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PROPERTIES USED IN GAS COMBUSTION SPREADSHEET

Exce Fuel HHV HHV CP, mols / combustible SCO,


l Com MW kcal / Btu / lb mol mols O2 Combustion Reaction
Cell p. gmol CO2 SO2 H20 N2
B10 H2 2.016 68.32 61,000 0 0 1 0 0.5 H2 + 0.5 O2 H20
B11 C1 16.043 212.79 23,874 1 0 2 0 2 CH4 + 2.0 O2 CO2 +2 H20
B12 C2 30.069 372.81 22,317 2 0 3 0 3.5 C2H6 + 3.5 O2 2 CO2 + 3 H2O
B13 C2= 28.054 337.23 21,637 2 0 2 0 3 C2H4 + 3.0 O2 2 CO2 + 2 H2O

B14 C3 44.096 530.57 21,658 3 0 4 0 5 C3H8 + 5.0 O2 3 CO2 + 4 H2O


B15 C3= 42.080 490.20 20,969 3 0 3 0 4.5 C3H6 + 4.5 O2 3 CO2 + 3 H2O
B16 C4 58.123 686.60 21,265 4 0 5 0 6.5 C4H10 + 6.5 O2 4 CO2 + 5 H2O
B17 C4= 56.107 647.39 20,769 4 0 4 0 6 C4H8 + 6.0 O2 4 CO2 + 4 H2O

B18 C5 72.150 844.33 21,064 5 0 6 0 8 C5H12 + 8.0 O2 5 CO2 + 6 H2O


B19 C5= 70.134 804.43 20,646 5 0 5 0 7.5 C5H10 + 7.5 O2 5 CO2 + 5 H2O
B20 C6 86.177 1,002.57 20,941 6 0 7 0 9.5 C6H14 + 9.5 O2 6 CO2 + 7 H2O

B21 H2S 34.076 134.47 7,103 0 1 1 0 1.5 H2S + 1.5 O2 SO2 + H2O
B22 COS 60.070 130.50 3,910 1 1 0 0 1.5 COS + 1.5 O2 CO2 + SO2
B23 CO 28.010 67.63 4,346 1 0 0 0 0.5 CO + 0.5 O2 CO2

B24 CO2 44.010 0 0 0 0 0 0 0 non-combustible


B25 O2 31.999 0 0 0 0 0 0 0 non-combustible
B26 N2 28.013 0 0 0 0 0 0 0 non-combustible
B27 H2O 18.015 0 0 0 0 0 0 0 non-combustible
B28 NH3 17.030 91.44 9,674 0 0 1.5 0.5 0.75 NH3 + 0.75 O2 0.5 N2 + 1.5 H2O

Abbreviations: Comp.= Component, CP = Combustion Products, SCO = Stoichiometric Oxygen, xs = Excess Air, avg. = average
Molecular weights (MW) calculated using: C = 12.011, H = 1.0079, O = 15.9994, N = 14.0067, S = 32.06
Higher heating values (HHV): C4 is avg. of nC4 and iC4; C4= is avg. of all C4= species; C5 is avg. of nC5 and iC5; C5= is avg. of all C5= species
HHV data from: CRC Handbook of Chemistry and Physics, 56th Edition; Perry's Chemical Engineers' Handbook, 6th Edition; and Phillips Petroleum
Company, Bulletin 521, 1962

O2 in combustion air = (1 + %xs / 100) (Total SCO) (O2 in fuel gas)


N2 in combustion air = (79/21) ( O2 in combustion air)
Wet Flue Gas: CO2 = (Total CO2 in CP) + (CO2 in fuel gas)
N2 = (Total N2 in CP) + (N2 in fuel gas) + (N2 in combustion air)
H2O = (Total H2O in CP) + (H2O in fuel gas) + (H20 in combustion air)
SO2 = (Total SO2 in CP)
O2 = (%xs / 100) (Total SCO)