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Table of Contents
Getting Started Workshop............................................................................................ 3 - 13
Getting Started Solutions ............................................................................................. 3 - 39
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Objective
After completing this workshop, youll be able to provide sufficient information to fully
define the thermodynamic basis of a simulation flowsheet. Additionally, you will be able
to fully define material streams and attach Stream Analyses to those streams to gain
further information.
Description
This workshop introduces you to some of the basic concepts necessary for creating
simulations in Aspen HYSYS. You will use Aspen HYSYS to define a hydrocarbon
stream which mimics the makeup and conditions of a typical upstream material flow. In
addition, you will learn how to determine specific properties of the stream by using the
Envelope and Property Table Analysis options.
This workshop includes the following tasks:
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The first item shown in the Properties Environment is the Component Lists folder. Here,
you can create component lists that are independent of (but can be associated with) the
individual Fluid Packages in the case.
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The following table describes the various buttons available on the Component Lists
object:
Button
Description
Add
Delete
Copy
Import
Export
The second folder in the Properties Environment is the Fluid Packages item. Depending
upon the desired property model, you have a choice between three available databases
when selecting a Fluid Package: Aspen HYSYS, Aspen Properties, or COMThermo. For
the workshops in this course, we will be using Aspen HYSYS as the database source.
The following table describes the various buttons available on the Fluid Packages object:
Button
Description
Add
Delete
Copy
Import
Export
Now that you have been introduced to the Properties Environment of Aspen HYSYS,
lets begin the workshop.
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Start a new case by opening Aspen HYSYS and selecting the New option.
On the Component Lists folder in the Navigation Pane, click the Add button.
Start by adding the first component; in this case it will be Nitrogen. Add it by
typing nitrogen or N2 into the Search for field in the component list window.
Once the desired component is highlighted click the <Add> button to add the
component to your component list.
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Components
H2S
CO2
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
n-Hexane
H2O
Note: You can select multiple components by holding down Ctrl on your keyboard and
selecting the desired components. Or hold down Shift and select a range of components.
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Next you will introduce a hypothetical component to your list. This hypothetical
component will represent a mixture of heavier hydrocarbons (i.e. heptanes, octanes, etc.)
in the gas stream mixture.
Click the Select menu item and choose the Hypothetical option.
In the Method menu item, choose the Create and Edit Hypos option. This will
allow you to quickly create a single hypothetical component.
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Note: When you click New Hypo, Aspen HYSYS adds a hydrocarbon class hypo by
default. If you want to add a hypo from another class, click the Hypothetical Manager
button in the Home tab of the ribbon and then in the view that displays, click the Settings
tab. This will open a form where you can add non-hydrocarbon class hypotheticals.
In the view for the hypo component you created, enter the Normal Boiling Point
for the component, which in our case is 110 C (230 F). No other properties are
90known, so everything else will be estimated.
Note: Aspen HYSYS always places an asterisk (*) after a hypo name so it can be
distinguished from databank components.
Click the Estimate Unknown button to estimate all the other properties and fully
define the hypothetical component.
Note: The minimum information required for defining a hypo is the Normal Boiling Pt or
the Molecular Weight and Liquid Density.
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When the hypo component has been defined, make sure the hypo component is
selected and highlighted.
Add the hypo component to the Selected Components list by selecting it and
clicking the < Add button.
You have now finished defining the component list. Using the Navigation Pane
on the left-hand side of the HYSYS window, select the Fluid Packages folder.
Click the Add button to add a Fluid Package. By default, it will be a HYSYS
Databank Fluid Package. This agrees with our component list as it was also set
up with the HYSYS Databank.
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Note: You can also verify your component list selection from the Fluid Packages menu.
Click the View button next to the Component List Selection field to double-check your
components.
Back in the Navigation Pane, click on the Fluid Packages folder icon. This will
show any created Fluid Packages and show the Fluid Package manipulation
buttons discussed earlier.
Click and highlight the current Fluid Package name Basis-1 and rename it as
GasPlant.
Once defined, Fluid Packages can be exported for use in another HYSYS case, creating a
single, common physical property source that can be used across multiple simulations.
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Make sure the GasPlant Fluid Package is highlighted and click the Export button
at the bottom of the form.
Note: Aspen HYSYS will automatically add the file extension .fpk when it saves your fluid
package. By default, the file is automatically saved to the Program Files folder \Aspen
HYSYS V8.8\Paks. It is preferred instead to save the .fpk file to a local, personal, or
easily accessible shared drive location.
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In Aspen HYSYS, there are two types of streams that can be added to a flowsheet;
material streams and energy streams. Material streams are used to represent process flows
and have defined parameters such as composition, temperature, pressure, and flow rate.
Energy streams are typically used to represent the heat duty or energy supplied to or
produced by a unit operation. Energy streams have only one parameter; heat flow. There
are a variety of ways to add material streams in Aspen HYSYS:
To use this...
Do this...
Object
Palette
Keyboard
Shortcut
Press the F11 Hot Key. The Stream property view opens.
Ribbon
Using the Object Palette (or one of the other described means) add a Material
Stream to your flowsheet.
If the stream property view is not displayed, double-click the newly created
stream in the flowsheet to bring up the property view, shown below:
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Highlight the Stream Name cell. Change the stream name to HC Feed and press
Enter.
Once a material stream has been created, there are two different methods that can be used
to enter stream composition:
On this page...
Do this...
Double-click the Molar Flow cell to enter mole fractions.
Conditions
or
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Use one of the methods described above to open the Input Composition for
Stream view.
Ensure that Mole Fractions is displayed as the Composition Basis and enter the
following values:
For this component...
Nitrogen
0.0083
H2S
0.0211
CO2
0.0107
Methane
0.5091
Ethane
0.1766
Propane
0.0752
i-Butane
0.0508
n-Butane
0.0398
i-Pentane
0.0441
n-Pentane
0.0339
n-Hexane
0.0202
H2O
0.0000
C7+
0.0102
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Click OK to save the compositions and close the Input Composition for Stream
window.
Now is a good opportunity to save your progress. Select the File tab in the
Ribbon and choose Save As. Browse to a suitable file-save location and save the
case as 02-GettingStarted.hsc.
Once composition has been defined, Aspen HYSYS can perform three types of flash
calculations on streams: Pressure-Temperature, Vapor Fraction-Temperature and Vapor
Fraction-Pressure. While enthalpy and entropy are also available to be specified for flash
calculations, this is not typically done. If two of the three process variables are known
(pressure, temperature and vapor fraction), Aspen HYSYS can perform a flash
calculation on the stream to calculate the third parameter, as well as the molar enthalpy
and molar entropy.
Note: Only two of these three stream parameters (pressure, temperature and vapor
fraction) can be supplied. If all three variables are somehow defined, a consistency error
will occur.
Perform a P-T flash calculation on the HC Feed stream by setting the pressure to
3000 kPa (435 psia) and the temperature to 25 C (77 F).
What is the resulting vapor fraction?
With the flash capabilities of Aspen HYSYS, it is possible to perform dew point and
bubble point calculations with ease. By specifying a vapor fraction of 1.0 and either the
pressure or temperature of the stream, Aspen HYSYS will determine the dew point
condition. Similarly, to calculate the bubble point, a vapor fraction of 0.0 and either the
stream pressure or temperature must be entered.
Delete the specified temperature and enter a vapor fraction of 1.0. What is the
dew point temperature at 3000 kPa (435 psia)?
Change the vapor fraction to 0.0. What is the bubble point temperature?
Delete the vapor fraction specification and return the temperature to its original
value of 25 C (77 F).
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The HC Feed stream is still not yet fully defined. In order to fully define a
stream, you must enter a molar, mass, or volumetric flow rate.
Enter a molar flow rate of 9000 kgmole/h (19840 lbmole/hr).
What is the Standard Gas Flow of the vapor phase?
Hint: To find the standard gas flow rate, select the Properties page from the stream
menu. Then move the mouse arrow to the left or right side of the view until the arrow
changes to the double-headed resizing arrows. Press and hold the left mouse button and
drag the edge of the view until all the phases can be seen.
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View the Home tab in the HYSYS ribbon. The Units selector is on the left hand
side:
Click the pull-down menu to select a unit set. There are three default unit sets
available: SI, EuroSI, and Field (English/Imperial).
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In the resulting Simulation Options window, make sure you are viewing the Units
of Measure from.
You can click and select a desired unit set for use, or even create your own
custom unit set by copying an existing set. In this exercise we will use one of the
built-in sets, so choose your preferred set and click OK.
Note: To change the units for an individual input specification, simply type the numerical
value of the specification and click the unit drop-down list. Choose the desired unit for
the value you are providing and Aspen HYSYS will convert the input back to the default
unit selected in your session preferences.
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Do this...
Ribbon
Stream Property
View
Navigation Pane
The Envelope Analysis allows you to examine relationships between selected parameters
for any stream of known composition, including streams with only one component.
Vapor-Liquid phase envelopes may be plotted for the following variables: PressureTemperature, Pressure-Volume, Pressure-Enthalpy, Pressure-Entropy, TemperatureVolume, Temperature-Enthalpy and Temperature-Entropy.
Open the HC Feed stream property view by double-clicking on the stream icon
on the flowsheet.
On the Attachments tab, click Analysis on the left side of the page.
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Click the Create button. The Available Stream Analysis view will appear.
Once the Available Stream Analysis menu appears, select Envelope and click the
Add button.
You should notice that an analysis titled Envelope-HC Feed is now listed. Make
sure it is highlighted and click the View button.
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Switching to the Performance tab allows you to view the graphical and tabular
representation of the phase envelope, as shown below.
Note: Numerical values can be copied from the results table in Aspen HYSYS to
Microsoft Excel using the copy command (Ctrl+C) in Aspen HYSYS and then the paste
command (Ctrl+V) in Excel.
The next Analysis you will use is the Property Table Analysis. The Property Table
Analysis allows you to examine physical property trends over a range of conditions in
both tabular and graphical formats. The analysis calculates dependent variables from
user-specified independent variable ranges (or values).
Viewing the Home tab in the HYSYS ribbon, click the Stream Analysis button.
The resulting view is into the Stream Analysis folder in the Navigation Pane.
You should see your Envelope Analysis listed here.
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Click and select the Add button. This will let you choose a particular Analysis
option. Select the Property Table.
The analysis must be linked to a given stream. In the Select Process Stream
window, choose HC Feed as the Object, and then click OK.
You should now see the created analysis in the Navigation Pane, titled Property
Table-HC Feed. Click on it to select and open it.
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Independent Variable 2
Variable 1
Pressure
Variable 2
Temperature
Mode
State
Mode
Incremental
State Values
Lower Bound
0 C (32 F)
Upper Bound
100 C (212 F)
# of Increments
10
Select the Design | Dep. Prop page and click the Add button.
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You will bring in one more dependent variable, so click Add again. Select the
Phase Thermal Conductivity | Vapour Phase and click OK to accept.
Click the Calculate button at the bottom of the view to generate the property
table.
Note: If the properties of the attached stream change, the Property Table utility will need
to re-calculate in order to update the results. You must manually re-click the Calculate
button!
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Examine the property table results in either graphical or tabular format on the
Performance tab.
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Challenge Exercises
Hint: Hover over the plot and use the Cross Hairs to more accurately assess the position
of the cursor.
Plot the 50% quality line for stream HC Feed. What temperature corresponds to
50 atm on this graph?
Hint: Right click on the plot and use the Graph Control dialog to change the display units
for Pressure.
Recommended Reading
Knowledge Base Solution 109322
How do I plot an envelope on a wet basis?
Knowledge Base Solution 109812
Calculate a phase envelope using the property table utility
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Questions
Task 2
Perform a P-T flash calculation on the HC Feed stream by setting the pressure to
3000 kPa (435 psia) and the temperature to 25 C (77 F). What is the resulting
vapor fraction?
0.7333
90.49 C (194.9 F)
-78.57 C (-109.4 F)
Task 4
What is the critical temperature and pressure for the stream HC Feed?
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Challenge Problems
Discern the dew point temperature of stream HC Feed at 7000 kPa (1015 psia)
using the Envelope analysis.
104.9 C (220.9 F); approximate solution found by hovering mouse/cross hairs over the
dew point curve on the Envelope plot
How does this compare to a rigorous flash calculation using the stream property
view?
Plot the 50% quality line for stream HC Feed. What temperature corresponds to
50 atm on this graph?
Approximately 1 C (34 F)
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