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08.11.2005
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08.11.2005
tion
a
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p
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30 yea slurry
w it h
ck
o
t
s
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e
f
Steam
Cooling Water
O2
Feed B
Quench
Water
Feed A
O2 + Steam
Feed
Gas-offtake
Soot Slurry
08.11.2005
Feedstock Flexibility
No limitations on Flash Point of
Feedstock
Viscosity up to 300 cSt
Particles up to 1 mm
Life Time of Burner
Higher Reliability and Availability
Quench
Water
Oxidant
(O2 Air)
Steam
Burner
Oxidant
(O2 Air)
Steam
Feed
Feed
Syngas
Syngas
Heat
Recovery
Boiler
Soot Slurry
Boiler Configuration
Quench Configuration
6
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Quench Configuration
Feedstock flexibility
HP-Steam available
highest thermal efficiency
MP-steam available
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500 kg/h
500 m3/h
(0.5 MMSCFD)
Reactor:
Operating Pressure
100 bar
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Liquid
Feeds
Storage
Natural
Gas
Compressor
Liquid O2
Pump and
Vaporizier
Flue Gas
Steam
Generator
Desulphurisation
Reactor
Soot Water
Cooler
Nitrogen
Supply
10
Instrument Air
Supply
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Measuring
Station
Power Supply
Flare System
Fresh
water
Soot Water
Analytical
Area
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Feedstock:
Residue Asphalt
C/H-Ratio
970 t/d
8.8 kg/kg
Ash Content
0.04 wt%
Viscosity at 180C
360 cSt
Viscosity at 290C
20 cSt
Flash Point
170 C
Products:
Ammonia
Equivalent H2
Urea
12
1350 t/d
113 000 Nm3/h
(100 MMSCFD)
2000 t/d
08.11.2005
Air
Air
Separation
HP-Steam
Boiler
Refrigeration
Unit
Pure
Hydrogen
O2
Liquid
Ammonia
HP-Steam
Feed
13
Gasification
+ WHB
Rectisol
H2S Removal
Carbon
Recovery
Claus Unit
Sulfur
CO-Shift
Rectisol
CO2 Removal
Pure CO2
Liquid
N2 Wash
NH3
Synthesis
Urea
Synthesis
Urea
Rectisol
Turbine Gas
Raw Syngas
Purisol
Pipeline Gas
Pure Off-Gas
aMDEA
Off-Gas
MDEA / DEA
Others
14
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Tail Gas
Treating
Sulphur
15
0.1 - 1
ppm
H2S + COS
10 - 50
ppm
CO2
Purisol
5 - 50
ppm
MDEA
3 - 50
ppm
aMDEA
1- 50
ppm
H2S
5 - 50
ppm
CO2
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Pure
Impure
CO2
CO2
Steam
MPG
Quench
Raw Gas
Shift
Gas
Cooling
O2
Selective
Rectisol
AGR
Low
HighBTU
BTU
S>
100Sulfur
ppm
Low
Fuel
FuelGas
Gas
97%
Hydrogen
Metha- Hydrogen
PSA
nation
H2S+CO2
Sulphur
O2
Carbon
Slurry
16
ASU
MARS
Air
Metals/Ash
OxyClaus
Waste Water
Treatment
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Process Water
2. Deep Desulfurization
4. CO2 purification
one Rectisol compares with five tasks to be performed in five processes steps
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08.11.2005
Trace Contaminants
Its the small bugs that can bother you most!
COS
Hg
VOCs
NH3
Carbonyls
CS2
HCN
Mercaptans
Wilhelm Busch
18
08.11.2005
Pure IGCC
M io N m 3/day ex G as ifiers
300
Others
250
Rectisol
200
150
100
50
0
1960
90 % of synthesis gas
produced by gasification
(non-IGCC use)
1965
1970
1975
1980
1985
1990
1995
2000
2005
08.11.2005
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08.11.2005
? Comments ?
Contact :
Ulrich Koss
Head Syngas Technology
Dept. A-TE
Phone
+49 69 5808 3740
Fax
+49 69 5808 2645
e-mail
ulrich_koss@lurgi.de
Dept. A-TEE
Phone
+49 69 5808 1418
Fax
+49 69 5808 2645
e-mail
dr_holger_schlichting@lurgi.de
Lurgi AG
D-60295 Frankfurt am Main
Germany
Internet: www.lurgi.de
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