Volume 137, Number 26, December 30, 2002

Sections from Chemical Abstracts Volume 137, Number 26

Chemical Abstract
ORGANIC CHEMISTRY SECTIONS
21 through 34
137 : 384797d Interaction of isatins with some five-membered
aminoheterocycles. Pushechnikov, Alexei O. ; Volochnyuk, Dimitrii M.;
Tolmachev, Andrei A. ( Research and Development Center for Chemistry and
Biology, National Taras Shevchenko Univerisity, Kiev Ukraine 01033). Synlett
2002, (7), 1140 1142 (Eng), Georg Theime Verlag. 5-Aminopyrazoles react with
izatins giving 3-(5-aminopyra-zol-3-yl)-3-hydroxy-2-oxindolines in high yield.
Analogously isatins react with 5-aminoisoxazole and 2-aminofuran. Under those
conditions 2-aminothiphene reacts yielding 3-(thein-2-ylimino)-2-oxindoline.
137 : 384797d Interaciunea izatinelor cu unii amino heterociclici cu 5
membri. Pushechnikov, Alexei O. ; Volochnyuk, Dimitrii M.; Tolmachev, Andrei A.
( Research and Development Center for Chemistry and Biology, National Taras
Shevchenko Univerisity, Kiev Ukraine 01033). Synlett 2002, (7), 1140 1142
(Eng), Georg Theime Verlag. 5-aminopirazolii reacioneaz cu izatina dnd 3- (5aminopirazol-3-yl)
-3-hidroxi-2-oxindol
cu
randament
ridicat.
Izatinele
reacioneaz cu 5-amino izoxazol i 2-aminofuran. n aceste condiii 2-amino
thiphene reacioneaz i se obine 3- (thein-2-ilimino) -2-oxindol.

Volume 139, Number 15, Octomber 13, 2003

Sections from Chemical Abstracts Volume 139, Number 15

Chemical Abstract
ORGANIC CHEMISTRY SECTIONS
21 through 34
139 : 230643e 1-Benzopyran -4(4H)- ones as novel activated alkenes in
the Baylis-Hillman reactions : a simple and facial synthesis of indolizinefused-chromones. Basavaiah, Deevi, Rao, Anumolu Jaganmohan (School of
Chemistry, Univeristy of Hyderabad, Hyderabad, 500 046 India). Tetrahedron
Letters 2003, 44(23), 4365-4368 (Eng), Elsevier Science Ltd. 1-Benzopyran
-4(4H)-one derivs. Have been successfully employed as novel activated alkenes
in the Baylis-Hillman coupling with heteroarom-aldehydes, nitrobenzaldehydes
and isatin-derivs and the corresponding adducts, derived from pyridine-2-carbox-

aldehyde, have been

framework I (R=H, Me ).

transformed

into

novel

indolizine-fused-chromone

139 : 230643e 1-Benzopiran -4 (4H) noi alchene activate in reactia

Baylis-Hillman: o simpla si usoara sinteza a indolizinei fuzata cu
cromone. Basavaiah, Deevi, Rao, Anumolu Jaganmohan (School of Chemistry,
Univeristy of Hyderabad, Hyderabad, 500 046 India). Tetrahedron Letters 2003,
44(23), 4365-4368 (Eng), Elsevier Science Ltd. Derivaii de benzopiran -4(4H) au
fost cu succes folosii ca noi alchene activate n reacia Baylis-Hillman cuplnduse cu hetero aromaldehide, nitro benzaldehide i derivaii de isatin alturi de
aditivii crora le corespund, derivai din piridin-2-carbox-aldehide, au fost
transformai n noi indolizine fuzate cu cromone I ( R=H, Me ).

Volume 137, Number 23, December 9, 2002

Sections from Chemical Abstracts Volume 137, Number 23

Chemical Abstract
ORGANIC CHEMISTRY SECTIONS
21 through 34
137: 337802s Three component 1,3 dipolar cycloaddition reactions in
synthesis of spiro[pyrrolidine -2,3-oxindoline] derivatives. El-Ahl, AbdelAzis S. ( Chemistry Departament, Faculty of Science, Mansoura University,
Mansoura, Egypt). Heteroatom Chemistry 2002, 13(4), 324-329 (Eng), John Wiley
& Sons, Inc. Regio and stereospecific synteses of serval spiro[pyrrolidine -2,3oxindole] derives. by cycloaddn. Trapping of azomethine ylides generated in situ,
via decarboxylative condensation of isatin with a -amino acids or by raction of
secondary amines with isatin, are reported. 2,6 Dibenzylidenecy-clohexanone,
2-arylidene-1-tetralone, and arylidenemalononitrile derives. Have been efficiently
used a trapping dipoarophiles. The regio and stereochem of the addns are
controlled by both frontier orbital and steric interactions.
137 : 337802s Trei componeni 1,3 - reacii de cicloadiie bipolari
n sintez spiro [pirolidin -2,3'-oxindol] derivat. El-Ahl, Abdel-Azis S. (
Chemistry Departament, Faculty of Science, Mansoura University, Mansoura,
Egypt). Heteroatom Chemistry 2002, 13(4), 324-329 (Eng), John Wiley & Sons,
Inc. S-a raportat capturarea azometimei generat n situ prin condensarea
decarboxilativ a isatinei cu un acid alfa-amino sau prin reacia unor amine
secundare cu isatin : derivai dibenzil-clorhexanon, 2-arylidene-1-tetralone i a
fost utilizat n mod eficient o modalitate de capturare. Regiunile sunt controlate
de orbitele frontale i interaciunile sterice.