Академический Документы
Профессиональный Документы
Культура Документы
Abstract
The draft decision regarding the Euroclassification of cables was
finally approved by the Standing Committee on Construction in
April 2006[1]. After publication in the Official Journal there will
be a three year period of coexistence with existing national test
requirements which will then start to be withdrawn in favour of
the new regulations. The new cable classification system includes
criteria for acid gas. Over the past 5 years considerable effort has
been devoted to validate the scientific basis of the approach. The
results of bench scale fire effluent toxicity assessments of 10
cables are reported and correlated with acid gas data. An
estimation of the component contribution to the fire gas toxicity of
each of the cables, measured under the three fire conditions
indicates that although CO is a significant contributor to fire
effluent toxicity, the presence of acid gases is the major
differentiator between the different types of cables tested. Results
are compared with previously published large scale toxicity data
on 5 of the cables tested in the current program.
The CPD
leads to CE marking.
1. Introduction
1.1
1.2
Our paper concerns the use of acidity criteria within the new
European classification system. The measurement of the toxic
yield of fire effluents and their impact on fire safety is being
considered within ISO Technical Committees. Significant
guidance documents and test methods have been published. The
criteria used for assessing smoke toxicity and how it must be
measured have been defined[8]. Parallel documents appertaining to
cables are currently being considered within the IEC (TC89,
IEC60695 series). It is accepted that, where appropriate, ISO/IEC
norms and test methods will be adopted within European
legislation.
Bench Scale Toxicity Assessment
Scale-up criteria for fire are difficult to define; particularly where
combustion toxicity is involved as product yields may differ by
two orders of magnitude, depending on conditions. The difficulty
in replicating the range of fire conditions found in real fires has
held back the development of bench-scale toxicity testing. Indeed,
in the United States, the underestimation of CO yield in small
scale tests is addressed by simply changing the results to give a
single value for the CO yield of 0.2 g/g in under ventilated
conditions[9] Once the relationship to full-scale fires has been
demonstrated, bench-scale toxicity assessment will provide a cost
effective alternative, particularly for material development and
screening, and ultimately for fire safety engineering.
2. Experimental
Materials. Ten cables were tested. All the cables complied with
the criteria for the specified standard. Five of the cables were also
tested in the large scale experiments completed at LSF10.
Type
Application
Conductor(s)
Insulation
Bedding
Sheath
Data
4x2x0.53mm
PE
None
LSZH1
Data
4x2x0.53mm
PE
None
LSZH
Data
4x2x0.53mm
PE
None
PVC
Cat 7 (SSTP)
Data
4x2x0.58mm
PE Foam
None
LSZH
PVC
None
None
None
LSZH
????
PVC
N07V-K
Energy
1x2.5mm
RZ1-K
Energy
3x1.5mm
In just the same way that large scale burning behaviour is not
easily predicted in small-scale tests, so fire toxicity is highly
dependent on the fire conditions, and particularly the length-scale
of the fire. Of the standard methods used for toxicity assessment,
there are three general types, well-ventilated or open methods,
closed box tests, and flow through methods such as tube furnaces.
Although most bench scale fire tests, such as the cone calorimeter,
are run in well-ventilated conditions, they are generally unsuitable
for estimation of toxic product yields because the high degree of
ventilation coupled with the rapid quenching of fire gases, gives a
high yield of products of incomplete combustion through
premature flame quenching, rather than through vitiation. The
closed box tests, such as the NBS Cup furnace (Potts Pot), the
Radiant Furnace test ASTM E1678 and tests using the NBS
Smoke Chamber (ASTM E662 and ISO 5659-2) give a complete
product yield of burning from well-ventilated right through to
fully vitiated, but without giving any indication of how the yield
varies with fire condition. Sampling from such devices during
burning is possible but this may either deplete the fire gases if
they are not returned to the box, or may change product, for
example by filtration prior to analysis, if they are to be
recirculated. The French railways test (NFX 70-100), is a small
scale (~1g) decomposition apparatus where the products are
analysed and a toxicity index is generated, but the ventilation is
controlled independently of the sample decomposition rate. This
decomposition part of the apparatus is very similar to that of the
RV-K
Energy
3x1.5mm
PVC
NHXMH
Energy
3x1.5mm
XLPE
PO/Chalk/A LSZH
TH
NHMH
Energy
3x1.5mm
PP
PO/Chalk
LSZH1
NYM*
Energy
3x1.5mm
PVC
PVC
PVC
furnace
temperature /C
primary air
flow/l min-1
smouldering
350
1.1
48.9
well-ventilated flaming
650
22.6
27.4
825
2.7
47.3
Gas sampling
furnace
Air in
1.0039
0.5351
0.6113
0.7841
0.7504
0.8146
0.5088
0.7338
mass of bedding
/g
0.2774
0.202
0.2903
mass of
insulation /g
0.283
0.1662
0.1868
0.187
0.2129
0.2464
0.1805
0.1995
0.2666
mass of polymer
used /mg
1004
996
1004
999
1000
997
997
995
999
1000
pH in bubblers
(900 ml)
4.3
5.1
2.2
4.3
2.7
4.5
9.3
2.4
2.5
2.53
pH of
connecting tube
rinsing water
(100 ml)
4.8
5.1
2.2
4.1
2.9
3.8
5.8
2.4
2.3
2.53
final pH (1000
ml)
4.4
5.1
2.2
4.2
2.7
4.5
8.6
2.4
2.4
2.53
conductivity in
bubblers (900
ml) /S mm-1
1.5
0.4
199.9
3.3
66.8
1.3
3.0
150.0
145.0
97.8
conductivity of
connecting tube
rinsing water
(100 ml) /S
mm-1
0.5
4.3
0.3
2.8
38.5
6.2
1.5
151.0
0.2
105.1
final
conductivity
(1000 ml) /S
mm-1
1.4
1.0
181.4
2.9
61.6
1.6
2.8
150.6
131.4
98.5
millimoles of
acid per gram of
polymer used
4.38
0.80
3.22
3.00
Calculated pH
n/a
n/a
2.36
n/a
3.10
n/a
n/a
2.49
2.52
n/a
160
180
1.8
Smouldering
1.6
Well-ventilated flaming
1.4
1.2
1
0.8
0.6
0.4
0.2
0
0
20
40
60
80
100
120
Conductivity/ S mm
Cat 5
UTP(c)
0.7208
(1)
NYM
mass of sheath
/g
FED
FED =
140
200
-1
FED
1.8
1.8
1.6
HCl
1.4
hypoxia
1.2
CO
1
0.8
Smouldering
Well-ventilated flaming
Developed fire - low ventilation
1.6
1.4
0.6
0.4
0.2
1.2
PVC data
RZ1-K
RV-K
Developed 825C
Smouldering 350C
Developed 825C
NO7V-K
Well-ventilated 650C
Developed 825C
Smouldering 350C
Well-ventilated 650C
Developed 825C
Smouldering 350C
Well-ventilated 650C
Smouldering 350C
Developed 825C
NHXMH
power
Well-ventilated 650C
Well-ventilated 650C
Developed 825C
UTP Cat 5
Smouldering 350C
Under-ventilated 825C
Developed 825C
0.6
Smouldering 350C
Developed 825C
Smouldering 350C
Well-ventilated 650C
Developed 825C
Smouldering 350C
Well-ventilated 650C
Developed 825C
Smouldering 350C
Well-ventilated 650C
0.8
Well-ventilated 650C
Smouldering 350C
FED
SSTP Cat 7
0.4
0.2
0
2
pH
1.8
1.6
hypoxia
CO
HCl
1.4
FED
1.2
1
0.8
0.6
0.4
0.2
RZ1-K
RV-K
NYM
NO7V-K
Large scale
Well-ventilated 650C
Large scale
Well-ventilated 650C
Large scale
Well-ventilated 650C
Large scale
Well-ventilated 650C
Large scale
Well-ventilated 650C
5. Conclusions
1.
SSTP Cat 7
2.
3.
4.
5.
The mass loss data for the large scale test shows differences in the
extent of burning for the different cables, which would impact on
the assessment of toxic hazard. While it is outside the scope of
this work, and clearly highly dependent on the fire scenario,
(including details such as the mounting and separation of the
cables) simply multiplying the FED by extent of burning (the ratio
of the mass lost in the large scale test to that in the tube furnace)
gives an indication of the relative toxic hazard for the particular
fire scenario represented by the prEN 50399-2-2 test. This data is
shown in Figure 7.
6. References
[1] CONSTRUCT 04/652 Draft COMMISSION DECISION
Implementing Council Directive 89/106/EEC as regards the
classification of the reaction to fire performance of cables.
[2] CONSTRUCT 04/652 Draft COMMISSION DECISION
Implementing Council Directive 89/106/EEC as regards the
classification of the reaction to fire performance of cables.
1.2
Large Scale
Well Ventilated
0.8
0.6
0.4
0.2
0
RZ1-K
RV-K
NYM
NO7V-K
SSTP Cat 7
J E Robinson
European Association of Flame Retardant Olefinic Cable
Compounds
c/o Borealis Polymers N.V.
Campus Mechelen,
Industriepark Noord,
Schalinhoevedreef 20 C,
B-2800 Mechelen,
Belgium.
GSM:
e-mail:
james.e.robinson@borealisgroup.com
Web:
www.frocc.org
Biography:
James Robinson has been involved for more than 25 years in the
development, manufacture and technical service of polyolefin
products for wire and cable applications. His current post is
Senior Technical Service Engineer within the Borealis Wire and
Cable business.