 2289-2307.
102.
H::>stetler, P. B., 1963, The stability and surface energy of

in water at 250C: Am. Jour. Sci., v. 21, p. 238-258.
103.
Huber, E. J., Jr., P'itzgibbon, G. c., and Holley, c. E., Jr., 1971,
Enthalpy of formation of dysprosium sesquioxide:
Jour. Chea.
Thermodynami=s, v. 3, p. 643-648.
104.
Huber, E. J., Jr., Head, E. L., and Holley, c. E., Jr., 1964, The
heats of foraa tion of zirconiua diboride and dioxide: Jour. Pbys.
Chemistry, v. 68, p. 3040-3042.
105.
Huber, E. J., Jr., and Holley, c.

E., Jr., 1953, The heat of
c::>mbustion of ceriua: Aa. Chem. Soc. Jour., v. 75, p. 5645-5646.
106.
Hull, H., and Turnbull, A.

G.,
1973,
1 theraocheaical study of
monohydrocalcite: Geocbia. et Cosaochim. Acta, v. 37, p. 685-694.
107.
Hultgren, R., Desai, P. D., Hawkins, D. T., ;>leiser, ft., Kelley,

K.
K., and Wagaan,. D. D., 1973, Selected values of the theraodynaaic
properties of the eleaents:
Amer. Soc. for ftetals, Metals Park,
Ohio, 636 p.
108.
Hultgren, R., Desai, P. D., Hawkins, D. T., Gleiser, ft., and Kelley,
K. K., 1973, Selected values of the therodynaaic
properties of
binary alloys: Amer. Soc. for ftetals, ftetals Park, Ohio, 1435 p.
109.
Humphrey, G. L.,
King,
thermodynamic values
Inv. 4870, 16 p.
110.
Hunt.zicker, J. J., and Westrua, E.

F., Jr.,
1971,
The agnetic
transition, heat capacity, and theraodynaaic properties of uraniua
dioKide fro 5 to 350 K: Jour. Che. Theraodynaaics, v. 3, p.
61-76.
brucite
E.
G., and Kelley,
K. K.,
1952, Soae
for ferrous oxide:
u. s. Bur. Bines Rept.
REPEBEICES
AND
NOTES
435
111.
Jeffes, J. H. E., Richardson, F. D., and Pearson, J.,

1954, The
heats of foraation of aanganous orthosilicate and aanganous
sulfide:
Faraday soc. rrans., v. so, p. 364-370.
112.
Jones, v. K., Gordon, J., and Long, E. 1., 1952, The heat capacities
of uraniua, uraniua trioxide, and uraniua dioxide froa 15 to 300
K: Jour. Cbea. Physics, v. 20, p. 659-699.
113.
Justice, B. H.,
and Vestrua, E. F., Jr.,
1969, Theraophysical
properties
of
the
lanthanide oxides.
v. Heat capacity,
theraodynaaic properties, and energy levels of ceriua (III) oxide:
Jour. Phys. Cheaistry, v. 73, p. 1959-1962.
114.
Kelley, K. K., 1937, Contributions to the data on theoretical

aetallurgy.
VII. The theraodynaaic properties of sulfur and its
inorganic coapounds:
u. s. Bur. Kines Bull. 406, 104 p.
115.
Kelley, K. K., 1960, Contributions to the data on theoretical

aetallurgy.
XIII.
High-teaperature heat-capacity, and entropy
data for the eleaents and inorganic coapounds:
u. s. Bur. Kines
Bull. 584, 232 p.
116.
Kelley, K. K., 1962, Heats and free energies of foraation

anhydrous silicates: D. s. Bur. !tines Kept. Inv. 5901, 32 p.
117.
Kelley, K. K., and Anderson, c. T., 1935, Contributions to the data

on theoretical aetallurgy.
IV. Betal carbonates - correlation
and applications of theraodynaaic properties: U. s.
Bur. Bines
Bull. 384, 73 p.
118.
Kelley, K. K., Barany, a., King, B. G., and Christensen, 1.

1959, Soae theraodynaaic properties of fluorphlogopite aica:
s. Bur. Bines Kept. Inv. 5436, 16 p.
of
o.,
D.
119.
Kelley, K. K., and Christensen, 1. u., 1961,

High-teaperature heat
content and entropies of crystalline geraaniua dioxide: o. s. Bur.
Rines Bept. Inv. 5710, 5 p.
120.
Kelley, K. K., and King, E. G., 1961, contributions to the data on

theoretical aetallurgy.
IIV.
Entropies of the eleaents and
inorganic coapounds: u. s. Bur. Bines Bull. 592, 149 p.
121.
Kelley, K. K., Shoaate, c.

E., and Huffaan, E. H.,
and potassium alums and
extraction of aluaina
Tech. Paper 688, 104 p.
122.
Kelley, K. K., Todd, s. s., and King, E. G., 1954, Heat and free
energy data for titanates of iron and the alkalina-earth aatals:
u. s. Bur. ftines Bept. Inv. 5059, 37 p.
123.
Kelley, K. K., Todd, s. s., Orr, B. L., King, E. G., ~nd Bonnickson,
K. B.,
1953, Theraodynaaic properties of sodiua-aluainua and
potassiua-aluainua silicates:
u. s. Bur. Bines Bept. Inv. 4955,
21 p.
124.
Khriplovich, L. !. , and Paukov, I. E., 1976, Heat capacity, entropy

and enthalpy of strontiua: Zhurnal Fizicheskoi Khiaii, v. SO, p.
567-568.
125.
King, E. G., 1948, Beat contents at high teaperatures of vanadiua

dichloride and vanadiua trichloride: la. Chea. soc. Jour., v. 70,
p. 2154-2155.
H., Young, P. B., Naylor, B. F., Salo, 1.

1946, Theraodynaaic properties of aaaoniua
related substances, with reference to
froa clay and alunite: u. s. Bur. Kines
THBRBODYIAftiC
436
PROPERTIES
OP
ftiHBBALS
126.
King, E.
G.,
1951, Beats ..of foraation of crystal.line calciua
orthosilicate,
tricalciua silicate and zinc orthosilicate: Aa.
Chea. soc. Jour., v. 73, p. 656-658.
127.
King, B. G., 1952, Heats of foraation of aanganous aetasilicate

(rhodonite) and ferrous ortbosilicate ( fayalite ): Aa. Chea. Soc.
Jour., v. 74, p. 4446-4448.
128.
King, B. G., Barany, B., Weller, w. w., and Pankratz, L.

Theraodynaaic properties of forsterite and serpentine:
Kines Be pt. Inv. 6962, 19 p.
B.,
o.
1967,
s. Bur.
129.
King, E. G., and Christensen, A. o., Jr., 1958, Beat contents above
298. 150K of oxides of cobalt and nickel: Aa. Chea. Soc. Jour., v.
80, p. 1800-18(11.
130.
King, E. G., and Christensen, A. o., 1961, Bigh-teaperature heat

contents and entropies of ceriua dioxide and coluabiua dioxide:
o. s. Bur. Kines Rept. Inv. 5789, 6 p.
131.
King, E. G., Ferrante, K. J., and Paaltratz, L.

B.,
1975,
Theraodynaaic data for Kg(OH) 2 (brucite):
u. s. Bur. Bines Bept.
InY. 8041, 13 p.
132.
King,
E.
G.,
Orr,
B. L., and Bonnickson, K. B., 1954, Lov
temperature heat capacity, entropy at 298.160K.,
and
high
temperature heat content of sphene (CaTiSi0 5 ): Am. Chea. Soc.
Jour., v. 76, p.4320-4321.
133.
King, E. G., Richardson, D. w., and Brazek,

formation of three oxides of rheniua:
u.
7323, 13 p.
134.
King, E. G., and Weller,

v. w., 1961a, Lov-teaperature heat
capacities and entropies at 298.150K of aonotungstates of sodiua,
magnesium, and calcium:
u. s. Bur. Bines Rept. Inv. 5791, 6 p.
135.
King, E. G., and Weller,

v. w., 1961b, Low-temperature heat
capacities and entropies at 298.150K of diaspore,
kaolinite,
dickite and halloysite: o. s. Bur. Bines Rept. Inv. 5810, 6 p.
136.
King, E.
G.,
and Weller,
w. w., 1961c, Low temperature heat
capacities
and
entropies at 298.150K of soma sodium- and
D. S. Bur. Bines Bept. Inv. 58SS, 8
calcium-aluainum silicates:
a. v.,
s. Bur.
1969, Heats of
Bines Bept. Inv.
p.
137.
King, E. G., and Weller, v. w., 1962, Lov-teaperature heat capacity

and entropy at 298.15011: of red mercuric sulfide: u. S. Bur. Kines
Rept. Inv. 6001, 4 p.
138.
King,
E.
G.,
and Weller,
w. w., 1962b, Lov-teaperature heat
capacities and entropies at 298.150K of antimony and indium
s~lfides:
o. s. Bur. Bines Rept. Inv. 604CI, S p.
139.
heat
King, E. G., and Weller, w. w.,
1970, Low-temperature
capacities
and
entropies
at
298.15
OK of goethite and
pyropbyllite: u. s. Bur. Kines rept. Inv. 7369, 6 p.
140.
King, E. G., Weller,

w. w., and Christensen, A. u.,
Theraodynamics of some oxides of molybdenum and tuagsten:
Bur. Bines Rept. Inv. 5664, 29 p.
141.
1960,
u. s.
King, E. G., Weller, w. w., Christensen, A. u., and Kelley, K.

K.,
1961, Some thermodynamic values for four titanium halides: U. s.
Bur. Bines Rept. Inv. 5799, 20 p.
REFERENCES
AND
NOTES
437
142.
King, E. G., Weller, w. w., and Pankratz, L. B., 1961, Theraodynamic

data for lanthanua sesquioxide: o. s. Bur. !tines Rept. Inv. 5857,
6 p.
143.
Kittrick, J. A., 1966, Free energy of formation of kaolinite from

solubility aeasurements:
Am. !ineralogist, v. 51, p. 1457-1466.
144.
Kiukkola, K., and Wagner, c., 1957, l!easurements on galvanic cells

involving solid electrolytes: Electrochea. Soc. Jour., v. 1U4 ,
p. 379-387.
145.
Klinedinst, K. A., and Stevenson, D. A., 1972, The determination of

the standard Gibbs energy of formation of ~-g~llium sesquioxide
from E.I!.F. measurewents using a yttria-doped thoria electrolyte:
Jour.
Chem. Theraodynaaics, v. 4, p. 565-574.
146.
Koehler, 1!. F., Barany, R., and Kelley, K. K., 1961, Heats and free
energies of formation of ferrites and aluminates of calcium,
magnesium, sodium, and lithium:
o. s. Bur. !tines Rept. Inv. 5711,
14 p.
147.
Koehler, 1!. F., and Coughlin, J. P., 1959,

Heats ot formation of
ferrous chloride,
ferric chloride and manganous chloride: Jour.
Phys. Chemistry, v. 63, p. 605-608.
148.
Kracek, P. c.'
of
1953, Thermochemical properties
minerals:
carnegie Inst.
1952-53,
Washington, Geophys. Lab.
Ann. Rept.
p. 69-74.
149.
Kracek,
F.
c.,
Neuvonen,
K. J., and Burley,
thermodynamic study of the stability of jadeite:
Sci. Jour., v. 41, p. 373-383.
u.,
1951,
A
!cad.
w~shington
150.
Kraaer, J. R.,
1964, sea water:
saturation
car bonates: Science, v. 146, p. 637-638.
151.
Krupka, K. 1!., 1975, written commun.
152.
Krupka, K. 1!.,
Robie,
R.
A., and Hemingway, B. s., The heat
capacities of corundum,
periclase, anorthite, C~Al 2 Si 2 0 8 ~lass,
muscovite,
pyrophyllite,
KA1Si 3 0 8
glass,
grossularite,
and
NaA1Si 3 0 8 glass between 350 and 1000 K: [abs.] EOS (Aa. Geophys.
Union Trans.), v. 58, p. 523.1977
153.
Landee, c.
P., and Westrum, E. F., Jr.,
1975, Thermophysical
measurements on transition-metal tungstates. I. Heat capacity of
zinc tungstate from 5 to 550 K:
Jour. Chem. Thermodynamics, v. 7,
p. 97 3-976.
154.
Landee, c.
P., and Westrum, E.
F., Jr.,
1976, Thermopyhsical
measurements on transition aetal tungstates. III. Heat capacity of
antiferroaagnetic manganese tungstate: Jour. Chem. Theraodynaaics,
v. 8, p. 663-674.
155.
Lander, J. J., 1951, Experimental heat contents of sro,

aao, cao,
BaC0 3 and SrC0 3 at high temperatures. Dissociation pressures of
BaC0 3 and SrC0 3 :
156.
Lyon, w. G. and Westrum, E. F., Jr., 1974, High temperature theraal

functions and the thermochemistry of zinc tungstate: Jour. Chea.
157.
Lyon, w. G., and Westrum, E. F., Jr., 1974, Heat capacities of zinc
tungstate and ferrous tungstate from 5 to 550 K:
Jour. Chea.
with
apatites
and
438
THER!ODYBA!IC
PROPERTIES
OF
!IBERlLS
158.
ftah, l. D., 1954, Heats of for.ation of chroaiu. oxide and cadaiua

oKide froa coabustion caloriaetry: Aa. Chea. soc. Jour., v. 76,
p. 3363-3365.
159.
Bah, l.
D., 1957, Heats of foraation
trioxide, and aolybdenu dioxide: Jour.
p. 1572-1573.
160.
Bah, A. D., 1960, Theraodynaaic properties of aanganese

coapounds: u. s. Bur. Bines Rept. Inv. 5600, 34 p.
161.
ftah, 1. D., 1961, Heats of foraation of ceriua

bisauth sesquioxide by coabustioo caloriaetry:
Rept. Inv. 5676, 7 p.
162.
!ah, A. D., 1962, Heats and free energies of foraation of galliua

sesquioxide and scandiua sesquioxide: u. s. Bur. Kines Rept. Inv.
5965, 6 p.
163.
Mah, A. D., and Adaai, L. H.,

1962,
foraation of geraaniua dioxide:
6034, 7 p.
164.
of aluaina, aolybdenua
Pbys. Cbeaistry, v. 61,
Heats
u.
s.
and
its
sesquioxide and
u. s. Bur. Kines
and free energies of

Bur. Bines Rept. Inv.
Mah, A. D., Pankratz, L. a., Weller, 11. 11., and King, E.

Theraodyna11ic data for cuprous and cupric oxides:
Mines Bept. Inv. 7026, 20 p.
G.,
1967,
u. s. Bur.
165.
McBride, J. J., and Vestrua, E. F., Jr., 1976, Lov-teaperature heat

capacity of anisotropic crystals. Laaellar aolybdenua disulfide:
J:>ur. Chell. Theraodynaaics, v. 8, p. 37-44.
166.
ftcftasters, o. D., Gschneidner, K.

A., Jr., Kaldis, E.,
and
Sampietro,
G., 1973, High-teaperature heat contents of the
europium chalcogenides, Euo, Eus, EaSe and EuTe:
Bare Earth
Research Conf., 10th, Vienna, 1973, Proc., v. 2, p. 97Q-975.
167.
Mills, K. c., 1974, Theraodynaaic data for inorganic sulpllides,

selenides and tellurides: London, Butt~rvorths, 845 p.
168.
Moore, G. E., 1943a, Heat content of ~anganese dioxide and carbonate

at high teaperatures: lm. Chem. Soc. Jour., v. 65, p. 1398-1399.
169.
Moore, G. E., 1943b, Heat contents at high teaperatures of the

anhydrous chlorides of calciua, iron, aagnesiua, and aanganese:
Am. Chell. Soc. Jour., v. 65, p. 1700-1703.
170.
Moore, ~. E., and Kelley, K. K., 1947, High temperature heat

contents of uraniua, uraniua dioxide, and uraniua trioxide: Aa.
Chem. Soc. Jour., v. 69, p. 2105-2107.
171.
l!orey, G. w., Fournier, R. o., and Rove, J. J., 1962, Solubility of

quartz in water in the teaperature interval fro 250 to 3ooo:
Geochia. et Cosaochia. Acta, v. 26, p. 1029-1043.
172.
M:>sesman, ft. A., and Pitzer, K. s., 1941, Theraodynamic properties

of the crystalline foras of silica: Am. Chea. Soc. Jour., v. 63,
p. 2348-2356.
173.
Mustajoki, Arvo, 1951, ftessungea der vahren spezifischen llaerae der

KCl-KBr-!ischkristalle ia Temperaturbereich 50-450 oc: suoaalaiseo
Tiedeakateian Toiituksia, Series A, I. ftatheaatica-Physica, v.
98, p. 7-45.
174.
Naylor, B. P., 1944, High-temperature heat contents of ferrous

magnesium chroaites: Ind. Eng. Cheaistry, v. 36, p. 933-934.
and
RBFBREICES
liD
439
IOTES
175.
Naylor, B. F., 1945, Beat contents at high teaperatures of aagnesiua

and calciua fluorides: la. Chea. Soc. Jour., v. 67, p. 15o-152.
176.
Naylor, B. F., 1946, Bigh-teaperature heat contents of TiO, Ti 2 o.,

Ti.0 59 and Ti0 2 : la. Chea. Soc.
Jour., v. 68, p. 1077-1080.
177.
tfaylor, B. F., and Cook, o. l., 1946, High-teaperature heat contents

of the aetatitanates of calciua, iron, and aagnesiua: la. Chea.
Soc. Jour., v. 68, p. 1003-1005.
178.
Neuvonen, K. J.,
1952a, Theraocheaical investigation
of
the
akeraanite-gehlenite series: Finland Coaa. Geol. Bull. 158, 50 p.
179.
Heuvonen, K. J., 1952b, Heat of foraation of aerviaite

and
aonticellite: la. Jour. Sci., Boven Voluae, pt. 2 1 p. 373-380.
180.
Iewton,
R. c., Charla, T.
v., and Kleppa, o. J. 1 1974, l
caloriaetric investigation of the stability of anhydrous aagnesiua
cordierite with application to granulite facies aetaaorphisa:
Contr. l!ineralogy and Petrology, v. 44, p. 295-311.
181.
o Brien, c. J., and Kelley,
182.
Oetting, F. L., 1970, On the true teaperature rise in isoperibol

caloriaetry: Jour. Chea. Theraodynaaics, v. 2, p. 727-739.
183.
O'Hare,
P.
1.
G.,
1972,
Theraocheaical
and
investigations of the sodi ua-o11:ygen systea. Part I.
enthalpy of foraation of sodiua o11:ide (Ra 2 0):
Physics, v. 56, p. 4513-4516.
184.
O'Hare, P. 1. G., and Hoekstra, H. B., 1973, Theraocheaistry of

uraniua coapounds II. standard enthalpy of foraation of c-sodiua
uranate (-B~ 2 oo.): J. Chea~ Theraodynaaics, v. 5, p. 769-775.
185.
O'Hare, P. l. G., and Hoekstra, H. a., 1974, Theraocheaistry of

uraniua coapounds II. Standard enthalpy of fora~tion of cesiua
uranate (Cs 2 uo.): Jour. Chea. Theraodynaaics, v. 6, p. 251-258.
186.
O'Hare, P. l. G., Shinn, 11. 1., l!razek, F. c., and l!artin, l. 1.,
1972, Theraodynaaic investigation of trisodiua uraniua(Y) oll:ide
( Na 3 uo.) I. Preparation and enthalpy of foraa tion: Jour. Chea.
187.
Openshaw, R. E., Heaingvay, B.S., Robie, B. l., llaldbaua, D. B.,

and Krupka, K. B., 1976, The heat capacities at low teaperatures
and entropies at 298.15 K of low albite, analbite, aicrocline, and
high sanidine: u. s. Geol. survey Jour. Research, v. 4, p. 195-204.
188.
Orr, R. L., 1953a, Hiqh-teaperature heat coatents of hafniua dioxide

and hafniua tetrachloride: lL Chea. Soc.
Jour.,
v. 75, p.
1231-1232.
189.
Orr, R. L., 1953b, Hiqh-teaperature heat contents of tantalua

niobiua oxides: la. Chea. Soc. Jour., v. 75 1 p. 2808-2809.
190.
orr, R. L., 1953c, High teaperature heat contents of aagnesiua

orthosilicate and ferrous orthosilicate: la. Chea. Soc. Jour. 1 v.
75, p. 528-529.
K.
K.,
1957, High teaperature heat
contents of cryolite, anhydrous aluainua fluoride and sodiua
fluoride: la. Chea. Soc. Jour., v. 79, p. 5616-5618.
theoretical
The standard
Jour. Chea.
and
440
THEB BODY Nl !IIC
PBOPEBTI ES
0l
I!INEBlLS
L.,
19 1.
orr, a.
1954,
High teaperature heat contents of aanganese
sesquioxide and
vanadiua aonoxide: Aa. Chea. Soc. Jour., v. 76,
p. 857-858.
192.
Orr, B. L., and Christensen, A.

u., 1958, High teaperature heat
contents of stannous and stannic sulfides: Jour. Phys. Cheaistry,
v. 62, p. 124-125.
193.
Osborne, D. W., Brletic, P. A., Hoekstra, H. R., and Flotow, B.

E.,
1976, Cesiua uranate, cs 2 00 4 : heat capacity and entropy froa 5 to
350 K and standard Gibbs energy of foraation at 298.15 K:
Jour.
Chea. Theraodynaaics, v. 8, p. 361-365.
194.
Osborne, D. w., and Flotow, B. E., 1972, Theraodynaaic investigation

of trisodiua uraniua( Y) oxide (lla 3 00 4 ) II.
Heat
capacity,
entropy, and enthalpy increaent froa 5 to 350 K. ~ibbs energy of
foraation at 298.15 K:
Jour. Chea.
Theraodynaaics, v. 4,
p.
411-418.
195.
Osborne, D. w., Flotow, H. E., Dalliager, R. P., and Hoekstra,

H.
R., 1974, Heat capacity of m-sodiua uranate (m-Ma 2 U0 4 ) froa 5 to
350 K. Standard Gibbs energy of foraation at 298.15 K: Jour. Chea.
196.
Osborne,
lf.
s.,
Stillson, H. F., and (;innings, D.
c., 1939,
fteasureaents of heat capacity and heat of vaporization of water in
the range oo to 100 oc: o. s. Hatl. Bur. Standards Jour. Research,
v. 23, p. 261-270.
197.
Otto, E. ft., 1964, Equilibriua pressures of oxygen over l!nz0 3 -I!n 3 0 4

at various teaperatures:
Electrochea. soc. Jour., v. 111, p.
88-92.
198.
Page, c. H., and Yigoureaux,

P.,
Eds.,
1972,
The International
Systea of Units ( SI): u. s. Natl. Bur. Standards Spec. Pub. 330,
45 p.
199.
Pankratz, L. B., 1964, Hi~h teaperature heat contents and entropies

of auscovite and dehydrated muscovite:
u. s. Bur. Bines Kept.
Inv. 6371, 6 p.
200.
Pankratz, L. B., 1966, High-teaperature heat contents and

of two praseodyaiua oxides and three terbiua oxides:
Bines Rept. Inv. 6781, 8 p.
entropies
S. Bur.
o.
201.
Pankratz, L. B., 1968, High-teaperature heat contents and entropies

of dehydrated analcite,
kaliophilite, and leacite: U.s. Bur.
Bines Rept. Inv. 7073, 8 p.
202.
Pankratz, L. B., and Kelley, K.

K., 1963a, High-teaperature heat
contents and entropies of sesquioxides of lutetiua, dysprosiua,
and ceriua: u. s. Bur. Bines Kept. Inv. 6248, 8 p.
203.
Pankratz, L. B., and Kelley., K. K., 1963b, Theraodynaaic data for

galliua and scandiua sesquioxides: 0. s. Bur. Bines Kept. Inv.
6198, 7 p.
204.
Pankratz, L. B., and Kelley, K. K., 1963c, Theraodynaaic data for

aagnesiua oxide (periclase):
u. s. Bur. Kines Rept. Inv. 6295, 5
p.
205.
Pankratz, L. B., and Kelley, K.

K., 1964a, High-teaperature heat
contents and entropies of andalusite, kyanite, and silliaani te:
u. s. Bur. Kines Kept. Inv. 6370, 1 p.
REFERENCES
lND
441
NOTES
206.
Pankratz, L. B., and Kelley, K. K., 1964b, High-teaperature heat

contents and entropies of akermanite, cordierite, gehlenite, and
mervinite:
u. s. Bur. l!ines Rept. Inv. 6555, 7 p.
207.
Pankratz, L. B., and King, E. G.,

1963, High-teaperature heat
contents and entropies of the sesquioxides of erbium, holaium,
thulium, and ytterbiua: o. s. Bur. Mines Rept. Inv. 6175, 8 p.
208.
Pankratz, L. B.,
and King,
E. G.,
1965, High-teaperature heat
contents and entropies of two zinc sulfides ~nd four solid
solutions of zinc and iron sulfides:
o. s. Bur. l!ines Rept. Inv.
6708, 8 p.
209.
Pankratz, L. B., and King, E. G., 1970, High-teaperature enthalpies

and entropies of chalcopyrite and bornite :
u. s. Bur. l!iaes
Rept. Inv. 7435, 10 p.
210.
Pankratz, L. B., King, E.

G.,
and
Kelley,
K.
K.,
1962,
High-temperature heat contents and entropies of sasquioxiies of
europiua, gadoliniua, neodyaiua, saaariua, and yttrium:
o. s.
Bur. Mines Bept. Inv. 6033, 18 p.
211.
Pankratz, L. B., and Weller, i. W., 1967, rheraodynamic properties

of three lithiua-aluainua silicates: o. s. Bur. Mines Kept. Inv.
7001, 13 p.
212.
Pankratz, L. B., and Weller, w. w., 1969,

ferric sulfate and indium sulfate: u.
7280, 8 p.
Theraodynaaic data for

Bur. Mines Kept. Inv.
s.
213.
Pankratz, L. B., Weller, w. w., and Kelley, K.

K.,
1963,
Lov-teaperature heat capacity and high-temperature heat content of
mullite:
u. s. Bur. Mines Rept. Inv. 6287, 7 p.
214.
Parker, V. B., Wagman, D. D., and Evans, w. H., 1971, Selected

values of cheaical theraodynamic properties.
Tables for the
alkaline earth eleaents (Eleaents 92 through 97 in the standard
order of arrangeaent): o. s.
Nat!. Bur. Standards Tech. Note
27Q-6, 106 p.
215.
Parker, v. B., iagaan, D. D., and Garvin, D., 1976, Selected

theraocheaical data coapatible with the CODlTl recoaaendations: U.
s. Natl. Bur. Staadards Interia Rept. 75-968, 31 p.
216.
Parks, G. 1., 1972, Free eaergies of foraation and

aqueous
solubilities of aluainua hydroxides and oxide hydroxides at 25 oc:
la. l!ineralogist, v. 57, p. 1163-1189.
217.
Richards, A. w., 1959, The heats of foraation and dissociation

zinc sulfide: Jour. lppl. Cheaistry, v. 9, p. 142-145.
218.
Richardson, D. w., and Brovn, R.

aalachite (Cu 2 (CO~)(OH)z): o.
a.,
s.
of
1974, Enthalpy of foraation of

Bur. ftiaes Bept. Iav. 7851, 5 p.
219.
Richardson, F. D., and Antill, J. E., 1955, r heraodynaaic properties

of cuprous sulfide and its aixtures vith sodiua sulfide:
Faraday
soc. rrans., v. 51, p. 22-33.
220.
Robie, R. 1., 1965, Heats and free energies of foraation of

troilite, herzenbergite,
magnesite, and rhodochrosite calculated
froa equilibriua data: u. s. Geol. survey Prof. Paper 525-D, p.
65-72.
442
THERMODYNA!UC
PROPEBTIES
OF
IIINERALS
221.
Robie, R. A., 1966, Thermodynamic properties of minerals, in Clark,

s. P., Jr., Ed., Handbook of physical constants, Geol. Soc.
America Mea. 97, p. 437-458.
222.
Robie, R. A., Bethke, P. 11., and Beardsley, K. 11., 1967, Selected

x-ray crystallographic data, molar volumes, and densities of
minerals and related substances: u. s. Geol. Survey Bull. 1248,
87 p.
223.
Robie, R. A., and Hemingway, B. s., 1972, The heat capacities at

low-temperatures and entropies at 298.15 K of nesquehonite,
MgC0 3 H 2 o, and hydromagnesite:
Am. !lineralogist, v. 57, p. 17681781.
224.
Robie, R. A., and Hemingway, B. s., 1973, The enthalpies of

!lgC0 3 3H 2 0, and hydroaagnesite,
formation
of
nesquehonite,
5Mg04C0 2 5H 2 0: U. S. Geol. survey Jour. Research, v. 1, p.
543-54 7.
225.
Robie, R. A., and Heaingway, B. s., 1977, ( !leasureaents on the enthalpy of formation of dolomite.] Unpublished data.
226.
Robie, R. A., Hemingway, B. s., and Wilson, w. H.,

1976, The heat
capacities of Calorimetry Conference copper and of auscovi te
KAl 2 (AlSi 3 )0 10 (0H)z, pyrophyllite Al 2 Si 4 0 10 (0H)z,
and
illite
K3 (Al 7 Mg)(Si 14 Al 2 )0 40 (0H) 8 between 15 and 375 K and their standard
entropies at 298.15 K: u. s. Geol. Survey Jour. Research, v. 4, p.
631-644.
227.
Robie, R.
A., Hemingway, B.s., and Wilson, w.
H.,
1978,
Low-temperature heat
capacities
and entropies of KA1Si 3 0 8 ,
NaA1Si 3 0 8 ,
and CaAl 2 Si 2 0 8 glasses and of
anorthite:
Aa.
Mineralogist, v. 63, p. 110-123.
228.
Robie, R. A., and Stout, J. w., 1963, Heat capacity from 12 to 3050K
and entropy of talc and tremolite: Jour. Phys. Chemistry, v. 67,
p. 2252-2256.
229.
Robie, R. A., and Waldbaum, D. R., 1968, Thermodynamic properties of

minerals and related substances at 298.150K (25.0DC) aqd one
atmosphere ( 1.013 bars) pressure and at higher temperatures: u. s.
Geol. Survey Bull. 1259, 256 p.
230.
Romanovskii, v. A., and Tarasov, v. v., 1960, Low-temperature heat

capacity and entropy at 298.l50K of the sulfides of elements in
group v of the D. I. llendeleev periodic table:
Soviet Physics
Solid state, v. 2, p. 1176-1181, Consultants Bureau, translated
from Fizika rverdogo Tela, v. 2, p. 1294-1299.
231.
Rosenqvist, T., 1954, A thermodynamic study of iron,

cobalt, and
nickel sulfi1es: Iron and Steel Inst. Jour., v. 176, p. 37-57.
232.
Rossini, F. D., 1956, Assignment of uncertainties to thermochemical

data,
in Rossini,
P. D., ed., Experimental thermo=hemistry: Hew
York, Interscience, p. 297-320.
233.
Rossini, P. D., Wagman, D. a., Evans, w. H., Levine, s., and Jaffe,
I.,
1952, Selected values of cheaical theraodynaaic properties:
U. S. Natl. Bur. Standards Circ. 500, 1268 p.
234.
Schuiling, R. D., Vergouwen, L., and Van der Rijst, H., 1976, Gibbs
energies of foraation of zircon (ZrSi04 ) , thorite ( ThSi0 4 ) , and
phenacite (Be 2 Si0 4 ): Aa. !lineralogist, v. 61, P 161-168.
REFERENCES
AND
NOTES
443
235.
Schuam, R. B., Wagaan, D. D., Bailey, s., Evans, w. H., and Parker,
v. B., 1973, Selected values of cheaical theraodynaaic properties.
Tables for the lanthanide (rare earth) eleaents: U. s. Natl. Bur.
Standards Tech. Mote 270-7, 75 p.
236.
Settle, J. L., Johnson, G. K., and Hubbard, w. N., 1974, The

enthalpy of foraation of dicesiua aonoxide (Cs 2 0): Jour. Chea.
237.
Shearer, J. A., and Kleppa, o. J., 1973, The enthalpies of foraation

of MgAl 2 0 4 , MgSiO:u Mg 2 Si0 4 and Al 2 Si05 by oxide aelt solution
caloriaetry: Jour. Inorganic and Nuclear Cheaistry, v. 35, p.
1073-1078.
238.
Shoaate, c. H., 1944, High-teaperature heat contents of aagnesiua

nitrate, calciua nitrate and barium nitrate:
Aa. Chea. Soc.
Jour., v. 66, p. 928-929.
239.
Shoaate, c. B., and Naylor, B. F., 1945, High-teaperature heat

contents of aluainua oxide, aluainua sulfate, potassiua sulfate,
aaaoniua sulfate and aaaoniua bisulfate: Aa. Chea. soc. Jour., v.
67, p. 72-75.
240.
Southard, J. c., 1941, A modified caloriaeter for high teaperatures.

The heat content of silica, wollastonite and thoriua dioxide above
250: Aa. Chea. Soc. Jour., v. 63, p. 3142-3150.
241.
Southard, J. c., and Moore, G. E., 1942, High-teaperature heat

content of !n 3 o,, ftnSi0 3 and Bn 3 C: Aa. Chea. Soc. Jour., v. 64,
p.
1769-1770.
242.
Southard, J. c., and Shoaate, c. H., 1942, Heat of foraation and

high-teaperature heat content of aanganous oxide and aanganous
sulfate. High-teaperature heat content of manganese: Aa. Chea.
Soc. Jour., v. 64, p. 1770-1774.
243.
Staveley, L.A. K., and Linford, a. G., 1969, The heat capacity and
entropy of calcite and aragonite, and their interpretation: Jour.
Chea. Theraodynaaics, v. 1, p. 1-11.
244.
Stout, J.
w.,
and Robie, B. A., 1963, Heat capacity froa 11 to

Entropy and heat of foraation of doloaiti: Jour. Phys.
Cheaistry, v. 67, p. 2248-2252.
3000K.
245.
Stubbles, J. a., and Birchenall, c. E., 1959, Redeteraination of the

lead-lead sulfide equilibriua between 585 and 9200
la. Inst.
!'lining !'let all. Petroleua Engineers Trans., v. 215, p. 535-539.
246.
Stubbles, J. a., and Richardson, F. D., 1960, Eqnilibria in the

systea aolybdenua+sulfur+hydrogen: Faraday Soc. Trans., v. 56, p.
146Q-1466.
247.
Stull, o. R., and Prophet, B., 1971, JANlF theraocheaical tables:

Natl. Standard Ref. Data Ser., u.s. Natl. Bur. Standards, v. 37,
1141 p.
248.
Stuve, J. B., 1974, Lov-teaperature heat capacities of

and wurtzite: o. s. Bur. Rines aept. Inv. 7940, 8 p.
sphalerite
249.
Stuve, J. a., and Ferrante, B. J., 1976, fheraodynaaic properties of

rheniua ozides, 8 to 1400 K: o. s. Bur. !ines Bept. Inv. 8199, 15
p.
250.
Taylor, 1. 1., Jr., and Saith, D. P., 1962', Theraodynaaic properties

of strontiua broaide aDd strontiaa nitrate: o. s. Bur. BiDes aept.
Inv. 5967, 12 p.
444
THERI'IODYNA!UC
PROPERTIES
OF
I'IINEJULS
251.
Taylor, R. w., and Schmalzried, H.,

1964 1
The free energy of
formation of some titanates, silicates, and magnesium alwainate
from measurements aade with galvanic cells involving
solid
electrolytes:
Jour. Phys. Chemistry, v. 68 9 p 2444-2449.
252.
Thompson, A. B., Newton, R. c., and Krupka, K. 1'1. 1 1977, Heat

capacity of synthetic l'lg 3 Al 2 Si 3 0 12 from 350 to 1000 K and the
entropy of pyrope: ( abs.) EOS (Am .. Geophys. Union Trans. ), v. 58,
p. 523.
253.
Todd, s. s., and Kelley, K. K., 1956, Heat and free-energy data for
tricalcium
dititanate,
sphene,
lithium
metatitanate,
and
zinc-titaniua spinel: u.s. Bur. Mines Rept. Inv. 5193, 18 p.
254.
Torgeson, D. R., and Sahama, T.

G.,
1948,
A hydrofluoric acid
solution calorimeter and the determination of the heats of
formation of l'lg 2 Si0 49 l'lgSi0 3 , and casio 3 :
Am. Chem.- Soc. Jour.,
v. 70, p. 2156-2160.
255.
Toulmin, P., III, and Barton, P. B., Jr., 1964 9 Thermodynaaic study
of pyrite and pyrrhotite:
Geochim. et cosmochim. Acta, v. 28 9 p.
641-671.
256.
Turnbull, A. G., 1973 1 A thermochemical study of vaterite:

et Cosaochia. leta., v. 37, p. 1593-1601.
Geochia.
257.
Ulbrich, H. H., and Waldbaua, D. a., 1976, Structural and other

contributions to the third-law entropies of silicates: Geochia. et
Cosaocbia. Acta, v. 40, p. 1-24.
258.
Vanderzee, c. E., Rodenburg, L. 11., and Berg, R.

L., 1974,
Theraocheaical studies on red and yellow orthorhoabic and on red
hexagonal aercuric oxide:
Jour. Chea. Thermodyn~aics, v. 6 9 p.
17-33.
259.
van Lier, J. A., de Bruyn, P. L., and overbeek, J. Th. G., 1960, The
solubility of quartz: Jour. Phys. Cheaistry, v. 64, p. 1675-1682.
260.
Victor, l. c., and Douglas, T. B., 1961, rheraodyna mi= properties of

thorium dioxide froa 298 to 1,200 OK:
D. s. Natl. Bur. Standards
Jour. Research, v. 651, p. 105-111.
261.
Victor, 1. c., and Douglas, T. B., 1963, Theraodynaaic properties of

aagnesiua oxide and berylliu oxide from 298 to 1200DK:
D. s.
Natl. Bur. Standards Jour. Research, v. 671, p. 325-329.
262.
Wagman, D. D., Evans, w. H., Parker, V. B., Halov, I., Bailey, s.

1'1.,
and Schuaa, B. H., 1968 9 Selected values of cheaical
theraodynamic properties. Tables for the
first
thirty-four
elements in the standard order of arrangeaent:
U. s. latl. Bur.
Standards Tech. Rote 270-l, 264 p.
263.
Wagaan, D. D., Evans, w. H., Parker, v. B., Balow, I., Bailey, s.

1'1.,
and Schuaa, R. H., 1969 1 Selected values of cheaical
thermodynamic properties. Tables for eleaents 35 through 53 in the
standard order of arrangeaent: D. s. latl.
Bur. Standards Tech.
llote 27Q-4, 1111 p.
264.
Wagman, D. D., Evans, w. H., Parker, v. B., Halov, I., Bailey, s.

1'1. 1
Schuaa, a. H., and Chorney, K. L., 1971, Selected values of
cheaical theraodynaaic properties. Tables for elements 54 through
61
in the standard order of arrangement: D. s. latl. Bur.
Standards Tech. Bote 270-5, 37 p.
265.
Wagaan, D. D., Evans, w. H., Parter, v. B., and Schuaa, B. B., 1976,
Cheaical theraodynaaic properties of
coapounds
of
sodiua,
potassiua and rubidiua: an interim tabulation of selected values:
U. s. latl. Bur. Standards Interia Rep. 76-1034.
REFEREMCES
AND
NOTES
266.
Wagner, J. B., and Wagner, c., 1957, Deteraination of the standard

at
3oooc:
free
energy of
formation of
cuprous sulfide
Electrochem. soc. Jour., v. 1011, p. 509-511.
267.
Waldbaua, D. R.,
1965, Theraodynaaic properties
of
aullite,
andalusite, kyanite and silliaanite: Am. l!ineraloqist, v. 50, p.
186-195.
268.
Waldbaua,
D.
R.,
1973,
The
configurational
entropies
of
Ca 2 1!gSi 2 0 7 -Ca 2 SiAl 2 0 7 melilites and related minerals:
Contr.
l!ineralogy and Petrology, v. 39, p. 33-511.
269.
Waldbaum, D. a., and Robie, R. A., 1971, Calorimetric investiqation

of Na-K mixing and polymorphism in the alkali feldspars: Zeitschr.
Kristalloqraphie, v. 184, p. 381-420.
270.
Weeks, 11. F., 1956, Heats of formation of metaaorphic minerals in

the systea cao-MgO-Si0 2 -H 2 0 and their petrological significance:
Jour. Geology, v. 611, p. 456-1172.
271.
Weller, w. w., 1965, Lov-teaperature heat capacities and entropies

at 298.150K of anhydrous sulfates of cobalt, copper, nickel, and
zinc: 0. s. Bur. l!ines Rept. Inv. 6669, 6 p.
272.
Weller, w. 11., 1966, Lov-teaperature heat capacities and entropies

at 298. 150K of ferrous aolybdate and ferrous tunqstate: u. s.
Bur. l!ines Re pt. Inv. 6782, 5 p.
273.
Weller, 11. w., and Kelley, K.

K.,
1963, Low-temperature heat
capacities and entropies at 298.150K of akermanite, cordierite,
gehlenite, and aerwinite:
2711.
Weller, i. 11., and Kelley,

K.
K.,
1964a, Lov-teaperature heat
capacities and entropies at 298.150K of sulfides of arsenic,
ger11aniua and nickel: u. s. Bur. mines Rept. Inv. 6511, 7 p.
275.
Weller, W. w., and Kelley,

K. K., 19611b, Lov-teaperature heat
capacities and entropies at 298.150K of lead aolybdate and lead
tungstates:
276.
Weller,
II.
w., and King, E. G., 1963a, Low-temperature heat
capacities and entropies at 298.150K of monomolybdates of sodiua,
magnesiua, and calcium:
o. s. Bur. Mines Rept. Inv. 6147, 6 p.
277.
Weller, 11. 11., and King, E. G., 1963b, Lov-teaperature heat capacity
and entropy at 298.150K of muscovite: o. s. Bur. Mines Bept. Inv.
6281, 4 p.
278.
Westrua, E. F., Jr., written communication, September, 1959.
279.
llestrua, E. F., Jr., and Beale, A. F., Jr., 1961, Heat capacities
and cheaical thermodynamics of cerium {III) fluoride and cerium
{IT) oxide fro 5 to JOOOK: Jour. Phys. Cheaistry, v. 65,
p.
353-355.
280.
Westrua, I. F., Jr., Chou, c., and Gronvold, F., 1959, Heat
capacities and theraodynaaic properties of the iron tellurides
Fe 1 11 Te and FeTe 2 froa 5 to 350 K: Jour. Chea. Physics, v. 30, p.
761.:764.
THERMODYNAMIC
44&
PROPERTIES
OF
MINERALS
281.
Westrum, E. F., Jr., and Gronvold, F., 1963, Che11ical theraodynaaics

of the actinide element chalcogenides - Proceedings
of
the
symposium on Thermodynamics of Nuclear ftaterials : Vienna, Aust.
Internat.
Atomic Energy Agency Proc. Ser., p. 3-3&.
282.
Westrum, E. F., Jr., and Gronvold, F.,

1970,
Manganese disulfide
( hauerite) and manganese ditelluride. Thermal properties from 5
to 350DK and antiferromagnetic transitions:
Jour. Chem.
Physics,
v. 52, p. 3820-3826.
283.
Westrum, E. F., Jr., Essene, E. J., and Perkins, D., IU, 1979,
Thermophysical
properties
of
the
garnet,
grossular,
v. 11, p. 57-66.
284.
Wise,
s. s.,
Margrave, J. L., Feder, H.

H.,
and
Hubbard,
W.
N.,
Fluorine bomb calorimetry.
V.
The heats of foration of
silicon tetrafluoride and silica:
Jour. Phys. Chemistry, v.
67,
1963,
p.
285.
815-8 21.
Heat content for corundum was obtained from a least squares fit
to
the data of Ditmars and Douglas (50) , Fredrickson and Chasanov
( 60) , Furukawa, and others
( 66),
Ginning s
and
Corruccini
(70),
Krupka,
and others (152),
and Oett..ing ( 182). For coesite
and stishovite, the heat content vas assumed to be tbe saae as
that of quartz (JANAF, 247) after the heat of the ~-p transition
was subtracted.
The heat content vas further constrained to fit
the heat capacity values given by Holm, Kleppa, and Westrum ( 101 ).
The entropy of tridymite is an average of that given by Anderson,
c. T., Am. Chem. soc. Jour., v. 58, p. 568 ( 1936),
and a value
calculated from the equilibrium curve in Tuttle,
o. P'.,
and
England, J. L., Carnegie Inst.
washington,
Geophys. Lab. Ann.
Bept.
1952-53, p. 61.
The entropies of phlogopite, monticellite,
and pyrope are estimates.
The
entropy
of
rhodonite
vas
corrected
for
magnetic
contribution
below 50 K. High
temperature heat content
of
tremolite
was
estimated.
The
enthalpy
of formation of andalusite is from Anderson, P.A.M.,
Newton, R.C., and Kleppa, O.J., Am. Jour. Sci.,
v.
211,
p.
285
( 1977 ).
The entropy of pyrope is from the work of Kolesnik, Yu. N., Nogteva,
V. V., and Paukov, I. Ye., 1977, Geokhimiya, p. 533. The high
temperature heat capacities of Ca-Al pyroxene are estimates.
286.
The enthalpy of formation of molybdenite at 298.15 K is from O'Hare,

P.A.G., Benn, E., Cheng, F. Yu., and Kuzmycz, G. (1970 Jour. Chern.
Thermodynamics, p. 797). The enthalpy of formation of pyrophyllite
at 298.15 K is from Krupka, K.M., Robie, R.A., and Hemingway, B.S.
(1979 Amer. Mineral., p. 86) and from Hemingway, B.S., Robie, R.A.
and Kittrick, J.A. (1978 Geochim. Cosmochim. Acta, p. 1533).
The enthalpy of formation of anorthite is based upon the heat of
solution of synthetic anorthite from Kracek (reference 148) rather
than the heat of solution for anorthite reported by Barany
(reference 9). The sample used by Barany contained 2 per cent by
weight of impurities. The corrections made by Barany were probably
in error for the titanium impurity (see reference 122) and for the
sodium feldspar impurity (see Kracek, F.C. and Neuvonen, K.J.,
1952, Amer. Jour. Sci., Bowen Volume) by -8.4 kJ/mol, indicating
a greater stability for anorthite than that obtained from the data
of Kracek and from the recent data of Charlu, T.V., Newten, R.C.
and Kleppa, O.J. (1978 Geochim. Cosmochim. Acta, p. 367).
The enthalpy of formation of grossular, Ca-Al pyroxene, and glass
of anorthite composition are based upon the enthalpy of formation
choosen for anorthite.
INDEX
OF
NAMES
447
Page
Acanthite
(argentite)
Akermanite
Bromargyrite
23,269
27,357,358
Bromellite
18,143
Alabandite
17,129
Altaite
Aluminum
Aluminum sulfate
Bromide ion
12
17
Bromine
12, 39
12, 31
Brucite
20,185
Bunsenite
20,199
Aluminum ion .
Aluminum oxide
Page
16,121
12
18,137,138
25,318
Ca-Al pyroxene 28,377,378
Aluminum trifluoride
24,290
Cadmium
Alunite
26,324
Cadmium ion
Ammonia
16. 120
Calcite 24,302,303
25,315
Calcium
Ammonium bisulfate
26,327
Calcium ferrite
Ammonia-niter
Ammonium ion
Analbite
29,412,413
Analcime
Anatase
Andalusite
16
29
22,233
27,341,342
Calcium nitrate
23
12,
40
25,320
Carbon dioxide
Arcanite
15, 96
24,300,301
18,148
Anhydrite
Aragonite
Carbon monoxide
18,147
18,146
Carbonate ion
18
Carbonic acid
18
(aqueous)
26,322
Cassiterite
Argon
12, 32
Celestite
Arsenic
12,
33
Cerianite
Arsenolite
Azurite
18
Cerium
25
Cerium ions
25
Cerium sesquioxide
Cerussite
21,224
26
18,150
Artinite
12
27,349,350
Calcium oxide
Carbon
Antimony
23,251
25,312
Calcium olivine
26,329
28,395,396
Calcium ion
Calomel
12
12. 4 2
Anglesite
Anorthite
12, 43
12,
44
12
18,151,152
25
Baddeleyite 22,249
Cesium
13, 48
Barite
25,319
Cesium hydroxide
19,155
Barium
12,
36
Cesium ion
Barium ion
12
Chalcanthite 26
18,142
Chalcocite
Berlinite
Barium oxide
26,331
Chalcocyanite
Beryllium
12,
13
17,122
25
Chalcopyrite
17,123
Beryllium ion 12
Chlorargyrite
23,273
Beryllium oxide
Chloride ion
37
18,143,144
12
Bianchite
26
Chlorine
12, 45
Bicarbonate ion
18
Chloromagnesite
24,279
Bismite
18,145
Chromite
23,256
Bismuth
12, 38
Chromium
13, 47
Bismuthinite
16
Chromium ion
Bisulfide ion
17
Chrysoberyl . 22
13
Bixbyite 20,188
Chrysotile
Boehmite 18,139
Cinnabar
29,425,426
Borax 26
Claudetite 18
17
Boric oxide 18,141
Clausthalite 17
Bornite
17,124
Clinoenstatite 28,387,388
Boron
12, 35
Cobalt 13, 46
Brochantite 26
Cobalt ions
13
448
INDEX
OF
NAMES
Page
Page
Cobalt spinel
23,255
Ferric ion
Cobaltous oxide
18,153
Ferric sulfate 26,321
Coccinite
24,297
Ferroselite 17
Coesite
21,219
Ferrous ion 13
Cohenite
16,119
Ferrous oxide
19,164
17
Fluorapatite
27,335
Cooper~te
13
Copper 13, 49
Fluoride ion
Cordierite 28,367,368
Fluorine 13, 53
18,137
Fluorite 24,291
Corundum
Cotunnite 24,284
Covellite
17
21,217
Cryolite 24,294
Cristobalite
13
Fluorphlogopite 29,420
Forsterite
28,363,364
Frohbergite
17
13
Gadolinium 13, 56
Cuprite 19,157
Gadolinium sesquioxide 19,168,169
Cupric ion
Cuprous ion
13
CaA1 2 si 2 o8 glass 28,397,398
Galena
17,132
Gallium 13,
55
Gallium sesquioxide ;. 19,167

Dawsonite
Dehydrated analcite
25
29,409
Gehlenite
27,351,352
Geikelite 23,266,267
Diamond 12, 41
Germanium
Diaspore 18
Germanium dioxide
19,170
Germanium dioxide glass
19,171
Dicalcium ferrite
23,252
Dicesium monoxide
Dicesium uranate
19
27,336
13. 57
Gibbsite 18,140
Goethite
19
Dickite 29
Gold 12, 34
Dilithium monoxide 20,181
Gosiarite 26
20,197
Greenockite 16
28,379,380
Grossular 27,353,354
19,177
Dirhenium heptoxide ~ 21
Gypsum 25
Diniobium pentoxide
Diopside
Dipotassium monoxide
Disodium monoxide
20,193
Disodium uranate 27,337
Hafnia
19,174
Hafnium 13, 60
Ditantalum pentoxide 21,226
Halite 24,282
Dititanium trioxide 22,234
Halloysite 29
Divanadium pentoxide
22,243
Hauerite 17
Divanadium tetroxide
22,242
Hausmannite ~ 20,189
Dolomite 24,304,305
Heazlewoodite 17
Dysprosium 13, 50
Helium 13, 59
Dysprosium sesquioxide 19,158
Hematite 19,165
Epsomite 26
Herzenbergite 17,133
Erbium 13, 51
Hexagonal anorthite 28
Erbium sesquioxide 19,159
High sanidine
Eskolaite 18,154
Holmium 14, 62
Hercynite 23
28,401,402
Eucryptite 28,385,386
Holmium sesquioxide 19,176
Europium 13, 52
Huebnerite 27
Europium oxide 19,160
Huntite 25
Europium sesquioxide 19,161,162
Hydrogen 13, 58
Hydrogen chloride 23,277
Fayalite 27,361,362
Hydrogen ion 13
27
Hydrogen sulfide 17,128
Ferberite
INDEX
OF
NAMES
449
Page
Page
Hydromagnesite 25
Manganosite 20,186
Hydrophilite 23,274
Marcasite 17,127
Hydroxide ion 19
Mascagnite 26,326
Hydroxyapatite 26,334
Massicot 21,206
Melanterite 26
Illite 29
Mercuric ion 13
Ilmenite 23,257,258
Mercurous ion
Indium
Mercury 13, 61
14, 64
13
Iodargyrite 24,296
Merwinite 27,355,356
Iodide ion 14
Metacinnabar 17
Iodine 14, 63
Methane 16,118
Iridium
14, 65
Microcline 28,399,400
Iron 13, 54
Millerite 17,131
Minium 21,209
Jadeite 2 8, 3 91 , 3 9 2
Mira b i 1 it e 2 6
Kaliophillite 28,405,406
Molybdenum 14, 73
Molybdenite 17,130
Kaolinite 29
Molybdenum dioxide 20,190
Karelianite 22,241
Molybdite 20,191
KA1Si
o
glass 28,403,404
3 8
Krypton 14, 67
Molysite 23,276
Kyanite 27,339,340
Monteponite 18
Lanthanum
Montroydite 19,175
Monohydrocalcite 24
Mont icelli te 2 7
14, 68
Lanthanum sesquioxide 20,180
Morenosite 26
Larnite (bredigite) 27,347,348
Mullite 27,345,346
Lawrencite 23,275
Muscovite
29,418,419
Lawsonite 27
Lead 15, 83
Neodymium 14, 77
Lead ion 15
Neodymium sesquioxide 20,198
Lead monoxide 21,207
Neon 14, 78
Leonhardite 28
Nepheline 29,416,417
Leucite 29,407,408
Nesquehonite 25
Litharge 20,205
Nickel 14, 79
Lithium
14, 69
Nickel chloride 24,283
Lithium aluminate
23,261
Nickelous ion 14
Lithium hydroxide 20,182
Niobium 14, 76
Lithium ion 14
Niobium dioxide 20,196
Low albite 29,410,411
Niobium monoxide 20,195
Lutetium
14, 70
Niter 25,313
Lutetium sesquioxide
20,183
Nitrate ion 20
Magnesioferrite 23,265
Nitrogen 14, 74
Magnesite 25,306,307
Nitrogen dioxide
Magnesium
NaA1Si
25,311
Nitrobarite
14, 71
3 8
20,192
glass 29,414,415
Magnesium ion 14
Magnesium nitrate 25,314
Oldhamite 16
Magnetite 19,166
Orpiment 16
Malachite 25
Orthophosphoric acid 20,203,204
Manganese 14, 72
Osmium 14, 81
Manganese ion 14
Otavite . 25
Manganese sulfate 26,325
Oxygen 14, 80
INDEX
450
OF
NAMES
Page
Page
Sanmartinite . 27
Palladium
15, 84
Periclase
20,184
Scandium 15,97
23,253,254
Scandium sesquioxide 21,214
Phenacite 27
Scheelite . 27
Phlogopite
29
Selenium . 15, 98
Phosphate ion 20
Selenium ion 15
Perovskite
Scacchite 24,280
Phosphorus 14, 82
Sellaite 24,292
Phosphorus monoxide
20,200
Siderite ~ 25
Phosphorus pentoxide 20,201,202
Silica glass 21,221
Picrochromite 23,263,264
Silicic acid (aqueous)
Platinum 15, 86
Silicon
21
Plattnerite o
21,208
Silicon monoxide o 21,215
15, 99
Plutonium o
15, 87
Sillimanite 27,343,344
Portlandite
18,149
Silver
Potassium o.
14, 66
Silver ion
o o .
12, 30
12
Potassium aluminum sulfate 26,323
Smithsonite o 25
Potassium bromide o
23,270
Soda niter o 25,316
Potassium hydroxide
19,179
Sodium
Potassium ion
Potassium superoxide
19,178
Powellite o
Praseodymium
14
27
15, 85
Praseodymium oxide 21,211
14,
75
Sodium hydroxide o 20,194

Sodium ion 14
Sphalerite 17,135
Spinel
Spodumene o
23,262
28,381-384
Praseodymium sesquioxide 21,210
Stannic sulfide o
Pseudobrookite
Steam 19,173
Pseudowollastonite
23,260
28,375,376
Stibnite
17,134
17
Pyrite o 17,126
Stishovite 21,220
Pyrolusite o. o o 20,187
Stolzite 27
Pyrope . . . . . . . . . . . . . . . .
28,365,366
Strengite 27
Pyrophyllite
29,423,424
Strontianite
Pyrrhotite o
17
25,309,310
Strontium 15,102
Strontium bromide 23,271
Quartz 21,216
Strontium ion
Strontium nitrate
15
25,317
Radon . . . . . . . . . . . . . . . . . . . . . . 15, 91
Strontium oxide 21,225
Realgar . . . . . . . . . . . . . . . . . . . . . . . .
16
Sulfate ion
Retgersite
26
Sulfide ion 15
Rhenium
Rhenium dioxide
15, 89
Sulfite ion
21
Sulfur
Rhenium trioxide
oo
21
21
15, 93- 95
21
Sulfur dioxide oo
21,212
Rhodium oooo 15,90
Sulfur trioxide
21,213
Rhodochrosite
25,308
Sulfuric acid . . . . . 26
28,389,390
Sylvite 24,278
Rhodonite
Rubidium 15, 88
Szomolnokite
26
Rubidium ion 15
Ruthenium
15, 92
Rutile . . . . . . . . . . . . . . . . . . . . . 22,232
Talc
29,421,422
Tantalum ooooo
15,103
Tellurite . 22
~alammoniac
24,281
Tellurium 15,105
15,100
Tenorite 19,156
21,222,223
Tephroite 28,369,370
Samarium
Samarium sesquioxide
INDEX
OF
NAMES
451
Page
Page
15,104
Uranium trichloride 24,286
Terbium oxide 22,228,229
Uranium trioxide 22,239
Terbium
Terbium sesquioxide 22,227

Tetratitanium heptoxide 22,236
Valentinite 21
Thallium 16,108
Vanadium
Thenardite 26,328
Vanadium dichloride 24,288
Thorianite 22,230
Vanadium monoxide 22,240
Thorium
16,106
Vanadium trichloride 24,289
Thulium
16' 109
Vaterite 24
ThQlium sesquioxide 22,237
Villiaumite 24,293
16,111
Tialite 22,250
Tin 15,101
Water 19,172
Titanite (sphene)
27,359,360
Whitlockite 26,332,333
Titanium 16,107
Willemite 28
Titanium oxide 22,231
Witherite
24,298,299
Titanium tribromide 23,272
Wollastonite
28,373,374
Titanium trichloride 24,285
Wulfenite 27
Titanomagnetite 23,259
Wurtzite 18,136
Tremolite
Wustite 19,163
28,393,394
Trevorite 23
Tridymite 21,218
Xenon 16,113
Trisodium uranium oxide 27,338

16,115
Trititanium pentoxide 22,235
Ytterbium
Troilite 17,125
Ytterbium sesquioxide 22,247
Tungsten 16,112
Yttrium 16,114
Tungsten dioxide 22,244
Yttrium sesquioxide 22,246
Tungsten trioxide 22,245

Tungstenite 17
Zinc 16,116
Zinc ion 16
Uraninite 22,238
Zinc titanium spinel 23,268
Uranium
16,110
Zincite , 22,248
Urnium ions 16
Zinkosite 26,330
2 4, 2 8 7
Zircon 2 8, 3 71, 3 7 2
Uranium tetrafluoride 24,295
Zirconium 16,117
Uranium tetrachloride
452
INDEX
OF
FORMULAS
Page
Page
Ag
12,
30
Ag +
12
Ca 12, 4 2
Ca ++
12
AgBr
23,269
Ca(N0 3 ) 2 25,312
AgCl
23,273
Ca(OH)
Agl
2 4, 296
Ag S 16, 121
2
Al 12, 31
Al+++ 12
Al (OH)
18, 140
3
24,290
AlF
3
AlO(OH)
AlP0
18,139
26,331
4
(so )
25,318
4 3
Al 2 o 3 18,137,138
Al
3Al 2 o 3 2Si0 2 27,345,346

Al Si0
27,339-344
5
2
Al Si 0 (0H)
29
4
2
2 5
Al Si o
COH)
29,423,424
2
2
4 10
Al Ti0
22,250
2
5
(Al Hg)(Si
Al )o
(0H) 29
7
40
14
2
Ar 12, 32
As
AsS
As o
2 3
As s
2 3
Au
12, 33
16
18
16
Ba
12, 34
12,
35
12, 36
Ba ++
12
Ba(N0 3 ) 2 25,311
Baco
24,298,299
3
BaO 18,142
Baso
4
Be
25,319
12, 37
Be++ 12
BeA1 o
22
2 4
18,143,144
18,149
2
CaA1 2 Si0 6 28,377,378
CaA1 Si o COH) 2 eH 2 0 27
2
2 7
caA1 s1 o 28,395-398
2
2 8
Caco 3 24,300-303
CaC0 eH 0 24
2
3
23,274
2
CaFe o
23,251
2 4
CaF
24,291
2
CaHg(C0 3 )
24,304,305
2
CaHg(Si0 )
28,379,380
3 2
CaHgSi0
27
4
CaHg (c0 ) 4 25
3
3
CaHoO
2 7
4
CaO 18,148
CaC1
CaS
caso
16
25,320
4
CaS0 2H o 25
2
4
CaSi0
28,373-376
3
CaTi0
23,253,254
3
CaTiSi0
27,359,360
5
Cawo
27
4
Ca Al Si0
27,351,352
2
2
7
ca Fe o
23,252
2
2 5
Ca HgSi 0
27,357,358
2 7
2
Ca Hg (Si o
)(0H)
28,393,394
2
2 5
8 22
Ca Si0
27,347-350
4
2
Ca (P0 >2 26,332,333
4
3
Ca Al si o 12 27,353,354
2
3
3
Ca Mg(Si0 )
27,355,356
4 2
3
Ca (P0 ) F 27,335
5
4 3
Ca (P0 ) 0H 26,334
5
4 3
Cd 12, 43
Cd++ 12
BeO
CdC0
Be Si0
27
4
2
Bi 12, 38
CdS
Bi+++ 12
Ce 12, 44
Bi o
18,145
2 3
Bi s
16
Ce +++
Br
Ceo 2
2 3
12
Br
16
12
Ce ++++ . 12
18,150
18,141
Ce 2 o 3 18,151,152
Cl- 12
40,
c1
12, 45
2
Co 13, 46
12,
CH 4
co
39
2
8203
12,
25
3
CdO 18
41
16,118
18,146
Co++ . 13
Co+++ 13
co 2 18' 14 7
CoO
co 3 =
Co
18
o4
18,153
23,255
INDEX
OF
453
FORMULAS
Page
Page
Cr 13, 4 7
FeTi0 3 23,257,258
Cr ++ 13
FeW0
, 27
4
Fe (so )
26,321
2
4 3
Fe o
19,165
2 3
Fe Si0 4 27,361,362
2
Fe Ti0
23,259
2
4
Fe Ti0
, 23,260
2
5
Fe 3 C 16,119
cr o
18,154
2 3
Cs 13, 48
Cs + 13
CsOH 19,155
o 19
2
Cs 2 uo 4 27,336
cs
Cu
13, 49
Cu + 13
Fe o
19,166
3 4
F
13, 53
2
Cu ++ 13
CuFeS 2 17,123
CuO 19,156
CuS
17
Ga 13, 55
Ga o
19,167
2 3
Gd 13, 56
.CuSO
25
4
CuS0 4 5H 2 o 26
Gd o
19,168,169
2 3
Ge , 13, 57
Cu (co ) (OH)
25
2
2
3
Cu 2 o 19,157
Geo 2 19,170,171
17,122
H+ 13
Cu 3 (0H) 2 (co 3 ) 2 25
Cu 4 so 4 (0H) 6 26
HC0 - 18
3
HC 1 2 3, 2 7 7
Cu 2 S
Cu 5 FeS 4
17,124
HS
17
He 13, 59
Dy 13, 50
Hf 13, 60
Dy o
19,158
2 3
Hf0
Er 13, 51
Hg ++
Er o
19,159
2 3
Eu 13, 52
HgCl 23
EuO 19,160
Eu 2 o 3 19,161,162
19,174
2
Hg 13, 61
13
Hgi
. . 24,297
2
HgO 19,175
HgS , 17
Hg ++ 13
2
13
Ho , , , 14, 62
Fe 13, 54
Ho 2 o 3 19,176
Fe++ 13
Fe+++ 13
H 2 0 19,172,173
Fe.
H 2 S 17,128
s 17
877
Fe. 947 o 19,163
Fe(P0 ) 2H 0 27
2
4
FeA1 o
23
2 4
FeC0
25
3
FeC1
23,275
2
FeC1
23,276
3
FeCr o
23,256
2 4
FeO 19,164
FeO(OH)
26
FeS0 H o , 26
4
2
,., 17
2
Fes 2 17,126,127
Fese
FeTe
, ,
H so
4
2
13, 58
26
H Po
20,203,204
3 4
H Si0
, , , 21
4
4
14
In 14, 64
Ir , 14, 65
I 2 14, 63
19
FeS 17,125
FeS0 4 7H 2 0
17
K14,66
K+ , , , , 14
KAl(S0 )
26,323
4 2
KA1Si0
28,405,406
4
KA1S1 o
29,407,408
2 6
KA1Si o
28,399-404
3 8
454
INDEX
OF
FORMULAS
Page
KA1 2 (A1Si 3 o 10 )(0H)
Page
29,418,419
2
KBr . 23,270
Mno
KCl 24,2 78
MnS0 4 . 26,325
KMg 3 (AlSi 3 o 10 )F
29,420
2
KKg 3 (AlSi 3o 10 )(0H) 2 29
KN0 3 25,313
MnSi0
KOH . 19,179
KO 2 . . . . . . . . . . 19, 17 8
Kr 14, 6 7
K2 A1 6 (0H) 12 Cso 4 >4 26,324
K2 0 19,177
K2 so 4 26,322
, 20,187
KnS
17,129
MnS
2
KnWO
28,389,390
3
. . . . . . . . . . . 17
27
4
Kn o
20,188
2 3
Kn s1o
28,369,370
2
4
Kn o
20,189
3 4
Ko 14, 73
Moo 2 20,190
Koo
. 20,191
3
MoS 2 17,130
La 14, 68
La o
20,180
2 3
Li 14,69
Li+
14
NH + , , . , . , 16,120
3
, , 16
NH
LiAl0
23,261
2
LiA1Si0 4 28,385,386
NH Cl , , , , 24,281
4
NH Hso
, , , . 26,327
4
4
(NH 4 ) 2 so 4 26,326
LiA1Si 2 o 6 28,381-384
NH 4 No
LiOH 20,182
,,., , 25,315
3
N0 2 . 20,192
Li o 20,181
2
Lu 14, 70.
N0
Lu o
. . . . . . . . . . . . . . . . . . . . . 20,183
2 3
Na + .'
, 20
3
Na 14, 75
14
NaAl(Si0 3 ) 2 28,391,392
Mg , , , 14, 71
Mg++ , ,
14
, , , , , , , , , , , , , , , , 25
NaAlC0 (OH)
3
2
NaA1Si0 4 29,416,417
Kg(C0 ) 3H o , , 25
2
3
Kg(N0 )
, 25,314
3 2
Mg ( 0 H)
, 2 0, 18 5
2
MgA1 o
, , , , , 23,262
2 4
MgC0 3 ,. 25,306,307
NaA1Si 2 o 6 29,409
MgC1 2 . .,
NaN0
24,279
MgCr 2 o 4 23,263,264
NaA1Si 2 0 6 eH 2 0 29
NaA1Si o 8 29,410-415
3
NaCl , 24,282
NaF , ,, , , , 24,293
, ,, , 25,316
3
NaOH , , , 20,194
MgFe o
2 4
MgF 2 . .
23,265
Na 2 s 4 o 7 10H 2 0 26
24,292
MgO , ,
20,184
Na o 20,193
2
Na so
26,328
2 4
Na so 10H 0 , , 26
2
2 4
Na uo
27,337
2 4
Na A!F
24,294
6
3
Na 3 uo 4 27,338
5Kg04C0 2 5H 2 o 25
MgS0 4 e7H 2 0 ,, ,, 26
MgSi0 3 28,387,388
MgTi0 3 23,266,267
Mg~(OH) 2 co 3 e3H 2 0 25
Kg 2 A1 3 (A1Si 5 o 18 )
28,367,368
Mg 2 s10 4
28,363,364
Kg 3 A1 2 s1 3 o 12 28,365,366
Kg 3 Si 2 o 5 (0H) 4
29,425,426
Nb
, , , , 14, 7 6
NbO , , , , , , 20, 195

Nb0
,,. ., , 20,196
2
Nb o
20,197
2 5
Nd , , , , , , 14, 77
Kn 14,
72
Nd o
20,198
2 3
Ne , , 14, 78
Mn ++
14
Ni
Mg 3 si 4 o 10 (0H) 2 29,421,422
KnC0
Mnc1
, 14, 79
25,308
Ni++ , , ,
24,280
NiC1 2 ;,,. 24,283
2
KnO , , , , , 20,186
NiFe o
, ,
2 4
14
23
INDEX
OF
FORMULAS
Page
455
Page
NiO
20,199
Sb
NiS
17,131
Sb o
21
2 3
Sb 2 s 3 17
N1S0 6H o 26
4
2
NiS0 7H o 26
4
2
N1 3 s 2 17
N
. .
14, 74
15, 96
Sc
Se
OH
19
15, 97
21,214
Sc o
2 3
Se 15, 98
15
Si 15, 99
Os
14, 81
SiO
14,80
Si0
14' 82
PO 20,200
Sm o
21, 21,222
2 3
Sn 15, 101
PO
20
Sno
, 15, 83
SnS
Pb
21,215
21,216-221
2
Sm
15,100
21,224
17,133
Pb++ , , , , ,
15
Sns 2
17,134
PbC0
25
Sr
15,102
PbC1
2
PbMoo
24,284
27
4
PbO 20,205-207
Pb0
21,208
17,132
PbS
PbS0 4 26,329
Sr ++
15
Sr(N0 3 ) 2 25,317
SrBr
23,271
2
SrC0
,, , 25,309,310
3
SrO , 21,225
SrS0
, 26
PbSe 17
PbTe
17
Ta . . . . . . . . . . . . . . . . . . . . . . . . .
PbW0
27
4
Pb o
. . . . . . . . . . . . . . . . . . . . . 21,209
3 4
Pd 15, 84
Ta 2 o 5 21,226
Tb 15,104
Pr
Tbo
. . . . . . . . . . . . . . . . 22,229
1 812
Tb 2 o 3 22,227
, , , ,
Pro
1 833
Pr 2 o 3
Pt
15,85
21,211
21,210
, , 15,
86
, . . . . . . . . . . . . . .
17
PtS
Pu
P 2 o 5
15, 8 7
20,201,202
15,103
Tbo 1 714 22,228
Te
Teo
15,105
22
2
Th 16,106
Th0
, , 22,230
2
Ti . . . . . . . . . . . . . . . . . . . . . . . . . 16,107
TiBr
Rb + , , , , , , , 15
23,272
3
24,285
3
TiO 22,231
Re . . . . . . . . . . . . . . . . . . . . . . . . . . 15, 89
Ti0
Rb , 15, 8 B
TiC1
Rh , , ,
15, 90
22,232,233
2
Ti o
22,234
2 3
Ti o
22,235
3 5
Ti o
22,236
4 7
Tl , , 16,108
Rn
15, 91
Tm
Ru
15, 92
Tm o
22,237
2 3
Reo 2 21
Reo
Re
so
o
2 7
21
21
. . . . . . . . . . . . . . . . . . . . . . 15, 93- 95
so
3
so 3
so 4
16,109
16,110
15
u+++ .
2 1, 2 L 2
u++++ .. 16
uc1
21,213
16
21
24,2.86
3
UC1 4 24,287
Z1
UF 4
24,295
INDEX
456
OF
FORMULAS
Page
uo
uo
22,238
. . . . . . . . . . . . . . . . . . . . . . . . 22,239
Page
y
Yb
16,114
16,115
Yb 0
v 16,111
, , , , , , 24,288
2
, , , , , , , , , 2 2 , 2 4 7
2 3
. ,, ,, ,, 22,246
Y o
2 3
VC1
2 4, 2 8 9
Zn 16,116
vo 22,240
Zn++ . 16
V2 o 3 , , ,, , 22,241
v 2 o 4 .,, 22,242
Znco
v o
, ,, ,, ,,, 22,243
2 5
ZnS 17, 18,135,136
VC 1
, , , , , , , , ,
, , , , , , , 25
3
ZnO ., ,, 22,248
ZnS0
w 16,112
wo
wo
WS
Xe
2
3
22, 2 44
22,245
, .,,,. , , , 1 7

16, 113
, ,, , ,, ,,, 26,330
4
ZnS0 4 6H 2 0 26
Znso 4 7H 2 o 26
, , , , , , , , , , , 28
zn s10
2
4
zn T10
, ,, , , , , 23,2&8
4
2
Zr 16,117
zro
22,249
2
ZrSi0
,, , . 28,371,372
4
i:I U.S. Government Printing Office: 1979-281-359/75

Report PDF

Загружено:

Сведения о документе

Оригинальное название

Авторское право

Доступные форматы

Поделиться этим документом

Поделиться или встроить документ

Параметры публикации

Этот документ был вам полезен?

Это неприемлемый материал?

Авторское право:

Доступные форматы

Report PDF

Загружено:

Авторское право:

Доступные форматы

Thermodynamic Properties

of Minerals and Related

and at Higher Temperatures

A summary of the thermodynamic data for minerals

Reprinted with corrections 1979

UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1978

DEPARTMENT OF THE INTERIOR

U.S. GEOLOGICAL SURVEY

First printing 1978

For sale by the Superintendent of Documents, U.S. Government Printing Office

Thermodynamic properties at 298.15 K -------------------------------------- 12

A. RoBIE, BRUCE S. HEMINGWAY, and jAMES R.

The purpose of these tables of thermodynamic properties is to present

THERMODYNAMIC PROPERTIES OF MINERALS

REFERENCE STATES AND TRANSITIONS

1.-Symbols, constants, a,nd conversion factors

THERMODYNAMIC PROPERTIES OF MINERALS

REFERENCE STATES AND TRANSITIONS

THERMODYNAMIC PROPERTIES OF MINERALS

Also, for an ideal gas,

REFERENCE STATES AND TRANSITIONS

(oxides)={[ -304.53+0]-[ -136.25+2( -91.18)]}= 14.08 kJ

(elements)={[ -5448. 79+( -729.98)]-[ -3488.51 +2( -1352.17)]}

ingless result ensues. If a reaction involves both multiple-oxide phases

tabulating the thermodynamic properties of aqueous ions has been given

Having chosen what we believe are the currently "best available"

THERMODYNAMIC PROPERTIES OF MINERALS

H;!JH>tT = <H~- H;!JH>tT- s~

log Kr:r = - AGor.T/2.30258 RT = - AG r,:z!JJ19.1444T

rounding off again tends to obscure small differences of major importance

THEBIIOD!IlftiC PIIOPIITIIS or ftUIULS

Jae and forula

S1LYIR ( RIPIIIIICI STATE)

lLUft1111ll! ( IIIPIIIICI STATE)

&IGOJ ( RIPIIIIJCI STATE)

AISIIIC (IIPIIIICI ST&TI)

GOLD (RIFIIIICI STATE)

BIOIIIME ( IIBFEBEMCE STAT!)

BROIIIME (IDEAL GAS)

CARBOM ( REFEBEICE STATE)

C&LCIUI! ( BEPBIEICE STATE)

CADII1011 ( IIFEBBICE Sl'&l'B)

CEliO II ( BIPEIEICE ST&l'll)

96.978 2111 2111

13.59.! 2&2 262

117.732 262 262

88.2611 2&2 2&2

&1>.522 2111 2111

CHLOBIIB ( RBPEBBICE Sl'il'IJ

98.2110 :l111 2111

BISIIUTH (RIPER liCE STATE)

BER'ILLIUII ( B!FBRBICE STATE)

B&IIIUft ( BBPBRIICE STAtE)

-------------------------------------- ~---- _:~~~= ~----~~: __ --__:~~:--___ :~~~~------ ---- ---~--~:! __ : f

58. 9Jl -113. (I (I

9.531 263 263

58.933 -lOS. CICI

-21.1176 263 2&J

CHROIIIUII ( BEFEB!JCI!! STATE)

COBALT ( BEFEREIC! STATE)

EBBIUII (REFERENCE STATE)

EUROPIUII (REFERENCE STATE)

FLDORUE ( BEFEREMCE STATE)

-------------------------------------- ~---- _:~~~= ~----: --::--_ :~~~~------ ---- ---~--~:! : f