CTEH Bakken Crude Burn

Bakken Crude Oil Burn Demonstration
Air Monitoring and Sampling Report

Prepared for:
Beaumont, TX
November 11, 2014
CTEH Project# 106829
January 16, 2014
Table of Contents
Executive Summary....................................................................................................................................... 1
1.0
Introduction .................................................................................................................................. 2
2.0
Chemicals of Interest .................................................................................................................... 3
3.0
Air Sampling and Monitoring Strategy .......................................................................................... 4
3.1
Real-Time Air Monitoring .............................................................................................................. 4
3.2
Analytical Air Sampling.................................................................................................................. 5
3.3
Personal Air Sampling ................................................................................................................... 5
4.0
Results ........................................................................................................................................... 6
4.1
Real-Time Results .......................................................................................................................... 6
4.2
Analytical Air Sampling Results ..................................................................................................... 8
4.3
Personal Air Sampling Results ....................................................................................................... 9
5.0
Discussion...................................................................................................................................... 9
5.1
Real-Time Air Monitoring Discussion .......................................................................................... 10
5.2
Analytical Air Sampling Discussion .............................................................................................. 10
5.3
Personal Sampling Results Discussion ........................................................................................ 12
6.0
Conclusion ................................................................................................................................... 12
List of Tables
Table 4.1.1 Summary of Radio-Telemetering AreaRAE Data ....................................................................... 6
Table 4.1.2 Summary of Data-Logged Particulate Monitoring (PM10) Data ................................................ 7
Table 4.1.3 Summary of Real-Time Hand-Held Air Monitoring Data ........................................................... 7
Table 4.2.1 Summary of Fixed Location Analytical Air Sampling Stations ................................................... 8
Table 4.2.2 Summary of Downwind Grab Sampling Results ........................................................................ 8
Table 4.3.1 Personnel Air Sampling ............................................................................................................. 9
Page | i
List of Appendices
Appendix A ................................................................................................................... Bakken Crude Oil SDS

Appendix B ............................................................................................. Exposure Standards and Guidelines
Appendix C ...................................................................................... Bakken Crude Oil Hydrocarbon Analysis
Appendix D ..................................................................................................... Air Sampling and Analysis Plan
Appendix E .................................................................................................................... Demonstration Maps
Appendix F ............................................................................................................................. AreaRAE Charts
Appendix G ............................................................................................................ Galson Laboratory Report
Page | ii
Executive Summary
On November 11, 2014, Center for Toxicology and Environmental Health (CTEH) conducted real-time
air monitoring and analytical air sampling in support of a controlled Bakken crude oil burn
demonstration in Beaumont, TX performed in conjunction with Williams Fire and Hazard Control. To
support this demonstration, members of the CTEH Toxicology Emergency Response Program (TERP)
arrived on site at 0900 on November 11, 2014, and approximately 1 hr. later, initiated air monitoring
and air sampling within the confines of the Beaumont Emergency Service Training (B.E.S.T.) facility in
accordance with the Air Sampling and Analysis Plan (SAP) developed prior to the demonstration. The
demonstration involved two controlled burns, each approximately 6-8 minutes in duration, followed by
rapid extinguishment by Williams Fire and Hazard Control personnel.
Throughout the duration of the demonstration, CTEH conducted real-time air monitoring using
chemical-specific colorimetric detector tubes, RAE Systems MultiRAE and UltraRAE instruments, SidePak
AM510s and radio-telemetering AreaRAE instruments. Real-time air monitoring was conducted for
volatile organic compounds (VOCs), percent lower explosive limit (LEL), benzene, carbon monoxide (CO),
nitrogen dioxide (NO2), sulfur dioxide (SO2), hydrogen sulfide (H2S), and particulate matter (as PM10).
While detections of VOCs and particulate matter were observed during the demonstration, no
detections above the site-specific action levels outlined in the Air SAP were observed.
To supplement real-time air monitoring efforts, CTEH collected integrated analytical air samples for
volatile organic compounds (VOCs) and polynuclear aromatic hydrocarbons (PAHs) in addition to
instantaneous (i.e. grab) samples for VOCs directly within the vicinity of the demonstration area. While
no PAH detections were observed, a number of light hydrocarbons were detected downwind of the
petroleum reservoir at concentration below the Texas Commission on Environmental Qualitys (TCEQ)
Short Term Air Monitoring Comparison Values. Additionally, two analytical VOC grab samples were
collected in the headspace of the crude oil tanker truck to characterize the concentration of crude oilassociated compounds that had volatile from the product. While a number of volatile hydrocarbons
were observed, a comparison of the analytes concentration to its respective Critical Health Protective
Value (CHPV) highlighted the relative importance of monitoring for benzene and hexane during
situations involving crude oil spills or releases. In this regards, personal air samples collected on Williams
Fire & Hazard Control personnel to assess the potential for exposure to benzene, toluene, ethylbenzene,
xylene (BTEX), n-hexane, and aldehydes yielded detections of only three analytes (benzene, toluene and
hexane). However, after adjustment for the period of exposure (100 minutes of an 8-hr work shift), no
exceedences of occupational exposure guidelines were observed.
The CTEH TERP team demobilized from the B.E.S.T. facility following the conclusion of the
demonstration at approximately 1230.
Page | 1
1.0
Introduction
On November 11, 2014, Center for Toxicology and Environmental Health (CTEH) conducted real-time
air monitoring and analytical air sampling in support of a controlled Bakken crude oil burn
demonstration in Beaumont, TX performed in conjunction with Williams Fire and Hazard Control. To
support this demonstration, members of the CTEH Toxicology Emergency Response Program (TERP)
arrived on site at 0900 on November 11, 2014, and approximately 1 hr. later, initiated air monitoring
and air sampling within the confines of the Beaumont Emergency Service Training (B.E.S.T.) facility. At
the time that CTEH arrived on site, the Bakken crude oil was in the process of being offloaded from a
tanker truck into an approximately 40 ft. diameter petroleum storage reservoir (Figure 1). The
demonstration involved two controlled burns, each approximately 6-8 minutes in duration, followed by
rapid extinguishment by Williams Fire and Hazard Control personnel.
Prior to and during the controlled burn events, CTEH personnel conducted real-time air monitoring for
crude oil-associated compounds in addition to crude oil combustion products using hand-held and radiotelemetering instruments within the Work Area. For the purposes of this demonstration, the Work Area
was defined as any location within the confines of the B.E.S.T. Facility, with specific emphasis placed on
those locations downwind of the petroleum storage reservoir and at the positions where demonstration
participants were staged. Hand-held instruments were utilized at these selected locations to assess
ambient concentrations of volatile organic compounds (VOCs), benzene, carbon monoxide (CO),
nitrogen dioxide (NO2), sulfur dioxide (SO2), hydrogen sulfide (H2S), and particulate matter (as PM10).
Radio-telemetering AreaRAE instruments were positioned at four locations surrounding the crude oil
reservoir to monitoring for VOCs and lower explosive limit (LEL) prior to and during both controlled burn
events.
To support air monitoring efforts, CTEH also conducted analytical air sampling throughout the
demonstration. As such, fixed integrated air sampling stations sampling for VOCs and polynuclear
aromatic hydrocarbons (PAHs) were established at 3 locations; one upwind and two downwind.
Sampling at these three analytical stations began prior to the first controlled burn and ceased after the
conclusion of the second controlled burn. Additionally, analytical VOC grab samples were collected in
the headspace of the crude oil tanker truck, downwind of the petroleum reservoir prior to the burn, and
downwind of the petroleum reservoir but underneath the majority of the smoke during the burn to
document and characterize the concentration of crude oil associated compounds, if any, present within
the breathing zone in ambient air. Analytical air samples were sent to AIHA-accredited Galson
Laboratories who voluntarily provided air sample analysis for this demonstration.
Lastly, in an effort to assess the potential for worker exposure, if any, to benzene, toluene,
ethylbenzene, xylene (BTEX), n-hexane, and aldehydes as a result of the demonstration, CTEH collected
passive air samples on two Williams Fire and Hazard Control personnel. One of these individuals was
Page | 2
involved in the offloading of crude oil from the tanker to the petroleum reservoir while the other
individual was involved in fire-fighting operations only.
Following the conclusion of the demonstration at 1230 on November 11, 2014, the CTEH TERP team
demobilized from the B.E.S.T. facility.
Figure 1
2.0
Location of B.E.S.T. Facility
Chemicals of Interest
As provided by Williams Fire and Hazard Control, the product burned during the demonstration was a
crude oil originating from the Bakken Shale. The product Safety Data Sheet (SDS) is available as
Appendix A. Crude oil is a complex mixture of hydrocarbons utilized as petroleum refining or chemical
manufacturing feedstock whose chemical constituents can vary depending upon the geographical areas
from which the oil is extracted. As a mixture, crude oil does not have established occupational exposure
levels; however, individual components of this mixture, e.g. benzene, are relatively volatile and may
have appreciably low occupational exposure limits due to the chronic or long-term effects of exposure
Page | 3
and, as such, require specific attention. Hence, benzene and to a lesser extent hexane and hydrogen
sulfide were also selected as chemicals of interest from a real-time air monitoring perspective.
Because the demonstration also involved brief periods of intentional crude oil burning, the products of
crude oil combustion including carbon monoxide (CO), sulfur dioxide (SO2), nitrogen dioxide (NO2),
formaldehyde and particulate matter (as PM10) were also targeted via real-time air monitoring efforts
alongside atmospheric flammability, as percentage of the lower explosive limit (LEL). Detailed
descriptions of occupational exposure standards and guidelines, for the above mentioned compounds,
are provided in Appendix B.
Additionally, a suite of volatile organic compounds (as identified in the SAP) that were determined to
have the greatest potential for human health impact based on the relative levels in air emitted from
fresh crude oil were also selected along with aldehydes (e.g. formaldehyde) and polynuclear aromatic
hydrocarbons (crude oil combustion products) as potential chemicals of interest from an analytical
perspective.
In an effort to fully characterize the product, a sample of this very dark hydrocarbon product was
collected by CTEH from the oil transportation tanker during offloading and a detailed hydrocarbon
analysis was performed using Method GPA-2196 (PIANO Method). As reported by SPL labs, the crude oil
hydrocarbon composition was highly variable (C2 C29) and with a major hydrocarbon range on the light
end (C5 C12). Selected constitutes examined included, but was not limited to, benzene (0.447 wt. %),
ethyl benzene (0.254 wt. %), toluene (1.148 wt. %), xylene (1.684 wt. %), and hexanes (3.243 wt. %). The
full detailed hydrocarbon analysis is provided in Appendix C.
3.0
Air Sampling and Monitoring Strategy
A preliminary air Sampling and Analysis Plan (SAP; Appendix D) was developed based on the information
provided by Williams Fire and Hazard Control prior to the demonstration. The SAP includes details of the
air monitoring and sampling methods, instrumentation, and site-specific action levels. Real-time air
monitoring, analytical air sampling and personal exposure sampling were conducted to demonstrate
CTEHs capabilities to provide information regarding the potential for chemical exposures within the
Work Area. The strategies surrounding the use of these techniques are outlined in Sections 3.1 3.3,
below.
3.1
Real-Time Air Monitoring
CTEH conducted real-time air monitoring for the chemicals of interest using hand-held instruments
(RAE Systems MultiRAE and UltraRAE instruments, Gastec colorimetric detector tubes, and SidePak
AM510s) and radio-telemetering AreaRAE instruments. Hand-held instruments were used to record the
ambient concentrations of chemicals of interest within the breathing zone at locations surrounding the
petroleum storage reservoir, with specific emphasis placed on those locations downwind of the
Page | 4
petroleum storage reservoir and at the positions where demonstration participants were staged.
Additionally, four AreaRAE air monitoring stations were established at locations surrounding the
petroleum reservoir in an effort to assess airborne concentration of VOCs and LEL. Readings collected on
AreaRAE instruments were periodically reviewed by CTEH personnel at a nearby location. This allowed
for rapid recognition, communication, and response to changing conditions should any abnormalities or
action level exceedences have been noted. Lastly, SidePak AM510 Instruments were deployed alongside
three of the four AreaRAE instruments and analytical sampling stations to assess the concentrations of
particulate matter, if any, present in the air as a result of the controlled crude oil burn. These
instruments were set to record particulate matter concentrations every 15 seconds or 1 minute and
their data was retrieved at the conclusion of the demonstration. Maps identifying the locations of realtime hand-held air monitoring readings in addition to AreaRAE and AM510 monitoring locations are
provided in Appendix E.
3.2
Analytical Air Sampling
To supplement real-time air monitoring efforts, CTEH collected both instantaneous (i.e. grab) and
integrated analytical air samples in the vicinity of the demonstration area. Three fixed analytical air
sampling stations were established: one upwind and two downwind of the petroleum reservoir. A map
of these fixed analytical air sampling stations is provided in Appendix E. At each of these fixed analytical
air sampling stations, air was sampled throughout the entire duration of the demonstration for VOCs
and PNAHs by USEPA Method TO-15 and NIOSH Method 5506, respectively. In addition to these
analytical air sampling stations, grab air samples1 were also collected and analyzed for VOCs in the
headspace of the crude oil tanker truck, downwind of the petroleum reservoir prior to the burn, and
downwind of the petroleum reservoir but underneath the majority of the smoke during the burn to
document and characterize the concentration of crude oil associated compounds, if any, present in the
ambient air. With the exception of the headspace samples from the crude oil tanker truck, the grab
samples were collected from within the breathing zone to represent the potential for exposure, if any,
to crude-oil associated vapors and combustion products.
3.3
Personal Air Sampling
Lastly, CTEH collected personal air samples on two individuals with potential for exposure to crude oilassociated compounds as a result of their participation in the demonstration. One of these individuals
was involved in the offloading of crude oil from the tanker to the petroleum reservoir (while wearing a
supplied air respirator) while the other individual was involved in fire-fighting operations only. CTEH
outfitted both individuals with a 3M OVM 3520 personal badge and an Assay 571 personal badge to
A grab sample is a sample of air that is collected at a particular time and place to characterize the environment at that particular location only
at that particular time and place.
Page | 5
assess their exposure to benzene, ethyl benzene, toluene, xylene, hexane, and aldehydes. These badges
were placed in the workers breathing zone for the duration of the demonstration (approximately 100
minutes). Following collection, OVM 3520 and Assay 571 badges were sent to Galson Laboratories for
analysis via NIOSH Method 1501 and OSHA Method 1007, respectively.
4.0
Results
4.1
Real-Time Results
Table 4.1.1 summarizes data recorded by the deployed AreaRAEs on November 11, 2014. Four AreaRAE
stations were established at locations surrounding the petroleum reservoir. The locations of AreaRAEs
are displayed on the demonstration map in Appendix E. Graphs of AreaRAE data and working
timeframes are provided in Appendix F. Table 4.1.2 and Table 4.1.3 summarize the data-logged
particulate matter monitoring data and real-time hand-held data for readings collected within the Work
Area, respectively. The locations of these particulate monitoring stations and real-time hand-held air
monitoring readings can be found in maps provided in Appendix E.
Table 4.1.1
Unit
AR01
AR02
AR03
AR04
Summary of Radio-Telemetering AreaRAE Data*

**
Analyte
Number of Readings
Number of Detections
LEL
558
< 1.0 %
VOC
558
< 0.1 ppm
LEL
558
< 1.0 %
VOC
558
0.1-1.1 ppm
LEL
555
< 1.0 %
VOC
555
76
0.1-21.3 ppm
LEL
556
< 1.0 %
VOC
556
49
0.1-12.8 ppm
Range of Detections
AreaRAE sensors have the potential to show false positive readings due to sensor drift. Sensor drift is defined as interference in the sensors
ability to accurately report the concentration of a chemical in the atmosphere and is often brought about by changes in environmental factors
(e.g. humidity and temperature changes). During response efforts, every effort was made to confirm drift events with a secondary instrument,
i.e. MultiRAE.
**
If no detections were observed, the instrument detection limit is listed in this column.
Page | 6
Summary of Data-Logged Particulate Monitoring (PM10) Data*
Table 4.1.2
Unit
Number of Readings
Avg. Concentration
Range of Detections
AS01
485
485
0.022 mg/m
0.011 - 0.292 mg/m
AS02
0.016 mg/m
0.013 - 0.020 mg/m
AS03
122
122
0.018 mg/m
0.009 - 0.157 mg/m
While both AS01 and AS03 recorded PM10 measurements over a similar time period, AS01 was recording readings every 15 seconds while AS03
was recording readings every one minute. The AM510 instrument at location AS02, while set to data-logging mode at the outset of the
demonstration, failed to record readings during the demonstration.
Table 4.1.3
Summary of Real-Time Hand-Held Air Monitoring Data

*
Analyte
Number of Readings
Range of Detections
Benzene
< 0.05 ppm
Carbon Monoxide
< 1 ppm
Hydrogen Sulfide
< 1 ppm
Nitrogen Dioxide
< 0.1 ppm
PM10
0.006 - 0.023 mg/m3
Sulfur Dioxide
< 0.05 ppm
VOC
24
0.1 - 5.7 ppm
If no detections were observed, the instrument detection limit is listed in this column.
Page | 7
4.2
Analytical Air Sampling Results
Table 4.2.1 summarizes the 1 hour ambient air sampling results of target (e.g. instrument calibrated)
analytes at analytical stations AS01, AS02, and AS03. Table 4.2.2 summarizes the downwind grab
sampling results of target analytes found at grab locations GB03, GB04, and GB05. Table 4.2.3 is a
summary of target analytes found in the headspace grab samples atop the tanker truck offloading crude
for the burn demonstration. A list of those compounds tentatively identified by the laboratory (TICs) in
VOC samples is provided in the Galson Laboratory Report in Appendix G.
Summary of Fixed Location Analytical Air Sampling Stations*
Table 4.2.1
No. of Samples
No. of Detections
Range of Detections
(ppb)
CARBON DISULFIDE
4.2
2,2,4-TRIMETHYLPENTANE
2.6
PROPYLENE
O-XYLENE
3-3.3
ACETONE
250-300
BENZENE
28-39
CYCLOHEXANE
63-89
ETHYLBENZENE
2.7-2.8
HEPTANE
77-110
2,2,4-TRIMETHYLPENTANE
33-83
M,P-XYLENES
9.2-11
PROPYLENE
100-130
TETRACHLOROETHYLENE
2.7
TETRAHYDROFURAN
2.5
TOLUENE
30-36
HEXANE
230-300
Location
Analyte
Upwind
(AS01)
Downwind
(AS02, AS03)
**
Table 4.2.1 is limited to target analytes analyzed by the lab using USEPA Method TO-15. A list of tentatively identified compounds can be
found in the Galson Laboratory Report in Appendix G.
**
While air samples were collected and analyzed for PNAH at each fixed location, no detections were observed.
Table 4.2.2
Summary of Downwind Grab Sampling Results*
Location
Analyte
No. of Samples
No. of Detections
Range of Detections
(ppb)
Prior to Controlled Burn

(GB 03)
PROPYLENE
13
HEPTANE
2.3
During Controlled Burn

(GB 04 & GB 05)
HEXANE
5.8
PROPYLENE
2-4.9
Page | 8
Summary of VOC Headspace Sampling Results*
Table 4.2.3
Location
Tanker Head Space
Analyte
Concentration**
(ppb)
ACETONE
150,000 56,569
BENZENE
4,150 212
CYCLOHEXANE
9,000 707
HEPTANE
10,350 919
HEXANE
48,000 5657
M,P-XYLENES
950 57
PROPYLENE
235,000 21,213
TOLUENE
2,900 141
** Results are reported as the average standard deviation from two samples.
4.3
Personal Air Sampling Results
Table 4.3.1 summarizes the results of personal badge sampling with a 3M OVM 3520 personal badge
and an Assay 571 personal badge to assess their exposure to benzene, ethyl benzene, toluene, xylene,
hexane, and aldehydes.
Table 4.3.1
Personnel Air Sampling
Analyte
No. of Samples
No. of Detections
Max. Reported TWA Result
Max. 8-hr TWA*
Benzene
1.4 ppm
0.29 ppm
Toluene
1.1 ppm
0.23 ppm
Ethyl Benzene
Not Detected
Not Detected
Xylene
Not Detected
Not Detected
11 ppm
2.89 ppm
Not Detected
Not Detected
Hexane
**
Aldehydes
*
8-hr. Time Weighted Average (TWA) was calculated by assuming no additional exposure to the hydrocarbon constituents for the remaining
380 minutes of the 8-hr shift.
**
Includes the following: acetaldehyde, benzaldehyde, butyraldehyde, crotonaldehyde, formaldehyde, isovaleraldehyde, propionaldehyde,
valeraldehyde
5.0
Discussion
CTEH performed real-time air monitoring and analytical air sampling within the confines of the B.E.S.T.
facility during the Bakken Crude Oil demonstration conducted by Williams Fire & Hazard Control in an
effort to characterize airborne emissions and assess the potential for worker exposure, if any, to crude
oil or its associated combustion products.
Page | 9
5.1
Real-Time Air Monitoring Discussion
During the approximately 3 hour time period that CTEH was present at the B.E.S.T. Facility which
included two 6-8 minute controlled burns CTEH collected approximately 5,100 real-time air
monitoring readings; the majority of which (87%) were measurements of VOCs and atmospheric
flammability (LEL) recorded on fixed-location radio-telemetering AreaRAE Units positioned at locations
surrounding the Bakken crude oil-containing petroleum reservoir. As outlined in Table 4.1.1, while VOCs
were detected on these radio-telemetering AreaRAE Units, their concentrations were relatively low and
did not exceed the VOC action level for the work area as outlined in the SAP (Appendix D). In a similar
manner, particulate matter (as PM10) observations recorded at two PM10 fixed-location monitoring
stations (AS01 and AS032) comprised approximately 12% of the real-time readings collected during the
demonstration. Of particular note, however, is that while the instruments at both stations recorded
observations over an approximate 2-hr timeframe (which included both controlled burn events), AS01
recorded readings at a rate of once every 15 seconds while AS03 recorded readings once every minute.
As observed in Table 4.1.2, when the data recorded at the downwind location (AS03) was compared
against that collected at the upwind location (AS03), no apparent difference in particulate matter
concentration was noted. In fact, both the average and maximum PM10 readings observed at the upwind
station (AS01) were greater than those observed at the downwind location (AS03); however, neither
station experienced an exceedence of the particulate matter action levels as set forth in the SAP. The
relatively low particulate matter readings at the downwind location are consistent with observations
made by field personnel that the smoke generated during the controlled burn travelled immediately
upwards and above the particulate matter monitoring stations.
In addition to fixed-location real-time air monitoring, CTEH field staff also conducted real-time handheld monitoring for particulate matter (as PM10) and VOCs as well as benzene, carbon monoxide (CO),
hydrogen sulfide (H2S), nitrogen dioxide (NO2), and sulfur dioxide (SO2) at locations surrounding the
petroleum reservoir with specific emphasis placed on downwind areas and at locations where
demonstration observers were staged. The results of these readings are presented in Table 4.1.3. With
regards to hand-held real-time air monitoring, only PM10 and VOCs were detected; however, the
concentrations of these analytes did not exceed their respective CTEH site-specific action levels.
5.2
Analytical Air Sampling Discussion
To supplement real-time air monitoring efforts, CTEH collected integrated analytical air samples for
VOCs and polynuclear aromatic hydrocarbons (PAHs) at three fixed locations: one upwind and two
downwind of the crude oil-containing petroleum reservoir. Sampling at these locations began prior to
initiation of the controlled burn and ceased following the conclusion of the demonstration. VOC and
2
While three fixed-location AM510 particulate monitoring stations were established during the event, the AM510 instrument at location AS02
failed to data-log readings during the demonstration.
Page | 10
PAH integrated air samples were collected over time periods of approximately 1 hour and 2 hours,
respectively. Additionally, three analytical air grab (nearly instantaneous) samples were collected at
locations downwind of the crude oil-containing petroleum reservoir; one collected prior the controlled
burn while the others collected during the burn, albeit underneath the majority of the smoke plume.
While PAHs were not detected during analytical air sampling efforts, all VOC analytical air samples
yielded detections, as outlined in Table 4.2.1 and Table 4.2.2. Because no occupational exposure
guidelines exist for a 1-hr exposure duration, the concentrations of VOCs were compared against the
Texas Commission on Environmental Quality (TCEQ) Short-Term (up to 1 hr.) Air Monitoring Comparison
Value (AMCV), if available3. As stated by the TCEQ, the AMCVs are chemical specific air concentrations
set to protect human health and welfare. Exposure to an air concentration at or below the AMCVs is not
likely to cause adverse health effects in the general public, including sensitive subgroups such as children,
the elderly, pregnant women, and people with preexisting health conditions. Because the TCEQ AMCV
values are developed with sensitive individuals (e.g. children and elderly) in mind, their use as screening
values for an occupational setting such as the Work Area is very conservative in nature. Nonetheless,
when the concentrations of VOCs observed at downwind locations were compared against their
respective TCEQ Short-Term AMCV4, no exceedences were observed. This indicates that these
compounds were not of a health concern during the time of the demonstration.
In addition to ambient air samples, CTEH also collected two analytical air samples from the headspace
of the crude oil-containing truck prior to off-loading into the petroleum reservoir in an effort to
characterize the vapor phase constituents of Bakken Crude Oil. As provided in Table 4.2.3, eight USEPA
Method TO-15 target analytes were detected within these samples, the greatest being propylene with a
concentration of 235,000 21,213 ppb (235 21.2 ppm). Propylene is a colorless gas with little potential
for adverse toxicological effects from brief periods of high exposures. After the inclusion of tentatively
identified compounds (TICs), eleven VOCs were detected at concentrations above 10,000 ppb (10 ppm).
In addition to propylene, these included (in order of average concentration; greatest first): pentane,
acetone, butane, isobutane, hexane, 1-methylpentane, methylcyclopentane, 2-methylcyclopentane,
cyclopentane, and heptane. However, when the maximum concentration of detected VOCs were
compared a critical health protective value (CHPV), defined as the minimum amongst the OSHA PEL or
the ACGIH TLV-TWA, in a ratiometric fashion to create a CHPV ratio -- benzene and hexane represent
the top two ranked potential target analytes. As such, it is recommended that these two analytes be
included in Air Sampling and Analysis Plans for future work where potential for exposure to crude oil
vapors in present.
TCEQ AMCV values are available for all Method TO-15 target analytes as listed in Tables 4.2.1 and 4.2.2 with the exception of carbon disulfide
and tetrahydrofuran.
4
One TO-15 target analyte (tetrahydrofuran) did not have an available TCEQ Short-Term AMCV; however, this analyte was detected in only 1
sample at a low concentration. Additionally, tetrahydrofuran was not detected in air samples collected from the headspace of the crude oilcontaining tanker truck. Hence, it is likely that the detection of this compound is not associated with the controlled burn.
Page | 11
5.3
Personal Sampling Results Discussion
CTEH collected personal air samples on two Williams Fire and Hazard Control employees to assess the
potential for worker exposure, if any, to benzene, toluene, ethylbenzene, xylene, n-hexane, and
aldehydes during the demonstration. One of these individuals was involved in the offloading of crude oil
from the tanker to the petroleum reservoir (using a supplied air respirator) while the other individual
was involved in fire-fighting operations only. As observed in Table 4.3.1, detections of benzene, toluene,
and hexane were observed on the individual involved in the offloading of crude oil from the tanker while
no compounds were detected on the individual involved in firefighting only. This is likely due to the
upwind position maintained by fire-fighting personnel while fighting the fire. When normalized to an 8
hr. time-weighted average (assuming no exposure for the remainder of the workday), no exceedences of
the compounds respective OSHA PEL or ACGIH TLV-TWA were observed. With this said, should an
individual work in such an environment where one would be exposed to vapors of crude oil for an 8-hr
time period, i.e. oil spill, caution should be taken and air monitoring for benzene undertaken to ensure
an overexposure to BTEX-related compounds does not occur.
6.0
Conclusion
CTEH provided air monitoring and analytical air sampling during the Williams Fire and Hazard Control
Bakken crude oil controlled burn demonstration. After a review of the air monitoring and air sampling
data, it was noted that airborne concentrations of crude-oil associated compounds did not meet or
exceed site-specific action levels (real-time monitoring) or the TCEQs short-term air monitoring
comparison values (AMCVs) during the burn. With this said, a review of the analytical air sampling data
indicates that benzene and hexane are the crude oil-associated compounds most likely to pose the
greatest hazard with respect to employees working in close proximity to free product for a full work
shift. As such, air monitoring for benzene and hexane should be included in sampling and analysis plans
for events involving the release of crude oil products.
Page | 12
Appendix A:
Bakken Crude Oil SDS
Crude Oil, Sweet
(Material) Safety Data Sheet
Version 1.1 Revision Date 2013-04-05
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Material Name:
Crude Oil, Sweet
Chemical Family:
Petroleum hydrocarbons
Synonyms:
Molecular Formula:
Product Description:
Product Use:
Manufacturer:
Crude Oil; Field Crude; Petroleum Crude; Petroleum Oil; Rock Oil; Sweet Crude
Mixture
A complex mixture of hydrocarbons, containing variable amounts of impurities.

Refinery / Chemical manufacturing feedstock; Fuel.
Continental Resources, Inc.
HSSE Department
20 N. Broadway/P.O. Box 269000
OKC, Oklahoma 73126
Telephone:
405.234.9000 (General)
1.800.424.9300 (Emergency Within USA & Canada)
+1 703.527.3887 (Emergency Outside USA & Canada, Collect Calls Accepted)
SECTION 2 HAZARDS IDENTIFICATION

Emergency Overview
DANGER
Highly flammable liquid and vapor (H225).

May be fatal if swallowed and enters airways (H304).
Causes mild skin irritation (H316).
Causes serious eye irritation (H319).
Harmful if inhaled (H332).
May cause cancer (H350).
May cause long lasting harmful effects to aquatic life (H412).
PREVENTION
Obtain special instructions before use (P201).
Do not handle until all safety precautions have been read and understood (P202).
Keep away from heat / sparks / open flames / hot surfaces no smoking (P210).
Ground / bond container and receiving equipment (P240).
Use explosion-proof electrical / ventilating / lighting equipment (P241).
Use only non-sparking tools (P242).
1
(M)SDS for
Crude Oil, Sweet
Take precautionary measures against static discharge (P243).

Avoid breathing dust / fume / gas / mist / vapors / spray (P261).
Wash thoroughly after handling (P264).
Do not eat, drink, or smoke when using this product (P270).
Use only outdoors or in a well-ventilated area (P271).
Avoid release to the environment (P273).
Wear gloves / eye protection / face protection (P280).
Use personal protective equipment as required (P281).
RESPONSE
IF SWALLOWED: Immediately call a poison control center or doctor / physician. Do not induce vomiting
(P301 + P310 + P331).
IF ON SKIN (or hair): Rinse skin with water and mild soap. Wash contaminated clothing before reuse (P303 +
P353 + P363).
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
control center or doctor / physician if you feel unwell (P304 + P340 + P312).
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing (P305 + P351 + P338).
If exposed / concerned: Get medical advice / attention (P308 + P313).
If skin irritation occurs: Get medical advice / attention (P332 + P313).
If eye irritation persists: Get medical advice / attention (P337 + P313).
IN CASE OF FIRE: Use dry chemical, carbon dioxide, or foam for extinction (P370 + P378).
STORAGE/DISPOSAL
Store in a well-ventilated place. Keep container tightly closed. Keep cool (P403 + P233 + P235).
Store locked up (P405).
Dispose of contents / container in accordance with local / regional / national / international regulations (P501).
Hazards Information
Physical Form:
Liquid
Explosive Limits:
0.4% (LEL) 15% (UEL)
Flash Point:
OSHA:
GHS:
-40 to 100 C (-40 to 212 F)

Flammable Liquid
Toxic
Irritant
Carcinogen
Flammable Liquids Category 2

Acute Toxicity Category 4
Skin Corrosion / Irritation Category 3
Serious Eye Damage / Eye Irritation Category 2A
Carcinogenicity Category 1A
Aspiration Hazard Category 1
Long-Term Hazards to the Aquatic Environment Category 3
NFPA
2
(M)SDS for
Crude Oil, Sweet
Potential Health Effects

Eye Health Effects:
Contact with eyes may cause moderate to severe irritation.
Inhalation Health Effects:
May contain or release toxic hydrogen sulfide vapor, which may accumulate in
the vapor spaces of storage and transport compartments. Exposure to high
concentrations of hydrogen sulfide (>1000 ppm) will cause immediate
unconsciousness and death through respiratory paralysis. Signs and symptoms
of overexposure to hydrogen sulfide include respiratory and eye irritation,
dizziness, nausea, coughing, a sensation of dryness and pain in the nose, and
loss of consciousness. Odor does not provide a reliable indicator of the presence
of hazardous levels in the atmosphere.
Skin Health Effects:
Ingestion Health Effects:
Carcinogenic Effects:
Component
Benzene
(71-43-2)
May cause skin irritation with prolonged or repeated contact. Liquid may be
absorbed through the skin in toxic amounts if large areas of skin are exposed
repeatedly.
Ingestion may cause aspiration of the liquids into the lungs. Aspiration may result
in chemical pneumonia, severe lung damage, respiratory failure, or even death.
Ingestion may also cause gastrointestinal problems, or central nervous system
effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss
of consciousness, coma, respiratory arrest, and death may occur.
Repeated and prolonged exposure may be harmful and may cause cancer.
NTP
Carcinogenic Effects
IARC
OSHA
Known Human Carcinogen
Group 1 - Carcinogenic
Specifically Regulated
Carcinogen
Evidence of Carcinogenicity
Not established
Toluene
(108-88-3)
Group 2B - Possible
Carcinogen
Not established
Not established
Xylenes
(1330-20-7)
Not established
Not established
Ethylbenzene
(100-41-4)
Potential Environmental Effects

Environmental Effects:
May cause harmful effects to aquatic life.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

3
(M)SDS for
Crude Oil, Sweet
Crude oil can contain minor amounts of sulfur-, nitrogen-, and oxygen-containing organic compounds as well as
trace amounts of heavy metals like mercury, arsenic, nickel, and vanadium. Composition can vary significantly
depending on its source.
Name
Petroleum
Hexane
Hazardous Components
CAS #
UN; EINECS
% (Weight)
110-54-3
UN1208; 203-777-6
< 10%
8002-05-9
UN1267; 232-298-5
95 - 100%
Benzene
71-43-2
UN1114; 200-753-7
< 5%
Toluene
108-88-3
UN1294; 203-625-9
< 5%
Ethylbenzene
Xylenes
Hydrogen sulfide
100-41-4
UN1175; 202-849-4
1330-20-7
UN1307; 215-535-7
7783-06-4
UN1053; 231-977-3
< 5%
< 5%
< 0.5%
Note: All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by
volume.
SECTION 4 FIRST AID MEASURES

Eye Contact
For direct contact, remove contact lenses if present. Immediately hold eyelids apart and flush the affected eye(s)
with clean water for at least 20 minutes. Seek immediate medical attention.
Skin Contact
Remove contaminated shoes and clothing and cleanse affected area(s) thoroughly by washing with mild soap and
water or a waterless hand cleaner. If irritation or redness develops and persists, seek medical attention.
Inhalation
If respiratory symptoms or other symptoms of exposure develop, move victim away from source of exposure and
into fresh air. If breathing difficulties develop, oxygen should be administered by qualified personnel. If victim is
not breathing, clear airway and immediately begin artificial respiration. Seek immediate medical attention.
Ingestion
Call a physician or poison control center immediately. Aspiration hazard: Do not induce vomiting or give anything
by mouth because this material can enter the lungs and cause severe lung damage. If spontaneous vomiting
occurs, lean victim forward to reduce the risk of aspiration and monitor for breathing difficulties. If victim is drowsy
or unconscious, place on the left side with the head down. If possible, do not leave victim unattended and observe
closely for adequacy of breathing. Seek immediate medical attention.
Notes to Physicians
At high concentrations hydrogen sulfide may produce pulmonary edema, respiratory depression, and/or
respiratory paralysis. The first priority in treatment should be the establishment of adequate ventilation and the
4
(M)SDS for
Crude Oil, Sweet
administration of 100% oxygen. Nitrite therapy (found in the cyanide antidote kit) has been suggested as a
therapy for hydrogen sulfide exposure. Amyl nitrite is given by inhalation (for 30 seconds every minute until an
intravenous line is established) followed by intravenous sodium nitrite (300 mg over absolutely no less than 5
minutes). This may aid recovery by forming sulfmethemoglobin, thus removing sulfide from combination in tissue.
The antidotal efficacy of nitrite therapy is controversial, but is currently recommended if it can be started within the
first few minutes after exposure. Nitrite therapy should not be allowed to interfere with the establishment of
adequate ventilation and oxygenation. (Source: ATSDR Toxic Substances Portal Hydrogen Sulfide).
Exposure Monitoring
Federal regulations (29 CFR 1910.1028) specify medical surveillance programs for certain exposures to benzene
above the action level or PEL (specified in Section (i)(1)(i) of the Standard). In addition, employees exposed in an
emergency situation shall, as described in Section (i)(4)(i), provide a urine sample at the end of the shift for
measurement of urine phenol.
Medical Conditions Aggravated by Exposure
Conditions which may be aggravated by exposure include skin disorders and eye disorders. Exposure to high
concentrations of this material may increase the sensitivity of the heart to certain drugs.
Other Comments
Before attempting rescue, first responders should be alert to the possible presence of hydrogen sulfide, a
poisonous gas, and should consider the need for respiratory protection (see Section 8).
SECTION 5 FIRE FIGHTING MEASURES

NFPA 704 Hazard Class:
Health:
1 (Slight)
Instability:
0 (Minimal)
Flammability:
3 (Serious)
Unusual Fire and Explosion Hazards
Flash point and explosive limits are highly dependent on the source. Unless otherwise indicated, treat as a
FLAMMABLE LIQUID. This material can be ignited by heat, sparks, flames, or other sources of ignition. Vapors
may travel considerable distances to a source of ignition where they can ignite, flash back, or explode. This
substance may create a vapor/air explosion hazard indoors, in confined spaces, outdoors, or in sewers. Vapors
are heavier than air and can accumulate in low areas. If container is not properly cooled, it can rupture in the heat
of a fire. This substance will float and can be reignited on surface water. Hazardous combustion/decomposition
products, including hydrogen sulfide, may be released by this material when exposed to heat or fire. Use caution
and wear protective clothing, including respiratory protection.
Extinguishing Media
Dry chemical, carbon dioxide, or foam and water streams is recommended. Water spray is recommended to cool
or protect exposed materials or structures. Carbon dioxide can displace oxygen; use caution when applying
carbon dioxide in confined spaces. Water alone may be ineffective for extinguishment.
5
(M)SDS for
Crude Oil, Sweet
Protection of Firefighters
For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective
clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, a self-contained
breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions
warrant (see Section 8).
Firefighting Procedures
Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire
extinguishers and other fire fighting equipment. For larger fires, isolate immediate hazard area and keep
unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from
immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and
to protect personnel. Cool equipment exposed to fire with water, if it can be done safely. Avoid spreading burning
liquid with water used for cooling purposes. For massive fires, the use of unmanned hose holders or monitor
nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal,
allowing the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to
extinguish the fire, often including the need for properly applied fire fighting foam.
Other Information
Combustion Products:
Flammable Properties:
Smoke, carbon monoxide, carbon dioxide, and other products of incomplete

combustion. Hydrogen sulfide and oxides of nitrogen and sulfur may be formed.
See Section 9 for Flash Point, Flammable/Explosive Limits, etc.
SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal Precautions
Spillages of liquid product will create a fire hazard and may form an explosive atmosphere. Keep all sources of
ignition and hot metal surfaces away from spill/release if safe to do so. The use of explosion-proof electrical
equipment is recommended. May contain or release poisonous hydrogen sulfide gas. If the presence of
dangerous amounts of hydrogen sulfide around the spilled product is suspected, additional or special actions may
be warranted, including access restrictions and use of protective equipment. Stay upwind and away from
spill/release. Avoid direct contact with material. For large spillages, notify persons down wind of the spill/release,
isolate immediate hazard area, and keep unauthorized personnel out. Wear appropriate protective equipment,
including respiratory protection, as conditions warrant (see Section 8).
Environmental Precautions
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other
unauthorized drainage systems, and natural waterways. Use foam on spills to minimize vapors. Use water
sparingly to minimize environmental contamination and reduce disposal requirements. If spill occurs on water
notify appropriate authorities and advise shipping of any hazard. Spills into or upon navigable waters, the
contiguous zone, or adjoining shorelines that cause a sheen or discoloration on the surface of the water, may
require notification of the United States National Response Center (phone number: 800.424.8802).
Containment Procedures
Carefully contain and stop the source of the spill, if safe to do so. Protect bodies of water by diking, absorbents, or
absorbent boom, if possible. Do not flush down sewer or drainage systems, unless system is designed and
permitted to handle such material. The use of fire fighting foam may be useful in certain situations to reduce
vapors. The proper use of water spray may effectively disperse product vapors or the liquid itself, preventing
6
(M)SDS for
Crude Oil, Sweet
contact with ignition sources or areas/equipment that require protection do not discharge solid water stream
patterns into the liquid resulting in splashing.
Clean-up Procedures
Notify relevant authorities in accordance with all applicable regulations. Immediate cleanup of any spill is
recommended. Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a
waste container for reclamation or disposal. Response and clean-up crews must be properly trained and must
utilize proper protective equipment (see Section 8).
SECTION 7 HANDLING AND STORAGE

Handling
Flammable. May vaporize easily at ambient temperatures. The vapor is heavier than air and may create an
explosive mixture of vapor and air. Beware of accumulation in confined spaces and low lying areas. Open
container slowly to relieve any pressure. Do not enter confined spaces such as tanks or pits without following
proper entry procedures such as ASTM D-4276 and OSHA 29 CFR 1910.146. Keep away from heat, sparks, and
open flame. Electrical equipment should be approved for classified area. Take precautionary measures against
static discharge. Bond and ground containers during product transfer to reduce the possibility of static-initiated fire
or explosion. Refer to NFPA-70 and/or API RP 2003 for specific bonding/grounding requirements. Non-sparking
tools should be used. Do not wear contaminated clothing or shoes. Keep contaminated clothing away from
sources of ignition such as sparks or open flames.
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
May contain or release dangerous levels of hydrogen sulfide. Avoid breathing vapors or mists. Use only outdoors
or in well-ventilated area. Wear protective gloves/clothing and eye/face protection. Wash thoroughly after
handling. Use good personal hygiene practices and wear appropriate personal protective equipment.
Storage
This material may contain or release poisonous hydrogen sulfide gas. In a tank, barge, or other closed container,
the vapor space above this material may accumulate hazardous concentrations of hydrogen sulfide. Check
atmosphere for oxygen content, hydrogen sulfide, and flammability prior to entry. Confined spaces should be
ventilated prior to entry. Keep container(s) tightly closed and properly labeled. Use and store this material in cool,
dry, well-ventilated areas away from heat, direct sunlight, hot metal surfaces, and all sources of ignition. Store
only in approved containers. The storage area should comply with NFPA 30
Flammable and Combustible Liquids
Code.Post area
No Smoking or Open Flame.Keep away from any incompatible material (see Section 10).
Protect container(s) against physical damage. Outdoor or detached storage is preferred. Indoor storage should
meet OSHA standards and appropriate fire codes.
Emptycontainers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind,
or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury
or death. The cleaning of containers previously containing this product should follow API STD 2015
Safe Entry
and Cleaning of Petroleum Storage Tanks.All containers should be disposed of in an environmentally safe
manner and in accordance with governmental regulations. Before working on or in tanks which contain or have
contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning,
repairing, welding, or other contemplated operations.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Suggestions provided in this section for exposure control and specific types of protective equipment are based on
readily available information. Users should consult with the specific manufacturer to confirm the performance of
7
(M)SDS for
Crude Oil, Sweet
their protective equipment. Specific situations may require consultation with industrial hygiene, safety, or
engineering professionals.
Personal Protective Equipment
Respiratory Protection:
Eye/Face Protection:
Skin Protection:
General Considerations:
Avoid breathing dust, fume, gas, mist, vapors, and/or spray. Obtain special
instructions before use. If engineering controls do not maintain airborne
concentrations below recommended exposure limits (where applicable) or to an
acceptable level (in countries where exposure limits have not been established),
an approved respirator must be worn. Where there is potential for airborne
exposure to hydrogen sulfide above exposure limits, a NIOSH approved, selfcontained breathing apparatus (SCBA) or equivalent operated in a pressure
demand or other positive pressure mode should be used. Under conditions
where hydrogen sulfide is not detected, a NIOSH certified air purifying respirator
equipped with organic vapor cartridges/canisters may be used. In the United
States, if respirators are used, a program should be instituted to assure
compliance with OSHA 29 CFR 1910.134. If benzene concentrations equal or
exceed applicable exposure limits, OSHA requirements for personal protective
equipment, exposure monitoring, and training may apply (OSHA 29 CFR
1910.1028 Benzene).
The use of eye protection (such as splash goggles) that meets or exceeds ANSI
Z.87.1 is recommended when there is potential liquid contact to the eye.
Depending on conditions of use, a face shield may be necessary.
The use of gloves impervious to the specific material handled is advised to
prevent skin contact. Users should check with manufacturers to confirm the
breakthrough performance of their products. Apron and long sleeves are
recommended.
When using, do not eat, drink or smoke. Always observe good personal hygiene
measures, such as washing after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and protective equipment
to remove contaminants. Handle in accordance with good industrial hygiene and
safety practice.
Engineering Controls
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits. Provide adequate ventilation and minimize the risk of inhalation of vapors and
mists. If current ventilation practices are not adequate to maintain airborne concentrations below the established
exposure limits, additional engineering controls may be required.
Exposure Limits / Guidelines

Component
Petroleum
(8002-05-9)
ACGIH
Not established
NIOSH
CEIL: 1800 mg/m3

TWA: 350 mg/m3
8
OSHA
Not established
(M)SDS for
Crude Oil, Sweet

Hexane
(110-54-3)
TWA: 50 ppm
TWA: 50 ppm
TWA: 500 ppm
Ethylbenzene
(100-41-4)
TWA: 0.5 ppm

STEL: 2.5 ppm
TWA: 0.1 ppm

STEL: 1 ppm
TWA: 20 ppm
TWA: 100 ppm

STEL: 125 ppm
TWA: 1 ppm
STEL: 5 ppm
TWA: 20 ppm
TWA: 100 ppm

STEL: 150 ppm
TWA: 200 ppm

CEIL: 500 ppm
Not established
TWA: 100 ppm
CEIL: 10 ppm
CEIL: 20 ppm
Benzene
(71-43-2)
Toluene
(108-88-3)
Xylenes
(1330-20-7)
Hydrogen sulfide
(7783-06-4)
TWA: 100 ppm

STEL: 150 ppm
TWA: 1 ppm
STEL: 5 ppm
TWA: 100 ppm
Note: State, local, or other agencies or advisory groups may have established more stringent limits. Consult an
industrial hygienist or similar professional, or your local agencies, for further information.
Supplemental Information
Component
Petroleum
(8002-05-9)
Carcinogenicity
Notations
Skin / Sensitization
Not established
Not established
Hexane
(110-54-3)
Not established
Potential significant contribution to overall

exposure by the cutaneous route (ACGIH
Skin Notation).
Benzene
(71-43-2)
Confirmed human carcinogen (ACGIH A1).
Ethylbenzene
(100-41-4)
Potential significant contribution to overall

exposure by the cutaneous route (ACGIH
Skin Notation).
Confirmed animal carcinogen with unknown

Not established
relevance to humans (ACGIH A3).
Toluene
(108-88-3)
Not classifiable as a human carcinogen

(ACGIH A4).
Xylenes
(1330-20-7)
Hydrogen sulfide
(7783-06-4)
Not established
Not classifiable as a human carcinogen

(ACGIH A4).
Not established
Not established
Not established
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Physical Form:
Liquid
Odor:
Petroleum
Color:
Varies (Amber / Brown / Black)
(M)SDS for
Crude Oil, Sweet
Molecular Weight:
Varies
Melting Point:
-60 -20 C (-76 -4 F)
Boiling Point:
Specific Gravity:
Bulk Density:
pH:
Water Solubility:
Viscosity:
Partition Coefficient:
Vapor Pressure:
Vapor Density:
Evaporation Rate:
Volatiles:
Flash Point:
Flash Point Test Method:

Explosive Limits:
Autoignition:
500 590 C (932 1094 F)

0.63 2.00 @ 20 C (68 F)
5.25 9.18 lbs/gal
No data available
Negligible
No data available
<0.1 (Water/Oil)
No data available
1.0 5.0
No data available
No data available
-40 100 C (-40 212 F)

Estimate
0.4% (LEL) 15% (UEL)
220 310 C (428 590 F)
SECTION 10 STABILITY AND REACTIVITY

Stability:
Stable under normal ambient and anticipated conditions of use.
Incompatible Materials:
Avoid contact with strong oxidizing agents and strong reducing agents.
Conditions to Avoid:
Hazardous Polymerization:
Avoid high temperatures and all sources of ignition. Prevent vapor accumulation.
Not known to occur.
SECTION 11 TOXICOLOGICAL INFORMATION

General Toxicity
Signs and Symptoms:
Aspiration Hazard:
Effects of overexposure may include irritation of the digestive tract, irritation of

the respiratory tract, nausea, vomiting, diarrhea and signs of nervous system
depression (e.g., headache, drowsiness, dizziness, loss of coordination,
disorientation and fatigue).
May be fatal if swallowed and enters airways.
10
(M)SDS for
Crude Oil, Sweet
Skin Sensitization:
Not expected to be a skin sensitizer.
Specific Target Organs:
At high concentrations (500 - 1000 ppm), hydrogen sulfide acts as a systemic

poison, causing unconsciousness and death. In lower concentrations (50 500
ppm), hydrogen sulfide acts as a respiratory irritant, and may cause fluid in the
lungs or bronchial pneumonia. Chronic exposure to hydrogen sulfide of 50 ppm
or greater may include bronchitis and inflammation of the mucous membrane of
the respiratory system. At 250 ppm hydrogen sulfide, chronic effects may include
brochial pneumonia and pulmonary edema.
Respiratory Sensitization:
Carcinogenicity:
Germ Cell Mutagenicity:

Reproductive Toxicity:
No data available.
May cause cancer, based on component information. Chronic application of

crude oil to mouse skin resulted in an increased incidence of skin tumors. IARC
concluded in its Crude Oil Monograph that there is limited evidence of
carcinogenicity in animals, and that crude oil is not classifiable as to its
carcinogenicity in humans (Group 3). It has not been listed as a carcinogen by
NTP or OSHA.
No data available.
No data available. Dermal exposure to crude oil during pregnancy resulted in

limited evidence of developmental toxicity in laboratory animals. Decreased fetal
weight and increased resorptions were noted at maternally toxic doses. No
significant effects on pup growth or other developmental landmarks were
observed postnatally.
Other Comments
This material may contain or liberate hydrogen sulfide, a poisonous gas with the smell of rotten eggs. The smell
disappears rapidly because of olfactory fatigue so odor may not be a reliable indicator of exposure. Effects of
overexposure include irritation of the eyes, nose, throat and respiratory tract, blurred vision, photophobia
(sensitivity to light), and pulmonary edema (fluid accumulation in the lungs). Severe exposures can result in
nausea, vomiting, muscle weakness or cramps, headache, disorientation and other signs of nervous system
depression, irregular heartbeats, convulsions, respiratory failure, and death.
This material may contain varying concentrations of polycyclic aromatic hydrocarbons (PAHs), which have been
known to produce a phototoxic reaction when contaminated skin is exposed to sunlight. The effect is similar in
appearance to an exaggerated sunburn, and is temporary in duration if exposure is discontinued. Continued
exposure to sunlight can result in more serious skin problems including pigmentation (discoloration), skin
eruptions (pimples), and possible skin cancers.
This material may contain trace amounts of heavy metals, some of which may concentrate in vessels and
equipment during production and processing operations. While some of these metals are known toxins, the
hazard is dependent upon the extent of accumulation. Significant deposits of elemental mercury have the
potential to create airborne vapors of the metal, which might result in a hazardous condition. Overexposure to
mercury is known to cause neurologic effects and damage the kidneys and developing fetus.
Toxicological Effects of Components

Component
Category
Petroleum
(8002-05-9)
Symptoms
Exposure Routes
Target Organs
Toxicological Information
Data
Inhalation, ingestion, skin, and/or eye contact.

Irritation eyes, nose, throat; dizziness, drowsiness, headache, nausea;
dry cracked skin; chemical pneumonitis (aspiration liquid).
Eyes, skin, respiratory system, central nervous system.
11
(M)SDS for
Crude Oil, Sweet

Short-Term Exposure No data available.
Long-Term Exposure
No data available.
Symptoms
Irritation eyes, nose; nausea, headache; peripheral neuropathy: numb

extremities, muscle weak; dermatitis; dizziness; chemical pneumonitis
(aspiration liquid).
Exposure Routes
Hexane
(110-54-3)
Benzene
(71-43-2)
Target Organs
Long-Term Exposure
Repeated or prolonged contact with skin may cause dermatitis. The

substance may have effects on the central nervous system and
especially peripheral nervous system, resulting in polyneuropathy.
Animal tests show that this substance possibly causes toxic effects
upon human reproduction.
Exposure Routes
Inhalation, skin absorption, ingestion, skin, and/or eye contact.
Symptoms
Irritation eyes, skin, nose, respiratory system; dizziness; headache,

nausea, staggered gait; anorexia, lassitude (weakness, exhaustion);
dermatitis; bone marrow depression; [potential occupational
carcinogen].
Target Organs
Eyes, skin, respiratory system, blood, central nervous system, bone

marrow.
The substance is irritating to the eyes, the skin and the respiratory tract.
Swallowing the liquid may cause aspiration into the lungs with the risk
of chemical pneumonitis. The substance may cause effects on the
Short-Term Exposure
central nervous system, resulting in lowering of consciousness.
Exposure far above the occupational exposure limit value may result in
unconsciousness and death.
Exposure Routes
Symptoms
Target Organs
Toluene
(108-88-3)
Eyes, skin, respiratory system, central nervous system, peripheral

nervous system.
The substance irritates the skin. Swallowing the liquid may cause
Short-Term Exposure aspiration into the lungs with the risk of chemical pneumonitis.
Exposure at high levels could cause lowering of consciousness.
Long-Term Exposure
Ethylbenzene
(100-41-4)
The liquid defats the skin. The substance may have effects on the bone
marrow and immune system, resulting in a decrease of blood cells.
This substance is carcinogenic to humans..
Irritation eyes, skin, mucous membrane; headache; dermatitis;

narcosis, coma.
Eyes, skin, respiratory system, central nervous system.
The substance is irritating to the eyes, the skin and the respiratory tract
Swallowing the liquid may cause aspiration into the lungs with the risk
Short-Term Exposure of chemical pneumonitis. The substance may cause effects on the
central nervous system. Exposure above the OEL could cause lowering
of consciousness.
Long-Term Exposure
This substance is possibly carcinogenic to humans. The substance

may have effects on the kidneys and liver, resulting in impaired
functions. Repeated contact with skin may cause dryness and cracking.
Exposure Routes
Inhalation, skin absorption, ingestion, skin, and/or eye contact.
Symptoms
Irritation eyes, nose; lassitude (weakness, exhaustion), confusion,

euphoria, dizziness, headache; dilated pupils, lacrimation (discharge of
tears); anxiety, muscle fatigue, insomnia; paresthesia; dermatitis; liver,
kidney damage.
12
(M)SDS for
Crude Oil, Sweet

Target Organs
Eyes, skin, respiratory system, central nervous system, liver, kidneys.
The substance is irritating to the eyes and the respiratory tract. The
substance may cause effects on the central nervous system. If this
Short-Term Exposure liquid is swallowed, aspiration into the lungs may result in chemical
pneumonitis. Exposure at high levels may result in cardiac dysrhythmia
and unconsciousness.
Long-Term Exposure
Exposure Routes
Xylenes
(1330-20-7)
Symptoms
Target Organs
No data available.
No data available.
No data available.
Short-Term Exposure No data available.

Long-Term Exposure
No data available.
Exposure Routes
Inhalation, skin, and/or eye contact.
Symptoms
Hydrogen sulfide
(7783-06-4)
The liquid defats the skin. The substance may have effects on the
central nervous system. Exposure to the substance may enhance
hearing damage caused by exposure to noise. Animal tests show that
this substance possibly causes toxicity to human reproduction or
development.
Target Organs
Irritation eyes, respiratory system; apnea, coma, convulsions;

conjunctivitis, eye pain, lacrimation (discharge of tears), photophobia
(abnormal visual intolerance to light), corneal vesiculation; dizziness,
headache, lassitude (weakness, exhaustion), irritability, insomnia;
gastrointestinal disturbance; liquid: frostbite.
Eyes, respiratory system, central nervous system.
The substance is irritating to the eyes and the respiratory tract. The
substance may cause effects on the central nervous system. Exposure
may result in unconsciousness. Exposure may result in death.
Short-Term Exposure
Inhalation of gas may cause lung oedema. The effects may be delayed.
Medical observation is indicated. Rapid evaporation of the liquid may
cause frostbite..
Long-Term Exposure
No data available.
Note: Data for Exposure Routes, Symptoms, and Target Organs were obtained from the NIOSH Pocket Guide to Chemical Hazards. Data for
Short- and Long-Term Exposure were obtained from the International Chemical Safety Cards from the International Occupational Safety and
Health Information Centre.
SECTION 12 ECOLOGICAL INFORMATION

Toxicity:
Persistence & Degradability:
Bioaccumulative Potential:
Mobility:
Experimental studies of acute aquatic toxicity show values for crude oil in the
range of 10 to over 100 mg/L. Crude oil should be regarded as harmful to aquatic
organisms, with the potential to cause long-term adverse effects.
Most crude oils are not regarded as readily biodegradable, however low
molecular weight components may be biodegradable.
Hydrocarbon components in this substance have the potential to bioaccumulate.
Crude oil spreads as a film on the surface of water, facilitating loss of its lighter
components by volatilization. In air, the volatile hydrocarbons undergo
photodegradation. The lower molecular weight aromatic hydrocarbons and some
polar compounds have low but significant water solubility. Some higher molecular
13
(M)SDS for
Crude Oil, Sweet
Other Adverse Effects:
weight compounds are removed by emulsification and these also slowly

biodegrade; others adsorb to sediment and sink. A further removal process from
water involving the heavier fraction is agglomeration to form tars, some of which
sink.
None anticipated.
SECTION 13 DISPOSAL CONSIDERATIONS

The generator of a waste is always responsible for making proper hazardous waste determinations and must
consider state and local requirements in addition to federal regulations.
This material, if discarded as produced, would not be a federally regulated RCRA "listed" hazardous waste.
However, it would likely be identified as a federally regulated RCRA hazardous waste for the following
characteristic(s) shown below. See Sections 7 and 8 for information on handling, storage and personal protection
and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents
which are not required to be listed in the MSDS but could affect the hazardous waste determination.
Container contents should be completely used and containers should be emptied prior to discard. Container
residues and rinseates could be considered to be hazardous wastes.
EPA Waste Number(s):
D001 - Ignitability characteristic

D018 - Toxicity characteristic (Benzene)
SECTION 14 TRANSPORTATION INFORMATION

DOT United States Department of Transportation
Shipping Name: PETROLEUM CRUDE OIL
ID Number: UN1267
Hazard Class: 3
Packing Group: I or II
Note: Some states may require UN1203 in some situations. Contact each jurisdiction for more information.
SECTION 15 REGULATORY INFORMATION

United States Regulations
CERCLA/SARA Section 311/312 (Title III Hazard Categories)

Acute Health:
Yes
Chronic Health:
Yes
Fire Hazard:
Yes
Pressure Hazard:
No
Reactive Hazard:
No
This material may contain one or more of the following chemicals identified by the EPA under Title 40 of the Code
of Federal Regulations (CFR), including the CAA (40 CFR 50-97), CERCLA (40 CFR 302.4), SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), and/or TSCA (40 CFR 700-766).
14
(M)SDS for
Crude Oil, Sweet
Component
CERCLA
SARA Section 302
Yes
5000 lb final RQ
Not listed
Benzene
(71-43-2)
Yes
Not listed
0.1 % de minimis
concentration
No
Ethylbenzene
(100-41-4)
10 lb final RQ (received
an adjusted RQ of 10
lbs based on potential
carcinogenicity in an
August 14, 1989 final
rule)
1.0 % de minimis
concentration
Yes
1000 lb final RQ
Not listed
Yes
Toluene
(108-88-3)
0.1 % de minimis
concentration
Yes
1000 lb final RQ
Not listed
1.0 % de minimis
concentration
No
Xylenes
(1330-20-7)
Yes
100 lb final RQ
Not listed
No
No
100 lb final RQ
100 lb EPCRA RQ
500 lb TPQ
1.0 % de minimis
concentration
Not listed
No
Hexane
(110-54-3)
Hydrogen sulfide
(7783-06-4)
CAA
Components Listed by Selected Parts of US 40 CFR
SARA Section 313
TSCA
No
This material may contain one or more of the following chemicals identified on individual state hazardous
substances lists. Contact each jurisdiction for more information.
Component
CA
MA
No
Hexane
(110-54-3)
Benzene
(71-43-2)
Hazardous Substance Lists

MN
NJ
PA
RI
Yes
Yes
Yes
Yes
Yes
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Ethylbenzene
(100-41-4)
Yes
Yes
Yes
Yes
Yes
Yes
Toluene
(108-88-3)
Yes
Yes
Yes
Yes
Yes
Yes
No
Yes
Yes
Yes
Yes
Yes
No
Yes
Yes
Yes
Yes
Yes
Petroleum
(8002-05-9)
Xylenes
(1330-20-7)
Hydrogen sulfide
(7783-06-4)
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of
1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
WARNING! This product contains a chemical known to the state of California to cause
reproductive/developmental effects.
SECTION 16 OTHER INFORMATION

15
(M)SDS for
Crude Oil, Sweet

Version Information
Version:
1.0
Status:
FINAL
Date of Issue:
2011-08-02
Guide to Abbreviations
ACGIH
ANSI
API
ATSDR
CAA
CAS
CEIL
CERCLA
CFR
EINECS
EPA
GHS
IARC
IOPC
LEL
NFPA
NTP
OSHA
PEL
RQ
SARA
STEL
TLV
TPQ
TSCA
TWA
UEL
UN
American Conference of Governmental Industrial Hygienists

American National Standards Institute
American Petroleum Institute
Agency for Toxic Substances and Disease Registry (United States)
Clean Air Act (United States)
Chemical Abstracts Service
Ceiling Exposure Limit
The Comprehensive Environmental Response, Compensation, & Liability Act (United States)
Code of Federal Regulations (United States)
European chemical Substances Information System
Environmental Protection Agency (United States)
Globally Harmonized System
International Agency for Research on Cancer
International Oil Pollution Compensation
Lower Explosive Limit
National Fire Protection Association
National Toxicology Program (United States)
Occupational Safety and Health Administration (United States)
Permissible Exposure Limit (OSHA)
Reportable Quantity
Superfund Amendments and Reauthorization Act (United States)
Short Term Exposure Limit (15 minutes)
Threshold Limit Value (ACGIH)
Threshold Planning Quantity
Toxic Substances Control Act (United States)
Time Weighted Average (8 hours)
Upper Explosive Limit
United Nations
Disclaimer / Statement of Liability
The information presented in this (Material) Safety Data Sheet is based on data believed to be accurate as of the date this (Material) Safety
Data Sheet was prepared. However, neither Continental Resources, Inc., nor any of their subsidiaries, vendors, or contractors, assumes any
liability whatsoever for the accuracy or completeness of the information contained herein. No responsibility is assumed for any damage or
injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product,
are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their
particular purpose and on the condition that they assume the risk of their use.
16
Appendix B:
Exposure Standards and Guidelines
B.1
Exposure Guidelines and Recommendations
Various governmental agencies and professional organizations have developed exposure standards and
guidelines specific for the chemicals of interest in the workplace. These are health-protective values
developed to protect workers from overexposures. Occupational guidelines and standards for the
chemicals of interest are discussed in Section 2.0 of the report.
B.2
OCCUPATIONAL EXPOSURE STANDARDS AND GUIDELINES
The Occupational Safety and Health Administration (OSHA) and The American Conference of
Governmental Industrial Hygienists (ACGIH) have established workplace exposure standards and
guidelines, respectively. Table B.2 summarizes the worker exposure standards and guidelines for the
chemicals of potential concern.
Occupational Exposure Standards and Guidelines*
Table B.2
ACGIH
a
OSHA
b
Analyte
TLV-TWA
TLV-STEL
PEL-TWA
PEL-STEL
Benzene
0.5 ppm
2.5 ppm
1 ppm
5 ppm
n-Hexane
50 ppm
NE
500 ppm
NE
Carbon Monoxide
25 ppm
NE
50 ppm
NE
Sulfur Dioxide
NE
0.25
5 ppm
NE
Nitrogen Dioxide
0.2 ppm
NE
NE
5 ppm (Ceiling)
Formaldehyde
NE
0.3 ppm (Ceiling)
0.75 ppm
2 ppm
Hydrogen Sulfide
1 ppm
5 ppm
NE
20 ppm (Ceiling)
f
50 ppm
Particulate Matter
3 mg/m
NE
NE
3**
5 mg/m
* ACGIH 2014a
** ACGIH recommends that concentrations of respirable particulate matter not otherwise classified be kept below 3 mg/m3.
NE = Not Established
a.
ACGIH TLV-TWA = Threshold Limit Value Time Weighted Average (TLV-TWA). The TWA concentration for a conventional 8 hour
workday and a 40 hour workweek, to which it is believed that nearly all workers may be repeatedly exposed, day after day,
without adverse effect (ACGIH, 2014b).
b.
ACGIH TLV-STEL = Threshold Limit Value Short Term Exposure Limit (TLV-STEL). A 15 minute TWA exposure that should not be
exceeded at any time during a workday, even if the 8-hour TWA is within the TLV-TWA. The TLV-STEL is the concentration to which it
is believed that workers can be exposed continuously for a short period of time without suffering from 1) irritation, 2) chronic or
irreversible tissue damage, 3) dose-rate dependent toxic effects, or 4) narcosis of sufficient degree to increase the likelihood of
accidental injury, impaired self-rescue, or materially reduced work efficiency. Exposures above the TLV-TWA up to the TLV-STEL
should be less than 15 minutes, should occur not more than 4 times per day, and there should be at least 60 minutes between
successive exposures in this range. (ACGIH, 2014b).
c.
OSHA PEL-TWA = Permissible Exposure Limit Time Weighted Average (PEL-TLV). Permissible concentration in air of a substance
that shall not be exceeded in any 8 hour work shift of a 40 hour work week. (OSHA 29 CFR: 1910.1000).
d.
OSHA PEL-STEL = Permissible Exposure Limit Short Term Exposure Limit (PEL-STEL). A 15 minute TWA exposure that should not be
exceeded at any time during a workday. (OSHA 29 CFR: 1910.1000).
e.
OSHA PEL-Ceiling = Permissible Exposure Limit Ceiling (PEL-C). The exposure limit that shall at no time be exceeded. If
instantaneous monitoring is not feasible, then the ceiling shall be assessed as a 15 minute time weighted average exposure, which
shall not be exceeded at any time during the working day (OSHA 29 CFR: 1910.1000).
f.
10-minute peak; once per 8-hour shift
Appendix C:
Bakken Crude Oil Hydrocarbon Analysis
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Appendix D:
Air Sampling and Analysis Plan
Preliminary Air Sampling and Analysis Plan

Version: 1.0
Drill
Location:
Client:
Version History:
Effective Date: 11/10/14
Bakken Crude Oil Burn Demonstration

Beaumont, TX
Williams Fire and Hazard
1.0
CTEH Project-Specific Action Levels

The following chemicals were determined to have the greatest potential for human health impacts based on the
relative levels in air of volatile organics emitted from fresh crude oil and/or combustion products, together with
published information regarding health-based worker and community exposure guidelines.
Plan/Assignment: WORK AREA
Objective: Report air levels before they reach those requiring respiratory protection or other precautionary actions
Analyte
Plan
Action Level
Basis
Action to be Taken
Total VOCs
Work
Area
30 ppm
1/10 ACGIH TLV for gasoline

Readings sustain for 15 minutes
Report reading to site management, evaluate

work practices. If VOC detected, conduct
further evaluation.
Benzene
Work
Area
0.5 ppm
OSHA PEL Action level Readings

sustained for 15 minutes
Evacuate area or don air purifying respirator;

report reading to site management.
Benzene
Work
Area
2.5 ppm
ACGIH STEL Reading sustained for

15 minutes

Hexane
Work
Ares
50 ppm
ACGIH TLV-TWA for n-Hexane

Reading sustained for 15 minutes

Hydrogen Sulfide
Work
Area
1 ppm
ACGIH TLV Reading sustained for

15 minutes
Evacuate area, report reading to site

management.
Combustion Products*
WHO guidelines for vegetation fire
events Reading sustained for 15
minutes
WHO guidelines for vegetation fire
events Reading sustained for 15
minutes
Particulate
Matter**
Work
Area
0.150
3
mg/m
Particulate
Matter**
Work
Area
0.350
3
mg/m
Carbon
Monoxide
Work
Area
25 ppm

15 minutes
Sulfur Dioxide
Work
Area
0.25 ppm
ACGIH STEL Reading sustained for

5 minutes
Nitrogen Dioxide
Work
Area
0.2 ppm

15 minutes
Formaldehyde
Work
Area
0.2 ppm
2/3 ACGIH Ceiling Instantaneous

Reading
Report reading to site management, notify

workers of potential for mild aggravation of
symptoms.
Recommend respiratory protection for
particulate matter (primarily for sensitive
individuals).
Report reading to site management, evaluate
work practices.
Evacuate area - Report reading to Site
management.
Report reading to site management,
recommend engineering control if possible.
recommend engineering control if possible.
*These components may be monitored for if active fire/smoke is visible.
Page 1 of 5
Version 1.0

Version: 1.0
**Particulate matter may be measured as PM10.
Plan/Assignment: COMMUNITY
Objective: Report levels that minimize nuisance levels in the community
Analyte
Plan
Action Level
Basis
Action to be Taken
Total VOCs
Comm.
Detection
Instrument detection limit
Report reading to Project Technical

Director
Combustion Products*
Particulate
Matter **
Comm.
0.039
mg/m3
Wildfire Smoke Guidelines for 1 -3

hr. avg. Moderate AQI

evaluate work practices, distribute
information about exposure avoidance.
Particulate
Matter **
Comm.
0.138
mg/m3
Wildfire Smoke Guidelines for 1 -3

hr. avg. Unhealthy for Sensitive
Groups
Report reading to site management, if

smoke event is projected to be prolonged,
notify possible sites for cleaner air shelters.
*These components will be monitored for if active fire/smoke is visible.

** Particulate matter will be measured as PM10.
Plan: All FLAMMABILITY

Objective: Report areas where flammability is most likely
Analyte Instrument Corrected Value
Correction Factor
Reading
Basis
Action to be Taken
LEL
1%
2.5 %
2.5 for crude oil LEL*
1% LEL
Egress and notify site management
VOCs
NA
NA
NA For crude oil PID
1% LEL as VOC
Egress and notify site management
*Rough estimate based on common crude oil volatiles
Page 2 of 5
Version 1.0

Version: 1.0
Methods
Real-Time Methods
Chemical
VOC
Benzene
Hexane
Hydrogen
Sulfide
LEL
MultiRAE
Detection
Limit*
0.1 ppm
PID 10.6 eV lamp
Measuring range: 0 5,000
NA
AreaRAE
0.1 ppm
PID 10.6 eV lamp
NA
UltraRAE
0.05 ppm
PID 9.8 eV lamp
Change SEP tube frequently (Ben. Cal Gas)
NA
MultiRAE
0.05 ppm
PID 10.6 eV lamp
0.47
AreaRAE
0.05 ppm
PID 10.6 eV lamp
0.47
Colorimetric
0.05 ppm
Gastec tube #121L
Range: 0.1 to 10 Volume: 500 ml
MultiRAE
0.43 ppm
PID 10.6 eV lamp
4.3
AreaRAE
0.43 ppm
PID 10.6 eV lamp
4.3
Colorimetric
1 ppm
Gastec tube #102L
Range: 4 to 50 Volume: 500 ml
1/12
MultiRAE
1 ppm
Sensor
Measuring range: 0 100 ppm
AreaRAE
1 ppm
Sensor
MultiRAE
0.33 ppm
PID 10.6 eV lamp
3.3
AreaRAE
0.33 ppm
PID 10.6 eV lamp
3.3
Colorimetric
0.1 ppm
Gastec tube #4LL
Range:0.25 to 2.5 Volume: 1,000 ml
1/10
MultiRAE
2.5 %
Sensor
Measuring range: 0 100%
2.5
AreaRAE
2.5 %
Sensor
Measuring range: 0 100%
2.5
Instrument
Tube#/Lamp
Correction
Factor
Notes
Combustion Products
670 nm Laser diode PM2.5 impactor 50% cut-off at 2.5 micron
PM10 impactor 50% cut-off at 10 micron
Sensor
Range: 0 500 ppm
SidePak
AM510
MultiRAE
0.001
mg/m3
1 ppm
Colorimetric
0.5 ppm
Gastec tube #1LC
Range: 0 30 ppm;
Sulfur
Dioxide
Colorimetric
0.05 ppm
Gastec tube #5Lb
Range: 0.05 30 ppm;
Volume: 800 ml
1/4
Nitrogen
Dioxide
Colorimetric
0.1 ppm
Gastec tube #9L
Range: 0.5 0.1 ppm;
Volume: 200 ml
Formaldehyde
Colorimetric
0.05 ppm
Gastec tube #91L
Range: 0.1 5 ppm;
PM10
Carbon
Monoxide
Volume: 100 ml
Volume: 500 ml
*For electronic instruments the detection limit and range is listed as the resolution adjusted by the correction factor.
Page 3 of 5
Version 1.0
NA

Version: 1.0
Analyte
Media/Can
Analytical Methods
Method
VOCs
Mini - Cans
PNAH
37PTFE 2.0 /
Treated
Amberlite XAD-2
Mod. NIOSH 5506
Aldehyde
Assay 571
Mod. OSHA 1007
BTEX (+Hexane)
3M 3520 Badge
EPA TO-15 with TICs
Modified NIOSH 1500/1501
Detection Limit
Compare to
appropriate
health based
exposure limit
Compare to
appropriate
health based
exposure limit
Compare to
appropriate
health based
exposure limit
Compare to
appropriate
health based
exposure limit
Target compounds
Benzene, Toluene, m,pXylene, 4-Ethyltoluene, 1,2,4trimethylbenzene, 1,2,5trimethylbenzene, Methylcyclopentane, Cyclohexane,
Pentane, Hexane, Heptane,
Octane, Decane, 2-methylbutane
18 PNAH Profile
Aldehyde Profile
Benzene, Toluene,
Ethylbenzene, Xylene,
Hexane.
General Information on Procedures (Assessment Techniques) Used

Procedure
Guardian Network
Hand-held Survey
Analytical sampling
Page 4 of 5
Description
A Guardian network may be established with AreaRAEs equipped with electrochemical
sensors will be positioned at established locations around the work zone. The
AreaRAEs will be telemetering instantaneous data at 15-second intervals to a computer
console. MultiRAE Pros may also be used in the network. The data will be visible in
real-time at the computer console and will be monitored 24 hours per day by CTEH
personnel.
CTEH staff members may utilize handheld instruments (e.g. MultiRAE Plus; ppbRAE,
Gastec colorimetric detector tubes, etc.) to measure airborne chemical concentrations.
CTEH will use these hand-held instruments primarily to measure the breathing zone.
Additionally, measurements can be made at grade level, as well as in elevated
workspaces, as indicated by chemical properties or site conditions. CTEH may also use
these techniques to verify detections observed by the AreaRAE network.
Analytical sampling may be used to validate the fixed station and hand-held data
monitoring data, or to provide data beyond the scope of the real-time instruments.
Analytical samples may be collected as whole air samples in evacuated canisters or on
specific collection media, and sent to an off-site laboratory for further chemical
analysis.
Version 1.0

Version: 1.0
Sampling Areas
Sampling Area
Work Area
Hot Zone
Community
Other
Description
The general area around the incident location where workers are actively or sporadically participating
in remediation activities.
The spill area where all major spill cleanup operations will be performed. Generally requiring a level of
personal protection above that required in the general work area.
The general area around the incident location where individuals not participating in remediation
activities could potentially be exposed to the spilled chemicals.
During the course of the remediation, some additional areas or specific tasks may require a unique set
of action levels or sampling (e.g. decontamination zones, commercial zones, etc.)
Quality Assurance/Quality Control Procedures

Method
Real-time
Analytical
Procedure
Real time instruments may be calibrated in excess of the manufacturers recommendations.
o At a minimum whenever indicated by site conditions or instrument readings.
Co-located sampling for analytical analysis may be conducted, if necessary, to assess accuracy
and precision in the field.
Lot numbers and expiration dates may be recorded with use of Gastec colorimetric tubes.
Chain of custody documents may be completed for each sample.
Name/Position
Prepared By:
Page 5 of 5
Mike Berg, Ph.D.
Signature
Date Signed
11/10/2014
Version 1.0
Appendix E:
Demonstration Maps
Real-Time Hand-Held Air Monitoring Locations
Bakken Crude Burn Demonstration
(
!
PM10
0.023 mg/m3
PM10
0.006 mg/m3
(!
(
!!
(
Project: 106829
Client: Williams Fire and Hazard Control
City: Beaumont, TX
County: Jefferson
PM10
0.018 mg/m3
!!
(
(!
(!
(
(
!
(
!
!!
(
(
(
!
PM10
0.023 mg/m3
!
( !
!
((
(
!
!
(
(
!
(
!
VOC
5.7 ppm
(
!
(
!
(
!
(
!
VOC
1.2 ppm
!
(
(
!
(
!!
(
(
!
(
!
VOC
0.2 ppm
(
!
(
!
!!
(
(
(
!
!
(
(
!
Legend
Real-Time Monitoring Location

(
!
(
!
0
VOC
0.1 ppm
Detection
No Detection
50
100
PROJECTION SYSTEM: UTM Zone 15N
200
Feet
COORDINATE SYSTEM: North American Datum 1983
Print Date: 12/1/2014
Appendix F:
AreaRAE Charts
Appendix G:
Galson Laboratory Report
Mr. Mike Berg

Center for Toxicology & Env. Health LLC
5120 North Shore Drive
North Little Rock, AR 72118
DOH ELAP #11626
AIHA-LAP #100324
Account# 13913
November 24, 2014
Login# L333388
Dear Mr. Berg:

Enclosed are the analytical results for the samples received by our laboratory on November 14, 2014. All
test results meet the quality control requirements of AIHA-LAP and NELAC unless otherwise stated in this
report. All samples on the chain of custody were received in good condition unless otherwise noted.
Please note the ID discrepancy recorded on the attached chain of custody. Per your request, the ID
from the actual sample has been used for this report.
Results in this report are based on the sampling data provided by the client and refer only to the samples
as they were received at the laboratory. Unless otherwise requested, all samples will be discarded 14 days
from the date of this report, with the exception of IOMs, which will be cleaned and disposed of after
seven calendar days.
Current Scopes of Accreditation can be viewed at www.galsonlabs.com in the accreditations section under
the "about Galson" tab.
Please contact Pamela Weaver at (888) 432-5227, if you would like any additional information regarding
this report.
Thank you for using Galson Laboratories.
Sincerely,
Galson Laboratories
[qcsig]
Mary G. Unangst
Laboratory Director
Enclosure(s)
Page 1 of 80
Report Reference:1 Generated:24-NOV-14 16:50
LABORATORY ANALYSIS REPORT
Client
Site
Project No.
: Center for Toxicology & Env. Health LLC

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
6601 Kirkville Road

East Syracuse, NY 13057
(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client ID : BETX1111PAH001
Date Sampled : 11/11/14
1-Nitropyrene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(e)pyrene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenzo(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Account No.: 13913

Login No. : L333388
Lab ID : L333388-13
Date Analyzed : 11/17/14
LOQ
ug
Parameter
11-NOV-14
14-NOV-14
17-NOV-14
859254
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
Filter
ug
Front
ug
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
Air Volume : 236.46 Liter
Back
ug
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
Total
ug
<0.4
<0.3
<0.3
<0.4
<0.4
<0.5
<0.4
<0.4
<0.5
<0.4
<0.4
<0.4
<0.4
<0.3
<0.5
<0.3
<0.3
<0.4
Conc
mg/m3
<0.002
<0.001
<0.001
<0.001
<0.002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.001
<0.002
<0.001
<0.001
<0.002
ppm
<0.0001
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0003
<0.0002
<0.0002
COMMENTS: Please see attached lab footnote report for any applicable footnotes.
Collection Media
: FilterTube
Supervisor: MWJ
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected
Field sampling was not performed by Galson.

provided by clients.
Page 2 of 80
Submitted by: CRD

Approved by : tlh
Date : 21-NOV-14 NYS DOH # : 11626
QC by: AMD
m3 -Cubic Meters
l
-Liters
ppm -Parts per Million
kg -Kilograms
NS -Not Specified
LOQ-Limit of Quantitation
Galson presents results based on sampling data
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
1-Nitropyrene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(e)pyrene
Chrysene
Fluoranthene
Fluorene
Naphthalene
Phenanthrene
Pyrene
Account No.: 13913

Login No. : L333388
Lab ID : L333388-14
LOQ
ug
Parameter
11-NOV-14
14-NOV-14
17-NOV-14
859254
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
Filter
ug
Front
ug
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
Back
ug
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
Total
ug
<0.4
<0.3
<0.3
<0.4
<0.4
<0.5
<0.4
<0.4
<0.5
<0.4
<0.4
<0.4
<0.4
<0.3
<0.5
<0.3
<0.3
<0.4
Conc
mg/m3
<0.001
<0.001
<0.001
<0.001
<0.002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.001
<0.001
<0.002
<0.001
<0.001
<0.001
ppm
<0.0001
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0001
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
Collection Media
: FilterTube
Supervisor: MWJ
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected

Page 3 of 80
Submitted by: CRD

Approved by : tlh
Date : 21-NOV-14 NYS DOH # : 11626
QC by: AMD
m3 -Cubic Meters
l
-Liters
kg -Kilograms
NS -Not Specified
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
1-Nitropyrene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(e)pyrene
Chrysene
Fluoranthene
Fluorene
Naphthalene
Phenanthrene
Pyrene
Account No.: 13913

Login No. : L333388
Lab ID : L333388-15
LOQ
ug
Parameter
11-NOV-14
14-NOV-14
17-NOV-14
859254
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
Filter
ug
Front
ug
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
Back
ug
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
Total
ug
<0.4
<0.3
<0.3
<0.4
<0.4
<0.5
<0.4
<0.4
<0.5
<0.4
<0.4
<0.4
<0.4
<0.3
<0.5
<0.3
<0.3
<0.4
Conc
mg/m3
<0.002
<0.001
<0.001
<0.001
<0.002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.001
<0.002
<0.001
<0.001
<0.002
ppm
<0.0001
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.0003
<0.0002
<0.0002
Collection Media
: FilterTube
Supervisor: MWJ
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected

Page 4 of 80
Submitted by: CRD

Approved by : tlh
Date : 21-NOV-14 NYS DOH # : 11626
QC by: AMD
m3 -Cubic Meters
l
-Liters
kg -Kilograms
NS -Not Specified
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
1-Nitropyrene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(e)pyrene
Chrysene
Fluoranthene
Fluorene
Naphthalene
Phenanthrene
Pyrene
Account No.: 13913

Login No. : L333388
Lab ID : L333388-16
LOQ
ug
Parameter
11-NOV-14
14-NOV-14
17-NOV-14
859254
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
Filter
ug
Front
ug
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
Air Volume : NA
Back
ug
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
Total
ug
<0.4
<0.3
<0.3
<0.4
<0.4
<0.5
<0.4
<0.4
<0.5
<0.4
<0.4
<0.4
<0.4
<0.3
<0.5
<0.3
<0.3
<0.4
Conc
mg/m3
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
ppm
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Collection Media
: FilterTube
Supervisor: MWJ
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected

Page 5 of 80
Submitted by: CRD

Approved by : tlh
Date : 21-NOV-14 NYS DOH # : 11626
QC by: AMD
m3 -Cubic Meters
l
-Liters
kg -Kilograms
NS -Not Specified
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
Client ID : L. HALL
11-NOV-14
14-NOV-14
17-NOV-14
859353
Account No.: 13913

Login No. : L333388
Lab ID : L333388-9
Time : 100 minutes
LOQ
ug
Parameter
Acetaldehyde
Benzaldehyde
Butyraldehyde
Crotonaldehyde
Formaldehyde
Isovaleraldehyde
Propionaldehyde
Valeraldehyde
Raw
ug
0.2
0.2
0.2
0.2
0.1
0.2
0.2
0.2
<0.2
<0.2
<0.2
<0.2
<0.1
<0.2
<0.2
<0.2
Total
ug
<0.2
<0.2
<0.2
<0.2
<0.1
<0.2
<0.2
<0.2
Conc
mg/m3
<0.2
<0.3
<0.3
<0.3
<0.06
<0.3
<0.2
<0.3
ppm
<0.1
<0.07
<0.1
<0.09
<0.05
<0.09
<0.09
<0.09
Collection Media
: AN571
Supervisor: MWJ
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected

Page 6 of 80
Submitted by: MWJ

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
QC by: AMD
m3 -Cubic Meters
l
-Liters
kg -Kilograms
NS -Not Specified
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
Client ID : T. JOHNSON
11-NOV-14
14-NOV-14
17-NOV-14
859353
Account No.: 13913

Login No. : L333388
Lab ID : L333388-10
LOQ
ug
Parameter
Acetaldehyde
Benzaldehyde
Butyraldehyde
Crotonaldehyde
Formaldehyde
Isovaleraldehyde
Propionaldehyde
Valeraldehyde
Raw
ug
0.2
0.2
0.2
0.2
0.1
0.2
0.2
0.2
<0.2
<0.2
<0.2
<0.2
<0.1
<0.2
<0.2
<0.2
Time : 100 minutes
Total
ug
<0.2
<0.2
<0.2
<0.2
<0.1
<0.2
<0.2
<0.2
Conc
mg/m3
<0.2
<0.3
<0.3
<0.3
<0.06
<0.3
<0.2
<0.3
ppm
<0.1
<0.07
<0.1
<0.09
<0.05
<0.09
<0.09
<0.09
Collection Media
: AN571
Supervisor: MWJ
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected

Page 7 of 80
Submitted by: MWJ

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
QC by: AMD
m3 -Cubic Meters
l
-Liters
kg -Kilograms
NS -Not Specified
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
Client ID : BLANK
11-NOV-14
14-NOV-14
17-NOV-14
859353
Account No.: 13913

Login No. : L333388
Lab ID : L333388-11
LOQ
ug
Parameter
Acetaldehyde
Benzaldehyde
Butyraldehyde
Crotonaldehyde
Formaldehyde
Isovaleraldehyde
Propionaldehyde
Valeraldehyde
Raw
ug
0.2
0.2
0.2
0.2
0.1
0.2
0.2
0.2
<0.2
<0.2
<0.2
<0.2
<0.1
<0.2
<0.2
<0.2
Time : NA
Total
ug
Conc
mg/m3
<0.2
<0.2
<0.2
<0.2
<0.1
<0.2
<0.2
<0.2
NA
NA
NA
NA
NA
NA
NA
NA
ppm
NA
NA
NA
NA
NA
NA
NA
NA
Collection Media
: AN571
Supervisor: MWJ
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected

Page 8 of 80
Submitted by: MWJ

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
QC by: AMD
m3 -Cubic Meters
l
-Liters
kg -Kilograms
NS -Not Specified
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
Client ID : BETX1111GB001
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-1
MDL
ppbv
Parameter
Propylene
Freon-12
Chloromethane
Freon-114
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Vinyl Bromide
Freon-11
Isopropyl Alcohol
Acetone
1,1-Dichloroethene
Methylene Chloride
Freon-113
Allyl Chloride
Carbon Disulfide
Trans-1,2-Dichloroethene
Methyl Tert-Butyl Ether
1,1-Dichloroethane
Vinyl Acetate
Methyl Ethyl Ketone
cis-1,2-Dichloroethylene
Hexane
Ethyl Acetate
4000
400
400
400
400
400
400
400
400
400
5000
50000
400
400
400
400
400
400
400
400
400
400
400
4000
400
LOQ
ppbv
10000
1000
1000
1000
1000
1000
1000
1000
1000
1000
5000
50000
1000
1000
1000
1000
2000
1000
1000
1000
1000
1000
1000
10000
1000
Result
ppbv
220000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
190000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
44000
ND
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
2000
200
200
200
200
200
200
200
200
200
200
2000
200
200
200
200
200
200
200
200
200
200
200
2000
200
Analytical Method : mod. OSHA PV2120/mod. EPA

Collection Media : Mini Can
Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 9 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
ppbv-Parts per Billion Volume
LOQ -Limit of Quantitation
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-1
MDL
ppbv
Parameter
Chloroform
Tetrahydrofuran
1,2-Dichloroethane
1,1,1-Trichloroethane
Cyclohexane
Carbon Tetrachloride
Benzene
1,4-Dioxane
2,2,4-Trimethylpentane
Heptane
1,2-Dichloropropane
Trichloroethylene
Bromodichloromethane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Toluene
Dibromochloromethane
Methyl Isobutyl Ketone
Methyl Butyl Ketone
1,2-Dibromoethane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
Bromoform
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
LOQ
ppbv
1000
1000
1000
1000
1000
1000
1000
4000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
4000
4000
1000
1000
1000
1000
1000
Result
ppbv
ND
ND
ND
ND
Qualifier
U
U
U
U
8500
ND
4000
ND
ND
U
U
9700
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
2800
ND
ND
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
U
U
Dilution
Factor
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 10 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-1
MDL
ppbv
Parameter
m & p-xylene
Styrene
o-Xylene
1,1,2,2-Tetrachloroethane
4-Ethyltoluene
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
Benzyl Chloride
1,4-Dichlorobenzene
1,2-Dichlorobenzene
600
400
400
400
400
400
400
400
400
400
400
LOQ
ppbv
2000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
Result
ppbv
910
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
J
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
200
200
200
200
200
200
200
200
200
200
200

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 11 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-2
MDL
ppbv
Parameter
Propylene
Freon-12
Chloromethane
Freon-114
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Vinyl Bromide
Freon-11
Isopropyl Alcohol
Acetone
1,1-Dichloroethene
Methylene Chloride
Freon-113
Allyl Chloride
Carbon Disulfide
1,1-Dichloroethane
Vinyl Acetate
Methyl Ethyl Ketone
Hexane
Ethyl Acetate
4000
400
400
400
400
400
400
400
400
400
5000
50000
400
400
400
400
400
400
400
400
400
400
400
4000
400
LOQ
ppbv
10000
1000
1000
1000
1000
1000
1000
1000
1000
1000
5000
50000
1000
1000
1000
1000
2000
1000
1000
1000
1000
1000
1000
10000
1000
Result
ppbv
250000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
110000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
52000
ND
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
2000
200
200
200
200
200
200
200
200
200
200
2000
200
200
200
200
200
200
200
200
200
200
200
2000
200

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 12 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-2
MDL
ppbv
Parameter
Chloroform
Tetrahydrofuran
1,2-Dichloroethane
Cyclohexane
Benzene
1,4-Dioxane
Heptane
1,2-Dichloropropane
Trichloroethylene
Toluene
Methyl Butyl Ketone
1,2-Dibromoethane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
Bromoform
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
LOQ
ppbv
1000
1000
1000
1000
1000
1000
1000
4000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
4000
4000
1000
1000
1000
1000
1000
Result
ppbv
ND
ND
ND
ND
Qualifier
U
U
U
U
9500
ND
4300
ND
ND
11000
ND
ND
ND
ND
ND
ND
3000
ND
ND
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 13 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-2
MDL
ppbv
Parameter
m & p-xylene
Styrene
o-Xylene
4-Ethyltoluene
1,3-Dichlorobenzene
Benzyl Chloride
1,4-Dichlorobenzene
1,2-Dichlorobenzene
600
400
400
400
400
400
400
400
400
400
400
LOQ
ppbv
2000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
Result
ppbv
990
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
J
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
200
200
200
200
200
200
200
200
200
200
200

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 14 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-3
MDL
ppbv
Parameter
Propylene
Freon-12
Chloromethane
Freon-114
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Vinyl Bromide
Freon-11
Isopropyl Alcohol
Acetone
1,1-Dichloroethene
Methylene Chloride
Freon-113
Allyl Chloride
Carbon Disulfide
1,1-Dichloroethane
Vinyl Acetate
Methyl Ethyl Ketone
Hexane
Ethyl Acetate
2
2
2
2
2
2
2
2
2
2
25
25
2
2
2
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
25
25
5.0
5.0
5.0
5.0
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Result
ppbv
Qualifier
13
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 15 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-3
Parameter
MDL
ppbv
Chloroform
Tetrahydrofuran
1,2-Dichloroethane
Cyclohexane
Benzene
1,4-Dioxane
Heptane
1,2-Dichloropropane
Trichloroethylene
Toluene
Methyl Butyl Ketone
1,2-Dibromoethane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
Bromoform
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
20
5.0
5.0
5.0
5.0
5.0
Result
ppbv
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 16 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-3
Parameter
MDL
ppbv
m & p-xylene
Styrene
o-Xylene
4-Ethyltoluene
1,3-Dichlorobenzene
Benzyl Chloride
1,4-Dichlorobenzene
1,2-Dichlorobenzene
3
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Result
ppbv
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 17 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
Client ID : BETX1111MC001
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-4
MDL
ppbv
Parameter
Propylene
Freon-12
Chloromethane
Freon-114
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Vinyl Bromide
Freon-11
Isopropyl Alcohol
Acetone
1,1-Dichloroethene
Methylene Chloride
Freon-113
Allyl Chloride
Carbon Disulfide
1,1-Dichloroethane
Vinyl Acetate
Methyl Ethyl Ketone
Hexane
Ethyl Acetate
2
2
2
2
2
2
2
2
2
2
25
25
2
2
2
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
25
25
5.0
5.0
5.0
5.0
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Result
ppbv
3.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.2
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 18 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-4
Parameter
MDL
ppbv
Chloroform
Tetrahydrofuran
1,2-Dichloroethane
Cyclohexane
Benzene
1,4-Dioxane
Heptane
1,2-Dichloropropane
Trichloroethylene
Toluene
Methyl Butyl Ketone
1,2-Dibromoethane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
Bromoform
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
20
5.0
5.0
5.0
5.0
5.0
Result
ppbv
ND
ND
ND
ND
ND
ND
ND
ND
2.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 19 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-4
Parameter
MDL
ppbv
m & p-xylene
Styrene
o-Xylene
4-Ethyltoluene
1,3-Dichlorobenzene
Benzyl Chloride
1,4-Dichlorobenzene
1,2-Dichlorobenzene
3
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Result
ppbv
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 20 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-5
MDL
ppbv
Parameter
Propylene
Freon-12
Chloromethane
Freon-114
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Vinyl Bromide
Freon-11
Isopropyl Alcohol
Acetone
1,1-Dichloroethene
Methylene Chloride
Freon-113
Allyl Chloride
Carbon Disulfide
1,1-Dichloroethane
Vinyl Acetate
Methyl Ethyl Ketone
Hexane
Ethyl Acetate
2
2
2
2
2
2
2
2
2
2
25
100
2
2
2
2
2
2
2
2
2
2
2
8
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
25
100
5.0
5.0
5.0
5.0
10
5.0
5.0
5.0
5.0
5.0
5.0
20
5.0
Result
ppbv
Qualifier
130
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
U
U
U
U
300
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
U
U
U
U
U
300
ND
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
4
1
1
1
1
1
1
1
1
1
1
1
4
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 21 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-5
Parameter
MDL
ppbv
Chloroform
Tetrahydrofuran
1,2-Dichloroethane
Cyclohexane
Benzene
1,4-Dioxane
Heptane
1,2-Dichloropropane
Trichloroethylene
Toluene
Methyl Butyl Ketone
1,2-Dibromoethane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
Bromoform
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
20
5.0
5.0
5.0
5.0
5.0
Result
ppbv
ND
2.5
ND
ND
89
ND
39
ND
33
110
ND
ND
ND
ND
ND
ND
36
ND
ND
ND
ND
ND
ND
2.7
ND
Qualifier
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 22 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-5
Parameter
MDL
ppbv
m & p-xylene
Styrene
o-Xylene
4-Ethyltoluene
1,3-Dichlorobenzene
Benzyl Chloride
1,4-Dichlorobenzene
1,2-Dichlorobenzene
3
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Result
ppbv
Qualifier
11
ND
3.3
ND
ND
ND
ND
ND
ND
ND
ND
U
J
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 23 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-6
MDL
ppbv
Parameter
Propylene
Freon-12
Chloromethane
Freon-114
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Vinyl Bromide
Freon-11
Isopropyl Alcohol
Acetone
1,1-Dichloroethene
Methylene Chloride
Freon-113
Allyl Chloride
Carbon Disulfide
1,1-Dichloroethane
Vinyl Acetate
Methyl Ethyl Ketone
Hexane
Ethyl Acetate
2
2
2
2
2
2
2
2
2
2
25
62.5
2
2
2
2
2
2
2
2
2
2
2
5
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
25
62.5
5.0
5.0
5.0
5.0
10
5.0
5.0
5.0
5.0
5.0
5.0
12.5
5.0
Result
ppbv
Qualifier
100
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
U
U
U
U
250
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
U
U
U
U
U
230
ND
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
2.5
1
1
1
1
1
1
1
1
1
1
1
2.5
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 24 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-6
Parameter
MDL
ppbv
Chloroform
Tetrahydrofuran
1,2-Dichloroethane
Cyclohexane
Benzene
1,4-Dioxane
Heptane
1,2-Dichloropropane
Trichloroethylene
Toluene
Methyl Butyl Ketone
1,2-Dibromoethane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
Bromoform
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
20
5.0
5.0
5.0
5.0
5.0
Result
ppbv
ND
ND
ND
ND
Qualifier
U
U
U
U
63
ND
28
ND
83
77
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
30
ND
ND
ND
ND
2.7
ND
2.8
ND
U
U
U
U
J
U
J
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 25 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-6
Parameter
MDL
ppbv
m & p-xylene
Styrene
o-Xylene
4-Ethyltoluene
1,3-Dichlorobenzene
Benzyl Chloride
1,4-Dichlorobenzene
1,2-Dichlorobenzene
3
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Result
ppbv
9.2
ND
3.0
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
J
U
J
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 26 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-17
MDL
ppbv
Parameter
Propylene
Freon-12
Chloromethane
Freon-114
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Vinyl Bromide
Freon-11
Isopropyl Alcohol
Acetone
1,1-Dichloroethene
Methylene Chloride
Freon-113
Allyl Chloride
Carbon Disulfide
1,1-Dichloroethane
Vinyl Acetate
Methyl Ethyl Ketone
Hexane
Ethyl Acetate
2
2
2
2
2
2
2
2
2
2
25
25
2
2
2
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
25
25
5.0
5.0
5.0
5.0
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Result
ppbv
4.9
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.8
ND
Qualifier
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 27 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-17
Parameter
MDL
ppbv
Chloroform
Tetrahydrofuran
1,2-Dichloroethane
Cyclohexane
Benzene
1,4-Dioxane
Heptane
1,2-Dichloropropane
Trichloroethylene
Toluene
Methyl Butyl Ketone
1,2-Dibromoethane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
Bromoform
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
20
5.0
5.0
5.0
5.0
5.0
Result
ppbv
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 28 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-17
Parameter
MDL
ppbv
m & p-xylene
Styrene
o-Xylene
4-Ethyltoluene
1,3-Dichlorobenzene
Benzyl Chloride
1,4-Dichlorobenzene
1,2-Dichlorobenzene
3
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Result
ppbv
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 29 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-18
MDL
ppbv
Parameter
Propylene
Freon-12
Chloromethane
Freon-114
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Vinyl Bromide
Freon-11
Isopropyl Alcohol
Acetone
1,1-Dichloroethene
Methylene Chloride
Freon-113
Allyl Chloride
Carbon Disulfide
1,1-Dichloroethane
Vinyl Acetate
Methyl Ethyl Ketone
Hexane
Ethyl Acetate
2
2
2
2
2
2
2
2
2
2
25
25
2
2
2
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
25
25
5.0
5.0
5.0
5.0
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Result
ppbv
2.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 30 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-18
Parameter
MDL
ppbv
Chloroform
Tetrahydrofuran
1,2-Dichloroethane
Cyclohexane
Benzene
1,4-Dioxane
Heptane
1,2-Dichloropropane
Trichloroethylene
Toluene
Methyl Butyl Ketone
1,2-Dibromoethane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
Bromoform
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20
20
5.0
5.0
5.0
5.0
5.0
Result
ppbv
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 31 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859644
Account No.: 13913

Login No. : L333388
Lab ID : L333388-18
Parameter
MDL
ppbv
m & p-xylene
Styrene
o-Xylene
4-Ethyltoluene
1,3-Dichlorobenzene
Benzyl Chloride
1,4-Dichlorobenzene
1,2-Dichlorobenzene
3
2
2
2
2
2
2
2
2
2
2
LOQ
ppbv
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Result
ppbv
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Qualifier
U
U
U
U
U
U
U
U
U
U
U
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1

Submitted by: BHB

Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
<
>
NA
NS
-Less Than
-Greater Than
-Not Applicable
-Not Specified
MG
UG
ND
KG
Page 32 of 80
-Milligrams
-Micrograms
-Not Detected
-Kilograms
M3 -Cubic Meters
L
-Liters
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859646
Account No.: 13913

Login No. : L333388
Lab ID : L333388-1
Tentatively Identified Compounds
CAS Number
Isobutane
Butane
Unknown Compound-1
Pentane
Butane, 2,2-dimethylCyclopentane
Pentane, 2-methylPentane, 3-methylCyclopentane, methylHexane, 2-methylPentane, 2,3-dimethylUnknown Compound-2
Hexane, 3-methylCyclopentane, 1,3-dimethyl-, cisCyclopentane, 1,3-dimethyl-, transCyclopentane, 1,2-dimethylCyclohexane, methylHeptane, 2-methylOctane
000075-28-5
000106-97-8
000109-66-0
000075-83-2
000287-92-3
000107-83-5
000096-14-0
000096-37-7
000591-76-4
000565-59-3
000589-34-4
002532-58-3
001759-58-6
002452-99-5
000108-87-2
000592-27-8
000111-65-9
Estimated
Concentration
ppbv
mg/m3
Retention
Time
4.97
5.25
5.41
6.80
7.72
8.60
8.73
9.21
10.89
12.48
12.59
12.75
12.82
13.12
13.22
13.32
14.46
15.67
16.52
140000
150000
1900
170000
1800
15000
44000
22000
27000
3600
1300
1300
4300
2400
2500
3600
8600
1400
2000
340
360
5.5
500
6.3
42
150
79
92
15
5.2
5.1
17
9.8
10
15
35
6.6
9.1

Submitted by: BHB
Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected
m3 -Cubic Meters
l -Liters
NS -Not Specified

kg -Kilograms
page 1 of 8
Page 33 of 80
Qual
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859646
Account No.: 13913

Login No. : L333388
Lab ID : L333388-2
CAS Number
Unknown Compound-1
Isobutane
Unknown Compound-2
Pentane
Butane, 2,2-dimethylCyclopentane
Pentane, 2-methylPentane, 3-methylCyclopentane, methylHexane, 2-methylPentane, 2,3-dimethylUnknown Compound-3
Hexane, 3-methylCyclopentane, 1,3-dimethyl-, cisCyclopentane, 1,3-dimethyl-, transCyclopentane, 1,2-dimethylCyclohexane, methylHeptane, 2-methylCyclohexane, 1,3-dimethyl-, cisOctane
000075-28-5
000109-66-0
000075-83-2
000287-92-3
000107-83-5
000096-14-0
000096-37-7
000591-76-4
000565-59-3
000589-34-4
002532-58-3
001759-58-6
002452-99-5
000108-87-2
000592-27-8
000638-04-0
000111-65-9
Estimated
Concentration
ppbv
mg/m3
Retention
Time
4.40
4.97
5.41
6.81
7.72
8.60
8.73
9.22
10.90
12.48
12.59
12.75
12.83
13.12
13.23
13.33
14.46
15.68
16.06
16.52
5100
150000
1800
170000
1800
15000
45000
23000
27000
3900
1400
1300
4800
2700
2700
3900
10000
1500
1400
2100
6.2
350
4.1
510
6.3
42
160
79
91
16
5.7
5.3
19
11
11
16
41
7.0
6.5
10

Submitted by: BHB
Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected
m3 -Cubic Meters
l -Liters
NS -Not Specified

kg -Kilograms
page 2 of 8
Page 34 of 80
Qual
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859646
Account No.: 13913

Login No. : L333388
Lab ID : L333388-3
CAS Number
Isobutane
Butane
Pentane
000075-28-5
000106-97-8
000109-66-0
Estimated
Concentration
ppbv
mg/m3
Retention
Time
4.97
5.26
6.80
9.2
14
5.8
0.022
0.034
0.017

Submitted by: BHB
Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected
m3 -Cubic Meters
l -Liters
NS -Not Specified

kg -Kilograms
page 3 of 8
Page 35 of 80
Qual
J
J
J
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859646
Account No.: 13913

Login No. : L333388
Lab ID : L333388-4
CAS Number
Methyl Alcohol
000067-56-1
Retention
Time
5.00
Estimated
Concentration
ppbv
mg/m3
7.3
0.0095 J

Submitted by: BHB
Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected
m3 -Cubic Meters
l -Liters
NS -Not Specified

kg -Kilograms
page 4 of 8
Page 36 of 80
Qual
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859646
Account No.: 13913

Login No. : L333388
Lab ID : L333388-5
CAS Number
Isobutane
Butane
Pentane
Pentane, 2-methylPentane, 3-methylCyclopentane, methylHexane, 2-methylPentane, 2,3-dimethylCyclopentane, 1,1-dimethylHexane, 3-methylCyclopentane, 1,3-dimethyl-, cisCyclopentane, 1,3-dimethyl-, transCyclohexane, methylHexane, 2,4-dimethylPentane, 2,3,4-trimethylHeptane, 2-methylHexane, 2,2,5-trimethylOctane
Unknown Compound-1
000075-28-5
000106-97-8
000109-66-0
000107-83-5
000096-14-0
000096-37-7
000591-76-4
000565-59-3
001638-26-2
000589-34-4
002532-58-3
001759-58-6
000108-87-2
000589-43-5
000565-75-3
000592-27-8
003522-94-9
000111-65-9
Estimated
Concentration
ppbv
mg/m3
Retention
Time
4.97
5.26
6.80
8.73
9.22
10.90
12.49
12.59
12.75
12.83
13.12
13.23
14.46
14.79
15.30
15.68
16.17
16.52
18.23
21
77
79
30
16
22
38
18
13
47
26
28
110
19
21
16
13
23
13
0.050
0.18
0.23
0.10
0.056
0.077
0.16
0.073
0.052
0.19
0.11
0.11
0.46
0.090
0.098
0.076
0.067
0.11
0.098

Submitted by: BHB
Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected
m3 -Cubic Meters
l -Liters
NS -Not Specified

kg -Kilograms
page 5 of 8
Page 37 of 80
Qual
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859646
Account No.: 13913

Login No. : L333388
Lab ID : L333388-6
CAS Number
Isobutane
Butane
Pentane
Pentane, 2-methylPentane, 3-methylCyclopentane, methylHexane, 2-methylPentane, 2,3-dimethylHexane, 3-methylCyclopentane, 1,3-dimethyl-, cisCyclopentane, 1,3-dimethyl-, transCyclohexane, methylHexane, 2,5-dimethylHexane, 2,4-dimethylPentane, 2,3,4-trimethylHexane, 2,3-dimethylHexane, 2,2,5-trimethylOctane
Unknown Compound-1
000075-28-5
000106-97-8
000109-66-0
000107-83-5
000096-14-0
000096-37-7
000591-76-4
000565-59-3
000589-34-4
002532-58-3
001759-58-6
000108-87-2
000592-13-2
000589-43-5
000565-75-3
000584-94-1
003522-94-9
000111-65-9
Estimated
Concentration
ppbv
mg/m3
Retention
Time
4.97
5.27
6.81
8.73
9.22
10.90
12.48
12.59
12.83
13.12
13.23
14.46
14.71
14.79
15.30
15.56
16.17
16.52
18.23
23
79
78
29
16
21
27
22
33
19
19
76
15
30
57
19
34
15
33
0.054
0.19
0.23
0.10
0.056
0.072
0.11
0.091
0.14
0.075
0.077
0.31
0.068
0.14
0.26
0.090
0.18
0.069
0.19

Submitted by: BHB
Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected
m3 -Cubic Meters
l -Liters
NS -Not Specified

kg -Kilograms
page 6 of 8
Page 38 of 80
Qual
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
J
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859646
Account No.: 13913

Login No. : L333388
Lab ID : L333388-17
CAS Number
Isobutane
Butane
Pentane
000075-28-5
000106-97-8
000109-66-0
Retention
Time
4.97
5.26
6.80
Estimated
Concentration
ppbv
mg/m3
Qual
5.4
9.6
8.7
J
J
J
0.013
0.023
0.026

Submitted by: BHB
Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected
m3 -Cubic Meters
l -Liters
NS -Not Specified

kg -Kilograms
page 7 of 8
Page 39 of 80
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
11-NOV-14
14-NOV-14
19-NOV-14 - 20-NOV-14
859646
Account No.: 13913

Login No. : L333388
Lab ID : L333388-18
CAS Number
Unknown Compound-1
Retention
Time
4.97
Estimated
Concentration
ppbv
mg/m3
5.4
0.0098 J

Submitted by: BHB
Approved by : nkp
Date : 21-NOV-14 NYS DOH # : 11626
Supervisor: MTW
QC by: AMD
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected
m3 -Cubic Meters
l -Liters
NS -Not Specified

kg -Kilograms
page 8 of 8
Page 40 of 80
Qual
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
Client ID : L. HALL
Benzene
Ethylbenzene
n-Hexane
Toluene
Xylene
Account No.: 13913

Login No. : L333388
Lab ID : L333388-7
Time : 100 Minutes
LOQ
ug
Parameter
11-NOV-14
14-NOV-14
17-NOV-14 - 18-NOV-14
859444
Raw
ug
2
5
5
5
15
16
<5
130
13
<15
Total
ug
16
<5
130
13
<15
Conc
mg/m3
4.4
<2
40
4.1
<5.7
ppm
1.4
<0.4
11
1.1
<1.3
Collection Media
: M3M-3500
Supervisor: KLD
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected

Page 41 of 80
Submitted by: KAG

Approved by : dnf
Date : 21-NOV-14 NYS DOH # : 11626
QC by: AMD
m3 -Cubic Meters
l
-Liters
kg -Kilograms
NS -Not Specified
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
Client ID : T. JOHNSON
Benzene
Ethylbenzene
n-Hexane
Toluene
Xylene
Account No.: 13913

Login No. : L333388
Lab ID : L333388-8
Time : 100 Minutes
LOQ
ug
Parameter
11-NOV-14
14-NOV-14
17-NOV-14 - 18-NOV-14
859444
Raw
ug
2
5
5
5
15
<2
<5
<5
<5
<15
Total
ug
<2
<5
<5
<5
<15
Conc
mg/m3
<0.6
<2
<2
<2
<5.7
ppm
<0.2
<0.4
<0.4
<0.4
<1.3
Collection Media
: M3M-3500
Supervisor: KLD
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected

Page 42 of 80
Submitted by: KAG

Approved by : dnf
Date : 21-NOV-14 NYS DOH # : 11626
QC by: AMD
m3 -Cubic Meters
l
-Liters
kg -Kilograms
NS -Not Specified
6601 Kirkville Road

(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com
Client
Site
Project No.

: NS
: 106829
Date Sampled
Date Received
Date Analyzed
Report ID
:
:
:
:
Client ID : BLANK
Lab ID : L333388-12
LOQ
ug
Parameter
Benzene
Ethylbenzene
n-Hexane
Toluene
Xylene
11-NOV-14
14-NOV-14
17-NOV-14 - 18-NOV-14
859444
Raw
ug
2
5
5
5
15
<2
<5
<5
<5
<15
Account No.: 13913

Login No. : L333388
Time : NA
Total
ug
<2
<5
<5
<5
<15
Conc
mg/m3
NA
NA
NA
NA
NA
ppm
NA
NA
NA
NA
NA
Collection Media
: M3M-3500
Supervisor: KLD
< -Less Than
> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected

Page 43 of 80
Submitted by: KAG

Approved by : dnf
Date : 21-NOV-14 NYS DOH # : 11626
QC by: AMD
m3 -Cubic Meters
l
-Liters
kg -Kilograms
NS -Not Specified
LABORATORY FOOTNOTE REPORT
Client Name
Site
Project No.
6601 Kirkville Road
(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com

:
: 106829
Date Sampled : 11-NOV-14

Date Received: 14-NOV-14
Date Analyzed: 17-NOV-14 - 20-NOV-14
Account No.: 13913

Login No. : L333388
Unless otherwise noted below, all quality control results associated with the samples
were within established control limits or did not impact reported results.
Unrounded results are carried through the calculations that yield the final result and the final
result is rounded to the number of significant figures appropriate to the accuracy of the
analytical method. Please note that results appearing in the columns preceeding the final
result column may have been rounded in order to fit the report format and therefore, if carried
through the calculations, may not yield an identical final result to the one reported.
The stated LOQs for each analyte represent the demonstrated LOQ concentrations prior to correction
for desorption efficiency (if applicable).
Unless otherwise noted below, reported results have not been blank corrected for any field blank or method blank.
L333388 (Report ID: 859254):
SOPs: il-n5506(11)
Results corrected for matrix- and compound-specific desorption efficiencies.
L333388 (Report ID: 859254):
Accuracy and mean recovery data presented below is based on a 95% confidence interval (k=2).
The estimated uncertainty applies to the media, technology, and SOP referenced in this report
and does not account for the uncertainty associated with the sampling process.
< -Less Than

> -Greater Than
NA -Not Applicable
Parameter
Accuracy
Mean Recovery
1-Nitropyrene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(e)pyrene
Chrysene
Fluoranthene
Fluorene
Naphthalene
Phenanthrene
Pyrene
+/-15.7%
+/-11.4%
+/-12.8%
+/-13.9%
+/-11.9%
+/-23%
+/-12.3%
+/-16.4%
+/-18.9%
+/-13.6%
+/-13.4%
+/-12.7%
+/-13%
+/-11.1%
+/-14.8%
+/-13.2%
+/-12.3%
+/-15.5%
108%
102%
99.7%
103%
105%
109%
110%
109%
105%
105%
103%
100%
106%
104%
108%
103%
106%
108%
Parameter
Method
1-Nitropyrene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(e)pyrene
mod.
mod.
mod.
mod.
mod.
mod.
mod.
mod.
mod.
mg -Milligrams
ug -Micrograms
ND -Not Detected
Page 44 of 80
NIOSH
NIOSH
NIOSH
NIOSH
NIOSH
NIOSH
NIOSH
NIOSH
NIOSH
m3 -Cubic Meters
l
-Liters
PEL
5506;
5506;
5506;
5506;
5506;
5506;
5506;
5506;
5506;
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
NA
NA
NA
NA
NA
0.2 mg/m3 (TWA)
NA
NA
NA
kg -Kilograms
NS -Not Specified
Client Name
Site
Project No.
6601 Kirkville Road
(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com

:
: 106829

Account No.: 13913

Login No. : L333388
L333388 (Report ID: 859254):

Parameter
Method
Chrysene
Fluoranthene
Fluorene
Naphthalene
Phenanthrene
Pyrene
mod.
mod.
mod.
mod.
mod.
mod.
mod.
mod.
mod.
PEL
NIOSH
NIOSH
NIOSH
NIOSH
NIOSH
NIOSH
NIOSH
NIOSH
NIOSH
5506;
5506;
5506;
5506;
5506;
5506;
5506;
5506;
5506;
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
NA
0.2 mg/m3 (TWA)
NA
NA
NA
NA
10 ppm (TWA)
NA
NA
L333388 (Report ID: 859353):

SOPs: LC-SOP-4(14)
ACETALDEHYDE - Total ug corrected for a desorption efficiency of 97%.
BENZALDEHYDE - Total ug corrected for a desorption efficiency of 98%.
BUTYRALDEHYDE - Total ug corrected for a desorption efficiency of 86%.
Crotonaldehyde - Total ug corrected for a desorption efficiency of 91%.
FORMALDEHYDE - Total ug corrected for a desorption efficiency of 96%.
ISOVALERALDEHYDE - Total ug corrected for a desorption efficiency of 84%.
PROPIONALDEHYDE - Total ug corrected for a desorption efficiency of 97%.
VALERALDEHYDE - Total ug corrected for a desorption efficiency of 86%.
Formaldehyde results have been corrected for the average background found on the media:
0.0361 ug for lot #12B13.
Acetaldehyde results have been corrected for the average background found on the media:
0.0196 ug for lot #12B13.
L333388 (Report ID: 859353):
< -Less Than

> -Greater Than
NA -Not Applicable
Parameter
Accuracy
Mean Recovery
Acetaldehyde
Benzaldehyde
Butyraldehyde
Crotonaldehyde
Formaldehyde
Isovaleraldehyde
Propionaldehyde
Valeraldehyde
+/-4.4%
+/-4.3%
+/-7.1%
+/-10.5%
+/-8.7%
+/-11.5%
+/-7.2%
+/-4.7%
98.2%
98.1%
103%
100%
97.4%
116%
101%
96.1%
Parameter
Method
Acetaldehyde
Benzaldehyde
Butyraldehyde
Crotonaldehyde
Formaldehyde
Isovaleraldehyde
Propionaldehyde
Valeraldehyde
mod.
mod.
mod.
mod.
mod.
mod.
mod.
mod.
mg -Milligrams
ug -Micrograms
ND -Not Detected
Page 45 of 80
OSHA
OSHA
OSHA
OSHA
OSHA
OSHA
OSHA
OSHA
PEL
1007;
1007;
1007;
1007;
1007;
1007;
1007;
1007;
m3 -Cubic Meters
l
-Liters
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
HPLC/UV
200 ppm (TWA)

NA
NA
2 ppm (TWA)
0.75 ppm (TWA)
NA
NA
NA
kg -Kilograms
NS -Not Specified
Client Name
Site
Project No.
6601 Kirkville Road
(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com

:
: 106829

Account No.: 13913

Login No. : L333388
L333388 (Report ID: 859644):

SOPs: in-vocs(26)
L333388-1-6,17-18 (Report ID: 859644):
Propylene results may be biased high due to co-elution with Propane.
L333388-1-2,5-6 (Report ID: 859644):
Acetone result may be biased high due to co-elution with 2-Methylbutane.
L333388-1-2 (Report ID: 859644):
Elevated levels of quantitation resulting from analysis at a 200x dilution. The dilution was
necessary because several target analytes concentrations exceeded the instrument calibration range.
L333388-4-6 (Report ID: 859644):
Sample canister was received at (or near) ambient pressure, indicating that the sampling
event may have ended prematurely. Reported results may not be representative of the
intended sampling duration.
L333388 (Report ID: 859644):
U = undetected, J = estimated
L333388 (Report ID: 859644):
< -Less Than

> -Greater Than
NA -Not Applicable
Parameter
Accuracy
Mean Recovery
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
4-Ethyltoluene
Allyl Chloride
Acetone
Bromoform
1,3-Butadiene
Benzene
Benzyl Chloride
Carbon Disulfide
Chlorobenzene
+/-27.4%
+/-21.4%
+/-18.3%
+/-18.9%
+/-25.6%
+/-22%
+/-27.4%
+/-23.6%
+/-21.2%
+/-24.6%
+/-25.6%
+/-26.6%
+/-17.8%
+/-20.6%
+/-20.2%
+/-26.4%
+/-20.4%
+/-22.2%
+/-25.2%
+/-18.1%
+/-28.4%
+/-23.4%
+/-21.6%
+/-23.4%
+/-22%
+/-20.6%
88.6%
96.5%
99.4%
102%
94.4%
93.7%
89.5%
99%
96.7%
93.9%
91.8%
92.2%
99.7%
94.4%
98.6%
96%
100%
96.6%
101%
98.5%
96%
107%
99.1%
94.5%
99.9%
93.2%
mg -Milligrams
ug -Micrograms
ND -Not Detected
Page 46 of 80
m3 -Cubic Meters
l
-Liters
kg -Kilograms
NS -Not Specified
Client Name
Site
Project No.
6601 Kirkville Road
(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com

:
: 106829

Chloroform
Cyclohexane
1,4-Dioxane
Ethyl Acetate
Ethylbenzene
Chloroethane
Freon-11
Freon-113
Freon-114
Freon-12
Heptane
Isopropyl Alcohol
Bromomethane
Chloromethane
Methylene Chloride
Methyl Ethyl Ketone
Methyl Butyl Ketone
m & p-xylene
Hexane
o-Xylene
Propylene
Styrene
Trichloroethylene
Tetrachloroethylene
Tetrahydrofuran
Toluene
Vinyl Acetate
Vinyl Bromide
Vinyl Chloride
+/-20.2%
+/-18.3%
+/-18.4%
+/-49%
+/-21%
+/-23%
+/-21.2%
+/-23.4%
+/-16.9%
+/-30%
+/-24.6%
+/-20.6%
+/-31.2%
+/-22%
+/-19.6%
+/-22.8%
+/-18%
+/-24%
+/-24.6%
+/-23.8%
+/-21.4%
+/-19.5%
+/-17.5%
+/-22.6%
+/-28.8%
+/-23.6%
+/-20%
+/-20.4%
+/-23.4%
+/-21.2%
+/-21%
+/-24.2%
+/-24.2%
+/-20%
+/-18.9%
Account No.: 13913

Login No. : L333388
96.6%
98.4%
98.2%
91.1%
96.5%
92.8%
101%
102%
99.8%
93.9%
104%
98.2%
93.1%
97.5%
96.5%
107%
95.9%
100%
97%
96.2%
93.2%
97.4%
98.7%
93.7%
110%
93.8%
99.9%
94.3%
98.9%
95%
106%
102%
91.6%
101%
101%
L333388 (Report ID: 859646):

Tentatively Identified Compounds (TICS) are estimated values. TICS are
calculated using an average response factor of 1 for all compounds.
SOPs: in-vocs(26)
U = undetected, J = estimated
L333388 (Report ID: 859444):
Benzene - Total ug corrected for a desorption efficiency of 100%.
Ethylbenzene - Total ug corrected for a desorption efficiency of 103%.
Toluene - Total ug corrected for a desorption efficiency of 102%.
Xylene - Total ug corrected for a desorption efficiency of 97%.
n-Hexane - Total ug corrected for a desorption efficiency of 103%.
SOPs: GC-SOP-12(8), GC-SOP-16(13), GC-SOP-9(12)
< -Less Than

> -Greater Than
NA -Not Applicable
mg -Milligrams
ug -Micrograms
ND -Not Detected
Page 47 of 80
m3 -Cubic Meters
l
-Liters
kg -Kilograms
NS -Not Specified
Client Name
Site
Project No.
6601 Kirkville Road
(315) 432-5227
FAX: (315) 437-0571
www.galsonlabs.com

:
: 106829

Account No.: 13913

Login No. : L333388
L333388 (Report ID: 859444):

< -Less Than

> -Greater Than
NA -Not Applicable
Parameter
Accuracy
Mean Recovery
Benzene
Ethylbenzene
Toluene
Xylene
n-Hexane
+/-7.2%
+/-8.4%
+/-8%
+/-9.4%
+/-7.3%
95%
94.7%
94.3%
98.5%
95%
Parameter
Method
Benzene
Ethylbenzene
Toluene
Xylene
n-Hexane
mod.
mod.
mod.
mod.
mod.
mg -Milligrams
ug -Micrograms
ND -Not Detected
Page 48 of 80
NIOSH
NIOSH
NIOSH
NIOSH
NIOSH
m3 -Cubic Meters
l
-Liters
PEL
1501; GC/FID BADGE
1501; GC/FID BADGE
1501/OSHA 111; GC/FID BADGE
1501; GC/FID BADGE
1500; GC/FID BADGE
1 ppm (TWA)
100 ppm (TWA)
200 ppm (TWA)
100 ppm (TWA)
500 ppm (TWA)
kg -Kilograms
NS -Not Specified
GC/MS QA-QC Check Report
Tune File : C:\MSDCHEM\1\DATA\P_2014\11\111914\P1119401.D

Tune Time : 11/19/14 09:14
Daily Calibration File : C:\MSDCHEM\1\DATA\P_2014\11\111914\P1119402.D
Internal Standard Areas:
287032
1320292
1337608
Sample
Client ID
File
WG301313-5
Continuing Verifier
P1119402
103
11/19/14 09:54
287032
1320292
1337608
WG301313-2
Lab Control Spike
P1119403
105
11/19/14 10:35
293559
1335678
1302066
WG301313-3
LCS Duplicate
P1119404
102
11/19/14 11:16
285068
1313869
1348981
WG301313-4
DLS
P1119406
100
11/19/14 12:39
247871
1154004
1142565
WG301313-1
Method Blank
P1119407
100
11/19/14 13:20
237859
1110941
1051615
L333388-3
BETX1111GB003
P1119410
99
11/19/14 16:10
209332
980248
898816
L333388-4
BETX1111MC001
P1119411
96
11/19/14 16:49
213639
1008453
985073
L333388-5
BETX1111MC002
P1119412
96
11/19/14 17:29
206980
886096
960804
L333388-6
BETX1111MC003
P1119413
99
11/19/14 18:10
206497
965240
987556
L333388-17
BETX1111GB004
P1119414
91
11/19/14 18:50
210261
975356
956756
L333388-18
BETX1111GB005
P1119415
95
11/19/14 19:30
208478
970668
948965
L333388-1
BETX1111GB001
P1119417
97
11/19/14 20:51
209895
978322
975900
WG301313-6
Continuing Verifier
P1119418
103
11/19/14 21:43
248682
1127363
1140759
L333388-2
BETX1111GB002
P1119419
97
11/19/14 22:35
243463
1057073
1056655
L333388-5
BETX1111MC002
P1119420
98
11/19/14 23:16
215518
1016922
1063193
L333388-6
BETX1111MC003
P1119421
98
11/19/14 23:57
221266
1047387
1083822
WG301313-7
Continuing Verifier
P1119423
102
11/20/14 01:18
222936
1024893
1079405
* = Value outside limits

page 1 of 1
Surr%
Acquired on
Surrogate Limits = 80 - 120
Page 49 of 80
Internal Standard Responses
Internal Standard Limits = +/- 40%
GC/MS QA-QC Check Report
Tune File : C:\MSDCHEM\1\DATA\P_2014\11\112014\P1120401.D

Tune Time : 11/20/14 10:15
Daily Calibration File : C:\MSDCHEM\1\DATA\P_2014\11\112014\P1120402.D
Internal Standard Areas:
230705
1066740
1095590
Sample
Client ID
File
WG301435-5
Continuing Verifier
P1120402
103
11/20/14 10:55
230705
1066740
1095590
WG301435-2
Lab Control Spike
P1120403
102
11/20/14 11:36
235178
1083987
1119080
WG301435-3
LCS Duplicate
P1120404
102
11/20/14 12:17
239794
1094415
1135130
WG301435-4
DLS
P1120406
98
11/20/14 13:40
210939
989303
980637
WG301435-1
Method Blank
P1120407
95
11/20/14 14:20
200836
954167
928867
L333388-1
BETX1111GB001
P1120408
99
11/20/14 15:32
215880
1009708
1016734
L333388-2
BETX1111GB002
P1120409
96
11/20/14 16:12
211335
984493
1014274
WG301435-6
Continuing Verifier
P1120413
101
11/20/14 18:52
193286
888971
954255
* = Value outside limits

page 1 of 1
Surr%
Acquired on
Surrogate Limits = 80 - 120
Page 50 of 80
Internal Standard Responses
Internal Standard Limits = +/- 40%
Galson
Laboratories
ASTD 50ppb STANDARD RECOVERY REPORT
6601 Kirkville Rd. E. Syracuse,NY 13057
Client
Account No.: 13913
Login No. : L333388
Lab Sample ID
Type
Spike Lot #
Instrument
Analysis Date
WG301313-5
CCV
IH491922
MS P
Nov 19, 2014 09:54
Limits
(%)
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Butadiene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Benzyl Chloride
Bromoform
Bromomethane
Carbon Disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cyclohexane
Ethyl Acetate
Ethylbenzene
Freon-11
Freon-113
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
True Value
(ppbv)
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
WG301313-6
CCV
IH491922
MS P
Nov 19, 2014 21:43
WG301313-7
CCV
IH491922
MS P
Nov 20, 2014 01:18
Found
(ppbv)
Recovery
(%)
True Value
(ppbv)
Found
(ppbv)
Recovery
(%)
True Value
(ppbv)
Found
(ppbv)
Recovery
(%)
50.9
53.6
52.0
49.9
50.8
54.6
52.8
55.4
50.5
50.1
54.0
51.8
55.0
56.1
52.8
50.6
53.1
48.1
50.7
50.7
58.2
52.2
58.5
49.5
48.4
51.7
50.9
51.3
50.6
51.2
51.4
51.6
50.3
53.9
50.9
52.0
50.0
49.8
102.
107.
104.
99.7
102.
109.
106.
111.
101.
100.
108.
104.
110.
112.
106.
101.
106.
96.2
101.
101.
116.
104.
117.
99.0
96.7
103.
102.
103.
101.
102.
103.
103.
101.
108.
102.
104.
100.
99.6
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
51.3
55.4
52.2
50.5
52.1
55.4
53.2
55.9
48.8
51.1
55.2
52.9
55.6
56.8
54.0
51.3
54.3
49.8
51.8
51.6
59.3
52.9
58.6
51.8
49.5
52.8
51.4
52.7
51.3
51.6
52.3
52.7
50.5
54.6
53.2
52.0
52.1
51.4
103.
111.
104.
101.
104.
111.
106.
112.
97.5
102.
110.
106.
111.
114.
108.
103.
109.
99.6
104.
103.
119.
106.
117.
104.
99.0
106.
103.
105.
103.
103.
105.
105.
101.
109.
106.
104.
104.
103.
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
53.3
56.1
52.4
51.9
52.4
56.6
53.5
57.2
53.0
52.0
55.7
52.2
58.1
57.5
54.5
52.7
54.9
51.2
51.8
53.4
60.8
54.3
59.3
51.8
50.7
54.4
52.0
52.2
52.7
52.1
53.1
54.1
50.4
54.8
53.9
53.5
53.2
52.6
107.
112.
105.
104.
105.
113.
107.
114.
106.
104.
111.
104.
116.
115.
109.
105.
110.
102.
104.
107.
122.
109.
119.
104.
101.
109.
104.
104.
105.
104.
106.
108.
101.
110.
108.
107.
106.
105.
page 1 of 4
Page 51 of 80
Galson
Laboratories
Freon-114
Freon-12
Heptane
Hexane
Isopropyl Alcohol
m & p-xylene
Methyl Butyl Ketone
Methyl Ethyl Ketone
Methylene Chloride
o-Xylene
Propylene
Styrene
Tetrachloroethylene
Tetrahydrofuran
Toluene
Trichloroethylene
Vinyl Acetate
Vinyl Bromide
Vinyl Chloride
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
Client
Account No.: 13913
Login No. : L333388
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 100.
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
54.6
52.2
50.7
50.8
51.4
104.
52.9
51.1
52.3
50.6
50.2
53.4
47.0
54.3
52.7
51.7
50.6
51.4
53.2
51.5
51.5
51.3
50.4
109.
104.
101.
102.
103.
104.
106.
102.
105.
101.
100.
107.
94.1
109.
105.
103.
101.
103.
106.
103.
103.
103.
101.
50.0
50.0
50.0
50.0
50.0
100.
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
56.1
53.2
51.5
51.1
52.7
106.
54.5
52.1
53.1
52.4
51.6
54.3
47.7
54.9
52.9
52.3
51.7
51.7
54.0
52.6
52.3
53.6
52.2
112.
106.
103.
102.
105.
106.
109.
104.
106.
105.
103.
109.
95.3
110.
106.
105.
103.
103.
108.
105.
105.
107.
104.
page 2 of 4
Page 52 of 80
50.0
50.0
50.0
50.0
50.0
100.
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
57.0
53.4
52.9
52.4
54.0
108.
53.6
51.6
52.6
53.5
53.0
55.4
45.2
55.3
53.2
53.6
51.6
53.2
55.0
53.6
53.5
53.1
51.8
114.
107.
106.
105.
108.
108.
107.
103.
105.
107.
106.
111.
90.3
111.
106.
107.
103.
106.
110.
107.
107.
106.
104.
Galson
Laboratories
Client
Account No.: 13913
Login No. : L333388
Lab Sample ID
Type
Spike Lot #
Instrument
Analysis Date
WG301435-5
CCV
IH491922
MS P
Nov 20, 2014 10:55
Limits
(%)
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Butadiene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Benzyl Chloride
Bromoform
Bromomethane
Carbon Disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cyclohexane
Ethyl Acetate
Ethylbenzene
Freon-11
Freon-113
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
True Value
(ppbv)
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
WG301435-6
CCV
IH491922
MS P
Nov 20, 2014 18:52
Found
(ppbv)
Recovery
(%)
True Value
(ppbv)
Found
(ppbv)
Recovery
(%)
51.1
55.9
52.1
49.9
48.6
56.3
53.4
56.8
51.1
50.8
55.2
51.5
56.7
57.6
54.5
51.3
55.1
50.1
48.1
50.8
60.5
52.6
58.7
50.3
47.3
52.3
51.7
52.0
48.5
51.1
51.6
52.5
50.7
54.6
50.6
52.6
51.6
50.3
102.
112.
104.
99.8
97.2
113.
107.
114.
102.
102.
110.
103.
113.
115.
109.
103.
110.
100.
96.3
102.
121.
105.
117.
101.
94.6
105.
103.
104.
96.9
102.
103.
105.
101.
109.
101.
105.
103.
101.
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
53.2
57.9
52.9
51.0
53.2
58.0
54.3
58.3
53.2
53.5
57.2
52.6
58.4
59.3
55.9
53.3
57.4
51.6
52.2
53.6
62.4
55.3
59.7
51.6
50.6
54.8
52.6
53.0
53.4
51.6
53.6
55.1
52.2
55.9
54.5
54.6
53.7
53.2
106.
116.
106.
102.
106.
116.
109.
117.
106.
107.
114.
105.
117.
119.
112.
107.
115.
103.
104.
107.
125.
111.
119.
103.
101.
110.
105.
106.
107.
103.
107.
110.
104.
112.
109.
109.
107.
106.
page 3 of 4
Page 53 of 80
True Value
()
Found
()
Recovery
(%)
Galson
Laboratories
Freon-114
Freon-12
Heptane
Hexane
Isopropyl Alcohol
m & p-xylene
Methyl Butyl Ketone
Methyl Ethyl Ketone
Methylene Chloride
o-Xylene
Propylene
Styrene
Tetrachloroethylene
Tetrahydrofuran
Toluene
Trichloroethylene
Vinyl Acetate
Vinyl Bromide
Vinyl Chloride
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
Client
Account No.: 13913
Login No. : L333388
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to
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 100.
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
55.0
51.5
51.2
50.4
52.6
107.
53.6
51.7
52.2
51.3
48.8
55.0
46.3
54.8
52.5
51.8
51.2
48.9
53.9
51.6
52.0
52.1
50.7
110.
103.
102.
101.
105.
107.
107.
103.
104.
103.
97.6
110.
92.6
110.
105.
104.
102.
97.8
108.
103.
104.
104.
101.
50.0
50.0
50.0
50.0
50.0
100.
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
57.2
51.8
53.9
52.6
55.1
112.
54.7
53.9
53.3
53.0
53.0
56.8
44.5
57.0
53.5
54.7
52.3
50.9
56.2
54.1
53.8
53.0
51.1
114.
104.
108.
105.
110.
112.
109.
108.
107.
106.
106.
114.
88.9
114.
107.
109.
105.
102.
112.
108.
108.
106.
102.
page 4 of 4
Page 54 of 80
Galson
Laboratories
Client
Account No.: 13913
Login No. : L333388
Lab Sample ID
Type
Spike Lot #
Instrument
Analysis Date
WG301313-4
DLS
IH486743
MS P
Nov 19, 2014 12:39
Limits
(%)
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Butadiene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Benzyl Chloride
Bromoform
Bromomethane
Carbon Disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cyclohexane
Ethyl Acetate
Ethylbenzene
Freon-11
Freon-113
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
to
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to
True Value
(ppbv)
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
WG301435-4
DLS
IH486743
MS P
Nov 20, 2014 13:40
Found
(ppbv)
Recovery
(%)
True Value
(ppbv)
Found
(ppbv)
Recovery
(%)
4.92
4.89
4.94
4.82
4.89
5.16
4.79
5.21
4.77
4.70
5.19
4.98
5.09
5.19
5.00
4.95
5.21
5.56
4.89
4.85
4.97
5.02
4.88
4.79
5.19
4.81
4.90
5.02
4.91
5.16
4.91
4.73
4.74
4.90
4.90
5.05
5.15
5.03
98.4
97.8
98.8
96.4
97.8
103.
95.8
104.
95.4
94.0
104.
99.6
102.
104.
100.
99.0
104.
111.
97.8
97.0
99.4
100.
97.6
95.8
104.
96.2
98.0
100.
98.2
103.
98.2
94.6
94.8
98.0
98.0
101.
103.
101.
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
4.98
4.99
5.27
5.08
5.07
5.28
4.87
5.17
4.85
4.91
5.13
4.91
5.10
5.29
4.87
5.00
5.24
5.58
4.92
4.95
5.00
4.95
4.86
5.02
5.28
5.00
5.08
4.96
5.12
5.30
5.03
4.82
4.76
4.83
4.90
5.19
5.27
5.18
99.6
99.8
105.
102.
101.
106.
97.4
103.
97.0
98.2
103.
98.2
102.
106.
97.4
100.
105.
112.
98.4
99.0
100.
99.0
97.2
100.
106.
100.
102.
99.2
102.
106.
101.
96.4
95.2
96.6
98.0
104.
105.
104.
page 1 of 2
Page 55 of 80
True Value
()
Found
()
Recovery
(%)
Galson
Laboratories
Freon-114
Freon-12
Heptane
Hexane
Isopropyl Alcohol
m & p-xylene
Methyl Butyl Ketone
Methyl Ethyl Ketone
Methylene Chloride
o-Xylene
Propylene
Styrene
Tetrachloroethylene
Tetrahydrofuran
Toluene
Trichloroethylene
Vinyl Acetate
Vinyl Bromide
Vinyl Chloride
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
Client
Account No.: 13913
Login No. : L333388
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to
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 10.0
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
140. 5.00
4.05
4.56
4.91
4.81
5.27
10.2
5.03
4.92
5.01
4.98
4.97
5.03
4.94
4.82
4.91
4.74
5.05
4.75
4.65
4.77
4.91
5.11
4.99
81.0
91.2
98.2
96.2
105.
102.
101.
98.4
100.
99.6
99.4
101.
98.8
96.4
98.2
94.8
101.
95.0
93.0
95.4
98.2
102.
99.8
5.00
5.00
5.00
5.00
5.00
10.0
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
3.96
4.42
4.75
4.98
5.35
10.3
4.87
5.04
5.07
4.99
5.01
5.06
4.97
4.87
5.00
4.95
4.96
4.98
4.84
4.98
4.97
5.18
5.10
79.2
88.4
95.0
99.6
107.
103.
97.4
101.
101.
99.8
100.
101.
99.4
97.4
100.
99.0
99.2
99.6
96.8
99.6
99.4
104.
102.
page 2 of 2
Page 56 of 80
Galson
Laboratories
LCS/LCS DUPLICATE REPORT
Client
Account No.: 13913
Login No. : L333388
Lab Sample ID
Type
Spike Lot #
Instrument
Analysis Date
WG301313-2
LCS
IH490902
MS P
Nov 19, 2014 10:35
Limits
(%)
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Butadiene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Benzyl Chloride
Bromoform
Bromomethane
Carbon Disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cyclohexane
Ethyl Acetate
Ethylbenzene
Freon-11
Freon-113
Freon-114
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
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to
True Value
(ppbv)
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
WG301313-3
LCSD
IH490902
MS P
Nov 19, 2014 11:16
Found
(ppbv)
Recovery
(%)
True Value
(ppbv)
Found
(ppbv)
Recovery
(%)
RPD
RPD
Limits
53.4
50.7
56.6
51.0
53.1
51.4
55.7
52.3
51.5
51.2
51.9
53.5
53.7
54.9
47.7
51.6
49.9
47.4
51.1
52.7
58.4
53.8
59.7
53.0
55.9
53.5
52.0
50.7
51.3
53.0
52.5
51.4
57.1
50.6
53.7
50.4
51.4
51.5
107.
101.
113.
102.
106.
103.
111.
105.
103.
102.
104.
107.
107.
110.
95.4
103.
99.8
94.8
102.
105.
117.
108.
119.
106.
112.
107.
104.
101.
103.
106.
105.
103.
114.
101.
107.
101.
103.
103.
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
53.3
49.0
53.7
51.0
54.2
49.5
53.3
52.0
52.4
51.9
49.5
53.8
51.4
53.2
48.5
51.3
48.6
48.1
52.6
52.8
55.4
54.0
57.6
54.3
56.5
53.2
50.9
51.8
52.0
53.6
53.4
51.1
54.8
50.7
51.7
51.8
52.3
52.8
107.
97.9
107.
102.
108.
99.1
107.
104.
105.
104.
99.0
108.
103.
106.
97.1
103.
97.2
96.2
105.
106.
111.
108.
115.
109.
113.
106.
102.
104.
104.
107.
107.
102.
110.
101.
103.
104.
105.
106.
0.225
3.47
5.25
-0.0392
-2.05
3.67
4.42
0.594
-1.73
-1.22
4.79
-0.429
4.36
3.13
-1.73
0.583
2.66
-1.49
-3.03
-0.152
5.32
-0.427
3.56
-2.55
-0.979
0.488
2.00
-2.30
-1.34
-1.11
-1.76
0.625
4.00
-0.178
3.68
-2.72
-1.83
-2.42
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
page 1 of 4
Page 57 of 80
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25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
Galson
Laboratories
Freon-12
Heptane
Hexane
Isopropyl Alcohol
m & p-xylene
Methyl Butyl Ketone
Methyl Ethyl Ketone
Methylene Chloride
o-Xylene
Propylene
Styrene
Tetrachloroethylene
Tetrahydrofuran
Toluene
Trichloroethylene
Vinyl Acetate
Vinyl Bromide
Vinyl Chloride
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
Client
Account No.: 13913
Login No. : L333388
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to
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to
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to
to
to
to
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 100.
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
55.7
51.1
51.4
46.6
106.
53.8
52.8
53.6
51.7
52.1
54.8
52.2
53.1
53.1
51.9
53.8
52.0
55.3
57.1
46.6
53.2
51.8
111.
102.
103.
93.2
106.
108.
106.
107.
103.
104.
110.
104.
106.
106.
104.
108.
104.
111.
114.
93.2
106.
104.
50.0
50.0
50.0
50.0
100.
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
56.5
50.8
51.6
48.3
103.
51.3
52.9
51.2
50.1
53.6
53.5
53.2
52.3
53.6
53.0
51.5
50.3
55.8
56.8
46.9
54.1
52.9
113.
102.
103.
96.5
103.
103.
106.
102.
100.
107.
107.
106.
105.
107.
106.
103.
101.
112.
114.
93.7
108.
106.
page 2 of 4
Page 58 of 80
-1.41
0.530
-0.544
-3.48
2.66
4.83
-0.246
4.58
3.18
-2.87
2.46
-1.88
1.59
-0.881
-2.10
4.43
3.42
-0.738
0.544
-0.513
-1.64
-2.20
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
to
to
to
to
to
to
to
to
to
to
to
to
to
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to
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
Galson
Laboratories
Client
Account No.: 13913
Login No. : L333388
Lab Sample ID
Type
Spike Lot #
Instrument
Analysis Date
WG301435-2
LCS
IH490902
MS P
Nov 20, 2014 11:36
Limits
(%)
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Butadiene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Benzyl Chloride
Bromoform
Bromomethane
Carbon Disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cyclohexane
Ethyl Acetate
Ethylbenzene
Freon-11
Freon-113
Freon-114
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
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to
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to
to
to
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to
to
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to
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to
True Value
(ppbv)
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
WG301435-3
LCSD
IH490902
MS P
Nov 20, 2014 12:17
Found
(ppbv)
Recovery
(%)
True Value
(ppbv)
Found
(ppbv)
Recovery
(%)
RPD
RPD
Limits
53.8
51.2
54.7
52.2
54.9
51.3
54.3
53.3
53.2
52.5
52.1
55.0
53.8
54.7
48.4
52.1
49.9
49.8
51.7
53.2
59.0
55.4
59.1
55.4
56.6
54.5
51.9
52.1
53.3
54.8
53.5
52.1
55.4
52.1
52.9
53.5
52.6
54.7
108.
102.
109.
104.
110.
103.
109.
107.
106.
105.
104.
110.
108.
109.
96.8
104.
99.9
99.6
103.
106.
118.
111.
118.
111.
113.
109.
104.
104.
107.
110.
107.
104.
111.
104.
106.
107.
105.
109.
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
54.9
51.2
55.4
52.9
54.8
51.0
54.8
53.2
53.6
53.4
51.9
55.7
54.9
54.4
48.8
53.2
49.9
49.5
52.8
54.5
59.0
55.5
59.2
55.8
57.7
55.6
52.7
54.4
53.4
55.9
54.2
52.4
55.8
52.2
53.6
53.4
53.7
54.9
110.
102.
111.
106.
110.
102.
110.
106.
107.
107.
104.
111.
110.
109.
97.6
106.
99.8
98.9
106.
109.
118.
111.
118.
112.
115.
111.
105.
109.
107.
112.
108.
105.
112.
104.
107.
107.
107.
110.
-2.01
0
-1.33
-1.41
0.237
0.508
-1.04
0.132
-0.806
-1.70
0.308
-1.34
-1.95
0.422
-0.864
-1.92
0.0401
0.665
-1.93
-2.58
0.0170
-0.253
-0.237
-0.684
-1.96
-2.00
-1.57
-4.49
-0.281
-1.99
-1.19
-0.651
-0.611
-0.288
-1.41
0.243
-1.98
-0.365
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
page 3 of 4
Page 59 of 80
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25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
Galson
Laboratories
Freon-12
Heptane
Hexane
Isopropyl Alcohol
m & p-xylene
Methyl Butyl Ketone
Methyl Ethyl Ketone
Methylene Chloride
o-Xylene
Propylene
Styrene
Tetrachloroethylene
Tetrahydrofuran
Toluene
Trichloroethylene
Vinyl Acetate
Vinyl Bromide
Vinyl Chloride
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
70.0
Client
Account No.: 13913
Login No. : L333388
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130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 100.
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
130. 50.0
56.6
52.6
53.3
49.8
106.
52.5
54.8
52.0
53.3
53.9
54.8
50.9
53.2
54.6
54.3
52.1
53.0
56.8
58.0
48.2
55.5
53.9
113.
105.
107.
99.6
106.
105.
110.
104.
107.
108.
110.
102.
106.
109.
109.
104.
106.
114.
116.
96.3
111.
108.
50.0
50.0
50.0
50.0
100.
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
58.6
53.3
53.0
48.8
107.
52.5
54.3
52.3
53.7
53.9
55.2
53.9
53.4
54.9
54.1
53.2
53.8
57.7
59.0
48.7
55.5
53.4
117.
107.
106.
97.7
107.
105.
109.
105.
107.
108.
110.
108.
107.
110.
108.
106.
108.
115.
118.
97.4
111.
107.
page 4 of 4
Page 60 of 80
-3.48
-1.28
0.489
1.91
-1.52
0.0381
0.899
-0.652
-0.691
-0.0186
-0.836
-5.90
-0.225
-0.639
0.406
-2.03
-1.46
-1.59
-1.74
-1.07
-0.0180
0.969
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
-25.0
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
Galson
Laboratories
METHOD BLANK REPORT
Client
:Center for Toxicology & Env. Health LLC
Account No.:13913
Login No. :L333388
Lab Sample ID
Type
Instrument
Analysis Date
Analysis Time
WG301313-1
BLANK
MS P
11/19/14
13:20
WG301435-1
BLANK
MS P
11/20/14
14:20
MDL LOQ Found QualFound

Qual
(ppbv) (ppbv) (ppbv)
(ppbv)
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Butadiene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Benzyl Chloride
Bromoform
Bromomethane
Carbon Disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cyclohexane
Ethyl Acetate
Ethylbenzene
Freon-11
Freon-113
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
25
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20.
5.0
5.0
25.
5.0
5.0
5.0
5.0
5.0
5.0
10.
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
page 1 of 2
Page 61 of 80
Galson
Laboratories
METHOD BLANK REPORT
Freon-114
Freon-12
Heptane
Hexane
Isopropyl Alcohol
m & p-xylene
Methyl Butyl Ketone
Methyl Ethyl Ketone
Methylene Chloride
o-Xylene
Propylene
Styrene
Tetrachloroethylene
Tetrahydrofuran
Toluene
Trichloroethylene
Vinyl Acetate
Vinyl Bromide
Vinyl Chloride
Client
:Center for Toxicology & Env. Health LLC
Account No.:13913
Login No. :L333388
2
2
2
2
25
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
5.0
5.0
5.0
5.0
25.
10.
20.
5.0
20.
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
page 2 of 2
Page 62 of 80
ORGANICS QC RECOVERY REPORT

Work Group WG301052
Sample: WG301052-1
Spikelot: IH491482-2
QC Type: DLS
Raw File:
Analysis date 11/17/14 11:55:06

Instrument: LC6
Approval Status: YES
Rec.
Limits
.099
101
70.0 to 130.
.097600
.1
97.6
70.0 to 130.
CHRYSENE
.084794
.1
84.8
70.0 to 130.
BENZO(E)PYRENE
.110262
.099
111
70.0 to 130.
BENZO(B)FLUORANTHENE
.109986
.1
110
70.0 to 130.
BENZO(K)FLUORANTHENE
.095795
.1
95.8
70.0 to 130.
BENZO(A)PYRENE
.072683
.099
73.4
70.0 to 130.
DIBENZO(A,H)ANTHRACENE
.093885
.099
94.8
70.0 to 130.
BENZO(G,H,I)PERYLENE
.099445
.1
99.5
70.0 to 130.
INDENO-1,2,3-CD-PYRENE
.112593
.099
114
70.0 to 130.
ACENAPHTHYLENE
.084889
.1
84.9
70.0 to 130.
ACENAPHTHENE
.103432
.1
103
70.0 to 130.
FLUORENE
.099020
.099
100
70.0 to 130.
PHENANTHRENE
.100545
.098
103
70.0 to 130.
ANTHRACENE
.093469
.1
93.5
70.0 to 130.
FLUORANTHENE
.086733
.098
88.5
70.0 to 130.
1-NITROPYRENE
.091421
.098
93.3
70.0 to 130.
PYRENE
.102606
.0989
104
70.0 to 130.
Parameter
Found
NAPHTHALENE
.099984
BENZO(A)ANTHRACENE
True
Sample: WG301052-2
DE Rec. Limits
RPD
Limits
RPD
Limits
QC Type: CCV
Raw File:
Analysis date 11/17/14 12:15:33

Instrument: LC6
Rec.
Limits
4.95
107
90.0 to 115.
5.41054
4.9995
108
90.0 to 115.
CHRYSENE
5.45282
4.9995
109
88.0 to 113.
BENZO(E)PYRENE
5.62940
4.95
114
90.0 to 123.
5.48622
4.9995
110
90.0 to 117.
5.36683
4.9995
107
88.0 to 115.
BENZO(A)PYRENE
5.87851
4.95
119
83.9 to 133.
5.36565
4.95
108
90.0 to 113.
5.47870
4.9995
110
86.8 to 120.
5.57532
4.95
113
90.0 to 120.
ACENAPHTHYLENE
5.28345
4.9995
106
89.8 to 113.
Parameter
Found
NAPHTHALENE
5.31073
BENZO(A)ANTHRACENE
True
DE Rec. Limits
Page 1 of 8
Printed: 11/24/14 13:27
Page 63 of 80

Work Group WG301052
Sample: WG301052-2
QC Type: CCV
Raw File:
Analysis date 11/17/14 12:15:33

Instrument: LC6
Rec.
Limits
4.9995
107
90.0 to 114.
5.40251
4.95
109
90.0 to 115.
PHENANTHRENE
5.43934
4.9
111
90.0 to 117.
ANTHRACENE
5.36581
4.9995
107
86.4 to 116.
FLUORANTHENE
5.49278
4.9
112
89.5 to 118.
1-NITROPYRENE
5.48160
4.9
112
88.8 to 120.
PYRENE
5.60758
4.9441
113
90.0 to 121.
Parameter
Found
ACENAPHTHENE
5.32582
FLUORENE
True
Sample: WG301050-2
DE Rec. Limits
RPD
Limits
DE Rec. Limits
RPD
Limits
Spikelot: NA
QC Type: MBLANK
Raw File:
Analysis date 11/17/14 13:16:50

Instrument: LC6
Parameter
Found
True
ACENAPHTHENE(FRONT)
<.3
ACENAPHTHENE(BACK)
<.3
ACENAPHTHYLENE(FRONT)
<.3
ACENAPHTHYLENE(BACK)
<.3
ANTHRACENE(FRONT)
<.3
ANTHRACENE(BACK)
<.3
BENZO(A)ANTHRACENE(FRONT)
<.3
BENZO(A)ANTHRACENE(BACK)
<.3
BENZO(A)PYRENE(FRONT)
<.3
BENZO(A)PYRENE(BACK)
<.3
BENZO(B)FLUORANTHENE(FRONT)
<.3
BENZO(B)FLUORANTHENE(BACK)
<.3
BENZO(E)PYRENE(FRONT)
<.3
BENZO(E)PYRENE(BACK)
<.3
BENZO(G,H,I)PERYLENE(FRONT)
<.3
BENZO(G,H,I)PERYLENE(BACK)
<.3
BENZO(K)FLUORANTHENE(FRONT)
<.3
BENZO(K)FLUORANTHENE(BACK)
<.3
CHRYSENE(FRONT)
<.3
CHRYSENE(BACK)
<.3
DIBENZO(A,H)ANTHRACENE(FRONT)
<.3
DIBENZO(A,H)ANTHRACENE(BACK)
<.3
Rec.
Limits
Page 2 of 8
Printed: 11/24/14 13:27
Page 64 of 80

Work Group WG301052
Spikelot: NA
Sample: WG301050-2
QC Type: MBLANK
Raw File:
Analysis date 11/17/14 13:16:50

Instrument: LC6
Parameter
Found
True
FLUORANTHENE(FRONT)
<.3
FLUORANTHENE(BACK)
<.3
FLUORENE(FRONT)
<.3
FLUORENE(BACK)
<.3
INDENO-1,2,3-CD-PYRENE(FRONT)
<.3
INDENO-1,2,3-CD-PYRENE(BACK)
<.3
NAPHTHALENE(FRONT)
<.3
NAPHTHALENE(BACK)
<.3
1-NITROPYRENE(FRONT)
<.3
1-NITROPYRENE(BACK)
<.3
PHENANTHRENE(FRONT)
<.3
PHENANTHRENE(BACK)
<.3
PYRENE(FRONT)
<.3
PYRENE(BACK)
<.3
Rec.
Limits
DE Rec. Limits
RPD
Limits
RPD
Limits
Spikelot: IH491482
Sample: WG301050-3
QC Type: BS
Raw File:
Analysis date 11/17/14 13:57:39

Instrument: LC6
DE Rec. Limits
Found
NAPHTHALENE
4.46267
4.95
90.2
91.1
83.3 to 123
BENZO(A)ANTHRACENE
4.98847
4.9995
99.8
102
87.5 to 123
CHRYSENE
4.97083
4.9995
99.4
101
83.1 to 123
BENZO(E)PYRENE
5.16668
4.95
104
107
84.8 to 134
5.14982
4.9995
103
106
90.0 to 128
5.02629
4.9995
101
104
84.4 to 125
BENZO(A)PYRENE
5.00453
4.95
101
103
75.0 to 144
4.86939
4.95
98.4
99.4
81.3 to 119
4.75915
4.9995
95.2
99.2
77.1 to 134
5.17850
4.95
105
106
85.3 to 130
ACENAPHTHYLENE
4.62247
4.9995
92.5
90.6
80.6 to 119
ACENAPHTHENE
4.69991
4.9995
94
92.2
84.6 to 119
FLUORENE
4.87873
4.95
98.6
102
87.1 to 121
PHENANTHRENE
4.96736
4.9
101
103
87.7 to 125
ANTHRACENE
4.79132
4.9995
95.8
97.8
81.8 to 124
True
Rec.
Limits
Parameter
Page 3 of 8
Printed: 11/24/14 13:27
Page 65 of 80

Work Group WG301052
Sample: WG301050-3
Spikelot: IH491482
QC Type: BS
Raw File:
Analysis date 11/17/14 13:57:39

Instrument: LC6
DE Rec. Limits
Found
FLUORANTHENE
5.03353
4.9
103
105
86.3 to 125
1-NITROPYRENE
5.06969
4.9
103
105
84.1 to 131
PYRENE
5.22938
4.9441
106
107
84.3 to 131
True
Sample: WG301050-4
Rec.
Limits
Parameter
RPD
Limits
Spikelot: IH491482
QC Type: BSD
Raw File:
Analysis date 11/17/14 14:18:00

Instrument: LC6
Parameter
Found
True
Rec.
Limits
DE Rec. Limits
RPD
Limits
NAPHTHALENE
4.68950
4.95
94.7
95.7
83.3 to 123 -4.93
-10 to 10.0
BENZO(A)ANTHRACENE
5.14350
4.9995
103
105
87.5 to 123 -2.9
-10 to 10.0
CHRYSENE
5.12747
4.9995
103
105
83.1 to 123 -3.88
-10.2 to 10.0
BENZO(E)PYRENE
5.33588
4.95
108
110
84.8 to 134 -2.76
-10 to 10.0
5.27119
4.9995
105
109
90.0 to 128 -2.79
-10 to 10.0
5.15112
4.9995
103
106
84.4 to 125 -1.9
-10 to 10.0
BENZO(A)PYRENE
5.11095
4.95
103
105
75.0 to 144 -1.92
-10.9 to 10.9
5.03389
4.95
102
103
81.3 to 119 -3.56
-10 to 10.0
4.84089
4.9995
96.8
101
77.1 to 134 -1.8
-10 to 10.0
5.28119
4.95
107
108
85.3 to 130 -1.87
-10.2 to 10.0
ACENAPHTHYLENE
4.84179
4.9995
96.8
94.9
80.6 to 119 -4.64
-11.8 to 10.0
ACENAPHTHENE
4.83318
4.9995
96.7
94.8
84.6 to 119 -2.78
-10 to 10.0
FLUORENE
5.06547
4.95
102
105
87.1 to 121 -2.9
-10 to 10.0
PHENANTHRENE
5.12899
4.9
105
107
87.7 to 125 -3.81
-10 to 10.0
ANTHRACENE
4.89701
4.9995
97.9
99.9
81.8 to 124 -2.12
-16.9 to 15.5
FLUORANTHENE
5.16275
4.9
105
108
86.3 to 125 -2.82
-10 to 10.0
1-NITROPYRENE
5.23045
4.9
107
108
84.1 to 131 -2.82
-10 to 10.0
PYRENE
5.27103
4.9441
107
108
84.3 to 131 -.93
-10 to 10.0
Sample: WG301050-5
Spikelot: IH491482
QC Type: BS
Raw File:
Analysis date 11/17/14 14:38:25

Instrument: LC6
DE Rec. Limits
Found
NAPHTHALENE
4.86397
4.95
98.3
107
83.3 to 123
PYRENE
4.44045
4.9441
89.8
110
84.3 to 131
True
Rec.
Limits
Parameter
Page 4 of 8
RPD
Limits
Printed: 11/24/14 13:27
Page 66 of 80

Work Group WG301052
Sample: WG301050-5
Spikelot: IH491482
QC Type: BS
Raw File:
Analysis date 11/17/14 14:38:25

Instrument: LC6
Parameter
Found
True
Rec.
Limits
DE Rec. Limits
BENZO(A)ANTHRACENE
4.22825
4.9995
84.6
108
87.5 to 123
CHRYSENE
4.03345
4.9995
80.7
105
83.1 to 123
BENZO(E)PYRENE
3.82845
4.95
77.3
114
84.8 to 134
4.04711
4.9995
81
112
90.0 to 128
3.91919
4.9995
78.4
109
84.4 to 125
BENZO(A)PYRENE
3.59785
4.95
72.7
110
75.0 to 144
3.59396
4.95
72.6
101
81.3 to 119
3.02597
4.9995
60.5
103
77.1 to 134
3.49952
4.95
70.7
110
85.3 to 130
ACENAPHTHYLENE
4.79205
4.9995
95.9
99.8
80.6 to 119
ACENAPHTHENE
4.68486
4.9995
93.7
104
84.6 to 119
FLUORENE
4.79086
4.95
96.8
108
87.1 to 121
PHENANTHRENE
4.75929
4.9
97.1
113
87.7 to 125
ANTHRACENE
4.37894
4.9995
87.6
103
81.8 to 124
FLUORANTHENE
4.60525
4.9
94
113
86.3 to 125
1-NITROPYRENE
4.74190
4.9
96.8
115
84.1 to 131
Sample: WG301050-6
RPD
Limits
RPD
Limits
Spikelot: IH491482
QC Type: BSD
Raw File:
Analysis date 11/17/14 14:58:53

Instrument: LC6
DE Rec. Limits
Found
NAPHTHALENE
4.86916
4.95
98.4
107
83.3 to 123
-10 to 10.0
PYRENE
4.47911
4.9441
90.6
110
84.3 to 131
-10 to 10.0
BENZO(A)ANTHRACENE
3.79772
4.9995
76
97.4
87.5 to 123 10.3
-10 to 10.0
CHRYSENE
4.21551
4.9995
84.3
110
83.1 to 123 -4.65
-10.2 to 10.0
BENZO(E)PYRENE
3.89499
4.95
78.7
116
84.8 to 134 -1.74
-10 to 10.0
3.95106
4.9995
79
110
90.0 to 128
-10 to 10.0
ACENAPHTHYLENE
4.88045
4.9995
97.6
102
80.6 to 119 -2.18
-11.8 to 10.0
3.95429
4.9995
79.1
110
84.4 to 125 -.913
-10 to 10.0
BENZO(A)PYRENE
3.65789
4.95
73.9
112
75.0 to 144 -1.8
-10.9 to 10.9
3.58687
4.95
72.5
101
81.3 to 119
3.08175
4.9995
61.6
104
77.1 to 134 -.966
-10 to 10.0
3.50140
4.95
70.7
111
85.3 to 130 -.905
-10.2 to 10.0
ACENAPHTHENE
4.71271
4.9995
94.3
105
84.6 to 119 -.957
-10 to 10.0
True
Rec.
Limits
Parameter
Page 5 of 8
1.8
-10 to 10.0
Printed: 11/24/14 13:27
Page 67 of 80

Work Group WG301052
Sample: WG301050-6
Spikelot: IH491482
QC Type: BSD
Raw File:
Analysis date 11/17/14 14:58:53

Instrument: LC6
Found
Parameter
True
Rec.
Limits
DE Rec. Limits
RPD
Limits
FLUORENE
4.97670
4.95
101
112
87.1 to 121 -3.64
-10 to 10.0
PHENANTHRENE
4.68451
4.9
95.6
111
87.7 to 125 1.79
-10 to 10.0
ANTHRACENE
4.23681
4.9995
84.7
99.7
81.8 to 124 3.26
-16.9 to 15.5
FLUORANTHENE
4.44701
4.9
90.8
109
86.3 to 125
3.6
-10 to 10.0
1-NITROPYRENE
4.59896
4.9
93.9
112
84.1 to 131 2.64
-10 to 10.0
Sample: WG301052-3
QC Type: CCV
Raw File:
Analysis date 11/17/14 18:23:06

Instrument: LC6
Rec.
Limits
4.95
108
90.0 to 115.
5.40640
4.9995
108
90.0 to 115.
CHRYSENE
5.48457
4.9995
110
88.0 to 113.
BENZO(E)PYRENE
5.59505
4.95
113
90.0 to 123.
5.51223
4.9995
110
90.0 to 117.
5.39975
4.9995
108
88.0 to 115.
BENZO(A)PYRENE
5.42467
4.95
110
83.9 to 133.
5.37693
4.95
109
90.0 to 113.
5.27932
4.9995
106
86.8 to 120.
5.65097
4.95
114
90.0 to 120.
ACENAPHTHYLENE
5.33572
4.9995
107
89.8 to 113.
ACENAPHTHENE
5.31781
4.9995
106
90.0 to 114.
FLUORENE
5.44927
4.95
110
90.0 to 115.
PHENANTHRENE
5.44241
4.9
111
90.0 to 117.
ANTHRACENE
5.17100
4.9995
103
86.4 to 116.
FLUORANTHENE
5.48392
4.9
112
89.5 to 118.
1-NITROPYRENE
5.56142
4.9
113
88.8 to 120.
PYRENE
5.54966
4.9441
112
90.0 to 121.
Parameter
Found
NAPHTHALENE
5.33766
BENZO(A)ANTHRACENE
True
Sample: WG301052-4
RPD
Limits
RPD
Limits
QC Type: CCV
Raw File:
Analysis date 11/18/14 00:50:59

Instrument: LC6
Parameter
DE Rec. Limits
Found
True
Rec.
Limits
DE Rec. Limits
Page 6 of 8
Printed: 11/24/14 13:27
Page 68 of 80

Work Group WG301052
Sample: WG301052-4
QC Type: CCV
Raw File:
Analysis date 11/18/14 00:50:59

Instrument: LC6
Rec.
Limits
4.95
108
90.0 to 115.
5.42960
4.9995
109
90.0 to 115.
CHRYSENE
5.47792
4.9995
110
88.0 to 113.
BENZO(E)PYRENE
5.63140
4.95
114
90.0 to 123.
5.45872
4.9995
109
90.0 to 117.
5.36009
4.9995
107
88.0 to 115.
BENZO(A)PYRENE
5.52923
4.95
112
83.9 to 133.
5.43814
4.95
110
90.0 to 113.
5.40650
4.9995
108
86.8 to 120.
5.62866
4.95
114
90.0 to 120.
ACENAPHTHYLENE
5.33775
4.9995
107
89.8 to 113.
ACENAPHTHENE
5.35836
4.9995
107
90.0 to 114.
FLUORENE
5.44582
4.95
110
90.0 to 115.
PHENANTHRENE
5.46844
4.9
112
90.0 to 117.
ANTHRACENE
5.25286
4.9995
105
86.4 to 116.
FLUORANTHENE
5.52674
4.9
113
89.5 to 118.
1-NITROPYRENE
5.41502
4.9
111
88.8 to 120.
PYRENE
5.63887
4.9441
114
90.0 to 121.
Parameter
Found
NAPHTHALENE
5.34980
BENZO(A)ANTHRACENE
True
Sample: WG301052-5
DE Rec. Limits
RPD
Limits
RPD
Limits
QC Type: CCV
Raw File:
Analysis date 11/18/14 02:12:47

Instrument: LC6
Rec.
Limits
4.95
109
90.0 to 115.
5.44997
4.9995
109
90.0 to 115.
CHRYSENE
5.49360
4.9995
110
88.0 to 113.
BENZO(E)PYRENE
5.66381
4.95
114
90.0 to 123.
5.46008
4.9995
109
90.0 to 117.
5.36261
4.9995
107
88.0 to 115.
BENZO(A)PYRENE
5.56519
4.95
112
83.9 to 133.
5.45914
4.95
110
90.0 to 113.
5.44475
4.9995
109
86.8 to 120.
5.64070
4.95
114
90.0 to 120.
ACENAPHTHYLENE
5.36161
4.9995
107
89.8 to 113.
Parameter
Found
NAPHTHALENE
5.37311
BENZO(A)ANTHRACENE
True
DE Rec. Limits
Page 7 of 8
Printed: 11/24/14 13:27
Page 69 of 80

Work Group WG301052
Sample: WG301052-5
QC Type: CCV
Raw File:
Analysis date 11/18/14 02:12:47

Instrument: LC6
Rec.
Limits
4.9995
108
90.0 to 114.
5.46553
4.95
110
90.0 to 115.
PHENANTHRENE
5.49460
4.9
112
90.0 to 117.
ANTHRACENE
5.18634
4.9995
104
86.4 to 116.
FLUORANTHENE
5.56051
4.9
113
89.5 to 118.
1-NITROPYRENE
5.43226
4.9
111
88.8 to 120.
PYRENE
5.64838
4.9441
114
90.0 to 121.
Parameter
Found
ACENAPHTHENE
5.39086
FLUORENE
True
DE Rec. Limits
Page 8 of 8
RPD
Limits
Printed: 11/24/14 13:27
Page 70 of 80

Work Group WG301126
Sample: WG301126-1
QC Type: DLS
Raw File:
Analysis date 11/17/14 16:22:50

Instrument: HP29A
Found
Parameter
True
Rec.
Limits
XYLENE
6.43771
6.2441
103
70.0 to 130.
ETHYL ALCOHOL
1.90426
2.0957
90.9
70.0 to 130.
TOLUENE
2.16880
2.0957
103
70.0 to 130.
ETHYL BENZENE
2.12606
2.0967
101
70.0 to 130.
N-HEXANE
2.17017
2.0726
105
70.0 to 130.
BENZENE
1.09174
1.0431
105
70.0 to 130.
Sample: WG301126-1
RPD
Limits
RPD
Limits
RPD
Limits
RPD
Limits
QC Type: DLS
Raw File:
Analysis date 11/17/14 16:22:50

Instrument: HP29B
Found
Parameter
True
Rec.
Limits
XYLENE
6.65815
6.2441
107
70.0 to 130.
ETHYL ALCOHOL
1.85772
2.0957
88.6
70.0 to 130.
TOLUENE
2.17089
2.0957
104
70.0 to 130.
ETHYL BENZENE
2.16946
2.0967
103
70.0 to 130.
N-HEXANE
2.13080
2.0726
103
70.0 to 130.
BENZENE
1.06641
1.0431
102
70.0 to 130.
Sample: WG301126-2
DE Rec. Limits
QC Type: CCV
Raw File:
Analysis date 11/17/14 16:53:35

Instrument: HP29A
Parameter
Found
True
Rec.
Limits
XYLENE
759.343 735.1785
103
89.8 to 110.
N-HEXANE
250.309 244.0309
103
88.6 to 110.
BENZENE
125.537 122.8178
102
88.8 to 110.
TOLUENE
254.991 246.7464
103
90.0 to 110.
ETHYL BENZENE
251.299 246.8699
102
90.0 to 110.
ETHYL ALCOHOL
235.083 246.7464
95.3
73.9 to 119.
Sample: WG301126-2
DE Rec. Limits
QC Type: CCV
Raw File:
Analysis date 11/17/14 16:53:35

Instrument: HP29B
Parameter
DE Rec. Limits
Found
True
Rec.
Limits
DE Rec. Limits
Page 1 of 4
Printed: 11/24/14 13:26
Page 71 of 80

Work Group WG301126
Sample: WG301126-2
QC Type: CCV
Raw File:
Analysis date 11/17/14 16:53:35

Instrument: HP29B
Parameter
Found
True
Rec.
Limits
XYLENE
753.681 735.1785
103
89.8 to 110.
BENZENE
124.297 122.8178
101
88.8 to 110.
TOLUENE
253.119 246.7464
103
90.0 to 110.
ETHYL ALCOHOL
232.364 246.7464
94.2
73.9 to 119.
ETHYL BENZENE
250.873 246.8699
102
90.0 to 110.
N-HEXANE
246.577 244.0309
101
88.6 to 110.
RPD
Limits
DE Rec. Limits
RPD
Limits
RPD
Limits
Spikelot: NA
Sample: WG301023-3
QC Type: MBLANK
Raw File:
Analysis date 11/17/14 17:54:47

Instrument: HP29A
Parameter
Found
True
BENZENE(FRONT)
<2
BENZENE(BACK)
<2
ETHYL BENZENE(FRONT)
<5
ETHYL BENZENE(BACK)
<5
ETHYL ALCOHOL(FRONT)
<5
ETHYL ALCOHOL(BACK)
<5
Total VOCs as n-Hexane(FRONT)
<40.
Total VOCs as n-Hexane(BACK)
<40.
N-HEXANE(FRONT)
<5
N-HEXANE(BACK)
<5
TOLUENE(FRONT)
<5
TOLUENE(BACK)
<5
XYLENE(FRONT)
<15
XYLENE(BACK)
<15
Rec.
Limits
Spikelot: IH491422
Sample: WG301023-4
QC Type: BS
Raw File:
Analysis date 11/17/14 18:56:35

Instrument: HP29A
Parameter
DE Rec. Limits
Found
True
Rec.
Limits
DE Rec. Limits
XYLENE
1490.12
1489
100
103
84.4 to 113
N-HEXANE
518.782
494.25
105
102
84.1 to 110
BENZENE
248.705
248.75
100
100
84.2 to 110
Page 2 of 4
Printed: 11/24/14 13:26
Page 72 of 80

Work Group WG301126
Spikelot: IH491422
Sample: WG301023-4
QC Type: BS
Raw File:
Analysis date 11/17/14 18:56:35

Instrument: HP29A
Parameter
Found
True
Rec.
Limits
DE Rec. Limits
TOLUENE
503.961
499.75
101
98.9
82.3 to 110
ETHYL BENZENE
500.903
500
100
97.3
82.1 to 110
ETHYL ALCOHOL
403.391
499.75
80.7
96.1
77.0 to 135
RPD
Limits
RPD
Limits
Spikelot: IH491422
Sample: WG301023-4
QC Type: BS
Raw File:
Analysis date 11/17/14 18:56:35

Instrument: HP29B
Parameter
Found
True
Rec.
Limits
DE Rec. Limits
XYLENE
1481.14
1489
99.5
103
84.4 to 113
N-HEXANE
511.887
494.25
104
101
84.1 to 110
BENZENE
246.666
248.75
99.2
99.2
84.2 to 110
TOLUENE
500.223
499.75
100
98.1
82.3 to 110
ETHYL BENZENE
500.813
500
100
97.2
82.1 to 110
ETHYL ALCOHOL
395.842
499.75
79.2
94.3
77.0 to 135
Spikelot: IH491422
Sample: WG301023-5
QC Type: BSD
Raw File:
Analysis date 11/17/14 19:27:12

Instrument: HP29A
Parameter
Found
True
Rec.
Limits
DE Rec. Limits
RPD
Limits
XYLENE
1478.80
1489
99.3
102
84.4 to 113 .976
-10 to 10.0
N-HEXANE
514.356
494.25
104
101
84.1 to 110 .985
-10 to 10.0
BENZENE
247.063
248.75
99.3
99.3
84.2 to 110 .702
-10 to 10.0
TOLUENE
500.340
499.75
100
98.2
82.3 to 110
.71
-10 to 10.0
ETHYL BENZENE
496.455
500
99.3
96.4
82.1 to 110 .929
-10 to 10.0
ETHYL ALCOHOL
403.647
499.75
80.8
96.2
77.0 to 135 -.104
-12.2 to 12.2
Spikelot: IH491422
Sample: WG301023-5
QC Type: BSD
Raw File:
Analysis date 11/17/14 19:27:12

Instrument: HP29B
Parameter
Found
True
Rec.
Limits
DE Rec. Limits
RPD
Limits
84.4 to 113 .976
-10 to 10.0
99.6
84.1 to 110
1.4
-10 to 10.0
98.5
84.2 to 110 .708
-10 to 10.0
XYLENE
1469.10
1489
98.7
102
N-HEXANE
507.146
494.25
103
BENZENE
244.897
248.75
98.5
Page 3 of 4
Printed: 11/24/14 13:26
Page 73 of 80

Work Group WG301126
Sample: WG301023-5
Spikelot: IH491422
QC Type: BSD
Raw File:
Analysis date 11/17/14 19:27:12

Instrument: HP29B
Parameter
Found
True
Rec.
Limits
DE Rec. Limits
RPD
Limits
TOLUENE
496.414
499.75
99.3
97.4
82.3 to 110 .716
-10 to 10.0
ETHYL BENZENE
495.608
500
99.1
96.2
82.1 to 110 1.03
-10 to 10.0
ETHYL ALCOHOL
401.425
499.75
80.3
95.6
77.0 to 135 -1.37
-12.2 to 12.2
Sample: WG301126-3
QC Type: CCV
Raw File:
Analysis date 11/18/14 01:04:50

Instrument: HP29A
Parameter
Found
True
Rec.
Limits
XYLENE
754.031 735.1785
103
89.8 to 110.
N-HEXANE
250.419 244.0309
103
88.6 to 110.
BENZENE
124.578 122.8178
101
88.8 to 110.
TOLUENE
252.458 246.7464
102
90.0 to 110.
ETHYL BENZENE
249.441 246.8699
101
90.0 to 110.
ETHYL ALCOHOL
239.644 246.7464
97.1
73.9 to 119.
Sample: WG301126-3
RPD
Limits
RPD
Limits
QC Type: CCV
Raw File:
Analysis date 11/18/14 01:04:50

Instrument: HP29B
Parameter
DE Rec. Limits
Found
True
Rec.
Limits
XYLENE
749.037 735.1785
102
89.8 to 110.
BENZENE
123.482 122.8178
101
88.8 to 110.
TOLUENE
250.454 246.7464
102
90.0 to 110.
ETHYL BENZENE
249.149 246.8699
101
90.0 to 110.
ETHYL ALCOHOL
237.661 246.7464
96.3
73.9 to 119.
N-HEXANE
247.026 244.0309
101
88.6 to 110.
DE Rec. Limits
Page 4 of 4
Printed: 11/24/14 13:26
Page 74 of 80

Work Group WG301099
Sample: WG301099-1
QC Type: DLS
Raw File:
Analysis date 11/17/14 18:38:30

Instrument: LC11
Rec.
Limits
.02
115
70.0 to 130.
.023726
.02
119
70.0 to 130.
BUTYRALDEHYDE
.026103
.02
130
70.0 to 130.
ACETALDEHYDE
.021293
.0198
107
70.0 to 130.
BENZALDEHYDE
.022330
.0201
111
70.0 to 130.
ISOVALERALDEHYDE
.022595
.0198
114
70.0 to 130.
VALERALDEHYDE
.023714
.0199
119
70.0 to 130.
PROPIONALDEHYDE
.018324
.0196
93.7
70.0 to 130.
Parameter
Found
FORMALDEHYDE
.023053
Crotonaldehyde
True
Sample: WG301099-2
Limits
DE Rec. Limits
RPD
Limits
DE Rec. Limits
RPD
Limits
Raw File:
Analysis date 11/17/14 18:46:37

Instrument: LC11
Rec.
Limits
5.002
100
87.8 to 110.
4.61336
5.0095
92.1
84.3 to 110.
BENZALDEHYDE
5.00098
5.0135
99.8
90.0 to 110.
ISOVALERALDEHYDE
4.65437
4.96
93.8
87.4 to 111.
VALERALDEHYDE
4.51409
4.98
90.6
76.5 to 110.
ACETALDEHYDE
4.99636
4.9599
101
90.0 to 110.
PROPIONALDEHYDE
5.02782
4.8907
103
90.0 to 110.
Crotonaldehyde
4.97951
4.995
99.7
89.1 to 110.
Parameter
Found
FORMALDEHYDE
5.01774
BUTYRALDEHYDE
True
Sample: WG301097-2
Spikelot: NA
QC Type: MBLANK
Raw File:
Analysis date 11/17/14 19:02:50

Instrument: LC11
Found
True
ACETALDEHYDE(RAW)
.002620
<0.2
Crotonaldehyde(RAW)
.049193
<0.2
BUTYRALDEHYDE(RAW)
.014271
<.2
BENZALDEHYDE(RAW)
.005833
<0.2
ISOVALERALDEHYDE(RAW)
.010569
<0.2
PROPIONALDEHYDE(RAW)
.005478
<0.2
<0.1
FORMALDEHYDE(RAW)
RPD
QC Type: CCV
Parameter
DE Rec. Limits
Rec.
Limits
Page 1 of 4
Printed: 11/24/14 13:25
Page 75 of 80

Work Group WG301099
Sample: WG301097-2
Spikelot: NA
QC Type: MBLANK
Raw File:
Analysis date 11/17/14 19:02:50

Instrument: LC11
Found
Parameter
VALERALDEHYDE(RAW)
True
Rec.
Limits
DE Rec. Limits
RPD
Limits
RPD
Limits
<0.2
Sample: WG301097-3
Spikelot: IH492583
QC Type: BS
Raw File:
Analysis date 11/17/14 19:10:57

Instrument: LC11
Limits
DE Rec. Limits
Parameter
Found
FORMALDEHYDE
4.69034
4.995
93.9
97.8
84.3 to 110
Crotonaldehyde
4.78093
4.995
95.7
105
84.4 to 116
BUTYRALDEHYDE
4.44847
4.995
89.1
104
90.0 to 114
BENZALDEHYDE
4.86871
5.0135
97.1
99.1
90.0 to 110
ACETALDEHYDE
4.85405
4.95
98.1
101
90.0 to 110
ISOVALERALDEHYDE
4.52908
4.96
91.3
109
90.0 to 134
VALERALDEHYDE
4.32163
4.98
86.8
101
89.0 to 110
PROPIONALDEHYDE
4.81831
4.8907
98.5
102
90.0 to 112
True
Sample: WG301097-4
Rec.
Spikelot: IH492583
QC Type: BSD
Raw File:
Analysis date 11/17/14 19:19:05

Instrument: LC11
Found
Parameter
True
Rec.
Limits
DE Rec. Limits
RPD
Limits
FORMALDEHYDE
4.63853
4.995
92.9
96.7
84.3 to 110 1.13
-10 to 10.0
Crotonaldehyde
4.73890
4.995
94.9
104
84.4 to 116 .957
-10 to 10.0
BUTYRALDEHYDE
4.37594
4.995
87.6
102
90.0 to 114 1.94
-10 to 10.0
BENZALDEHYDE
4.79120
5.0135
95.6
97.5
90.0 to 110 1.63
-10 to 10.0
ISOVALERALDEHYDE
4.45793
4.96
89.9
107
90.0 to 134 1.85
-10.2 to 10.0
VALERALDEHYDE
4.24917
4.98
85.3
99.2
89.0 to 110
1.8
-10 to 10.0
ACETALDEHYDE
4.79382
4.95
96.8
99.8
90.0 to 110
1.2
-10 to 10.0
PROPIONALDEHYDE
4.77672
4.8907
97.7
101
90.0 to 112 .985
-10 to 10.0
Sample: WG301098-2
Spikelot: NA
QC Type: MBLANK
Raw File:
Analysis date 11/17/14 19:51:30

Instrument: LC11
Parameter
BENZALDEHYDE(FRONT)
Found
.005038
True
Rec.
Limits
DE Rec. Limits
RPD
Limits
<.2
Page 2 of 4
Printed: 11/24/14 13:25
Page 76 of 80

Work Group WG301099
Sample: WG301098-2
Spikelot: NA
QC Type: MBLANK
Raw File:
Analysis date 11/17/14 19:51:30

Instrument: LC11
Parameter
Found
0
BENZALDEHYDE(BACK)
True
Rec.
Limits
DE Rec. Limits
RPD
Limits
RPD
Limits
RPD
Limits
<.2
Sample: WG301098-3
Spikelot: IH492583
QC Type: BS
Raw File:
Analysis date 11/17/14 20:07:40

Instrument: LC11
Parameter
Found
BENZALDEHYDE
4.76583
True
Rec.
5.0135
95.1
Sample: WG301098-4
Limits
DE Rec. Limits
97
86.1 to 110
Spikelot: IH492583
QC Type: BSD
Raw File:
Analysis date 11/17/14 20:15:45

Instrument: LC11
Parameter
Found
BENZALDEHYDE
4.75443
True
Rec.
5.0135
94.8
Sample: WG301099-3
Limits
DE Rec. Limits
96.8
86.1 to 110 .206
-10 to 10.0
QC Type: CCV
Raw File:
Analysis date 11/17/14 21:28:42

Instrument: LC11
Rec.
Limits
5.002
99.4
87.8 to 110.
4.94553
4.995
99
89.1 to 110.
BUTYRALDEHYDE
4.56584
5.0095
91.1
84.3 to 110.
BENZALDEHYDE
4.94485
5.0135
98.6
90.0 to 110.
ISOVALERALDEHYDE
4.58937
4.96
92.5
87.4 to 111.
ACETALDEHYDE
4.96368
4.9599
100
90.0 to 110.
VALERALDEHYDE
4.43018
4.98
89
76.5 to 110.
PROPIONALDEHYDE
4.99381
4.8907
102
90.0 to 110.
Parameter
Found
FORMALDEHYDE
4.97269
Crotonaldehyde
True
Sample: WG301099-4
DE Rec. Limits
RPD
Limits
RPD
Limits
QC Type: CCV
Raw File:
Analysis date 11/17/14 22:25:17

Instrument: LC11
Parameter
Found
FORMALDEHYDE
4.98015
BENZALDEHYDE
4.98274
Rec.
Limits
5.002
99.6
87.8 to 110.
5.0135
99.4
90.0 to 110.
True
DE Rec. Limits
Page 3 of 4
Printed: 11/24/14 13:25
Page 77 of 80

Work Group WG301099
Sample: WG301099-4
QC Type: CCV
Raw File:
Analysis date 11/17/14 22:25:17

Instrument: LC11
Parameter
Found
True
Rec.
Limits
ISOVALERALDEHYDE
4.64162
4.96
93.6
87.4 to 111.
VALERALDEHYDE
4.46312
4.98
89.6
76.5 to 110.
ACETALDEHYDE
4.97992
4.9599
100
90.0 to 110.
PROPIONALDEHYDE
4.99126
4.8907
102
90.0 to 110.
Crotonaldehyde
4.94589
4.995
99
89.1 to 110.
BUTYRALDEHYDE
4.58302
5.0095
91.5
84.3 to 110.
DE Rec. Limits
Page 4 of 4
RPD
Limits
Printed: 11/24/14 13:25
Page 78 of 80
Page 79 of 80
Page 80 of 80

CTEH Bakken Crude Burn

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CTEH Bakken Crude Burn

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Bakken Crude Oil Burn Demonstration

Air Monitoring and Sampling Report

Chemicals of Interest .................................................................................................................... 3

Air Sampling and Monitoring Strategy .......................................................................................... 4

Real-Time Air Monitoring .............................................................................................................. 4

Analytical Air Sampling.................................................................................................................. 5

Personal Air Sampling ................................................................................................................... 5

Real-Time Results .......................................................................................................................... 6

Analytical Air Sampling Results ..................................................................................................... 8

Personal Air Sampling Results ....................................................................................................... 9

Real-Time Air Monitoring Discussion .......................................................................................... 10

Analytical Air Sampling Discussion .............................................................................................. 10

Personal Sampling Results Discussion ........................................................................................ 12

Appendix A ................................................................................................................... Bakken Crude Oil SDS

Location of B.E.S.T. Facility

Air Sampling and Monitoring Strategy

Real-Time Air Monitoring

Analytical Air Sampling

Personal Air Sampling

at that particular time and place.

Summary of Radio-Telemetering AreaRAE Data*

< 0.1 ppm

Summary of Data-Logged Particulate Monitoring (PM10) Data*

0.011 - 0.292 mg/m

0.013 - 0.020 mg/m

0.009 - 0.157 mg/m

Summary of Real-Time Hand-Held Air Monitoring Data

< 0.05 ppm

< 0.1 ppm

0.006 - 0.023 mg/m3

< 0.05 ppm

0.1 - 5.7 ppm

Analytical Air Sampling Results

Summary of Downwind Grab Sampling Results*

Prior to Controlled Burn

During Controlled Burn

Summary of VOC Headspace Sampling Results*

Tanker Head Space

Personal Air Sampling Results

Personnel Air Sampling

Max. Reported TWA Result

Max. 8-hr TWA*

Real-Time Air Monitoring Discussion

Analytical Air Sampling Discussion

failed to data-log readings during the demonstration.

Personal Sampling Results Discussion

Crude Oil, Sweet

(Material) Safety Data Sheet

Version 1.1 Revision Date 2013-04-05

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Crude Oil, Sweet

A complex mixture of hydrocarbons, containing variable amounts of impurities.

SECTION 2 HAZARDS IDENTIFICATION

Highly flammable liquid and vapor (H225).

Continental Resources, Inc.

Take precautionary measures against static discharge (P243).

0.4% (LEL) 15% (UEL)

-40 to 100 C (-40 to 212 F)

Flammable Liquids Category 2

Continental Resources, Inc.

Potential Health Effects

Contact with eyes may cause moderate to severe irritation.

Inhalation Health Effects:

Skin Health Effects: