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a substituent.
CYCLOALKANES
Rule 1.
*SINGLE SUBSTITUENT ON A RING
No need to number its position on
the ring
Rule 2.
Rule 3.
Systematic name of a complex substituent
should be enclosed in parentheses to avoid
possible ambiguities.
COMPLEX SUBSTITUENT PRESENT MORE THAN
ONCE
ALKENES
2 SUBSTITUENTS HAVE SAME LOW
NUMBER
Ring is numberedeither clockwise or
counterclockwisein the direction that gives
the third substituent lowest possible number.
Rule 1.
NAME THE STEM
Find longest chain that includes both
carbons making up the double bond.
NOTE: Molecule may have longer carbon
chains, but ignore them.
Rule 2.
ALKYNES
Rule 1. IUPAC rules for alkenes also apply to
alkynes, the ending -yne replacing -ene.
Rule 6.
NAMING ALKENOLS
The stem incorporating both functions is
numbered to give the carbon bearing the OH
group the lowest possible assignment.
Note: last e in alkene is dropped in
naming of alkenols
Rule 3.
ALKENYNES
hydrocarbons containing both double and triple bonds
Rule 4.
ALKYNOLS
Alkynes incorporating hydroxy function are
named alkynols. OH group takes precedence
over both double and triple bonds in the
numbering of a chain
Note: omission of the final e of -ene in
-enyne and of -yne in -ynol.
NOTE:
Alkenes and alkynes rank below amines in order
of precedence. But, when a carbon carbon
double or triple bond is part of the parent chain or
ring of a molecule:
Insert -en(e)- or -yn(e)- just before the
suffix for the highest-ranking functional
group.
CARBOXYLIC
ACIDS
Rule 1. Replace ending e in
by -oic acid.
alkane
by
BENZOIC ACIDS
DICARBOXYLIC SYSTEMS
Dicarboxylic systems are labeled alkanedioic
acids.
ALDEHYDES
Rule 1. Replace ending -e of alkane by -al. An
alkane thus becomes an alkanal.
Rule 2.
For historical reasons, simpler aldehydes often
retain their common names. These names are
derived from the common name of the
corresponding carboxylic acid, with the ending
ic or -oic acid replaced by -aldehyde,
ALCOHOLS
Rule 3.
CARBALDEHYDES
NOTE:
Instead
of
benzenecarbaldehyde,
benzaldehyde is more widely used.
Rule 1.
Replace ending -e of the alkane is replaced by
-ol.
Rule 2.
In more complicated branched systems, name of
alcohol is based on longest chain containing the
OH substituent not necessarily the longest
chain in the molecule.
Rule 3. To locate positions along the chain,
number each carbon atom beginning from end
closest to the OH group.
KETONES
Rule 5.
CYCLOALKANOLS
cyclic alcohols
Carbon carrying the functional group automatically
receives number 1.
AMINES
MONOSUBSTITUTED BENZENES
Rule 1. Some monosubstituted benzenes are named
that
is,
as
alkanamines.
The name of the alkane stem is modified by
replacing the ending -e by -amine. The position
of the functional group is indicated by a prefix
designating the carbon atom to which it is
attached, as in the alcohols.
Rule 2. BENZENAMINES
The aromatic amines, or anilines, are
called benzenamines.
For secondary and tertiary amines, the
largest alkyl substituent on nitrogen is chosen as
the alkanamine stem, and the other groups are
named by using the letter N-, followed by the
name of the additional substituent(s).
AVECC